Combined With Diverse-type Separation (e.g., Electro-osmotic Barrier Separation Combined With Centrifugal Separation, Etc.) Patents (Class 204/542)
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Patent number: 11986816Abstract: The present invention relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from clays and minerals, and recycled products.Type: GrantFiled: July 7, 2022Date of Patent: May 21, 2024Assignee: LILAC SOLUTIONS, INC.Inventors: David Henry Snydacker, Nicolás Andrés Grosso Giordano, Amos Indranada, Alysia Lukito, Mustafa Juzer Bootwala, Daniel Keane Laporte, Christina Fleming
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Patent number: 11951467Abstract: The present invention relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from clays and minerals, and recycled products.Type: GrantFiled: July 7, 2022Date of Patent: April 9, 2024Assignee: LILAC SOLUTIONS, INC.Inventors: David Henry Snydacker, Nicolás Andrés Grosso Giordano, Amos Indranada, Alysia Lukito, Mustafa Juzer Bootwala, Daniel Keane Laporte, Christina Fleming
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Patent number: 11920246Abstract: A method for producing one or more hydroxide solids includes providing a catholyte comprising an electrolyte solution; contacting the catholyte with an electroactive mesh cathode to electrolytically generate hydroxide ions, thereby precipitating the one or more hydroxide solid(s); and removing the one or more hydroxide solids from the surface of the mesh where they may deposit.Type: GrantFiled: October 18, 2022Date of Patent: March 5, 2024Assignee: The Regents of the University of CaliforniaInventors: Xin Chen, Erika Callagon La Plante, Gaurav Sant, David Jassby, Dante Adam Simonetti, Thomas Traynor
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Patent number: 11485660Abstract: A method for desalination is provided. An electric potential difference is applied across a saline solution, where a salinity of the saline solution is in a range of 2.5 to 7.8 parts per thousand. The saline solution is separated, using electrodialysis, into a concentrated saline solution and a first diluate. The concentrated saline solution is transferred to a reverse osmosis chamber. The concentrated saline solution is pumped through a partially permeable membrane, thereby removing salt ions from the concentrated saline solution, and creating a second diluate and a brine solution. A pressure of the solution is then increased, using a pressure exchanger, by transferring water pressure from the brine solution to the concentrated saline solution. The first diluate and the second diluate are combined, where a first recovery ratio of the first diluate is greater than a second recovery ratio of the second diluate.Type: GrantFiled: April 19, 2022Date of Patent: November 1, 2022Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALSInventors: Naef A. A. Qasem, Muhammad M. Generous, Syed Mohammad Zubair
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Patent number: 11396469Abstract: The hybrid desalination and energy production system includes a desalination system for separating seawater into purified water and brine, an electrodialysis system for treating the brine and outputting low salinity water, a hypersaline brine solution, and H2 gas; an evaporator for treating the hypersaline brine solution and outputting salt and water vapor; a superheater for treating the water vapor and outputting a superheated water vapor; a turbine for receiving the superheated water vapor to generate energy; a gas scrubber for receiving the H2 gas from the electrodialysis system and producing dry hydrogen; and a hydrogen cell for receiving the dry hydrogen and outputting energy. A condenser converts the vapor into condensate and low salinity water. A desalinated water collection tank receives the desalinated or low salinity water. A pressure retarded osmosis system receives the brine, the low salinity water, and condensate from the condenser to produce dilute brine.Type: GrantFiled: December 29, 2020Date of Patent: July 26, 2022Assignee: KUWAIT UNIVERSITYInventor: Bader Shafaqa Al-Anzi
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Patent number: 10196290Abstract: The invention refers to the electrolytic treatment of olive mill waste water with recovery of the residual oil, removal and valorization of the solids and subsequently to the wet oxidation of oil free waste through electrolytic produced oxidants, the inactivation of the oxidants, the passing of the treated wastewater through activated carbon and their final treatment by the process of reverse osmosis and the recovery of the Sodium Chloride that is recycled, returning in the process of the electrolytic treatment of the oil free olive mill waste water.Type: GrantFiled: March 27, 2014Date of Patent: February 5, 2019Assignee: Androniki VestakiInventor: Androniki Vestaki
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Patent number: 10137385Abstract: A device for extraction of pollutants by multichannel tubular membrane containing at least one fluid channel allowing the fluid to go through a feed inlet to an outlet end characterized in that membrane comprises at least an extraction channel filled with molten salt in order to adsorb said pollutants having to be extracted from the said fluid. Advantageously, the membrane is a ceramic membrane. An application is for the treatment of traces of pollutants in a liquid or gaseous fluid. For example, the removal of small pollutants as volatile organic compounds from an aqueous stream in industrial wastewater treatment or other water treatment applications, or the separation of aromatic compounds form an hydrocarbon feed in petrochemical applications. Another application is in the removal of water traces in products of high added value as pharmaceutical, cosmetic or biocarburant for example.Type: GrantFiled: June 25, 2015Date of Patent: November 27, 2018Assignees: UNIVERSITE D'AIX-MARSEILLE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFInventors: Stephane Anguille, Philippe Moulin, Fabrice Testa
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Patent number: 9476133Abstract: A portable hydrogen and oxygen supply system produces gaseous hydrogen and gaseous oxygen from water. It separates the gasses and vents them into two separate chambers. The supply system creates water disassociation through an array of concentric hexagonal hydrogen collector tubes, anode rods and a cathode matrix, all of which are submersed in water. The anode rods and cathode matrix are supplied DC electrical current. The water separates (disassociates) as atomic hydrogen is drawn to the negatively charged anode rods and the atomic oxygen is drawn to the positively charged cathode matrix. The hydrogen, on its path to the anode, passes through the walls of the hydrogen collector tubes to be collected in the first chamber. The oxygen is unable to pass through the walls of the tubes, and remains outside the tubes to be collected in the second chamber.Type: GrantFiled: March 19, 2014Date of Patent: October 25, 2016Inventor: Brian Daniel Gilman
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Patent number: 8986530Abstract: Embodiments of analysis systems, electrophoresis devices, and associated methods of analysis are described herein. In one embodiment, a method of analyzing a sample containing an electrolyte includes sequentially introducing a leading electrolyte, a sample electrolyte, and a trailing electrolyte into a extraction channel carried by a substrate. The extraction channel has a constriction in cross-sectional area. The method also includes applying an electrical field to separate components of the sample electrolyte into stacks and to concentrate the separated components by forcing the sample electrolyte to migrate through the constriction in the extraction channel. Thereafter, the applied electrical field is removed and the separated and concentrated components of the sample are detected in a detection channel carried by the substrate.Type: GrantFiled: April 12, 2012Date of Patent: March 24, 2015Assignee: Washington State UniversityInventors: Cornelius F. Ivory, Dan M. Leatzow
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Publication number: 20130220815Abstract: A system and method for hardwood pulp liquid hydrolysate conditioning is provided. The system includes a first evaporator, a hydrolysis unit, at least one lignin separation device, a neutralization device, a precipitate removal device, a solvent extraction unit, a lignin removal and recovery unit, an acid and furfural separation and conditioning unit, and an electrodialysis device, which process a quantity of hardwood mix to produce a desalinated solution containing sugar.Type: ApplicationFiled: August 23, 2012Publication date: August 29, 2013Inventors: Darrell M. Waite, Richard Arnold, James St. Pierre, Hernant P. Pendse, William H. Ceckler, Amy Elizabeth Luce, Rino P. Dumont
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Publication number: 20130225787Abstract: A process for the preparation of lactic acid includes: a) providing an aqueous medium comprising magnesium lactate; b) adding to the aqueous medium a monovalent base to form an aqueous medium comprising a water soluble monovalent lactate salt and a solid magnesium base; c) separating the magnesium base from the aqueous medium; d) adjusting the concentration of the monovalent lactate salt in the aqueous medium, e) subjecting the aqueous medium to water-splitting electrodialysis, to produce a first solution comprising monovalent base and a second solution comprising lactic acid and monovalent lactate salt, the electrodialysis being carried out to a partial conversion of 40 to 98 mole %; f) separating the second solution into lactic acid and a solution comprising the monovalent lactate salt by vapour-liquid separation; g) recycling the solution of step f) comprising the monovalent lactate salt to step d).Type: ApplicationFiled: February 8, 2011Publication date: August 29, 2013Applicant: Purac Biochem BVInventors: Peter Johannes Marie Baets, Willem Jacob Groot
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Publication number: 20130224805Abstract: A process and apparatus for converting cellulosic biomass pulp into a sugar solution is provided. The process includes combining a quantity of cellulosic biomass pulp with a quantity of acid and a quantity of enzyme. The combined quantity of cellulosic biomass pulp, enzyme, and acid are placed in an enzymatic hydrolysis reactor having a predetermined temperature range and predetermined pH level, thereby producing a quantity of monomeric sugar solution.Type: ApplicationFiled: August 23, 2012Publication date: August 29, 2013Inventors: Darrell M. Waite, Richard Arnold, James St. Pierre, Rino P. Dumont, James Alan Hargreaves, William H. Ceckler
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Publication number: 20130087501Abstract: In a desalination system, water is treated, for example by reverse osmosis, to produce desalinated product water and a reject stream. Salt from the reject stream is transferred to a flow of low salinity wastewater, such as effluent from a municipal wastewater treatment plant. For example, the reject stream may be fed to the high salinity cell in an electrodialysis (ED) unit. The adjacent low salinity cell receives the low salinity wastewater. The high salinity and low salinity cells are separated by ion exchange membranes. The salty wastewater is discharged, for example to the ocean. The salt-reduced reject stream is treated to extract more product water from it, for example by recycling it to the feed water. Less feed water is needed to produce a given volume of product water. If a thermal desalination unit is combined with divalent ion selective ion exchange membranes, then scaling is reduced.Type: ApplicationFiled: October 6, 2011Publication date: April 11, 2013Applicant: GENERAL ELECTRIC COMPAYInventors: Neil Edwin MOE, John BARBER
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Patent number: 8404093Abstract: An embodiment is a method and apparatus to provide de-ionization. First and second conductive porous membranes are placed between a feed channel having a feed flow and first and second concentration channels having first and second concentration flows to separate the feed channel from the concentration channels. Cathode and anode electrodes are placed on external sides of the concentration channels. A voltage supply distribution network provides independent voltages across the channels to cause movement of ions in the feed and concentration flows toward the electrodes.Type: GrantFiled: December 4, 2008Date of Patent: March 26, 2013Assignee: Palo Alto Research Center IncorporatedInventors: Armin R. Volkel, Meng H. Lean
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Publication number: 20120316368Abstract: A process for the preparation of succinic acid comprising the steps of: a) providing an aqueous medium comprising magnesium succinate by fermentation of a carbohydrate source, in the presence of a magnesium base; b) processing the aqueous medium wherein the magnesium succinate is treated with a monovalent base, prior to or after a crystallisation step, to provide a magnesium base and an aqueous solution comprising a monovalent succinate salt; c) adjusting the concentration of the monovalent succinate salt to between 10 and 35 wt. %; d) subjecting the aqueous solution to water-splitting electrodialysis, to produce a first solution comprising monovalent base and a second solution comprising succinic acid and monovalent succinate salt, the electrodialysis causing conversion of 40 to 95 mole %; e) separating the second solution into succinic acid and the monovalent succinate salt by crystallisation; f) recycling the monovalent succinate salt solution of step e) to step d).Type: ApplicationFiled: February 14, 2011Publication date: December 13, 2012Inventors: Willem Jacob Groot, Jan Van Breugel
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Patent number: 8303814Abstract: A cross-flow filtration system includes a first filter element having a first conduit for receiving a flow of a first aqueous feed stream, a second conduit operable to discharge a flow of first permeate water and a third conduit operable to discharge a flow of first retentate water. The cross-flow filtration system includes a coil assembly disposed about the first conduit. The first coil assembly is operable to subject the first aqueous feed stream to electromagnetic pulses. A second filter element is in fluid communication with the first filter element via the third conduit. The second filter element is operable to receive the first retentate water via the third conduit. A second coil assembly is disposed about the third conduit and is operable to subject the first retentate water to electromagnet pulses.Type: GrantFiled: February 15, 2012Date of Patent: November 6, 2012Assignee: Clearwater Systems CorporationInventor: David Wayne Alley
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Patent number: 8273251Abstract: A fluid feed stream is flowed, subject to electromagnetic pulses, to a filter element via an input feed conduit for the filter element. A coil assembly is disposed about the input feed conduit and an AC power source is connected with the coil assembly. The AC power source has a period including first and second half-cycles of opposing polarities. A switch in series with the coil assembly forms a series connected circuit. A second switch connected with the coil assembly forms a second circuit. A control means closes the first switch and opens the second switch during a first half-cycle of the AC power source. During a second half-cycle, the control means closes and then opens the second switch to produce a first large ringing pulse in the coil assembly. A subsequent pulse may be produced either before or after the first pulse substantially decays.Type: GrantFiled: September 7, 2007Date of Patent: September 25, 2012Assignee: Clearwater Systems CorporationInventor: David Wayne Alley
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Publication number: 20120211366Abstract: The present invention relates to an environmentally friendly, simple and economic process for producing xylose. The process comprises the steps of: a) countercurrently extracting tropical fruit biomass by hydrolysis with sulfuric acid to obtain a high-concentration xylose extract; b) adjusting the extract to a pH of 1.5-2.5 and decolorizing and filtering the pH-adjusted extract; c) desalting the filtrate in an electrodialysis device; and d) recycling a waste sulfuric acid solution recovered from step c), to step a), and concentrating and directly recovering the desalted filtrate to obtain xylose crystals.Type: ApplicationFiled: October 30, 2009Publication date: August 23, 2012Applicant: CJ Cheiljedang CorporationInventors: Joo-hang Lee, Jun-gap An, Seung-won Park, Taek-beom Kim, Seong-bo Kim, Dong-hoon Lee, Woon-hwa Lee, Dae-Ho Son, Seung-bae Ji, Kang-pyo Lee
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Patent number: 8237117Abstract: The present invention relates a use of the electrocapture-based separation technology combined with mass spectrometrical fragmentation methods, e.g. sequence of polypeptides by collision-induce dissociation mass spectrometry, for the identification and/or characterization molecules of interest. It also relates the combination of the electrocapture-base separation technology with other liquid separation methods, as e.g. liquid chromatography, in order to achieve multi-dimensional separations prior mass spectrometrical analysis. In addition, it relates physical interfaces between electrocapture-based separations and different types mass spectrometers for on-line or off-line analysis, as well as the coupling of electrocapture-based separations, liquid chromatography and different types of mass spectrometrometers.Type: GrantFiled: March 1, 2011Date of Patent: August 7, 2012Assignee: PerkinElmer Health Sciences, Inc.Inventor: Juan Astorga-Wells
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Patent number: 8133373Abstract: A continuous electrochemical pump comprising a water generator compartment, an anode compartment on one side of said generator compartment, a cation exchange barrier, separating the generator compartment from the anode compartment, a first electrode in electrical communication with the anode compartment, a cathode compartment adjacent the generator chamber, an anion exchange barrier, separating the generation compartment from the cathode compartment, and a second electrode in electrical communication with the cathode compartment. Use of the pump as a sample concentrator. A feedback loop for the pump. A reservoir, with or without an intermediate piston, on the output side of the pump.Type: GrantFiled: August 15, 2008Date of Patent: March 13, 2012Assignee: Dionex CorporationInventors: Hamish Small, Yan Liu, Christopher A. Pohl
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Publication number: 20110284377Abstract: Systems and methods for removing hydrogen peroxide from water purification systems are provided. In a general embodiment, the present disclosure provides a water purification system including a water treatment unit, an electrodeionization unit and a hydrogen peroxide decomposition catalyst in fluid connection with the electrodeionization unit. The water purification system can be fluidly connected to a renal treatment system.Type: ApplicationFiled: May 18, 2011Publication date: November 24, 2011Applicants: BAXTER HEALTHCARE S.A., BAXTER INTERNATIONAL INC.Inventor: Justin B. Rohde
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Patent number: 8012355Abstract: The present invention discloses a method and apparatus for separating particles and dissolved matter from an untreated fluid stream. Specifically, the present invention includes a first pressure source which transports untreated fluid or contaminated aqueous fluid into a separator annulus with a filter element disposed therein. The untreated fluid is placed under appropriate pressure sufficient to produce turbulent flow, increased particle kinetics and/or cavitation allowing the desired fluid to penetrate and pass into and through the filter media. The treated fluid is then transported to a collection tank. The contaminant matter retained by the filter media may be removed by the nearly instantaneous reverse pressurization of the separator annulus by a second pressure source thereby removing the contaminant particles away from contact with the filter media, and which may then be transported to a waste collection tank or a separator for further treatment.Type: GrantFiled: April 8, 2008Date of Patent: September 6, 2011Assignee: PSS Acquisitionco LLCInventor: Raymond Ford Johnson
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Patent number: 7938956Abstract: The invention relates to a method and a system for purifying water whereby: the water to be purified is pressurized (13); a pressurized flow of said water is directed onto at least one selective permeability membrane to divide (11) the flow of pressurized water into a permeate flow and a retentate flow; the permeate flow is electrodeionized (12) to produce a flow of purified water consisting of the electrodeionized permeate flow; the flowrate of the retentate flow (19) is reduced; a substantially constant predetermined pressure (21) is maintained on the selective permeability membrane(s); and a substantially constant predetermined permeate flowrate is maintained. It also relates to a tangential filtration module suitable for the above kind of system.Type: GrantFiled: February 12, 2010Date of Patent: May 10, 2011Assignee: Millipore CorporationInventor: Yves Gaignet
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Patent number: 7918980Abstract: A flow cell for electrophoretically-assisted capturing analytes from a flow. The flow cell includes a specimen chamber, a first membrane, a second membrane, a first electrode chamber, and a second electrode chamber. The specimen chamber may have a sample inlet and a sample outlet. A first portion of the first membrane may be coupled to a first portion of the specimen chamber. A first portion of the second membrane may be coupled to a second portion of the specimen chamber. The first electrode chamber may be configured to accept a charge. A portion of the first electrode chamber may be coupled to a second portion of the first membrane. A second electrode chamber may be configured to accept an opposite charge. A portion of the second electrode chamber may be coupled to a second portion of the second membrane.Type: GrantFiled: April 5, 2006Date of Patent: April 5, 2011Assignee: George Mason Intellectual Properties, Inc.Inventor: Victor Morozov
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Patent number: 7902500Abstract: The present invention relates a use of the electrocapture-based separation technology combined with mass spectrometry (e.g. sequence of polypeptides by collision-induce dissociation mass spectrometry, for the identification and/or characterization molecules of interest). In addition, it relates physical interfaces between electrocapture-based separations and different types mass spectrometers for on-line analysis, as well as the coupling of electrocapture-based separations, liquid chromatography and different types of mass spectrometrometers. It also relates the combination of the electrocapture-base separation technology with other liquid separation methods, as e.g. liquid chromatography, in order to achieve multidimensional separations prior mass spectrometrical analysis. The invention also relates to a separation device comprising a capture device, a fluidic connector e.g. an electrospray source, an electrospray interface-source and a mass spectrometer.Type: GrantFiled: December 6, 2005Date of Patent: March 8, 2011Assignee: PerkinElmer Health Sciences, Inc.Inventor: Juan Astorga-Wells
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Patent number: 7846340Abstract: A water treatment system provides treated or softened water to a point of use by removing a portion of any hardness-causing species contained in water from a point of entry coming from a water source, such as municipal water, well water, brackish water and water containing foulants. The water treatment system typically treats the water containing at least some undesirable species before delivering the treated water to a point of use. The water treatment system has a reservoir system in line with an electrochemical device. The electrochemical device of the water treatment system is operated at a low current and low flow rate to minimize water splitting or polarization, which minimizes scale formation.Type: GrantFiled: November 13, 2003Date of Patent: December 7, 2010Assignee: Siemens Water Technologies Corp.Inventors: Evgeniya Freydina, Anil D. Jha, Frederick Wilkins, Aytac Sezgi, Reshma Madhusudan
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Patent number: 7731827Abstract: The invention relates to a method for capturing charged molecules of interest traveling in an electrolyte flow stream through an electrically non-conductive channel, comprising at least one anode and at least one cathode individually separated from said channel, but in electrical contact with said flow stream, by a conductive ion selective semi-permeable membrane. Said membrane interferes with the normal migration of ions towards its respective electrode, generating at least two zones of different electric field. Balance between hydrodynamic and electrical forces captures certain ions into the flow stream. it also relates to a device for performing the method.Type: GrantFiled: June 17, 2005Date of Patent: June 8, 2010Assignees: PerkinElmer Health Sciences, Inc., Biomotif AB, Hans JornvallInventors: Juan Astorga-Wells, Sang-Ryoul Park, Harold Swerdlow, Gerald Jesson, Ulf Lindberg, Tomas Bergman, Hans Jornvall, Mats Jonsson
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Publication number: 20100105126Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.Type: ApplicationFiled: December 15, 2009Publication date: April 29, 2010Inventors: Allen B. Wright, Klaus S. Lackner, Ursula Ginster
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Patent number: 7691246Abstract: In one embodiment, a system comprises a filter and at least one electrodeionization (EDI) unit for chemical recovery. The filter is adapted to receive a fluid and to remove a selected chemical element or contaminant from the fluid. The EDI unit is coupled to the filter and adapted to recover a chemical element from the fluid and to separate the recovered chemical element from the fluid.Type: GrantFiled: May 24, 2005Date of Patent: April 6, 2010Assignee: Exergy Technologies CorporationInventor: Fred P. Reinhard
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Publication number: 20090321260Abstract: A liquid or water treatment apparatus comprising one or both of an electrodialysis cell and a cavitation unit. The cavitation unit generates cavitation in the liquid by flow of the liquid into a constriction where cavitation bubbles are formed and then to an outlet where cavitation bubbles implode, and the constriction includes an aperture formed by walls which are long and narrowly spaced in a plane normal to the flow direction. The electrodialysis cell is arranged with an inlet flow path for directing only part of a quantity of water to be treated through the electrodialysis cell, and an outlet flow path for returning a product of the electrodialysis cell to the remainder of the water.Type: ApplicationFiled: September 1, 2009Publication date: December 31, 2009Applicant: OceanSaver ASInventor: Aage Bjørn ANDERSEN
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Patent number: 7407585Abstract: The invention relates to a method and a system for purifying water whereby: the water to be purified is pressurized (13); a pressurized flow of said water is directed onto at least one selective permeability membrane to divide (11) the flow of pressurized water into a permeate flow and a retentate flow; the permeate flow is electrodeionized (12) to produce a flow of purified water consisting of the electrodeionized permeate flow; the flowrate of the retentate flow (19) is reduced; a substantially constant predetermined pressure (21) is maintained on the selective permeability membrane(s); and a substantially constant predetermined permeate flowrate is maintained. It also relates to a tangential filtration module suitable for the above kind of system.Type: GrantFiled: March 4, 2004Date of Patent: August 5, 2008Assignee: Millipore CorporationInventor: Yves Gaignet
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Publication number: 20080121585Abstract: A method for treating water includes removing a supersaturated sparingly soluble salt via a self-sustaining de-supersaturation process in which the supersaturated water is contacted with a nucleation material that is reused in the process. Supersaturated reject water from reverse osmosis systems may be de-supersaturated, reducing scale formation on downstream water treatment systems and pipelines. The method may be used for treatment of sulfate-contaminated groundwater, and groundwater contaminated via mining and processing of sulfide ores, and in other applications.Type: ApplicationFiled: November 26, 2007Publication date: May 29, 2008Inventor: James D. Mavis
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Patent number: 7066900Abstract: An electrophoresis system for removing or reducing concentration of a metabolic component from blood or plasma of a subject is provided. A method for removing or reducing concentration or amount of a metabolic component in blood or plasma of a subject is also provided. The system and method include use of a set of ion permeable barriers and the application of an electrical potential across these barriers to selectively remove metabolic components from blood or plasma.Type: GrantFiled: September 4, 2002Date of Patent: June 27, 2006Assignee: Life TherapeuticsInventors: Steven Anthony Botto, Philip John Roeth, Ellie Louise Faramus, Chenicheri Hariharan Nair
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Patent number: 6824662Abstract: An electrodeionization apparatus and method for purifying a fluid. A fluid, such as water, can be purified by removing weakly ionizable species from the fluid. Weakly ionizable species may be dissociated at different pH levels to facilitate removal from the fluid in an electrodeionization device.Type: GrantFiled: October 27, 2003Date of Patent: November 30, 2004Assignee: USFilter CorporationInventors: Li-Shiang Liang, Anil Jha, John Arba, Stephane Dupont
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Patent number: 6824740Abstract: Systems and methods for the electronic sample preparation of biological materials utilize the differential charge-to-mass ratio and/or the differential affinity of sample constituents to separation materials for sample preparation. An integrated system is provided for performing some or all of the processes of: receipt of biological materials, cell selection, sample purification, sample concentration, buffer exchange, complexity reduction and/or diagnosis and analysis. In one embodiment, one or more sample chambers adapted to receive a buffer solution are formed adjacent to a spacer region which may include a trap or other affinity material, electrophoretic motion of the materials to be prepared being effected through operation of electrodes. In another aspect of this invention, a transporter or dipstick serves to collect and permit transport of materials, such as nucleic acids, most preferably DNA and/or RNA.Type: GrantFiled: April 28, 2000Date of Patent: November 30, 2004Assignee: Nanogen, Inc.Inventors: Edward L. Sheldon, III, Thomas R. Jackson, Paul D. Swanson, Bradley S. Scott, Michael J. Heller
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Publication number: 20040178074Abstract: The present invention provides, in one aspect, an apparatus or electrophoretic separation of analytes. In one aspect, the apparatus comprises a disc-shaped substrate defining (1) a central reservoir region, (2) a plurality of electrophoretic channels in fluid communication with, and emanating substantially radially from, the central reservoir region, the channels being coplanar with each other, and each channel having (i) a proximal end which is linked to the reservoir region, and (ii) a distal end, and preferably (3) for each channel, at least one chamber, and preferably three chambers, linked by a passageway in fluid communication with the distal end of that channel.Type: ApplicationFiled: December 8, 2003Publication date: September 16, 2004Applicant: Applera CorporationInventors: Timothy M. Woudenberg, Reid B. Kowallis
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Patent number: 6649037Abstract: An electrodeionization apparatus and method for purifying a fluid. A fluid, such as water, can be purified by removing weakly ionizable species from the fluid. Weakly ionizable species may be dissociated at different pH levels to facilitate removal from the fluid in an electrodeionization device.Type: GrantFiled: May 29, 2001Date of Patent: November 18, 2003Assignee: United States Filter CorporationInventors: Li-Shiang Liang, Anil Jha, John Arba, Stephane Dupont
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Patent number: 6610546Abstract: An electrolytic suppressor including (a) packing (a suppressor bed of ion exchange resin or a flow-through monolith), (b) an electrode chamber adjacent the suppressor, (c) a first electrode in the electrode chamber, (d) a barrier separating the packing from the first electrode chamber preventing significant liquid flow but permitting transport of ions only of the same charge as the packing, (e) a second electrode in electrical communication with the resin bed, and (f) a recycle conduit between the suppressor outlet port and said electrode chamber. Charged transverse partitions with openings may be included to create a serpentine liquid path.Type: GrantFiled: August 25, 2000Date of Patent: August 26, 2003Assignee: Dionex CorporationInventors: Yan Liu, Kannan Srinivasan, Nebojsa Avdalovic, Hamish Small, John M. Riviello
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Patent number: 6537436Abstract: An electrodialysis treatment system utilizing a plurality of disparate layers of an electrodialysis cell stack for separation of components in liquid mixtures. The system for electrodialysis treatment for purification and deionizing liquids includes providing an operation of pretreatment by filtration for removal of inorganic and organic contaminants and generating a filtrate effluent. An adsorbing operation for adsorbing organic contaminants from the filtrate effluent of the pretreatment operation is provided by utilizing activated carbon adsorption and generating a liquid fraction. A deionizing operation for continuously purifying the liquid fraction is provided by utilizing an electrodialysis stack having a plurality of ion exchange membranes and separating gaskets for selectively removing contaminant ions from the liquid fraction of the adsorbing operation.Type: GrantFiled: May 31, 2001Date of Patent: March 25, 2003Inventors: Ernst Schmidt, Michael E. Williams, Brian M. Schmidt, James Schmidt, Erich Schmidt
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Patent number: 6514398Abstract: Electrodeionization apparatus and method. The electrodeionization apparatus includes an ion-depleting compartment in which alternating layers of an electroactive media are positioned. One of the alternating layers is doped to provide a more balanced current distribution through the apparatus. The method involves providing reducing the difference in conductivity between the alternating layers positioned in the ion-depleting compartment by adding a dopant material to one of the layers.Type: GrantFiled: June 5, 2001Date of Patent: February 4, 2003Assignee: United States Filter CorporationInventors: Felice DiMascio, Anil Jha, Gary C. Ganzi, Frederick Wilkins
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Patent number: 6508985Abstract: An electrolyitic suppressor including (a) a suppressor bed of ion exchange resin, (b) an electrode chamber adjacent the suppressor, (c) a first electrode in the electrode chamber, (d) a barrier separating the suppressor bed from the first electrode chamber preventing significant liquid flow but permitting transport of ions only of the same charge as the suppressor bed resin, (e) a second electrode in electrical communication with the resin bed, and (f) a recycle conduit between the suppressor outlet port and said electrode chamber. The second electrode may be in contact with the ion exchange resin in the suppressor or located in second electrode chamber.Type: GrantFiled: June 8, 2001Date of Patent: January 21, 2003Assignee: Dionex CorporationInventors: Hamish Small, Yan Liu, John M. Riviello, Nebojsa Avdalovic, Kannan Srinivasan
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Publication number: 20020192832Abstract: Methods and devices for continuous electrochemically suppressed ion chromatography are disclosed. In preferred aspect of the invention, a chromatography effluent comprising analyte ions and electrolyte is split into a first chromatography effluent flow stream and a second chromatography effluent flow stream. Electrolysis ions selected from the group consisting of hydronium ions and hydroxide ions are generated by the electrolysis of water. Electrolysis ions of the same charge as the electrolyte and the second chromatography effluent stream are flowed through a stationary phase thereby suppressing the electrolyte in the second chromatography effluent flow stream. The analyte ions are subsequently detected in the suppressed second chromatography effluent flow stream.Type: ApplicationFiled: July 8, 2002Publication date: December 19, 2002Applicant: Alltech Associates, Inc.Inventors: James M. Anderson, Raaidah Saari-Hordhaus, Bart C. Benedict, Carl Sims, Yuri Gurner, Hung Anthony Pham
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Patent number: 6495371Abstract: For anion analysis, the method includes: (a) flowing an aqueous liquid sample stream containing anions to be detected and cation hydroxide through a separator bed, (b) flowing the aqueous effluent from the separator bed through a flow-through suppressor, (c) flowing the effluent liquid from the suppressor past a detector, (d) recycling said liquid effluent from the detector through a cathode chamber proximate to the suppressor bed and separated by a first barrier, and (e) applying an electrical potential between the cathode and the anode. Water is electrolyzed at the anode to cause cations on the cation exchange resin to electromigrate toward the barrier and to be transported across the barrier toward the cathode while water in the cathode chamber is electrolyzed to generate hydroxide ions which combine with the transported cations to form cation hydroxide in the cathode chamber.Type: GrantFiled: June 8, 2001Date of Patent: December 17, 2002Assignee: Dionex CorporationInventors: Hamish Small, Yan Liu, John M. Riviello, Nebojsa Avdalovic, Kannan Srinivasan
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Patent number: 6444107Abstract: An electrodialytic method and device for the simultaneous production of acids and bases of high purity and higher concentration operates by splitting corresponding salts in aqueous solution using an electrolysis cell. The electrolysis cell includes a cathode chamber in which an alkali is formed, a salt chamber for supplying a salt to be split, an acid chamber in which the acid is formed, and an anode chamber through which a mineral acid flows as a proton carrier. The anode is a hydrogen-consuming electrode. The method and device are preferably used in the production of hydrochloric acid and sodium hydroxide solution.Type: GrantFiled: February 5, 2001Date of Patent: September 3, 2002Assignee: SGL Technik GmbHInventors: Georg Härtel, Christian Bienhüls, Jürgen Künzel
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Patent number: 6428666Abstract: A method for separating and concentrating charged species from uncharged or neutral species regardless of size differential. The method uses reversible electric field induced retention of charged species, that can include molecules and molecular aggregates such as dimers, polymers, multimers, colloids, micelles, and liposomes, in volumes and on surfaces of porous materials. The retained charged species are subsequently quantitatively removed from the porous material by a pressure driven flow that passes through the retention volume and is independent of direction thus, a multi-directional flow field is not required. Uncharged species pass through the system unimpeded thus effecting a complete separation of charged and uncharged species and making possible concentration factors greater than 1000-fold.Type: GrantFiled: February 22, 1999Date of Patent: August 6, 2002Assignee: Sandia National LaboratoriesInventors: Anup K. Singh, David W. Neyer, Joseph S. Schoeniger, Michael G. Garguilo
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Patent number: 6325976Abstract: An electrolyitic suppressor including (a) a suppressor bed of ion exchange resin, (b) an electrode chamber adjacent the suppressor, (c) a first electrode in the electrode chamber, (d) a barrier separating the suppressor bed from the first electrode chamber preventing significant liquid flow but permitting transport of ions only of the same charge as the suppressor bed resin, (e) a second electrode in electrical communication with the resin bed, and (f) a recycle conduit between the suppressor outlet port and said electrode chamber. The second electrode may be in contact with the ion exchange resin in the suppressor or located in second electrode chamber.Type: GrantFiled: February 26, 1998Date of Patent: December 4, 2001Assignee: Dionex CorporationInventors: Hamish Small, Yan Liu, John M. Riviello, Nebojsa Avdalovic, Kannan Srinivasan
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Publication number: 20010040093Abstract: An apparatus and process produces salts by an electrodialysis operation. The basic electrodialysis apparatus is a cell having a number of compartments separated by membranes. A DC source is connected to drive a current through a feed stream passing through the cell which splits the salt stream into an acid and a base. The incoming feed may be nanofiltered to remove divalent metal. The base loop may be in communication with an ion exchange column packed with a material that removes multivalent cations. Depending upon the material being processed and the desired end result either or both the nanofiltration and the ion exchanged column may be used in the apparatus.Type: ApplicationFiled: February 14, 2001Publication date: November 15, 2001Applicant: Archer Daniels Midland CompanyInventor: K. N. Mani
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Patent number: 6187197Abstract: A multi-stage apparatus and a process for recycling used engine coolant employs a combination of filtration, dissolved air floatation, centrifugation (hydrocyclone separation), semi-permeable nano filtration, reverse osmosis, and continuous deionization for separating ethylene glycol, with or without propylene glycol, and water from used engine coolant. The engine coolant is pre-filtered through a series of filters. The filters remove particulate contaminates. This filtered fluid is then subjected to dissolved air floatation and/or centrifugation to remove organic petroleum contaminants. Then, it is pressurized prior to being passed through semi-permeable nano filtration. The nano filtration separates the feed stream into a ultra filtration solution and a concentrated waste solution. The concentrate solution is returned to a centrifuged coolant tank for continuous circulation through the nano filtration device.Type: GrantFiled: October 28, 1998Date of Patent: February 13, 2001Inventor: Marvin Haddock
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Patent number: 6077434Abstract: A method and apparatus for increasing the current efficiency of suppressor and suppress-like pretreatment devices is disclosed for the purpose of suppressing a high concentration of eluent without the detrimental effects of excess heat generation. The method and apparatus may be used in ion chromatography.Type: GrantFiled: January 15, 1999Date of Patent: June 20, 2000Assignee: Dionex CorporationInventors: Kannan Srinivasan, Victor Berber Barreto, Christopher A. Pohl, James R. Thayer, Neboisa Avdalovic
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Patent number: 6054053Abstract: Peak resolution in reversed-phase electrochromatography is improved in either of two alternative ways. The first is by a stepwise increase in the concentration of acetonitrile or other equivalent buffer constituent or modifier after the sample has been loaded, and the second is the inclusion of a surfactant in the mobile phase.Type: GrantFiled: May 18, 1999Date of Patent: April 25, 2000Assignee: Bio-Rad Laboratories, Inc.Inventors: Stellan Hjerten, Jia-Li Liao