Abstract: Disclosed is a method and apparatus for alternatively feeding liquid to be distributed in a chemical process tower through a plurality of liquid distributors positioned at the same level within the tower. Very low flowrates with very uniform liquid distribution is achieved with this invention.

Abstract: Vapor and liquid contact structure for distillation, fractionation, rectification, absorption, and the refining, in a column, of various liquid materials such as petroleum, chemical, and alcohol solutions. Provision is made for the inclusion of vertically-spaced bubble plate chambers, having respective liquid/vapor contact devices, to accommodate contact of counter-current flows of reflux liquid and vapors. Downcomer means including slanted ramps, disposed outside of the vapor conduit-defining interior, define elongate downcomer structure for liquid flow and thereby, i.e., by such slanted construction, reduce froth or foam passing to a next lower contact device, eliminating unwanted counter-current gas entrainment between contact devices. Liquid flow rates over exit weirs beyond 30 gpm/inch are obtained. Downcomer reflux reservoir depth can be adjusted by an adjustable gate proximate the slot opening to a given contact device.

Abstract: A distillation tray of the sieve type with a chordal weir or outlet has vapor passages therethrough. The density of vapor passages in the main liquid flow area immediately between the liquid inlet and the liquid outlet of the tray is higher than in the remaining area of the tray so that more vapor flow will be directed into the more active main liquid flow area of the tray, whereby the vapor leaving the tray from the main liquid flow area has substantially the same composition as the vapor leaving the tray from the other area.

Abstract: A support device for supporting a packing material in a packed column having an upwardly flowing gas and a downwardly flowing liquid. The device comprises a plate having a plurality of formations. Each formation comprises spaced side walls connected by an upper wall, with apertures being provided in the side walls to permit the flow of the gas therethrough. A collecting channel is provided on at least one of the formations to collect the downwardly flowing liquid. The formations have a plural-skin construction to reduce the amount of liquid flowing through the apertures. The formations are provided with streamlining in order to improve the efficiency of gas flow.

Abstract: A stripping column is comprised of one or more mixing channels situated in parallel arrangement, each channel in the form of a zigzag strip through which liquid cascades in a series of falls alternating with a corresponding series of pools. Simultaneously, vapor travels upwardly in a counter-current manner, intimately mixing with the liquid when forced through each successive pool. The column is especially useful in separating alcohol from fermented mash. The column is preferably employed with three other identical columns in a parallelogram structure to make a distillation unit of greater efficiency and capacity.

Abstract: The present invention is a distillation vapor and feed mixing and subsequent separation process and apparatus involving the introduction of a vaporizing liquid feed into a flash zone via a tangential nozzle into a mixing and separation chamber which directs the feed into a circumferential path to enhance mixing, and the redirection of rising vapors from the distillation below the flash zone by baffling these vapors into the chamber inlet. The rising vapors are inspirated by the high velocity feed at the inlet side of the chamber and intimate contact and mixing of the rising vapors with the vaporizing feed are enhanced by creating a spinning action. Preferably, the chamber runs peripherally and slightly downward along the inside wall of the distillation column along an arc no greater than 360.degree.. Alternatively, the mixing section of the mixing and separation chamber may be located outside of the distillation tower and the feed, passing through a jet ejector would inspirate the rising vapors.

Abstract: Process and apparatus for the preliminary determination of the efficiency of the trays of distillation and/or absorption columns in order to establish the actual tray number of the columns, as well as for those columns the tray number of which was determined thereby. Each column section of different geometry or load is loaded with a set of trays (12) with air water system consisting at least of two trays having identical geometry (13,13a) and one air distributor (14). On the basis of the recognition that each set of trays (12) may be regarded as a cascade consisting of mixers which include series-connected mixers formed from the trays (13,13a), the liquid content of which is mixed by ascending vapor, or gas, in this case by air.

Abstract: An improved method and apparatus for de-entraining liquid droplets from a vaporous stream as it leaves a flash zone of a separation tower. The removal of the droplets is accomplished by a chimney which directs vapor flow through two direction changes of about 180.degree. each. The chimney comprises a riser and hat which have an annulus between them. The cross-sectional area of the annulus is less than that of the cross-sectional area of the riser, so the momentum imparted to the entrained droplets drives them downwardly while the lighter vapor undergoes the second direction change and continues upwardly. The chimney may further reduce entrainment by having an extended portion of the riser below a plate and a lip attached to the inside perimeter of an opening of the riser above the tray. Preferably a lower portion of the riser has a larger cross-sectional area than an upper portion of the riser.

Abstract: Dual interrelated distillation columns are disclosed wherein the heat for a first column is transferred by thermal conduction through a common wall or surface to a second column to increase efficiency and decrease waste of energy. In one embodiment, the first heat generating column is a cylindrical column, and the second column is an annular column concentric to the first column. This concentric arrangement permits the heat generated in the first column to flow outwardly into the second column, thereby improving its efficiency and reducing the heat loss. Typically, the inner first column is a high pressure rectifying column, and the outer concentric column is a stripping column. In an alternate embodiment, the inner column can simply be a portion of a high pressure distillation process, and the outer column is a portion of a lower pressure distillation column.

Abstract: A packing element for use in an exchange column is provided. The packing element is of the type consisting of a plurality of corrugated plates placed adjacent to one another, with the corrugations of adjacent plates forming a criss-cross pattern. A plurality of regular linear arrays of "W"-shaped openings, alternating with linear arrays of "V"-shaped openings are formed in each plate. The locations of these openings or notches with respect to the corrugations are so arranged as to create liquid drip points and flow paths on the individual plates that improve the mixing and mass transfer characteristics of the packing element.

Abstract: A distillation or absorption column tray whose characteristic frequency is a specific function of the radius of circular apertures in its bottom wall, of the surface tension of the body of liquid therein at the operating temperature of the column and of the density of such liquid. This reduces the amplitude of vibrations of the tray under the action of ascending vapors and/or gases and hence increases the useful life of the tray.

Abstract: Method and apparatus for distilling a liquid mixture to separate a volatile vapor fraction therefrom. The liquid is forced to flow along a meander-like path through a plurality of concentrically arranged chambers of a rotating drum. In the radially outermost chamber, a heating unit is provided which brings the liquid to a boiling temperature to allow formation of vapor. The liquid thus freed of volatile constituents is then discharged from the outermost chamber in which the liquid is subjected to a maximum centrifugal acceleration while the vapor moves radially inwardly under the action of the centripetal force to the innermost chamber from where the vapor containing volatile constituents is discharged.

Abstract: A stripping column is comprised of one or more mixing channels situated in parallel arrangement, each channel in the form of a zigzag strip through which liquid cascades in a series of falls alternating with a corresponding series of pools. Simultaneously, vapor travels upwardly in a counter-current manner, intimately mixing with the liquid when forced through each successive pool. The column is especially useful in separating alcohol from fermented mash. The column is preferably employed with three other identical columns in a parallelogram structure to make a distillation unit of greater efficiency and capacity.

Abstract: An apparatus and method are provided for the fractional distillation of liquids in a fractionation column wherein cool liquids from the bottom tray of the column are effectively prevented from passing out directly with bottoms product before first passing through a reboiler. The column is of the type which includes a hollow shell having a surge baffle plate which divides a bottom portion of the shell interior into a first region and a second region. A separation baffle plate is provided which extends into the first region. At least one seal pan whose bottom is closely adjacent to the upper edge of the separation baffle receives liquids flowing from the bottom tray by means of a downcomer.

Abstract: A method of distillation employing a heat pump (which may be driven by a compressor) using a vapor stream from within the distillation system as a heat source and a liquid stream from within the distillation system as a heat sink. The selection of heat-source vapors and heat-sink liquid is such that at least one is withdrawm from the phase-contacting region of the distillation system. The return of streams withdrawm from the phase-contacting region of the distillation system to the distillation system is such that at least one of the streams is returned at a temperature different from that of the point from which it was withdrawn, and all withdrawn streams are returned in manner such that a stream removed as vapor is returned at a point with a temperature at most that at the point it was withdrawn, and a stream removed as liquid is returned at a point with a temperature at least that at which it was withdrawn.

Abstract: Gas/liquid contacting apparatus comprising a normally substantially vertically extending column enclosing a plurality of substantially horizontal gas/liquid guiding units vertically spaced apart from one another and extending over substantially the cross section of the column. Each gas/liquid guiding unit comprising a plurality of alternating upwardly converging gas passages and downwardly converging liquid passages, the gas passages and the liquid passages alternating in vertical direction. The liquid passages have open upper ends, and are provided with bottomwalls and with liquid discharge openings at or near said bottomwalls. Each upwardly converging gas passage is provided with an open lower end and terminates at its upper end in a plurality of substantially horizontal, parallel walls having a length increasing in downward direction and forming a plurality of substantially horizontal, constricted gas outlets.

Abstract: A method and apparatus for separating at least one component of a mixture from another without the aid of gravity comprises, in one embodiment, a heat pipe structure having an inlet and spaced outlets, a wick element disposed within the heat pipe for inducing a capillary flow of condensed phase mixture in liquid form therealong and spaced heating and cooling elements for creating zones of higher and lower temperature, respectively, within the heat pipe structure. In an alternate embodiment, a sorbent column is provided having an inlet and spaced outlets, a sorbent material disposed along the inner wall of the column for inducing a flow of adsorbed mixture therealong and spaced heating and cooling elements for creating zones of higher and lower temperature.

Abstract: Dual interrelated distillation columns are disclosed wherein the heat from a first column is transferred by thermal conduction through a common wall or surface to a second column to increase efficiency and decrease waste of energy. In one embodiment, the first heat generating column is a cylindrical column, and the second column is an annular column concentric to the first column. This concentric arrangement permits the heat generated in the first column to flow outwardly into the second column, thereby improving its efficiency and reducing the heat loss. Typically, the inner first column is a high pressure rectifying column, and the outer concentric column is a stripping column. In an alternate embodiment, the inner column can simply be a portion of a high pressure distillation process, and the outer column is a portion of a lower pressure distillation column.

Abstract: A hydrotreating reactor having a plurality of vertically spaced contacting stages having frusto-conical baffles for back-mixing hydrocarbon oil being treated and a plurality of clear oil outlets in fluid communication with a corresponding plurality of annular stilling chambers.

Abstract: Metal vapor-liquid contact plates disposed in face-to-face contact with respective corrugations inclined to the horizontal across an open notional plane. The metal packing is disposed within a vapor-liquid contact column for the purpose of bringing about mass and heat transfer between liquid and vapor passing in opposite directions therethrough. The body portion of each metal plate comprises metal that has been slitted to provide both surfaces thereof with a very large number of apertures with little wasted material. The metal lands defining the apertures are, moreover, twisted and angulated. The apertures in the plates also trap liquid and expose it to the vapor stream on both sides of the metal affording self-spreading of the liquid and turbulent vapor flow therethrough. In this manner, the assembly affords optimal pressure drop characteristics, surface to vapor passage area ratio, and vapor-liquid distribution characteristics.

Abstract: In a tray-type gas-liquid contactor, such as a distillation, rectification, or absorption column, in which mass transfer is effected between gas and liquid through a gas-liquid contact, the height of both wing parts of a weir provided along the periphery of the tray is made not less than 1.2 times that of the central part so that, when the contactor is installed, for example, on a floating offshore structure, the performance of the apparatus is not adversely affected by an inclination or oscillating motion.

Abstract: A distillation method and apparatus which comprises (a) a distillation zone adapted for the countercurrent contact of liquid and vapor, (b) a reboiler feed liquid compartment (c) means for directing distillation zone liquid into the reboiler liquid feed compartment, (d) a thermosyphon reboiler for partial vaporization of liquid thereto to produce reboiled vapor and liquid flows, (e) a conduit for the flow of liquid from the reboiler liquid feed compartment to the reboiler, (f) a reboiler return liquid compartment, (g) a conduit for the flow of reboiled liquid from the reboiler to the reboiler return compartment, (h) a conduit for the flow of reboiled vapor from the reboiler to the distillation zone, (i) means for communication of liquid by gravity flow between the reboiler feed compartment and the reboiler return compartment to provide substantially equal liquid levels in the two reservoirs, (j) a distillation zone liquid product compartment, (k) means for overflow of liquid from the reboiler return compartme

Abstract: A packing unit having a set of deflectors within a cage for deflecting each of two fluids moving through the unit, the deflectors being arranged so that in any image of the unit formed by parallel rays projected onto a plane, regardless of how the unit is oriented with respect to the plane, at least half of the area enclosed by the perimeter of the image will be a shaded area, no more than 35% of the shaded area being produced by surfaces of said deflectors oriented at more than 60.degree. to said rays.

Abstract: Process tower vapor-liquid contact method and apparatus comprising stacks of corrugated contact plates having perforated lamella disposed therebetween. The corrugated plates are disposed in face-to-face contact with respective corrugations inclined to the horizontal and separated one from the other by a perforated sheet. The assembly affords optimal pressure drop characteristics, surficial area, vapor passage area, and vapor-liquid distribution characteristics with maximum efficiency. The sandwiched plate separating adjacent corrugated contact plates greatly increases the mass and heat transfer between the liquid and vapor phases passing thereacross by effectively segregating opposed corrugated channels and establishing a plurality of vapor-liquid contact areas positioned for engaging both vapor and liquid flow in opposed directions through the oppositely inclined corrugations of adjacent plates.

Abstract: An apparatus comprised of a mass transfer microchannel plate (MCP) struct distillation column in a columnar configuration within an air tight cylindrical housing. The apparatus may be used in separation of organic chemicals like petrochemicals, vegetable oils, inorganic chemicals like steam stripping of bromine from aqueous potassium chloride/potassium bromide solutions, corrosive as well as separation of hazardous gases.The MCP structures may have an electric field or electromagnetic field across the MCP to create synergestic mass transfer separation potential either to increase or decrease separations. Blood filtering as well as other biomedical separations are possible by this synergestic mass transfer.Catalytic depositions within the channels of the MCPs, either as wall coatings with the channels open or as solid porous catalytic material that has osmosis action thereacross further enhances chemical reactions during the separation process or during passage through the channels.

Abstract: A process for the nondegenerative distillation of C.sub.6 -C.sub.24 -fatty acids, of the type obtained by splitting natural fats and oils or by synthetic processes, such as for example the oxidation of paraffins, the crude product is thermally dried under reduced pressure, the dried and heated crude product is subjected to fractional evaporation in falling-film evaporators, optionally in the presence of superheated steam, and the various vapor fractions are deposited in condensers. The thermal drying process is conducted at a temperature of 60.degree.-80.degree. C. and a pressure of 90-100 mbars. The de-watered crude product is fractionated in a film-forming evaporator and, after distillation, passes to a rectification column which condenses the low boiling constituents as the main runnings.

Abstract: Mass transfer apparatus such as a distillation or rectification column which is divided so that the vapor flow is in two streams each in a separate zone, and wherein in each zone the liquid/vapor contacting stages have an inlet and an outlet disposed on opposite sides of an active area but to the same side of the division and such that liquid flow from the inlet across the active area to the outlet is generally rectiliner and parallel to the plane of the division, the locations of the stages in one zone being staggered axially relative to those of the stages in the other zone along the column and the liquid from each outlet being directed to an inlet of the next lower stage in the column whereby the liquid flow down the column is directed alternately from one zone to the other as it is passed successively from stage to stage down the column.

Abstract: A volatile component over a wide range of concentrations in a multicomponent feed to a distillation column is accommodated at varying feed flow rates without destroying bubble tray efficiency. This is effected by establishing on a bubble tray a plurality of separation zones having discrete and different liquid pressure seals above bubble apertures on the tray. To avoid entrainment, vapor flow restrictors are utilized with bubble apertures in at least one separation zone having less liquid head to offset a tendency of proportionately increased vapor flow through such a bubble aperture during operation of separation zones having a liquid head differential. Intermediate weirs or bubble apertures having different elevations below a liquid level on the tray can be used to establish such separation zones of differing liquid heads.

Abstract: Fractionating apparatus especially designed for use in non-adiabatic distillation comprising two series of corrugated horizontally spaced sheets, each of the two series of sheets extending vertically, one series of such sheets being offset vertically from the other series, and forming a plurality of vertically disposed side channels on each side of the adjacent corrugated metal sheets. The side channels provide a tortuous vertical path for upward flow of vapor, and liquid descending from above is split at each offset horizontal fin of the corrugated sheets and mixed with the neighboring stream, thereby providing efficient mixing of the liquid phase as well as the gas phase, such horizontal fins also providing additional liquid holdup, as the descending liquid tends to puddle on the topside of the fins.

Abstract: A pan-type liquid distribution assembly or fractionator which regulates the liquid flow through distribution tubes and, at the same time, provides for clearing away of unwanted fouling material which, in the past, has served to detract from the operation by plugging or partially plugging the liquid pour-points. Adjustment of the flow through, and/or, the unfouling of, the liquid pour-tubes can be performed from a point external of the fractionator, so as not to interfere with the ongoing operation of the fractionation column. A further feature is the ability to adjust liquid flow through each individual tube to alter the distribution pattern of the liquid across the top of a packed fractionation bed.

Abstract: A multi-tray apparatus for contacting a liquid with a gas is described, the apparatus being characterized by a perforated structure, located beneath downward flow means in the trays, for distributing downward flowing liquid uniformly over the trays.

Abstract: A packing material for a packed tower through which fluids to be processed are adapted to flow in contact with each other. The packing material comprises a packing block of honeycomb structure comprising partition walls defining a multiplicity of channels which are formed in parallel to each other as fluid passages through the packing block. The packing block includes plural plane sides in which said channels are open at opposite ends thereof. At least one of these plane sides is non-orthogonal or inclined to a line of extension of the channels. This at least one non-orthogonal plane side may have a larger surface area than the rest of the plane sides of the packing block. The packing block is preferably a polyhedron having not less than eight planes sides each as viewed in elevation, so that said channels are open in non-orthogonal relation with at least two of the plane sides of the polyhedron.

Abstract: A plate for columns performing distillation and/or absorption processes in which through openings in the plate body are provided with an inlet weir and with an outlet weir and in such openings inserts (8-21; 30) are fixedly mounted containing through holes with changing cross-sections, each insert (8-12; 30) contains a through hole which with respect to the flow direction of vapor and/or gas has an inlet zone (19;25) with an inwardly decreasing cross-section, an intermediate cylindrical zone (20, 26) connected thereto and, as a continuation thereof, an outlet zone (21;27) having an outwardly increasing cross-section; the plate body (2) and the upper surface of the inserts (8-12; 30) are aligned in a common or essentially common plane and, at least some of the inserts (8-12; 30); have through holes with their geometrical axis (x) being inclined under an acute angle (.alpha.) with respect to the upper plane of the plate body (2).

Abstract: Disclosed herein is a stripping tower adapted to remove unreacted vinyl chloride from a suspension or emulsion of a vinyl chloride resin after its polymerization reaction. The tower is a packed tower filled with a packing such as Tellerette packing. A condenser is provided in direct attachment to a top portion of the packed tower so that steam, which is discharged together with stripped monomeric vinyl chloride gas, is condensed in the condenser, separated from the monomeric vinyl chloride gas and then recirculated to the packed tower. Use of a packed tower as a stripping tower and steam as a stripping medium enjoys good removal efficiency of monomeric vinyl chloride but is accompanied by occurrence of a large volume of foams of a polyvinyl chloride slurry in the tower. Foams of the slurry eventually overflow from the top of the tower and do not permit any further continuation of the operation.

Abstract: Tower packing elements adapted for dumped packing and employed to effect vapor-liquid contact in vapor-liquid contact columns for the purposes of bringing about mass and heat transfer between the liquid and vapor phases. Each packing element is of the saddle variety and is arcuately formed about orthogonal notional axes. The body of the saddle comprises expanded metal; that is, metal that has been perforated, lanced, and/or expanded by stretching along oppositely oriented axes. Also disclosed are methods of forming a segmented, semi-toroidal tower packing element from metal which has been expanded, as well as from metal which has been slitted, and which is expanded at the same time as it is formed into a saddle shape. In this manner, the advantages of metal in tower dump packing can be utilized in a saddle configuration maximizing vapor-liquid contact and efficiency of the mass and heat transfer.

Abstract: A Snyder-type distilling column having improved floating ball vapor valves. When used in a standard Snyder-type column, the valve comprises a spherical upper portion and a downwardly extending guide stem. When used in a microcolumn, the upper portion is mushroom shaped with a downwardly extending guide stem. The lower surface of either upper portion forms the valve face and includes multiple indentations therein. When a ball valve is closed, the indentations form by-pass passages to permit draining of condensed liquids therethrough thereby preventing flooding of the column. The indentations also permit the passage of vapors through the ball valve indentations thereby preventing sticking which can occur with a tight fitting ball valve and cause rotation of the ball valve during use which also assists in preventing sticking.

Abstract: A randomly dumpable self orienting or orderly stackable hollow or cellular plastic packing elements of uniformly distributed high surface area and open cells comprised of adjacent first and second hollow triangular structures angularly displaced 60.degree. relative to one another about a central axis each including inclined structural side members connected together at apexes of the triangular structure and at crossing portions of the inclined structural members of the first and second triangular structure. Each of the inclined structural side members of each triangular structure is connected to a radial structural member of a Y-shape structure located on the adjacent outer side of each of the first and second triangular structures and interconnected by a central hub about the central axis of the packing element.

Abstract: An improved cascade weir type extraction zone is described in which at least one of the weir means is disposed above the associated tray. This improved extraction zone is of particular utility in lube oil processing operations.

Abstract: This invention relates to a distillation system for effecting separation of a multicomponent fluid and to an improved bubble-cap design which can accommodate very wide ranges of vapor and liquid loadings. A portion of the tray is provided with bubble caps having first and second slot openings with the second slot opening at an elevation higher than the first opening.

Abstract: A novel fractional distillation process and applications thereof to the production of thermal or mechanical energy from two low level heat sources wherein a mixture of two highly non-ideal reactive solutions such, for example, as of the water/ammonia type, is separated into its water and ammonia components in an apparatus comprising a cascade of condensers and evaporators operating respectively at the temperature of the cold source and at the temperature of the hot source and at staggered pressures. The residue and distillate formed are remixed in a mixing apparatus when it is desired to recover the thermal energy of dilution of the solutions.The invention is applicable, in particular, to the heating of buildings from low level thermal energy and from the thermal energy of "cold wind".

Abstract: A gas-liquid contacting apparatus is provided having downcomers which are closed at their lower ends by perforated, inclined, liquid distributing, gas entry retarding, plates. The downcomers each depend from a drainage opening bounded by a weir on a perforated, liquid frothing tray. Alternate trays have central drainage openings and are interposed with trays having drainage openings adjacent opposite tray sides. The trays have liquid frothing perforations across the whole of each tray including the area beneath each drainage opening. The perforations beneath a drainage opening occupy an area per unit area of the drainage opening in the range 0 to 25% less than the perforations per unit area in the remainder of that tray. The apparatus produces a frothing layer on the trays in which the perforated, inclined, liquid distributing, gas entry plates are immersed and, which gives a good liquid flow distribution across the tray so that a high efficiency of contact between the gas and the liquid is achieved.

Abstract: An improved system for separating higher boiling hydrocarbon products from methane in a gas/liquid extraction plant. The improvements lies in combining the fractionating tower with a counterflow plate and tube heat exchanger through which the refrigerated low pressure gas flows from top end to bottom end, and the precooled high pressure gas flows upwardly in counterflow relation. The heat exchanger is in the form of an annular chamber with tubes running the full length from bottom to top and plates forcing a zig-zag flow of the cold gas. This sets up a more or less linear temperature gradient which is impressed on the fractionating tower inside of the heat exchanger, which forms the inner wall of the heat exchanger and makes for more efficient and effective fractionation of the entering gas and vapor mixture.

Abstract: A packing (11) consists of laminated grids (a,b, . . . ) placed directly against each other. Each grid (a,b, . . . ) consists of approximately zigzag-shaped laminated strips (13-17) which run in the direction of the flow (22), are inclined towards the grid plane and are formed jointly in one piece with areal crossing points (b 18). The laminated strips (13-17) have recesses (20, 21) at the outer edges of the crossing points (18). In this way, it is achieved that the liquid phase flowing down on a laminated strip to a crossing point is directed, at least partially, across the crossing point to the adjacent laminated strip. The packing which can be produced in a simple and inexpensive way has a high specific surface and distributes the liquid on all sides transversely to the direction of the flow (22) whereby the turbulence required for the surface renewal develops at the crossing points of the grids.

Abstract: A gas-liquid contacting tray of the crossflow type with improved means for initiating bubbling activity at the tray inlet region comprising spaced-apart imperforate wall members extending substantially vertically upwardly and transverse to the liquid flow path, contiguously associated and coextensive at their upper edges with an intermediate perforated wall member horizontally extending therebetween.

Abstract: Mass transfer apparatus such as a distillation or rectification column which is divided so that the vapor flow is in two streams each in a separate zone, and wherein in each zone the liquid/vapor contacting stages have an inlet and an outlet disposed on opposite sides of an active area but to the same side of the division and such that liquid flow from the inlet across the active area to the outlet is generally rectilinear and parallel to the plane of the division, the locations of the stages in one zone being staggered axially relative to those of the stages in the other zone along the column and the liquid from each outlet being directed to an inlet of the next lower stage in the column whereby the liquid flow down the column is directed alternately from one zone to the other as it is passed successively from stage to stage down the column.

Abstract: A packed counter-current column in which the gas and the liquid is contacted in a column packed with layers of reproducible elements of regular polygonal section, each of which has a lower part shaped to form a nozzle by overlapping of two opposite walls of the element, which walls also form slits between themselves and the other walls, and an upper part including an arcuate or angular bend which narrows the upper part of the element. The layers may be spaced apart by from 0 to 3 times the height of a layer and superimposed or rotated in a horizontal plane relative to each other by an optional angle. The configuration introduces to the normal counter-current flow an additional conflow vortex and cross-flow motion in the elements and a turbulent motion between the layers.

Abstract: Free oil, often an objectionable impurity in synthetic organic detergents, such as sodium lauryl sulfate, is removed from aqueous solutions by extraction thereof with hexane in the presence of lower alkanol, with the proportion of the alkanol present being in a relatively narrow range with respect to the sodium lauryl sulfate, in which range it helps to promote efficient extraction of the free oil by the hexane without solubilizing the hexane in the aqueous medium to such an extent as to result in an extracted detergent containing an unacceptably high proportion of hexane. Separation of the free oil from the aqueous detergent solution is effected in an extractor, to which the hexane is added, in mixture with a minor proportion of lower alkanol, normally isopropanol, and extraction of the free oil takes place after a preliminary mixing of isopropanol with detergent acid or neutralized base in a neutralization vessel and/or in a mixer upstream of the extractor.

Abstract: A method for removing vinyl chloride monomer rapidly from a large amount of slurry of vinyl chloride resin to give waste water separated from said slurry, exhaust gas used in the drying of separated resin and resin product which are not objectionable from the environmental sanitation or to produce such a treated slurry which can give waste water separated from said slurry, exhaust gas used in the drying of separated resin and resin product which are not objectionable from the environmental sanitation by the repetition of said method. In said method a slurry of vinyl chloride resin is caused to flow down a plate column in which flow of slurry on the trays in each step of plates is treated with steam in a combination of specified plates and specified conditions of treatment.

Abstract: Apparatus is provided for converting sea or other undrinkable waters to drinkable water without the use of driven or moving parts. Reliance upon gradient effects is made to effect the vaporization of, for example, sea water, followed by the condensation of the vapor to form distilled water. Gradient effects are achieved through the provision of differentials in the thermal conductivity, capillary activity, adsorptive, absorptive and/or pressure characteristics of particulate materials, or combinations of such physicals. For example, a column is packed with material graded as to its conductivity, the least thermally conductive material being nearest the cold or ambient water that is to be purified. In packing the column each successive layer of material has a greater thermal conductivity than the layer beneath it with the most conductive being at the top near the outlet arm of the column.

Abstract: An atomization/distillation unit for separating a component from a mixture containing that component having a chamber, a container incorporated within the bottom of the chamber for receiving the mixture, a heater for heating the mixture to a temperature sufficient to vaporize the component but insufficient to vaporize the entire mixture, an atomizer located within the container for spraying said mixture upward in the chamber thereby aiding in further vaporization of the component, and agitator plates operating in conjunction with the atomizer for propelling the vapor upward in the chamber. Cooling coils are located in the top portion of the chamber in order to condense the vaporized component. Once condensed, the distillate is easily removed from the chamber. The atomization/distillation system is effective in combining atomization and distillation in order to maximize recovery of the desired component in a highly energy efficient manner.