Distillation Residue As Heat Source Patents (Class 203/23)
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Patent number: 10144682Abstract: A butadiene extraction processes designed for flexible operations, with or without a compressor, is disclosed. The ability to run at both high and low pressures provides added process flexibility.Type: GrantFiled: April 3, 2017Date of Patent: December 4, 2018Assignee: Lummus Technology Inc.Inventors: Robert J. Brummer, Thomas Alexander Dwyer
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Publication number: 20150129412Abstract: A method for recovering base oil from waste lubricating oil by separating base oil range constituents from a waste lubricating oil mixture, thereafter separating higher quality base oil constituents and lower quality base oil constituents from the base oil recovered from the waste lubricating oil mixture and thereafter treating the lower quality base oil constituents to produce marketable base oil. The total base oil produced from a waste lubricating oil mixture by this process is greater than the quantity producible by previous processes using only base oil separation from the waste lubricating oil mixture or processes which use only treatment of the base oil recovered from the waste lubricating oil mixture to produce the product base oil.Type: ApplicationFiled: January 20, 2015Publication date: May 14, 2015Inventor: Martin R. MacDonald
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Patent number: 8951391Abstract: A solar distillation apparatus utilizing a substantially vertical reactor assembly is disclosed. The reactor includes a tubular outer shell, a base, a cap, and a central tension member. The annular space between the outer tube and the central tension member forms the reactor chamber. Seawater or other feed liquid enters the reactor chamber through the base plate. Reflected or direct solar energy heats the feed liquid, generating low pressure vapor. The vapor exits the reactor through the cap structure or the base. The concentrate left behind settles by gravity to the bottom region of the reactor's liquid column. Extension tubes on the feed openings allow feed liquid to enter the liquid column above the concentrate layer and avoid excessive mixing of the feed liquid and the concentrate. The concentrate exits the reactor through one or more openings in the base.Type: GrantFiled: May 2, 2011Date of Patent: February 10, 2015Inventor: Miles McClure
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Publication number: 20140246302Abstract: The invention relates to the petroleum-processing industry, in particular, to a retarded coking process directed to the production of gas oil fractions (light gas oil and two types of heavy gas oil). The method comprises heating a starting stock, feeding same into an evaporator for mixing with recycled material and forming a secondary stock, coking the secondary stock and fractionating the resulting coking products in a rectification column, thereby producing gas, petrol; light and heavy coking gas oils, and bottoms. Heavy coking gas oil is used as the recycled material. The method envisages feeding cooled heavy gas oil to mass-exchange devices in the lower part of the rectification column, and feeding a metered quantity of cooled light gas oil to mass-exchange devices in the upper part of the rectification column. The quantity of cooled light and heavy gas oils which can be fed in changes depending on the required quantity and quality of the light and heavy gas oils and bottoms being produced.Type: ApplicationFiled: August 29, 2012Publication date: September 4, 2014Inventors: Gennady Georgievich Valyavin, Victor Pavlovich Zaporin, Sergei Vital'evich Sukhov, Mikhail Vladimirovich Mamaev, Igor Viktorovich Bidilo, Konstantin Gennad'evich Valyavin
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Patent number: 8771478Abstract: A modular distillation apparatus including at least one heat exchanger that preheats contaminated liquids: a heater that heats the contaminated liquid from the heat exchanger; an evaporator condenser adapted o boil the contaminated liquid coming out of the heater to produce water vapor and contaminant concentrate, and condenser the water vapor into distilled water; a vacuum chamber capable of operating at below atmospheric pressure, the vacuum chamber housing the evaporator condenser and including at least one partition to separate the distilled water from the contaminate concentrate; a vapor compressor operably associated with the vacuum chamber to receive water vapor from the evaporator condenser in the vacuum chamber and pump the water vapor at pressure back through the evaporator condenser, wherein the heat exchanger recovers sensible heat from outgoing condensed distilled water and contaminant concentrate recycled from the vacuum chamber.Type: GrantFiled: April 24, 2008Date of Patent: July 8, 2014Assignee: Equus Environmental Ltd.Inventor: Dudley Edgar James Ward
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Publication number: 20130240346Abstract: An anti-thermosensitization rectification tower comprising a rectification tower, a T-shaped condenser, a baffle plate, a tower bottom, a falling-film reboiler and a recirculation system, wherein the T-shaped condenser is secured exactly on the top of the rectification tower without any pipeline in between, and the circular baffle plate is installed in the T-shaped condenser; an annular sump located between the rectification tower and the T-shaped condenser for collecting the liquid condensed in the T-shaped condenser and channeling it out of the rectification tower into a liquid-collecting tank, and a centrifugal pump utilized to connect together the tower bottom and the falling-film reboiler to form a high-speed circulation system, wherein the tower bottom is an elongated conduit and the falling-film reboiler is in the form of a stout shell-and-tube heat exchanger is provided.Type: ApplicationFiled: March 14, 2011Publication date: September 19, 2013Applicant: NANJING UNIVERSITYInventors: Zhibing Zhang, Zheng Zhou, Gaodong Yang, Defang Sun, Ling Zhang
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Patent number: 8535487Abstract: A process for purifying an aqueous stream from a Fischer-Tropsch reaction that includes feeding the aqueous stream to a system that includes a distillation column equipped with a partial condenser and a total condenser, at least partially condensing the vaporized stream leaving the head of the distillation column and collecting a first distillate in which in heavier by-products, totally condensing the remaining portion of the vaporized stream leaving the partial condenser and collecting a liquid stream which is returned to the distillation column as a reflux and removing a purified aqueous stream from the bottom of the distillation column.Type: GrantFiled: May 30, 2008Date of Patent: September 17, 2013Assignee: ENI S.p.A.Inventors: Lino Carnelli, Carla Lazzari, Gianni Pandolfi
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Publication number: 20130001062Abstract: A process for recovering butanol from a mixture comprising a water-immiscible organic extractant, water, butanol, and optionally a non-condensable gas, is provided. The butanol is selected from 1-butanol, 2-butanol, isobutanol, and mixtures thereof. The extractant comprises at least one solvent selected from the group consisting of C7 to C22 fatty alcohols, C7 to C22 fatty acids, esters of C7 to C22 fatty acids, C7 to C22 fatty aldehydes, and mixtures thereof.Type: ApplicationFiled: September 12, 2012Publication date: January 3, 2013Applicant: BUTAMAX(TM) ADVANCED BIOFUELS LLCInventors: MICHAEL CHARLES GRADY, William D. Parten, Bruce M. Vrana, Yihui Tom Xu, Joseph J. Zaher
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Patent number: 8282790Abstract: Embodiments of the invention are directed toward a novel pressurized vapor cycle for distilling liquids. In an embodiment of the invention, a liquid purification system is revealed, including the elements of an input for receiving untreated liquid, a vaporizer coupled to the input for transforming the liquid to vapor, a head chamber for collecting the vapor, a vapor pump with an internal drive shaft and an eccentric rotor with a rotatable housing for compressing vapor, a condenser in communication with the vapor pump for transforming the compressed vapor into a distilled product, and an electric motor with motor rotor and magnets hermetically sealed within the fluid pressure boundary of the distillation system.Type: GrantFiled: October 29, 2007Date of Patent: October 9, 2012Assignee: DEKA Products Limited PartnershipInventors: Jason A. Demers, Scott A. Leonard, Kingston Owens
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Publication number: 20120145530Abstract: There is provided a method for a purification of trichlorosilane, the method including: performing a pretreatment for separating a chlorosilane mixture from reaction products of a trichlorosilane production reaction; performing a first purification for separating the chlorosilane mixture into a first top stream and a first bottom stream; performing a second purification for separating the first top stream into a second top stream and a second bottom stream; and performing a third purification for separating the second bottom stream into a third top stream and a third bottom stream, wherein the performing of the third purification is carried out under pressure conditions higher than those of the performing of the second purification, and a heat exchange is generated between the second bottom stream and the third top stream.Type: ApplicationFiled: December 13, 2011Publication date: June 14, 2012Applicant: LG CHEM, LTD.Inventors: Chul-Hwan CHOI, Jeong-Seok LEE, Kwang-Wook CHOI, Joon-Ho SHIN, Dong-Kyu KIM
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Publication number: 20120145529Abstract: A fluid delivery apparatus is provided for supplying a fluid mixture to a distillation column or reactor. The apparatus can be used to enhance the heat duty, the flow and/or the flow stability of an existing thermosiphon reboiler which supplies a heated fluid to the column or reactor. The apparatus includes an integrated eductor which receives and increases the fluid velocity of a supplemental fluid into which the heated fluid is aspirated to form a fluid mixture then delivered to the column or reactor. A process and a system utilizing the apparatus are also disclosed, as well as a method of retrofitting an existing system with the apparatus.Type: ApplicationFiled: December 14, 2010Publication date: June 14, 2012Inventors: Alphonzo George Nelson, Les Jackowski
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Publication number: 20120097520Abstract: The invention provides a process and apparatus for the separation of a gaseous feed comprising a mixture of hydrocarbons and nitrogen gas, the process comprising the steps of: (i) cooling and at least partially condensing the gaseous feed; (ii) feeding the cooled and at least partially condensed feed from step (i) to a fractionation column comprising reboil to produce an overhead hydrocarbon vapour stream enriched in nitrogen and a condensed hydrocarbon product stream low in nitrogen, wherein prior to the fractionation, the feed stream is divided into at least two streams including: a) a first stream which is expanded and fed to the fractionation column; b) a second stream which is expanded, heated and fed to a lower stage of the fractionation column than the first stream, (iii) removing a hydrocarbon product stream low in nitrogen from the fractionation column; and (iv) removing a hydrocarbon vapour stream enriched in nitrogen from the fractionation column.Type: ApplicationFiled: March 23, 2010Publication date: April 26, 2012Applicant: COSTAIN OIL, GAS & PROCESS LIMITEDInventors: Grant Leigh Johnson, Adrian Joseph Finn, Terence Ronald Tomlinson
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Patent number: 8128787Abstract: Processes for removing water from organic solvents, such as ethanol. The processes include distillation in two columns operated at sequentially higher pressure, followed by treatment of the overhead vapor by one or two membrane separation steps.Type: GrantFiled: August 27, 2008Date of Patent: March 6, 2012Assignee: Nitto Denko CorporationInventors: Nicholas P. Wynn, Yu Huang, Masakatsu Urairi, Richard W Baker
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Patent number: 8114255Abstract: Processes for removing water from organic solvents, such as ethanol. The processes include distillation in two columns operated at sequentially higher pressure, followed by treatment of the overhead vapor by one or two membrane separation steps.Type: GrantFiled: August 27, 2008Date of Patent: February 14, 2012Assignee: Membrane Technology & Research, Inc.Inventors: Leland M Vane, Franklin R Alvarez, Yu Huang, Richard W Baker
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Patent number: 8021519Abstract: A system for distilling sea or brackish water includes a feed water arrangement for supplying feed water from a feed water source to one or more flashing stages. Each flashing stage has a water flash evaporator for vaporizing at least part of the water therein, and a condenser for receiving the vapour and converting at least a part of the vapour into distilled water. A heat storage arrangement provided with a heat generating source for storing heat energy is used to heat a fluid medium flowing through it. A heat exchange arrangement receives the hot fluid medium and transfers heat to a stream of vapour flowing under pressure from each flashing stage. The vapour leaving the heat exchange arrangement being at a raised temperature is arranged to be condensed into water at the condenser and to transfer some of its latent heat to the evaporator.Type: GrantFiled: September 14, 2005Date of Patent: September 20, 2011Inventor: Gregory Mark Paxton
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Patent number: 8002953Abstract: An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.Type: GrantFiled: July 13, 2007Date of Patent: August 23, 2011Assignees: AMT International Inc., CPC Corporation, TaiwanInventors: Fu-Ming Lee, Kuang-Yeu Wu, Lindsey Vuong, Fong-Cheng Su, Tzong-Bin Lin, Jyh-Haur Hwang, Hung-Chung Shen, Po-Sung Cheng, Tai-Ping Chang
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Publication number: 20110132741Abstract: The invention comprises an absorption heat pump to supply energy to a distillation process or an outside process. The streams used to effect the absorption heat pump are to be combined in any case as a feedstream to a conversion process, and energy thus is conserved by avoiding the necessity of reseparating the streams.Type: ApplicationFiled: December 3, 2009Publication date: June 9, 2011Applicant: UOP LLCInventors: Paul A. Sechrist, Stanley J. Frey
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Patent number: 7955478Abstract: A solar distillation apparatus utilizing a substantially vertical reactor assembly is disclosed. The reactor includes a tubular outer shell, a base, a cap, and a central tension member. The annular space between the outer tube and the central tension member forms the reactor chamber. Seawater or other feed liquid enters the reactor chamber through the base plate. Reflected or direct solar energy heats the feed liquid, generating low pressure vapor. The vapor exits the reactor through the cap structure or the base. The concentrate left behind settles by gravity to the bottom region of the reactor's liquid column. Extension tubes on the feed openings allow feed liquid to enter the liquid column above the concentrate layer and avoid excessive mixing of the feed liquid and the concentrate. The concentrate exits the reactor through one or more openings in the base.Type: GrantFiled: February 14, 2007Date of Patent: June 7, 2011Inventor: Miles McClure
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Publication number: 20100288623Abstract: The invention relates to the oil processing industry and can be used for producing vacuum in a vacuum petroleum distillation column. The inventive method involves pumping out a vapour-gas medium from the column by means of a gas-gas ejector in such a way that a vapour-gas mixture is formed at the entry thereof and supplying said mixture to a condenser for producing a gas mixture and a vapour phase condensate. The gas mixture is supplied from the condenser to a liquid-gas jet apparatus and the condensate is delivered to an additional separator. A hydrocarbon-containing condensate is removed from the additional separator for the intended use thereof and a water-containing condensate is fed to a steam generator for producing steam by supplying heat of a hot distillate evacuated from the vacuum column. The thus obtained steam is used in the gas-gas ejector as a high-pressure gas.Type: ApplicationFiled: November 6, 2008Publication date: November 18, 2010Inventor: Valery Grigorievich Tsegelsky
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Patent number: 7737318Abstract: The invention relates to a process for preparing 1-butenic fractions having less than 2000 ppm of isobutene in relation to 1-butene from technical mixtures of C4 hydrocarbons I which contain at least 1-butene and 2000 ppmw to 8% by mass of isobutene based on the 1-butene, with or without n-butane, isobutane and/or 2-butenes.Type: GrantFiled: December 14, 2006Date of Patent: June 15, 2010Assignee: Evonik Oxeno GmbHInventors: Silvia Santiago-Fernandez, Armin Rix, Jochen Praefke, Dirk Roettger, Markus Winterberg, Wilfried Bueschken
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Patent number: 7641772Abstract: A distillation unit (10) employs a fluid circuit (FIG. 8) in which a counterflow heat exchanger (102, 104, 106, 108, 110) transfers heat from condensate and concentrate to feed liquid to be distilled. The pumping system (100, 238) that drives fluid through the circuit is arranged to keep the pressure in the counterflow heat exchanger's condensate higher than that in its feed-liquid passage. This tends to discourage the contamination that could otherwise occur in the concentrate if the fluid isolation ordinarily maintained between those passages is compromised.Type: GrantFiled: January 20, 2005Date of Patent: January 5, 2010Assignee: Zanaqua Technologies, Inc.Inventor: William H. Zebuhr
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Patent number: 7619126Abstract: A process for recovering crude 1,3-butadiene from a C4 fraction by extractive distillation using a selective solvent in a dividing wall column (TK) in which a dividing wall (T) is arranged in the longitudinal direction of the column to form a first subregion (A), a second subregion (B) and a lower common column region (C) and which is preceded by an extractive scrubbing column (K), wherein the operation of the dividing wall column (TK) is set by regulation of the energy input into the dividing wall column (TK) via a bottom vaporizer (V) and setting of the number of the theoretical plates in the lower common column region (C) so that a bottom stream (17) consisting of purified solvent is obtained from the dividing wall column (TK), is proposed.Type: GrantFiled: May 19, 2004Date of Patent: November 17, 2009Assignee: BASF AktiengesellschaftInventor: Bernd Heida
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Patent number: 7572352Abstract: Salt-containing water is desalinated by first passing salt-containing water through a heat exchanger disposed in a basin containing solar-heated brine formed by several layers of water lying one above the other in the basin, each of the layers of water forming the brine having a higher salt content than the layer present there above. The heat exchanger is in the lowermost layer of water having a higher temperature than the temperature of the layers of water lying above the lowermost layer of water. The salt-containing water is heated in the basin by solar energy indirect heat exchange with the solar-heated brine to obtain heated salt-containing water. At least part of the heated salt-containing water is evaporated to obtain water vapor, and the water vapor is condensed to obtain desalinated water.Type: GrantFiled: November 26, 2003Date of Patent: August 11, 2009Inventor: Hans Josef Van Els
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Publication number: 20090057128Abstract: An improved process for separation of liquid mixtures involves vapor stripping followed by mechanical compression of the vapor which is then exposed to a permeation membrane for separation of the compressed vapor.Type: ApplicationFiled: August 30, 2007Publication date: March 5, 2009Inventors: Leland Vane, Franklin R. Alvarez
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Patent number: 7465376Abstract: The invention provides for the removal of impurities from treatment fluid including a base liquid and a variety of impurities contained in the base liquid by conveying the treatment fluid to at least one preheating separating device, including a preheating heat exchanger and a separator unit, before the admixture of a carrier gas to the treatment fluid. The treatment fluid is preheated by the preheating heat exchanger to a temperature below the boiling temperature of a base liquid so that the liquid impurities with lower boiling temperatures than the base liquid are evaporated and expelled thermally, whereby the evaporated and expelled impurities are separated in the separator unit of the preheating separator device. The treatment fluid is then evaporated and separated from impurities having a higher boiling point than the base liquid.Type: GrantFiled: February 9, 2002Date of Patent: December 16, 2008Inventors: Joachim Neubert, Karl-Ferdinand Staab
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Patent number: 7442348Abstract: A sulfur-bearing residue treatment system is provided for the recovery of valuable organic components and the reduction of capital costs and operating costs. The treatment system involves the use of a stripping vessel in conjunction with a heating apparatus. All elements of the treatment system may be coupled together to form one integral piece of equipment.Type: GrantFiled: June 17, 2005Date of Patent: October 28, 2008Assignee: Rohm and Haas CompanyInventors: Curtis Instad Carlson, Jr., Michael Stanley DeCourcy, Jamie Jerrick John Juliette, Thomas Albert Kaminski, Nelson Ivan Quiros, Paul Benjamin Schladenhauffen
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Patent number: 7408074Abstract: Process for preparing an alkene oxide, which comprises at least the steps (i), (ii) and (v): (i) providing a stream S1 comprising compressed, liquid alkene; (ii) depressurizing at least part of the stream S1 with absorption of heat and with at least partial vaporization of the liquid alkene; (v) reacting the alkene obtained in (ii) with a hydroperoxide in the presence of at least one solvent and at least one catalyst to give a mixture comprising alkene oxide and the solvent or solvents.Type: GrantFiled: April 16, 2004Date of Patent: August 5, 2008Assignee: BASF AktiengesellschaftInventors: Hans-Georg Goebbel, Peter Bassler, Joaquim Henrique Teles, Peter Rudolf
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Patent number: 7378536Abstract: Process for preparing propylene oxide, which comprises at least the steps (iii) and (iv) (iii) separating off propylene oxide from a mixture (M1) comprising propylene oxide and at least one solvent by distillation in a distillation column, giving a bottom stream and a vapor stream consisting essentially of propylene oxide; (iv) compressing the vapor stream obtained in (iii) by means of at least one compressor to give a compressed vapor.Type: GrantFiled: April 16, 2004Date of Patent: May 27, 2008Assignee: BASF AktiengesellschaftInventors: Hans-Georg Goebbel, Peter Bassler, Joaquim Henrique Teles, Peter Rudolf
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Patent number: 6966974Abstract: The invention relates to a method for evaporating a solution and an evaporator applied to it. The evaporator (1) has parallel plate heat exchanger elements (3) fitted inside a jacket (2), consisting of a flexible plastic film, for example, and a liquid distribution space (4) common to the elements, from where the solution to be evaporated can be spread, through supply channels (6), on the heat transmission surfaces (4) of the elements to run from the top downwards. The solution (10) that has not evaporated on the surfaces is recycled from the bottom of the evaporator back to the liquid distribution space, and from there to the heat transmission surfaces (4) of the elements for re-evaporation. In connection with evaporation, precipitate is separated from the solution as a result of over-saturation, ending up in the recirculation flow with the solution and being separated from the solution in the liquid distribution space (14) that works as a separator for the precipitate.Type: GrantFiled: March 31, 2000Date of Patent: November 22, 2005Assignee: Oy Casparado ABInventors: Leif Ramm-Schmidt, Kari Myreen, Matti Laajaniemi
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Patent number: 6939444Abstract: A sulfur-bearing residue treatment system is provided for the recovery of valuable organic components and the reduction of capital costs and operating costs. The treatment system involves the use of a stripping vessel in conjunction with a heating apparatus. All elements of the treatment system may be coupled together to form one integral piece of equipment.Type: GrantFiled: June 7, 2002Date of Patent: September 6, 2005Assignee: Rohm and Haas CompanyInventors: Curtis Instad Carlson, Jr., Michael Stanley DeCourcy, Jamie Jerrick John Juliette, Thomas Albert Kaminski, Nicole Rendon Koegel, Nelson Ivan Quiros, Paul Benjamin Schladenhauffen, Peter John Schmeidler, Robert R. Maven, William Harry Engle, Jr., Arthur Meisch
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Patent number: 6835287Abstract: An apparatus comprising first to third columns, wherein the outlet of a first column reboiler and the inlet of a second column condenser are connected by a first introduction conduit, and the outlet of a second distillation column reboiler and the inlet of a third column condenser are connected by a second introduction conduit, and additionally the outlet of the second column condenser and the inlet of the first column reboiler are connected by a first return conduit, and the outlet of the third column condenser and the inlet of the second column reboiler are connected by a second return conduit.Type: GrantFiled: October 11, 2000Date of Patent: December 28, 2004Assignee: Nippon Sanso CorporationInventors: Hitoshi Kihara, Hiroshi Tachibana, Shigeru Hayashida, Hiroshi Kawakami
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Publication number: 20040026225Abstract: The invention concerns appliances, one of which uses solar energy as sole source of power. It comprises an accumulation solar water heater (222) and quasi-reversible liquid/vapour heat exchanging alveolar elements, provided with hydrophilic coatings. Elements of types E and C, respectively assigned to water evaporation (224a, b, c) and to vapour condensation (226a-b) are interposed, with narrow free spaces, in a heat-insulated treatment chamber (223), arranged above the boiler (222). Hot water coming from the heater (222) flows in closed circuit, by thermosiphon, from the top downwards of elements E and from the bottom upwards of elements C. A slightly cooling member (242) is interposed between the bottom collectors (240-244) of elements E and C. Hot water spills over slowly from the top of the hydrophilic coatings of elements E and the vapour produced is condensed opposite, on the walls of elements C.Type: ApplicationFiled: June 12, 2003Publication date: February 12, 2004Inventor: Jean-Paul Domen
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Patent number: 6689251Abstract: A distiller (10) that employs a rotary heat exchanger (32) introduces water to be evaporated into evaporation chambers (56). During most of its operation, it collects the water that has passed through the evaporation chamber (56) without evaporating, and it reintroduces the thus-collected liquid back into the evaporation chamber, where it also adds a minor amount of unrecirculated feed liquid to make up for evaporation and concentrate removal. Simultaneously, a minor amount of feed liquid is fed into one side of a transfer pump (116). During this mode of operation, the impurities concentration in the recirculating liquid tends to increase as a result of the evaporation of pure water vapor. Periodically, the erstwhile recirculating liquid is redirected to the other side of the transfer pump (116), where it causes the feed liquid stored in the transfer pump's first side to be fed without accompanying recirculant liquid into the rotary heat exchanger's evaporation chambers.Type: GrantFiled: January 18, 2001Date of Patent: February 10, 2004Assignee: Ovation Products CorporationInventor: William H. Zebuhr
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Publication number: 20040000470Abstract: A method to purify N,N-dimethylacetamide (DMAc) from an aqueous solution containing acetic acid as a contaminant. Two fractional distillation columns are arranged in a series. The solution containing the contaminant is provided to the first column with a temperature profile to result in acetic acid partitioning into the overhead water. The material remaining in the bottom portion of the first column is recycled to the first column and also provided into a second column, whereby DMAc free of acetic acid contamination is recovered, and remaining DMAc and acetic acid are returned to the first column for further separation. The method uses standard fractional distillation procedures and equipment, thus eliminating the need for more complex extractions and/or chromatographic separations.Type: ApplicationFiled: July 1, 2002Publication date: January 1, 2004Applicant: MALLINCKRODT INC.Inventor: Michael J. Gentilcore
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Publication number: 20030209419Abstract: A mechanical water still (10) includes an impervious dome-like upper surface (12) and a membrane base (14) that is coupled (26) to the impervious dome-like structure (12) to form, when inflated, a chamber (20). The membrane base (14) supports a water pervaporation process therethrough. A water collection well (16) has an opening into which water droplets condensed from the water pervaporation process collect. The water collection well (16) is sited within the membrane base (14) and generally extends outwardly and downwardly from the membrane base (14), as shown in FIG. 1. In use, a contaminated water source (24) is brought into, ideally, complete contact with the membrane base (14), with the water collection well (16) arranged both to act as a heat sink into the water source (24) and to provide stability to the water still (10) when floating and immersed in the water source (24).Type: ApplicationFiled: June 10, 2003Publication date: November 13, 2003Inventors: Mark Christopher Tonkin, Mark Andrew Young, Neil David Eckert
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Publication number: 20030132097Abstract: A desalination device includes a saltwater input line and a desalinator having a water input connected to the input line, a fresh water output and a brine output. A fuel cell generates electricity and is connected to an energy source for the desalinator. A heat exchanger transfers waste heat from the fuel cell to desalinator.Type: ApplicationFiled: January 15, 2002Publication date: July 17, 2003Inventors: Brian Kenet, Pedro Joaquin Sanchez Belmar
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Publication number: 20030132095Abstract: A method for distilling water includes the steps of entering brine to be distilled into a sub-atmospheric boiler having a brine section with a brine output and a water vapor output; concentrating brine in the brine section to a concentration of at least 250 grams of salt or contaminants per liter; stirring the brine in the brine section; and exiting the brine through the brine output. A distiller with a subatmospheric boiler having a stirring device is also provided.Type: ApplicationFiled: January 15, 2002Publication date: July 17, 2003Inventors: Brian Kenet, Pedro Joaquin Sanchez Belmar
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Publication number: 20030019736Abstract: The present invention provides a system and method for utilizing DDGS by-products from an ethanol plant. In one embodiment, the DDGS is burned to release thermal energy, which is used to produce steam needed for the operation of the ethanol plant. This method can realize approximate 67% savings in the fuel cost over the conventional propane-fueled ethanol plant.Type: ApplicationFiled: June 6, 2002Publication date: January 30, 2003Inventor: Daniel T. Garman
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Publication number: 20020092758Abstract: A distillation unit (10) employs counterflow-heat-exchanger modules (102, 104, 106, 108, and 110) to use the heat from water that has come from a rotary heat exchanger (32) to heat feed water that is being sent to it for distillation. In one of the modules the feed water is heated only by concentrate that results from the distillation process, whereas only condensate heats the feed water in the other modules. By thus employing four different flows in two sets of heat-exchanger modules rather than three flows in a single set, the distillation unit can employ relatively simple counterflow-heat-exchanger modules and easily adjust flows to achieve a desired output concentration in response to different expected feed concentrations while maintaining optimum feed flows.Type: ApplicationFiled: January 18, 2001Publication date: July 18, 2002Inventor: William H. Zebuhr
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Patent number: 6355145Abstract: A method for removing a contaminant from a fluid feed stream containing the contaminant. The method includes the steps of providing a feed stream and heating it in a first step to at least partially remove some of the contaminants and recover energy from a concentrate and distillate generated. Further heating the feed stream in a second heating step in a heated separator generates a saturated vapor fraction and a concentrated liquid contaminant fraction. The vapor fraction may be compressed to generate a temperature differential in the reboiler exchanger with the vapor fraction being passed into contact with a reboiler exchanger to provide a stream of condensed vapor from the reboiler. The stream may be circulated through the reboiler exchanger and the heated separator to maintain from about 1% to about 50% by mass vapor in the stream. The apparatus includes a unique configuration of a vapor compressor, heated separator in combination with a forced circulation circuit to generate the decontamination result.Type: GrantFiled: January 14, 1998Date of Patent: March 12, 2002Assignee: Aqua-Pure Ventures, Inc.Inventors: Steve Kresnyak, Minoo Razzaghi, Robert Spiering
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Patent number: 6120651Abstract: A method permits concentration of a water-miscible organic liquid in a mixture of such liquid and water, with recovery of a desired concentrate of the water-miscible organic liquid and water, and a relatively clean water containing only a very low contest of the water-miscible organic liquid which enables disposal of the water in sewage systems, the method thus enhancing the ability to satisfy environmental concerns; the method has particular application to the recovery of a reusable glycol/water mixture from diluted spent aircraft deicer fluid (ADF).Type: GrantFiled: May 20, 1999Date of Patent: September 19, 2000Assignee: Inland Technologies Inc.Inventors: Peter Henry Firth Gammon, Gary James Dinn, John Joseph Whitten
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Patent number: 5968321Abstract: Distillation system having an evaporator/condenser core with heat transfer plates welded together along their edges to form alternate boiling and condensing chambers. Feed liquid is supplied to the boiling chambers through a pair of heat exchangers which preheats the liquid and a steam stripper utilizing ceramic pieces to remove gasses from the liquid. Vapor from the boiling chambers is compressed and delivered to the condensing chambers where it is condensed and gives up its heat to the liquid in the boiling chambers. Pumps positioned between the two heat exchangers draw the condensed product and unvaporized feed liquid containing dissolved solids from the evaporator/condenser and circulate them through the heat exchangers to transfer heat to the feed liquid.Type: GrantFiled: February 13, 1996Date of Patent: October 19, 1999Assignee: Ridgewood WaterPure CorporationInventor: Stephan B. Sears
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Patent number: 5925223Abstract: A process and apparatus for improving the thermal efficiency of a steam turbine power generating plant while simultaneously desalinating seawater or brine and purifying water which contains minerals, salts, and other dissolved solids. Exhaust gases from a power plant is heat exchanged against water in a secondary ecomomizer which circulates water at a temperature near, or slightly above the dewpoint of the combustion exhaust of the high-pressure boiler. The heated water is flashed to produce low-pressure steam. The low-pressure steam is condensed against the last effect of a multi-effect desalinization unit. Steam from the first effect of the desalination unit is condensed against steam condensate from the power plant turbine to preheat the condensate and thereby recover heat from the power plant's exhaust gas. Salinous water is fed to the multi-effect desalinization unit to produce fresh water and a concentrated brine.Type: GrantFiled: April 1, 1997Date of Patent: July 20, 1999Inventors: Gary D. Simpson, Karl Lin
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Patent number: 5882485Abstract: A process for the separation of dimethyl ether and chloromethane in mixturesA process for the separation of dimethyl ether and chloromethane in mixtures by two distillation steps. In the first step, the mixture is subjected to an extractive distillation with water, aqueous salt solutions or organic liquids as extractant, the top product being chloromethane. In the second step, the dimethyl ether is separated from the extractant.Type: GrantFiled: June 23, 1997Date of Patent: March 16, 1999Assignee: Hoechst AktiengesellschaftInventors: Peter Roth, Erhard Leistner, Hans Haverkamp, Wolfgang Wendel, Michael Kleiber
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Patent number: 5770020Abstract: The invention relates to a distillation apparatus (1) which is suitable in particular for the distillation of sea water into fresh water. The apparatus includes a plurality of flat, bag-like elements (3) formed from a thin film material such as plastic film and placed one against the other, the elements serving as heat exchangers between a vaporizing liquid flowing along the exterior surfaces of the element and a condensing vapor directed to the inside of the element, and a compressor (15) for increasing the pressure and temperature of the generated vapor before it is directed to the inside of the elements. The essential idea of the invention is that at the upper end of each bag-like element (3) there is a honeycomb-structured end strip (4) having substantially the width of the element, the strip containing parallel feeding ducts (26) separated from each other by partition walls, the ducts distributing the liquid to be evaporated over the entire width of the element surface.Type: GrantFiled: November 18, 1996Date of Patent: June 23, 1998Assignee: Keeran Corporation N.V.Inventors: Peter Koistinen, Reijo Rantala
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Patent number: 5670027Abstract: A method of drying a gas making use of the distillation of a liquid desiccant, the method comprising the introduction of a stream of make-up liquid containing water and of an organic solvent miscible with water, the solvent being a more volatile solvent than water under the conditions of the method and forming no azeotropes with water, in an intermediate zone of an elongated vertical contact and fractional distillation zone.Type: GrantFiled: October 16, 1995Date of Patent: September 23, 1997Assignee: TechnipInventor: Henri Paradowski
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Patent number: 5645694Abstract: An improved vapor compression distillation process and apparatus are provided having a container with a substantially horizontal longitudinal center axis, two opposing end plates closing each end of the container, a first and second passage area defined within and on opposing ends of the container, each adjacent one of the end plates, a collecting chamber defined within the container between the first and second passage areas, a plurality of generally horizontal tubes spacedly exposed within the collecting chamber generally parallel to the longitudinal axis of the container, each of the tubes having two opposing ends which open into the first and second passage areas respectively, two opposing plates positioned on opposite ends of the horizontal tubes, each plate engaging similar ends of the horizontal tubes, a vapor compressor attached to the container such that the vapor compressor communicates with an upper area of the collecting chamber and communicates with the first passage area, at least one passage foType: GrantFiled: March 31, 1993Date of Patent: July 8, 1997Assignee: Vacom II, L.P.Inventors: James M. Stewart, Bobby D. Morris
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Patent number: 5622605Abstract: A process and apparatus for desalinating seawater or brine and purifying water which contains minerals, salts, and other dissolved solids while simultaneously generating power. The salinous water is heated in a boiler to form steam and a concentrated brine. The concentrated brine is removed from the boiler, the steam produced in the boiler is washed with fresh water to remove trace salts and inorganic materials, and water bearing trace salts and inorganic materials are returned to the boiler. The washed steam is expanded across a turbine to generate electrical or mechanical power which is utilized as a product. The steam exhausted from the turbine is collected and condensed, and one portion of the condensed water is utilized as a fresh water product and another portion of the condensed water is used as the wash water to wash the steam produced in the boiler. Energy efficiency is improved by heat exchanging the hot concentrated brine against the salinous feed water or by flashing the brine to produce steam.Type: GrantFiled: April 10, 1995Date of Patent: April 22, 1997Inventors: Gary D. Simpson, Karl Lin
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Patent number: 5591310Abstract: An apparatus for distillation of a liquid near or above its critical point wherein the liquid contains a dissolved solid. The apparatus includes a separation section wherein the liquid may be separated into a vapor and a liquid residue separated by a liquid surface. The apparatus includes a pump for pumping liquid into the apparatus so as to establish and maintain the liquid and vapor in the separation section at a desired pressure and a heat source for heating the liquid and vapor so as to establish a rising temperature profile in the separation section. The pump and heat source are cooperatively controllable for regulating the position of the liquid surface so that liquid residue can be discharged from immediately below the liquid surface.Type: GrantFiled: December 8, 1993Date of Patent: January 7, 1997Assignee: Grundfos International A/SInventor: Henrik G. Olrik
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Patent number: 5587054Abstract: A vapor compression distillation system including a boiler/condenser assembly wherein a portion of the condensate is redirected back to the condenser inlet to extract superheat from the compressed vapor and transfer it to the liquid in the boiler. The vapor entering the condenser is reduced to a saturation condition to prevent heat build up in the condenser to improve heat transfer efficiency. When the temperature of the incoming feed water is within the operating range of the boiler/condenser assembly, the system is operated under vacuum sufficient to match the boiler temperature with the temperature of the incoming feed water so that no preheater or waste heat recovery exchanges are required.Type: GrantFiled: October 11, 1994Date of Patent: December 24, 1996Assignee: Grano Environmental CorporationInventor: Robert C. Keith