Abstract: A recovery method of nickel according to the present invention comprises pretreatment step to prepare a solution for electrolysis by adding hexanesulfonate salt to a treatment solution including nickel, and nickel recovery step to recover nickel in a metal form by electrolysis of the above solution for electrolysis. The present invention can produce nickel in high purity with simple process with low cost, and can recover and reproduce nickel in a metal form with at least 99.5% of high purity and at least 90% of recovery rate.
Type:
Grant
Filed:
November 7, 2012
Date of Patent:
August 12, 2014
Assignee:
Korea Institute of Science and Technology
Inventors:
Hwa Young Lee, Byung Won Cho, Joong Kee Lee
Abstract: A process for the selective recovery of Mo, V, Ni, Co and Al from spent hydroprocessing catalysts includes the steps of treating the spent catalysts to recovery metals, support as well as chemicals. The process steps include deoiling, decoking, washing, dissolving, complexing agent treatment, acid treatment and solvent extraction. This process uses limited steps than conventional processes by the use of ultrasonic agitation for metal extraction and the presence of a chelating agent particularly Ethylene Diamine Tetra-Acetic Acid (EDTA). The process also discloses the compete recovery of the extracting agent EDTA with high purity for reuse.
Type:
Grant
Filed:
November 10, 2010
Date of Patent:
October 16, 2012
Assignee:
Kuwait Institute for Scientific Research
Abstract: An acidic aqueous electrolyte solution for production of a nickel cathode is provided which includes nickel ions, and 2,5-dimethyl-3-hexyne-2,5-diol. The 2,5-dimethyl-3-hexyne-2,5-diol may be present in the acidic aqueous electrolyte solution in an amount ranging from about 5 ppm to about 300 ppm. Also provided is a process for electrowinning or electrorefining a nickel cathode which includes providing an acidic aqueous electrolyte solution including nickel ions, and 2,5-dimethyl-3-hexyne-2,5-diol; and electrolytically depositing nickel to form a nickel cathode. Addition of 2,5-dimethyl-3-hexyne-2,5-diol results in a reduction of striations and other defects which may occur on the surface of cathodes made by electrowinning or electrorefining.
Abstract: Upon performing electrolysis with a solution containing nickel as the electrolytic solution, anolyte is adjusted to pH 2 to 5; impurities such as iron, cobalt and copper contained in the anolyte are eliminated by combining any one or two or more of the methods among adding an oxidizing agent and precipitating and eliminating the impurities as hydroxide, eliminating the impurities through preliminary electrolysis, or adding Ni foil and eliminating the impurities through displacement reaction; impurities are thereafter further eliminated with a filter; and the impurity-free solution is employed as catholyte to perform the electrolysis. The present invention relates to a simple method of performing electrolytic refining employing a solution containing nickel from nickel raw material containing a substantial amount of impurities, and provides technology on efficiently manufacturing high purity nickel having a purity of 5N (99.999 wt %) or more.
Abstract: A bio-leaching method is provided for recovering metal from a metal containing ore. The ore is subjected to contact with a microorganism selective to the oxidation of sulfur. A sulfur containing compound is mixed with the microorganism before, during or after contact with the ore to systemically form sulfuric acid to leach the metal from the ore. The ore is in the form of a slurry, a heap, a charge in a vat and is bioleached for a time sufficient to dissolve the metal in the ore and form a metal-rich leachate and an ore residue. The metal can then be extracted from the metal-rich leachate. The metal containing ore may contain base metals, precious metals, or platinum group metals. Upon formation of the metal-rich leachate, the ore residue may be further processed to recover any precious metals or platinum group metals that may be present.
Type:
Grant
Filed:
November 17, 1999
Date of Patent:
May 14, 2002
Assignee:
BHP Minerals International, Inc.
Inventors:
Willem P. C. Duyvesteyn, Julia R. Budden, Manuel R. Lastra
Abstract: A process for controlling the micelle size distribution of an alkylene oxide dispersion in a nickel-plating electrolyte is used to maintain the electrolyte in a condition suitable for producing nickel coatings having a uniform satin finish in which finish characteristics such as roughness depth are maintained within desired limits. The process involves steps of removing a portion of the electrolyte from the electroplating bath, filtering the alkylene oxide from the electrolyte removed from the electroplating bath, adding alkylene oxide to the electroplating bath, and returning the filtered electrolyte to the electroplating bath. The process removes larger alkylene oxide micelles from the electrolyte and replaces them with smaller micelles to maintain a desired micelle size distribution.
Type:
Grant
Filed:
March 31, 2000
Date of Patent:
October 23, 2001
Assignee:
Lacks Enterprises, Inc.
Inventors:
Lawrence P. Donovan, III, Roger J. Timmer, David P. Hartrick