Abstract: A process is provided for the recovery of hydrocarbons, and especially heavy hydrocarbons, from oil-bearing strata, wherein mining liquids are injected at a bottom level and removed at an upper collecting level together with displaced liquid hydrocarbons, and the mining liquids are separated from the product hydrocarbons at the well-head and re-injected. The mining liquids may consist, in part, of an unrefined fraction from product cracking or semi-refining carried out in the vicinity of the well head, together with inorganic solvents, and are injected under pulsating pressure at a temperature not exceeding 100.degree. C. The strata can be deliberately fractured horizontally at the injection and collecting levels to promote desirable flow patterns, the fractures being propped open by means of a particulate filling medium. Hot gas under pressure can be injected at the boundaries of the working zone to create barriers to flow by the melting and re-solidifying of heavy hydrocarbons.

Abstract: One or more in situ oil shale retorts are alternately operated in a combustion mode and a purge mode with a steam or water purge to produce a greater yield of shale oil. Hydrogen-rich off gases emitted during purging are mixed with the shale oil in a reactor in the presence of a catalyst, after being stripped of carbon dioxide, to produce a high quality shale oil. The reactor off gases, purge mode off gases, and/or hydrogen gases can also be used as the purge gas.

Abstract: A method is disclosed for forming a carbon dioxide-containing mixture which is miscible with crude oil. The method comprises maintaining a mixture of crude oil and carbon dioxide in an extraction zone at a temperature and pressure such that multiple phase equilibrium is achieved therebetween. A carbon dioxide-rich phase that includes a mixture of carbon dioxide and hydrocarbons is withdrawn and is miscible with the reservoir crude oil when injected into the reservoir from which the crude oil was produced.

Abstract: The disclosed invention is a one step or two step process for extracting surfactant from produced emulsions of oil, water and surfactants, concentrating the surfactants into a relatively small volume emulsion middle phase that can be reutilized in surfactant flooding and separating substantial quantities of salable oil from the emulsions.In the two step process, a sulfonated alkyl benzene is added and mixed with the emulsion, which partitions upon settlement into three phases, a clean oil phase, a first microemulsion middle phase and an aqueous phase. An ethoxylated phenol is then added and mixed to the first middle phase to yield at least two more similar phases with the middle phase containing the concentrated surfactants. Alternately, the sulfonated alkyl benzene and the ethoxylated phenol can be combined and added in a one step extraction process.

Abstract: Disclosed is a method for extracting surfactants from produced emulsions of oil, water and surfactant and concentrating the surfactants into a relatively small volume, surfactant-rich, middle phase that can be reutilized in surfactant flooding. A first extraction is performed with an aqueous solution of a first extracting compound, which yields three phases after separation, a substantially water-free and surfactant-free crude oil phase, a first surfactant-rich middle phase and an oil-free aqueous phase. The first extracting compounds employed are the alkali metal salts and ammonium salts of cumene sulfonate, propyl benzene sulfonate, ethyl benzene sulfonate, methyl ethyl benzene sulfonate, diethyl benzene sulfonate, methyl propyl benzene sulfonate, xylene sulfonate and dicyclopentadiene sulfonate.

Abstract: A method and apparatus for oil field steam production and use. Heated refractory particles are flowed through a steam generator in heat exchange relation with well water to generate steam. In accordance with one aspect of the invention, the steam is flowed into a well to heat oil in the well. In accordance with another aspect of the invention, the refractory particles are heated by flowing through a solar receiver in heat exchange relation with solar radiation.

Abstract: An invention for extracting surfactants from produced emulsions of oil, water and surfactant and concentrating the surfactants into a relatively small volume, emulsion phase that can be reutilized in surfactant flooding. The two phases left behind in the extraction are a substantially water-free and surfactant-free crude oil phase and an oil-free aqueous phase. The extracting compounds employed are the alkali metal salts and ammonium salts of cumene sulfonate, propyl benzene sulfonate, ethyl benzene sulfonate, methyl ethyl benzene sulfonate, diethyl benzene sulfonate, methyl propyl benzene sulfonate, xylene sulfonate and dicyclopentadiene sulfonate.

Abstract: A process of utilizing natural gas to obtain a miscible drive fluid for low pressure reservoirs is described. The process involves upgrading natural gas to ethane, propane and butane constituents which are fabricated into a mixture which is miscible at the reservoir conditions. The process is operated so as to maximize the reuse of the upgraded miscible drive fluid and therefore lower the cost of enhancing the oil recovery from a low pressure reservoir.

Abstract: A method is disclosed for increased recovery of crude petroleum from a subsurface formation containing petroleum deposits. The method combines steam and gas distillation drive using foam to divert the steam/gas and to establish a thermal barrier against heat loss into the surrounding formations. A noncondensable gas is injected with or after steam to produce a distillate bank which is moved through the formation from an injection well toward a production well. Fluids produced at the production well are monitored to provide information for control of the injected materials at the injection well.

Abstract: An in-situ process for recovering hydrocarbons from a diatomite-type formation which comprises contacting the diatomite formation with a C.sub.4 -C.sub.10 alcohol and thereafter displacing the hydrocarbon-alcohol mixture with an aqueous alkaline solution towards a production well. The aqueous alkaline solution can be displaced with additional solution or another suitable medium such as a connate water drive.

Abstract: A method for in-situ coal gasification to recover a product gas having a predetermined H.sub.2 /CO ratio by introducing controlled amounts of carbon dioxide recovered from the product gas along with steam and oxygen injected into the coal deposits. The H.sub.2 /CO ratio of the product gas is preferably maintained within the range of 1.5 to 4.0.

Abstract: A process is disclosed for the extraction and generation of solvent for continuous injection into a reservoir or subterranean deposit for the recovery of crude oil or liquified coal. Solvent contained in the recovered liquid mixture of organic compounds is vaporized by the bubbling and agitation of atmospheric air through a tank in which the recovered liquid mixture has been pumped. Various solvent compounds such as ethers or aromatic hydrocarbons are vaporized and drawn off from the tank by a suction pump or compressor and continuously reinjected into the deposit through an injection well. Apparatus in the form of a vertically disposed tube having an ambient atmospheric inlet is disposed within the solvent generator tank. Conventional storage tanks may be converted for the process by utilizing a telescoping tube arrangement which may be installed through a standard gaging or inspection port in the tank.

Abstract: Bitumen is recovered from a subterranean formation of heavy oil sands traversed by at least one injection well and at least one associated production well in fluid communication with each injection well. Air in admixture with a heating fluid selected from the group consisting of low quality steam, hot water, or mixtures thereof, and an alkalinity agent are injected into the formation by way of each injection well. The subterranean heavy oil sands are thereby raised to a temperature in the range of about 200.degree. to 350.degree. F. A portion of the bitumen at reduced viscosity is oxidized without burning to produce additional petroleum acids which are neutralized to form emulsifying agents. The condensed steam and/or hot water contacting the bitumen form with it a bitumen-water emulsion. By pressure from the injected mixture of air and heating fluid, the resulting bitumen-water emulsion is then recovered from each production well.

Abstract: Crushed raw oil shale is fed into a geothermal compartment or reservoir under oil shale retorting conditions using the reservoir as a source of heat for retorting. After retorting is completed hydrocarbon products are removed from the compartment or reservoir. The resultant spent shale is subsequently used to fill voids in the reservoir. Hydraulic fluids are then placed into the compartment or reservoir and sufficient pressure applied to fracture the reservoir or compartment causing another geothermal compartment or reservoir to be formed.

Abstract: A method for the recovery of viscous crude oil from a subterranean, viscous crude oil-containing formation penetrated by an injection well and a spaced-apart production well wherein produced crude oil recovered from the production well is subjected to a visbreaking operation to produce a hot visbroken crude oil solvent reduced in viscosity and injecting the hot visbroken crude oil solvent into the formation via the injection well to reduce the viscosity of oil remaining in the oil formation and thereby enhance recovery of oil from the formation. A predetermined amount or slug of the hot visbroken crude oil solvent may be injected into the formation followed by injection of another fluid such as a gas or an aqueous fluid to drive the hot solvent and the oil through the formation toward the production well for recovery of fluids including oil.

Abstract: Thermal treatment apparatus for downhole deployment comprising a combustion stage with an elongated hot wall combustion zone for the substantially complete combustion of the fuel-air mixture and an ignition zone immediately upstream from the combustion zone in which a mixture of atomized liquid fuel and air at or below stoichiometric ratio is ignited; together with a water injection stage immediately downstream from the combustion zone through which essentially partuculate free high temperature combustion products flow from the combustion zone and into which water is sprayed. The resulting mixture of steam and combustion products is injected into an oil formation for enhancing the speed and effectiveness of reservoir response due to physical, chemical, and/or thermal stimulation interactions.

Abstract: A flame front is ignited and passed through an underground oil shale retort to produce shale oil. The flame front is supported by a specially blended feed gas consisting essentially of air, steam and retort off gases. Product yield and quality are increased by varying the volumetric ratio of air, steam and retort off gases in the feed gas during retorting in proportion to the oil yield, or the relative richness, leanness and kerogen content of the oil shale being heated by the flame front, or in proportion to the amount of carbon residue on the retorted shale being combusted.

Abstract: A method for conditioning a flow of hot geothermal brine or aqueous liquid to reduce scale formation by pH-sensitive, dissolved materials includes injecting into the flow of brine or liquid an anhydrous, halogenated acid precursor which hydrolyzes in the brine or liquid to form a hydrohalic acid. The acid precursor, which may be tetrachloromethane, is preferably injected into an extraction well at the vicinity of the producing formation at a rate reducing the pH of the brine or liquid about one pH unit, or to about 3.5, near the injection point. The method also provides for increasing, if necessary, the acid precursor hydrolysis rate in the brine or liquid by atomizing the injected acid precursor with a pressurized fluid, preferably gaseous nitrogen.

Abstract: Greater product yield and quality as well as simplified gas recovery can be attained by a huff and puff process for retorting oil shale. The process can be advantageously carried out in in situ retorts under ground as well as in surface retorts above ground. In the process, an active retort of raw oil shale is retorted without prior combustion of oil shale therein with retort off gases, which have been heated in a spent shale retort. In the preferred mode, retort off gases from the active retort and air are alternately injected into the spent retort to cyclically heat the off gases and combust the coked shale. The retort off gases can be deoiled and optionally scrubbed of carbon dioxide and hydrogen sulfide before being heated in the spent retort.

Abstract: The disclosed invention is a method for efficiently recovering viscous petroleum from hydrocarbon formations, particularly consolidated tar sand formations. A superheated paraffinic solvent under elevated pressure and temperature is injected into the formation. Thereafter, the formation is rapidly produced until pressure is depleted. The injection and production depletion cycle is then repeated.

Abstract: Method for the underground gasification of solid fuels in which an underground fuel deposit is initially opened up and then converted into a gaseous fuel by means of a gasification medium. The opening of the fuel deposit is effected by treatment with a gas which is in the supercritical state, which takes on the volatile organic substances of the solid fuel and the water contained in the solid fuel. The dissolved organic compounds and the water are separated from the charged supercritical gas phase above ground in at least two fractions by pressure reduction and/or a change in temperature.

Abstract: A process for increasing recovery of oil from oil-bearing earth formations wherein H.sub.2 S from sour wellhead gas is oxidized to SO.sub.3 which in turn is reacted with a petroleum hydrocarbon mixture to produce a petroleum sulfonate. The petroleum sulfonate is incorporated into an oil recovery enhancing fluid and introduced through an injection well into an oil-bearing earth formation to displace oil toward a production well.

Abstract: A portion of crude shale oil produced from an in situ oil shale retort is blended with shale oil produced from a Tosco II retorting process to produce a blended shale oil composition having a pour point lower than the pour point of the shale oil produced from the Tosco II retorting process.

Abstract: A process and apparatus for recovering oil from an oil-bearing formation which comprises the steps of injecting into the oil-bearing formation a heated aerosol fog of organic chemicals which are soluble in oil, the fog preferably being at an elevated temperature and pressure. The heated aerosol fog penetrates the formation dissolving caked oil and oil trapped within the formation thereby increasing its permeability. The dissolved oil is extracted from the formation along with the injected chemicals and the chemicals are thereafter separated from the oil.

Abstract: A process for the production of heavy oil from a subterranean oil reservoir by the injection of a hot aqueous fluid into the reservoir and the injection of a diluent solvent down the production well to produce a blend of solvent and oil having a decreased viscosity. The reservoir oil has a density greater than the density of water. The diluent solvent has a density such that the density of the resulting blend recovered from the production well also has a density greater than the density of the water. The water produced from the production well is separated from the blend and the blend then fractionated to recover a solvent fraction of the requisite density. This solvent fraction is then returned to the production well to produce additional blend within the well in a continuation of the process.

Abstract: A method for recovering viscous oil from a subterranean, viscous oil-containing formation by initiating an in-situ combustion operation in the formation using a mixture of oxygen and an inert gas having a low oxygen concentration, preferably about 21 vol. %. After a predetermined period of time, the oxygen concentration is increased to a predetermined higher level, preferably within the range of 95 to 99.5 vol. %. Once the oxygen concentration has reached the desired value, water may be simultaneously injected continuously or intermittently. After a predetermined period of time, produced combustion gas enriched in carbon dioxide separated from the produced oil is compressed and recycled as a diluent for the injected oxygen in place of the inert gas.

Abstract: Viscous oil is recovered from a subterranean, viscous oil-containing formation by injecting a slug of CO.sub.2 carbonated water containing a CO.sub.2 solubility promoter, a slug of a CO.sub.2 solubility demoter, and a water drive to displace the mobilized oil to a production well for recovery.

Abstract: Shale oil gas is recovered in situ from water-flooded, naturally porous, subterranean oil shale formations by injecting superheated steam under pressure into such formations through injection boreholes extending into the formations. Heat is transferred from the superheated steam to the oil shale, thereby in effect retorting the oil shale and converting the organic (kerogen) content thereof into oil in liquid or vapor form, usually accompanied by some gas. The released shale oil and gas are collected in the water naturally occurring in such a formation and in water resulting from the condensation of the injected steam and are recovered through extraction boreholes by moving both the water and the collected shale oil products to the surface through such boreholes. This is normally effected by pressure of the injected steam, but may be aided, if necessary, by pumping from the extraction boreholes.

Abstract: Oil shale is retorted, preferably in situ, by passing velocity flow of super-heated air through one or more conduit-like passages in direct contact with exposed surfaces of oil shale. Kerogen pyrolysis products are recovered by condensation of the vapors and collection of the condensate and by collection of the gases and separation of the valuable gases from the normally waste gases. Some of the waste gases may be recycled with the air for controlling combustion of the kerogen content of the shale.

Abstract: Hydrogen sulfide is selectively oxidized in a gas stream containing at least 20 mol percent a carbon dioxide using an iron catalyst, preferably Fe.sub.2 O.sub.3 supported on a ceramic honeycomb support.

Abstract: An enhanced recovery process in which liquid sulfur is burned in an oyxgen-containing gas underground to form SO.sub.2. The SO.sub.2 may itself act as a drive fluid for the recovery of oil or it may react with limestone in the formation to form CO.sub.2, an alternate drive fluid.

Abstract: Low heating value gases are combusted substoichiometrically in two combustion zones in series in contact with two different supported platinum catalysts in which the concentration of platinum in the catalyst in the first zone is higher than the concentration of platinum in the second catalyst. The combusted gas of reduced carbon monoxide can be directly vented to the atmosphere after energy has been extruded from it for a useful purpose.

Abstract: A method for in situ separation of bitumen from bitumen-bearing subterranean deposits includes the step of injecting a solvent composition into the deposit. The solvent composition must have an inverse critical solution temperature in a two-phase system with water and be selected from a particular group of amines that includes triethylamine and diisopropylamine. When the solvent composition contacts the bitumen in the deposit, the bitumen is dissolved by the solvent. Thereafter, the bitumen/solvent mixture is removed and separated into a bitumen component and a solvent component. The bitumen is thereafter processed to yield a usable petroleum product.

Abstract: Hydrocarbon liquids and/or gases are recovered from thick underground deposits of oil-bearing limestone or dolomite by drilling two or more boreholes from the earth's surface into the lower part of the deposit, establishing communication between the boreholes, burning the oil in said limestone or dolomite in an area between the boreholes to decompose the alkaline earth carbonate into alkaline earth oxide, flushing out the alkaline earth oxide formed by the combustion with water to form a cavity, collapsing the overlying oil-bearing limestone or dolomite into the cavity to form a rubblized zone extending vertically to a point near the upper boundary of the deposit, driving a flame front vertically through the rubblized zone to liberate hydrocarbon liquids and produce gases, and recovering the liquids and/or gases from the rubblized zone.

Abstract: The combustible component of a gas stream of low heating value is combusted using less than a stoichiometric amount of oxygen with minor production of carbon monoxide due to the use of an oxygenation catalyst comprising at least three metals in a perovskite-type crystal structure. This combusted gas can be directly vented to the atmosphere after energy has been extracted from it for a useful purpose.

Abstract: An enhanced petroleum oil recovery method for increasing the quantity of oil recoverable from an underground deposit thereof is provided which involves injecting into a first point in such deposit a liquid mixture of low molecular weight, light hydrocarbons; alternately reducing and raising the back pressure exerted on said deposit so as to alternately induce boiling and condensation of said light hydrocarbon mixture; recovering from a second point in said deposit under controlled back pressure a mixture of said light hydrocarbons and oil; separating the light hydrocarbons from the extracted petroleum oil by distillation; and then recycling the light hydrocarbons to the injection step. Another aspect of the invention involves utilizing the essential features thereof for the recovery of oil from oil-bearing sands, e.g. tar sands, which are mined and brought to the surface.

Abstract: The method of extracting hydrocarbons from an underground deposit of material containing hydrocarbons, which comprises injecting aqueous solutions of low resistivity into at least a portion of the deposit, heating a portion of the deposit underground by means of a varying magnetic field and controlling the flow of fluids from the heated portion of the deposit to the delivery point until the temperature of the heated portion of the deposit has reached a selected value at which substantial pyrolysis occurs of hydrocarbons released from the deposit. The value of temperature resulting is less than the break-out pressure of the overburden. When the selected temperature and the pressure have been reached the flow of fluids from the heated portion of the deposit is controlled by a pressure controller to maintain the pressure until heating stops. At this time the vapor pressure is reduced to atmospheric pressure.

Abstract: Disclosed is a method and apparatus for the enhanced recovery of liquid hydrocarbons from underground formations, said method comprising recovering a mixture comprising carbon dioxide and contaminants comprising hydrocarbon, hydrogen sulfide, or mixtures thereof, from an underground formation; combusting said mixture with an oxygen enriched gas to form a concentrated carbon dioxide stream; and injecting at least a portion of said concentrated carbon dioxide stream into an underground formation to enhance recovery of liquid hydrocarbon.

Abstract: Oil recovery from formations is effected using a gas stream containing steam, carbon dioxide and nitrogen which is injected into the formation to form a water-oil mixture which is removed from the formation. The gas stream is formed by wet oxidation of a carbonaceous material which includes residual oil in the aqueous material remaining from oil separation.

Abstract: A method of heating a hydrocarbon material contained in a recovery zone in an underground hydrocarbon material-bearing formation to reduce the viscosity thereof for facilitating recovery of the hydrocarbon material, in which a gaseous penetration medium comprising a gaseous working fluid and a carrier gas, is fed into the formation at a penetration pressure sufficient for penetration of the recovery zone, the working fluid being a water soluble gas which generates heat of solution upon absorption in an aqueous medium, and in which the partial pressure of the working fluid in relation to the penetration pressure and the temperature prevailing in the recovery zone is controlled to inhibit working fluid condensation but to provide for absorption of working fluid by water present in the formation to release heat for heating the hydrocarbon material in the recovery zone.

Abstract: A process for enhanced oil recovery by gas injection into oil-bearing formations which comprises wet oxidizing combustible carbonaceous materials with oxygen, air or a mixture of oxygen and air to obtain a gas comprising a mixture of water vapor and carbon dioxide (and nitrogen in the event air is used), substantially free of oxides of sulfur and nitrogen; injecting said gaseous mixture into an oil-bearing formation to produce a mixture of oil and water; extracting said mixture of oil and water from the oil-bearing formation; separating the water from the latter mixture; and recycling the water to the wet oxidation reactor. Residual oil in the recycled water provides additional fuel for the wet oxidation reaction, and at the same time the need for costly water treatment is eliminated.

Abstract: Land-fill gas containing principally methane and carbon dioxide is injected into a partially depleted oil reservoir to stimulate crude oil production. Solution of injected gas, especially carbon dioxide, in the crude oil materially reduces its viscosity which together with pressurization increases oil flow. Gas separated from produced oil is fractionated into valuable methane-rich gas and carbon dioxide-rich gas which is recycled to the oil reservoir. Part or all of the land-fill gas may be first fractionated and the resultant carbon dioxide-rich gas then injected into the reservoir.

Abstract: The recovery of petroleum produced from an oil reservoir is enhanced by injecting water such as from a geopressured aquifer having a natural gas content at or near saturation at a temperature above 300.degree. F. into the oil reservoir at a flow rate sufficient to develop a back-pressure in the oil reservoir equal to between about 80% of its fracture pressure and a pressure below its fracture pressure and producing oil from the oil reservoir when the injection of water necessary to maintain the back-pressure below the oil reservoir fracture pressure drops below a predetermined level. The recovery of petroleum also is enhanced by using sand screening means to complete a portion of the well bore penetrating into the oil reservoir and a straddle packer assembly means which can be raised and lowered relative to the screening means.

Abstract: A method is disclosed for restoring a clay rich aquifer which has been solution mined with ammonium ions. Calcium carbonate is precipitated from a solution pumped through the aquifer by the addition of calcium oxide, calcium hydroxide, or a mixture thereof in quantities sufficient to raise the pH to at least about 9.5. The precipitated calcium carbonate is separated from the solution and the ammonium ion is then removed from the solution by standard techniques. The solution is recycled through the aquifer and these steps are repeated until the bicarbonate ion concentration has been reduced to such an extent that the addition of at least one soluble salt of calcium, magnesium, or potassium to the solution does not result in precipitation of calcite underground, plugging the aquifer. Recycling with the addition of the soluble salt is continued until the ammonium ion concentration is reduced to a desired level. Finally, residual amounts of the salt are removed from the aquifer using standard techniques.

Abstract: Disclosed are systems for removing hydrocarbons from subterranean deposits thereof. A fluid-impervious barrier screen is formed to isolate parts of the deposit or to isolate the deposit from adjacent fluid-permeable earth formations. The barrier screens are formed by fracturing a vertical zone in the formation by micropercussive fracturing or detonation of microexplosive charges in a series of closely-spaced bore-holes to form a vertically extending fractured plane. The fractured plane is sealed with a sealing medium to form a fluid-impervious screen.Hydrocarbons trapped in the enclosed deposit zone are flushed from the formation by recirculating a fluid medium such as superheated brine and/or hot gases through the enclosed deposit zone under sufficient pressure to cause turbulent flow through the pore formations and to relieve the overburden pressure. The flushing medium may be injected in a series of pressure pulses to force the fluid through the pores by hydraulic ramming.

Abstract: The present invention provides a multistage process for the removal of tar, water and particulate contaminants from a hot product gas resulting from the in-situ gasification of an underground coal deposit, which comprises passing the hot product gas through a first heat exchange zone in indirect heat exchange relationship with a gasification gas to thereby sufficiently reduce the temperature of the product gas so as to separate the tar present in the product gas and provide a substantially tar-free product gas. Thereafter, the tar-free product gas is withdrawn from the first heat exchange zone and passed through at least one subsequent heat exchange zone in indirect or direct heat exchange relationship with a heat exchange material which has a lower temperature than the product gas. A major portion of the water originally present in the hot product gas is removed in the subsequent heat exchange zone.

Abstract: An improved method of restoring a subterranean clay-containing formation having ammonium ions absorbed on the clay, wherein the formation is flushed with a halogenated restoration fluid having a halogen therein which reacts with the ammonium ion in the formation to decompose the ammonium ions is disclosed. The barren ammonia-containing restoration fluid, after it passes through the formation, is withdrawn, reconstituted and recycled as fresh restoration fluid back into the formation. The barren fluid is treated with an appropriate base to raise the pH to a highly alkaline level, the treated highly alkaline barren fluid is passed through an airstripping tower to strip substantially all the ammonia from the fluid, chlorine gas is added to the fluid from which the ammonia has been stripped, while controlling the amount of chlorine to produce a reconstituted restoration fluid of a predetermined pH level. Finally, the reconstituted restoration fluid is recycled back into the formation.

Abstract: A process and installation for the flooding of petroleum deposits and oil shale and, more particularly, through the use of dispersions of non-ionogenic, boundary surface-active materials in water as the flooding medium. For the flooding of petroleum-hydrocarbon materials from petroleum deposits and oil shale there can be utilized dispersions of non-ionogenic, boundary surface-active glycolipids, and such preferred structures can be employed which are produced from hydrocarbon mixtures as the C-source. This is effected in two stages with predetermined technological measures. In the first stage, there are initially produced glycolipids through microorganisms with alkane mixtures under predetermined parameters in semi- or continual process cycles and, in the second stage, separated from the cellular material through temperature, pH, osmotic shock. The formed glycolipids can also be separated from the cellular material with unpolarized, organic solvent media.

Abstract: An improved surfactant waterflood method for the recovery of oil from a subterranean reservoir utilizing an anionic surface-active agent wherein an aqueous postflush slug containing a nonionic solubilizer is employed to minimize retention of the surface-active agent in the reservoir matrix.

Abstract: Treatment of emulsions of oil and water produced from surfactant recovery operations whereby the produced emulsions containing surfactants are demulsified and the surfactants are recovered in the water phase.