Abstract: The invention is directed to a method for producing metal-containing (e.g., non-oxide, oxide, or elemental) nano-objects, which may be nanoparticles or nanowires, the method comprising contacting an aqueous solution comprising a metal salt and water with an electrically powered electrode to form said metal-containing nano-objects dislodged from the electrode, wherein said electrode possesses a nanotextured surface that functions to confine the particle growth process to form said metal-containing nano-objects. The invention is also directed to the resulting metal-containing compositions as well as devices in which they are incorporated.
Type:
Application
Filed:
March 12, 2014
Publication date:
September 18, 2014
Applicant:
UT-Battelle, LLC
Inventors:
Adam Justin Rondinone, Ilia N. Ivanov, Sean Campbell Smith, Chengdu Liang, Dale K. Hensley, Ji-Won Moon, Tommy Joe Phelps
Abstract: An electric current is passed through an acidic solution containing one or more soluble metal salts in an electrolytic cell divided by an anion exchange membrane. The acidic solution is fed into the cathode compartment whereby the passage of electric current at sufficient voltage causes the generation of hydrogen at the cathode. This gives rise to a localized very highly polarized region at the cathode resulting in a localized effective high relative pH. This causes the metal cation species to precipitate as a hydroxide (or oxide) species and electroadsorption/electrocoagulation causes the finely precipitated hydroxide (or oxide) species to adhere to the cathode. Electrodialytic transport of the liberated acid anions across the anion exchange membrane selectively removes the acid anions. Oxygen and hydrogen ions are formed by hydrolysis as the counter-reaction at the anode. Hydrogen ions combine with the anions to regenerate sulfuric acid.
Type:
Application
Filed:
January 20, 2010
Publication date:
June 21, 2012
Inventors:
Adam Justin Blunn, Adam Daniel Longstaff
Abstract: The present invention relates to a process for production of alkali metal chlorate, and to a method of activating a cathode comprising electrolyzing an electrolyte comprising alkali metal chloride in an electrolytic cell in which at least one anode and at least one cathode are arranged wherein a) said electrolyte comprises chromium in any form in an amount ranging from about 0.01-10?6 to about 500-10?6 mol/dm3 b) said electrolyte comprises molybdenum, tungsten, vanadium, manganese and/or mixtures thereof in any form in a total amount ranging from about 0.1-10?6 mol/dm3 to about 0.5-10?3 mol/dm3.
Type:
Application
Filed:
April 23, 2010
Publication date:
March 15, 2012
Applicant:
AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
Inventors:
Magnus Rosvall, Kristoffer Hedenstedt, Annicka Sellin, Johan Gustavsson, Ann Cornell
Abstract: A method for the preparation of materials comprises the steps of: a) taking a first material comprising a compound of a first metal or of a first metal alloy, b) inserting said first material into an electrochemical cell as a first electrode, the electrochemical cell including a second electrode including a second metal different from a metal incorporated in the first material and an electrolyte adapted to transport the second metal to the first electrode and insert it into the first material by a current flowing in an external circuit resulting in the formation of a compound of the second metal in the first electrode material, the method being characterized by the step of treating the first electrode material after formation of the compound of the second metal to chemically remove at least some of the compound of the second metal to leave a material with a nanoporous structure.
Type:
Application
Filed:
March 29, 2007
Publication date:
August 19, 2010
Applicant:
Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.
Inventors:
Yong-Sheng Hu, Yu-Guo Guo, Palani Balaya, Joachim Maier, Sarmimala Hore
Abstract: A cermet composite material is made by treating at an elevated temperature a mixture comprising a compound of iron and a compound of at least one other metal, together with an alloy or mixture of copper and a noble metal. The alloy or mixture preferably comprises particles having an interior portion containing more copper than noble metal and an exterior portion containing more noble metal than copper. The noble metal is preferably silver. The cermet composite material preferably includes alloy phase portions and a ceramic phase portion. At least part of the ceramic phase portion preferably has a spinel structure.
Type:
Grant
Filed:
July 24, 2000
Date of Patent:
December 25, 2001
Assignee:
Alcoa Inc.
Inventors:
Siba P. Ray, Robert W. Woods, Robert K. Dawless, Robert B. Hosler
Abstract: A method for pickling products in a metal alloy containing iron, and products in titanium and alloys thereof, in the absence of nitric acid as an oxidizing agent, and for the recovery of the exhausted solutions, characterized in that the recovery of the exhausted solutions deriving from pickling comprises the following steps: sending of the pickling solution, both as catholyte and as anolyte, in an electro-chemical cell optionally of the membrane type to separate the Fe2+ (or Ti2+) ions to be disposed of, from the Fe3+ (or of the Ti3+ and Ti4+) ions to be recovered, obtained by reduction at the cathode of the Fe3+ ions which are in the catholyte to Fe2+ (or of the Ti3+ and Ti4+ ions to Ti2+) and of oxidation at the anode Fe2+ (or Ti2+) ions which are in the anolyte to Fe3+ (to Ti3+ and Ti4+); treating the catholytic solution coming out of the cell and enriched in Fe2+ (or Ti2+) ions as to allow the separation in two phases, a
Abstract: The invention provides a novel cyanochromium-complex-based magnetic material formed on an electrode, which is excellent in magnetic properties and of which magnetic properties are reversibly controllable, by impressing a reduction potential which electrochemically reduces Cr.sup.3+ into Cr.sup.2+ in a solution containing at least [Cr(CN).sub.6 ].sup.3- and Cr.sup.3+.
Type:
Grant
Filed:
October 30, 1997
Date of Patent:
September 12, 2000
Assignee:
Kanagawa Academy of Science and Technology
Abstract: Purification of Natrium Sulfat, separation of chrome by the electrocoagulation of Chrome using a bioelectrode cell (AC). The bioelectrode cell is a series of electrodes (Fe--Cr--Fe--Cr), and AC is applied to the first and the last electrodes.
Type:
Grant
Filed:
March 19, 1998
Date of Patent:
March 7, 2000
Inventors:
Aron Mikhailovich Khalemsky, Andrei Nikolaevich Shmidt, deceased, Boris Andreivich Pakhomov, Sergei Abramovich Payusov
Abstract: A process for galvanic deposition of chromium coatings is provided in which the base material is subjected to a galvanic chromium plating bath to form a hard chromium coating with beaded or columnar type surface structure, and the beaded or columnar type surface structure is subsequently filled and smoothed with galvanically applied black chromium. The resulting combined coatings yield increased wear resistance, lower friction values, even without lubricants, and increased corrosion resistance.