Copper And Zinc Electrically Coupled Or Alloyed Into One Or More Electrodes Patents (Class 204/196.22)
  • Patent number: 8372251
    Abstract: According to various embodiments, a system includes a gasifier that includes a shell made of a first material exposed to a gasification region inside the gasifier and a patterned anode layer coupled to the shell inside the gasifier. The patterned anode layer is made of a second material, and the patterned anode layer is configured to protect the shell from corrosion by condensing hot gas in the gasification region.
    Type: Grant
    Filed: May 21, 2010
    Date of Patent: February 12, 2013
    Assignee: General Electric Company
    Inventors: George Albert Goller, Paul Stephen Dimascio, Rebecca Evelyn Hefner
  • Patent number: 8372260
    Abstract: A marine drive cathodic protection control circuit and method controls ohmic current from a power source to an anode according to electrical reference potential sensed by a reference electrode. The ohmic current is interrupted for an interruption interval, and reference potential is sensed during the interruption interval. The ohmic current is controlled according to reference potential sensed during the interruption interval.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: February 12, 2013
    Assignee: Brunswick Corporation
    Inventors: Richard E. Staerzl, Michael M. Blackwood
  • Patent number: 8268134
    Abstract: According to various embodiments, a system includes a turbine engine component that includes a first material having a surface exposed to a fluid flow path and a sacrificial anode layer disposed on the surface. The sacrificial anode layer includes a second material that is electrochemically more active than the first material and the second material is configured to preferentially corrode to protect the first material from corrosion.
    Type: Grant
    Filed: May 21, 2010
    Date of Patent: September 18, 2012
    Assignee: General Electric Company
    Inventors: George Albert Goller, Paul Stephen Dimascio, Rebecca Evelyn Hefner
  • Patent number: 8157983
    Abstract: The galvanic cathodic protection of steel embedded in concrete structures is enhanced by the utilization of a flexible composite anode assembly containing a sacrificial anode member. The anode member is at least partially covered by a matrix comprising an ionically-conductive material. The conductive material includes at least one electrochemical activating agent such as a mixture of lithium bromide and lithium nitrate and a compressible water-retaining mineral such as a phyllosilicate mineral. The presence of this mineral in the matrix increases the current delivered by the anode, thereby resulting in a greater level of cathodic protection, and a longer effective service life of the anode. Exfoliated vermiculite is a preferred phyllosilicate mineral and is present in an amount of between about 2% and about 15% by weight, based on the total weight of the matrix.
    Type: Grant
    Filed: February 25, 2008
    Date of Patent: April 17, 2012
    Inventor: John E. Bennett
  • Patent number: 7909982
    Abstract: A single anode system used in multiple electrochemical treatments to control steel corrosion in concrete comprises a sacrificial metal that is capable of supporting high impressed anode current densities with an impressed current anode connection detail and a porous embedding material containing an electrolyte. Initially current is driven from the sacrificial metal [1] to the steel [10] using a power source [5] converting oxygen and water [14] into hydroxyl ions [15] on the steel and drawing chloride ions [16] into the porous material [2] around the anode such that corroding sites are moved from the steel to the anode restoring steel passivity and activating the anode. Cathodic prevention is then applied. This is preferably sacrificial cathodic prevention that is applied by disconnecting the power source and connecting the activated sacrificial anode directly to the steel.
    Type: Grant
    Filed: March 14, 2006
    Date of Patent: March 22, 2011
    Inventors: Gareth Glass, Adrian Roberts, Nigel Davison
  • Patent number: 7749362
    Abstract: A method of protecting steel in concrete is disclosed. It consists of connecting the steel (6) to a discrete sacrificial anode assembly (7) comprising a base metal (1), a relatively small quantity of catalytic activating agent in contact with the base metal and a substantially inert porous layer (3) that surrounds the base metal and catalytic activating agent. The inert porous layer efficiently maintains a sustainable concentration gradient of the catalytic activating agent between the base metal and the surrounding environment as a result of the electric field across this layer. The preferred porous layer comprises a material that exhibits a net repulsion of negative ions from its pore system and the preferred catalytic activating agent comprises doubly charged sulphate ions as small electric fields maintain very high concentration gradients of these ions resulting in high concentrations at the base metal surface and insignificant concentrations at the assembly periphery.
    Type: Grant
    Filed: October 17, 2005
    Date of Patent: July 6, 2010
    Inventors: Gareth Glass, Adrian Roberts
  • Patent number: 7585397
    Abstract: A novel cathodic protection system is provided that automatically controls and adjusts the voltage potential between an anode and a structure to protect the structure from corrosion. The cathodic protection system is self-powered, requiring no external power source or batteries. A cathodic protection circuit is configured to provide a cathodic protection current from the anode to the structure through an electrolyte. A power generation circuit is configured to generate power from a galvanic cell formed from the anode and an isolated electrode when cathodic protection is interrupted. A voltage potential control circuit is powered by the power generation circuit and is configured to (a) determine a structure-to-electrolyte reference voltage for the electrolyte and structure, and (b) adjust the cathodic protection current from the anode to the structure to maintain the reference voltage substantially the same as a set voltage.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: September 8, 2009
    Assignee: Farwest Corrosion Control Company
    Inventor: John C. Bollinger
  • Patent number: 7422665
    Abstract: An anode for use in cathodic protection of steel in concrete is formed from an electrically conductive material such as zinc and an ionically conductive material which is preferably a humectant and/or has a pH greater than 12 to enhance current flow. The materials are intimately intermixed through at least a part of the anode body and compressed into the anode body with an electrical connecting lead formed into a core of the body which is wholly conductive material. Portions of the electrically conductive material are pressed into electrical contact to form a plurality of electrically conductive paths within the anode body. Many of the voids in the body are interconnected to form a plurality of ionically conductive paths through the anode body by causing the humectant to migrate through the voids. The large surface area between the ionically conductive paths and the electrically conductive paths increase significantly the contact surface area of the anode body to increase current flow.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: September 9, 2008
    Inventor: David Whitmore
  • Patent number: 7402233
    Abstract: A cathodic protection system is provided for cathodically protecting an metallic substrate against corrosion, where the system comprises a sacrificial anodic material containing, but not limited to, zinc, magnesium, aluminum or a mixture of these materials, with a ceramic magnet, coupled with a plug, embedded into the sacrificial anode in such a way as to take advantage of the magnetic flux for transfer of electrons from the sacrificial anode to the object being protected, the unit is affixed to the object being protected by use of an electrically-conductive adhesive. The electrical connection may be established via the combination of the ceramic magnet and the electrically-conductive adhesive. The magnet may be magnetized in the direction of its thickness.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: July 22, 2008
    Inventor: Glen E. Morgan
  • Patent number: 7264697
    Abstract: A sacrificial marine anode with a water proof encased current tester to alert an operator of proper connectivity, current status of the cathodic protection system for an associated marine structure, and status of current tester power supply is disclosed.
    Type: Grant
    Filed: September 24, 2004
    Date of Patent: September 4, 2007
    Assignee: California Corrosion Concepts, Inc.
    Inventors: Mohammed Ali, J. Darby Howard, Jr., Chris Lisson
  • Publication number: 20040134795
    Abstract: This invention pertains to the protection of metals from corrosion and/or fouling from exposure to environments such as, for example, seawater. The protection in accordance with this invention is achieved through the use of conductive zinc-containing coatings in combination with applied current cathodic protection.
    Type: Application
    Filed: July 23, 2003
    Publication date: July 15, 2004
    Inventors: Daniel R. Demarco, Basil V. Gregorovich, Robert C. Nahas, Shi Hua Zhang
  • Publication number: 20020023848
    Abstract: Cathodic protection of a structure including a steel member at least partly buried in a covering layer, such as steel rebar in a concrete structure, is provided by embedding sacrificial anodes into the concrete layer at spaced positions over the layer and connecting the anodes to the rebar. Each anode is inserted into a drilled hole in the layer and is electrically attached to the rebar in the same or an adjacent hole by a steel pin which is attached to the reinforcement by arc welding or by impact. In the arrangement where the anode and the attachment are in the same hole, the pin passes into or through the anode so as to hold the anode rigidly within the hole. The hole is filled by a settable filler material.
    Type: Application
    Filed: July 24, 2001
    Publication date: February 28, 2002
    Inventor: David Whitmore
  • Patent number: 6331242
    Abstract: Corrosible metallic elements of tank are protected by an anodic encasement sleeve. The anodic encasement sleeve employs an inner sacrificial anodic layer and an outer environmental barrier layer to provide both cathodic and barrier protection against corrosion. Following application of the sleeve, typically by drawing or wrapping, the anodic encasement sleeve remains substantially unbonded from the tank, though it is electrically connected by conductive means. Because of the substantially unbonded relationship between the sacrificial anodic layer and the metallic elements of the tank, if electrolyte is present under the environmental barrier (due to breaches, installation error, condensation, etc.), the electrolyte may enter the unbonded area between the tank and the anodic material. This increases the ratio of anodic material to tank available, which makes the cathodic protection more efficient and effective for an extended duration.
    Type: Grant
    Filed: June 21, 2000
    Date of Patent: December 18, 2001
    Assignee: United States Pipe and Foundry Company, Inc.
    Inventor: A. Michael Horton
  • Patent number: 6200397
    Abstract: A novel method and apparatus to apply a corrosion protection in the form of a zinc (or other sacrificial anodic material) tape to a tubular member such as pipe or coiled tubing to used as an underground or underwater pipeline or flow line is disclosed. The zinc tape is applied with sufficient heat and pressure to form a metallurgical bond between the zinc tape and underlying metal pipe. This allows the zinc tape to act simultaneously as a continuous protective metal barrier to the normal scrapes and nicks the pipe experiences during installation and as a sacrificial anode. The novel apparatus preheats the zinc tape with a nozzle containing heated gas such as nitrogen as it approaches the pipe surface. At the point of contact with the pipe surface, the nozzle continues heating the tape and pipe surface while a plurality of pressure rollers exert sufficient force on the zinc tape to form a metallurgical bond between the zinc tape and the pipe surface.
    Type: Grant
    Filed: November 8, 1999
    Date of Patent: March 13, 2001
    Inventor: John R. Allen
  • Patent number: 6193857
    Abstract: Cathodic protection of concrete-reinforcing steel reinforcing elements is accomplished utilizing an anode of a metal (e.g. zinc) having a more negative electrical potential than the steel reinforcing element, and connecting at least one wire made of a ductile metal to the anode. The anode may be cast around the wire, or a twisted portion of two or more wires. The wires are wrapped around one or more of the reinforcing elements and electrically and physically connect the anode to the reinforcing elements. The cathodic protection is maintained over a sustained period of time by casting a cementitious material around the anode, e.g. a mortar containing an electrolyte solution having a pH of at least about 14 when the anode is zinc.
    Type: Grant
    Filed: May 6, 1999
    Date of Patent: February 27, 2001
    Assignee: Foseco International Limited
    Inventors: Nigel Davison, Christopher D. Gorrill