Thermal Effect Compensating Means Patents (Class 204/247.5)
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Patent number: 10889906Abstract: An aluminum reduction cell having a shell structure with a pair of longitudinally extending sidewalls, a pair of transversely extending endwalls, a bottom wall, and an open top having an upper edge. The aluminum reduction cell also has a transverse support structure with transverse bottom beams located under the shell structure and extending transversely between the sidewalls, each of the transverse bottom beams having a pair of opposed ends. The aluminium reduction cell also has compliant binding elements fixed to the transverse support structure, each extending vertically along an outer surface of one of the sidewalls for applying an inwardly directed force said sidewall. The compliant binding elements are in the form of cantilever springs. Each spring has a metal member with a lower end which is secured to the transverse support structure, and a compliant, upper free end which is movable inwardly and outwardly in response to expansion and contraction of the shell structure.Type: GrantFiled: November 20, 2015Date of Patent: January 12, 2021Assignee: Hatch Ltd.Inventors: Daniel Richard, Dale Pearen, John Andrew Ferguson Shaw, Bert O. Wasmund, Maciej Urban Jastrzebski
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Patent number: 9957627Abstract: Broadly, the present disclosure relates to sidewall features (e.g. inner sidewall or hot face) of an electrolysis cell, which protect the sidewall from the electrolytic bath while the cell is in operation (e.g. producing metal in the electrolytic cell).Type: GrantFiled: September 8, 2015Date of Patent: May 1, 2018Assignee: Alcoa USA Corp.Inventors: Xinghua Liu, Robert A. DiMilia, Joseph M. Dynys, Jeffrey S. Martello
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Patent number: 9850586Abstract: The invention provides a lining for an aluminium electrolyzer having inert anodes and is enclosed in a cathode casing comprising a bottom formed from taller blocks having projections and shorter bottom blocks. The shorter bottom blocks are mounted at the ends of the bottom of the cathode device. The shorter bottom blocks alternate with the taller bottom blocks having projections. Vertical channels are provided in the projections of the blocks over the entire thickness of the block for the mounting of conductive elements formed from aluminium and are attached in the lower part to a current-carrying collector that is in the form of a plate which extends out of the ends of the bottom blocks and through the longitudinal sides of the cathode casing.Type: GrantFiled: November 13, 2012Date of Patent: December 26, 2017Assignee: UNITED COMPANY RUSAL ENGINEERING AND TECHNOLOGY CENTRE LLCInventors: Aleksandr Olegovich Gusev, Aleksey Gennad'evich Burtsev, Sergey Vladimirovich Skuratov, Vyacheslav Georgievich Grigor'ev, Sergey Viktorovich Tepikin, Aleksandr Victorovich Ermakov, Boris Sergeevich Efremov, Yuriy Vasil'evich Shemet
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Patent number: 9340887Abstract: Broadly, the present disclosure relates to sidewall features (e.g. inner sidewall or hot face) of an electrolysis cell, which protect the sidewall from the electrolytic bath while the cell is in operation (e.g. producing metal in the electrolytic cell).Type: GrantFiled: March 12, 2014Date of Patent: May 17, 2016Assignee: Alcoa, Inc.Inventors: Xinghua Liu, Robert A. DiMilia, Joseph M. Dynys, Jeffrey S. Martello
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Patent number: 8440059Abstract: The invention relates to an electrolytic cell for obtaining aluminum, including a pot shell, at least one cathode block arranged at least partially in the pot shell, at least one anode suspended above the cell and dipping into the upper portion of the electrolytic cell, and an insulation at least partially covering the internal surface of the pot shell and located between the cathode block and the pot shell, the pot shell and the elements that it contains delimiting a crucible intended to receive an electrolytic bath in contact with the cathode block, characterized in that the insulation is at least partially made of carbon-based blocks having a heat conductivity lower than 1 W/m/K.Type: GrantFiled: April 25, 2007Date of Patent: May 14, 2013Assignee: Carbone SavoieInventor: Jean-Michel Dreyfus
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Patent number: 8425112Abstract: A measuring device is provided having a protective cover and a sensor arranged in the protective cover. The protective cover has a carrier tube made of metal and closed on one end. A first coating made of an aluminum non-wettable material is arranged on an outer surface of the carrier tube, and a further coating made of aluminum-wettable material is applied on the first coating.Type: GrantFiled: May 28, 2009Date of Patent: April 23, 2013Assignee: Heraeus Electro-Nite International N.V.Inventors: Paul Verstreken, Jozef Theodoor Aegten
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Patent number: 8419908Abstract: It is a task of the present invention to provide an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt, the electrolytic apparatus being advantageous in that the electrolysis can be performed without the occurrence of the anode effect even at a high current density and without the occurrence of an anodic dissolution. In the present invention, this task has been accomplished by an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt at an applied current density of from 1 to 1,000 A/dm2, the electrolytic apparatus using a conductive diamond-coated electrode as an anode.Type: GrantFiled: February 14, 2012Date of Patent: April 16, 2013Assignee: Toyo Tanso Co., Ltd.Inventors: Tetsuro Tojo, Jiro Hiraiwa, Hitoshi Takebayashi, Masashi Kodama
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Patent number: 8303795Abstract: In the method and system, a number of electrolytic cells are arranged as a cell group, which cells are separated by a number of partition walls; in each cell, a number of anodes and cathodes are arranged in an alternating order, so that in each cell, next to each anode, there is arranged a cathode, and so that in each cell, each individual anode is fitted in the same anode line with the anode of the adjacent cell, and in each cell, each individual cathode is fitted in the same cathode line with the cathode of the adjacent cell, and each anode is galvanically connected to at least one cathode of the adjacent cell. The flowing direction of the current passing in the cell group is deviated in different directions in order to make the current flow mainly in the direction of the cell group.Type: GrantFiled: June 5, 2009Date of Patent: November 6, 2012Assignee: Outotec OyjInventors: Henri Virtanen, Olli Jarvinen, Lauri Palmu, Ilkka Laitinen
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Patent number: 8273224Abstract: A collector bar for electrical connection to a busbar system of an electrolytic cell, the collector bar being received within a recess in a cathode block of the cathode of the electrolytic cell; wherein the collector bar comprises a first conductor which electrically connects to the busbar system, the first conductor having an external surface or surfaces which electrically contact the cathode block and at least one second conductor having a lower electrical resistance to the first conductor, the second conductor being positioned on at least one external surface of the first conductor in electrical contact with the first conductor.Type: GrantFiled: October 29, 2008Date of Patent: September 25, 2012Assignee: BHP Billiton Innovation Pty LtdInventors: Ingo Bayer, Bruce Ringsby Olmstead
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Patent number: 8206560Abstract: Disclosed is an aluminum electrolytic cell having profiled cathode carbon blocks structures, comprising a cell case, a refractory material installed on the bottom, an anodes and a cathode. The cathode carbon blocks include a profiled structure having projections on the top surface of the carbon blocks, that is, a plurality of projections are formed on a surface of the cathode carbon blocks. The aluminum electrolytic cell having the cathode structure according to the present invention can reduce the velocity of the flow and the fluctuation of the level of the cathodal molten aluminum within the electrolytic cell, so as to increase the stability of the surface of molten aluminum, reduce the molten lose of the aluminum, increase the current efficiency, reduce the inter electrode distance, and reduce the energy consumption of the production of aluminum by electrolysis.Type: GrantFiled: December 17, 2007Date of Patent: June 26, 2012Assignees: Northeastern University Engineering & Research Institute Co, Ltd., Northeastern University, Shenyang Beiye Metallurgical Technology Co., Ltd.Inventor: Naixiang Feng
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Patent number: 8142623Abstract: It is a task of the present invention to provide an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt, the electrolytic apparatus being advantageous in that the electrolysis can be performed without the occurrence of the anode effect even at a high current density and without the occurrence of an anodic dissolution. In the present invention, this task has been accomplished by an electrolytic apparatus for producing fluorine or nitrogen trifluoride by electrolyzing a hydrogen fluoride-containing molten salt at an applied current density of from 1 to 1,000 A/dm2, the electrolytic apparatus using a conductive diamond-coated electrode as an anode.Type: GrantFiled: May 10, 2007Date of Patent: March 27, 2012Assignee: Toyo Tanso Co., Ltd.Inventors: Tetsuro Tojo, Jiro Hiraiwa, Hitoshi Takebayashi, Masashi Kodama
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Patent number: 7776190Abstract: Cathodes for aluminum electrolysis cells are formed of cathode blocks and current collector bars attached to those blocks. The cathode slots receiving the collector bar are lined with expanded graphite lining thus providing longer useful lifetime of such cathodes and increased cell productivity. The expanded graphite provides a good electrical and thermal conductivity especially with its plane layer.Type: GrantFiled: June 23, 2008Date of Patent: August 17, 2010Assignee: SGL Carbon SEInventors: Frank Hiltmann, Martin Christ, Werner Langer, Oswin Öttinger
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Patent number: 7776191Abstract: Cathodes for aluminum electrolysis cells are formed of cathode blocks and current collector bars attached to those blocks. The cathode block has a cathode slot for receiving the collector bar and has a higher depth at a center than at both lateral edges of the cathode block. Additionally, the collector bar thickness is higher at the center than at both lateral edges of the cathode block. This cathode configuration provides a more even current distribution and, thus, a longer useful lifetime of such cathodes and increases cell productivity.Type: GrantFiled: October 14, 2008Date of Patent: August 17, 2010Assignee: SGL Carbon SEInventors: Frank Hiltmann, Philippe Beghein
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Patent number: 7749363Abstract: A cell for the electrowinning of aluminium by the electrolysis from an aluminium compound dissolved in a molten electrolyte (50), comprises: (I) a plurality of non-carbon anodes (10), each anode being suspended in operating in the molten electrolyte by an anode stem (11) that connects the anode (10) to a positive current source; and (II) a thermic insulating cover (60,60?) which covers the electrolyte (50) and through which each anode stem (11) extends from the positive current source to an anode (10). The insulating cover (60,60?) comprises a plurality of movable sections (60) that together cover a substantial part of the electrolyte (50). Each movable section (60) covers a corresponding portion of the electrolyte (50) that is located therebelow and that can be uncovered by moving the corresponding movable section (60).Type: GrantFiled: June 3, 2003Date of Patent: July 6, 2010Assignee: Moltech Invent SAInventors: Vittorio De Nora, Georges Berclaz
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Patent number: 7699963Abstract: An electrolytic cell for the production of metal by electrolytic reduction of a metal bearing material dissolved in a molten salt bath, the cell including a shell, and a lining on the interior of the shell, the lining including a bottom cathode lining and a side wall lining including a plurality of fluid ducts positioned against the interior surface of the shell for conducting fluid there through, the fluid ducts extending along the sides of the shell, and communicating with pump means to flow fluid through the fluid ducts.Type: GrantFiled: April 5, 2007Date of Patent: April 20, 2010Assignee: BHP Billiton Innovation Pty Ltd.Inventor: Ingo Bayer
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Patent number: 7618519Abstract: This invention relates to a cathode element for use in a pot of an electrolytic cell intended for production of aluminum. The cathode element comprises a cathode block and a steel connection bar. The connection bar includes at least one metal insert, whose electrical conductivity is greater than the electrical conductivity of the said steel. The presence of an insert according to the invention can simultaneously result in a very large drop in the global cathode voltage and a very strong reduction in the current density at the head of the block.Type: GrantFiled: April 1, 2005Date of Patent: November 17, 2009Assignee: Aluminum PechineyInventors: Delphine Bonnafous, Jean-Luc Basquin, Claude Vanvoren
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Patent number: 7527715Abstract: The invention relates to a cooling method of a igneous electrolytic cell for aluminium production wherein heat transfer fluid droplets (or “divided heat transfer fluid”) are produced, preferentially in a confined volume in contact with a specified surface of at least one wall of the shell of the pot of the electrolytic cell, so as to induce the evaporation of all or part of said droplets by contact with said surface and remove the heat from said surface. The invention also relates to a cooling system capable of implementing the cooling method. The invention makes it possible to obtain a high cooling efficiency due to the latent heat of vaporisation of the heat transfer fluid.Type: GrantFiled: July 7, 2003Date of Patent: May 5, 2009Assignee: Aluminum PechineyInventors: Laurent Fiot, Claude Vanvoren, Airy-Pierre Lamaze, Bernard Eygulnent, Jean-Luc Basquin
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Patent number: 7504016Abstract: This invention relates to a method for controlling additions of powder materials into an electrolytic cell designed for the production of aluminium by fused bath electrolysis. The method according to the invention, which can easily be automated, can be used to maintain monitoring of operation of the feed even during anode effects.Type: GrantFiled: September 28, 2004Date of Patent: March 17, 2009Assignee: Aluminum PechineyInventors: Claude Ritter, Benoît Sulmont
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Patent number: 7465379Abstract: An arrangement of one or more structural elements (3) in a cell lining, in particular for use as a side lining in aluminum electrolysis cells (5). The design of and choice of materials for side linings can be fitted in existing electrolysis cells, plus the design and production of the stated material is selected in view of the main purpose of the material, which is to utilize it for the purpose of energy recovery in electrolysis cells. Possible materials for use in the elements and production of these elements are disclosed.Type: GrantFiled: March 12, 2004Date of Patent: December 16, 2008Assignees: Cronus Energy AS, Norsk Hydro ASAInventor: Ole-Jacob Siljan
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Patent number: 7445696Abstract: For an electrolytic cell, an apparatus and method are described that use one or more sensors to measure magnetic field strength about a conductor carrying electrical current. A processor is in electrical communication with the sensors and determines a compensated magnetic field strength based on the magnetic fields of other conductors that also carry electrical current to or from the electrolytic cell. The processor uses this compensated magnetic field strength to determine the cathode electrical current carried by the conductor and to identify open and short circuits between the anodes and cathodes of the cell. The described apparatus and method account for interactions between the magnetic fields of the neighboring cathodes.Type: GrantFiled: March 17, 2005Date of Patent: November 4, 2008Assignee: Kennecott Utah Copper CorporationInventors: Eugene Yanjun You, Antonio Berges-Dreyfous, David B. George, Daniel Kim, Keming Zhou
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Patent number: 7316765Abstract: An apparatus for controlling a molten salt electrolyzer in which an electrolytic bath in a solid form as contained in the electrolyzer is melted to automatically attain a state allowing electrolysis, which apparatus comprises detecting means for detecting the changes in state of the electrolyzer by means of detectors fitted to the electrolyzer, and adjusting means for adjusting, after using the detecting means, the liquid electrolytic bath levels to a state allowing electrolysis.Type: GrantFiled: June 30, 2004Date of Patent: January 8, 2008Assignee: Toyo Tanso Co., Ltd.Inventors: Tetsuro Tojo, Jiro Hiraiwa, Osamu Yoshimoto
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Patent number: 7255783Abstract: Operations in an electrolytic cell for producing aluminum are controlled by sensing infrared radiation on an outer surface of a cell chamber to determine an actual temperature. When the actual temperature is greater than a target temperature, a crust hole is repaired or the actual rate of addition of aluminum fluoride to the cell is increased. When the actual temperature is less than a target temperature, the actual rate of addition of aluminum fluoride to the cell is reduced.Type: GrantFiled: August 21, 2003Date of Patent: August 14, 2007Assignee: Alcoa Inc.Inventors: Jay N. Bruggeman, Michael L. Slaugenhaupt
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Patent number: 6977031Abstract: An anode assembly for conducting electrical energy to an electrolytic smelting cell including an anode of high electrically conductive material connected to a yoke, the ends of the yoke being receivable within anodes, the yoke including a core of highly electrically conductive material and an outer structural sheath extending substantially the length of the yoke, the anode rod being in electrical contact with the core of the yoke and provided with a protective structural collar secured to the outer structural sheath of the yoke. In order for the electrical and thermal contact between the core and sheath to be maintained, the differential coefficient of thermal expansion over the operating temperature range of the assembly is preferably substantially the same or within 4×10?6 m/mk.Type: GrantFiled: August 11, 2000Date of Patent: December 20, 2005Assignee: SRA Technologies Pty Ltd.Inventors: Vjekoslav Jakovac, Vladimir Kanovnik, Drago Juric
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Patent number: 6811677Abstract: The present invention relates to an electrolytic cell for the production of aluminum comprising an anode and an electrolytic tank where the electrolytic tank comprises an outer shell made from steel and carbon blocks in the bottom of the tank forming the cathode of the electrolytic cells. At least a part of the sidewall of the electrolytic tank consists of one or more evaporation cooled panels, and wherein high temperature, heat resistant and heat insulating material is arranged between the evaporation cooled panels and the steel shell. The invention also includes a method for maintaining a crust on the sidewall of the tank and for recovering heat from the cooling medium inside the panel for transformation into electrical energy.Type: GrantFiled: May 16, 2003Date of Patent: November 2, 2004Assignee: Elkem ASAInventors: Jan Arthur Aune, Kai Johansen, Per Olav Nos
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Patent number: 6540887Abstract: A cell for the electrowinning of aluminium comprises at least one non-carbon metal-based anode (10) having an electrically conductive metallic structure (12, 13, 15) which is suspended substantially parallel to a facing cathode (20, 21, 22). Such metallic structure (12, 13, 15) comprises a series of parallel horizontal anode members (15), each having an electrochemically active surface (16) on which during electrolysis oxygen is anodically evolved. The electrochemically active surfaces (16) are in a generally coplanar arrangement to form the active anode surface. The anode members are spaced apart from one another by inter-member gaps forming flow-through openings (17) for the circulation of electrolyte (30) driven by the escape of anodically-evolved oxygen. The electrolyte (30) may circulate upwardly and/or downwardly in the flow-through openings (17) and possibly around the anode structure (12, 13, 15).Type: GrantFiled: July 2, 2001Date of Patent: April 1, 2003Assignee: Moltech Invent SAInventor: Vittorio de Nora
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Publication number: 20030010628Abstract: A cell for the electrowinning of aluminum using anodes (10) made from a alloy of iron with nickel and/or cobalt is arranged to produce aluminum of low contamination and of commercial high grade quality. The cell comprises a cathode (20) of drained configuration and operates at reduced temperature without formation of a crust or ledge of solidified electrolyte. The cell is thermally insulated using an insulating cover (65,65a,65b,65c) and an insulating sidewall lining (71). The molten electrolyte (30) is substantially saturated with alumina, particularly on the electrochemically active anode surface, and with species of at least one major metal present at the surface of the nickel-iron alloy based anodes (10). The cell is preferably operated at reduced temperature from 730° to 910° C. to limit the solubility of these metal species and consequently the contamination of the product aluminum.Type: ApplicationFiled: April 27, 2002Publication date: January 16, 2003Inventors: Vittorio De Nora, Jean-Jacques Duruz
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Patent number: 6447667Abstract: A cermet anode of an electrolytic cell is protected from thermal shock during cell start-up by coating an outer surface portion of the anode with a coating composition comprising carbon or aluminum or a mixture thereof. A particularly preferred coating composition includes an aluminum underlayer adjacent the outer surface portion of the anode, and a carbon overlayer overlying the underlayer. A support structure assembly supporting the cermet anode includes a high alumina ceramic material. In a preferred embodiment, the high alumina ceramic material is protected from thermal shock and corrosion by the coating composition of the invention.Type: GrantFiled: January 18, 2001Date of Patent: September 10, 2002Assignee: Alcoa Inc.Inventors: Calvin Bates, Patricia A. Stewart, Larry F. Wieserman
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Patent number: 6436270Abstract: A method and a device for controlling the movement of a combined alumina feeding and crust breaking chisel in an aluminum production cell, wherein the chisel is moved downwards and upwards by means of a pneumatic cylinder which is alternatively fed with pressurized air, wherein electrical contact between the chisel and the melt is detected when the chisel reaches the melt, wherein it is monitored whether said electrical contact has been reached within a predetermined time interval, and if not, air at a second, high, pressure is fed to said first, and wherein air at high pressure is fed to the second side of the cylinder after said electrical contact has been established so as to quickly withdraw the chisel from the hot melt in order to minimize heat transfer from the melt to the cylinder.Type: GrantFiled: July 19, 1999Date of Patent: August 20, 2002Assignee: AB Rexroth MecmanInventor: Lars-Göran Sander
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Patent number: 6358393Abstract: A cell for the production of aluminium by the electrolysis of an aluminium compound dissolved in a molten electrolyte, in which an outer mechanical structure forming an outer shell (21) houses therein one or more inner electrically-conductive cathode holder shells or plates (31) which contain a cathode mass (32) and is/are connected electrically to the busbar. The cathode mass (32) has an aluminium-wettable top surface (37), preferably at a slope forming a drained cathode. The inner cathode holder shell or shells (31) is/are separated from the outer shell (21) by an electric and thermic insulation (40), the cathode holder shell(s) (31) also serving to distribute current uniformly to the cathode mass (32). The or each cathode (30) formed by the cathode holder shell (31) and cathode mass (32) is removable from the cell as a unit.Type: GrantFiled: March 30, 2000Date of Patent: March 19, 2002Assignee: Moltech Invent S.A.Inventors: Georges Berclaz, Vittorio de Nora
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Patent number: 6251237Abstract: An electrolytic pot for the production of aluminum by the Hall-Héroult electrolysis process includes a cooling device for blowing air with localized jets, advantageously with variable flow, in order to evacuate and dissipate thermal energy from the pot. An aluminum production plant using the Hall-Héroult electrolysis process has at least some pots which, either individually or in common, include at least one cooling device.Type: GrantFiled: November 18, 1999Date of Patent: June 26, 2001Assignee: Aluminium PechineyInventors: Jerome Bos, Benoit Feve, Pierre Homsi