Miscellaneous Patents (Class 201/41)
  • Patent number: 4308102
    Abstract: Flue gas discharged from a recuperator or regenerator of a coke oven battery has the steam thereof removed by means of a direct or indirect cooling and condensation operation. After the steam is removed from the flue gas it is then passed through a coke dry cooling plant in direct contact with hot coke therein to form dry cooled coke while simultaneously increasing the temperature of the flue gas. The flue gas is then passed through a coal preheating plant to directly contact and dry and preheat moist coking coal contained therein. The entire system is open, such that a given quantity of the flue gas passes only once through the system. When the temperature of the flue gas as received from a coke oven battery is extremely high, then the flue gas may be subjected to a partial cooling operation prior to the cooling and condensation operation.
    Type: Grant
    Filed: February 21, 1980
    Date of Patent: December 29, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Claus Flockenhaus, Joachim F. Meckel
  • Patent number: 4290854
    Abstract: A horizontal coke oven battery construction in which a pusher is mounted to extend into the batteries from one side and push coke out of the batteries on the opposite side, comprises a plurality of coke oven batteries disposed in a row. A first waste gas flue extends along the pusher side of the batteries and a second waste gas flue extends along the coke side. A stack flue at one end of the batteries is connected to the first and second waste gas flues. The construction includes means for directing the heating gases into each oven battery during operation so that, in respect to the pusher and coke size, approximately one-half of the batteries is heated by upward burning and the other half is heated by downward burning. For example, all odd numbered batteries may be heated in the same direction and all even numbered batteries heated in the same direction.
    Type: Grant
    Filed: December 13, 1979
    Date of Patent: September 22, 1981
    Assignee: Firma Carl Still
    Inventors: Manfred Strobel, Friedrich, both of Thiersch
  • Patent number: 4284476
    Abstract: A heat carrier gas is passed through a coke dry cooling plant in direct contact with hot coke therein to form dry cooled coke while simultaneously increasing the temperature of the heat carrier gas. The heat carrier gas is then passed through a coal preheating plant to directly contact and dry and preheat moist coking coal contained therein. The entire system is open, such that a given quantity of the heat carrier gas passes only once through the dry cooling plant and the coal drying and preheating plant. The heat carrier gas may be a flue gas which is passed directly to the coke dry cooling plant without any preliminary pretreatment, and preferably is a flue gas which is supplied directly from a regenerator or recuperator of a coke oven battery. Alternatively, the heat carrier gas may be in the form of a fuel gas which is inert with respect to the hot coke, for example a waste gas or stack gas supplied from an adjacent metallurgical installation, such as a steel mill.
    Type: Grant
    Filed: February 21, 1980
    Date of Patent: August 18, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Claus Flockenhaus, Joachim F. Meckel
  • Patent number: 4283253
    Abstract: An improved coke oven battery and an improved method for production of coke and byproducts are provided. The filling gas escaping during the filling of the oven chambers with coal is initially rendered inert by admixing flue gas. Then the resulting gas mixture of filling gas and flue gas is withdrawn via a conduit fed with flushing liquor from the coke oven gas off-take main and is added to the raw coke oven gas after the coke oven gas off-take main. The tar and coal containing flushing liquor coming from the filling gas conduit is fed back to the coke oven gas off-take main after removal of the tar.
    Type: Grant
    Filed: September 18, 1980
    Date of Patent: August 11, 1981
    Assignee: Krupp-Koppers GmbH
    Inventors: Joachim Polenz, Hans Wagner
  • Patent number: 4282066
    Abstract: Coal, either as coal fines or as coal briquettes, is introduced into a coking chamber and is thereat exposed to microwave radiation to transform the coal into hot coke. Preferably, the microwave radiation is at a frequency of from twenty to 3000 MHz. The hot coke is then passed to a cooling zone whereat photocells absorb radiant energy from the hot coke and transform the thus absorbed radiant energy into electricity.
    Type: Grant
    Filed: March 22, 1979
    Date of Patent: August 4, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Horst Fach, Hayri Ergun
  • Patent number: 4270980
    Abstract: A method for recovering and utilizing heat of coke-oven gas, which comprises: through heat exchange with a high-temperature coke-oven gas generated from a coke oven battery and containing vaporized coal tar, vaporized low boiling point substances and dust, drying and preheating a blended raw material coal fine to be charged into coking ovens of said coke oven battery, and, on the other hand, causing most of said coal tar contained in said coke-oven gas to condense and deposit onto the particle surfaces of said coal fine during the process of said heat exchange, thereby recovering and utilizing sensible heat and condensation heat of said coke-oven gas and substances contained therein, and at the same time, eliminating most of the contained coal tar from said coke-oven gas.
    Type: Grant
    Filed: May 3, 1979
    Date of Patent: June 2, 1981
    Assignee: Nippon Kokan Kabushiki Kaisha
    Inventors: Teruo Shimotsuma, Kazuo Kunioka, Hiroaki Nishio, Yasuo Okuyama
  • Patent number: 4263100
    Abstract: A method reducing fine dust emission during the time that predried and preheated coal is charged into coke ovens comprises directing wet coal to be carbonized into direct contact with a hot process gas so that the coal is transported dry and heated, directing the hot process gas with the heated coal to a plurality of different separators in succession with the first separator being set to separate only around from 80 to 90% of the total amount of the coal and without separating the fine dust, and a subsequent separator separate the remaining amount of the solid matter including the fine dust, compacting the dust removed from all of the separators and mixing them together, and charging the compacted mixed dust into the coke oven. The apparatus for effecting the invention includes a material separator which is designed as a gravity separator or gravity sifter which is arranged to discharge into a connection between the mixed and compacted dust separator in separate additional separators.
    Type: Grant
    Filed: September 20, 1979
    Date of Patent: April 21, 1981
    Assignee: Firma Carl Still GmbH & Co. KG.
    Inventors: Dieter Stalherm, Janos Bocsanczy
  • Patent number: 4251322
    Abstract: A process of treating coke oven doors and jambs with a material containing micro micron particles of graphite in a liquid carrier is described that forms a penetrating lubricating adhesive coating on the coke oven doors and jambs which acts to prevent leakage of tar and other coke by-products as heretofore common in the art and the resultant inability of maintaining a sealing relation between the doors and jambs.
    Type: Grant
    Filed: July 20, 1979
    Date of Patent: February 17, 1981
    Inventor: Michael D. La Bate
  • Patent number: 4251207
    Abstract: Coking coal is preheated and dried by passing hot carrier gas into a generally vertical flash drying pipe, then passing comminuted coal into the same pipe, the carrier gas being blown with a flow speed to move the coal upwards in the pipe and passing at about the midpoint of the pipe a mixture of hot combustion gases and additional hot recycle gas branched off from the other hot waste gas line into the pipe so as to cause further heating and moving of the coal, the further heating being carried out in a uniform and gentle manner. At the end of the pipe the coal and carrier gas are separated and the coal is recovered while the waste gas are recycled into a blower and therefrom into the vertical flash drying pipe with a branch leading part of the recycle gas into a mixing chamber with the combustion gases so as to lower the temperature of the combustion gases when the same are passed into the pipe.
    Type: Grant
    Filed: February 26, 1979
    Date of Patent: February 17, 1981
    Assignee: Bergwerksverband GmbH
    Inventors: Kurt-Gu_nther Beck, Georg Pollert, Wolfgang Rohde
  • Patent number: 4249855
    Abstract: A method for introducing particulate solids upwardly through a bottom solids inlet of a solids upflow vessel wherein after full extension of a piston to displace solids from a feed cylinder into the solids upflow vessel, the piston is partially retracted to "relax" the bed of solids in the solids upflow vessel. The bed relaxation step reduces the piston-to-solids pressure during the pumping stroke as well as substantially reducing the solids loading pressure on the device used to prevent backflow of solids from the upflow vessel during refilling of the feed cylinder.
    Type: Grant
    Filed: September 12, 1979
    Date of Patent: February 10, 1981
    Assignee: Union Oil Company of California
    Inventor: Roland O. Dhondt
  • Patent number: 4247365
    Abstract: A method of cooling and dedusting degasification gases which escape from coal degasification chambers particularly gases which are obtained in high temperature or low temperature carbonization of bituminous and subbituminous coals and which pass from degasification chambers through risers and bends into collection mains and in the bends or in the collecting mains themselves which comprises directing crude tar having a temperature in excess of 50.degree. C. and lower than 170.degree. C. into the bends and collecting mains either alone or with water added which has a temperature and is of a quantity such that it completely evaporates in the collecting main.
    Type: Grant
    Filed: December 16, 1977
    Date of Patent: January 27, 1981
    Assignee: Firma Carl Still GmbH & Co. KG
    Inventors: Heinrich Weber, Horst Dungs, Franz Beckmann, Hugo Schmauch, Karl-Heinz Flasche
  • Patent number: 4247366
    Abstract: A method of preparing and delivering coal to a coking plant, comprises, conveying the coal to the plant on a moving conveyor while an inert combustion gas is directed over the coal being conveyed. The combustion gas is generated by burning a fuel with air to produce a substantially inert combustion gas which is passed over the coal during its conveying and, thereafter, passed through a cooler for removing the moisture which has been picked up from the coal by the gas. The heating and predrying inert gases are advantageously generated by the direct combustion of air and fuel which are passed through flash dryer tubes and one or more separate separator systems and then delivered into a conveyor pipeline through which the coal is conveyed. A portion of the gases which are generated are also directed with a return gas to a filter for removal of any coal therefrom and to a cooler for removing the moisture picked up from the coal and then back into the stream for delivery to the conveyor for the coal.
    Type: Grant
    Filed: April 18, 1978
    Date of Patent: January 27, 1981
    Assignee: Firma Carl Still
    Inventors: Johannes Knappstein, Dieter Stalherm, Janos Bocsanczy
  • Patent number: 4246071
    Abstract: This invention is directed to a process for making coke and recovering the heat therefrom for preheating the firing gas to the coke oven. The process involves the use of the coke oven firing gas to extract the sensible heat from the hot coke from the coking oven to both preheat the firing gas for the coke oven and cool the hot coke. Significant economies are achieved in the two-fold function of coke production and heat recovery in accordance with the method disclosed.
    Type: Grant
    Filed: April 16, 1979
    Date of Patent: January 20, 1981
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Claus Flockenhaus, Joachim F. Meckel
  • Patent number: 4244785
    Abstract: Charging gases from each coking chamber in a battery of coke ovens are withdrawn through a closable ascension pipe into only a first gas main. The gases liberated during carbonization of the coal charge in each oven chamber are withdrawn through a closable ascension pipe into only a second gas main throughout the remainder of the carbonization process. The gases in each gas main are sprayed with flushing liquor. Gases are continuously transferred from the second gas main through pipes into the first gas main to equalize the gas pressure within the gas mains. Flushing liquor removed from the first gas main is processed to remove the tar content therefrom and to provide a clear flushing liquor which is used to spray charging gases within the first gas main.
    Type: Grant
    Filed: June 21, 1978
    Date of Patent: January 13, 1981
    Inventor: Lewis Alderman
  • Patent number: 4240877
    Abstract: A method of preheating coal for coking comprises bringing a hot operating gas into direct contact with the coal to preheat the coal. Both the coal and the operating gas are passed into a separator and the separator is operated so as to effect the separation of the coarse preheated coal for delivery to the coke oven from the operating gases and coal dust. The operating gases and coal dust are then passed into a deduster to remove the coal dust from the operating gases. A portion of the removed dust is continuously directed into an accumulator. The dust is either supplied from the deduster or the accumulator to a combustion furnace where it is burned to generate at least a portion of the operating gas.
    Type: Grant
    Filed: April 30, 1979
    Date of Patent: December 23, 1980
    Assignee: Firma Carl Still GmbH & Co. KG
    Inventors: Dieter Stahlherm, Gerhard Rutkowski, Janos Bocsanczy, Hans Becker
  • Patent number: 4235624
    Abstract: Hot coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation, to partial oxidation and cracking with an oxygen-containing gas, thereby forming a hot cracked gas rich in carbon monoxide and hydrogen. The hot coke oven gas may be subjected to a desulfurization operation prior to the partial oxidation and cracking. Alternatively, the hot cracked gas may be subjected to a desulfurization operation after the partial oxidation and cracking. When the coke ovens are part of an overall metallurgical installation which includes an air separation and dissociation plant for obtaining substantially pure oxygen, the oxygen-containing gas employed in the partial oxidation and cracking may comprise oxygen enriched gas which is taken from an intermediate stage of the air separation and dissociation plant.
    Type: Grant
    Filed: July 27, 1978
    Date of Patent: November 25, 1980
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Claus Flockenhaus, Joachim F. Meckel
  • Patent number: 4235604
    Abstract: Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO.sub.2 -containing gas, with a steam reforming catalyst.
    Type: Grant
    Filed: December 29, 1977
    Date of Patent: November 25, 1980
    Assignee: Didier Engineering GmbH
    Inventors: Dietrich Wagener, Claus Flockenhaus, Joachim F. Meckel
  • Patent number: 4233137
    Abstract: A method for recovering sensible heat from a thermally decomposed high temperature hydrocarbon gas product in the form of high pressure steam of from 40 to 100 kg/cm.sup.2 has been discovered. This method comprises pre-cooling at first the thermally decomposed gas product of high temperature by mixing said gas product with sprayed low temperature hydrocarbon oil as a quenching oil to a temperature of about 300.degree. to 400.degree. C.; and then passing the mixture through the tubes of a shell-and-tube type heat exchanger so as to transfer the heat of said resulting mixture into a high pressure water flowing through the space of the shell side thereof to recover a high pressure steam, followed by separating the condensed hydrocarbon oil from the mixture to reuse said oil by recirculation.
    Type: Grant
    Filed: March 30, 1979
    Date of Patent: November 11, 1980
    Assignees: Chiyoda Chemical Engineering & Construction Co., Ltd., Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kiyoji Ozaki, Akinobu Fukuhara, Takuji Hosoi, Yasuo Sagi
  • Patent number: 4231845
    Abstract: Injection of steam into the ascension pipe of each coking chamber in a coking plant is continued for a period of time after charging of that chamber so as to create a slightly sub-atmospheric pressure in the chamber during the initial stage of the coking process, in order to reduce leakage of gas and fumes to the atmosphere past the doors and filling openings. A time clock operated by the coke pusher machine or by the coal charging machine stops this injection of steam after a desired period of time.
    Type: Grant
    Filed: June 18, 1979
    Date of Patent: November 4, 1980
    Assignee: Hoogovens Ijmuiden, B.V.
    Inventors: Timen Vander, Nicolaas J. Thijssen, Jan F. de Blok, Jan Middel
  • Patent number: 4230528
    Abstract: Prior to starting up a plant in which fine coke is produced by mixing high bituminous lignite coal with circulating hot fine coke serving as a heat carrier in the plant, hot inert gas is admitted into the mixing unit in which the coal and coke are admixed. Only after all parts of the plant are thus preheated, the operation of the plant is started up.
    Type: Grant
    Filed: September 1, 1978
    Date of Patent: October 28, 1980
    Assignee: Bergwerksverband GmbH
    Inventor: H. J. Jagnow
  • Patent number: 4224109
    Abstract: The waste heat resulting from a coke oven operation is recovered in a two-stage proceeding. The waste gas is first cooled to not more than about 400.degree. C. in a recuperator or regenerator of the oven to principally utilize the heat radiation of the gas. Then, in a second stage, the gas is subjected to further cooling in a separate heat exchanger to principally exploit the heat convection of the gas. The process permits to recover waste gas on both basic principles of waste recovery, that is the recovery by radiation and the recovery by convection.
    Type: Grant
    Filed: July 24, 1978
    Date of Patent: September 23, 1980
    Assignees: Bergwerksverband GmbH, Didier Engineering GmbH
    Inventor: Claus Flockenhaus
  • Patent number: 4222824
    Abstract: A recuperative coke oven includes at least one recuperator chamber arranged below an oven chamber. Hot undergrate firing exhaust gas is passed from the oven through the recuperator chamber. At least one elongated recuperator extends into the recuperator chamber. The recuperator includes an inner tube and a coaxially outer tube. The inner end of the inner tube is open, and the inner end of the outer tube is closed to define an annular chamber between the two tubes. Combustion air to be heated is introduced into the inner tube and passed therethrough. The combustion air then reverses direction and passes through the annular chamber and is thereat heated by the hot exhaust gas passing through the recuperator chamber. The heated combustion air is discharged from the annular chamber and passed to the heating flues of the oven.
    Type: Grant
    Filed: February 22, 1979
    Date of Patent: September 16, 1980
    Assignees: Didier Engineering GmbH, Bergwerksverband GmbH
    Inventors: Claus Flockenhaus, Edgar Hartkopf
  • Patent number: 4213489
    Abstract: A one-spot coke quench car is provided with a coke pile dispersement means to evenly distribute the coke within the car to permit additional coke to be accommodated and as an aid in more uniform quenching. The car has a sloping conduit therein and an exterior water metering valve that is fluidly connected to a pressurized tank of water mounted on the quench car frame. A small quantity (about two gallons) of water is pressurized in the water metering valve which can be opened to allow the small quantity of water to flow immediately and almost instantaneously through the sloping conduit and into the pile of incandescent coke. The water suddenly flashes, explosively, into a large volume of steam, expanding rapidly to disperse the coke within the quench car so that it is more nearly level therein.
    Type: Grant
    Filed: January 10, 1979
    Date of Patent: July 22, 1980
    Assignee: Koppers Company, Inc.
    Inventor: George R. Cain
  • Patent number: 4211608
    Abstract: A process for controlling emissions resulting from hot coke being discharged from an oven of a battery of coke ovens from the beginning of discharge until the time when the coke arrives at a quenching station. The coke from the oven passes through a coke guide and a fume hood into an open-top, one-spot quenching car. The hood covers the car during discharge and is connected to an exhaust system, including a gas cleaning device, which draws air into the hood in an amount sufficient to control emissions and for combustion of the volatile matter and other combustibles emitted from the coke during the time coke is discharged into the quenching car and for a short period of time thereafter. During the movement of the open-top, one-spot quenching car from under the hood to the quenching station, the visible emissions given off by the hot coke are less than 40% opacity.
    Type: Grant
    Filed: October 19, 1978
    Date of Patent: July 8, 1980
    Assignee: Bethlehem Steel Corporation
    Inventors: Daniel Kwasnoski, Carl R. Symons
  • Patent number: 4207145
    Abstract: A jumper pipe forms a passageway between the free spaces above coal charges in adjacent coking chambers for the natural flow of relatively cooler coke oven gas from the free space above the coal charge in the most recently charged one of the coking chambers into the free space above the coal charge in the other of the coking chambers to reduce the relatively higher temperature therein. An inert atmosphere is maintained along at least part of the passageway to prevent the flow of coke oven gas essentially during decarburization and the pushing of coke from either of the two adjacent coking chambers. Valve members at opposite end portions of the jumper pipe are moved to at least partially-closed positions to facilitate the maintenance of an inert atmosphere therein. A supply or steam or gaseous nitrogen is used to maintain the inert atmosphere in the jumper pipe. The inert gas prevents the entrance of coke oven gas into a coking chamber while undergoing decarburization.
    Type: Grant
    Filed: July 27, 1978
    Date of Patent: June 10, 1980
    Assignee: Jones & Laughlin Steel Corporation
    Inventors: Harry D. Hatters, Joseph M. Stoll
  • Patent number: 4203803
    Abstract: Method for charging a coke oven chamber. Where the chamber is charged through a single charging hole with a stream of flowable preheated particulate coal at a flow rate of between substantially 8-20 tons per minute. The coal flows sufficiently in the chamber to assure filling of the chamber to substantially 100% of the volumetric capacity of the same. Due to the flowability of the preheated coal the charge is self-leveling.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: May 20, 1980
    Assignees: Bergwerksverband GmbH, Didier Engineering GmbH
    Inventors: Joachim F. Meckel, Wolfgang Rohde, Werner Siebert, Dietrich Wagener, Claus Flockenhaus, Manfred Galow
  • Patent number: 4202735
    Abstract: In a coking operation where the heating medium is introduced into the furnace by way of a bottom fire box and wherein heat exchangers are provided for the waste gases, the waste gas is passed through a plurality of parallel channels serving as said heat exchangers and the useful portion of the total system available for such exchange is reduced when the coking time is increased beyond the time required at normal operation.
    Type: Grant
    Filed: April 10, 1978
    Date of Patent: May 13, 1980
    Assignee: Krupp-Koppers GmbH
    Inventors: Heinz Durselen, Franz-Josef Onnebrink, Arnulf Schuffler
  • Patent number: 4202733
    Abstract: Coal is preheated prior to passing it into a coking installation by feeding measured amounts of the relatively wet coal into and through one or more circulation dryers heated to an elevated temperature and collecting the hot coal in a collecting bin and automatically measuring the level of the hot coal in said bin and automatically adjusting the amount of coal fed into said dryer depending on the level of coal measured in said collecting bin. Means are provided for preventing further adjustment of the coal feed rate should the exhaust gas temperature of a dryer fall outside the limits of a preselected preset temperature range and to bring the process back under level-actuated feed rate control once the exhaust gas temperature moves back within the preset range.
    Type: Grant
    Filed: November 7, 1978
    Date of Patent: May 13, 1980
    Assignees: Bergwerksverband GmbH, Didier Engineering GmbH
    Inventors: Willy Luke, Gunter Gabriel
  • Patent number: 4201627
    Abstract: A process for quenching hot coke discharged from an oven of a battery of coke ovens into a one-spot car. The process utilizes a unique arrangement of two sets of narrow angle spray nozzles to quench the coke. In addition to quenching the coke, one set of spray nozzles initially knocks down the peak portion of the coke pile and distributes the coke so that the exposed surface of the coke is substantially level. The quench liquid discharged through the narrow angle spray nozzles contacts about 50% to about 70% of the substantially level, exposed surface of the hot coke. Sufficient openings are provided adjacent the bottom of the one-spot car to drain the quench liquid to prevent the buildup of quench liquid in the quench car.
    Type: Grant
    Filed: March 15, 1979
    Date of Patent: May 6, 1980
    Assignee: Bethlehem Steel Corporation
    Inventors: David M. Chuss, James W. Scheirer
  • Patent number: 4189457
    Abstract: A method for sealing a by-product coke oven in which a silicone material is caused to foam to form a foaming silicone composition preferably by mixing a first mixture of organohydrogensiloxane and hydroxylated organosiloxane with a second mixture of organohydrogensiloxane most desirably with a platinum catalyst, and heating the mixture to provide a volumetrically expandable foam. The volumetrically expandable foam is sprayed around the periphery of coke oven doors, slip-joints and similar points of gaseous emissions where it undergoes a foaming acting in the presence of the heat of the oven such that the foam volumetrically expands to provide a seal that prevents the emission of gas, dust, and smoke during the coking cycle.
    Type: Grant
    Filed: November 24, 1978
    Date of Patent: February 19, 1980
    Assignee: H. L. Clement Company
    Inventor: Henry L. Clement, Jr.
  • Patent number: 4181507
    Abstract: A process is disclosed for the treatment of the residual gases which are produced when hydrogen sulfide is reduced, by combustion, to elementary sulfur by the Claus process. The residual gases are fed through a heated conduit and gas scrubber, wherein the temperature of those residual gases are maintained above the melting point of sulfur. A portion of the raw coke oven gas condensate is admitted to the gas scrubber to be returned to the coke oven battery main from the flushing liquid separator as flushing liquor. The residual gases are then conducted through the coke oven gas purification process equipment along with the raw coke oven gas where the residual gases are intermixed with the raw coke oven gas prior to tar separation.
    Type: Grant
    Filed: January 12, 1979
    Date of Patent: January 1, 1980
    Assignee: Koppers Company, Inc.
    Inventor: Kurt Nolden
  • Patent number: 4178215
    Abstract: A method of manufacturing blast furnace coke wherein said coke is obtained by a process in which coal to be used for making briquettes is mixed with a caking substance having a softening point of 40.degree.-250.degree. C. with or without a solvent having fluidity at the mixing temperature and dissolvable to said caking substance, the resultant mixture being mixed by means of a powerful mixer capable of applying mixing energy of 0.01KW/Kg or more at a temperature of 40.degree.-250.degree. C. for 1-10 minutes, while a heating medium such as steam is passed therethrough and is then subjected to briquetting with a roll press. The briquette obtained is either carbonized directly or after blending with coal ready for coke oven charging.
    Type: Grant
    Filed: September 29, 1976
    Date of Patent: December 11, 1979
    Assignees: Sumitomo Metal Industries Limited, Sumikin Coke Company Limited
    Inventors: Yoshio Kiritani, Michio Tsuyuguchi, Tetsuo Ibaragi, Katsuhiro Yano, Yoshihiko Sunami, Kunihiko Nishioka
  • Patent number: 4178266
    Abstract: As hot crude coke oven gas is conveyed from coke ovens to a position of utilization, condensation of higher hydrocarbons from the coke oven gas is prevented by increasing the temperature of the coke oven gas to a temperature such that higher hydrocarbons are prevented from condensing therefrom. This increase in temperature may be achieved by injecting oxygen-containing gas into the hot crude coke oven gas, to thereby produce a partial combustion of the coke oven gas. Alternatively, when the coke oven gas is being conveyed to a thermal cracking reactor wherein the coke oven gas is thermally cracked to form a cracked gas, the temperature of the coke oven gas may be increased by passing the coke oven gas through a heat exchanger in indirect heat exchange relation with the cracked gas.
    Type: Grant
    Filed: December 29, 1977
    Date of Patent: December 11, 1979
    Assignee: Didier Engineering GmbH
    Inventors: Rudolf Burkert, Claus Flockenhaus, Joachim F. Meckel, Dietrich Wagener
  • Patent number: 4176011
    Abstract: Method of operating a coke oven battery arranged in a battery in connection with a predrying or preheating plant for the coal to be coked comprises predrying and preheating coke oven charge moist coal by bringing it into contact with a circulated current of hot inert gas to remove water from the charge with the inert gas comprising a gas containing only a small amount of oxygen and a remainder comprising nitrogen, carbon dioxide and steam, charging the preheated and predried coal into a coke oven, directing the coke oven gases generated in the oven out through an offtake, and adding an amount of steam corresponding approximately to the amount of water removed from the charge coal during the predrying and preheating to the coke oven gases in the gas offtake. The apparatus includes a closed circuit in which steam is added to a line and then superheated by a heater and is directed into a secondary flash heater.
    Type: Grant
    Filed: October 14, 1977
    Date of Patent: November 27, 1979
    Assignee: Firma Carl Still
    Inventor: Johannes Knappstein
  • Patent number: 4162944
    Abstract: A method and apparatus for spotting a pusher machine or other door-handling machine in relation to a coke oven. The method and apparatus are particularly useful for aligning a door extractor carrying a door with an open hot oven, but also may be used to align a pusher ram. The apparatus includes left and right heat or light sensitive detectors at opposite sides of the part to be aligned with the oven and aimed at oblique angles toward the extended center line of the part. When both detectors are actuated simultaneously, the part is aligned accurately with the oven.
    Type: Grant
    Filed: November 11, 1977
    Date of Patent: July 31, 1979
    Assignee: United States Steel Corporation
    Inventor: John A. Belcher
  • Patent number: 4157940
    Abstract: A method for operating a battery of horizontal coke ovens which are connected to primary and secondary gas-collecting mains extending alongside the battery, wherein dust-laden gas which occurs during charging of an oven is caused to flow through the secondary main while the velocity of the gas in the secondary main is maintained at a level which will prevent settling of the dust and the temperature within the secondary main is maintained at a level which will prevent condensation of tars.
    Type: Grant
    Filed: January 27, 1978
    Date of Patent: June 12, 1979
    Assignee: Dr. C. Otto & Comp. G.m.b.H.
    Inventor: Lewis A. Watson
  • Patent number: 4146435
    Abstract: An improved dust collecting system for a coke oven employs a bag filter dust collector as a common dust collector for both the coke discharge operation and the coal charging operation. First, the dust spouted out in the coke discharge operation and then successively and alternatingly, the dust spouted out in the coal charging operation and in the coke discharge operation are collected, whereby fine coal particles deposited out in the coal charging step are deposited on the layer of the fine coke particles firstly deposited out in the coke discharging operation. In addition, a combustion chamber is provided for burning the gases and dusts spouted off in the coal charging operation and a pre-dust wet-type collector is utilized therein for preliminary filtering before the same is fed to the common bag filter dust collector.
    Type: Grant
    Filed: April 18, 1977
    Date of Patent: March 27, 1979
    Assignees: Mitsubishi Chemical Industries, Ltd., Kansai Netsukagaku Kabushiki Kaisha
    Inventors: Hajime Ueno, Kentaro Kakumura, Nobukastu Sasaki, Yorito Sato
  • Patent number: 4141797
    Abstract: The operation of a battery of coke ovens with regenerative change of draught on heating flues includes adjustably controlling the combustion of gases in the heating flues to insure uniform vertical heating of the coking coal in the coke oven chambers. Control elements for the operation of discrete heating flues in each heating wall are adjusted to insure uniform heating of the coking coal along the length of the heating walls. A gas supply rate is selected for the delivery of gas into the heating flues to define a carbonizing time corresponding to a high output capacity of coke from the coke oven battery. The heat consumption by the coking coal in the coke oven chambers is reduced during each regenerative half period by interruptions to the supply of gas at the gas supply rate without modifying or adjusting the control elements employed to insure uniform heat distribution in the heating flues.
    Type: Grant
    Filed: December 9, 1976
    Date of Patent: February 27, 1979
    Assignee: Dr. C. Otto & Comp. G.m.b.H
    Inventors: Erich Pries, Folkard Wackerbarth
  • Patent number: 4139419
    Abstract: Coal not normally used for coking is, prior to feeding to coking batteries, processed in a vertical suspension preheater heated by combustion gases from the coking batteries; the coal particles are separated from these combustion gases in two alternately operating sets of primary and secondary cyclone separators and are then supplied to coking batteries together with part of the combustion gases which serve as carrier gases for the coal particles.
    Type: Grant
    Filed: January 21, 1977
    Date of Patent: February 13, 1979
    Assignee: Hutni projekt Praha, projekcni a inzenyrska organizace
    Inventor: Jaroslav Limberg
  • Patent number: 4139451
    Abstract: A method for dewatering tar-water mixtures obtained from the coking of coal is disclosed. The method involves adding to the tar from 150 to 3,000 ppm of a di-tri butyl ethoxylated phenol compound dissolved in water, heating the tar-water mixture, and then agitating it to allow contact with the chemical additive. This is followed by allowing the mixture to settle forming an aqueous upper phase and a lower dewatering tar phase.
    Type: Grant
    Filed: December 12, 1977
    Date of Patent: February 13, 1979
    Assignee: Nalco Chemical Company
    Inventors: Audrone M. Pavilcius, William H. Lindenberger
  • Patent number: 4123331
    Abstract: Method of keeping sprinkling water used for sprinkling in the uptakes of coke ovens in a clean condition, comprises directing the sprinkling water condensate which is collected after circulation in the uptakes, and which includes tar, tar oils, hydrocarbons and ammonia, into a separator to separate a clean sprinkling liquid therefrom, and returning this liquid to the flue and also directing a tar which is free of solids into the flue with the sprinkling liquid, at least during an initial period of operation of the coking oven.
    Type: Grant
    Filed: December 23, 1976
    Date of Patent: October 31, 1978
    Assignee: Firma Carl Still Recklinghausen
    Inventor: Dieter Laufhutte
  • Patent number: 4119525
    Abstract: A low-impurity coke suitable for the production of electrodes for aluminium manufacture is prepared by extracting coal volatile matter content greater than about 28% by weight on a dry ash free basis with a highly aromatic hydrocarbon extractant of which the middle 90% boils in the range 250.degree. to 350.degree. C at a temperature of about 380.degree. to 450.degree. C, in the liquid phase, insoluble matter is separated off and the extract is heated to remove distillable oil and coked wherein the residence time of coal in the extraction step is controlled and the weight ratio of extractant to coal during extraction is maintained greater than 3:1 to maintain a substantially constant specific resistivity of the filter cake.
    Type: Grant
    Filed: May 21, 1976
    Date of Patent: October 10, 1978
    Assignee: Coal Industry (Patents) Limited
    Inventors: Michael David Gray, Geoffrey Michael Kimber
  • Patent number: 4118282
    Abstract: A process and apparatus for the destructive distillation of high molecular weight organic materials such as organic wastes, particularly those containing hydrocarbon groups, using ultrasonic and microwave generators together to irradiate, and molecularly disperse the organic molecules in the organic materials. At least initially a portion of the organic materials are preferably irradiated with a laser beam or other initiator to initiate molecular motion in the organic materials and produce elemental carbon in situ from the organic materials so that the process will begin rapidly. Carbon and/or particulate catalysts which promote or increase the absorption of microwaves are preferably admixed with the organic materials.
    Type: Grant
    Filed: August 15, 1977
    Date of Patent: October 3, 1978
    Assignee: Wallace Energy Conversion, Inc.
    Inventor: Floyd D. Wallace
  • Patent number: 4116779
    Abstract: A vertical vessel, having a low bed of broken material, having included combustible material, is initially ignited by a plurality of ignitors spaced over the surface of the bed, by adding fresh, broken material onto the bed to buildup the bed to its operating depth and then passing a combustible mixture of gas upwardly through the material, at a rate to prevent back-firing of the gas, while air and recycled gas is passed through the bed to thereby heat the material and commence the desired laterally uniform combustion in the bed. The procedure permits precise control of the air and gaseous fuel mixtures and material rates, and permits the use of the process equipment designed for continuous operation of the vessel.
    Type: Grant
    Filed: March 23, 1977
    Date of Patent: September 26, 1978
    Assignee: Paraho Corporation
    Inventor: Harry A. Harris
  • Patent number: 4111756
    Abstract: After replacement of the walls of one chamber of a coking battery this one chamber is heated up by withdrawing relatively hot air from another still-hot chamber of the coking battery and injecting it into the cold chamber. This is done by means of a conduit extending between the two chambers and provided with an internal nozzle that conducts the hot gas from the hot chamber to the cool chamber by jet-pump action. This hot gas is mixed with relatively cool air so as slowly to heat the cool chamber up.
    Type: Grant
    Filed: November 12, 1976
    Date of Patent: September 5, 1978
    Assignee: Krupp-Koppers GmbH
    Inventors: Gunther Lagemann, Wilhelm Heisterkamp
  • Patent number: 4110168
    Abstract: A process for the facile isolation of distillation by-products of coking operations, which include dusts and tars, comprising cooling said distillation by-products with ammoniacal waters and adjusting the dust:tar ratio between 1.3 and 1.6, thereby allowing separation of substantially clarified ammoniacal waters and a substantially solid product of said tars and dusts.
    Type: Grant
    Filed: December 29, 1976
    Date of Patent: August 29, 1978
    Assignee: Houilleres du Bassin de Lorraine
    Inventor: Henri Brice
  • Patent number: 4104128
    Abstract: The specification discloses apparatus and methods for recovery of coal fines and for recycling thereof incidental to a self-contained system for charging preheated coal into coke ovens. The apparatus enables a system for charging preheated coal into coke ovens to meet pollution control regulations. The apparatus comprises four circulating streams of liquid for carrying coal fines in a slurry, namely, the charge main liquor circuit, the excess recycle gas scrubber circuit, the charge line condenser circuit and the charge bin vent condenser circuit. The -28 mesh coal with the liquor from the various circuits goes to a clarifier or thickener. Floating fines from top and settled fines from the bottom of the thickener are pumped via a fines tank to filters from which the solid or coagulated fines are restored to the wet coal feed to the heaters.
    Type: Grant
    Filed: July 21, 1976
    Date of Patent: August 1, 1978
    Assignee: Wilputte Corporation
    Inventors: Paul V. Faber, Edwin R. Daly, Prithvi Jain
  • Patent number: 4100031
    Abstract: A process for preparing blast furnace cokes which contain large amounts of low-grade coal which comprises the steps of adding a binder to a coal for making briquettes which comprises a substantially low-grade coal such as non- and/or poorly-coking coal; either alone or when blended in an amount of up to about 40% or more with a charging coal; mixing the binder and the coal briquetting the mixture in a roll press to form briquettes of two or more types; blending the resulting briquettes of different types with a charging coal in a total amount of about 35% or more of the briquettes based on the charging coal and, to prepare a blended charging coal; and carbonizing the blended charging coal in a coke oven.
    Type: Grant
    Filed: January 4, 1977
    Date of Patent: July 11, 1978
    Assignee: Sumikin Coke Company Limited
    Inventors: Yoshio Kiritani, Michio Tsuyuguchi
  • Patent number: 4090945
    Abstract: Continuously determining the bulk density of raw and retorted oil shale, the specific gravity of the raw oil shale and the richness of the raw oil shale provides accurate means to control process variables of the retorting of oil shale, predicting oil production, determining mining strategy, and aids in controlling shale placement in the kiln for the retorting.
    Type: Grant
    Filed: March 25, 1977
    Date of Patent: May 23, 1978
    Assignee: Paraho Corporation
    Inventor: Adam A. Reeves
  • Patent number: 4086143
    Abstract: In a coking process wherein coal is subjected to coking in chamber furnaces by means of combustion of a fuel gas in the heat flues of the furnace and transfer of the generated heat through the walls of the furnace, the heat supply is effected, during the entire course of the coking operation, according to a preestablished programmed control scheme related to a uniform or mean rate of heat supply, the supply of heat being at a maximum at the commencement of the coking operation and being gradually reduced during the continuing coking operation.
    Type: Grant
    Filed: July 22, 1976
    Date of Patent: April 25, 1978
    Assignee: Bergwerksverband GmbH
    Inventors: Heinrich Echterhoff, Wolfgang Simonis, Wolfgang Rohde, Kurt-Gunther Beck