And Refining Char, E.g., Desulfurizing Coke Patents (Class 201/17)
  • Patent number: 4011303
    Abstract: Sulfur-bearing coke is desulfurized by heating it and reacting it with dilute sulfur vapor to form carbon disulfide. The reaction will proceed utilizing air-polluting sulfur components in the coke, thereby removing such components to provide a relatively non-polluting coke as a fuel.
    Type: Grant
    Filed: November 12, 1975
    Date of Patent: March 8, 1977
    Assignee: William H. Sayler
    Inventor: Douglas MacGregor
  • Patent number: 4007092
    Abstract: A low sulfur coke product is obtained in an integrated fluid coking and gasification process in which an oxygen-containing gas is introduced into the upper portion of the gasification zone and steam is introduced into the lower portion of the gasification zone. The desired degree of coke desulfurization is controlled by controlling the thickness of the gasifier coke layer on the gaseous reactor leaving solids per pass.
    Type: Grant
    Filed: March 18, 1975
    Date of Patent: February 8, 1977
    Assignee: Exxon Research and Engineering Company
    Inventors: William J. Metrailer, Walter Weissman
  • Patent number: 3993455
    Abstract: Mineral matter, including pyrite, is removed from coal by treatment of the coal with aqueous alkali at a temperature of about 175.degree. to 350.degree. C, followed by acidification with strong acid.
    Type: Grant
    Filed: June 25, 1973
    Date of Patent: November 23, 1976
    Assignee: The United States of America as represented by the Secretary of the Interior
    Inventors: Leslie Reggel, Raphael Raymond, Bernard D. Blaustein
  • Patent number: 3991557
    Abstract: Pulverized coal having a sulfur content of up to 2.5% is introduced into a gasification vessel together with air preheated to a temperature above 900.degree. F. The pulverized coal and preheated air react in the gasification vessel which is operated at temperatures in excess of 1800.degree. F. with a residence time of less than three seconds therein. The reaction between the concurrent downwardly flowing coal and air produces a product comprising partially gasified char entrained in a product gas comprising methane, hydrogen, hydrogen sulfide and oxides of carbon. The partially gasified low sulfur char entrained in the product gas is withdrawn from the gasifier and conducted to a waste heat boiler to provide steam as a source of energy for power generation. Thereafter, the low sulfur char is separated from the product gas and fed to a char storage hopper which maintains the char at a temperature above 900.degree. F. and preferably above 1100.degree. F.
    Type: Grant
    Filed: February 20, 1976
    Date of Patent: November 16, 1976
    Inventor: Ernest E. Donath
  • Patent number: 3988120
    Abstract: A method of desulfurizing high sulfur low grade coal by immerising it in an aqueous solution of a polar compound containing nonpolar groups bonded with polar groups, thereby providing low sulfur coal.
    Type: Grant
    Filed: November 26, 1974
    Date of Patent: October 26, 1976
    Inventor: Tung-Yu Chia
  • Patent number: 3970434
    Abstract: Coal is gasified in the presence of a small but effective amount of alkaline earth oxide, hydroxide or carbonate to yield a char fraction depleted in sulfur. Gases produced during the reaction are enriched in sulfur compounds and the alkaline earth compound remains in the char fraction as an alkaline earth oxide. The char is suitable for fuel use, as in a power plant, and during combustion of the char the alkaline earth oxide reacts with at least a portion of the sulfur oxides produced from the residual sulfur contained in the char to further lower the sulfur content of the combustion gases.
    Type: Grant
    Filed: October 7, 1974
    Date of Patent: July 20, 1976
    Assignee: The United States of America as represented by the United States Energy Research and Development Administration
    Inventors: Stanley J. Gasior, Albert J. Forney, William P. Haynes, Richard F. Kenny
  • Patent number: 3960513
    Abstract: A process for reducing the amount of free and combined sulfur, such as pyritic, organic or elemental sulfur in coal; removing of these sulfur species may be made in an acid, basic or neutral solutions; at least 50 percent and up to 90 percent of sulfur, by weight, originally present in coal may be removed.
    Type: Grant
    Filed: March 29, 1974
    Date of Patent: June 1, 1976
    Assignee: Kennecott Copper Corporation
    Inventors: Jagdish Chandra Agarwal, Richard Andre Giberti, Louis John Petrovic
  • Patent number: 3957620
    Abstract: In the treatment of petroleum heavy oil by thermally cracking a petroleum heavy oil mixed with an alkali metal carbonate or carbonates at a cracking temperature of 450.degree. to 650.degree.C and recovering the resulting low sulfur liquid hydrocarbon and light hydrocarbon gas, (1) gasification of residual coke produced by said cracking, in the presence of the alkali metal carbonate or carbonates and an alkali metal sulfide or sulfides by-produced during the cracking, with steam alone or steam together with an oxygen-containing gas, at 550.degree. to 800.degree.C and under the atmospheric pressure to 10 atm. to produce a hydrogen- and CO.sub.2 -- rich gas, and (2) regeneration from said by-produced alkali metal sulfide or sulfides to said alkali metal carbonate or carbonates, with CO.sub.2 gas produced by said gasification and steam, are simultaneously carried out in the same reaction zone.
    Type: Grant
    Filed: August 13, 1973
    Date of Patent: May 18, 1976
    Assignee: Daikyo Oil Company Ltd.
    Inventors: Yukimasa Fukui, Teikichi Hosoi, Hisashi Makita, Heihachiro Mukaida, Toshiro Takahashi
  • Patent number: 3954674
    Abstract: This invention relates to a process for the simultaneous desulfurization and calcination of "green coke.
    Type: Grant
    Filed: December 26, 1973
    Date of Patent: May 4, 1976
    Inventor: Thomas Reis
  • Patent number: 3948617
    Abstract: The reduction of emission of sulphur dioxide from fuels containing sulphur components when such fuels are combusted. The reduction of such sulphur dioxide emissions upon the combustion of such sulphur containing fuels is accomplished by the introduction into such fuels an alkali additive which is pressure fed into such fuels at a point closely adjacent the burner structure for the combustion process thus insuring for the intimate mixture of such alkali material with the fuels to be combusted. The alkali material serves to neutralize the sulphur containing impurities which are normally caused to exit through a conventional stack exit for the exhaust gases from the burner.
    Type: Grant
    Filed: February 19, 1974
    Date of Patent: April 6, 1976
    Inventor: Benjamin Withorn
  • Patent number: 3942956
    Abstract: A nitrogenous ingredient is eliminated from solid fuel, for example, coal, by treating in a treating chamber, the coal with a treating gas having a predetermined temperature and composition at a temperature of 650.degree. to 1200.degree.C, the treating gas being prepared by uniformly mixing, in a conditioning chamber located upstream from the treating chamber, a predetermined amount of steam or water and hydrogen gas or a mixture gas containing at least 30% by volume of hydrogen gas together with an inert burnt gas containing at most 2% by volume of oxygen gas.
    Type: Grant
    Filed: February 6, 1975
    Date of Patent: March 9, 1976
    Assignee: Mifuji Iron Works, Ltd.
    Inventor: Shozo Ito
  • Patent number: 3933596
    Abstract: Coke is desulfurized by calcining coke at a temperature of 1600.degree. - 2200.degree. F. in admixture with sodium carbonate, followed by direct contact with phosgene or a mixture of carbon monoxide and chlorine at a temperature of 1200.degree. - 1800.degree. F. to produce coke having sulfur contents of less than 0.5 percent.
    Type: Grant
    Filed: April 1, 1974
    Date of Patent: January 20, 1976
    Assignee: The Lummus Company
    Inventors: Raymond H. Long, Morgan C. Sze