Involving Fuel Cell Patents (Class 205/343)
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Patent number: 6912450Abstract: A hydrogen fuel supply system includes a hydrogen generator for generating hydrogen from an energy source at an outlet pressure. An outlet conduit feeds the hydrogen to a user. A controller controls the hydrogen generator to produce hydrogen at the outlet pressure. An input interface receives user demand data and activates the controller in accordance with the user demand data.Type: GrantFiled: April 22, 2004Date of Patent: June 28, 2005Assignee: Stuart Energy Systems Corp.Inventors: Matthew J. Fairlie, William J. Stewart, Andrew T. B. Stuart, Steven J. Thorpe, Charlie Dong
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Patent number: 6841292Abstract: A method and apparatus estimate hydrogen concentration in a reformate stream produced by a fuel processor of a fuel cell. A sensor measures carbon monoxide, carbon dioxide, and water in the reformate stream. A fuel meter controls fuel input to the fuel processor. An air meter controls air input to the fuel processor. A water meter controls water input to the fuel processor. A transport delay estimator recursively estimates transport delay of the fuel processor. A hydrogen estimator associated with the transport delay estimator, the air, water and fuel meters, and the sensor estimates hydrogen concentration in the reformate stream. The hydrogen estimator includes a fuel processor model that is adjusted using the estimated transport delay. The carbon monoxide, the carbon dioxide and the water are measured using a nondispersive infrared (NDIR) sensor.Type: GrantFiled: May 14, 2004Date of Patent: January 11, 2005Assignee: General Motors CorporationInventors: Patricia J. Nelson, Manish Sinha
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Patent number: 6822124Abstract: A method for producing alcoxylated carbonyl compounds of general formula (I) (compounds I): R1aR2C(OR3)b wherein R1, R2 represent hydrogen or C1-C6-alkyl, R3 independently means C1-C6-alkyl, a is 0 or 1, b 2 or 3 with the proviso that the sum of a and b is 3, by means of anodic oxidation of germinal dialcoxy compounds of general formula (II) (compounds II) wherein R4, R5, R6, R7 represent hydrogen or C1-C6-alkyl, R5, R6 represent C1-C6-alkyl or C1-C6-alcoxy, in the presence of a C1-C6-alkyl alcohol (compounds III). A usual compound (compound IV) is used as a cathodic depolarizer suitable for electrochemical oxidation. The anodic oxidation and cathodic reduction is carried out in an undivided electrolyte cell in the presence of C1-C6-alkyl alcohols.Type: GrantFiled: May 22, 2003Date of Patent: November 23, 2004Assignee: BASF AktiengesellschaftInventors: Hermann PĆ¼tter, Andreas Fischer
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Publication number: 20040217011Abstract: The present invention relates to a bipolar plate for fuel cells, comprising at least a shaped, at least partially electrically conductive foil (1), the bipolar plate having a channel structure (5) formed by the shaping of the foil (1), to convey reactants to electrodes of adjacent fuel cells and to carry away reaction products, and a microstructure (4) is integrated into the foil (1) to increase the rigidity of the foil (1). The invention also relates to a method for manufacturing corresponding bipolar plates.Type: ApplicationFiled: March 31, 2004Publication date: November 4, 2004Inventors: Raimund Strobel, Bernd Gaugler, Ludwig Jorissen, Kurt Hohe, Joachim Scherer, Dominique Tasch
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Publication number: 20040209132Abstract: A method and apparatus estimate hydrogen concentration in a reformate stream produced by a fuel processor of a fuel cell. A sensor measures carbon monoxide, carbon dioxide, and water in the reformate stream. A fuel meter controls fuel input to the fuel processor. An air meter controls air input to the fuel processor. A water meter controls water input to the fuel processor. A transport delay estimator recursively estimates transport delay of the fuel processor. A hydrogen estimator associated with the transport delay estimator, the air, water and fuel meters, and the sensor estimates hydrogen concentration in the reformate stream. The hydrogen estimator includes a fuel processor model that is adjusted using the estimated transport delay. The carbon monoxide, the carbon dioxide and the water are measured using a nondispersive infrared (NDIR) sensor.Type: ApplicationFiled: May 14, 2004Publication date: October 21, 2004Inventors: Patricia J. Nelson, Manish Sinha
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Patent number: 6800386Abstract: A process for preparing hydrogen in a fuel processor assembly containing a device for supplying a high voltage electrical discharge within the fuel processor, a first catalytic body disposed within the fuel processor, and a second catalytic body disposed within the fuel processor. Each of the catalytic bodies have different shapes.Type: GrantFiled: February 25, 2002Date of Patent: October 5, 2004Assignee: Nanoset, LLCInventors: Xingwu Wang, Huihui Duan, Bigang Min
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Publication number: 20040188270Abstract: A mixed hydrogen-oxygen fuel generator system uses an electrolytic solution to generate gaseous hydrogen-oxygen fuel through the electrolysis of water. This generator system includes: at least one electrolytic cell with multiple metallic plates used as an internal isolation system in which two of the plates separately connect to both the positive and negative terminal of a DC circuit. These plates are used for the electrolysis of the electrolytic solution in the cell(s) to produce, under pressure, mixed hydrogen-oxygen fuel. The apparatus also includes a cooling system containing a water cooling tank in which there are two zones: one is the electrolytic solution circulation coil and the another is a water circulation zone.Type: ApplicationFiled: April 5, 2004Publication date: September 30, 2004Inventors: Nai Sung Chou, Choi Shiu Sum, Chou Te-Hung, Hui Lin
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Patent number: 6770186Abstract: A hydrogen-fueled motor vehicle including at least one hydrogen-fueled locomotion subsystem and at least one refuelable hydrogen generator operative to supply hydrogen fuel to the hydrogen-fueled locomotion subsystem on demand. The refuelable hydrogen generator includes at least one electrochemical reactor operative to generate the hydrogen fuel from water on demand and a refueling subsystem providing at least one of water, electrolyte, hydrogen, a metal containing material and electrical power to the electrochemical reactor. A refueling method is also provided.Type: GrantFiled: November 13, 2001Date of Patent: August 3, 2004Assignee: Eldat Communication Ltd.Inventors: Oren Rosenfeld, Jonathan Russell Goldstein, Nimrod Sandeerman
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Patent number: 6764588Abstract: A method of and system for flushing one or more cells or components thereof in a particle-based electrochemical power source is provided. Reaction solution is delivered to and withdrawn from the one or more cells when the electrochemical power source is in a standby mode of operation.Type: GrantFiled: May 17, 2002Date of Patent: July 20, 2004Assignee: Metallic Power, Inc.Inventors: Stuart I. Smedley, Donald James Novkov, Kent I. Smedley, Raymond H. Alstadt, Frederick R. Grochulski
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Patent number: 6756141Abstract: A fuel cell includes an anode electrode, a cathode electrode, and a third electrode interposed between the anode and the cathode electrodes. The third electrode preferably includes an electrically conductive component. The third electrode preferably includes a metallic and a polymer grid and/or a conducting polymer. The third electrode may be used to control processes of the anode and/or the cathode electrodes. The third electrode may also be used to monitor the health of any component of the fuel cell.Type: GrantFiled: December 28, 2001Date of Patent: June 29, 2004Assignee: Southwest Research InstituteInventors: Michael A. Miller, Craig M. Wall
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Patent number: 6745105Abstract: An energy distribution network is provided including an energy source; a hydrogen production facility connected to the energy source; a recipient for hydrogen from the hydrogen production facility; and a controller. The controller controls the production of hydrogen by the hydrogen production facility based on inputs including energy resource availability.Type: GrantFiled: September 1, 1999Date of Patent: June 1, 2004Assignee: Stuart Energy Systems CorporationInventors: Matthew J. Fairlie, William J. Stewart, Andrew T. B. Stuart, Steven J. Thorpe, Charlie Dong
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Publication number: 20040068865Abstract: The present invention provides high-throughput systems and methods for the fabrication and evaluation of electrode and electrolyte materials for solid oxide fuel cells. The present invention includes systems and methods for synthesizing and optimizing the performance of electrodes and electrode-electrolyte combinations and utilizes small-scale techniques to perform such optimization based on chemical composition and variable processing. Advantageously, rapid device performance systems and methods coupled with structural and surface systems and methods allow for an increased discovery rate of new materials for solid oxide fuel cells.Type: ApplicationFiled: October 10, 2002Publication date: April 15, 2004Inventors: John Lemmon, Chang Wei, Venkat Venkataramani, James Ruud, Wayne Hasz, Anthony Thompson, Curtis Johnson, Oltea Siclovan, Canan Hardwicke, Stephen Ruthowski, Melvin Jackson, Michael Pilliod
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Patent number: 6695963Abstract: Disclosed is an organic electrolysis reactor for performing an electrolytic oxidation reaction of a system comprising a substrate and a reductant, comprising: a casing; an anode which comprises an anode active material and which is ion-conductive or active species-conductive; a cathode which comprises a cathode active material and which is ion-conductive or active species-conductive; and means for applying a voltage between the anode and the cathode, wherein the means for applying a voltage is disposed in the outside of the casing and connected to the anode and the cathode, wherein the anode and the cathode are disposed in spaced relationship in the casing to partition the inside of the casing into an intermediate compartment between the anode and the cathode, and an anode compartment on the outside of the anode.Type: GrantFiled: October 9, 2001Date of Patent: February 24, 2004Assignee: Asahi Kasei Kabushiki KaishaInventors: Kiyoshi Otsuka, Ichiro Yamanaka, Ken Suzuki
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Patent number: 6685818Abstract: A process for the electrochemical preparation of hydrogen peroxide, in particular an aqueous hydrogen peroxide solution, by the electrochemical reaction of oxygen and hydrogen in a fuel cell. By increasing the thickness of the membrane layer in a membrane electrode unit (MEU) in the fuel cell, it is possible to substantially increase the concentration of H2O2 in the aqueous hydrogen peroxide solution obtained at the cathode.Type: GrantFiled: September 25, 2001Date of Patent: February 3, 2004Assignee: Degussa AGInventors: Thomas Lehmann, Patrik Stenner
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Publication number: 20040016650Abstract: The invention relates to a method and devices for the chemical reaction of liquid, vapor or gaseous hydrocarbons with either water or water vapor and either air or oxygen, to produce a hydrogen-rich synthesized gas for use in fuel cells. In the process, the chemical reaction of the reactants takes place on the catalytically coated surface of a material that is electrically conductive, and as a consequence of the feeding an electrical voltage, directly heatable and consequently temperature-controllable.Type: ApplicationFiled: July 29, 2002Publication date: January 29, 2004Inventor: Karl H. Klug
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Publication number: 20040007476Abstract: A method and apparatus for the generation and collection of an aqueous peracid solution at the cathode of a PEM electrolyzer. The electrochemical process introduces carboxylic acid (such as distilled table vinegar, lactic acid, citric acid or combinations) to the anode and a source of oxygen to the cathode. The PEM electrolyzer has a gas diffusion cathode having a cathodic electrocatalyst that is capable of hydrogen peroxide generation. The peracid solution is generated at the gas diffusion cathode and the solution is very pure and may be used for disinfecting or sterilizing various items or solutions. In a second embodiment, the carboxylic acid may be provided directly to the cathode, such as in the form of an acid vapor.Type: ApplicationFiled: July 9, 2002Publication date: January 15, 2004Inventors: Charles L. K. Tennakoon, K. Scott McKenzie, Michelle Will, Elizabeth I.H. McGrew
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Patent number: 6620537Abstract: A hydrocarbon fueled hydrogen generator and hydrogen fueled electric power generating system and apparatus comprising hydrocarbon fuel and oxidizer delivery and mixing apparatus, ignition and combustion apparatus igniting the mixture of fuel and oxidizer, apparatus receiving and conducting the gases of combustion through a sulfur absorbing unit and removing sulfur from the gases, a steam reformer unit reforming carbon monoxide gas into hydrogen gas and carbon dioxide gas, a carbon monoxide scavenger unit reforming residual carbon monoxide gas to hydrogen gas and carbon dioxide gas; apparatus receiving the hydrogen gas and carbon dioxide gas and operating to liquefy and separate the carbon dioxide gas from the hydrogen gas; and, structure to hold and deliver the liquid carbon dioxide to useful end; and structure to hold and deliver hydrogen gas to the anode of a hydrogen fueled electric power generating fuel cell.Type: GrantFiled: February 15, 2001Date of Patent: September 16, 2003Inventors: Ralph C. Struthers, Georges A. Maxwell
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Patent number: 6592741Abstract: A metal hydride is supplied into a reactor while being converted into fine particles. By injecting water from an injector, the metal hydride is hydrolyzed to generate hydrogen. The water supplied to the reactor is water generated by a fuel cell. This allows omission or a size reduction of a water tank for the hydrolysis, and therefore allows a size reduction of the system as a whole. It is possible to adopt a construction in which waste heat from the fuel cell is supplied to pyrolyze the metal hydride, a construction in which heat generated by the hydrolysis is used to pyrolyze another metal hydride, etc.Type: GrantFiled: June 29, 2001Date of Patent: July 15, 2003Assignee: Toyota Jidosha Kabushiki KaishaInventors: Haruyuki Nakanishi, Shinichi Matsumoto
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Patent number: 6555055Abstract: A system having a fluid source and a pasteurizer coupled with a disinfectant unit in flow communication with the fluid source for use in disinfecting dental or other water lines. The combination of pasteurizer and disinfectant unit is adapted to receive water from the fluid source. A fluid delivery unit is provided in flow communication with the pasteurizer and disinfectant unit combination. The disinfectant unit has a means for supplying hydrogen and oxygen and a means for generating hydrogen peroxide in flow communication with the means for supplying hydrogen and oxygen.Type: GrantFiled: July 30, 1999Date of Patent: April 29, 2003Assignee: Lynntech, Inc.Inventors: Alan J. Cisar, Adrain Denvir, G. Duncan Hitchens, Thomas D. Rogers
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Patent number: 6544400Abstract: A hydrogen source system delivers a controlled fuel stream to applications, using wicking to control the contact between a mixture of NaBH4, NaOH and H2O and a hydrolyzing catalyst to create a feedback mechanism to automatically maintain a constant pressure production supply of hydrogen. A small compact device packaged for storage, the system operates in any orientation and is mobile. The system is a small portable packaged hydrogen generator for small fuel cells to power applications that are currently powered by batteries. These packaged devices have higher energy per unit mass, higher energy per unit volume, are more convenient for energy users, environmentally less harmful, and less expensive than conventional power sources.Type: GrantFiled: March 30, 2001Date of Patent: April 8, 2003Assignee: Manhattan Scientifics, Inc.Inventors: Robert G. Hockaday, Patrick S. Turner, Marc D. DeJohn, Carlos J. Navas, Heathcliff L. Vaz, L. Luke Vazul
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Patent number: 6516905Abstract: A vehicle comprising a combustion engine capable of delivering mechanical power for driving at least one wheel drive shaft with driving wheels, auxiliary vehicular electric loads, an alternator powered by the combustion engine for generating electricity, an electric storage device for storing alternator generated electricity, and at least one auxiliary electric power supply for supplying electrical energy to said electric loads. The auxiliary electric power supply includes a fuel cell system with an anode fuel input and a cathode fuel input, and an electrolyzer which is capable of generating hydrogen and oxygen. The hydrogen production side of said electrolyzer is in fluid connection with the at least one anode fuel supply.Type: GrantFiled: August 24, 2001Date of Patent: February 11, 2003Assignee: Ballard Power Systems AGInventors: Rob Baumert, Craig Greenhill, Robert Hastings, Jim Smith
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Patent number: 6503648Abstract: A fuel cell assembly comprised of an electrostrictive device for producing an electrical current, a device for producing a conditioned electrical current by conditioning the electrical current so that the amplitude of the electrical current does not vary by more than about 10 percent, an electrolytic device for converting water to hydrogen and oxygen with the conditioned electrical current, and a fuel cell device for converting the oxygen and hydrogen into a direct electrical current.Type: GrantFiled: March 26, 2001Date of Patent: January 7, 2003Assignee: Biomed Solutions, LLCInventor: Xingwu Wang
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Publication number: 20020195334Abstract: An autonomous pushed liquid recirculation system (APLRS) is installed in a vessel, such as an electroplating tank. It situates around the interior perimeter and adjusts to changes in the level of liquid, maintaining the same location and orientation respective to the liquid's surface. It establishes a current near the surface that pushes liquid across the narrow horizontal dimension of the tank from a front wall to a rear wall. The current serves to push any bubbles resultant from operations within the tank to the rear wall. Over the rear wall is mounted an abbreviated exhaust hood covering only a short width of the surface of the tank along the rear wall. Because the exhaust system has to scavenge only a portion of the surface since all bubbles now burst along the rear wall, a much smaller air handling apparatus may be specified with an attendant savings in energy costs.Type: ApplicationFiled: August 20, 2002Publication date: December 26, 2002Inventors: Kent James Hay, Shaoying Qi
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Publication number: 20020195349Abstract: A method of storage and redistribution of electrical energy comprising the steps of: producing hydrogen and oxygen through water electrolysis in an electrolyzer (1) operating under pressure; collecting the hydrogen and oxygen so obtained in respective pressurized tanks (3, 5); reconverting into water and electrical energy hydrogen and oxygen, through an electrochemical reaction of the latter in a fuel cell (9) fed from the tanks (3, 5), distinguishes itself by the fact that in the electrolyzer (1) and in the fuel cell (9) a same liquid phase is used and by the fact that the water produced in the fuel cell (9) by the hydrogen and oxygen reconversion step, is collected in the respective liquid phase and transferred together with the liquid phase to the electrolyzer (1) in order to undergo electrolysis.Type: ApplicationFiled: May 29, 2002Publication date: December 26, 2002Applicant: CASALE CHEMICALS SAInventor: Sioli Giancarlo
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Patent number: 6497973Abstract: A system for generating and consuming borohydride ions comprising two electrochemical cells. At least one of the cells is configured for installation on a vehicle that is propelled by electricity.Type: GrantFiled: June 27, 1997Date of Patent: December 24, 2002Assignee: Millennium Cell, Inc.Inventor: Steven Amendola
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Patent number: 6495025Abstract: The method of producing O2 from water, that includes subjecting water to electrolysis, to produce H2 and O2, returning H2 to a water storage zone, drying the produced O2, using air as a drying agent, flowing a stream of that drying agent air to the cathode side of fuel cell, flowing a stream of produced hydrogen to the anode side of the fuel cell, for reaction with O2 in the agent air to produce water electrical energy and heat, and using electrical energy produced by fuel cell in the electrolysis.Type: GrantFiled: April 20, 2001Date of Patent: December 17, 2002Assignee: Aerovironment, Inc.Inventor: Omourtag Velev
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Patent number: 6448621Abstract: A novel technology for sensing mechanical quantities such as force, stress, strain, pressure and acceleration has been invented. This technology is based on a change in the electrochemically generated voltage (electromotive force) with application of force, stress, strain, pressure or acceleration. The change in the voltage is due to a change in the internal resistance of the electrochemical cell with a change in the relative position or orientation of the electrodes (anode and cathode) in the cell. The signal to be detected (e.g. force, stress, strain, pressure or acceleration) is applied to one of the electrodes to cause a change in the relative position or orientation between the electrodes. Various materials, solid, semisolid, gel, paste or liquid can be utilized as the electrolyte. The electrolyte must be an ion conductor. The examples of solid electrolytes include specific polymer conductors, polymer composites, ion conducting glasses and ceramics.Type: GrantFiled: June 2, 2000Date of Patent: September 10, 2002Inventor: Mrinal Thakur
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Patent number: 6423203Abstract: The invention describes a method for the direct connection of fuel cells to electrolyzers of electrochemical plants producing hydrogen as a by-product. The by-product hydrogen is fed to the fuel cells and the electric energy thereby produced is transferred to the electrolyzers, with the consequent saving of the overall energy consumption. The direct coupling avoids the need for DC/AC converters or voltage adjusters and may be effected either in series or in parallel. In the latter case the fuel cell are assembled in modules, the number and voltage of which is regulated by means of interrupters activated by a computerised control and supervision system. As an alternative, the voltage of the modules may be varied by varying the pressure of the air fed to the fuel cells.Type: GrantFiled: October 27, 2000Date of Patent: July 23, 2002Assignee: Nuvera Fuel Cells Europe S.r.l.Inventors: Giuseppe Faita, Angelo Ottaviani
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Publication number: 20020051898Abstract: An exemplary embodiment of the regenerative electrochemical cell system comprises: a fuel cell module comprising a fuel cell oxygen inlet in fluid communication a water storage device, and a fuel cell hydrogen inlet in fluid communication with both an oxygen source and with a gaseous portion of an water phase separation device; an electrolysis module comprising an electrolysis water inlet in fluid communication with the water storage device via a fuel cell oxygen outlet, and an electrolysis water outlet in fluid communication with the fuel cell hydrogen.Type: ApplicationFiled: September 28, 2001Publication date: May 2, 2002Inventors: Lawrence C. Moulthrop, Trent M. Molter, A. John Speranza, Mark A. Lillis, William Smith, Jason Shiepe, Thomas M. Skoczylas
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Publication number: 20020036147Abstract: A process for the electrochemical preparation of hydrogen peroxide, in particular an aqueous hydrogen peroxide solution, by the electrochemical reaction of oxygen and hydrogen in a fuel cell. By increasing the thickness of the membrane layer in a membrane electrode unit (MEU) in the fuel cell, it is possible to substantially increase the concentration of H2O2 in the aqueous hydrogen peroxide solution obtained at the cathode.Type: ApplicationFiled: September 25, 2001Publication date: March 28, 2002Inventors: Thomas Lehmann, Patrik Stenner
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Publication number: 20020025457Abstract: A system and method for the storage of electrical energy or of hydrogen, the method includes the steps of (a) electrolysis of water to yield hydrogen, (b) reaction of the hydrogen from step (a) with carbon dioxide to from at least one storage compound; (c) storage of the storage compound; and (d) subsequent conversion of the storage compound back to hydrogen or use of the storage compound to fuel an engine, such as an internal combustion engine, or to generate electricity directly or indirectly. One storage compound is methanol.Type: ApplicationFiled: April 27, 2001Publication date: February 28, 2002Inventors: Peter Jeremy Dodd, Alan Stockwell, Ian Duckels
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Publication number: 20020006535Abstract: An integrated power module for generating thermal and electrical power is provided within a housing which includes inlets for fuel and for air, a reformer chamber, a fuel cell stack, and a combustion chamber. Oxygen-containing gas, such as air, is introduced into the module along a path in one direction in heat exchange relationship with reaction products produced in the reaction chamber traveling in an adjacent path, preferably in an opposite direction, to preheat the incoming oxygen-containing gas. A nozzle having an injector for the fuel and for the oxygen-containing gas delivers these gases to the interior of the reformer chamber, where ignition is supplied by a suitable device. The reaction products from the reformer chamber are fed to a fuel cell which will consume certain of the reaction products, such as hydrogen gas, with oxygen provided from the reaction chamber acting as an oxidizing gas.Type: ApplicationFiled: March 12, 2001Publication date: January 17, 2002Inventors: Richard Woods, Leonard Greiner, David Moard
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Patent number: 6332968Abstract: Electrochemical processes using solid gas-impervious membranes are disclosed for gas cleanup by (A) providing an electrochemical cell comprising first and second zones separated by a solid gas-impervious membrane comprising a mixed metal oxide material of a perovskite structure having electron conductivity and oxygen ion conductivity, (B) passing a gas containing N2O, NO, NO2, SO2, SO3, or a mixture thereof, in contact with the membrane in the first zone, and (C) passing a gas capable of reacting with oxygen in contact with the membrane in the second zone. More particularly, the mixed metal oxide material of a perovskite structure comprises a combination of elements selected from the group consisting of lanthanides, alkaline earth metals, Y, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, and Nb, oxides thereof, and mixtures of these metals and metal oxides. Advantageously a catalyst is present in the first zone.Type: GrantFiled: January 26, 2000Date of Patent: December 25, 2001Assignee: The Standard Oil CompanyInventors: Terry J. Mazanec, Thomas L. Cable, John G. Frye, Jr., Wayne R. Kliewer
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Publication number: 20010045364Abstract: A hydrogen source system delivers a controlled fuel stream to applications, using wicking to control the contact between a mixture of NaBH4, NaOH and H2O and a hydrolyzing catalyst to create a feedback mechanism to automatically maintain a constant pressure production supply of hydrogen. A small compact device packaged for storage, the system operates in any orientation and is mobile. The system is a small portable packaged hydrogen generator for small fuel cells to power applications that are currently powered by batteries. These packaged devices have higher energy per unit mass, higher energy per unit volume, are more convenient for energy users, environmentally less harmful, and less expensive than conventional power sources.Type: ApplicationFiled: March 30, 2001Publication date: November 29, 2001Inventors: Robert G. Hockaday, Patrick S. Turner, Marc D. DeJohn, Carlos J. Navas, Heathcliff L. Vaz, L. Luke Vazul
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Publication number: 20010037948Abstract: This invention discloses regeneration methods to remove carbon monoxide (CO) from reformate fuel using an adsorption and electro-catalytic oxidation (ECO) approach. One method of the invention comprises a first ECO cell and a second ECO cell, and the other method comprises a first ECO cell and a first charge storage device. Both methods eliminate the requirement of an external power supply that leads to higher cost, additional power consumption and more processor complexity for the CO removal processor.Type: ApplicationFiled: May 3, 2001Publication date: November 8, 2001Applicant: Honeywell International, Inc.Inventors: Di-Jia Liu, James C. Williams, Mark Kaiser, Stanley F. Simpson
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Patent number: 6156184Abstract: A proton exchange membrane comprising a perfluorosulfonic acid having silica particles embedded therein at a concentration of 0.01 to 5% by weight, said particles having a dimension of 0.001 to 10 micrometers, the membrane having a crystalline phase and an amorphous phase in a ratio adjusted by controlled thermal treatment at a temperature higher than the glass transition temperature, an electrochemical cell containing said membrane and a process for oxidizing a fuel in said electrochemical cell.Type: GrantFiled: December 7, 1998Date of Patent: December 5, 2000Assignee: De Nora S.p.A.Inventors: Vincenzo Antonucci, Antonino Arico'
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Patent number: 6146518Abstract: An improved process for providing hydrogen from an electrolytic cell having an anolyte solution having an anolyte liquid level; a catholyte solution having a catholyte liquid level; generating oxygen at an oxygen pressure above the anolyte level; generating hydrogen at a hydrogen pressure above the catholyte level; the improvement comprising detecting at least one of the anolyte and the catholyte liquid levels as anolyte level and catholyte level data; feeding the level data to central processing means; determining the pressure differential between the levels from the level data, and pressure adjustment data by the central processing means; and providing the adjustment data to pressure control means to maintain the pressure differential within a selected range. The process offers a low cost method of controlling the pressure differential to within 2 cm WC of a set point.Type: GrantFiled: September 1, 1999Date of Patent: November 14, 2000Assignee: Stuart Energy Systems Inc.Inventors: Matthew J. Fairlie, William J. Stewart, Charlie Dong
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Patent number: 6117302Abstract: A process and apparatus are disclosed for electrolytically smelting alumina to produce aluminum metal, including providing a combination solid oxide fuel cell and electrolytic smelting cell for the production of aluminum from refined alumina positioned near tile solid oxide fuel cell. In one aspect, an alumina ore refinery for producing the refined alumina is positioned near the solid oxide fuel cell, and refined alumina is passed at a temperature of at least 900.degree. C. directly from the alumina ore refinery to the electrolytic smelting cell. In one aspect, the solid oxide fuel cell incorporates a planar construction having a solid state cathode material of lanthanum strontium manganate, a solid electrolyte of yttria stabilized zirconia, and a nickel/yttria stabilized zirconia cermet anode.Type: GrantFiled: August 18, 1998Date of Patent: September 12, 2000Assignee: Aluminum Company of AmericaInventor: David J. Roha
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Patent number: 6033793Abstract: An integrated power module for generating thermal and electrical power is provided within a housing which includes inlets for fuel and for air, a reformer chamber, a fuel cell stack, and a combustion chamber. Oxygen-containing gas, such as air, is introduced into the module along a path in one direction in heat exchange relationship with reaction products produced in the reaction chamber traveling in an adjacent path, preferably in an opposite direction, to preheat the incoming oxygen-containing gas. A nozzle having an injector for the fuel and for the oxygen-containing gas delivers these gases to the interior of the reformer chamber, where ignition is supplied by a suitable device. The reaction products from the reformer chamber are fed to a fuel cell which will consume certain of the reaction products, such as hydrogen gas, with oxygen provided from the reaction chamber acting as an oxidizing gas.Type: GrantFiled: February 27, 1998Date of Patent: March 7, 2000Assignee: Hydrogen Burner Technology, Inc.Inventors: Richard R. Woods, Leonard Greiner, David Moard
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Patent number: 6024859Abstract: An electrochemical converter is disposed within a pressure vessel that collects hot exhaust gases generated by the converter for delivery to a cogeneration bottoming device, such as a gas turbine. The bottoming device extracts energy from the waste heat generated by the converter, such as a fuel cell for the generation of electricity, yielding an improved efficiency energy system. Bottoming devices can include, for example, a gas turbine system or an heating, ventilation or cooling (HVAC) system. The pressure vessel can include a heat exchanger, such as a cooling jacket, for cooling the pressure vessel and/or preheating an input reactant to the electrochemical converter prior to introduction of the reactant to the converter. In one embodiment, a compressor of a gas turbine system assembly draws an input reactant through the pressure vessel heat exchanger and delivers the reactant under pressure to a fuel cell enclosed therein.Type: GrantFiled: September 17, 1998Date of Patent: February 15, 2000Assignee: Ztek CorporationInventor: Michael S. Hsu
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Patent number: 5983488Abstract: A process for manufacture of molten carbonate fuel cell matrices in which an aluminate precursor material and a lithium salt are mixed in an aqueous or organic solvent, resulting in formation of a suspension, the suspension is heated to a temperature less than a boiling of the solvent, resulting in formation of a slurry comprising a lithium aluminate precursor material, at least one casting additive is added to the slurry, the slurry is formed into a desired shape, the desired shape is dried or cured to yield a green molten carbonate fuel cell structure, and the green molten carbonate fuel cell structure is heated after assembly into a molten carbonate fuel cell to the molten carbonate fuel cell operating temperature, resulting in transformation of the lithium aluminate precursor material to lithium aluminate.Type: GrantFiled: July 30, 1997Date of Patent: November 16, 1999Assignee: M-C Power CorporationInventors: Diane S. Erickson, Charles R. Bernat
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Patent number: 5980726Abstract: The present invention relates to a unique, compact hydrogen electrochemical system which eliminates the need for explosion-proof equipment. This system merely separates the electrical equipment from the hydrogen source with a wall, but employs a positive pressure, of about 0.1 inches water column, air purge throughout the system to prevent the introduction of hydrogen gas to the electrical equipment and to recover and use waste heat.Type: GrantFiled: May 5, 1998Date of Patent: November 9, 1999Assignee: Proton Energy SystemsInventors: Lawrence C. Moulthrop, Jr., A. John Speranza, Robert H. Byron, Jr.
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Patent number: 5925322Abstract: The present invention relates to a combined cycle system of enhanced efficiency. The system comprises a top stage, such as a fuel cell, a partial oxidation reactor or a heat engine, and an oxygen-enriching device, such as a temperature swing adsorption device or a chemical reactor bed device, as its bottom stage. The bottom stage uses waste heat produced by the top stage to enrich the oxygen content of air that is inputted to the bottom stage, thereby producing an oxygen-enriched gas mixture as the bottom stage output. This output mixture constitutes a superior oxidant which is fed back as an input for the top stage, thus enhancing the energy conversion efficiency, cheapness, and compactness of the combined cycle system as compared to that of ordinary fuel cells, partial oxidation reactors and heat engines that use unenriched air as their oxidant input.Type: GrantFiled: July 18, 1997Date of Patent: July 20, 1999Assignee: H Power CorporationInventor: John Werth
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Patent number: 5876583Abstract: The invention concerns membrane electrolyzers suitable for processes such as water or hydrogen halides electrolysis, as well as electrochemical generators fed with gases containing hydrogen and oxygen for direct conversion into electric energy. These apparatuses generally consist of a filter-press assembly of conductive bipolar plates (2), electrodes (4), sealing gaskets (5) membranes (6) and internal longitudinal ducts for feeding the reactants and withdrawing the products and residual reactants. The invention is directed to the method for repairing said electrolyzers or generators when an elementary cell is malfunctioning. This method comprises making at least two perforations in the peripheral area of the bipolar plates (2) and/or gaskets (5) of the malfunctioning cell to reach distribution channels (9, 11) which connect the compartments containing the electrodes (4) with said longitudinal ducts.Type: GrantFiled: September 8, 1997Date of Patent: March 2, 1999Assignee: De Nora S.p.A.Inventors: Massimo Brambilla, Claudio Mantegazza
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Patent number: 5766443Abstract: The process for preparing an aqueous alkaline solution containing a peroxide and/or percarbonate includes providing an electrochemical cell comprising a porous oxygen diffusion cathode including a carbon woven or nonwoven fabric, a gas diffusion anode containing a carbon woven or nonwoven fabric and fed gaseous hydrogen or an anode including a metal grid coated with a noble metal catalyst and coated on a side facing the cathode with a proton-permeable membrane acting as a solid polymer electrolyte, an electrolyte-containing chamber between the cathode and the anode containing an electrolyte and a direct current source connected across the anode and cathode; feeding an aqueous feed solution containing at least one alkali hydroxide and/or alkali carbonate in a concentration of from 30 to 180 g/l into the electrolyte-containing chamber to provide the electrolyte; supplying an oxygen-containing gas containing molecular oxygen to the carbon woven or nonwoven fabric of the cathode; operating the direct current sourType: GrantFiled: January 2, 1996Date of Patent: June 16, 1998Assignee: Metallgesellschaft AktiengesellschaftInventors: Eilhard Hillrichs, Ulrich Sander
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Patent number: 5736026Abstract: Integrated ethanol manufacturing by fermentation of biomass, with an electrical fuel cell generator of electrical and heat energy, the cogeneration including use by the fuel cell of the alcohol, and of the carbon dioxide from the fermentation, which increases the generation of energy, and use by the alcohol manufacturing of the heat and electrical energy from the fuel cell, which increases the fuel manufacture.Type: GrantFiled: February 5, 1996Date of Patent: April 7, 1998Assignee: Energy Research CorporationInventors: Pinakin S. Patel, Jen Jung Fan
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Patent number: 5733430Abstract: A gas diffusion electrode is constituted by forming a porous layer comprising a super-fine particle catalyst of silver or gold and a fluorine-containing material on a substrate and connecting a gas-liquid permeable collector to the substrate.The gas diffusion electrode can be used stably as an oxygen cathode for a sodium chloride electrolysis, etc., for a long period of time without causing decreased water repellency of the fluorine-containing material in the gas diffusion electrode and without lowering the activity of the electrode substance.Type: GrantFiled: April 3, 1996Date of Patent: March 31, 1998Assignee: Permelec Electrode Ltd.Inventors: Takahiro Ashida, Takayuki Shimamune, Yoshinori Nishiki
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Patent number: 5512145Abstract: This invention relates to a method and apparatus for converting energy to hydrogen gas using an electrolyzer and a metal alloy hydride tank for hydrogen storage, wherein a passive load matching device between the energy source and the electrolyzer maximizes hydrogen output, and the electrolyzer and the metal alloy hydride tank operate at mutually low pressure, near ambient, such that pressurization of the system is not required.Type: GrantFiled: October 7, 1994Date of Patent: April 30, 1996Assignee: The Cooper Union for the Advancement of Science and ArtInventor: Joel W. Hollenberg