Abstract: A treatment system for treating water, such as produced water that is produced during hydraulic fracturing. The system employs a combination of a plasma spark discharge and an RF oscillating electric field. The plasma spark discharge and the RF oscillating electric field may be employed simultaneously or in an overlapping manner within a chamber to treat the water. The treatment system is able to kill microorganisms as well as reduce or eliminate fouling due to, for example, bicarbonates. In some embodiments, grids are employed to further enhance the heat produced by the RF oscillating electric field.

Abstract: A quencher for a flow cell battery is described. The quencher utilizes a quench solution formed from FeCl2 in a dilute HCl solution in order to quench chlorine emissions from the flow cell battery. A quench sensor is further described. The quench sensor monitors the concentration level of FeCl2 in the quench solution and may also monitor the level of the quench solution in the quencher.

Abstract: Systems are described for dissolving metal silicates to: produce metal hydroxide; remove carbon dioxide or other acid gases from the atmosphere or other gas mixture by reacting such gases with the metal hydroxide; penetrate or excavate metal silicates; extract metals or silicon-containing compounds from metal silicates; and produce hydrogen and oxygen or other gases.

Abstract: An automated self-propelled robotic pool cleaner having a housing and drive means for moving the pool cleaner over at least the bottom wall of a pool, is provided with an integral on-board electrochemical chlorine generator for producing chlorine from a chlorine compound, e.g., sodium chloride, that is dissolved in the pool water, a source of electrical power operatively connected to the electrochemical chlorine generator, control means for initiating and terminating the operation of the chlorine generator, and an outlet for discharging water containing chlorine ions produced by the electrochemical generator to thereby distribute the chlorine into the water proximate the exterior of the pool cleaner housing as the pool cleaner follows a programmed operational mode across the bottom and/or side walls of the pool.

Abstract: In a process for chlorine-alkali electrolysis, use is made of an oxygen depletion cathode. The process is run with a high excess of oxygen. The oxygen needed for this is provided for a device of the gas separation, for example a VPSA plant or an air fractionation plant. The large quantities of oxygen produced lead to considerable costs of the process. According to the invention, the oxygen-rich atmosphere remaining after passing through the process is fed back into the device for gas separation as input gas. The device the gas separation is therefore operated with an oxygen-rich input gas and therefore produces a larger quantity of oxygen-rich gas, which in turn is fed to the oxygen depletion cathode. As a result of the circulation of the gas, the economy of the overall process is increased considerably.

Abstract: The electrochemical reactors disclosed herein provide novel oxidation and reduction chemistries and employ increased mass transport rates of materials to and from the surfaces of electrodes therein.

Abstract: The present disclosure is a system and method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode. The method may include a step of contacting the first region with a catholyte including carbon dioxide and contacting the second region with an anolyte including a recycled reactant. The method may further include applying an electrical potential between the anode and the cathode sufficient to produce carbon monoxide recoverable from the first region and a halogen recoverable from the second region.

Abstract: The present disclosure is a system and method for producing a first product from a first region of an electrochemical cell having a cathode and a second product from a second region of the electrochemical cell having an anode. The method may include a step of contacting the first region with a catholyte comprising carbon dioxide. The method may include another step of contacting the second region with an anolyte comprising a recycled reactant. The method may include a step of applying an electrical potential between the anode and the cathode sufficient to produce a first product recoverable from the first region and a second product recoverable from the second region. The second product may be removed from the second region and introduced to a secondary reactor. The method may include forming the recycled reactant in the secondary reactor.

Abstract: Electrolyser comprising at least one single electrolyser element which comprises at least one anode compartment with an anode, one cathode compartment with a cathode and one ion exchange membrane arranged between the anode and the cathode compartments, with the anode and/or cathode being a gas diffusion electrode. A gap is provided between the gas diffusion electrode and the ion exchange membrane, with an electrolyte inlet arranged at the upper end of the gap and an electrolyte outlet at the lower end of the gap and a gas inlet and a gas outlet. The electrolyte outlet extending into a discharge header, and the electrolyte inlet connected to an electrolyte feed tank and having an overflow, the overflow connected to the discharge header, with a coiled hose connecting the electrolyte feed tank with the electrolyte inlet and with a coiled hose connecting the overflow with the discharge header.

Abstract: A quencher for a flow cell battery is described. The quencher utilizes a quench solution formed from FeCl2 in a dilute HCl solution in order to quench chlorine emissions from the flow cell battery. A quench sensor is further described. The quench sensor monitors the concentration level of FeCl2 in the quench solution and may also monitor the level of the quench solution in the quencher.

Abstract: A support member for an improved three-chambered electrolytic cell is disclosed. A porous synthetic support system for exchange membranes in electrolytic cells is used for exchange membrane protection in electrolytic cells for the in situ generation of electrolysis solutions, such as bleach or hypochlorous acid.

Abstract: A highly stable aqueous solution having a molecular cluster with dimensions which are small enough to ensure substantial chemical-physical stability thereof for a relatively long time. To prepare the solution a fluid treatment device is used, which comprises at least one chamber (7) and at least one anode (4) and one cathode (3) arranged in the chamber (7). The anode (4) and cathode (3) are at least partly made of a first metallic material. At least one of the at least one cathode (3) and anode (4) comprises a coating of nanoparticles (5) of a second metallic material.

Abstract: Systems are described for dissolving metal silicates to: produce metal hydroxide; remove carbon dioxide or other acid gases from the atmosphere or other gas mixture by reacting such gases with the metal hydroxide; penetrate or excavate metal silicates; extract metals or silicon-containing compounds from metal silicates; and produce hydrogen and oxygen or other gases.

Abstract: Systems and methods for recovering chlorine gas or an alkali metal from an electrolytic cell having an acid-intolerant, alkali-ion-selective membrane are disclosed. In some cases, the cell has an anolyte compartment and a catholyte compartment with an acid-intolerant, alkali-ion selective membrane separating the two. While a cathode is disposed within a catholyte solution in the catholyte compartment, a chlorine-gas-evolving anode is typically disposed within an aqueous alkali-chloride solution in the anolyte compartment. As current passes between the anode and cathode, chlorine ions in the anolyte solution can be oxidized to form chlorine gas. In some cases, the cell is configured so the chlorine gas is rapidly removed from the cell to inhibit a chemical reaction between the chlorine gas and the anolyte solution. In some cases, a vacuum or a heating system is used to increase the rate at which chlorine gas exits the cell. Other implementations are also described.

Abstract: Aqueous composition containing at least one salt in an amount of at least 30 g/kg of composition, of which the total organic carbon content is at least 1 ?g of C/l and at most 5 g of C/l of composition and which contains at least one carboxylic acid.

Abstract: Methods for the reductive post-treatment of NaCl-containing solutions, wherein such methods comprise: providing a NaCl-containing solution obtained from an anode side of an NaCl electrolysis cell, the solution comprising reducible components; and subjecting the solution to cathodic electrochemical reduction.

Abstract: Methods and systems for generating biocidal solution having a predetermined level of available free chlorine and pH, including an electrolytic cell that generates the biocidal solution by an electrolytic reaction, the electrolytic cell including an input pipe for receiving an input brine solution, an anode chamber including an anode and a cathode chamber including a cathode separated by a separator, electrical connections for application of voltage to the anode and cathode; temperature sensing means for detecting a temperature of a solution of the electrolytic cell and outputting a signal indicative of the detected temperature; and process control means for adjusting the voltage applied to the electrolytic cell by the process control means thereby maintaining the level of available free chlorine and pH at the predetermined level in response to the signal output from the temperature sensing means.

Abstract: An automated self-propelled pool cleaner having a housing, a water pump for moving water through the housing, drive means for moving the pool cleaner over the surface of the salt water pool to be cleaned, and an integral electrochemical chlorine generator mounted in the housing, includes a processor/controller that is programmed to activate the chlorine generator, the pump and drive means in predetermined operational sequences that minimize wear and tear on the water pump and drive means, while at the same time distribute and maintain a safe level of sanitizing chlorine in the pool, to thereby obviate the need for an in-line chlorinator or other chemical additive treatments; an optional automated sensor device can be provided to activate a secondary maintenance program which enables the pool cleaner to operate over prolonged periods of time as the sole means for filtering and sanitizing the pool water.

Abstract: The invention relates to a process for preparing chlorine in three process steps, wherein a catalytic oxidation of hydrogen chloride to chlorine over a uranium oxide catalyst is performed in a first process step, the chlorine formed is at least partly removed in a second step, and an electrochemical oxidation of hydrogen chloride to chlorine is performed in a third process step.

Abstract: An electrode material, an electrode and a process for hydrogen chloride electrolysis based on platinum metal as catalyst, in which the electrode material has a nanosize mixture of platinum particles and silver particles, is described.

Abstract: Process for the reduction of oxygen in aqueous chlorine- and/or chloride-containing solutions in the presence of a catalyst comprising nitrogen-doped carbon nanotubes.

Abstract: An electrolysis stack (53) with oxygen-depolarized cathodes (31) employs solid-plate anodes (38) and porous-plate cathodes (42). The stack (53) of electrolysis cells (29) (e.g, hydrogen-chloride or chlor-allkali cells) each include an ion exchange membrane (32) sandwiched between an anode conductor (34) and a permeable cathode (35); an oxygen-consuming gas diffusion cathode (31) is adjacent the cathode conductor of each cell. Between the anode conductor of one cell and the gas diffusion cathode of an adjacent cell there is a composite bipolar plate (51) including a solid plate (38) having channels (39) for conducing salt solution and product of the process; the bipolar plates also include a porous plate (42) having channels (43) for conducting oxidant adjacent the gas diffusion cathode and channels (49) connected to a source of liquid (such as water or dilute sodium hydroxide).

Abstract: A chlorine dioxide solution generator includes a chlorine dioxide gas source. An eductor system is fluidly connected to the chlorine dioxide gas source for at least partially effecting the dissolution of chlorine dioxide gas into an aqueous liquid stream. An absorption system is fluidly connected to the eductor system that is capable of effecting additional dissolution of the chlorine dioxide gas into said aqueous liquid.

Abstract: An electrode for electrochemical processes for gas production, which in the installed state is located parallel and opposite to an ion exchange membrane and consists of a multitude of horizontal lamellar elements which are structured and three-dimensionally shaped and are in contact with only one surface with the membrane, wherein the lamellar elements have grooves and holes, the major part of the holes being placed in the grooves and the surfaces of such holes or part thereof are located in the grooves or extend into the grooves whereby the holes are ideally placed in the contact area of the respective lamellar element with the membrane.

Abstract: Apparatuses and methods for removing carbon dioxide and other pollutants from a gas stream are provided. The methods include obtaining hydroxide in an aqueous mixture, and mixing the hydroxide with the gas stream to produce carbonate and/or bicarbonate. Some of the apparatuses of the present invention comprise an electrolysis chamber for providing hydroxide and mixing equipment for mixing the hydroxide with a gas stream including carbon dioxide to form an admixture including carbonate and/or bicarbonate.

Abstract: An insulating end cap for a cylindrical electrolysis cell the type comprising at least two tubular electrodes with a cylindrical membrane arranged co-axially between them, comprises a first annular section with first and second axial ends, having at its first axial end a circular seating or one end of an outer cylindrical electrode and at its second end a circular aperture, of smaller diameter than the circular seating and co-axial therewith, to accommodate one end of the membrane. A second annular section of the end cap is detachably secured to the first and has a central circular aperture of smaller diameter than the central aperture of the first section and co-axial therewith, to accommodate one end of the inner cylindrical electrode. The two part construction of the end cap facilitates the assembly of the cell, and reduces the likelihood of breakage of the fragile ceramic membrane.

Abstract: A method for generating energy and/or fuel from the halogenation of a carbon-containing material and/or a sulfur-containing chemical comprises supplying the carbon-containing material (e.g., coal, lignite, biomass, cellulose, milorganite, methane, sewage, animal manure, municipal solid waste, pulp, paper products, food waste) and/or the sulfur-containing chemical (e.g., H2S, SO2, SO3, elemental sulfur) and a first halogen-containing chemical to a reactor. The carbon-containing material and/or the sulfur-containing chemical and the halogen-containing chemical are reacted in the reactor to form a second halogen-containing chemical and carbon dioxide, sulfur and/or sulfuric acid. The second halogen-containing chemical is dissociated (e.g., electrolyzed) to form the first halogen-containing chemical and hydrogen gas (H2). The first halogen-containing chemical can be Br2 and the second halogen-containing chemical can be HBr. Any carbon dioxide formed during reaction can be directed to a prime mover (e.g.

Abstract: A composition for treating water contained in enclosures, such as swimming pools, spas, whirlpool tubs and cooling towers, which includes at least one boron compound, cyanuric acid, at least one mineral remover and at least one clarifier is provided. A composition and method for treating salt water contained in enclosures using halogen generators to generate sterilizing halogen in situ, wherein the method includes adding to the water effective amounts of a composition having at least one boron compound, cyanuric acid, at least one mineral remover and at least one clarifier, such that they are present in the water simultaneously is also provided.

Abstract: An electrode for electrochemical processes for gas production, which in the installed state is located parallel and opposite to an ion exchange membrane and consists of a multitude of horizontal lamellar elements which are structured and three-dimensionally shaped and are in contact with only one surface with the membrane, wherein the lamellar elements have grooves and holes, the major part of the holes being placed in the grooves and the surfaces of such holes or part thereof are located in the grooves or extend into the grooves whereby the holes are ideally placed in the contact area of the respective lamellar element with the membrane.

Abstract: Chlorine is produced by electrolysis of aqueous HCl, in a membrane electrolyzer, using cathodic mediators such as Fe(III) and/or Cu(II) chlorides and a non-catalysed 3-dimensional cathode, with the real surface area at least ten times higher than its projected area. The HCl electrolysis section is combined with an oxidizer for regeneration of the mediator, product water removal step and optional HCl recovery step. Under optimized conditions chlorine can be produced at very high current densities of 30 kA/m2, without initiating undesired H2 evolution reaction at the cathode.

Abstract: The present invention relates to a novel economical on-site electrochemical based membrane cell based process with the capability of producing high strength sodium hypochlorite and/or elemental chlorine gas in any ratio as required by the needs of a water or wastewater treatment plant. The system is compact and modular, using membrane cell based electrolyzers and utilizing novel process modifications and sensors to allow for the unattended control and safe operation of the process. The process allows the operator to produce elemental chlorine gas and sodium hypochlorite in any product ratio, such that 5% to 100% of the total chlorine produced by the process can be converted to high strength bleach. The process has the flexibility to produce stable high quality, low to high strength sodium hypochlorite solutions in concentrations ranging from about 2 to 15% trade as NaOCl.

Abstract: A solid formulation for use with sodium chloride and a chlorine generator to provide safe, clean chlorinated recreational water. The formulation comprises a chlorine stabilizing agent and a phosphate remover agent. An enhanced salt comprising a chlorine stabilizing agent, a phosphate remover agent and sodium chloride is also described. The formulation and enhanced salt can also contain a metal chelating agent and a pH balancing agent. A cleaning agent may also be included. A fast dissolving sodium cyanurate compound is used for the chlorine stabilizing agent. A method, kit, and system for providing safe, clean chlorinated recreational water are also disclosed.

Abstract: An oxygen-depolarized cathode for aqueous hydrochloric acid electrolysis membrane cells is described, the cathode being in contact with the membrane and capable of preventing the release of hydrogen into oxygen even at the highest current densities. Hydrochloric acid may also be of technical grade with a concentration limited to 15%, whereas the operating temperature must not exceed 60° C. The cathode contains a mixture of rhodium sulphide and a metal of the platinum group applied in a single layer or alternatively applied separately in two distinct layers.

Abstract: An electrolytic cell for producing chlorine and basic hydrogen peroxide suitably includes an anode partition and a cathode partition separated by a membrane. The cathode partition is divided into a catholyte compartment and a gas plenum by a gas diffusion cathode. The anode partition electrolyzes alkali chloride received from the laser to produce free chlorine and alkali ions. The catholyte partition reduces oxygen received from the gas plenum through the cathode, and produces alkaline peroxide from the oxidized components combined with alkali ions received through the membrane from the anode partition. The cell is particularly useful in a fuel regeneration system (FRS) for a chemical oxygen iodine laser (COIL).

Abstract: A bipolar assembly for filter-press type electrolyzers is described comprising a single sheet, whose two faces work respectively as anodic and cathodic wall, characterised by a design of perimetral flanges which greatly simplifies its construction enhancing its reliability. The peripheral flanges are made of a first flange obtained by folding the peripheral portion of the single sheet and of a second flange formed by a rod or a tube with quadrangular section or, alternatively, the first and second flange are pre-formed by folding of adequate strips subsequently fixed to the single sheet. The electrolyser resulting from the assemblage of a multiplicity of assemblies of the invention is particularly suited to the process of electrolysis of hydrochloric acid solutions carried out with chlorine-evolving anodes and oxygen-consuming cathodes.

Abstract: A chlorine generator cell (10) contains components that require physical isolation between the anode compartment (20), cathode compartment (30), and outside environment. The cell (10) also contains a membrane (50) that provides selective electrical conductivity between the anode compartment (20) and cathode compartment (30). The cell (10) consists of a series of pipe fittings that allow access to the interior of cell (10) for placement of water and salt to generate chlorine. The anode stem (71) and cathode stem (81) located outside of cell (10) are connected to a power supply (91). Power supply (91) may be further connected to a power controller (92) that allows for adjustment of the energy output of power supply (91) to the optimum energy level, thus the desired chlorine output. This invention provides a chlorine generator that is portable, yet is allows for expanded size with additional pipe fittings as needed.

Abstract: Process for the production of ZnCl2 from a Zn bearing primary and/or secondary material comprising the steps of reacting the Zn bearing material with a chlorinating agent such as Cl2 to convert metals into chlorides and vaporising the volatile components of the reaction product at a temperature between the melting point of said reaction product and the boiling point of ZnCl2, thereby recovering a Zn rich chlorinated melt, and thereafter distilling ZnCl2 from this Zn rich chlorinated melt, thereby recovering purified ZnCl2 and a Zn-depleted chlorinated melt.

Abstract: Lightweight and reactive metals can be produced from ore, refined from alloy, and recycled from metal matrix composites using electrolysis in electrolytes including an ionic liquid containing a metal chloride at or near room temperature. Low electric energy consumption and pollutant emission, easy operation and low production costs are achieved.

Abstract: The invention relates to a method for the electrolysis of aqueous solutions of hydrogen chloride, for producing chlorine by means of a gas-diffusion electrode in compliance with set operating parameters.

Abstract: The present invention relates to a process for electrochemical oxidation of bromide to bromine, more particularly to oxidation of bromide ions in brine, bittern and effluents using an indigenous cation exchange membrane flow cell.

Abstract: The invention relates to a process for the electrochemical preparation of chlorine from aqueous solutions of hydrogen chloride in an electrolysis cell, comprising an anode chamber and a cathode chamber, the anode chamber being separated from the cathode chamber by a cation exchange membrane, the anode chamber containing an anode and the cathode chamber a gas diffusion cathode, and the aqueous solution of hydrogen chloride being passed into the anode chamber and an oxygen-containing gas into the cathode chamber, and the oxygen pressure in the cathode chamber being at least about 1.05 bar.

Abstract: The invention relates to a gas diffusion electrode (1) comprising a hydrophobic gas diffusion layer (3b), a reaction layer (3a), and a hydrophilic layer (5) arranged in the mentioned order wherein the reaction layer (3a) is arranged to a barrier layer (4), which barrier layer (4), on its opposite side, is arranged to the hydrophilic layer (5). The invention also relates to a method for manufacturing such a gas diffusion electrode (1), and to an electrolytic cell, and use thereof.

Abstract: Chlorine is produced by electrolysis of aqueous HCl, in a membrane electrolyzer, using cathodic mediators such as Fe(III) and/or Cu(II) chlorides and a non-catalysed 3-dimensional cathode, with the real surface area at least ten times higher than its projected area. The HCl electrolysis section is combined with an oxidiser for regeneration of the mediator, product water removal step and optional HCl recovery step. Under optimised conditions chlorine can be produced at very high current densities of 30 kA/m2, without initiating undesired H2 evolution reaction at the cathode.

Abstract: A method and apparatus for the electrochemical treatment of an aqueous solution in an electrolytic cell is described. Output solution having a predetermined level of available free chlorine is produced by applying a substantially constant current across the cell between an anode and a cathode while passing a substantially constant throughput of chloride ions through the cell.

Abstract: The present invention provides a cation exchange membrane which has excellent durability, a high limiting current density, a low direct current membrane resistance and excellent selectivity to monovalent cations. In the present invention, a cation exchange membrane excellent in selective permeability to monovalent cations is produced by bringing high molecular cations into contact with a surface of a cation exchange membrane in the presence of anions of an oxyacid or anions of an organic sulfonic acid.

Abstract: The invention is directed to compositions of health and beauty care products which are produced by mimicking the human body's own defense mechanisms and the methods to produce and use such compositions. The products are water based, oil and surfactant free and can be antimicrobicidal, without causing drying or itching of the skin. Moreover, such products enhance hydration and moisturizing of the skin and prevent itching. The products are based on water solutions of mixed oxidants, mimicking those produced by the human immune system cells. The invention also describes the processes for producing such products. Such products can be used independently, or to prepare creams, gels, lotions, tooth and other pastes, powders, suppositories, body and hair shampoos and rinses, oral and body hygiene rinses, creams and other products which would be obvious to those skilled in the art.

Abstract: A method for making chlorine dioxide, by passing an aqueous feed solution comprising sodium chlorite into a non-membrane electrolysis cell comprising an anode and a cathode, adjacent to the anode, while flowing electrical current between the anode and the cathode to electrolyze the aqueous feed solution and convert the halogen dioxide salt to halogen dioxide. The anode is preferably a porous anode through which the aqueous feed solution passes to maximize the conversion of chlorite to chlorine dioxide.

Abstract: Chlorine dioxide is produced at high conversion rates from aqueous sodium chlorite solution by electrochemical oxidation in an undivided electrochemical cell. The cell utilizes an anode of high surface area through which the aqueous sodium chlorite solution flows into an interelectrode gap between the anode and a cathode. Water or acidified water is fed into the interelectrode gap to function as catholyte and also to dilute the electrolyzed sodium chlorite solution to provide an aqueous solution of chlorine dioxide exiting from the electrochemical cell.

Abstract: Aqueous alkali metal chloride solutions, typically destined for electrolysis for the production of chlorine and containing a contaminating amount of iodine values in other than the periodate state, are purified by oxidizing the iodine values therein to the periodate oxidation state of +7 and then separating such periodate values therefrom. The starting alkali metal chloride solutions may also contain contaminating amounts of ammonium values, which in turn are oxidized, preferably simultaneously, to molecular nitrogen and degassed therefrom.

Abstract: An electrode for electrolyzing an electrolyte comprising an ammonium fluoride (NH4F)-hydrogen fluoride (HF)-containing molten salt and having a composition ratio (HF/NH4F) of 1 to 3 to prepare a nitrogen trifluoride (NF3) gas and an electrolyte for use in the preparation of NF3 gas, and a preparation method of the NF3 gas by the use of the electrode and the electrolyte. The electrode comprises nickel having 0.07 wt % or less of Si content and containing a transition metal other than nickel. The electrolyte also contains a transition metal other than nickel.