Solid Sorption Or Desorption Patents (Class 204/551)
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Patent number: 11243027Abstract: Disclosed herein are devices systems and methods for removing moisture from a material via radio frequency electromagnetic wave exposure. A moisture-removal system can include having spaced apart a first and a second electrical conductor extending along a same first direction, each of the first and second electrical conductor comprising opposing broad top and bottom sides, the broad bottom side of the first electrical conductor facing the broad top side of the second electrical conductor. The system includes a material containing moisture at least partially filling the space between the first and the second electrical conductor. The system further includes at least one first wire attached to a first radio frequency generator and to the first end of the first electrical conductor. The system also includes at least one second wire attached to the electrical ground of the first radio frequency generator to the first end of the second electrical conductor.Type: GrantFiled: February 27, 2020Date of Patent: February 8, 2022Assignee: Drymax DDG LLCInventors: Kevin Eichhorn, Pratheik Ajit, Havneet Singh
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Patent number: 10544052Abstract: The present invention provides for a device useful or removing dissolved ions from water comprising or configured to comprise composite resin electrodes. The present invention provides for a device useful for removing dissolved ions from water comprising or configured to comprise composite resin electrodes. The present invention also provides for a method for removing dissolved ions from water comprising providing said device, and using it thereof.Type: GrantFiled: October 5, 2015Date of Patent: January 28, 2020Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Chinmayee V. Subban, Ashok J. Gadgil, Robert Kostecki, Guoying Chen
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Patent number: 10486167Abstract: A fuel and/or lubricant system for an engine can include an engine component configured to be in fluid communication with the fuel and/or lubricant, and an alternating current (AC) source electrically connected to the engine component to create an electric field of alternating polarity to subject particles within the fuel and/or lubricant to dielectrophoresis as the fuel and/or lubricant passes through the electric field to prevent deposits from forming on the engine component. In certain embodiments, the engine component can be a filter screen configured to filter the fuel and/or lubricant to subject particles within the fuel and/or lubricant to dielectrophoresis as the fuel and/or lubricant passes through the filter screen.Type: GrantFiled: July 13, 2016Date of Patent: November 26, 2019Assignee: Delavan Inc.Inventors: Rhonda R. Willigan, Haralambos Cordatos
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Patent number: 10287191Abstract: Apparatus with flow-through capacitors for the purification of a liquid, which comprises: at least one cell (2) provided with at least one flow-through capacitor (4) provided with two or more electrodes facing each other, between which a liquid to be treated is susceptible to flow; electrical power supply means (13) adapted to supply a direct supply voltage (VA); a modulation circuit (14) connected in input to the electrical power supply means (13) in order to receive the supply voltage (VA) and provided with switches (22?, 22?; 23?, 23?) actuatable to apply at least one operating voltage between the facing electrodes of each capacitor (4).Type: GrantFiled: November 15, 2013Date of Patent: May 14, 2019Assignee: IDROPAN DELL'ORTO DEPURATORI S.R.L.Inventor: Tullio Servida
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Patent number: 10026982Abstract: Embodiments described herein provide for water reclamation from the exhaust stream of a RSOFC while the RSOFC operates in fuel cell mode. The reclaimed water is stored for use by the RSOFC while in electrolysis mode. An embodiment includes a RSOFC, a condensate tank, a condenser, and a controller. The RSOFC generates electrical power and water vapor by consuming hydrogen gas in the fuel cell mode, and consumes electrical power and water to generate the hydrogen gas in the electrolysis mode. The condenser condenses the water vapor into water, and directs the water to the condensate tank. The controller, responsive to transitioning the RSOFC from the fuel cell mode to the electrolysis mode, supplies the water to the RSOFC from the condensate tank, and supplies the electrical power to the RSOFC to electrolyze the water and to generate the hydrogen gas.Type: GrantFiled: July 19, 2016Date of Patent: July 17, 2018Assignee: The Boeing CompanyInventors: Joshua M Mermelstein, Catherine Cannova
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Patent number: 9644277Abstract: An electrolyzer or unitized regenerative fuel cell has a flow field with at least one channel, wherein the cross-sectional area of the channel varies along at least a portion of the channel length. In some embodiments the channel width decreases along at least a portion of the length of the channel according to a natural exponential function. The use of this type of improved flow field channel can improve performance and efficiency of operation of the electrolyzer device.Type: GrantFiled: April 10, 2015Date of Patent: May 9, 2017Assignee: Loop Energy Inc.Inventors: Sean Michael MacKinnon, Matthew Paul Paone, Raoul Jacob Kingma, Greg John Montie
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Publication number: 20130284600Abstract: A medium for isolating or releasing an electrostatically charged component from or into an aqueous composition. The medium has a polyelectrolyte film on at least one surface of an article wherein the polyelectrolyte film is characterized by an interpenetrating network of a predominantly positively charged polymer and a predominantly negatively charged polymer. The predominantly positively charged polymer, the predominantly negatively charged polymer or both contain (i) a pH sensitive imidazole repeat unit having a pKa between 3 and 9, or (ii) a redox sensitive repeat unit selected from the group consisting of quaternized bipyridine repeat units, coordinated metal repeat units, pyrrole repeat units, aniline repeat units, thiophene repeat units and combinations thereof having a redox potential between +1.2 volts and ?1.2 volts versus a standard hydrogen electrode.Type: ApplicationFiled: June 28, 2013Publication date: October 31, 2013Inventors: Joseph B. Schlenoff, Zhijie Sui, David S. Salloum, Hassan Rmaile
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Patent number: 8496797Abstract: Electrodeionization methods and apparatus wherein ion exchange membranes are not utilized. Instead, ion exchange materials such as beads, fibers, etc., are disposed in alternating layers of anion exchange (AIX) materials and cation exchange (CIX) materials between opposite polarity electrodes. In a regeneration stage, a current is applied across the electrodes with water splitting occurring along at least one of the interfacial areas between neighboring AIX and CIX materials. The H+ and OH? ions formed via water splitting migrate in response to the electrical current and displace the salt ions in the respective AIX and CIX. The stack is flushed during the regeneration stage to remove the concentrated salt solution. During a deionization phase, the electrical current is terminated with influent fed to the stack for deionization. The salt ions in the influent are depleted via ion exchange as the influent contacts the AIX and CIX.Type: GrantFiled: December 14, 2010Date of Patent: July 30, 2013Assignee: General Electric CompanyInventor: John H. Barber
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Patent number: 8491768Abstract: Nanoparticles in a colloid are purified, with the colloid including a fluid, unwanted matter, and the nanoparticles to be purified. An electric field is applied that is substantially spatially uniform over a distance that is at least equal to a characteristic dimension of the nanoparticles, so that at least some of the nanoparticles move towards at least one collection surface as a result of the force arising between their electrical charge and the electric field, whereupon nanoparticles are collected on said at least one collection surface. The collection surface(s) may be one or more electrodes to which a voltage potential is applied. The collected nanoparticles are then removed from the collection surface, e.g., by dispersing them into another fluid.Type: GrantFiled: June 23, 2010Date of Patent: July 23, 2013Assignee: International Business Machines CorporationInventors: Xin Ai, John David Bass, Ho-Cheol Kim, Robert Dennis Miller, John Campbell Scott, Qing Song
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Publication number: 20120273358Abstract: The invention provides a method of inhibiting biological damage to a cellulosic structural element exposed to environmental moisture, said method comprising applying a pulsed asymmetric electrical voltage to a decay-prone region of a said element over a prolonged time period.Type: ApplicationFiled: October 28, 2010Publication date: November 1, 2012Applicant: MILJOTEKNOLOGI ASInventors: Erik Larnoy, Andreas Treu, Hasse V. Halvorsen
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Patent number: 8246804Abstract: A method for the treatment of an aqueous stream containing both anionic and cationic species is provided. The method comprises the following steps. Circulating water continuously through an essentially closed loop, the loop incorporating an ion adsorption unit which, in turn, comprises a water permeable layer of an ion adsorbing material. Feeding an aqueous solution containing the anionic and the cationic species to the essentially closed loop. Passing the circulating water, including the aqueous solution containing the ionic and the cationic species, through the ion adsorbing material in the ion adsorption unit in a continuous manner. While at the same time applying an electric potential across the thickness of the layer of ion adsorbing material and removing from the ion adsorption unit more concentrated aqueous solutions of the separate ionic species. Discharging each of the aqueous solutions from the ion adsorption unit.Type: GrantFiled: September 10, 2004Date of Patent: August 21, 2012Assignee: Edwards LimitedInventors: Christopher Peter Jones, Peter James Mawle
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Patent number: 8133380Abstract: A method and device for regenerating an ion exchanger can regenerate an ion exchanger easily and quickly, and can minimize a load upon cleaning of the regenerated ion exchanger and disposal of waste liquid. A method for regenerating a contaminated ion exchanger includes: providing a pair of a regeneration electrode and a counter electrode, a partition disposed between the electrodes, and an ion exchanger to be regenerated disposed between the counter electrode and the partition; and applying a voltage between the regeneration electrode and the counter electrode while supplying a liquid between the partition and the regeneration electrode and also supplying a liquid between the partition and the counter electrode.Type: GrantFiled: August 14, 2008Date of Patent: March 13, 2012Assignee: Ebara CorporationInventors: Takayuki Saito, Tsukuru Suzuki, Yuji Makita, Kaoru Yamada, Masayuki Kumekawa, Hozumi Yasuda, Osamu Nabeya, Kazuto Hirokawa, Mitsuhiko Shirakashi, Yasushi Toma, Itsuki Kobata
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Patent number: 7780834Abstract: An apparatus and method for electrochemically modifying the retention of a species on a chromatography material is disclosed. The apparatus comprises a housing having an effluent flow channel adapted to permit fluid flow therethrough. The effluent flow channel comprises chromatography material. The apparatus further comprises first and second electrodes positioned such that at least a portion of the chromatography material is disposed between the first and second electrodes, and fluid flow through the apparatus is between, and in contact with, the first and second electrodes.Type: GrantFiled: October 31, 2007Date of Patent: August 24, 2010Assignee: Dionex CorporationInventors: James M. Anderson, Jr., Raaidah Saari-Nordhaus, Carl W. Sims, Yuri E. Gerner
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Patent number: 7718046Abstract: A method and device are provided for affinity gradient focusing for directing at least one analyte in a solution containing a pseudostationary phase and located in a channel such as a capillary or a microchannel. The method includes establishing a steady-state spatial gradient in a retention factor of the pseudostationary phase for the at least one analyte. The analyte is caused to be moved within the channel whereby the concentration of the at least one analyte changes at one or more positions along the gradient. The pseudostationary phase is charged and the analyte is either neutral or charged or alternatively, the pseudostationary phase is neutral and the analyte is charged. The device may include a fluid channel, a pseudostationary phase having a retention factor gradient, an electrical current source and a pump system for establishing the bulk flow in the solution in the channel.Type: GrantFiled: June 10, 2004Date of Patent: May 18, 2010Assignee: The United States of America, as represented by the Secretary of Commerce, the National Institute of Standards & TechnologyInventors: David J. Ross, Peter B. Howell, Wyatt N. Vreeland
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Patent number: 7531075Abstract: An apparatus and method for electrochemically modifying the retention of a species on a chromatography material is disclosed. The apparatus comprises a housing having an effluent flow channel adapted to permit fluid flow therethrough. The effluent flow channel comprises chromatography material. The apparatus further comprises first and second electrodes positioned such that at least a portion of the chromatography material is disposed between the first and second electrodes, and fluid flow through the apparatus is between, and in contact with, the first and second electrodes.Type: GrantFiled: May 18, 2005Date of Patent: May 12, 2009Assignee: Dionex CorporationInventors: James M. Anderson, Jr., Raaidah Saari-Nordhaus, Carl W. Sims, Yuri E. Gerner
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Patent number: 7402283Abstract: An acid or base is generated in an aqueous solution by the steps of: (a) providing a source of first ions adjacent an aqueous liquid in a first acid or base generation zone, separated by a first barrier (e.g., anion exchange membrane) substantially preventing liquid flow and transporting ions only of the same charge as said first ions, (b) providing a source of second ions of opposite charge adjacent an aqueous liquid in a second acid or base generation zone, separated by a second barrier transporting ions only of the same charge as the second ions, and (c) transporting ions across the first barrier by applying an electrical potential through said first and second zones to generate an acid-containing aqueous solution in one of said first or second zones and a base-containing aqueous solution in the other one which may be combined to form a salt. Also, electrolytic apparatus for performing the above method.Type: GrantFiled: September 11, 2002Date of Patent: July 22, 2008Assignee: Dionex CorporationInventors: Yan Liu, Nebojsa Avdalovic
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Patent number: 7364646Abstract: An apparatus and method for electrochemically modifying the retention of a species on a chromatography material is disclosed. The apparatus comprises a housing having an effluent flow channel adapted to permit fluid flow therethrough. The effluent flow channel comprises chromatography material. The apparatus further comprises first and second electrodes positioned such that at least a portion of the chromatography material is disposed between the first and second electrodes, and fluid flow through the apparatus is between, and in contact with, the first and second electrodes.Type: GrantFiled: May 1, 2003Date of Patent: April 29, 2008Assignee: Dionex CorporationInventors: James M. Anderson, Jr., Raaidah Saari-Nordhaus, Carl W. Sims, Yuri E. Gerner
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Patent number: 7291271Abstract: The invention provides a non-cyclic, meso-frequency traveling wave electro-kinetic system capable of use in purification/separation and/or refrigeration/heat pump processes. In particular, the invention provides an adsorption system that can be used for fine or bulk chemical separations of liquid and gaseous materials. Similarly, the adsorption system can be readily adapted to function as a refrigeration/heat pump unit for use in heating and cooling systems. This reusable adsorption system provides high efficiency purification and/or cooling/heating with low energy demands and no moving parts. The invention can function in parallel or in series with other similar such adsorption units (though it can also operate as a single unit).Type: GrantFiled: December 9, 2003Date of Patent: November 6, 2007Assignee: Separation Design Group, LLCInventor: S. Douglas Galbraith
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Patent number: 7288176Abstract: A method and apparatus is provided for generating a high purity eluant suitable for use in chromatography. The high purity eluant may be generated by providing water and a first stationary phase comprising exchangeable cations. Electrolysis ions are generated by the electrolysis of water. The electrolysis ions are selected from the group consisting of hydronium ions and hydroxide ions. The hydronium ions are passed through the first stationary phase so that the hydronium ions replace the cations in the first stationary phase. Thereafter, a source of desired ions is combined with the cations to form a high purity eluant containing the desired ions.Type: GrantFiled: April 23, 2003Date of Patent: October 30, 2007Assignee: Dionex CorporationInventors: James M. Anderson, Jr., Raaidah Saari-Nordhaus
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Patent number: 7153476Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.Type: GrantFiled: June 21, 2002Date of Patent: December 26, 2006Assignee: Dionex CorporationInventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
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Patent number: 7138042Abstract: An electrically regeneratable battery of electrochemical cells for capacitive deionization (including electrochemical purification) and regeneration of electrodes is operated at alternate polarities during consecutive cycles. In other words, after each regeneration step operated at a given polarity in a deionization-regeneration cycle, the polarity of the deionization step in the next cycle is maintained. In one embodiment, two end electrodes are arranged one at each end of the battery, adjacent to end plates. An insulator layer is interposed between each end plate and the adjacent end electrode. Each end electrode includes a single sheet of conductive material having a high specific surface area and sorption capacity, preferably a sheet formed of carbon aerogel composite. The batter further includes a plurality of generally identical double-sided intermediate electrodes that are equidistally separated from each other, between the two end electrodes.Type: GrantFiled: March 15, 2004Date of Patent: November 21, 2006Assignee: The Regents of the University of CaliforniaInventors: Tri D. Tran, David J. Lenz
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Patent number: 6955922Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.Type: GrantFiled: July 7, 2000Date of Patent: October 18, 2005Assignee: Dionex CorporationInventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
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Publication number: 20040067301Abstract: The medical devices of the invention comprise a portion having a porous surface for release of at least one biologically active agent therefrom. The porous surface is made of a material such as a polymer having a plurality of voids. To load the porous surface with a biologically active agent or drug, an electrophoresis method is employed. In this method, a device having a porous surface is placed into a drug solution or suspension, along with an electrode. An electric current is applied to the device and electrode. Under such a current, the drug, which has a positive or negative charge, will be loaded into the pores or voids of the porous surface.Type: ApplicationFiled: October 3, 2003Publication date: April 8, 2004Applicant: Schneider (USA), Inc.Inventor: Ni Ding
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Patent number: 6706196Abstract: A method and apparatus provide fluid treatment at a plurality of distinct points using a length of energized magnetically conductive conduit in fluid communication with non-magnetic coupling devices. The instant invention prevents the formation and accumulation of contaminants within conduits and on equipment utilized in the transportation, delivery and processing of fluid columns. It may also be utilized to accelerate the separation of oil and water and increase the efficiency of oil/water separation equipment.Type: GrantFiled: February 23, 2002Date of Patent: March 16, 2004Inventor: Herbert W. Holland
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Patent number: 6687638Abstract: An inspection equipment integrity system uses independent sensors and processing capabilities to determine the integrity of inspection equipment. The sensors detect the presence of packages at predetermined positions. The system further receives input from the inspection equipment regarding decisions made during inspection of the packages. The system uses the position information and inputs from the inspection equipment to determine the integrity of the inspection equipment. A further sensor determines the integrity of inspection equipment used to redirect packages based on decisions made by the inspection equipment.Type: GrantFiled: August 10, 2001Date of Patent: February 3, 2004Assignee: General Hills, Inc.Inventors: Michael G. Poterek, Mike E. Geddis, Martin Lymn, Mike Teasdale
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Patent number: 6682701Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.Type: GrantFiled: July 7, 2000Date of Patent: January 27, 2004Assignee: Dionex CorporationInventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
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Publication number: 20030209439Abstract: An apparatus and method for electrochemically modifying the retention of a species on a chromatography material is disclosed. The apparatus comprises a housing having an effluent flow channel adapted to permit fluid flow therethrough. The effluent flow channel comprises chromatography material. The apparatus further comprises first and second electrodes positioned such that at least a portion of the chromatography material is disposed between the first and second electrodes, and fluid flow through the apparatus is between, and in contact with, the first and second electrodes.Type: ApplicationFiled: May 1, 2003Publication date: November 13, 2003Applicant: Alltech Associates, Inc.Inventors: James M. Anderson, Raaidah Saari-Nordhaus, Carl W. Sims, Yuri E. Gerner
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Publication number: 20030159933Abstract: The one and two-dimensional separation of proteins extending through the membrane (membrane proteins) is a prerequisite for a complete analysis of the proteome of a functionally intact cell organelle. A substantial drawback of prior art methods for separating is that their applicability is limited to peripheral water-soluble proteins. The aim of the novel method is to electrophoretically separate membrane proteins in one or two dimensions. To this end, membranes from cell organelles, whose membrane protein stock should be separated, are placed on planar supports whose surface was modified using suitable methods in such a manner that the membrane proteins maintain their ability to laterally diffuse in the membrane plane after being placed on the support. By subsequently applying electrical fields, the proteins can be electrophoretically displaced in the membrane plane and, as a result, can be separated in one or two dimensions according to their different charge characteristics.Type: ApplicationFiled: April 28, 2003Publication date: August 28, 2003Inventors: Thomas Bayerl, Erich Sackmann
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Publication number: 20020182741Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.Type: ApplicationFiled: June 21, 2002Publication date: December 5, 2002Applicant: Dionex CorporationInventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
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Publication number: 20020177233Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.Type: ApplicationFiled: June 21, 2002Publication date: November 28, 2002Applicant: Dionex CorporationInventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
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Publication number: 20020148731Abstract: A method for dehydrating a porous material using electro-osmosis, includes applying a pattern of D.C. voltage pulses to an anode system embedded in the porous material, wherein the anode system is electrically interactive with a cathode structure embedded in earth, and wherein the pattern of D.C. voltage pulses, has a pulse period T in a range from about 3 to about 60 seconds, and each pulse period T includes a positive pulse duration of T+ from about 0.7 T to about 0.97 T, a negative pulse duration of T− from about 0.01 T to about 0.05 T, and a neutral pulse duration of Tp from about 0.02 T to about 0.25 T. In another embodiment, each pulse period includes two or more positive pulses separated by at least one of either a negative pulse or a neutral pulse, with the positive pulse duration being the combined duration of the two positive pulses.Type: ApplicationFiled: April 2, 2002Publication date: October 17, 2002Inventors: Egil Bjerek, Henning Olson
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Patent number: 6423199Abstract: An electrochemical ion exchange cell comprises a metal carbollide as ion exchange material. The carbollide is preferably a polynuclear cobalt dicarbollide and is typically substituted by chlorine. Also novel are polynuclear metal carbollides comprising a substituted carbollide cage, as well as metal carbollides comprising a carbollide cage substituted by a moiety having a —COOH or —SH group.Type: GrantFiled: April 10, 2000Date of Patent: July 23, 2002Assignee: British Nuclear Fuels plcInventors: Nigel Dennis Tinker, James Darcy McKinney, Simon James Richards
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Publication number: 20020084188Abstract: An electrically regeneratable battery of electrochemical cells for capacitive deionization (including electrochemical purification) and regeneration of electrodes is operated at alternate polarities during consecutive cycles. In other words, after each regeneration step operated at a given polarity in a deionization-regeneration cycle, the polarity of the deionization step in the next cycle is maintained. In one embodiment, two end electrodes are arranged one at each end of the battery, adjacent to end plates. An insulator layer is interposed between each end plate and the adjacent end electrode. Each end electrode includes a single sheet of conductive material having a high specific surface area and sorption capacity, preferably a sheet formed of carbon aerogel composite. The battery further includes a plurality of generally identical double-sided intermediate electrodes that are equidistally separated from each other, between the two end electrodes.Type: ApplicationFiled: January 3, 2002Publication date: July 4, 2002Applicant: The Regents of the University of California.Inventors: Tri D. Tran, David J. Lenz
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Patent number: 6395143Abstract: The invention relates to a system, process and apparatus for separating biosorbent and sorbate. Biomass enclosed within a membrane system is coupled to an electrode, which is capable of being placed in contact with the sorbate containing material in the presence of a counter electrode. An electric field may be discharged across the electrodes and ionic species will migrate into the membrane enclosed system. The migrated species within the membrane can be taken up and processed by the biosorbtive processes of the biomass. The system may be used to remove dye stuffs, metal, heavy metals, radionuclides and other pollutants from natural and artificial sources.Type: GrantFiled: August 18, 1999Date of Patent: May 28, 2002Assignee: University of UlsterInventors: Anthony McHale, Mark Bustard
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Publication number: 20020029957Abstract: The invention relates to a system, process and apparatus for separating biosorbent and sorbate. Biomass enclosed within a membrane system is coupled to an electrode, which is capable of being placed in contact with the sorbate containing material in the presence of a counter electrode. An electric field may be discharged across the electrodes and ionic species will migrate into the membrane enclosed system. The migrated species within the membrane can be taken up and processed by the biosorbtive processes of the biomass. The system may be used to remove dye stuffs, metal, heavy metals, radionuclides and other pollutants from natural and artificial sources.Type: ApplicationFiled: August 18, 1999Publication date: March 14, 2002Inventors: ANTHONY MCHALE, MARK BUSTARD
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Publication number: 20020017463Abstract: The present invention is directed to an apparatus and method for deionization and hydrogen fuel production in a fuel generation mode, and electricity production in a power generation mode. In one embodiment, a capacitive deionization (CDI) device receives water and electrical energy to produce deionized water that is transferred to a proton electrode membrane electrolysis (PEME) device to produce hydrogen fuel by electrolysis. A storage system receives the hydrogen. The hydrogen is transferred from the storage system to a proton electrode membrane fuel cell (PEMFC) device that produces electrical energy. In another embodiment, the PEME and the PEMFC are functionally combined in a unitary regenerative fuel cell (URFC). In still another embodiment, a humidification unit and the CDI are functionally combined. In yet another embodiment, a CDI, URFC and the humidification unit are combined in a single unitary assembly.Type: ApplicationFiled: June 5, 2001Publication date: February 14, 2002Inventor: Walter Roberto Merida-Donis
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Patent number: 6316270Abstract: A method for generating high purity acid or base in an aqueous stream for use as an eluent for chromatography and, particularly, ion chromatography. For generating a base for anion chromatography, the aqueous stream is directed through a cation exchange bed having a first strongly acidic and a second weakly acidic portions. An electrical potential is applied to the bed. Cations on the bed electromigrate into the aqueous stream while hydroxide ions are electrolytically generated to form a base-containing eluent. Anions to be detected and the generated eluent flow through a chromatographic separator. The chromatographic effluent flows past a detector.Type: GrantFiled: December 23, 1999Date of Patent: November 13, 2001Assignee: Dionex CorporationInventors: Hamish Small, Nebojsa Avdalovic, Yan Liu
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Patent number: 6309532Abstract: An electrically regeneratable electrochemical cell (30) for capacitive deionization and electrochemical purification and regeneration of electrodes includes two end plates (31, 32), one at each end of the cell (30). A new regeneration method is applied to the cell (30) which includes slowing or stopping the purification cycle, electrically desorbing contaminants and removing the desorbed contaminants. The cell (30) further includes a plurality of generally identical double-sided intermediate electrodes (37-43) that are equidistally separated from each other, between the two end electrodes (35, 36). As the electrolyte enters the cell, it flows through a continuous open serpentine channel (65-71) defined by the electrodes, substantially parallel to the surfaces of the electrodes. By polarizing the cell (30), ions are removed from the electrolyte and are held in the electric double layers formed at the carbon aerogel surfaces of the electrodes.Type: GrantFiled: April 12, 1999Date of Patent: October 30, 2001Assignee: Regents of the University of CaliforniaInventors: Tri D. Tran, Joseph C. Farmer, Laura Murguia
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Patent number: 6258237Abstract: A method of depositing diamond particles on a surface of a substrate is provided. The method is effected by (a) charging the diamond particles by a positive charge to obtain positively charged diamond particles; and (b) electrophoretically depositing the positively charged diamond particles on the surface of the substrate, for obtaining a green diamond particles coat on the surface of the substrate.Type: GrantFiled: December 30, 1998Date of Patent: July 10, 2001Assignees: Cerd, Ltd., Iscer, Ltd.Inventors: Leah Gal-Or, Rony Goldner, Nina Sezin, David Brandon, Shai Gilboa, Albir A. Layyous
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Patent number: 6235219Abstract: Compositions useful as desiccants are disclosed. The compositions may be prepared by admixing components comprising a hygroscopic material and an organic polymer in a solvent to form a solution, followed by drying the solution to remove solvent and provide a moisture-deficient hygroscopic material dispersed in the organic polymer. Alternatively, the compositions may be prepared by admixing components comprising a hygroscopic material and molten organic polymer to form a fluid admixture, followed by cooling the fluid admixture to a non-fluid state. The compositions of the present invention may comprise (1) a hygroscopic material dispersed in polyvinyl alcohol, (2) a deliquescent material dispersed in an organic polymer, or (3) hygroscopic material and polymeric material both dissolved in solvent.Type: GrantFiled: August 2, 1999Date of Patent: May 22, 2001Inventor: Thomas Beckenhauer
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Patent number: 6225129Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.Type: GrantFiled: February 2, 1998Date of Patent: May 1, 2001Assignee: Dionex CorporationInventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
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Patent number: 6214204Abstract: An electrode for deionization of water is made of a continuous activated carbon structure. The activated carbon is derived from a synthetic carbon precursor. The structure has openings, inlet and outlet ends such that water entering the inlet end passes through the openings and exits through the outlet end, a conductive coating on at least part of the outer surface of the structure, and a metal wire in contact with the structure. A deionization system is made up of the electrodes in series so that the outlet end of one electrode is next to the inlet end of the nearest downstream electrode. The metal wire of each electrode is connected to a power source to deliver the opposite charge as the charge delivered to its neighboring electrodes. Each of the electrodes is fixedly attached to and sealed within a housing with an air and moisture-tight seal. Openings in the housing between the electrodes, allow air to be removed before use.Type: GrantFiled: August 27, 1999Date of Patent: April 10, 2001Assignee: Corning IncorporatedInventors: Kishor P. Gadkaree, Joseph F. Mach, John L. Stempin
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Patent number: 6096179Abstract: A carbon-reinforced electrode is disclosed. The electrode is formed from a high surface area absorptive material ("HSAAM electrode") made from resorcinol, formaldehyde, a carbon reinforcing agent, a catalyst, and reaction products thereof, and is in a carbonized form. This electrode removes ions from a liquid when an electric current is applied. The liquid may be passed through a thickness of the electrode, or may be passed by the surface of the electrode. A method of making the HSAAM electrodes is also disclosed. The HSAAM electrodes are formed from setting a polymerized mixture of resorcinol, formaldehyde and a carbon reinforcing agent supplied in the form of carbon fibers, carbon felt or cellulose under controlled temperature and time constraints, and subsequently firing the resulting product so as to carbonize the electrode.Type: GrantFiled: June 3, 1999Date of Patent: August 1, 2000Assignee: Southeastern Trading, LLPInventors: James R. Fajt, David A. Caple, Brian B. Elson
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Patent number: 6090259Abstract: An apparatus for deionization of a liquid is disclosed. The apparatus has a number of deionization cells, each cell having two different types of electrodes. The first type of electrode is formed from a high surface area absorptive material ("HSAAM electrode") made from resorcinol, formaldehyde, a carbon reinforcing agent, a catalyst, and reaction products thereof, and is in a carbonized form. This electrode removes ions when an electric current is applied. The second type of electrode, which does not remove ions, is formed from a non-HSAAM material. Each deionization cell has a single HSAAM electrode bordered on either side by a non-HSAAM electrode, and adjacent deionization cells do not share any electrodes of either type. The non-HSAAM electrodes are formed from carbon cloth or carbon felt fixed to one side of a plexiglass sheet, and two such sheets are needed to form a cell.Type: GrantFiled: August 20, 1999Date of Patent: July 18, 2000Assignee: Southeastern Trading, LLPInventors: James R. Fajt, David A. Caple, Brian B. Elson
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Patent number: 6054053Abstract: Peak resolution in reversed-phase electrochromatography is improved in either of two alternative ways. The first is by a stepwise increase in the concentration of acetonitrile or other equivalent buffer constituent or modifier after the sample has been loaded, and the second is the inclusion of a surfactant in the mobile phase.Type: GrantFiled: May 18, 1999Date of Patent: April 25, 2000Assignee: Bio-Rad Laboratories, Inc.Inventors: Stellan Hjerten, Jia-Li Liao
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Patent number: 6036921Abstract: An apparatus for generating high purity acid or base in an aqueous stream for use as an eluent for chromatography and, particularly, ion chromatography. For generating a base for anion chromatography, the aqueous stream is directed through a cation exchange bed. An electrical potential is applied to the bed. Cations on the bed electromigrate into the aqueous stream while hydroxide ions are electrolytically generated to form a base-containing eluent. Anions to be detected and the generated eluent flow through a chromatographic separator and a detector. In one embodiment, between separation and detection, the separated anion stream flows through a second cation exchange bed with no electrical potential applied. The second bed serves as a suppressor. After completion of the desired number of cycles, flow through the first and second cation exchange beds may be reversed by appropriate valving for the next sample stream.Type: GrantFiled: January 13, 1998Date of Patent: March 14, 2000Assignee: Dionex CorporationInventors: Hamish Small, Nebojsa Avdalovic, Yan Liu
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Patent number: 6007771Abstract: Apparatus and methods for holding and cleaning non-permeable contact lenses which includes the application of an electromagnetic field about the contact lenses which are held in a cavity containing a conductive solution and an adsorbent membrane to capture the contaminants being removed from the lenses. Proteins, lipoproteins and other contaminants adhere to the surface of non-permeable lenses. An adsorbent is positioned between the lens and an electric current source so that current flows from the current source through the adsorbent and over the surface of the contact lens so that contaminants on the lens are loosened and migrate to the adsorbent to which they adhere, thus permitting effective removal from the solution.Type: GrantFiled: July 18, 1997Date of Patent: December 28, 1999Inventors: Theodore H. Rehmeyer, James R. Shultz
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Patent number: 5980718Abstract: A fuse and filter arrangement for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event.Type: GrantFiled: May 4, 1998Date of Patent: November 9, 1999Assignee: The Regents of the University of CaliforniaInventors: Richard A. Van Konynenburg, Joseph C. Farmer
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Patent number: 5954937Abstract: An electrically regeneratable electrochemical cell (30) for capacitive deionization and electrochemical purification and regeneration of electrodes includes two end plates (31, 32), one at each end of the cell (30). Two end electrodes (35, 36) are arranged one at each end of the cell (30), adjacent to the end plates (31, 32). An insulator layer (33) is interposed between each end plate (31, 32) and the adjacent end electrode (35, 36). Each end electrode (35, 36) includes a single sheet (44) of conductive material having a high specific surface area and sorption capacity. In one embodiment, the sheet (44) of conductive material is formed of carbon aerogel composite. The cell (30) further includes a plurality of generally identical double-sided intermediate electrodes (37-43) that are equidistally separated from each other, between the two end electrodes (35, 36).Type: GrantFiled: November 15, 1996Date of Patent: September 21, 1999Assignee: The Regents of the University of CaliforniaInventor: Joseph C. Farmer
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Patent number: 5944972Abstract: A method for producing deionized water by self-regenerating type electrodialysis deionization, which comprises (i) using a deionized water-producing apparatus containing an electrodialyzer comprising cation exchange membranes and anion exchange membranes alternately arranged between an anode compartment provided with an anode and a cathode compartment provided with a cathode, demineralizing compartments compartmentalized with anion exchange membranes on the anode side and compartmentalized with cation exchange membranes on the cathode side, and concentrating compartments compartmentalized with cation exchange membranes on the anode side and compartmentalized with anion exchange membranes on the cathode side, the electrodialyzer having ion exchangers accommodated in the demineralizing compartments, and (ii) applying a voltage while supplying water to be treated to the demineralizing compartments to remove impurity ions in the water to be treated, wherein at least a part of the untreated water or already treateType: GrantFiled: March 25, 1998Date of Patent: August 31, 1999Assignees: Asahi Glass Company Ltd., Glegg Water Conditioning, IncorporatedInventors: Hiroshi Toda, Tohru Hoshi, David Florian Tessier