Separatory And Thermolytic Patents (Class 202/84)
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Patent number: 6011187Abstract: This invention provides a method for reclaiming oil from waste plastic in such a way that thermosetting resins and solid foreign matter in the plastic will not pose a problem. This method greatly reduces the burden of presorting the garbage or industrial waste. To achieve this objective when oil is to be reclaimed from a waste plastic containing chlorine compounds, such as vinyl chloride, the plastic must first be stripped of chlorine. Prior to pyrolysis, while being conveyed forward in a continuous stream, the plastic is mixed with heated sand and/or an additive agent to raise its temperature to 250-350.degree. C. This creates a product which is comprised of a mixture of sand and substantially dechlorinated plastic. The product is mixed with heated sand to heat it directly to a temperature of 350-500.degree. C. It is maintained at this temperature until pyrolysis occurs.Type: GrantFiled: October 27, 1997Date of Patent: January 4, 2000Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Hirotoshi Horizoe, Takeshi Amari, Hiroshi Nagai, Shizuo Yasuda, Yuji Kaihara, Yoshimasa Kawami, Yasumasa Matsukawa
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Patent number: 5891310Abstract: The cycle time for a delayed coker unit is reduced by externally heating the coke drum near the junction of the drum shell and the supporting skirt thereof prior to beginning the hot coker feed fill step. This reduces the thermal stresses at the area around the welds of the drum skirt.Type: GrantFiled: June 20, 1997Date of Patent: April 6, 1999Assignee: Conoco Inc.Inventor: David K. Nelsen
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Patent number: 5871618Abstract: Disclosed is an apparatus and a process for reclaiming fuel oil from waste oil. The apparatus comprises a thermal cracking unit for cracking the high boiling hydrocarbon material into lighter, lower boiling, material so as to separate hydrocarbon vapor products from viscous materials; a condenser/heat exchanger for condensing the hydrocarbon vapor products to the liquid state; a fuel stabilization unit for chemically treating the condensates so as to give a oil product and solid sediment; and a polishing unit for forming a high quality fuel oil by physically removing solid contaminants. According to the present invention, high quality fuel oil can be obtained together with an environmentally innocuous solid ash cake, through a simple and efficient process.Type: GrantFiled: January 16, 1997Date of Patent: February 16, 1999Inventors: Sung Rae Lee, Henry Kong, Roy B. Jeffries, Norman L. Arrison, Wlodzimierz P. Rzazewski
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Patent number: 5423950Abstract: The reactor forms a chamber which contains the reaction process. There are accesses to the chamber for receiving shredded tires and oil. There are egresses from the chamber for discharging the tire oil and for discharging unreacted elements. Apparatus is located within the chamber which separates the unreacted components of the shredded tires from the tire oil. The apparatus also provides for the removal of the unreacted elements from the chamber means. The reactor also includes a heater which heats the inside of the chamber to a temperature sufficient to cause a reaction between the shredded tires and the oil.Type: GrantFiled: October 28, 1993Date of Patent: June 13, 1995Assignee: Texaco Inc.Inventors: Vahan Avetisian, Constantin Bugescu, Robert S. Burton, III, Craig J. Castagnoli, Suk-Bae Cha, Kenneth S. Lee, Allen M. Robin
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Patent number: 5178733Abstract: A method and apparatus for producing oil, bitumen, precious metals, and hydrocarbon gases from mined oil-bearing rock material, such as tar sands and soil shale. The rock is ground, preconditioned in a heated and pressurized atmosphere devoid of oxygen, and subsequently centrifuged in the presence of an oil-replacement gas to produce oil, and also any precious metal particles that are present in the oil-bearing rock material. The produced oil and precious metals are subsequently separated from each other by centrifuging.Type: GrantFiled: July 2, 1991Date of Patent: January 12, 1993Inventor: Jay P. Nielson
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Patent number: 4944845Abstract: Apparatus for the treatment of a liquid hydrocarbon charge containing solids or solids-forming contaminants, e.g., inorganic solids, metals and asphaltenes, which includes a contactor vessel having a liquid charge inlet, a vaporizing media inlet above the charge inlet and a vapor-solids outlet. An atomizer is positioned in the charge inlet for forming small particles of the liquid charge and directing the particles of liquid in a substantially horizontal flat pattern into the contactor vessel. A premix downcomer having a dispersion grid positioned therein is located in the vaporizing media inlet for introducing a fluidized mixture of a gas dispersion media and hot circulating solid particles into the contactor vessel in a substantially vertical flat pattern to traverse the path of the liquid particles and intimately contact the liquid particles.Type: GrantFiled: July 3, 1989Date of Patent: July 31, 1990Inventor: David B. Bartholic
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Patent number: 4670104Abstract: A process and system is provided to produce and dedust oil from oil shale and other types of solid hydrocarbon-containing material. In the process, raw oil shale is retorted, preferably with solid heat carrier material, to liberate an effluent product stream of hydrocarbons containing entrained particulates of dust derived from the oil shale or other solid hydrocarbon-containing material. A fraction of oil containing most of the dust is separated from the effluent product stream and fed to one or more dedusters. The dust-laden oil is dissolved in a special mixture of dedusting solvents which contains both polar and non-polar dedusting solvents. In the deduster, the dissolved oil is separated into a dedusted stream of oil and solvents and a residual stream of dust-laden sludge. Solvents are recovered from the dedusted stream as well as the sludge. The recovered solvents are recycled to the deduster for use in dedusting the oil.Type: GrantFiled: June 28, 1985Date of Patent: June 2, 1987Assignees: Standard Oil Company (Indiana), Gulf Oil Corporation (Pennsylvania)Inventor: James L. Taylor
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Patent number: 4613408Abstract: Apparatus producing fuel from waste products of the type capable of forming a flammable oil and gas when heated. The apparatus and method are particularly useful for disposing of discarded vehicle tires and at the same time producing fuel capable of operating engines or burners. The system utilizes a cooking pot and cooling apparatus for condensing gas formed in the cooking vessel to produce a flammable oil. The system including the cooking vessel is closed except for outlets from the cooling apparatus for both the oil and gas, whereby no appreciable pollution is discharged to atmosphere.Type: GrantFiled: November 23, 1984Date of Patent: September 23, 1986Inventor: William A. Howard
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Patent number: 4608126Abstract: An environmentally acceptable disposal site has at least one vapor break extending through a pile of synthetic fuel tailings, spent catalyst, spent ore, and/or other waste material. The vapor breaks can be permeable seams or columns of porous rocky overburden and/or a pneumatic pipeline. Circulation of air through the vapor breaks can be enhanced by air blowers, fans, or other force air inducers. The top and sides of the pile are covered with top soil and vegetated with trees, shrubbery, and grass to minimize erosion and blowing of the tailings as well as to provide a pleasing aesthetic appearance. The tailings preferably comprise spent oil shale which has been combusted, cooled, and moisturized. Desirably, the disposal site is built and operated in conjunction with a surface retort, combustor, heat recovery unit (cooler), and associated equipment.Type: GrantFiled: March 26, 1984Date of Patent: August 26, 1986Assignees: Amoco Corporation, Chevron U.S.A., Inc.Inventors: George H. Watson, David B. McWhorter, Adrian Brown
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Patent number: 4600476Abstract: A retort apparatus for recovering oil from crushed oil shale moved through an elongated housing, includes a plurality of heat exchangers located in the housing for transferring heat to or from the shale. The heat exchangers are spaced to define in sequence a drying zone, a preheating zone, a cracking and distillation zone, and a waste heat recovery zone. An auxiliary heating assembly connected to the heat exchangers delivers sufficient heat to raise the temperature of the shale in the cracking and distillation zone to the critical temperature for separating hydrocarbons in vapor form therefrom. The tubes of the heat exchangers are elongated ovals in cross-section and are offset from each other in alternate rows to increase the area of heat exchange and to reduce the temperature drop between the entering heated air and exiting heated air flowing through each heat exchange tube.Type: GrantFiled: February 28, 1985Date of Patent: July 15, 1986Assignee: Edwards Engineering CorporationInventor: Ray C. Edwards
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Patent number: 4552621Abstract: An apparatus comprises a reaction chamber provided with a charging hole, a branch pipe for discharging a suspension, and a branch pipe for withdrawing a vapor-gas phase which branch pipe is communicated with a condenser. The apparatus further includes a heater provided with a heat-exchanger for preheating a solvent, said heat-exchanger being introduced into said heater and communicated with said reaction chamber through nozzles adapted for jet feeding of the solvent into the reaction mass.At the outlet of the reaction chamber there is mounted a distillation column communicated with the branch pipe for discharging the suspension and provided in the upper portion thereof with a branch pipe for withdrawal of the vapor-gas phase, while in the lower portion thereof there is provided a branch pipe for discharging a distillation residue.Type: GrantFiled: June 17, 1983Date of Patent: November 12, 1985Assignee: Belorussky Politekhnichesky InstitutInventors: Genrikh D. Lyakhevich, Anatoly P. Khimanych, Vasily G. Suzansky, Vulf P. Kovalerchik
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Patent number: 4551232Abstract: Process and facility for upgrading heavy hydrocarbonaceous materials for making coke suitable for metallurgical purposes comprises mixing the heavy hydrocarbonaceous materials with a diluent having a closely controlled boiling range and subjecting the oil diluent mixture to distillation and careful fractionation so as to maximize liquid yields in the coking step.Type: GrantFiled: February 9, 1983Date of Patent: November 5, 1985Assignee: Intevep, S.A.Inventors: Jose L. Calderon, Humberto Betancourt
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Patent number: 4502919Abstract: An arrangement for extracting crude oil from oil shale comprising: a low temperature carbonization reactor; a processing means for feeding a slurry of oil shale, solvent and hydrogen into the low temperature carbonization reactor; a separating means for separating the resulting gaseous low temperature carbonization mixture from the used oil shale and for separating the low temperature carbonization mixture into gaseous and liquid low temperature carbonization products; a gas turbine the exhaust gas outlet of which is connected to two heat exchangers, one of which heat exchangers is disposed in a circulation system for a scavenging gas, which circulation system includes a separating reactor (which forms part of said separating means) in which in use the scavenging gas flows upwardly in counterflow to the oil shale for separation of the fluid low temperature carbonization mixture from the used oil shale, and the other of which heat exchangers is disposed between the low temperature carbonization reactor and saiType: GrantFiled: October 7, 1983Date of Patent: March 5, 1985Assignee: Kraftwerk Union AktiengesellschaftInventors: Gerd Brunner, Rainer Hoffmann, Konrad K/u/ nstle
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Patent number: 4394215Abstract: The invention provides a process and an apparatus for hydrogenative liquefaction of coal to produce high yields of gasoline fraction and optional yields of diesel and residue fraction, all of superior quality. The coal is slurried and digested in two separate and distinct streams. The pasting oil of the first stream is heavy residue fraction derived to a substantial extent from the second stream, preferably mixed with light oil derived partly or wholly from the first stream. The pasting oil of the second stream is middle oil derived from the fractionated discharge of the first stream, any shortfall being made up from the discharge of the second stream. A high degree of flexibility is possible by varying the ratio of coal fed to the respective streams between 3:1 and 1:3, and individual manipulation of the process parameters within each stream in respect of pressure, temperature, catalyst, residence time, pasting oil composition and coal quality.Type: GrantFiled: November 23, 1981Date of Patent: July 19, 1983Assignee: Sasol One (Proprietary) LimitedInventors: Berend Jager, Andries Brink, Cornelis Kleynjan
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Patent number: 3945890Abstract: Organic and pseudo-organic materials, such as waste materials, for example, are processed in a converter system and decomposed into various usable and reusable forms. Inorganic metals and salts are treated likewise in the same converter system and processed into various usable and reusable forms. While being carried by a conveyor through a controlled atmosphere treatment chamber, virtually free from combustion supporting air or other oxidizing agents, the feed material is caused to progressively thermally break down into its more basic constituents which flow out of the material treatment chamber in a continuous liquid and gaseous vapor stream. Negative pressure is applied upstream from the material treatment chamber to lead the liquid and gaseous vapor stream through successive processing stages of collection containers, condensers and gas scrubbers. The variable negative pressure is sufficient to maintain the pressure in the material treatment chamber within a range of slightly above ambient pressure.Type: GrantFiled: July 26, 1974Date of Patent: March 23, 1976Inventor: Klaus M. Kemp