Abstract: Heavy oil from underground oil sands or tar sands is liquified with recirculation of superheated water and when brought to the ground surface is then wet oxidized for its heat value. The sulphur content of the products of wet oxidation is then wet reduced to elemental sulphur for by-product. The carbon dioxide gas generated as a product of wet oxidation is injected back to wells for its value as a diluter of the oil. Heat produced from wet oxidation is used for useful work at wells site.

Abstract: Production fluid from a well and emulsion breaking chemicals enter a settling vessel where much of the fluid separates into distinct levels by gravity with water at the bottom, an oil-water emulsion above the water, oil-with-emulsion above the emulsion, and gas above the oil-with-emulsion. The oil with the emulsion has two to five percent emulsion in it. The oil-with-emulsion flows over a weir into a weir box and then into the inlet of a centrifugal, pitot separator which breaks the emulsion contained in the oil by the action of a centrifugal force field to produce distinct streams of oil and water. The water feeds back into the vessel and the oil goes to storage. In the event that the emulsion feed to the separator is insufficient, the oil-with-emulsion level in the weir box falls and oil recirculates from the separator into the vessel to raise the level of oil-with-emulsion. Water leaves the vessel as required to maintain an appropriate water-emulsion interface level.

Abstract: Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. Dilute carbon monoxide-containing streams, as from underground coal gasification with air or the effluent from blast furnace operations, can be used without pretreatment to convert the carbon monoxide and/or to separate inert gases therefrom. Conversion of the active surface carbon with high pressure steam enables a high pressure product methane stream to be generated without expensive compression equipment and high energy consumption. Nickel, cobalt, iron, ruthenium, rhenium and alloys thereof are preferred catalysts, with the surface area thereof being preferably at least about 10 m.sup.2 /gr.

Abstract: A process and apparatus for removing an impurity from a gas by means of selective absorption of a gas impurity by a suitable absorbent. The absorbent and gas are contacted in a cocurrent flow contacter which is submerged in the absorbent. The flow of the absorbent in the absorber can be induced by means of the dispersion of the gas in the absorbent thereby avoiding the need for pumps or other means to induce circulation. The process and the apparatus can be used for the removal of carbon dioxide from natural gas with the use of salt water, e.g., sea water as the absorbent. The invention is specially useful for removing carbon dioxide from natural gas obtained from a natural gas well located in off shore waters that produces a gas with a high concentration of carbon dioxide as the apparatus can be erected on the ocean floor and use the surrounding sea water as absorbent.

Abstract: A process and apparatus for removing an impurity from a gas by means of selective absorption of a gas impurity by a suitable absorbent. The absorbent and gas are contacted in a contacting zone which is divided into a plurality of compartments with the absorbent and gas flowing cocurrently in each individual compartment. The overall system, however, is a countercurrent flow system wherein the absorbent flows downwardly and the gas flows upwardly. The process and the apparatus can be used for the removal of carbon dioxide from natural gas with the use of salt water as the absorbent. The invention is especially useful for a natural gas well located in offshore waters that produces a gas with a high concentration of carbon dioxide as the apparatus can be erected on the ocean floor and use the surrounding sea water as absorbent.

Abstract: A method for producing substantially pure carbon dioxide in a single phase at the surface from a subterranean formation. A pump means, e.g., electrically driven, submergible, centrifugal pump system, is positioned downhole in a carbon dioxide production well. The carbon dioxide flows from the formation to the inlet of the pump means wherein the carbon dioxide is compressed to raise the pressure to values greater than the critical pressure of the produced carbon dioxide plus the amount of pressure that the carbon dioxide will lose due to (a) the static fluid head above the pump means and (b) flow friction from the pump means to a central processing and compression station on the surface. By so boosting the pressure within the well, the carbon dioxide will be produced at the surface at a pressure greater than the critical pressure of the produced carbon dioxide, thereby insuring the carbon dioxide will be in a single phase, supercritical state.

Abstract: Methods of and apparatus for recovering bitumen from tar sands and the like in which the tar sand is mechanically dislodged from the formation in which it is deposited and in which a solvent for the bitumen is mixed with the mined material to reduce the viscosity of the bitumen and thereby facilitate the transfer of the mined material to an operation where the bitumen is separated from solid components of the tar sand.

Abstract: A separation compartment of a multiphase separation vessel receives production fluid from a petroleum well and that fluid separates by gravity into the gas, oil and water phases in the vessel. An adjustable siphon leads from a water space in the separation compartment to a discharge compartment of the vessel. The level of the discharge from the siphon determines the elevation of an oil phase-water phase interface within the separation compartment and the presence of the desired of the fluid phases at a pickup for power fluid. The siphon includes a removable line that permits a change in the elevation of the outlet of the line into the discharge compartment. Preferably, the discharge compartment comprises an upstanding pipe, the top of which acts as a weir for receiving oil from the separation compartment. Oil from the vessel may pass through a cyclone for further separation of solids from the oil and then introduced by a pump back into the well to act as the power fluid for the well.

Abstract: A method and system for dewatering gas wells on an intermittent, cyclical, period which operates to eject water from the well without loss of gas from the well, or inordinate shut down delays. The said method and system for dewatering gas wells includes time controlled valves and the pressure differential between the tubing and the casing to periodically dewater the well, without the ususal loss of gas.

Abstract: Oil is recovered from underground reservoirs using hydrocarbons produced from cracking equipment located near the site. The equipment is operated at pressures proximate existing underground formation pressure to produce hydrocarbons for direct injection into the formation with reduced or no further compression. The hydrocarbons are injected at selected locations in the reservoir to pressurize the field, effectively reduce the oil viscosity and cause its flow into production wells. Specialized field cracking equipment, such as units for simple, small scale, low fouling operation that circulate heavy coke slurries, may be used to produce the hydrocarbons for injection.

Abstract: A method for preventing the deposition of sulfide and/or sulfate scale during the production of a hot two-phase geothermal fluid which contains hydrogen sulfide, barium heavy and/or transition metals, and at least a critical minimum amount of calcium in solution. Gaseous oxygen is injected into the geothermal fluid at a critical rate to selectively oxidize the hydrogen sulfide to intermediate sulfide oxidation products, such as thiosulfates. Thereafter the geothermal fluid is separated into gaseous and liquid phases. Where iron is present in the geothermal fluid, the degree of turbulence induced during the oxidation step is selectively controlled in order to prevent the deposition of iron pyrites.

Abstract: Crude shale oil produced by in situ retorting of oil shale can contain from about 1 to 2% sulfur by weight, the sulfur being distributed widely through the lower and higher boiling fractions of the shale oil. Substantially non-condensible sulfur containing gas such as hydrogen sulfide is evolved from such crude shale oil by maintaining such shale oil at an elevated temperature in the substantial absence of added reagent, with the maximum temperature below thermal decomposition temperatures of such shale oil for sufficient time to lower the sulfur content of the shale oil.

Abstract: A sewage treatment process wherein sewage is passed into a deep subterranean shaft is improved by passing a liquor of the sewage into the subterranean shaft through an inner shaft which extends only partway down into the subterranean shaft. Located at the lower proximity of the inner shaft is a mixing shaft. The mixing shaft extends from the lower end of the inner shaft to a point near the bottom of the subterranean shaft. Incorporated into the mixing shaft are a plurality of liquor mixing nozzles. The descending sewage liquor passes downwardly through the mixing nozzles to the bottom of the subterranean shaft. It then ascends upwardly in the subterranean shaft. The action of the descending liquor through the nozzles entrains ascending liquor from the subterranean shaft back into the descending liquor. This recirculates the liquor in the bottom of the shaft allowing for extended contact time of the liquor with the microorganisms used in the liquor to aerobically digest the sewage.

Abstract: Natural gas taken from a gas well is loaded continuously and at a preselected, generally uniform rate into a movable separate pressure vessel means until such is filled with a discrete batch of natural gas at a pressure in excess of 800 psia, whereupon it is replaced with another separate pressure vessel means, with no interruption of gas flow. The filled, movable vessel means is then transported to an off-loading terminal. Well shock is thus controlled, and maximum natural gas recovery obtained. A generally uniform flow rate is obtained by a regulating valve, when well head pressure exceeds about 800 psia, and by a compressor when the well head pressure is below such value.

Abstract: Viscous petroleum including bitumen may be recovered from unconsolidated sand formations such as tar sand deposits by hydraulic mining. Hot water of steam and an amine are introduced into the subterranean deposit with sufficient velocity to dislodge bitumen and particles of sand therefrom. The process is a single wellbore operation using rotatable vertically moveable injection string with one or more jets near the bottom thereof, with separate return flow path to surface, the inlet to which may be on the bottom of the injection string. The injection string may be raised or lowered while rotating and jetting so the full vertical thickness of tar sand interval is contacted by aqueous mining fluid. Jet pump may be used to pump petroleum to surface. The aqueous hydraulic mining fluid comprises hot water or steam and an amine having the following formula:R.sub.1 R.sub.2 NR.sub.3wherein R.sub.1 and R.sub.2 are each hydrogen or a C.sub.1 to C.sub.6 and preferably a C.sub.2 to C.sub.

Abstract: A crude shale oil is produced by in situ retorting of oil shale in a fragmented permeable mass of formation particles containing oil shale in an in situ oil shale retort in a subterranean formation containing oil shale. A combustion zone is advanced through the fragmented mass by introducing an oxygen containing gas to the mass on the trailing side of the combustion zone and withdrawing an off gas from the fragmented mass on the advancing side of the combustion zone. Gas flow advances the combustion zone through the fragmented mass and transfers heat of combustion to a retorting zone on the advancing side of the combustion zone. Kerogen in oil shale in the retorting zone is decomposed to produce gaseous and liquid products including crude shale oil. Crude shale oil produced by such a process and having characteristics described herein is withdrawn from the fragmented mass on the advancing side of the retorting zone.

Abstract: A technique is described for breaking the very strong emulsion of shale oil and water produced by an in situ oil shale retorting process so that separate shale oil and water phases can be recovered. The emulsion is broken by maintaining a volume of such emulsion at a bulk temperature of at least about 120.degree. F., and momentarily heating portions of emulsion to a temperature substantially higher than the bulk temperature of the emulsion. Preferably the emulsion of shale oil and water is held at a bulk temperature in the range of from about 120.degree. to 190.degree. F. in contact with heating means maintained in the range of from about 170.degree. F. to about 240.degree. F. Momentary localized heating of emulsion to a temperature substantially higher than the bulk temperature of the emulsion accelerates the breaking of the emulsion.

Abstract: In accordance with the method of the present invention, methane and other similar fuel components are separated from the brine found in geopressurized geothermal zones by immersing gas permeable membranes selective for these fuel components into the brine in these zones, and permitting these fuel components to permeate through the membranes while rejecting the brine. The permeated fuel components then are collected.

Abstract: Hydrogen sulfide is removed from a three-phase mixture of crude oil, natural gas, and water as it issues as a stream from an oil well by first adding liquid sulfur dioxide to the stream without substantially changing its temperature or pressure and then turbulencing the stream to react most of the hydrogen sulfide therein with the sulfur dioxide. Water containing an additive capable of forming a salt with the remaining trace hydrogen sulfide is then added to the stream and then the desulfurized natural gas is separated out of the stream. Hot and sulfur-free crude oil is then injected into the stream to melt the sulfur therein and the stream is then gravitationally separated into sulfur, water, and pure sulfur-free crude oil, some of the last of which is heated and reintroduced into the stream upstream to heat same and melt the sulfur therein.

Abstract: Disclosed is a process for the in situ retorting of oil shale and energy recovery from generated off gases. An underground retort containing rubblized oil shale is subjected to retorting, thereby forming shale oil and off gases. The off gases are purified and burned in a gas turbine. Commonly this process comprises forming a subterranean in situ retort containing rubblized oil shale having a void space of about 5 to about 40 percent; passing a retorting gas through the in situ retort to effectively retort the oil shale and produce a mixture of shale oil and off gases; subjecting the mixture of shale oil and off gases to a preliminary separation to remove gross quantities of shale oil from the off gases; passing a portion of the off gases to a purification zone so as to remove off gas impurities which would be detrimental to the environment or the operation of downstream equipment; and passing a portion of the purified off gases to a gas turbine where said off gases are burned and power is generated.

Abstract: There is provided an apparatus for the chemical decontamination of layers of earth and/or water contaminated with organic materials comprising the following block units:Device for withdrawal of water from a water pressure line which water is to be treated and returned into the layers of earth,A mixing device for the preparation of a mixture of water and at least one strong, chemical oxidizing agent and/or bactericide,A degassing device for removal of excess gas from the mixture,A distribution device for distributing the mixture to several feed lines, andSeveral mobile sprinkling and/or feeding lines with drain pipes to feed the aqueous mixture to and/or the layers of earth whereby the drain pipes are at most lowered to the still water level in the water bearing layers of ground.There is also described a method of using the apparatus.

Abstract: A process incorporating integrated units and combined cycle energy production is provided for the recovery and upgrading of oil containing deposits which are not readily amenable to recovery and upgrading, to produce therefrom a light oil and elemental sulphur. Residual hydrocarbons generated in the process are gasified to produce hot gases which are used as a source of energy for process use, including electric power. The electric power is utilized to electrolyze water and produce hydrogen for use in upgrading and oxygen for use in gasification. The integration of gasification of residual hydrocarbons to produce, inter alia, electric power with the electrolysis of water to produce hydrogen for upgrading, and efficient use, distribution and recovery of energy in combined energy cycles provides an economical and essentially energy sufficient process with the flexibility to be adapted for the recovery and upgrading of various low yield oil deposits.

Abstract: High pressure product fluid from a petroleum well goes into a high pressure separation vessel where preliminary phase separation of the constituents takes place. Oil and gas leave the preliminary separator by a flow line. Power fluid for a triplex pump flows from the high pressure separator into a separator tank that opens to atmosphere. Here, further separation of the phases takes place and power fluid low in abrasive solid content is taken off by a charging pump and fed to the triplex pump. The triplex pump increases the head of the power fluid and introduces it to the well. The power fluid may be either water or oil.

Abstract: In a method for producing hydrocarbon gas from aquifers which contain gas in water solution, water is produced from wells distributed through the aquifer and solution gases are recovered from the produced water. The aquifer pressure declines as production continues; gas comes out of water solution and a gas phase saturation builds up in the aquifer. When gas saturation exceeds a critical value, gas in gaseous phase flows through the aquifer rock to the producing wells and the ratio of total gas to total water produced increases substantially.

Abstract: Sulfur dioxide is removed from a process gas by passing the process gas through a first fragmented permeable mass of particles containing treated oil shale and including alkaline earth metal oxides at a sufficient temperature to remove sulfur dioxide from the process gas. Gas containing sulfur dioxide from the first fragmented mass is passed through a second fragmented permeable mass of particles containing treated oil shale and including alkaline earth metal oxides. Water in the second fragmented mass combines with alkaline earth metal oxides in the second fragmented mass and sulfur dioxide in the gas from the first fragmented mass with resultant removal of sulfur dioxide from gas from the first fragmented mass.

Abstract: Impurities are removed from impure water by introducing the impure water into a fragmented permeable mass of particles containing raw oil shale. The water introduced can be water containing hydrocarbons such as water obtained from retorting oil shale or water containing suspended solids such as blowdown from a steam generator. After introducing impure water into the fragmented permeable mass, the mass of particles can be retorted. This is particularly advantageous when the introduced water contains hydrocarbons because at least part of the hydrocarbons removed from impure water can be recovered by retorting.

Abstract: Thixotropic compositions having initially relatively high viscosity which can decrease with time are employed in a method for cleaning a borehole. The compositions are prepared by admixing water and chloroform with an anionic surfactant, a cationic surfactant, an acid to adjust the pH of the aqueous phase to 4.5 or less, and a buffer salt. These compositions are valuable drilling fluids, fracturing fluids, and surfactant fluids for chemical flooding in tertiary oil recovery.

Abstract: A process for enhanced recovery of petroleum from subterranean formations is disclosed, wherein steam is injected into a formation via an injection well, and a mixture of petroleum and steam condensate is produced via a production well, wherein the produced mixture is flashed for production of a steam-distilled hydrocarbon fraction, and wherein the steam distilled hydrocarbon fraction is injected, with additional steam, into a subterranean formation for increased recovery of petroleum. The process disclosed is particularly useful in recovery of heavy (low API gravity) petroleum.

Abstract: Disclosed is a process for removing acidic impurities from off-gases generated in the retorting of oil shale comprising contacting a rubblized mass of oil shale which has been substantially depleted in hydrocarbonaceous materials with water, so as to extract basic components from the mass; and contacting off-gases, which were generated during the retorting of oil shale and which contain acidic impurities, with the water containing basic components so as to substantially remove said acidic impurities from said off-gases.

Abstract: A technique is described for breaking the very strong emulsion of shale oil and water produced by an in situ oil shale retorting process so that separate shale oil and water phases can be recovered. The emulsion is broken by heating it to a temperature of at least about 120.degree. F. and holding at a temperature in the range of from about 120.degree. to 180.degree. F. for about one day. Preferably the shale oil and water are held in the range of from about 130.degree. to 150.degree. F. for about one day and the phases separated by gravity. Heat for the process can be obtained by injecting water into a spent in situ oil shale retort for generating steam and transferring heat from the steam to the emulsion.

Abstract: A method of producing combustible gases, synthetic crude oils, coal chemicals and heat from coal in situ utilizes the combined teachings of in situ gasification, liquefaction and pyrolysis.

Abstract: Sulfur dioxide is removed from a process gas by passing the process gas through a fragmented permeable mass of particles containing treated oil shale and including alkaline earth oxides. Water in the fragmented mass combines with alkaline earth oxides in the fragmented mass and sulfur dioxide in the process gas with resultant removal of sulfur dioxide from the process gas.

Abstract: A method of producing combustible gases, synthetic crude oils, coal chemicals and heat from coal in situ utilizes the combined teachings of in situ gasification, liquefaction and pyrolysis.

Abstract: A combination structure adapted for use in a catalytic process for stimulating the recovery of hydrocarbons from porous and permeable hydrocarbon bearing strata in earth formations utilizing at least one injection well and at least one production well both completed in said hydrocarbon bearing strata and a finely divided hydrocarbon cracking catalyst which is delivered by and through said structural combination of parts and elements to said strata by injection gas controlled at suitable pressure, temperature and O.sub.2 content to promote and advance in place catalytic cracking of hydrocarbons and catalyst regeneration within said strata to be produced by utilizing said combination structure or its equivalent.

Abstract: There is disclosed an improved system method for in situ extraction of mineral values from subterranean deposits of ores of the oxide; carbonate; sulphide, or other type ores which contain sought-for metal values and which evolve gas when reacted with suitable chemicals in solution and/or gaseous form. The invention is particularly applicable to in situ mining of the previously found types of copper, nickel, manganese, etc. oxide, carbonate, and sulphide ores and the like; and especially features conservation of energy which otherwise would be wasted.

Abstract: The flow from geothermal wells is stimulated by injecting a liquid at selected levels in the well with the liquid having a boiling point below the temperature of the geothermal fluid at the levels of injection at the operating pressure at the levels of injection. The geothermal fluid and vaporized injected fluid from the well are applied to a system for extracting the heat energy as well as for cleaning sand and other well depositions that may accumulate in the geothermal well. The system may include a direct contact heat exchanger having either a vertical chamber or a horizontal chamber. The contactor has a plurality of zones including a boiler zone, one or more separation zones, and at least one heat exchange zone. The contactor may also include a wash zone and a flash zone.In the wash zone there is advantageously included recirculation trays vertically spaced for washing the vapor to remove entrained substances, such as minerals dissolved in the fluid from the geothermal wells.

Abstract: A method of producing combustible gases, synthetic crude oils, coal chemicals and heat from coal in situ utilizes the combined teachings of in situ gasification, liquefaction and pyrolysis in separated coal blocks.

Abstract: A method of extracting highly viscous nonfracturable oil from earthen deposits is presented by the instant invention. A plurality of radially extending horizontal conduits direct heated hydrocarbon vapors into the formation. The vapors are selected to have a boiling point above the pour point of the viscous oil. Thus, as the vapors rise in the formation, they will be in heat exchange relationship with the viscous oil to cause the latter to flow downwardly. In addition to the thermal exchange of energy, the vapors will move toward molecular equilibrium with the viscous oil formation. This latter action will cause the vapors to "strip off" the more volatile, lower boiling components, from the descending liquid oil. The liquified oil, on the other hand, will condense the less volatile, higher boiling point fraction of the vapors.

Abstract: A cleanout procedure for use in a well with low bottom hole pressure that has become filled with sand. It employs a conductor string of pipe and a wash string of pipe inside the conductor string, both inserted in the well. A high pressure gas is applied to the inner annulus formed by the conductor and wash string, and the workover wash fluid is circulated down the wash string up the outer annulus formed by the well casing and the conductor string, to be joined by the gas and so wash out the sand through the outer annulus. Sand is separated at the surface.

Abstract: A method of producing combustible gases, synthetic crude oils, coal chemicals and heat from coal in situ utilizes the combined teachings of in situ gasification, liquefaction and pyrolysis in separated coal blocks.

Abstract: A process and system for insitu hydrogenation employing a gas generator in a borehole for burning a hydrogen-rich mixture of hydrogen and oxygen. The gas generator comprises a housing forming a chamber with a combustion zone at one end and a restricted outlet at the other end. Hydrogen and oxygen are supplied downhole to the generator to form a hydrogen-rich combustible mixture in the combustion zone which is burned whereby hydrogen and steam are injected from the restricted outlet. The flow of hydrogen and oxygen to the generator is controlled to maintain the temperature of the exhaust gases at a level sufficient to crack the hydrocarbons in the formation into lighter segments for reaction with the excess hot hydrogen to form lighter and less viscous end products which are recovered from a production well.

Abstract: A system for the mining of geothermal energy in which a plurality of geothermal wells radiate from a single surface site into a subsurface geothermal reservoir. The wells can be drilled by conventional slant drilling techniques and each may contain a closed end heat exchanger which receives water and generates steam. Some of the heat exchangers are disposed vertically and others are implanted horizontally. By alternating production of the wells in a programmed cyclical manner, convective movement of the hydrothermal fluid will occur within the geothermal zone. The generated steam is collected in a reservoir at the surface site and utilized to generate electricity. The condensate from the turbine can be recycled to the wells.

Abstract: A method of extracting hydrocarbons, energy and other products in situ from an underground coal deposit. A selected part of the coal deposit is heated by electrical induction to temperatures high enough to effect the destructive distillation of coal. The gases and liquids so produced are collected. Next, air or oxygen is injected into the remaining deposit which consists primarily of coke in order to burn it in place. The hot combustion gases thereby yielded are led to the surface of the deposit to generate energy. Lastly, the heat remaining underground after the coke has been burned is extracted by injecting water or steam into the deposit. The resulting steam is conducted to the surface to drive a steam turbine. The electrical induction heating is conveniently effected by passing a selected time varying current through a conductive path encompassing that part of the coal deposit to be heated.

Abstract: This disclosure relates to a fluid carrier recovery system for recovering oil and like liquid deposits from an underground source wherein the oil is deposited in an unpumpable form and wherein the oil is recovered by directing into the oil deposit a carrier which will fill a large volume of the oil deposit and which will flow upwardly through a flow passage in the earth to a location adjacent or above the surface of the earth, followed by the introduction into the lower part of such volume of a solvent for the oil, the solvent having a lesser specific gravity than the carrier and being operative on the oil to form oil-solvent droplets which float in the carrier and flow to the top of the flow passage for recovery. The carrier is preferably water and the solvent may be an inexpensive mineral spirit immiscible with water.

Abstract: Circulating oil used for removal of sulfur in sour gas wells is contacted with an aqueous solution of an organic amine and allowed to separate into an oil phase and an aqueous amine phase containing the sulfur. The oil is then returned to circulation to the gas well and the aqueous amine phase is removed for regeneration which is accomplished by precipitating the sulfur with CO.sub.2 and stripping out the CO.sub.2 from the aqueous amine solution with heat and/or vacuum.

Abstract: An emulsion of crude oil and water that is recovered from an underground reservoir is broken by the addition of a naturally occurring brine to effect separation and recovery of the oil phase of the emulsion. Advantageously, brine taken from the same geologic formation as the crude oil can be used as the emulsion breaker.

Abstract: Methods of and apparatus for recovering hydrocarbons from tar sands, oil shales, exhausted oil bearing formations and the like by solvent extraction.

Abstract: Solid hydrocarbon materials present in subsurface earth formation such as, for example, the coke like residue remaining in a subterranean tar sand deposit which has previously been exploited by controlled oxidation depletion, is converted to a synthesis gas composition by contacting the solid hydrocarbon material with an oxygen enriched gas or essentially pure oxygen and a moderating fluid such as water, steam or carbon dioxide to control the reaction temperature so as to ensure the generation of carbon monoxide and hydrogen within the formation. The oxygen and steam or carbon dioxide may be injected as a mixture or simultaneously by separate injection means, or oxygen may be injected for intervals of time interrupted by brief periods of carbon dioxide, steam or water injection. The effluent is predominantly gaseous carbon monoxide, hydrogen, and lesser amounts of carbon dioxide and methane and, occasionally liquid hydrocarbons.

Abstract: Bituminous hydrocarbons are recovered from unconsolidated tar sands by in-place, selective leaching with a hot condensate formed upon contact with hot solvent vapors injected in the formation. The composition and temperature of the vapors are regulated so that a less soluble fraction of the tar is left behind as a residue. This residue does not dissolve in the vapors passing through the already leached portion of the formation and continues to act as a sand-supporting and immobilizing agent. Thus, subsidence of the leached formation and release of sand grains (which tend to interfere with removal of the leachate from the formation) are avoided. Solvent for the process is obtainable by distillation or cracking of the produced bitumens.

Abstract: This invention relates to the recovery of petroleum from tar and heavy oil sands in which one or more injection passages and two or more removal passages are established between the surface of the ground and an underground petroleum deposit. Hot water is injected into the petroleum deposit at a temperature above the pour point temperature of the petroleum substance, and heat is transferred until the petroleum substance becomes flowable. Under the influence of induced pressure, the petroleum substance is made to flow countercurrent to the flow of heat, with the petroleum substance captured at the surface of the ground.