Abstract: An improved gasification system, in which synthesis gas is produced through the operation of a fuel gas production bed comprising an upper layer (66) of organic input material, typically in the form of pellets or briquettes of substantially uniform size and configuration, two intermediate layers, one intermediate layer (70) for carbonizing the input material, and the other intermediate layer (72) for partially oxidizing and substantially completely pyrolyzing the input material and a lower layer (68) of tar-free charcoal. The length of the gas production bed from the top of the upper intermediate layer to the point where gas exits from the gas production bed is approximately at least 1.5 times the diameter of the bed, but not less than 7 feet. The removal of charcoal from the gas production bed is controlled and the operation of the bed otherwise controlled such that the charcoal produced during the process is activated carbon.

Abstract: Increased yields of liquid hydrocarbon are obtained from a carbonaceous material (e.g., coal) by a two-stage process comprising pretreatment of the carbonaceous material with an appropriate gas in a first stage, followed by pyrolysis of the pretreated carbonaceous material, in a second stage.

Abstract: Coke is produced from coal by coking the coal, and optionally by drying and/or preheating the coal prior to coking, and further optionally by dry cooling the coke subsequent to coking. At least the coking step is achieved in a pressure tight container which may be a transportable or tippable container. The coking step is performed in the container by conducting a gas through the container in direct or indirect heat exchange relationship with the coal and forming coke. The coking step includes a phase of lump coke formation achieved by heating the coal in a temperature range of between approximately 250.degree. and 600.degree. C. by indirect heat exchange only.

Abstract: An apparatus and method for gas treating a particle bed wherein a uniform temperature gradient is achieved. A support member, such as a grate, serves to support a bed of particles on a surface thereof. The support member is moved in a predetermined direction. Gas is released from a plurality of positions at different depths in the bed.

Abstract: Hydrogen sulfide issuing from an oil shale retort is captured in an absorbent bed. When the bed is regenerated as with oxygen containing gas, the sulfur dioxide liberated is reintroduced into the retort for reaction with the spent shale.

Abstract: An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

Abstract: A method for thermally flashing gases and liquids from a particle-form, normally solid carbonaceous material, including: contacting the carbonaceous material with a gas, which may supply at least part of the necessary heat, at essentially atmospheric pressure and a temperature and residence time sufficient to maximize the flashing of gases and liquids from the carbonaceous material but insufficient to decompose significant amounts of the flashed gases and liquids. Preferably, the carbonaceous material is entrained in the gas to form an entrained descending body of carbonaceous material in the contact zone. Residual solids containing carbonaceous material may be burned to produce fuel gas or reacted with steam or air and steam to form a synthesis gas and at least part of the flue gas or the synthesis gas utilized as the contact gas.

Abstract: A cyclic char gasifier process and apparatus are described wherein reactant gases are first compressed into the pores of a char fuel to react and then the reacted gases are expanded out of the char fuel pores. This cycle of compression and expansion is repeated with fresh reactant gases supplied for each compression and with reacted gases removed at each expansion. Air and steam are preferred reactant gases when the char fuel is to be gasified by oxidation. Reacted gases from such an oxidation gasifier plant are preferred reactant gases when the char fuel is to be partially gasified by devolatilization. Rapid reaction to a rich product gas can occur over the large surface area inside the char pores and the undesireable Neumann reversion reaction is suppressed by the strongly reducing conditions prevailing therein. The gases of devolatilization gasification can be used to enrichen the gases of oxidation gasification by using two cyclic char gasifier plants in a combination system.

Abstract: A two-step method and apparatus, according to the fluidized bed principle, for the production of coke, rich gas and pyrolysis tar, with the object of executing the method in a compact apparatus arrangement, with high energy efficiency and high throughput capacity.This is accomplished by a sequence in which the fine grains removed from the drying vapor mixture are removed from the actual pyrolysis process, and a hot gas, alien to the carbonization, is used as fluidization medium in the pyrolysis reactor, and with a hot gas-high performance separator being used for the dust separation from the pyrolysis gas, with the combustion exhaust gas produced in the combustion chamber being used for the indirect heating of the fluidization medium, for the pre-heating of the gas, which is alien to the carbonization, and for the direct heating in the dryer.

Abstract: A method of pyrolyzing and desulfurizing coal in a transport reactor to recover volatile fuel values and hydrogen by heating particulate coal entrained in a carrier gas substantially free of oxygen to a pyrolysis temperature in a zone within three seconds.

Abstract: The rate of calcining carbonaceous material in a rotary kiln is increased by introducing oxygen into the inlet of air fans mounted on the kiln. The introduction of oxygen is effected during a predetermined portion of each kiln revolution and is effective to enrich the oxygen content of air supplied to the kiln to approximately 23-25% oxygen. By so enriching the interior kiln atmosphere during calcining of material such as petroleum coke, greater temperatures are obtained than will be obtained by the use of air alone thereby accelerating the evolution and combustion of volatile materials during calcination. The accelerated evolution and combustion of such volatiles enables the rate at which carbonaceous materials can be calcined in a kiln of a predetermined length to be increased.

Abstract: A method and apparatus for sealing the drive end of a chamber for the preparation and hydrogenation of coal with hydrogen to form hydrocarbons in which the chamber comprises a hollow cylinder with a rotatable element therein having a conveying web thereon and in a sealing region a pressurized sealing substance such as coal particles mixed with oil is fed from a storage container through a feed passage into an annular recess at a pressure higher than that in the chamber so that the scaling substance passes through a conical annular gap which tapers towards the chamber. A further narrower gap on the drive side of the recess leads to a further annular recess from which the sealing substance can be extracted through a return pipe. Pressure comparison means control the feed pressure in the feed passage. The recesses and the annular gap can be provided by machining the rotatable element rather than the hollow cylinder and forward feed screw forms may be provided on the rotatable element in the sealing region.

Abstract: In plant for hydrogenating coal to form hydrocarbons, wherein coal in powder or piece form is fed from a hopper into a preparation chamber, is compressed, conveyed and heated by a rotor comprising a rotating friction element and passed, through a feed aperture, into a hydrogenation chamber wherein hydrogen is injected into it by nozzles, monitoring and controlling means are provided whereby upon the pressure in the hydrogenation chamber rising above that in the end of the preparation chamber adjacent the hydrogenation chamber, as measured by sensors and gauges, the feed aperture is closed and the rotor is stopped. Preferably the feed aperture is closed by providing a conical portion on the rotor and a conical seat on the cylinder forming the chamber, the rotor normally being held in a position to keep the feed aperture open by an hydraulic cylinder but upon the pressure sensors sensing over pressure in the chamber, the cylinder is vented by control means to close the feed aperture.

Abstract: A process and apparatus for production of synthetic hydrocarbon fuels from peat providing wide variation of the composite proportion of liquid-gas output while maintaining high overall carbon conversion to useful fuel. The process and apparatus utilizes three process stages in a single vessel providing functions of drying wet peat, provisions for addition of both wet and dry peat to a hydropyrolysis zone and gasification of the peat char.

Abstract: A method is disclosed for recovering liquids and gases by a rapid hydropyrolysis of carbonaceous solids which comprises subjecting the carbonaceous material in a stream of carrier gas to a first pressure and a first temperature below the decomposition temperature of the carbonaceous material; reducing substantially in a single step the pressure on the stream of carbonaceous material from the first pressure to a second pressure, the ratio of the first pressure to the second pressure being at least 1.

Abstract: A continuously operable retort-type processing system for the recovery of petroleum-like products from comminuted oil-bearing shale and other oil-yielding particulate solid materials. The retort portion of the system includes an insulated retort outer shell for a wall jacket-type heat exchanger. Disposed within the retort, all driven from a common axially disposed motor-driven shaft, are a plurality of stirring fingers, wall scrapers and discharge shovels, the latter for use in discharge of spent solid material from the retort. The system envisions burning gases from the process to provide a fluid heat exchange medium as a source of the heat required for the process. The system further includes means for the admixture of steam and acetic acid with the starting particulate materials prior to its introduction into the retort.

Abstract: Particulate oil shale is subjected to a pyrolysis with a hot, non-oxygenous gas in a pyrolysis vessel, with the products of the pyrolysis of the shale contained kerogen being withdrawn as an entrained mist of shale oil droplets in a gas for a separation of the liquid from the gas. Hot retorted shale withdrawn from the pyrolysis vessel is treated in a separate container with an oxygenous gas so as to provide combustion of residual carbon retained on the shale, producing a high temperature gas for the production of some steam and for heating the non-oxygenous gas used in the oil shale retorting process in the first vessel. The net energy recovery includes essentially complete recovery of the organic hydrocarbon material in the oil shale as a liquid shale oil, a high BTU gas, and high temperature steam.

Abstract: In the fluidized carbonization and calcination of coal to form a reactive coal calcinate for admixture with bituminous binder for briquetting, curing, and coking to produce form coke, the improvement of recovering medium BTU gases in the overheads by using as the fluidizing medium oxygen diluted with steam or carbon dioxide and removing the steam or carbon dioxide from the overheads.

Abstract: A method for recovering and utilizing heat of coke-oven gas, which comprises: through heat exchange with a high-temperature coke-oven gas generated from a coke oven battery and containing vaporized coal tar, vaporized low boiling point substances and dust, drying and preheating a blended raw material coal fine to be charged into coking ovens of said coke oven battery, and, on the other hand, causing most of said coal tar contained in said coke-oven gas to condense and deposit onto the particle surfaces of said coal fine during the process of said heat exchange, thereby recovering and utilizing sensible heat and condensation heat of said coke-oven gas and substances contained therein, and at the same time, eliminating most of the contained coal tar from said coke-oven gas.

Abstract: A method and apparatus for cooling dustlike or fine-grained reaction residue emanating from a reactor is disclosed. According to the method reaction residue emanating from a reactor passes downwardly into a cooling shaft where it is maintained in the form of a pile of bulk material under a gas pressure of 20 to 200 bars while cooling gas passes upwardly through said cooling shaft in counter-current and is removed at the top of said cooling shaft into the reactor. The apparatus comprises means for effecting cooling of such reactor residue.

Abstract: A single retort and accumulator structure includes two heating zones for successively removing volatile material from dried crushed coal so that the resultant calcined char has less than about 7 weight percent volatile material and is suitable as a raw material for producing formcoke. In the first zone (carbonizing zone) heat carrying solids are introduced with crushed coal to heat the powdered coal to a temperature in the order of about 800.degree. F. to 1000.degree. F. and produce a carbonized char containing about 10% to 20% by weight of volatile material. The resultant carbonized char is fed onto a trommel, or rotating cylindrical or tapered screen, and the char passes through the screen into a calcining fluidized bed zone. The fluidized bed is maintained by upwardly directed jets of an oxygen containing gas and steam. The temperature of the fluidized bed zone is in the vicinity of about 1200.degree. F. to 1600.degree. F.

Abstract: Crushed oil shale is segregated into a major portion of relatively large particles and a minor portion of "fines," such as will pass through 1/8-inch screen openings. The large particles are subjected to retorting in an upflowing bed in countercurrent contact with a downflowing hot eduction gas, while the fines are fed onto and controllably transported across the hot planar surface of a free-standing truncated cone of spent shale at the top of the retort.

Abstract: Prior to starting up a plant in which fine coke is produced by mixing high bituminous lignite coal with circulating hot fine coke serving as a heat carrier in the plant, hot inert gas is admitted into the mixing unit in which the coal and coke are admixed. Only after all parts of the plant are thus preheated, the operation of the plant is started up.

Abstract: An improved method and apparatus for producing hardened carbonaceous agglomerates from a feedstock selected from the group consisting of finely divided coal solids, finely divided coal-derived solids and hydrocarbonaceous binders is disclosed.

Abstract: In the multi-stage fluidized carbonization of coal to produce, oil, gas and char, oil containing vapors from the first stage are used as the fluidizing gas to dry the incoming coal feed. The oil vapor pressure of the fluidizing gas is maintained at a value under 10 mm. to prevent oil condensation in the fluidized drying vessel. The technique makes possible the recovery of sensible heat from the first stage overheads.

Abstract: A method for converting coal to liquid hydrocarbons or oil-soluble solids mprises the steps of contacting said coal with oxygen for at least 15 minutes, at a temperature from about 90.degree. to about 225.degree. C., heating the oxidized coal to a temperature from about 250.degree. to about 450.degree. C., and maintaining the temperature for at least 15 minutes.

Abstract: This invention comprises an apparatus and process for drying and/or heating materials. This invention was designed for use in the production of charcoal from wood feed material; however, it can be used to heat and/or dry many types of materials. Feed material is disposed in a reactor, wherein there is provided a first array of input channels extending through said feed material, through which hot gases are introduced into said feed material, and a second array of output channels extending through said feed material to collect and exit those hot gases and any gases or vapors derived from the heating and/or drying of the feed material.

Abstract: Crushed oil shale is segregated into a major portion of relatively large particles and a minor portion of "fines" which will pass through screen openings up to about 1/4 inch in size. The large particles are subjected to retorting as an upflowing moving bed in countercurrent contact with downflowing hot eduction gas, while the fines are retorted by controlled distribution over the hot upper surface of the bed of retorted large particles.

Abstract: Apparatus for conducting the flash pyrolysis of a primary material, particularly coal, and employing a secondary material, particularly hot char, as a heat source, comprising a rectangular slot for injection of a stream of particulate coal, which communicates with a substantially rectangular reactor or pyrolysis chamber. Wells are positioned on opposite sides of the pyrolysis chamber and in communication therewith, for introduction of fluidized secondary material, particularly hot char, into the pyrolysis chamber for admixture therein with and for heating the stream of primary material, such as coal. The pyrolysis chamber has a transition chamber, and a cylindrical separator chamber communicates with the transition chamber for receiving pyrolysis products. The separator chamber is provided with a tangential inlet, a solids outlet conduit positioned about 90.degree. around the circumference of the separator chamber from the tangential inlet, and a perforate gas receiver.

Abstract: Hydrocarbons are formed of coal and water. The water is converted or dissociated separately into hydrogen and oxygen in a first chemical reactor by thermochemical and/or electrolytic processing. The resulting hydrogen is then reacted with the coal in a second reactor to produce the hydrocarbons. Residual carbon from the second reactor is reacted in a third reactor with oxygen derived from the first reactor to produce carbon monoxide. The carbon monoxide is reacted with residual hydrogen from the second reactor or hydrogen from the first reactor to produce additional hydrocarbons. The energy for the endothermic and/or electrolytic processing in the reactors and for auxiliary equipment of the apparatus is supplied by a very high-temperature, gas-cooled, nuclear reactor by heat interchange with the cooling gas, helium. The cooling gas operates through heat-exchange means which isolates the cooling gas from the processing apparatus.

Abstract: A process for producing calcined coke agglomerates characterized by having a low reactivity to carbon dioxide. The process includes calcining green coal agglomerates at a temperature within the range of 1700.degree. F. to 1950.degree. F. (927.degree. C. to 1066.degree. C.) in a calciner. The agglomerates are exposed to a gaseous atmosphere which before cracking contains not less than 20% by volume of at least one straight chain aliphatic hydrocarbon gas containing one to four carbon atoms. The gaseous atmosphere is preheated to a temperature within the range of 200.degree. F. to 700.degree. F.(93.degree. C. to 371.degree. C.) prior to being introduced into the calciner. Carbon produced when the hydrocarbon gas is cracked, is deposited as vitreous carbon on the surfaces, in the fissures and in the pores of the agglomerates. The calcined coke aggglomerates discharged from the calciner have a reactivity to carbon dioxide of between 2% to 8%.

Abstract: A horizontal circulating carbonizer comprising an annular horizontally rotatable circulating hearth disposed rotatably, a carbonizer body covering said hearth, a coal feeder equipped on the carbonizer body, a preheating zone disposed in the vicinity of said feed coal supply opening, a carbonizing zone connected to said preheating zone, a cooling zone connected to the carbonizing zone, and a discharger of cooled coke, and a process for the preparation of coke using this horizontal circulating carbonizer.

Abstract: A vertical vessel, having a low bed of broken material, having included combustible material, is initially ignited by a plurality of ignitors spaced over the surface of the bed, by adding fresh, broken material onto the bed to buildup the bed to its operating depth and then passing a combustible mixture of gas upwardly through the material, at a rate to prevent back-firing of the gas, while air and recycled gas is passed through the bed to thereby heat the material and commence the desired laterally uniform combustion in the bed. The procedure permits precise control of the air and gaseous fuel mixtures and material rates, and permits the use of the process equipment designed for continuous operation of the vessel.

Abstract: Coke is produced with high yield and low sulfur by heating and drying ground coking coal at 200.degree. to 300.degree. C. for 15 to 120 minutes in air, and then heating in two semicoking stages in nitrogen in fluidized bed reactors. The first semicoking stage is 400.degree. to 600.degree. C. for 10 to 60 minutes while the second is 800.degree. to 1,100.degree. C. for 10 to 60 minutes. Tar is condensed from the offgases of the first semicoking stage and the residual gas is divided and 15 to 95% recycled to the first semicoking reactor. Similarly, 15 to 95% of the offgases from the second semicoking reactor is recycled. The condensed tar is fed to the final coke-forming operation.

Abstract: Apparatus for continuously pyrolyzing, vaporizing or gasifying a particulated carbonaceous feed material in which preheated heat-containing bodies or pebbles are admixed with the feed material in a stratified manner to form a downwardly moving columnar reaction mass, with a remaining portion of the pebbles substantially devoid of any feed material disposed in a surrounding layer relative to the reaction mass. Gas is continuously passed transversely through the reaction mass and surrounding layer in a manner to sweep the gaseous pyrolysis reaction products out of the reaction chamber and wherein the layers of pebbles surrounding the reaction mass serve to effect a deposition of carbonaceous residue preventing encrustation and fouling of the reactor.

Abstract: The specification discloses apparatus and methods for recovery of coal fines and for recycling thereof incidental to a self-contained system for charging preheated coal into coke ovens. The apparatus enables a system for charging preheated coal into coke ovens to meet pollution control regulations. The apparatus comprises four circulating streams of liquid for carrying coal fines in a slurry, namely, the charge main liquor circuit, the excess recycle gas scrubber circuit, the charge line condenser circuit and the charge bin vent condenser circuit. The -28 mesh coal with the liquor from the various circuits goes to a clarifier or thickener. Floating fines from top and settled fines from the bottom of the thickener are pumped via a fines tank to filters from which the solid or coagulated fines are restored to the wet coal feed to the heaters.

Abstract: Process for producing formed coke for metallurgical use from coal powder by continuously heating with a high temperature gas as heating medium for carbonizing agglomerated coal which are made of coal powder and a binder such as coal tar, pitch and petroleum asphalt, comprising providing tuyeres for introducing gas at the middle and the lower parts of an upright type carbonization oven, adjusting temperature of the gas to be supplied to the tuyere at the middle part at 600.degree. to 800.degree. C, adjusting the supply rate of the gas so as to maintain the temperature of the gas on the agglomerated coal at 300.degree. to 500.degree. C, and further adjusting the supplied heat to the lower part of the carbonization oven including the lower tuyere to amount less than 50% of the total supplied heat.

Abstract: A process for making low sulfur oil by reacting aqueous reactive sludges and slurries with hot, pressurized carbon monoxide and hydrogen (synthesis gas) wherein the wastes are first concentrated by coking in the liquid phase under a pressure of 300 to 3000 psig at a temperature of 400.degree. to 550.degree. F for from 5 minutes to 2 hours.

Abstract: Apparatus and process for continuously pyrolyzing or gasifying a particulated carbonaceous feed material in which preheated heat-containing bodies or pebbles are admixed with the feed material in a stratified manner to form a downwardly moving columnar reaction mass, with a remaining portion of the pebbles substantially devoid of any feed material disposed in a surrounding layer relative to the reaction mass. Gas is continuously passed transversely through the reaction mass and surrounding layer in a manner to sweep the gaseous pyrolysis reaction products out of the reaction chamber, and wherein the layers of pebbles surrounding the reaction mass serve to effect a deposition of carbonaceous residue, preventing encrustation and fouling of the reactor system.

Abstract: An apparatus for treating raw material comprises a mixing chamber having fuel and air inlets for admitting therein fuel and air which are mixed to produce a combustible mixture. A combustion chamber receives the combustible mixture and burns the same to evolve hot products of combustion which are fed directly into an adjoining conditioning chamber. Additional gas is supplied to the conditioning chamber and mixed with the products of combustion to form a conditioned treating gas having a prescribed temperature and composition. To promote rapid and uniform mixing of the gases and hence form a uniform treating gas, the conditioning chamber is connected directly to and has a volume one and one-half to six times greater than that of the combustion chamber. A treating chamber disposed downstream from the conditioning chamber receives both the preconditioned treating gas and the raw material to be treated and the raw material is acted thereon by the treating gas while temporarily stored in the treating chamber.

Abstract: Coke is produced with high yield and low sulfur by heating and drying ground coking coal at 200.degree. to 300.degree. C. for 15 to 120 minutes in air, and then heating in three semicoking stages in fluidized bed reactors. The first semicoking stage is 300.degree. to 470.degree. C. for 10 to 20 minutes; the second is 400.degree. to 600.degree. C. for 10 to 20 minutes; while the third is 800.degree. to 1100.degree. C. for 10 to 20 minutes. Tar is condensed from the offgases of the first two semicoking stages and the residual gas from each is divided and 60 to 80% recycled as fluidizing gas to the same semicoking reactor. 10 to 20% of the offgases from the third semicoking stage is recycled to the third stage as fluidizing gas. In addition, oxygen is used as make-up fluidizing gas in each of the three stages, in the amount of 10 to 30 liters per kilogram of dry coal in the first stage, 5 to 20 liters per kilogram of dry coal in the second stage, and 40 to 100 liters per kilogram of dry coal in the third stage.

Abstract: A modified rotary kiln suitable for calcining normally solid carbonaceous material, having adapted thereto at one end a firing crown and means for admitting combustible gases or liquids and air; a feeding means for such solid carbonaceous material to be calcined adapted to the other end of the kiln; and wherein the combustion gases and solid materials travel countercurrently in the kiln during calcination, wherein: at least one series of at least two tuyeres passes through the wall of the kiln symmetrically spaced to and at about a point longitudinally in the middle one-half of the longitudinal axis of the kiln; each tuyere terminating within the kiln through a nozzle on the side of the tuyere at a height sufficient for the discharge of exterior oxidizing gases passing therethrough at a point above the bed of the carbonaceous material in the kiln, directing the exterior oxidizing gases toward the feed end at about the same acute angular direction from a line passing through the nozzle and parallel to the long

Abstract: A fluid coking process is provided in which a relatively large amount of hydrogen sulfide is added to the coker fluidizing gas. A preferred fluidizing gas is a mixture of hydrogen and hydrogen sulfide.

Abstract: A method for treating raw material comprises mixing fuel and air in a mixing chamber to produce a combustible mixture, ejecting the combustible mixture into a combustion chamber and burning it therein to evolve hot products of combustion which are fed directly into an adjoining conditioning chamber. Additional gas is supplied to the conditioning chamber and mixed with the products of combustion to form a conditioned treating gas having a prescribed temperature and composition. To promote rapid and uniform mixing of the gases and hence form a uniform treating gas, the conditioning chamber is connected directly to and has a volume 11/2 to 6 times greater than that of the combustion chamber. A treating chamber disposed downstream from the conditioning chamber receives both the preconditioned treating gas and the raw material to be treated and the raw material is acted thereon by the treating gas while temporarily stored in the treating chamber.

Abstract: A single regenerative coke oven battery is constructed and operated as a plurality of individual and separate groups of heating walls, each group capable of independent reversal and heating cycles. During slow-down operations, one or more of the individual groups of heating walls is shut down for a preselected time period, with no flow of combustion air, fuel and waste gas in the heating walls, while the remainder of the groups are operated at substantially full air and gas flow. The battery is capable of a slow-down operation while avoiding uneven coking and variations in the amount of byproduct coke oven fuel gas generated.

Abstract: A pyrolysis reactor has a feed system which includes one or more circularly arcuate feed tubes removably inserted through the outer wall of the reactor. Each feed tube is slidably disposed in a corresponding circularly arcuate external guide sleeve for positioning the discharge end of each feed tube at a predetermined location and orientation within the reactor. A hot particulate material normally suspended in a fluid carrier is fed into the reactor. The inlet end(s) of the feed tube(s) can be connected to a source of particulate agglomerative carbonaceous material suspended in a fluid carrier for injection into the reactor, preferably at a location where the hot particulate material is uniformly distributed throughout the cross-section of the reactor. Means can be provided to cool the particulate agglomerative carbonaceous material during transit through the feed tube(s) to prevent agglomeration in the feed tube(s).

Abstract: Pulverulent coke and granular reactive coke are produced, respectively, from fines and grains of coal of grades which are not normally usable for coking, containing more than 15% of volatile matter and having a swelling index between 1 and 8, by carbonization between 600.degree. C and 1100.degree. C, wherein combustion air in excess of that which would be necessary to bring the coke to the desired coking temperature is introduced into a slightly inclined rotary tubular oven through which the coal passes during its conversion into coke, the air introduction being effected between the coke outlet and the zone in which the product reaches its maximum temperature and being controlled so that the temperature of the gases issuing from the oven is kept above 600.degree. C. At least 60% of the air is preferably introduced at the downstream end of the oven, and further air may be introduced at intermediate points along the oven length.

Abstract: Process for making low sulfur oil by reacting aqueous reactive sludges and slurries with hot, pressurized carbon monoxide and hydrogen (synthesis gas) wherein the wastes are first concentrated by coking in the liquid phase under a pressure of 300 to 3000 psig at a temperature of 400.degree. to 550.degree. F for from 5 minutes to 2 hours.

Abstract: A process for the dry distillation of used rubber in a fluidized bed-forming oven comprises heating used rubber under agitation in the presence of solid particles to temperatures sufficient to make the rubber pulverized and further heating the thus-obtained rubber particles to temperatures sufficient to pyrolyze the rubber particles while forming a fluidized bed thereof and burning a part thereof in the stream of an oxygen-containing fluidizing gas.

Abstract: In the production of formed coke, the temperatures and times of the oxidation and carbonization phases can be reduced if 5 to 12% by volume of oxygen is included in the fluidizing gas in a fluidized bed reactor in which the carbonization phase is conducted.