Abstract: The present invention discloses a saline glycerine wastewater treatment system and technology. The whole technological process mainly includes a reaction process, an evaporation process, a crystallization process, a filtration process and a drying process. The present invention first proposes the use of an “ammonia-alkali reaction principle” to treat high-salt glycerine wastewater, which mainly solves the problem of treating a large amount of calcium chloride-containing glycerine wastewater produced in the production process of propylene oxide and epichlorohydrin in chlor-alkali industry, and places emphasis on solving the problems that low value-added calcium chloride produced in the wastewater treatment process of a traditional method has low quality, is basically accumulated as solid waste and is difficult to treat, and chloride ions have adverse effects on the biochemical process of wastewater treatment.

Abstract: Provided is a particle drying method capable of sufficiently removing the volatile component and down-regulating the increase of the viscosity of the particles after the removal of the volatile component. There is provided a method for producing heterophasic propylene polymerization material particles, the method including: (1) performing monomer polymerization in the presence of a catalyst including a solid catalyst component so as to obtain a component I; (2) performing monomer polymerization in the presence of the component I so as to obtain the component II, so that particles including a volatile component are produced; and (3) causing the particles to contact with an inert gas-containing stream so as to remove the volatile component from the particles.

Abstract: Disclosed are a system for controlling an ethylene vinyl acetate (EVA) copolymerization process and a method of controlling the same. The system for controlling the EVA copolymerization process may include a database for analysis configured to store analysis data obtained by matching processing conditions with measured data for first EVAs produced under the processing conditions, a computer programmed to estimate a VA content with respect to second EVA using the analysis data, a computer programmed to estimate a molecular weight distribution of the second EVA using the VA content estimated in the VA content estimation unit and processing factors corresponding thereto, and a computer programmed to estimate a recovery system blockage phenomenon using the VA content estimated and the molecular weight distribution estimated.

Abstract: The present invention deals with a process of polymerising at least one olefin in a fluidised bed in a fluidised bed polymerisation reactor comprising a top zone, a middle zone in direct contact and below, a bottom zone in direct contact with and below the middle zone and wherein the reactor does not comprise a fluidisation grid. The process comprises passing a stream comprising the fluidisation gas and polymer particles into a separation step and withdrawing a stream comprising the polymer particles from the separation step and returning it to the polymerisation reactor. The process comprises adding a support gas stream to the stream comprising the polymer particles downstream of the separation step.

Abstract: The invention provides systems and methods for the pre-concentration of a target molecule from feed solution comprising a low concentration of the target molecule.

Abstract: The present invention relates to a process for treating polyolefin granules in a treatment vessel comprising the steps of: —Providing a bed of granules in liquid in said treatment vessel —Withdrawing a first stream of liquid from said treatment vessel, wherein said first stream of liquid contains hydrocarboneous compounds —introducing a first stream of vapour into said treatment vessel —Withdrawing a second stream of vapour from said treatment vessel wherein said second stream of vapour contains volatile hydrocarboneous compounds —Recovering the granules from said treatment vessel wherein said first stream of vapour has a temperature from Tb to Tb+10° C., wherein Tb is the boiling point of the liquid at the applied pressure, and said first stream of vapour produces an upwards rising vapour stream in said treatment vessel, the superficial vapour velocity of which is no more than 0.2 m/s, and a plant suitable for conducting said process.

Abstract: An improved water desalination system is disclosed, in which contaminated water such as seawater or brackish water is preheated and fed into a primary pressure vessel through a distribution head. The seawater is distributed from the distribution head over a non-adherent surface such as a plurality of silicone chords hanging below a distribution tank or a cone- and cylindrical-shaped surface. The water is exposed to a high temperature steam environment in the chamber to cause at least a portion of the water in the contaminated water to evaporate, while the remaining concentrated salts from the contaminated water fall to the bottom of the chamber. A portion of the steam in the primary pressure vessel is withdrawn to be condensed into fresh water. The energy withdrawn with the steam extracted from the primary pressure vessel is made up by a supplemental energy apparatus, such as a steam generator.

Abstract: The present invention is directed to an enhanced process for separating dissolved and suspended solids from valuable or harmful liquids and more particularly to improving the operational aspects and separation efficiency of treating certain water miscible fluids including those used for oil and gas processing such as glycols, as well as automobile and aircraft fluids, that have become contaminated with dissolved and/or suspended solid matter.

Abstract: A process for co-manufacture of acrylonitrile and hydrogen cyanide comprises combining a stream comprising hydrogen cyanide and an acrylonitrile reactor product stream, to produce a combined product stream, having a ratio of acrylonitrile to hydrogen cyanide of about 9 to 1 or less, which can be varied; and treating the combined product stream in a recovery/purification system of acrylonitrile process wherein pH is controlled by addition of an acid to prevent HCN polymerization. The ratio of acrylonitrile to hydrogen cyanide is generally between 2 to 1 and 9 to 1. The stream comprising hydrogen cyanide is advantageously a hydrogen cyanide product stream from a hydrogen cyanide synthesis reactor.

Abstract: Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction, which comprises feeding a part of said aqueous stream to a saturator, feeding a part of said aqueous stream to a distillation and/or stripping column, feeding the aqueous stream leaving the head of said distillation and/or stripping column to said saturator. Said process allows at least a part of the aqueous stream coming from the Fischer-Tropsch reaction to be used as process water in the synthesis gas production plant, subsequently sent to the Fischer Tropsch plant for the production of hydrocarbons.

Abstract: The invention relates to a method and a device with the aid of which hydrogen halide and water are removed from biomass hydrolyzates containing halogen acid. The core of the invention is an evacuated container (B1), which is continuously supplied with a heat-transfer medium and which is completely filled with the heat-transfer medium in a part. In said evaporation chamber, the biomass hydrolyzate is likewise continuously introduced. In the container (B1), heat is transferred from the heat-transfer medium to the hydrolyzate, wherein hydrogen halide and water are continuously evaporated. The remaining hydrolyzate particles are continuously discharged with the cooled heat-transfer medium and continuously removed by means of the heat-transfer medium and continuously separated from said heat-transfer medium. The invention described can also be used to treat other mixtures or solutions for the purpose of evaporation.

Abstract: Methods and apparatuses for extractive distillation using internal addition of steam to an extractive distillation column from a reboiler are described herein. The apparatuses include an extractive distillation column, a reboiler (for example, a kettle reboiler) coupled to the extractive distillation column, and a steam input line. The steam input line is coupled to an internal steam sparger device of the reboiler. Methods utilizing the apparatuses to perform extractive distillation of a hydrocarbon feed stream are also described herein.

Abstract: The invention relates to the oil processing industry and can be used for producing vacuum in a vacuum petroleum distillation column. The inventive method involves pumping out a vapor-gas medium from the column by of a gas-gas ejector in such a way that a vapor-gas mixture is formed at the entry thereof and supplying said mixture to a condenser for producing a gas mixture and a vapor phase condensate. The gas mixture is supplied from the condenser to a liquid-gas jet apparatus and the condensate is delivered to an additional separator. A hydrocarbon-containing condensate is removed from the additional separator for the intended use thereof and a water-containing condensate is fed to a steam generator for producing steam by supplying heat of a hot distillate evacuated from the vacuum column. The thus obtained steam is used in the gas-gas ejector as a high-pressure gas.

Abstract: Processes for the recovery of ethanol, useful as a fuel, from various cellulosic feedstock materials fermented to produce ethanol-containing beer are disclosed. The present invention provides a method and a system for ethanol recovery from highly viscous fermented citrus waste biomass. The systems overcome various challenges, including effectively stripping the ethanol from biomass beer in an energy efficient and economical manner that may allow for the further dehydration of the ethanol/water mix in a traditional rectifier distillation column. In certain embodiments, a series of flash stages and beer stripping columns are capable of operating with highly viscous slurries and/or feedstocks containing high levels of solids.

Abstract: The present invention relates to a mixture of ethylenediamine (EDA) and N-methyl-ethylenediamine (Me-EDA) with a low content of Me-EDA, which comprises at least 99.5% by weight of ethylenediamine, and wherein the concentration of N-methylethylenediamine is in the range from 0.005 to 0.15% by weight. The present invention further relates to a process for distillative workup of a mixture comprising EDA, Me-EDA and water, by introducing the mixture into a distillation column which is operated at a column top pressure of 10 mbar to 4 bar, wherein the weight ratio of water to ethylenediamine in the mixture used is a*X:Y where X is the proportion by weight of water and Y is the proportion by weight of ethylenediamine at the azeotropic point of a binary mixture of water and ethylenediamine at the column top pressure in question, and a is a real number with a value of 0.9 or more.

Abstract: An improved water desalination system is disclosed, in which contaminated water such as seawater or brackish water is preheated and fed into a primary pressure vessel through a distribution head. The seawater is distributed from the distribution head over a non-adherent surface such as a plurality of silicone chords hanging below a distribution tank or a cone- and cylindrical-shaped surface. The water is exposed to a high temperature steam environment in the chamber to cause at least a portion of the water in the contaminated water to evaporate, while the remaining concentrated salts from the contaminated water fall to the bottom of the chamber. A portion of the steam in the primary pressure vessel is withdrawn to be condensed into fresh water. The energy withdrawn with the steam extracted from the primary pressure vessel is made up by a supplemental energy apparatus, such as a steam generator.

Abstract: The invention relates to a method for reprocessing waste acid from methods for producing nitro-aromatics, in particular for producing dinitrotoluene (DNT) or trinitrotoluene (TNT), to recover concentrated and purified sulfuric acid and nitric acid, wherein in a first stage, the waste acid is separated in a stripping column countercurrently with water vapor from the bottom of the stripping column into at least one vapor phase, which contains nitric acid and possibly nitro-organics, and a pre-concentrated sulfuric acid, and the vapor phase and the pre-concentrated sulfuric acid are condensed and/or reprocessed in downstream method stages, wherein in the first stage of the method, in addition to the stripping, according to the invention the nitric acid contained in the stripping vapor is concentrated in the presence of additional concentrated sulfuric acid so that nitric acid in a highly concentrated form suitable for feeding back into the nitriding process is obtained directly in the first stage.

Abstract: One exemplary embodiment can be an apparatus for treating a hydrocarbon stream having one or more compounds with a boiling point of about 140° to about 450° C. The apparatus can include an extraction zone and a regeneration zone. The extraction zone can include at least one settler. Each settler can have a height and a length. Typically the length is greater than the height. Also, the settler can form a boot, which can be adapted to receive a feed at one end. The regeneration zone may include a regenerator for an ionic liquid. The regenerator can include a column adapted to provide a regenerated ionic liquid to the extraction zone.

Abstract: The present invention relates to a method of anhydrous ethanol production using circulation by multiple towers' alternation, the procedure includes the steps of heating, adsorption, internal circulation, vacuum suction, washing and resolving etc. The method can prolong the life of adsorbent, reduce the heat exchanger's surface, cooling water, the equipment investment and energy consumption, provide high ethanol recovery rate and high dehydration, and protect environment.

Abstract: A method for purifying used antifreeze is disclosed. An antifreeze recycling systems uses a simple-distillation apparatus adapted to distill clean antifreeze from used antifreeze. A novel scraper blade is used in the simple-distillation apparatus. Also, antifreeze recycling methods that minimize waste and generate nontoxic, landfillable waste are provided. An antifreeze product produced by the present method, and a nontoxic, landfillable sludge product produced by the present method, are disclosed.

Abstract: Provided is a method of purifying hydrochloric acid by removing an organic substance having a boiling point of ?25° C. to 120° C. under atmospheric pressure from a first organic substance-containing hydrochloric acid that contains the organic substance and has a hydrogen chloride concentration higher than an azeotropic hydrogen chloride concentration under atmospheric pressure. The method includes the step of subjecting a second organic substance-containing hydrochloric acid to distillation using a distillation tower under atmospheric pressure, to distill out the organic substance from a top of the distillation tower. The second organic substance-containing hydrochloric acid is obtained by mixing the first organic substance-containing hydrochloric acid and water or dilute hydrochloric acid and has the hydrogen chloride concentration lower than the azeotropic hydrogen chloride concentration under atmospheric pressure.

Abstract: The invention relates to a device and method for preparing liquid from solid materials such as medicinal materials. It includes liquid and materials for preparing the liquid at the beginning and the end of the process. The device uses a steam generator, an intermediate switch valve and a material chamber, which are connected sequentially with pipes, and further includes an outlet pipe, which is at the bottom of the material chamber. The method involves the steps of: distillation and absorption; immersion; and repetition. The device and method for preparing liquid alternates the distillation and immersion steps, which reduces harmful substance in the prepared liquid that would otherwise occur by conventional methods. The method not only extracts soluble effective matter, but also reduces loss of volatile effective matter. Ultimately, the method makes the steps for preparing liquid simple and clear, and it can prepare liquid quantitatively, effectively and without pasty and shrinkable characteristics.

Abstract: A distillation process for separating a target component from a mixture containing a solvent and the target includes the steps of flashing off a vapor mixture of said solvent and said target in an evaporator, separating said target from said vapor mixture, and providing additional solvent to said evaporator to maintain the temperature of said evaporator substantially below the boiling point of said target. The process also includes the step of removing accumulated non-volatile components from said evaporator by allowing the non-volatile components to precipitate from a mixture of the target and the solvent.

Abstract: A method and apparatus for treating for disposal oil contaminated substrates, such as drill cuttings from drilling with an oil-based mud, by steam distillation. If necessary, the contaminated substrate 10 can be pretreated with an emulsion breaker 14. The contaminated substrate 10 can be treated with steam 16 in a first mixing still 12. The substrate can be optionally treated with a second steam source 20 in a second mixing still 18. The steam provides heat to vaporize the oil, moisture to treat the substrate and water to the reaction mixture. Recoverable constituents in the vapor can be condensed in a vapor collection system 24. The treated substrate 22 is essentially free of oil and can have a controlled water content. The process exhibits low energy consumption, rapid treatment, compact equipment and a high degree of process control.

Abstract: A method of separating propylene oxide from a mixture (M) comprising propylene oxide and methanol, said method comprising: (i) introducing said mixture (M) into an extractive distillation column; (ii) additionally introducing an extracting solvent into said extractive distillation column; (iii) distilling propylene oxide overhead from said extractive distillation column as top stream; (iv) withdrawing a bottoms stream from said extractive distillation column; (v) compressing the top stream obtained overhead in (iii) by means of at least one compressor to give a compressed vapor.

Abstract: A process of separating a purified propylene oxide from a crude epoxidation product produced, preferably, in an epoxidation reaction of propylene with hydrogen peroxide. The process involves removing bulk water, bulk methanol, and unreacted propylene from the crude epoxidation product and thereafter subjecting the resulting propylene oxide product to extractive distillation with water as an extraction solvent. Under distillation conditions, including a bottoms temperature of greater than about 55° C. and less than about 75° C., an overhead or side-cut distillate stream containing a purified propylene oxide is obtained with low yield loss of propylene oxide to propylene glycols and other glycol heavies. The purified propylene oxide can be further purified in a finishing distillation to obtain propylene oxide meeting commercial grade purity requirements.

Abstract: A sulfur-bearing residue treatment system is provided for the recovery of valuable organic components and the reduction of capital costs and operating costs. The treatment system involves the use of a stripping vessel in conjunction with a heating apparatus. All elements of the treatment system may be coupled together to form one integral piece of equipment.

Abstract: A method for collecting acrylic acid is provided, which includes the step of collecting acrylic acid using an aqueous medium from a reaction gas containing acrylic acid obtained by catalytic vapor-phase oxidation of propane, propylene, and/or acrolein, the step being conducted so as to satisfy the following formula (1) (B/A)<1.25 (1) wherein A represents a weight fraction of acrylic acid to all condensable ingredients in the reaction gas before collecting acrylic acid and B represents a weight fraction of acrylic acid in bottoms of a collection device used in the step of collecting. According to the method, acrylic acid can be efficiently collected from the reaction gas containing acrylic acid obtained by catalytic vapor-phase oxidation.

Abstract: In accordance with the invention, propylene oxide is formed by reaction of propylene and hydrogen peroxide or by reaction of propylene, oxygen and hydrogen in methanol solvent, methanol and methyl formate are separated from propylene oxide by extractive distillation wherein the aqueous bottoms from methanol recovery distillation is used as extractive distillation solvent after first having been neutralized.

Abstract: Process and installation for extracting a monomer from an aqueous broth of a polymer, in which, after the broth has been heated, the broth is subjected to a depressurization in a depressurization chamber and is then introduced into a vertical column, divided into several chambers, on which are superimposed perforated plates, where the broth is flushed with an ascending stream of inert gas.

Abstract: A process is provided for the distillative separation of pentene nitrile isomers which have a relative volatility alpha ranging from 1.0 to 1.3 in the pressure range from 1 to 500 kPa, wherein the distillation is carried out in the presence of a liquid diluent which forms with the pentene nitrile isomers, under the same pressure conditions, azeotropes whose relative volatility alpha is higher than that of the pentene nitrile isomers to be separated.

Abstract: A process of treating waste solvent acetonitrile streams which contain at least one water extractable impurity such as isopropyl acetate to remove substantially all of the impurity by distilling the waste solvent acetonitrile in the presence of water for a time sufficient to allow the water extractable impurity to be extractively distilled from the acetonitrile. In preferred embodiments of the present invention the feed may contain either a mixture of waste solvent acetonitrile and crude acetonitrile or crude acetonitrile free of hydrogen cyanide by itself.

Abstract: This invention is directed to a method of removing dimethyl ether from an olefin stream. Dimethyl ether is removed from the olefin stream by first separating the olefin stream into a first stream comprising dimethyl ether and lighter boiling point compounds, and a second stream comprising C4+ olefin and higher boiling point hydrocarbons. The dimethyl ether is then separated from the first stream using extractive distillation.

Abstract: A process for cleaning apparatus in which (meth)acrylic acid-containing organic solvents have been treated and/or generated and contain fouling and/or polymer and residues of organic solvent, in which the apparatus contents are subjected to a steam distillation in the apparatus.

Abstract: Methods of recovering free fatty acids having a low ester content from alkanol-containing solutions and oil mixtures containing tocopherols are disclosed which involve atmospheric or vacuum stripping at low temperatures. The recovered fatty acids have a high acid value, and have high commercial value in the production of high quality (high acid value) products, e.g., dimerized fatty acids, useful in polyamide resins.

Abstract: A method and apparatus for isolation of a barely volatile organic compound in a sample suspected to contain the same, e.g. a dioxin, which includes continuously adding superheated steam and a volatile and hardly water-soluble/water-insoluble solvent to a liquid or solid sample suspected to contain said organic compound to be isolated, a solid sample being dissolved in said solvent which can dissolve said organic compound to be isolated, distilling off an azeotropic mixture of said organic compound and said solvent by steam distillation, separating a solvent phase of said solvent dissolving said organic compound and said water phase, and recovering quantitatively said organic compound from said solvent. The dioxins are then further subjected to analysis, for example, GC, HRGC-MS and the like.

Abstract: A process for separating hydrogen chloride from a mixture including an N-(C1-C18)-alkyl-2-pyrrolidone and hydrogen chloride by distilling the mixture including an N-(C1-C18)-alkyl-2-pyrrolidone and hydrogen chloride at from 100 to 220° C. and from 50 to 850 hPa in the presence of water in a distillation column, condensing the water as water-hydrogen chloride azeotrope at the top by cooling, returning the water-hydrogen chloride azeotrope to the distillation column, separating off gaseous hydrogen chloride at the top and taking off the N-(C1-C18)-alkyl-2-pyrrolidone from the bottom.

Abstract: A distillation procedure is provided for the separation of impurities from organic materials such as glycols and glycol ethers whereby a liquid stripping component is interfaced into a distillation column with or below the organic material introduction, heat being provided by a reboiler, the stripping component and impurities being removed overhead.

Abstract: A process for pretreating a oily/water stream for closed loop dilution steam production within an ethylene plant using countercurrent multi-stage extraction to remove both free and dissolved organic solutes from in-situ (net) quench water with an organic solvent to yield an aqueous raffinate containing only residual amounts of organic solute. The raffinate is steam stripped to remove the residual organic solutes, yielding a pretreated quench water stream substantially free of organic material. The pretreated quench water is suitable for reuse to generate dilution steam (without fouling). The (solvent) extract from extraction is regenerated in a solvent regenerator having an overhead stream for purging light ends, a bottom stream for purging heavy ends, and a heart-cut side stream for recycling solvent to the extractor.

Abstract: A process for separating water from methanol in an aqueous methanol initial mixture, comprising subjecting said mixture to azeotropic distillation in the presence of sufficient added methyl acrylate to form an azeotrope with most of the methanol in said initial mixture such that a substantial proportion of methanol in the initial mixture is removed as an azeotrope of methanol and methyl acrylate in the overhead vapors resulting from said distillation and a major proportion of water in said initial mixture is removed in the liquid residue of said distillation.

Abstract: A process for producing methylal that involves feeding a liquid containing methanol, formaldehyde and water to an uppermost reactor of at least four solid acid catalyst-filled reactors which are each externally connected to an intermediate portion of a distillation column; and forcibly circulating a liquid containing methanol, formaldehyde, water and produced methylal in a temperature range of 80° C. to 100° C.

Abstract: The present invention provides a distillation separation method whereby tertiary butyl acetate is separated by distillation as an overhead stream from a bottoms acetic acid stream with the proviso that water is incorporated in the system such that the bottoms acetic acid stream contains water in amount of 0.1 to 5 wt %.

Abstract: The preparation of polyamides, their oligomers or mixtures thereof, where appropriate with other reaction products, takes place by reacting amino nitrites (A) and, where appropriate, other polyamide-forming monomers and/or oligomers with water (D) in a reactive distillation, wherein the reaction product (P) is discharged from the bottom of the reactive distillation apparatus, and ammonia (N) which is produced and, where appropriate, other low molecular weight compounds which are produced, and water, are taken off overhead.

Abstract: The present invention relates to a process for separating hydrogen chloride from a mixture comprising an N-(C1-C18)-alkyl-2-pyrrolidone and hydrogen chloride by distilling the mixture comprising an N-(C1-C18)-alkyl-2-pyrrolidone and hydrogen chloride at from 100 to 220° C. and from 50 to 850 hPa in the presence of water by means of a distillation column, condensing the water as water-hydrogen chloride azeotrope at the top by cooling, returning the water-hydrogen chloride azeotrope to the distillation column, separating off gaseous hydrogen chloride at the top and taking off the N-(C1-C18)-alkyl-2-pyrrolidone from the bottom.

Abstract: A distillation procedure is provided for the separation of impurities from organic materials such as glycols and glycol ethers whereby a liquid stripping component is interfaced into a distillation column with or below the organic material introduction, heat being provided by a reboiler, the stripping component and impurities being removed overhead.

Abstract: An apparatus and a method for removing residual monomers from a slurry containing a polyvinyl chloride. The apparatus has a cylindrical tower with plural perforated plates provided in a vertical direction in the tower, plural chambers formed on the perforated plates serving as their bottom surface, slurry introducing portions provided at two or more of the chambers, flow-down sections provided between the perforated plates to allow the slurry to sequentially flow down from the perforated plate of an upper chamber to the perforated plate of a lower chamber, a steam introducing port at a bottom portion of the tower, a deaerating port at a top portion of the tower, a slurry discharging port at a chamber below a chamber having the slurry introducing port, and hot water ejectors directly under the perforated plates directed at least toward the lower surface of the perforated plates.

Abstract: A process for concentrating spent sulphuric acids particularly sulphuric acids which arise during the nitration of hydrocarbons with nitric acid in the presence of sulphuric acid, wherein single- or multi-stage concentration is effected under vacuum.

Abstract: A distillation procedure is provided for the separation of impurities from organic materials such as glycols and glycol ethers whereby a liquid stripping component is interfaced into a distillation column with or below the organic material introduction, heat being provided by a reboiler, the stripping component and impurities being removed overhead.

Abstract: A procedure is provided for the separation of close boiling impurities from products which have slightly higher polarity than the impurities, for example, separation of di-propylene glycol di-tert-butyl ether (DE) from di-propylene glycol mono-tert-butyl ether (DPTB) by distillation, water or steam being used as stripping component with heat provided by a reboiler.

Abstract: A process for working up crude, liquid vinyl acetate feed containing acetic acid, water and ethyl acetate and optionally smaller amounts of other impurities by distillation, wherein there is introduced into the distillation column, above the feed point of the crude, liquid vinyl acetate, 0.1 to 5% by weight of water, based on the crude, liquid vinyl acetate feed, and 0.1 to 60% by weight of acetic acid, based on the crude, liquid vinyl acetate feed.