Particle Bed Separator (e.g., Inert Particles, Ion Exchange Beads, Etc.) Patents (Class 204/647)
  • Patent number: 12172908
    Abstract: A device for removing ions from a solution. The device includes first and second flow channels between an anion exchange membrane and first and second flow plates, respectively. The first flow channel has a first land volume positioned between the first land regions and the anion exchange membrane. The first flow channel has a first channel volume positioned between the anion exchange membrane and the first channel regions and spaced apart from the anion exchange membrane. The second flow channel has a second land volume positioned between the second land regions and the anion exchange membrane. The second flow channel has a second channel volume positioned between the anion exchange membrane and the second channel regions and spaced apart from the anion exchange membrane. The device also includes an intercalation material positioned within the first land and channel volumes or the second land and channel volumes.
    Type: Grant
    Filed: August 12, 2021
    Date of Patent: December 24, 2024
    Assignee: Robert Bosch GmbH
    Inventors: Saravanan Kuppan, Münir M. Besli, Sondra Hellstrom, Jake Christensen
  • Patent number: 11761097
    Abstract: A method includes providing raw water into a first filter assembly to remove solids from the raw water to form a filtrate, providing the filtrate from the first filter assembly into a second filter assembly to electrochemically remove ionics from the filtrate to form purified water, and providing the purified water to an electrolyzer to generate hydrogen by electrolyzing the purified water.
    Type: Grant
    Filed: December 17, 2020
    Date of Patent: September 19, 2023
    Assignee: Ohmium International, Inc.
    Inventors: Arne Ballantine, Chockkalingam Karuppaiah, Ramesh Srinivasan
  • Patent number: 8973596
    Abstract: A manifold for use with an applicator assembly is provided. The manifold includes a base having at least a first proximal extension and a distal extension. The at least first proximal extension includes an outer flange and an inner flange and defines a recess therebetween. The manifold further includes at least a first connection member securely affixed to the first proximal extension. The first connection member includes an annular flange configured to be received within the recess of the at least first proximal extension and the annular flange defines a proximal cavity. The manifold further includes at least a first seal member received within the proximal cavity between the first proximal extension and the first connection member. The seal member is configured to permit flow through the manifold in a first direction and obstruct flow through the manifold in a second direction.
    Type: Grant
    Filed: June 11, 2013
    Date of Patent: March 10, 2015
    Assignee: Confluent Surgical, Inc.
    Inventor: Les Hull
  • Patent number: 8926814
    Abstract: This invention relates to environment protection, and discloses apparatus and method for electrokinetic in-situ leaching remediation of contaminated soil. The apparatus includes a DC electrical source, electrode chambers, electrodes, permeable reactive barriers (PRBs), electrode solution pH testers, electrode solution extraction tubes, a heating pipe network, a heat exchanger, leacheate sprayers, acid-base adjusting solution sprayers, a multichannel peristaltic pump, automatic control devices, an electrode solution storage tank, an electrode solution treatment pond, an in-line pump, single-channel peristaltic pumps, a flowmeter, a time control device, a leacheate storage tank, an acid solution storage tank, an alkali solution storage tank, and soil pH testers.
    Type: Grant
    Filed: April 14, 2014
    Date of Patent: January 6, 2015
    Assignee: North China Electric Power University
    Inventors: Li He, Jiaqi Zhang, Shichao Sun, Hongwei Lu
  • Patent number: 8871063
    Abstract: A process for selective removal of a gaseous product (P) from a gaseous system comprising said product and other components (R1, R2), wherein the gaseous system is admitted to a first environment, which is separated from a second environment by a boundary wall, and a permeation membrane (3, 300) forms at least part of said boundary wall; a spatially non-uniform electric field (4) is generated between a first electrode or first plurality of electrodes (1, 301) located in the first environment and a second electrode or second plurality of electrodes (2, 302) located in the second environment, so that field lines of said non-uniform electric field cross said membrane, and a dielectrophoretic force generated on particles of said gaseous component (P) is at least part of a driving force of the permeation through said membrane, an amount of said product (P) being selectively removed from the first environment and collected in the second environment.
    Type: Grant
    Filed: June 10, 2011
    Date of Patent: October 28, 2014
    Assignee: Casale SA
    Inventor: Sergio Panza
  • Publication number: 20130240361
    Abstract: A device for the removal of toxic substances from biofluids has an electrocatalytic decomposition filter positioned between an inlet and an outlet. The filter includes a DC power source, a set of electrodes with a catalytic surface or in direct contact with sorbents offering catalytic activity, and an electrosorption filter for removing toxic substances.
    Type: Application
    Filed: May 1, 2013
    Publication date: September 19, 2013
    Applicant: ICinnovation BV
    Inventor: Frank Simonis
  • Patent number: 8496797
    Abstract: Electrodeionization methods and apparatus wherein ion exchange membranes are not utilized. Instead, ion exchange materials such as beads, fibers, etc., are disposed in alternating layers of anion exchange (AIX) materials and cation exchange (CIX) materials between opposite polarity electrodes. In a regeneration stage, a current is applied across the electrodes with water splitting occurring along at least one of the interfacial areas between neighboring AIX and CIX materials. The H+ and OH? ions formed via water splitting migrate in response to the electrical current and displace the salt ions in the respective AIX and CIX. The stack is flushed during the regeneration stage to remove the concentrated salt solution. During a deionization phase, the electrical current is terminated with influent fed to the stack for deionization. The salt ions in the influent are depleted via ion exchange as the influent contacts the AIX and CIX.
    Type: Grant
    Filed: December 14, 2010
    Date of Patent: July 30, 2013
    Assignee: General Electric Company
    Inventor: John H. Barber
  • Patent number: 8313630
    Abstract: Method for the removal of ions and ionizable substances from a polar liquid (10) comprising at least one process wherein said polar liquid (10) is split into a first stream (F1) and a second stream (F2), Said first stream (F1) passing through an electrochemically regenerable ion-exchange material (2) located where an electric field between two electrodes (4, 5) is applied, said first stream (F1) flowing from one electrode (4) to the other electrode (5) so that the ions to be removed are migrating in the direction reverse to the first stream flow through said ion-exchange material (2), Said second stream (F2) rinsing said one electrode (4), and said material is regenerated by the ions which are formed at the other electrode (5). Device in particular for the implementation of said method.
    Type: Grant
    Filed: December 28, 2009
    Date of Patent: November 20, 2012
    Assignee: EMD Millipore Corporation
    Inventor: Andrej Grabowski
  • Patent number: 8293099
    Abstract: Apparatus and method for detecting current or potential generated in a liquid sample suitable for use in a chromatography or other liquid sample analytical system. One embodiment is an electrolytic ion transfer device with a signal detector in communication with the electrodes of the transfer device. Another is a combination ion transfer device/electrolyte generator. Another substitutes a detector for the ion transfer device in the combination.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: October 23, 2012
    Assignees: Dionex Corporation, Board of Regents, The University of Texas System
    Inventors: Purnendu K. Dasgupta, Bingcheng Yang, Kannan Srinivasan
  • Patent number: 8246804
    Abstract: A method for the treatment of an aqueous stream containing both anionic and cationic species is provided. The method comprises the following steps. Circulating water continuously through an essentially closed loop, the loop incorporating an ion adsorption unit which, in turn, comprises a water permeable layer of an ion adsorbing material. Feeding an aqueous solution containing the anionic and the cationic species to the essentially closed loop. Passing the circulating water, including the aqueous solution containing the ionic and the cationic species, through the ion adsorbing material in the ion adsorption unit in a continuous manner. While at the same time applying an electric potential across the thickness of the layer of ion adsorbing material and removing from the ion adsorption unit more concentrated aqueous solutions of the separate ionic species. Discharging each of the aqueous solutions from the ion adsorption unit.
    Type: Grant
    Filed: September 10, 2004
    Date of Patent: August 21, 2012
    Assignee: Edwards Limited
    Inventors: Christopher Peter Jones, Peter James Mawle
  • Publication number: 20120160693
    Abstract: An apparatus for manufacturing bichromal balls including first and second supply containers; a pair of microchannels for moving the first and second liquids; a pair of nozzles at which the microchannels contact each other; and an actuator, and a method for manufacturing bichromal balls using the same.
    Type: Application
    Filed: December 13, 2011
    Publication date: June 28, 2012
    Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.
    Inventors: Yong-Il KWON, Hwansoo Lee, Subong Jang, Seungjoo Shin, Younghoon Kwak
  • Publication number: 20100278695
    Abstract: The invention provides improved separation media for use in chromatography and electrophoresis, or for the selective absorption of certain components of a sample mixture, especially in a preliminary stage of an analysis. Improved media according to the invention comprises first particles capable or retaining one or more of the components of a sample mixture and second particles selected to have a higher thermal conductivity than the first particles, so that the thermal conductivity of the media is higher than that of media comprising the first particles alone. The media may be incorporated in packed or capillary columns for chromatography (especially nanoflow HPLC) or for capillary electrophoresis, or may be coated on a substrate. Particular embodiments of the media may comprise mixtures of first particles comprising siliceous polymers, second particles of gold, diamond or graphite. Chromatographic columns and apparatus incorporating them are also disclosed.
    Type: Application
    Filed: May 6, 2008
    Publication date: November 4, 2010
    Applicant: WATERS TECHNOLOGIES CORPORATION
    Inventors: David Alden Piper, Joseph A. Kareh
  • Patent number: 7780834
    Abstract: An apparatus and method for electrochemically modifying the retention of a species on a chromatography material is disclosed. The apparatus comprises a housing having an effluent flow channel adapted to permit fluid flow therethrough. The effluent flow channel comprises chromatography material. The apparatus further comprises first and second electrodes positioned such that at least a portion of the chromatography material is disposed between the first and second electrodes, and fluid flow through the apparatus is between, and in contact with, the first and second electrodes.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: August 24, 2010
    Assignee: Dionex Corporation
    Inventors: James M. Anderson, Jr., Raaidah Saari-Nordhaus, Carl W. Sims, Yuri E. Gerner
  • Publication number: 20100116656
    Abstract: An electrophoretic fluid separation structure (100) comprising a substrate (101) and a plurality of vertical nanowires (102) grown on the substrate (101).
    Type: Application
    Filed: April 17, 2008
    Publication date: May 13, 2010
    Applicant: NXP, B.V.
    Inventors: Pablo Garcia Tello, Vijaraghavan Madakasira
  • Patent number: 7632404
    Abstract: Ion transport apparatus (e.g. an electrolytic eluent generator or a suppressor for ion chromatography) in which ions in a first chamber are transported to a liquid in second chamber through a wall comprising an ion exchange bead sealed in a bead seat. The wall is capable of transport ions but of substantially blocking bulk liquid flow.
    Type: Grant
    Filed: November 15, 2007
    Date of Patent: December 15, 2009
    Assignees: Dionex Corporation, Board of Regents, The Univesity of Texas System
    Inventors: Purnendu K. Dasgupta, Bingcheng Yang, Kannan Srinivasan, Masaki Takeuchi
  • Publication number: 20090032401
    Abstract: Disclosed are a method and apparatus that use an electric field for improved biological assays. The electric field is applied across a device having wells, which receive reactants, which carry a charge. The device thus uses a controllable voltage source between the first and second electrodes, which is controllable to provide a positive charge and a negative charge to a given electrode. By controlled use of the electric field charged species in a fluid in a fluid channel are directed into or out of the well by an electric field between the electrodes. The present method involves the transport of fluids, as in a microfluidic device, and the electric field-induced movement of reactive species according to various assay procedures, such as DNA sequencing, synthesis or the like.
    Type: Application
    Filed: July 10, 2008
    Publication date: February 5, 2009
    Applicant: The Board of Trustees of the Leland Stanford Junior University
    Inventors: Mostafa Ronaghi, Tarun Khurana, Juan G. Santiago
  • Patent number: 7402283
    Abstract: An acid or base is generated in an aqueous solution by the steps of: (a) providing a source of first ions adjacent an aqueous liquid in a first acid or base generation zone, separated by a first barrier (e.g., anion exchange membrane) substantially preventing liquid flow and transporting ions only of the same charge as said first ions, (b) providing a source of second ions of opposite charge adjacent an aqueous liquid in a second acid or base generation zone, separated by a second barrier transporting ions only of the same charge as the second ions, and (c) transporting ions across the first barrier by applying an electrical potential through said first and second zones to generate an acid-containing aqueous solution in one of said first or second zones and a base-containing aqueous solution in the other one which may be combined to form a salt. Also, electrolytic apparatus for performing the above method.
    Type: Grant
    Filed: September 11, 2002
    Date of Patent: July 22, 2008
    Assignee: Dionex Corporation
    Inventors: Yan Liu, Nebojsa Avdalovic
  • Patent number: 7364646
    Abstract: An apparatus and method for electrochemically modifying the retention of a species on a chromatography material is disclosed. The apparatus comprises a housing having an effluent flow channel adapted to permit fluid flow therethrough. The effluent flow channel comprises chromatography material. The apparatus further comprises first and second electrodes positioned such that at least a portion of the chromatography material is disposed between the first and second electrodes, and fluid flow through the apparatus is between, and in contact with, the first and second electrodes.
    Type: Grant
    Filed: May 1, 2003
    Date of Patent: April 29, 2008
    Assignee: Dionex Corporation
    Inventors: James M. Anderson, Jr., Raaidah Saari-Nordhaus, Carl W. Sims, Yuri E. Gerner
  • Patent number: 7288176
    Abstract: A method and apparatus is provided for generating a high purity eluant suitable for use in chromatography. The high purity eluant may be generated by providing water and a first stationary phase comprising exchangeable cations. Electrolysis ions are generated by the electrolysis of water. The electrolysis ions are selected from the group consisting of hydronium ions and hydroxide ions. The hydronium ions are passed through the first stationary phase so that the hydronium ions replace the cations in the first stationary phase. Thereafter, a source of desired ions is combined with the cations to form a high purity eluant containing the desired ions.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: October 30, 2007
    Assignee: Dionex Corporation
    Inventors: James M. Anderson, Jr., Raaidah Saari-Nordhaus
  • Patent number: 7153476
    Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: December 26, 2006
    Assignee: Dionex Corporation
    Inventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
  • Patent number: 6955922
    Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: October 18, 2005
    Assignee: Dionex Corporation
    Inventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
  • Publication number: 20040130851
    Abstract: A staged or serial deionization system is described. The system includes N deionization subsystems. The system has a charging state for deionizing fluid and a discharging state for deionizing the respective deionization subsystem. In the charging state, ionized fluid is discharged serially. In the discharging state, N deionization subsystems are discharged in parallel, thereby reducing the ecological impact of the discharge brine.
    Type: Application
    Filed: October 27, 2003
    Publication date: July 8, 2004
    Inventor: Sadeg M. Faris
  • Patent number: 6682701
    Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: January 27, 2004
    Assignee: Dionex Corporation
    Inventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
  • Publication number: 20030209439
    Abstract: An apparatus and method for electrochemically modifying the retention of a species on a chromatography material is disclosed. The apparatus comprises a housing having an effluent flow channel adapted to permit fluid flow therethrough. The effluent flow channel comprises chromatography material. The apparatus further comprises first and second electrodes positioned such that at least a portion of the chromatography material is disposed between the first and second electrodes, and fluid flow through the apparatus is between, and in contact with, the first and second electrodes.
    Type: Application
    Filed: May 1, 2003
    Publication date: November 13, 2003
    Applicant: Alltech Associates, Inc.
    Inventors: James M. Anderson, Raaidah Saari-Nordhaus, Carl W. Sims, Yuri E. Gerner
  • Patent number: 6610186
    Abstract: The invention concerns a method for separating particles or molecules whereby these particles or molecules are introduced in a separating medium and a moving force is applied to them in said medium. The method is characterised in that the separating medium is a ferrofluid, i.e. a colloidal suspension of magnetic particles and a magnetic field is applied to this ferrofluid generating therein at least an alternation of a zone rich in magnetic particles and a zone poor in magnetic particles, part at least of the region of the ferrofluid in which this alternation is generated is passed through by the particles or molecules to be separated during their migration.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: August 26, 2003
    Assignee: Centre National de la Recherche Scientifique (CNRS)
    Inventors: Pascal Mayer, Jérôme Bibette, Jean-Louis Viovy
  • Patent number: 6495015
    Abstract: An electrokinetic pump capable of producing high pressure is combined with a nozzle having a submicron orifice to provide a high pressure spray device. Because of its small size, the device can be contained within medical devices such as an endoscope for delivering biological materials such as DNA, chemo therapeutic agents, or vaccines to tissues and cells.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: December 17, 2002
    Assignee: Sandia National Corporation
    Inventors: Joseph S. Schoeniger, Phillip H. Paul, Luke Schoeniger
  • Publication number: 20020182741
    Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.
    Type: Application
    Filed: June 21, 2002
    Publication date: December 5, 2002
    Applicant: Dionex Corporation
    Inventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
  • Publication number: 20020177233
    Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.
    Type: Application
    Filed: June 21, 2002
    Publication date: November 28, 2002
    Applicant: Dionex Corporation
    Inventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
  • Patent number: 6485624
    Abstract: The invention relates to a process and apparatus for the capacitive demineralization of liquids containing ions in which, after introducing the liquid into a container, an electric field is applied to capacitor plates (8, 9), which leads to ions of the liquid being conducted through a filter wall (7). The ions conducted through are deposited on the capacitor plates (8, 9) as bilayers (15, 16). By introducing pulsed voltage peaks, microcrystalline structures which result from ionic compounds are precipitated and then removed from the apparatus (1).
    Type: Grant
    Filed: April 9, 2001
    Date of Patent: November 26, 2002
    Inventors: Uwe Pfefferle, Alois Sitter
  • Patent number: 6423199
    Abstract: An electrochemical ion exchange cell comprises a metal carbollide as ion exchange material. The carbollide is preferably a polynuclear cobalt dicarbollide and is typically substituted by chlorine. Also novel are polynuclear metal carbollides comprising a substituted carbollide cage, as well as metal carbollides comprising a carbollide cage substituted by a moiety having a —COOH or —SH group.
    Type: Grant
    Filed: April 10, 2000
    Date of Patent: July 23, 2002
    Assignee: British Nuclear Fuels plc
    Inventors: Nigel Dennis Tinker, James Darcy McKinney, Simon James Richards
  • Publication number: 20020084188
    Abstract: An electrically regeneratable battery of electrochemical cells for capacitive deionization (including electrochemical purification) and regeneration of electrodes is operated at alternate polarities during consecutive cycles. In other words, after each regeneration step operated at a given polarity in a deionization-regeneration cycle, the polarity of the deionization step in the next cycle is maintained. In one embodiment, two end electrodes are arranged one at each end of the battery, adjacent to end plates. An insulator layer is interposed between each end plate and the adjacent end electrode. Each end electrode includes a single sheet of conductive material having a high specific surface area and sorption capacity, preferably a sheet formed of carbon aerogel composite. The battery further includes a plurality of generally identical double-sided intermediate electrodes that are equidistally separated from each other, between the two end electrodes.
    Type: Application
    Filed: January 3, 2002
    Publication date: July 4, 2002
    Applicant: The Regents of the University of California.
    Inventors: Tri D. Tran, David J. Lenz
  • Patent number: 6395143
    Abstract: The invention relates to a system, process and apparatus for separating biosorbent and sorbate. Biomass enclosed within a membrane system is coupled to an electrode, which is capable of being placed in contact with the sorbate containing material in the presence of a counter electrode. An electric field may be discharged across the electrodes and ionic species will migrate into the membrane enclosed system. The migrated species within the membrane can be taken up and processed by the biosorbtive processes of the biomass. The system may be used to remove dye stuffs, metal, heavy metals, radionuclides and other pollutants from natural and artificial sources.
    Type: Grant
    Filed: August 18, 1999
    Date of Patent: May 28, 2002
    Assignee: University of Ulster
    Inventors: Anthony McHale, Mark Bustard
  • Patent number: 6387243
    Abstract: A method for separating metal ions absorbed on a resin includes: suspending or percolating a cationic exchange resin charged with a polar solvent containing an eluting agent or a mixture of eluting agents containing at least an organic or mineral ligand complexing the metal ions to be separated; circulating a direct electric current, whether constant or not, in the charged eluting solution forming an electrolyte so as to recuperate at least a metal by deposition; and finally optionally repeating the last step by setting up one or several cathode(s) made of another metal and by re-adjusting the cathode potential and the anode/cathode potential difference to new values, depending on the new type of metal to be recuperated. An installation for treating/recycling photographic bath waste includes an exchanger connected to a tank for waste bath to be treated, to a treated waste bath tank, to a regenerating solution tank and to an electrolysis vessel.
    Type: Grant
    Filed: December 14, 1999
    Date of Patent: May 14, 2002
    Inventor: Gerard Gasser
  • Publication number: 20020029957
    Abstract: The invention relates to a system, process and apparatus for separating biosorbent and sorbate. Biomass enclosed within a membrane system is coupled to an electrode, which is capable of being placed in contact with the sorbate containing material in the presence of a counter electrode. An electric field may be discharged across the electrodes and ionic species will migrate into the membrane enclosed system. The migrated species within the membrane can be taken up and processed by the biosorbtive processes of the biomass. The system may be used to remove dye stuffs, metal, heavy metals, radionuclides and other pollutants from natural and artificial sources.
    Type: Application
    Filed: August 18, 1999
    Publication date: March 14, 2002
    Inventors: ANTHONY MCHALE, MARK BUSTARD
  • Publication number: 20020017463
    Abstract: The present invention is directed to an apparatus and method for deionization and hydrogen fuel production in a fuel generation mode, and electricity production in a power generation mode. In one embodiment, a capacitive deionization (CDI) device receives water and electrical energy to produce deionized water that is transferred to a proton electrode membrane electrolysis (PEME) device to produce hydrogen fuel by electrolysis. A storage system receives the hydrogen. The hydrogen is transferred from the storage system to a proton electrode membrane fuel cell (PEMFC) device that produces electrical energy. In another embodiment, the PEME and the PEMFC are functionally combined in a unitary regenerative fuel cell (URFC). In still another embodiment, a humidification unit and the CDI are functionally combined. In yet another embodiment, a CDI, URFC and the humidification unit are combined in a single unitary assembly.
    Type: Application
    Filed: June 5, 2001
    Publication date: February 14, 2002
    Inventor: Walter Roberto Merida-Donis
  • Patent number: 6316270
    Abstract: A method for generating high purity acid or base in an aqueous stream for use as an eluent for chromatography and, particularly, ion chromatography. For generating a base for anion chromatography, the aqueous stream is directed through a cation exchange bed having a first strongly acidic and a second weakly acidic portions. An electrical potential is applied to the bed. Cations on the bed electromigrate into the aqueous stream while hydroxide ions are electrolytically generated to form a base-containing eluent. Anions to be detected and the generated eluent flow through a chromatographic separator. The chromatographic effluent flows past a detector.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: November 13, 2001
    Assignee: Dionex Corporation
    Inventors: Hamish Small, Nebojsa Avdalovic, Yan Liu
  • Patent number: 6290909
    Abstract: Apparatus and method for driving a sample, having a well-defined volume, under pressure into a chromatography column. A conventional high pressure sampling valve is replaced by a sample injector composed of a pair of injector components connected in series to a common junction. The injector components are containers of porous dielectric material constructed so as to provide for electroosmotic flow of a sample into the junction. At an appropriate time, a pressure pulse from a high pressure source, that can be an electrokinetic pump, connected to the common junction, drives a portion of the sample, whose size is determined by the dead volume of the common junction, into the chromatographic column for subsequent separation and analysis. The apparatus can be fabricated on a substrate for microanalytical applications.
    Type: Grant
    Filed: April 13, 2000
    Date of Patent: September 18, 2001
    Assignee: Sandia Corporation
    Inventors: Phillip H. Paul, Don W. Arnold, David W. Neyer
  • Patent number: 6284124
    Abstract: Electrodeionization apparatus and method. The electrodeionization apparatus includes an ion-depleting compartment in which alternating layers of an electroactive media are positioned. One of the alternating layers is doped to provide a more balanced current distribution through the apparatus. The method involves reducing the difference in conductivity between the alternating layers positioned in the ion-depleting compartment by adding a dopant material to one of the layers.
    Type: Grant
    Filed: January 29, 1999
    Date of Patent: September 4, 2001
    Assignee: United States Filter Corporation
    Inventors: Felice DiMascio, Anil Jha, Gary C. Ganzi, Frederick Wilkins
  • Patent number: 6277257
    Abstract: An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based systems. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (Microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.
    Type: Grant
    Filed: March 18, 1999
    Date of Patent: August 21, 2001
    Assignee: Sandia Corporation
    Inventors: Phillip H. Paul, David J. Rakestraw, Don W. Arnold, Kenneth R. Hencken, Joseph S. Schoeniger, David W. Neyer
  • Patent number: 6265224
    Abstract: The present invention relates to methods in which ion exchange resins are used to reduce the amount of substances which interfere with nucleic acid hybridization in samples. The methods also stabilize the samples. Kits containing the ion exchange resins render the methods convenient to use.
    Type: Grant
    Filed: June 9, 1999
    Date of Patent: July 24, 2001
    Assignee: Becton, Dickinson and Company
    Inventors: Matthew P. Collis, Anne B. Brown, Oscar J. Llorin, Thomas L. Fort
  • Patent number: 6224728
    Abstract: A valve for controlling fluid flows. This valve, which includes both an actuation device and a valve body provides: the ability to incorporate both the actuation device and valve into a unitary structure that can be placed onto a microchip, the ability to generate higher actuation pressures and thus control higher fluid pressures than conventional microvalves, and a device that draws only microwatts of power. An electrokinetic pump that converts electric potential to hydraulic force is used to operate, or actuate, the valve.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: May 1, 2001
    Assignee: Sandia Corporation
    Inventors: Michael C. Oborny, Phillip H. Paul, Kenneth R. Hencken, Gregory C. Frye-Mason, Ronald P. Manginell
  • Patent number: 6225129
    Abstract: Method and apparatus for generating an acid or base, e.g. for chromatographic analysis of anions. For generating a base the method includes the steps of providing a cation source in a cation source reservoir, flowing an aqueous liquid stream through a base generation chamber separated from the cation source reservoir by a barrier (e.g. a charged membrane) substantially preventing liquid flow while providing a cation transport bridge, applying an electric potential between an anode cation source reservoir and a cathode in the base generation chamber to electrolytically generate hydroxide ions therein and to cause cations in the cation source reservoir to electromigrate and to be transported across the barrier toward the cathode to combine with the transported cations to form cation hydroxide, and removing the cation hydroxide in an aqueous liquid stream as an effluent from the first base generation chamber. Suitable cation sources include a salt solution, a cation hydroxide solution or cation exchange resin.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: May 1, 2001
    Assignee: Dionex Corporation
    Inventors: Yan Liu, Hamish Small, Nebojsa Avdalovic
  • Patent number: 6214204
    Abstract: An electrode for deionization of water is made of a continuous activated carbon structure. The activated carbon is derived from a synthetic carbon precursor. The structure has openings, inlet and outlet ends such that water entering the inlet end passes through the openings and exits through the outlet end, a conductive coating on at least part of the outer surface of the structure, and a metal wire in contact with the structure. A deionization system is made up of the electrodes in series so that the outlet end of one electrode is next to the inlet end of the nearest downstream electrode. The metal wire of each electrode is connected to a power source to deliver the opposite charge as the charge delivered to its neighboring electrodes. Each of the electrodes is fixedly attached to and sealed within a housing with an air and moisture-tight seal. Openings in the housing between the electrodes, allow air to be removed before use.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: April 10, 2001
    Assignee: Corning Incorporated
    Inventors: Kishor P. Gadkaree, Joseph F. Mach, John L. Stempin
  • Patent number: 6074537
    Abstract: A method and apparatus concentrates, collects and removes heavy metals, other cations, and anions from media permitting generation of electrical fields. The heavy metals and other cations are electrochemically concentrated and precipitated for rapid removal from the aqueous media. The media, which may be aqueous, soils or wastes, is filtered and passed through a cation or anion exchange resin beds. Metals or anions are captured and held in the resin beds. Current is then applied through the resin beds using opposing electrodes of opposite polarity. In the metal removal units, heavy metals and other cations are concentrated around the negative electrode and lifted to a top of the electrode chamber using hydrogen gas lift. The concentrated solution of heavy metals and cations are removed from the chamber above the negative electrode and are circulated to provide additional time for growth and precipitation.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: June 13, 2000
    Assignee: Compliance Consultants, Inc.
    Inventors: Robert E. Marks, Stephen D. Field, Mary Madden Field
  • Patent number: 6036921
    Abstract: An apparatus for generating high purity acid or base in an aqueous stream for use as an eluent for chromatography and, particularly, ion chromatography. For generating a base for anion chromatography, the aqueous stream is directed through a cation exchange bed. An electrical potential is applied to the bed. Cations on the bed electromigrate into the aqueous stream while hydroxide ions are electrolytically generated to form a base-containing eluent. Anions to be detected and the generated eluent flow through a chromatographic separator and a detector. In one embodiment, between separation and detection, the separated anion stream flows through a second cation exchange bed with no electrical potential applied. The second bed serves as a suppressor. After completion of the desired number of cycles, flow through the first and second cation exchange beds may be reversed by appropriate valving for the next sample stream.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: March 14, 2000
    Assignee: Dionex Corporation
    Inventors: Hamish Small, Nebojsa Avdalovic, Yan Liu
  • Patent number: 6019882
    Abstract: A compact high pressure hydraulic pump having no moving mechanical parts for converting electric potential to hydraulic force. The electrokinetic pump, which can generate hydraulic pressures greater than 2500 psi, can be employed to compress a fluid, either liquid or gas, and manipulate fluid flow. The pump is particularly useful for capillary-base systems. By combining the electrokinetic pump with a housing having chambers separated by a flexible member, fluid flow, including high pressure fluids, is controlled by the application of an electric potential, that can vary with time.
    Type: Grant
    Filed: April 7, 1998
    Date of Patent: February 1, 2000
    Assignee: Sandia Corporation
    Inventors: Phillip H. Paul, David J. Rakestraw
  • Patent number: 6013164
    Abstract: A compact high pressure hydraulic system having no moving parts for converting electric potential to hydraulic force and for manipulating fluids. Electro-osmotic flow is used to provide a valve and means to compress a fluid or gas in a capillary-based system. By electro-osmotically moving an electrolyte between a first position opening communication between a fluid inlet and outlet and a second position closing communication between the fluid inlet and outlet the system can be configured as a valve. The system can also be used to generate forces as large as 2500 psi that can be used to compress a fluid, either a liquid or a gas.
    Type: Grant
    Filed: June 25, 1997
    Date of Patent: January 11, 2000
    Assignee: Sandia Corporation
    Inventors: Phillip H. Paul, David J. Rakestraw
  • Patent number: 5980718
    Abstract: A fuse and filter arrangement for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: November 9, 1999
    Assignee: The Regents of the University of California
    Inventors: Richard A. Van Konynenburg, Joseph C. Farmer
  • Patent number: 5958213
    Abstract: A water treating apparatus for treating water, includes: an oil drop separator for separating oil drops from water to be treated which has an electrode in which an anode is made of amphoteric metal, a power source for supplying an electric power to the electrode, a treating tank for housing the electrode and the water, a water inlet through which the water is led to the treating tank, and a water outlet through which the treated water is exhausted from the treating tank; and a three-dimensional fixed bed type electrolytic tank for treating the water which has been treated by the oil drop separator which has a fixed bed type electrode, a power source for supplying an electric power in which a polarity is reversed periodically, to the fixed bed type electrode, a treating tank for housing the fixed bed type electrode and the water, a water inlet through which the water is led to the treating tank, and a water outlet through which the treated water is exhausted from the treating tank.
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: September 28, 1999
    Assignee: Konica Corporation
    Inventor: Nobutaka Goto
  • Patent number: 5954936
    Abstract: The invention provides a method and processing system for removing both anionic and cationic technetium complexes from an aqueous solution by adjusting the pH of the solution to greater than approximately 2, and directing the solution into an integrated resin and electrochemical plating device. The integrated resin and plating device has a resin bed or resin membrane in which is disposed one or more cathodes, and one or more anodes. A potential generator produces at least a 1 volt potential between the cathodes and the anodes. As the solution passes through the resin, the technetium complexes are adsorbed onto it. When a sufficient concentration of technetium complexes is adsorbed, the plating process can atlernatively be driven to plate out the technetium onto the cathodes, or to collect various species in system anolytes/catholytes.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: September 21, 1999
    Assignee: Scientific Ecology Group, Inc.
    Inventors: Thomas Stephen Snyder, David Charles Grant