Solid Product Patents (Class 201/16)
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Patent number: 10858592Abstract: Optimized, heat-integrated methods and systems are provided to produce multiple, high-value products from oil shale, while minimizing overall energy and water usage. A method for producing multiple products from oil shale comprises: feeding raw oil shale into a heated retorting unit, to convert kerogen into a retorted stream; introducing the retorted stream to a distillation column to generate a high-cetane diesel stream, an ?-olefin-containing chemical stream, an asphalt/asphalt additive stream, and an overhead gas stream, wherein heat contained in the retorted stream is harnessed as distillation energy; separating the overhead gas stream into a fuel gas stream and a purge gas stream; combusting the fuel gas stream to generate hot flue gas; heating the purge gas with hot flue gas; feeding the heated purge gas directly to the heated retorting unit; and recovering the high-cetane diesel stream, the ?-olefin-containing chemical stream, and the asphalt/asphalt additive stream as products.Type: GrantFiled: June 6, 2018Date of Patent: December 8, 2020Inventors: Ronald C. Stites, Otto John Schneider
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Patent number: 10041003Abstract: The invention provides an apparatus which consists of two fluidized beds 1 and 2 separated by a vertical divides' 5. A positive displacement device such as an auger 3 moves the bed material from the reduction side to the combustion side of the device below the fluidization zone. The height of the two fluidized beds is equalized by movement of the bed material through a hole 4 In the vertical divider, from the high temperature side 1 (zone 1) to the tow temperature side 2 (zone 2). The bed material that moves through the hole 4 provides energy to drive reactions that may occur on the reduction side. Energy may also be provided to zone 2 by means of conductive and radiative heat transfer through the dividing wall 5. Energy is provided to zone 1 by means of an exothermic reaction, typically combustion of a fuel 13 using air 12.Type: GrantFiled: June 13, 2014Date of Patent: August 7, 2018Assignee: University of PretoriaInventor: Michael David Heydenrych
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Patent number: 9926492Abstract: A method for liquefaction of coal or other solid carbonaceous material includes passing the material through a reformer having a temperature gradient therein, the temperature gradient generally increasing as the material flows down through the reformer. The more valuable volatile components of the material exit the material at their respective vaporization temperatures, and pass out of the reformer for processing in condensers. Some of each fraction of the volatile material flow is re-heated and recycled through the reformer to supply heat to maintain the temperature gradient, the recycling injection occurring at a level below that where the fraction exited the reformer so that the recycled fraction will again pass out of the reformer to be condensed. At the bottom of the reformer, the non-volatile portion of the carbonaceous material is removed from the reformer for further processing or sale.Type: GrantFiled: April 8, 2011Date of Patent: March 27, 2018Assignee: Frontier Applied Sciences, Inc.Inventor: Joseph A. Witherspoon
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Patent number: 9683187Abstract: A method for the torrefaction of biomass comprises receiving biomass having a given moisture content. The biomass is heated in a generally inert environment by indirect contact. The biomass is subsequently torrefied by exposing the biomass to a flow of combustion gases in the generally inert environment. The biomass is outlet with a reduced moisture content.Type: GrantFiled: May 27, 2013Date of Patent: June 20, 2017Assignee: AIREX ENERGIE INC.Inventor: Guy Prud'Homme
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Publication number: 20140197020Abstract: The present invention provides a system and a process for preparing activated carbon from fly ash. The system of the present invention comprises a flotation system and a carbonization system. The present invention has the following advantages. Firstly, since a fuel gas-flue gas loop structure is arranged, the combustible fuel gas produced in carbonization process enters the combustion means for combustion via this loop structure, and also via this loop structure, the high temperature flue gas generated by the combustion enters the carbonization furnace to heat up and carbonize the charcoal powder raw material within the carbonization furnace. Such a solution not only saves energy, but also prevents a substantial amount of combustible gas from being emitted to the atmosphere, thereby reducing environmental pollution. Secondly, since two cylinders are arranged in the carbonization furnace, the charcoal powder raw material in the inner cylinder enters the outer cylinder and then exits from the outer cylinder.Type: ApplicationFiled: December 29, 2011Publication date: July 17, 2014Applicant: FUJIAN LONGYAN LONGNENG FLYASH COMPREHENSIVE UTILIZATION CO.LTD.Inventor: Minqing Xu
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Patent number: 8772559Abstract: A biochar generator may include a pyrolysis chamber, a heater connected to the pyrolysis chamber and a biochar collection chamber in communication with the pyrolysis chamber. A biochar collection chamber sensor may sense a composition of the biochar collected in the biochar collection chamber to define a sensed composition of the biochar. A controller in electrical communication with the biochar collection chamber sensor may utilize the sensed composition of the biochar to dynamically alter conditions in the pyrolysis chamber to alter the composition of the biochar.Type: GrantFiled: July 22, 2013Date of Patent: July 8, 2014Assignee: Data Flow Systems, Inc.Inventor: Thomas F. Smaidris
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Publication number: 20140048402Abstract: A coke oven includes an oven chamber, an uptake duct in fluid communication with the oven chamber, the uptake duct being configured to receive exhaust gases from the oven chamber, an uptake damper in fluid communication with the uptake duct, the uptake damper being positioned at any one of multiple positions, the uptake damper configured to control an oven draft, an actuator configured to alter the position of the uptake damper between the positions in response to a position instruction, a sensor configured to detect an operating condition of the coke oven, wherein the sensor includes one of a draft sensor, a temperature sensor configured to detect an uptake duct temperature or a sole flue temperature, and an oxygen sensor, and a controller being configured to provide the position instruction to the actuator in response to the operating condition detected by the sensor.Type: ApplicationFiled: August 17, 2012Publication date: February 20, 2014Inventors: John F. Quanci, Peter U. Chun, Milos J. Kaplarevic, Vince G. Reiling
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Publication number: 20130327629Abstract: Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.Type: ApplicationFiled: July 8, 2011Publication date: December 12, 2013Applicants: ENSYN RENEWABLES, INC.Inventors: Paolo Palmas, Paul A. Sechrist, Sid Kulprathipanja, Stanley J. Frey, Barry Freel, Daniel N. Myers
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Patent number: 8558044Abstract: A biochar generator to be carried by a vehicle may comprise a pyrolysis chamber, an auger, a heater, and a vapor condenser each connected to the pyrolysis chamber. The biochar generator may also include a synthesis gas collection chamber to collect synthesis gas, and a bio oil collection chamber to collect bio oil, each in communication with the vapor condenser. A biochar collection chamber may be included to collect biochar dispensed from the pyrolysis chamber.Type: GrantFiled: October 26, 2011Date of Patent: October 15, 2013Inventor: Thomas F Smaidris
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Publication number: 20130248347Abstract: A coke oven of a horizontal construction of the non-recovery or heat recovery type is shown. The oven has at least one coking chamber, in which laterally vertical downcomers as well as horizontal bottom flues extend underneath the coking chamber for indirect reheating of the coking chamber. At least a part of the interior walls of the coking chamber is configured as a secondary heating source by coating it with a high-emission coating (HEB) that shows an emission degree equal to or higher than 0.9, and consists of the substances Cr2O3 or Fe2O3 or a mixture containing these substances, with the portion of Fe2O3 amounting to at least 25% by weight in the mixture, and with the portion of Cr2O3 amounting to at least 20% by weight in the mixture.Type: ApplicationFiled: May 23, 2013Publication date: September 26, 2013Applicant: UHDE GMBHInventor: Ronald Kim
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Publication number: 20130228443Abstract: Described herein are biofuel pyrolysis devices and methods of use thereof. The devices described herein include a reactor having a plurality of chambers wherein the chambers of the reactor can be arranged to have at least one aerobic chamber and anaerobic chamber. In certain aspects, the devices described herein can be used for distilling biomass and for potentially generating torrefied products, which include, but are not limited to, torrefied biomass. In certain aspects, the method describe herein include, but are not limited to, introducing biomass onto at least one tray of a plurality of trays in a first chamber of the reactor, heating the biomass in the first chamber with heated vapor from at least one vapor inlet, and transferring the biomass from an upper tray to at least one of the following: a lower tray, a biomass outlet, another chamber (i.e., at least a second chamber), or any combination thereof.Type: ApplicationFiled: March 2, 2012Publication date: September 5, 2013Inventor: Edward DEPOULI
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Publication number: 20130211169Abstract: The invention relates to a process for converting hydrocarbons into unsaturated products such as acetylene and/or ethylene. The invention also relates to converting acetylene to olefins such as ethylene and/or propylene, to polymerizing the olefins, and to equipment useful for these processes.Type: ApplicationFiled: August 17, 2012Publication date: August 15, 2013Inventors: Frank Hershkowitz, Paul F. Keusenkothen, Jeffrey W. Frederick, Richard J. Basile, John W. Fulton
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Publication number: 20130199920Abstract: The invention relates to a device for producing an energy carrier and/or raw material carrier from moisture-containing and/or dry biomass with the aid of a heatable carbonisation reactor (1) having a closable inlet opening (13). The biomass is converted in the carbonisation reactor (1) into a solid, pourable or gaseous energy carrier and/or raw material carrier and for interim storage of the energy carrier and/or raw material carrier is then delivered via a closable outlet opening (14) to a coolable tank (9) connected to the carbonisation reactor (1). The tank (9) is connected to an adjoining heatable gasification reactor (16), in which gas and waste substances, such as ash, are separated from the energy carrier.Type: ApplicationFiled: February 14, 2011Publication date: August 8, 2013Inventor: Elhan Demir
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Publication number: 20130192972Abstract: Method and equipment for producing coke (PC) during indirectly heated gasification, in which coal particles are supplied to a gasification reactor (1) and process gas (P) supplied during the gasification is reduced in it to synthesis gas (S), whereby the synthesis gas (S) is removed from the gasification reactor (1). The method is distinguished in that at the same time a gasification takes place, a coking of coal takes place in an inner reactor (4) arranged inside the gasification reactor (1), that the inner reactor (4) is indirectly heated, that coke (PC) and combustible gases are produced in the inner reactor (4) during the coking, and that the combustible gases are used for the indirect heating in the gasification in the gasification reactor (1).Type: ApplicationFiled: October 10, 2011Publication date: August 1, 2013Inventor: Rolf Ljunggren
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Patent number: 8460516Abstract: A coke oven of a horizontal construction of the non-recovery or heat recovery type is shown. The oven has at least one coking chamber, in which laterally vertical downcomers as well as horizontal bottom flues extend underneath the coking chamber for indirect reheating of the coking chamber. At least a part of the interior walls of the coking chamber is configured as a secondary heating source by coating it with a high-emission coating (HEB) that shows an emission degree equal to or higher than 0.9, and consists of the substances Cr2O3 or Fe2O3 or a mixture containing these substances, with the portion of Fe2O3 amounting to at least 25% by weight in the mixture, and with the portion of Cr2O3 amounting to at least 20% by weight in the mixture.Type: GrantFiled: August 9, 2007Date of Patent: June 11, 2013Assignee: Uhde GmbHInventor: Ronald Kim
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Patent number: 8404909Abstract: A method of biomass pyrolysis is described which includes chemical looping of combustion char so that carbon dioxide can be captured from the combustion of the char as well as producing useable compounds from pyrolyzing biomass in a pyrolysis reactor including a metal oxide carrier particles which is in operative cooperation with a char combustor and oxidation reactor and separator for separating carbon dioxide from the flue gas produced by the char combustor.Type: GrantFiled: December 9, 2009Date of Patent: March 26, 2013Assignee: Chevron U.S.A. Inc.Inventor: Raja A Jadhav
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Publication number: 20120312678Abstract: A method for coking coals having high driving pressure properties in a “non-recovery” or “heat-recovery” coking oven, wherein a coking oven battery which is composed of coking oven chambers arranged side by side is used for cyclic coking of coal, and wherein an amount of coal preheated to a high temperature is admitted into the coking chamber that is to be filled at such a level that the driving pressure resulting from the coking can escape over the coke cake into the gas chamber, in such a manner that the coking oven chamber wall surrounding the coking oven chamber is relieved by the driving pressure resulting from the coking. Also disclosed is a device with which this method can be carried out.Type: ApplicationFiled: February 4, 2011Publication date: December 13, 2012Applicant: THYSSENKRUPP UHDE GMBHInventors: Ronald Kim, Franz-Josef Schuecker
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Publication number: 20120305379Abstract: A method of treating untreated low calorific coal containing moisture and organic volatiles includes feeding untreated coal to a dryer, and drying the coal. The dried coal is subjected to a pyrolyzing step where oxygen-deficient gases are brought into contact with the coal, thereby lowering the volatile content of the coal and producing a stream of pyrolysis effluent gases. The pyrolysis effluent gases are subjected to a separation process to separate lean fuel gases from liquids and tars, wherein the separation process removes less than about 20 percent of the pyrolysis effluent gases as the liquids and tars, with the remainder being the lean fuel gases. The lean fuel gases are returned to the dryer combustor, the pyrolyzer combustor, or the pyrolyzer.Type: ApplicationFiled: June 3, 2011Publication date: December 6, 2012Applicant: MR&E, Ltd.Inventors: Dennis W. Coolidge, Deane A. Horne, Ronn G. Smith
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Patent number: 8203024Abstract: A method for torrefying biomass comprises using an oxidation catalyst to combust gas produced by torrefaction, and thereby produce combustion flue gas. The method also comprises introducing the combustion flue gas into a torrefaction reactor and/or a cooler.Type: GrantFiled: September 21, 2011Date of Patent: June 19, 2012Assignee: Advanced Toffefaction Systems, LLCInventor: Mark Alan Leonhardt
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Publication number: 20110226603Abstract: The invention relates to a method and to devices for producing operating materials or fuels, humus, Maillard or similar reaction products from a solid-liquid mixture of water and a carbonaceous component and for treating said mixture, wherein the solid-liquid mixture is treated at a temperature of over 100° C. and a pressure of over 5 bar.Type: ApplicationFiled: November 23, 2009Publication date: September 22, 2011Inventor: Dominik Peus
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Patent number: 8002972Abstract: A system for producing petroleum products from oil shale includes one or plural kiln lines made up of plural series-connected, indirect-fired, inclined rotary kilns. Plural kiln lines are operated for parallel processing. Oil shale is advanced through kilns in succession and exhausted from each kiln line substantially free of hydrocarbons. Successive kilns along the advancement of oil shale are maintained at successively higher temperatures. A fuel distinct from hydrocarbons in oil shale, such as syngas from a gasifier or hydrogen gas from a separator, drives pyrolysis to extract hydrocarbons. A refining unit located proximate to the kiln lines upgrades extracted hydrocarbons into petroleum products and separates the petroleum products by criteria. A heat extraction unit recovers heat from exhausted oil shale for reuse in kilns. A method involves drying oil shale followed by heating dry oil shale in successively hotter pyrolysis environments.Type: GrantFiled: October 12, 2007Date of Patent: August 23, 2011Assignee: EnShale, Inc.Inventors: Robert D. Morris, Jr., Robert D. Morris, III
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Publication number: 20110120852Abstract: A device for a directed gas routing of primary air into a coke chamber oven is disclosed. The primary air is conducted through the coke chamber top into the gas space of a coke oven battery and is laterally deflected as it enters into the gas space of the coke chamber. Also disclosed is a method for lateral deflection of primary air after its entry into the coke oven chamber, thus improving the distribution of the primary air in the coke oven chamber.Type: ApplicationFiled: April 28, 2009Publication date: May 26, 2011Inventor: Ronald Kim
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Publication number: 20110078951Abstract: A gasifier combines two reactors using externally generated preheated high temperature steam injection into the first reactor, where the heating demand for gasification is supplied by the sensible energy from the steam. The gasifier can produce a medium and higher LCV syngas. The first reactor is a fixed bed gasification section where the coarse feedstock is gasified, and the second reactor is an entrained-bed gasification section where the liquid and fine feedstock is gasified. Solid coarse feedstock is devolatilized in the first fixed bed reactor of the gasifier with high-temperature steam, and subsequently, in the second reactor subjected to a higher temperature sufficient to crack and destroy tars and oils. Activated carbon may be formed as co-product. The gasifier may be used with various solid and liquid feedstocks. The gasifier is capable of gasifying such different feedstocks simultaneously.Type: ApplicationFiled: May 29, 2009Publication date: April 7, 2011Applicant: Boson Energy SAInventors: Wlodzimierz Blasiak, Weihong Yang
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Publication number: 20110017582Abstract: A processing vessel is loaded with a feedstock including organic material and at least one additive which is non-inert to the organic material. A bottom portion of the feedstock is heated to a pyrolytic state for producing a horizontal thermal layer within the feedstock which thermally decomposes organic material into carbon as the non-inert additive reacts with the organic material. Vapor is directed downwardly through the feedstock while discharging volatile organic compounds from a lower portion of the chamber. Prior to complete thermal decomposition of the feedstock, the direction of vapor flow within the feedstock is reversed wherein the vapor flows upwardly through the feedstock while the volatile compounds are discharged from an upper portion of the chamber. Pressure and vapor flow within the chamber are regulated during upward vapor flow to regulate vertical movement of the thermal layer within the feedstock for controlling the extent of thermal decomposition of the feedstock.Type: ApplicationFiled: July 23, 2009Publication date: January 27, 2011Inventor: Michael J. LURVEY
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Publication number: 20100300866Abstract: A method of forming a pyrolysed biocarbon from a pyrolyzable organic material is delineated. The method involves the conversion of pyrolyzable organic materials to biocarbon for subsequent use. A carbonization circuit is employed with individual feedstock segments being advanced through the circuit. The method facilitates user manipulation of rate of advancement of the feedstock through the circuit, selective collation of volatiles from pyrolyzing feedstock, selective exposure of predetermined feedstock segments to collated volatiles as well as thermal recovery and redistribution as desired by the user. This results in the capacity for a customizable biocarbon product, the latter being an auxiliary feature of the methodology.Type: ApplicationFiled: May 26, 2009Publication date: December 2, 2010Inventors: Hendrik van Aardt, Phil Marsh, Hugh McLaughlin
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Publication number: 20100065412Abstract: The invention relates to a horizontally designed, non-heat recovery-type coke oven comprising at least one coking chamber, downcomers that are laterally disposed in relation to the coking chamber, and bottom ducts which are horizontally arranged below the coking chamber in order to indirectly heat the coking chamber. At least some of the interior walls of the coking chamber are embodied as a secondary heating area by coating the interior walls with a high-emission coating (HEB). The minimum emissivity of said high-emission coating is 0.9. Preferably, the high-emission coating (HEB) is made of Cr2O3, Fe2O3, or a mixture containing said substances, the Fe2O3 moiety in a mixture amounting to at least 25 percent by weight and the Cr2O3 moiety in a mixture amounting to at least 20 percent by weight.Type: ApplicationFiled: August 9, 2007Publication date: March 18, 2010Applicant: UHDE GMBHInventor: Ronald Kim
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Publication number: 20100065413Abstract: The invention relates to a horizontally designed, non-heat recovery-type coke oven comprising at least one coking chamber, downcomers that are laterally disposed relative to the coking chamber, and bottom ducts which are horizontally arranged below the coking chamber in order to indirectly heat the coking chamber. One or more heating elements are located in the gas chamber which is not filled with solid matter when the coke oven is appropriately used.Type: ApplicationFiled: September 7, 2007Publication date: March 18, 2010Applicant: UHDE GMBHInventor: Ronald Kim
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Publication number: 20100006415Abstract: The present invention relates to a system for treating flammable wastes and a method for treating the same, and more particularly, to a thermal decomposition treatment system of the flammable waste and a waste treatment method of the waste using the same through which the flammable waste inputted into a trash burner is shielded from air or gas and the waste is thermally decomposed and carbonated through a indirect heating by a heating tube for combustible gas to be extracted and recovered for a reuse without emitting contaminated gas, etc.Type: ApplicationFiled: January 22, 2009Publication date: January 14, 2010Inventor: Jong Ho Lee
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Publication number: 20090250331Abstract: The present invention provides an autothermal torrefaction device, which can be either stationary of mobile. Embodiments of the present invention include a torrefaction chamber having a chamber inlet for receiving biomass and at least one chamber outlet. The torrefaction chamber can be substantially surrounded by an exterior housing defining an outer jacket and having a jacket inlet and a jacket outlet. The outer jacket and torrefaction chamber define a space therebetween such that a burner unit including an inlet operatively connected to the chamber outlet and an outlet operatively connected to the jacket inlet allows vapors produced or released from within the torrefaction chamber to travel into the burner unit for combustion of at least a portion of the vapors and subsequently travel through the space between the jacket and the torrefaction chamber to provide heat necessary for autothermal torrefaction of biomass.Type: ApplicationFiled: April 3, 2009Publication date: October 8, 2009Inventors: Christopher B. Hopkins, Rucker Preston Burnette, JR.
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Patent number: 6830597Abstract: The subject invention pertains to unique and advantageous systems for gasifying and/or liquefying biomass. The systems of the subject invention utilize a unique design whereby heat from a combustion chamber is used to directly gasify or liquefy biomass. In a preferred embodiment, the biomass is moved through a reactor tube in which all the gasification and/or liquefaction takes place. Preferably, char exits the biomass reactor tube and enters the combustion chamber where the char serves as fuel for combustion. The combustion chamber partially surrounds the reactor tube and is in direct thermal contact with the reactor tube such that heat from the combustion chamber passes through the reactor wall and directly heats the biomass within the reactor tube.Type: GrantFiled: February 18, 2000Date of Patent: December 14, 2004Assignee: Green Liquids and Gas TechnologiesInventor: Alex E. S. Green
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Patent number: 6048374Abstract: The subject invention pertains to unique and advantageous systems for gasifying and/or liquefying biomass. The systems of the subject invention utilize a unique design whereby heat from a combustion chamber is used to directly gasify or liquefy biomass. In a preferred embodiment, the biomass is moved through a reactor tube in which all the gasification and/or liquefaction takes place. Preferably, char exits the biomass reactor tube and enters the combustion chamber where the char serves as fuel for combustion. The combustion chamber partially surrounds the reactor tube and is in direct thermal contact with the reactor tube such that heat from the combustion chamber passes through the reactor wall and directly heats the biomass within the reactor tube.Type: GrantFiled: August 18, 1997Date of Patent: April 11, 2000Inventor: Alex E. S. Green
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Patent number: 4946658Abstract: A pelletized mixture of gypsum, carbonaceous material and pyrite is charged to a travelling grate where the charge is heated under suitable conditions to produce a solid sintered material which has a broad spectrum of applications due to its chemical and physical properties and a gaseous effluent containing sulfur dioxide, sulfur or mixtures thereof.Type: GrantFiled: May 11, 1989Date of Patent: August 7, 1990Assignee: Florida Institute of Phosphate ResearchInventors: Jerome H. Marten, George M. Lloyd, Jr.
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Patent number: 4927430Abstract: A method of generating a de-sulphurized volatile matter and a relatively low Btu gas includes the initial step of pyrolyzing coal to produce volatile matter and a char. The volatile matter is fed to a first de-sulphurizer containing a de-sulphurizing agent to remove sulphur therefrom. At the same time, the char is gasified to produce a relatively low Btu gas. The low Btu gas is fed to a second de-sulphurizer containing the de-sulphurizing agent to remove sulphur therefrom. A regenerator is provided for removing sulphur from the de-sulphurizing agent. Portions of the de-sulphurizing agent are moved among the first de-sulphurizer, the second de-sulphurizer, and the regenerator such that the regenerator regenerates the de-sulphurizing agent. Preferably, the portions of the de-sulphurizing agent are moved from the second de-sulphurizer to the first de-sulphurizer, from the first de-sulphurizer to the regenerator, and from the regenerator to the second de-sulphurizer.Type: GrantFiled: May 26, 1988Date of Patent: May 22, 1990Inventor: Albert Calderon
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Patent number: 4744969Abstract: The present invention relates to the coproduction of a combustible feed gas stream useable as an energy source and a sulfur-containing second gas stream useable as a feedstock for the production of sulfuric acid. The process includes heating coal in the presence of an oxygen-lean atmosphere under partial coal gasifying conditions to produce a solid carbonaceous char and a crude coal-gas stream. Sulfur-containing compounds are removed from the coal gas stream and converted to solid sulfur-containing materials. The solid sulfur-containing materials are combined with the solid carbonaceous char and gypsum to form a feed mixture. The non-gypsum portion of the feed mixture contains sufficient reducing potential to release substantially all of the sulfur in the gypsum as gaseous compounds of sulfur in a +4 or lower oxidation state. The feed mixture is heated under reducing conditions to produce a sulfur-containing second gas stream and a solid sintered product.Type: GrantFiled: December 10, 1986Date of Patent: May 17, 1988Assignee: Florida Institute of Phosphate ResearchInventors: Jerome H. Marten, Timothy J. Kendron
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Patent number: 4650546Abstract: Slugs (4) of products dehydrated by compression are thrust into the tube (11) up to the hearth (15). The hot gases from the hearth passing round the tube (11) heat it up in order to release the gases and carbonize the solids which burn in the form of coke in the bottom (16) of the hearth. Household refuse may thus be eliminated not only without expense but with recovery of energy from it.Type: GrantFiled: February 12, 1982Date of Patent: March 17, 1987Inventor: Gwenole J. Le Jeune
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Patent number: 4640760Abstract: Tar sands are solvent extracted to form an oil-containing extract and a sandy residue. The solvent can be distilled from the oil and recycled. Residual solvent vapors can be adsorbed on an adsorbent bed. The sandy residue can be flash pyrolyzed to provide a combustible synthesis gas and/or combusted to provide process heat. Where the adsorber bed is formed from activated charcoal, a pair of beds on swing adsorption/regeneration cycles can be regenerated with steam and provide for continuous adsorption solvent vapors.Type: GrantFiled: August 31, 1984Date of Patent: February 3, 1987Assignee: Phillips Petroleum CompanyInventor: William G. Billings
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Patent number: 4599161Abstract: Hydrogen sulfide issuing from an oil shale retort is captured in an absorbent bed. When the bed is regenerated as with oxygen containing gas, the sulfur dioxide liberated is reintroduced into the retort for reaction with the spent shale.Type: GrantFiled: November 30, 1984Date of Patent: July 8, 1986Assignee: Phillips Petroleum CompanyInventors: James Scinta, Arlo J. Moffat
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Patent number: 4495058Abstract: Superheated steam generated by passing wet steam through a superheater containing a fluidized or partially fluidized bed of hot particulate solids recovered from a retorting process especially useful in a process for recovering hydrocarbon vapors from a hydrocarbonaceous solid such as oil shale.Type: GrantFiled: June 6, 1983Date of Patent: January 22, 1985Assignee: Chevron Research CompanyInventors: Robert A. Farnham, Lawrence P. Zestar, Corey A. Bertelsen
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Patent number: 4477331Abstract: A method and apparatus is disclosed for retorting particulate solid materials, particularly hydrocarbon-containing materials such as oil shale, oil sands, tar sands, coal shale, coal tailings, and the like, for the recovery of a volatile constituent such as oil or gas. A rotary retorting apparatus is employed which consists of a cylindrical drum, or other similar regularly shaped chamber, with a substantially horizontal axis of rotation and having multiple compartments for retorting and combustion and, optionally, spent solids cooling. The apparatus further includes solids transport chutes for forward and backward circulation of solids, arranged for the intercompartmental transfer of solids with the capability of additions at one or more points in each compartment. Employing the method and apparatus, particulate solids feedstock is heated by recycled spent solids material to remove the volatile constituent of the feedstock in the retort section.Type: GrantFiled: May 17, 1983Date of Patent: October 16, 1984Assignee: PEDCo, Inc.Inventors: Leland M. Reed, William A. Reed, Walter C. Saeman
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Patent number: 4448668Abstract: Crushed, retorted shale particles recovered from a shale oil retort but still containing combustible materials are burned under oxidizing conditions in a fluidized combustor to remove substantially all of the hydrocarbonaceous materials. Hot combustion flue gases are recovered, divided, and delivered to two heat exchangers, the first for indirectly preheating recycled retort education gases and the second for indirectly heating water. Also recovered from the combustor are shale particles, which are introduced into a fluidized cooling vessel and therein cooled by indirectly exchanging heat with water while traces of residual hydrocarbons burn from the shale.Type: GrantFiled: December 20, 1982Date of Patent: May 15, 1984Assignee: Union Oil Company of CaliforniaInventor: Roland F. Deering
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Patent number: 4398076Abstract: A process and system for producing and utilizing to advantage vapors and gases from a hydrocarbon feedstock such as crushed oil shale, a coal and shale mixture, or straight coal. A prime mover driven by steam generated in the system produces electrical energy for supplying electrical power to the microwave oven employed. The prime mover is steam driven, such steam being supplied by a boiler. The boiler is, in turn, provided with a series of heat sources taking the form of the hot, spent shale, and/or coke from the coal, passing through such oven as well as perhaps portions of condensate or residue and portions or all of the gases generated in the system. The system thus reduces and in some cases may even eliminate power requirements otherwise imposed on an external electrical power source. Principally, however, the system generates sufficient energy as to be a major supplement to the energy requirement of an external power source.Type: GrantFiled: March 6, 1981Date of Patent: August 9, 1983Inventor: Lester Hanson
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Patent number: 4364796Abstract: A method and a system for disposing of the pyrolysis gas generated in a pyrolyzing system to refine the same are presented in which an absorbing agent for eliminating harmful gas is introduced into a thermal reactor in such an amount that a large percent of such agent is unreacted but it is efficiently recovered together with char from the pyrolysis gas and also these recovered materials are utilized to remove oil and tar from water used in cleaning the pyrolysis gas, the recovered solid particles of the char and unreacted absorbing agent and the oil and tar separated from the cleaning water being recirculated in the pyrolyzing system.Type: GrantFiled: January 13, 1981Date of Patent: December 21, 1982Assignee: Seiichi Ishizaka, President of Agency of Industrial Science and TechnologyInventors: Yoshiaki Ishii, Naoyoshi Ando, Tsutomu Kume, Shosaku Fujinami
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Patent number: 4336125Abstract: A process and apparatus for production of synthetic hydrocarbon fuels from peat providing wide variation of the composite proportion of liquid-gas output while maintaining high overall carbon conversion to useful fuel. The process and apparatus utilizes three process stages in a single vessel providing functions of drying wet peat, provisions for addition of both wet and dry peat to a hydropyrolysis zone and gasification of the peat char.Type: GrantFiled: March 6, 1981Date of Patent: June 22, 1982Assignee: Institute of Gas TechnologyInventors: Sanford A. Weil, Dharamvir Punwani, William W. Bodle
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Patent number: 4320795Abstract: A process for the transfer of heat between solids is described in which a particulate solid is allowed to fall at a substantially uniform rate through a dilute phase fluidized bed of another particulate solid.Type: GrantFiled: March 14, 1977Date of Patent: March 23, 1982Assignee: Shell Oil CompanyInventors: John E. Gwyn, Scott C. Roberts
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Patent number: 4309197Abstract: There is provided a method for processing a pulverized solid fuel by heat, which comprises the steps of drying said fuel and subjecting the latter to two-stage pyrolysis with the resulting formation of vapor, gaseous products and small coke. According to the invention, at least a part of the small coke is additionally heated to a temperature of 800.degree. to 1500.degree. C. by combustion gas and/or by partial burning of the small coke, whereafter the heated small coke is separated from the combustion gas, fed to the first stage of pyrolysis and for drying the fuel. The heated small coke is gasified by steam. The resultant gasification products are separated from the small coke which is then fed as the heat carrier to the first stage of pyrolysis.Type: GrantFiled: September 13, 1979Date of Patent: January 5, 1982Inventors: Zinovy F. Chukhanov, Zinovy Z. Chukhanov, Sergei A. Tsuprov, Vladimir I. Samsonov, Vadim A. Karasev
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Patent number: 4280876Abstract: Method and apparatus for pyrolyzing agglomerative coals which comprises introducing a fluidized bed of hot char particles into a pyrolysis chamber or reactor, and injecting upwardly into the chamber a high velocity jet of agglomerative coal particles in a carrier gas, the fluidized hot char particles surrounding the high velocity coal jet and heating the coal particles to yield gaseous products and char. The hot char particles in the fluidized state and disposed around the coal jet are entrained in the upwardly expanding coal jet and mixed with the coal particles, so that by the time the coal particles contact the pyrolysis chamber wall, such coal particles being heated by the char have passed through the tacky state and are no longer tacky and do not adhere to the chamber wall. The gaseous product and char formed during pyrolysis are rapidly removed from the pyrolysis chamber, and such char can be separated, e.g.Type: GrantFiled: August 14, 1979Date of Patent: July 28, 1981Assignee: Occidental Research CorporationInventor: Norman W. Green
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Patent number: 4274941Abstract: Fine grained coal is fed into a first chamber of a generally horizontally extending fluidizing bed reactor while a stream of hot solid heat exchange material is passed through the chamber. The coal is then subjected to a fluidizing action with a low nitrogen and low oxygen content so as to degas the coal particles and obtain the combustible gases and liquid byproducts. The coke particles thus formed are then passed into an adjoining second chamber which acts as the combustion chamber and are subjected therein to fluidization with air and burning. Steam is generated in water-filled conduits passing through said second chamber. The heat exchanger particles are simultaneously heated up and are continuously fed back into the first zone of the reactor to contact fresh coal introduced thereinto.Type: GrantFiled: October 8, 1975Date of Patent: June 23, 1981Assignee: Bergwerksverband GmbHInventors: Klaus Janssen, Werner Peters, Hans-Dieter Schilling
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Patent number: 4263124Abstract: In a continuous process for recovery of liquid hydrocarbons from a solid carbonaceous material by pyrolysis of the carbonaceous material in the presence of a particulate source of heat, particulate contamination of the liquid hydrocarbons is minimized. This is accomplished by removing fines from the solid carbonaceous material feed stream before pyrolysis, removing fines from the particulate source of heat before combining it with the carbonaceous material to effect pyrolysis of the carbonaceous material, and providing a coarse fraction of reduced fines content of the carbon containing solid residue resulting from the pyrolysis of the carbonaceous material before oxidizing carbon in the carbon containing solid residue to form the particulate source of heat.Type: GrantFiled: June 5, 1979Date of Patent: April 21, 1981Assignee: Occidental Petroleum CorporationInventors: Gary H. Wickstrom, Everett W. Knell, Benjamin W. Shaw, Yue G. Wang
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Patent number: 4263125Abstract: A process and apparatus for production of synthetic hydrocarbon fuels from peat providing wide variation of the composite proportion of liquid-gas output while maintaining high overall carbon conversion to useful fuel. The process and apparatus utilizes three process stages in a single vessel providing functions of drying wet peat, provisions for addition of both wet and dry peat to a hydropyrolysis zone and gasification of the peat char.Type: GrantFiled: July 20, 1979Date of Patent: April 21, 1981Assignee: Institute of Gas TechnologyInventors: Sanford A. Weil, Dharamvir Punwani, William W. Bodle
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Patent number: 4247367Abstract: This disclosure is directed to an economical system for the pyrolysis of municipal solid waste to recover valuable by-products while reducing the putrecibility and bulk of the residue requiring disposal. Prior to this treatment, the solid waste has been processed to remove most of the metallic components, and shredded, which steps are not part of the invention disclosed. The pyrolysis and by-product recovery technology is complicated by (a) the inherent variability of the chemical and physical characteristics of the shredded solid waste as received at the pyrolysis plant and (b) the relatively low heat value of said waste as thus received.Type: GrantFiled: November 16, 1979Date of Patent: January 27, 1981Inventor: Bertram B. Reilly