Abstract: A water purification electrode composed of a porous carbon material is disclosed. The electrode may be used as a flow-through cathode in an electro-peroxone process providing high H2O2 production activity for electrochemical wastewater treatment. The porous carbon material is a binding agent-free carbon structure that enables H2O2 to be electro-generated in situ at cathode. The porous carbon material may be synthesized from resorcinol and can provide a relatively large reaction surface area of 200-800 m2/g. The porous carbon material also achieves low energy consumption as well as a wide pH working range, making it suitable for treating many types of organic, inorganic, and biological contaminants in water. The electrode may be integrated with an anode, ozone generator, and other components into a compact, integrated water purification system.

Abstract: An electrolytic reactor for the electrolytic treatment of a fluid is disclosed. The reactor comprises an electrolytic chamber, an electrode cartridge comprising an electrode assembly longitudinally extending from a crown section configured to operatively seal the electrolytic chamber when the electrode assembly is inserted in the electrolytic chamber; an inlet extending perpendicularly to a vertical longitudinal axis defined by the electrolytic chamber; and an outlet extending through the crown section along the vertical longitudinal axis defined by the electrolytic chamber, the outlet being configured to be in fluid communication with the electrolytic chamber when the electrolytic chamber is sealed by the crown section. Advantageouslly, by having the outlet extending upwardly above the electrodes, any dead zone typically found on electrodes at the level of the outlet are eliminated, increaing as such the useful surface area of the electrodes spanning the entire length of the electrolytic chamber.

Abstract: A capacitive adsorption module assembly is proposed. The capacitive adsorption module assembly includes a plurality of capacitive adsorption modules, each having a disk-shaped spacer configured to form a flow path through which feed flows, a cation exchange membrane attached to any one of an upper surface and a lower surface of the spacer, a first electrode attached to the cation exchange membrane, an anion exchange membrane attached to the other of the upper surface and the lower surface of the spacer, and a second electrode attached to the anion exchange membrane, wherein the capacitive adsorption modules are vertically stacked such that adjacent capacitive adsorption modules share or contact the first electrode or the second electrode, and at least one first terminal and second terminal passing through the stacked modules being provided.

Abstract: Disclosed is a split continuous operation micro-grid dynamic membrane bioreactor. The split continuous operation micro-grid dynamic membrane bioreactor comprises a biological treatment unit and a drum dynamic membrane filtration unit, wherein the biological treatment unit comprises a microbiological treatment tank, and a water inlet pipe is arranged on the microbiological treatment tank; the drum dynamic membrane filtration unit comprises a filter tank, and a drum micro-grid dynamic membrane mechanism is arranged in the filter tank; the drum micro-grid dynamic membrane mechanism comprises a filter drum, a backwashing device is arranged above the filter drum, and a sludge collecting tank is arranged in the filter drum; a water outlet is formed in the bottom of the filter tank; a mixed liquid pipe is arranged between the microbiological treatment tank and the filter drum; and a sludge discharge header pipe is arranged on the sludge collecting tank.

Abstract: A method and device for removing chloride ions in desulfurized wastewater by electrochemical coupling in which the device comprises: an electrolyte tank having a top and a bottom wherein the tank is used as a separator in a separation process and as an electrode regenerator in an electrode regeneration process; two electrodes comprising a hydrogen evolution electrocatalysis function electrode and an electrochemically switched ion exchange (ESIX) function electrode respectively, wherein the electrodes are connected with each other by a wire; two DC circuits having opposite electric field directions and used alternately in the separation process and the electrode regeneration process respectively; the bottom of the electrolyte tank is provided with a purified high-concentration chloride ion wastewater inlet and a flocculation product outlet; the top of the tank is provided with a dechlorination treatment water outlet and a hydrogen collecting port; and, in the electrode regeneration process, the electrolyte tan

Abstract: A membrane separation pretreatment apparatus including a membrane separation unit and a first underwater plasma discharge unit disposed in front of the membrane separation unit is provided. The membrane separation pretreatment apparatus includes a membrane separation unit configured to remove particulate matter contained in raw water, and a first underwater plasma discharge unit disposed in front of the membrane separation unit and configured to cause a portion of the raw water to be introduced into the membrane separation unit to perform underwater plasma discharging.

Abstract: The invention provides a device to purify waste water by a two-step procedure containing an electroflotation unit and an electrical disinfection unit integrated into the same overall construction. Characteristic to the construction is that the said two units have a common anode and two individual cathodes which can be in different potentials in respect to the common anode.

Abstract: A dispersion for use with an effluent treatment system, and methods of making and using such a dispersion, whereby the dispersion includes an amount of polymer substantially uniformly dispersed within an aqueous solvent; wherein the dispersion is generated by combining an amount of gas with the amount of polymer and the aqueous solvent, the amount of gas effective to substantially uniformly disperse the amount of polymer within the aqueous solvent.

Abstract: The disclosure teaches an apparatus for circulating electrically conductive solutions between electro-chemical cells. The apparatus is able to decrease the size or surface area of the cells and operate the electro-chemical at reduced amperage. Movement of the solution over the plates also facilitates reduced build up of scale on the plates. The flow rate or treatment dwell time can be controlled.

Abstract: Method for treating sewage, comprising at least one step of electrolytically treating sewage, an energy transfer step comprising at least one selected in the group comprising: a temperature raising treatment, an ultrasound treatment. The electrolytic treatment and energy transfer steps determining the dissociation from the sewage of gas comprising nitrogen. Further, the method comprises a step of separating gases comprising nitrogen from the mass of sewage.

Abstract: The invention relates to a method for enriching water with oxygen by an electrolytic process, that comprises the following series of steps: the electrolysis of Cl? Br? ion-free water in an electrolysis cell in which the anode and the cathode are separated by a gas-tight membrane that is pervious to electric charges; b) recovering the oxygen-enriched water from the anode compartment of the electrolysis cell.

Abstract: The invention relates to a cavitation and electrocoagulation reactor comprising a hollow cylindrical cathode having a cylindrical anode coaxially disposed therein to form an annular interelectrode gap between the contact surfaces. An inlet sleeve and an outlet sleeve disposed in the respective inlet and outlet of the cathode and abutting against opposite ends of the anode seal the interelectrode gap from the respective inlet and outlet of the cathode. A set of channels disposed in the wall of the inlet sleeve connect the inlet to the interelectrode gap. Similarly, a set of openings disposed in the outlet sleeve connect the interelectrode gap to the cathode outlet. An electrical source has first and second terminals respectively connected to the anode and the cathode. The method for removing contaminants from a contaminated fluid flow involves the simultaneous application of hydrodynamic cavitation and electrocoagulation to the contaminated fluid flow.

Abstract: Corrosion-inhibited hypochlorite compositions and methods of use are disclosed. Corrosion inhibitors including sugar acids and calcium compounds, polyacrylate and calcium compounds, and/or zinc and calcium compounds are used with hypochlorite sources to enhance the longevity and performance of electrochemical cells as well as reducing corrosion of metal in contact with the generated hypochlorite sources. The methods for generation employ a variety of electrochemical cells, beneficially including use of portable electrochemical cell system for production of corrosion-inhibited hypochlorite cleaning solutions.

Abstract: A method and apparatus are provided for generating and applying a sanitizing liquid. The method includes moving a mobile floor cleaning device along a floor and electrochemically activating a liquid on the mobile floor cleaning device by passing the liquid through a functional generator having first and second electrode chambers that are separated by an ion exchange membrane such that the liquid activated in the first electrode chamber comprises O3 molecules. Substantially all of the liquid activated in the first and second electrode chambers are dispensed from the device within 5 seconds of the time at which the liquids are activated by the functional generator without an intermediate step of storing either of the liquids produced in the first or second electrode chambers. At least some of the dispensed liquid is recovered from the floor with a recovery device carried by the mobile floor cleaning device.

Abstract: Methods for electrolysis of water to oxygen gas are provided. The method utilizes dimeric copper cations in water at a basic pH. The cations are provided in the water by adding a complex in solid form with an appropriate anion, or through a “self-assembly” method whereby a copper salt and appropriate ligands are added to water adjusted to a basic pH. The cations decrease the overpotential of water electrolysis, thereby providing for efficient generations of oxygen gas using a catalyst formed from an abundant material (copper).

Abstract: Corrosion inhibitor compositions and methods of use are disclosed. Corrosion inhibitors are selected from polyacrylate and calcium corrosion inhibitors, zinc and calcium corrosion inhibitors and/or sugar acids and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.

Abstract: Water sanitizing apparatus is provided for pools, spas hot tubs and other similar bathing facilities that integrates an ozone generator and a chlorine generator in one unit, in addition to exposing a flow of water to be purified to ultraviolet radiation from the ozone generator for advanced oxidation reactions. In one embodiment, a mixing venturi allows for mixing various substances together prior to insertion into the motive flow. In another embodiment the venturi is constructed as inserts that allow tuning of the venturi for individual systems. In other embodiments, salt is added to a portion of the water flow as a concentrated brine from which chlorine is generated, or the salt may be simply be added to the water of the facility at a much lower concentration and chlorine generated from the flow of water through the apparatus.

Abstract: Methods and systems for treating wastewater. Wastewater slurry collected in a tank is routed by a macerator pump. The macerated slurry is piped to an electrolytic cell to oxidize and disinfect it. The slurry is then piped to an electrocoagulation cell. Suspended solid particles are flocculated in the electrocoagulation cell. The flocculated slurry is routed to a primary settling tank for separation of sludge and a substantially clarified supernatant. The supernatant is piped to a secondary clarifying tank to facilitate further separation of the sludge. The sludge is discharged to a sludge collection tank. The turbidity levels of the sludge discharged is continually monitored. When the turbidity level equals a pre-determined low value, the sludge discharge is stopped. The substantially clarified supernatant may be discharged as an effluent following dechlorination.

Abstract: A water purification system includes at least one flow electrolysis cell Each cell comprising an input for receiving wastewater, a cathode, a non-sacrificial anode, and an output for outputting purified water. The non-sacrificial anode is capable of being operated at an input power of at least about, 1000 W up to about 5000 W to form electrooxidation cocktail, and the electrooxidation cocktail treats the wastewater to form purified water.

Abstract: The present invention relates to Nitrogen-rich water production system that produces water rich in nitrogen; wherein such water is considered as a fertilizer since nitrogen is an essential nutrient for plants and one of their constituents. Thus, such Nitrogen-rich water can be mixed with irrigation water. The system of the present invention comprises a source of water vapor; an air pump; a source of high potential difference; an electrochemical reaction chamber, wherein such chamber comprises two electrical conductive plates with an air gap between them, means for adjusting the size of such air gap, an inlet, two outlets, a plate of a non-electrical conductive material; and a chemical reaction chamber that comprises a source of atomized water, an inlet, an outlet; a flask, and a plurality of valves. The present invention uses high potential difference to initiate the electrochemical reaction for the production of nitrogen-rich water.

Abstract: The wastewater treatment apparatus of present invention has an electro-coagulation unit for removing contaminants with at least one anode and at least one cathode and an electro-oxidation unit for oxidizing contaminants with at least one anode and at least one cathode wherein oxidants are electrochemically generated. Based on the type of wastewater, the apparatus can have an electro-flotation unit between the electro-coagulation unit and the electro-oxidation unit. The apparatus also has an oxidant removal unit which can have a metal ion-liberating electrode for reacting with and removing residual oxidants. In some cases, portions of effluent from the oxidant removal unit can be recirculated to the electro-coagulation unit for increased efficiency.

Abstract: A water treatment system includes a reservoir for holding water to be treated, one or more primary electrode pairs at least partially immersed in water held in the reservoir, a power supply adapted to power the one or more primary electrode pairs, and an agitator operable to cause movement in the water and particles and gases therein. Water is treated in the system by performing at least a first electrolysis phase wherein one or more of the primary electrode pairs are powered using electrical current of a first polarity such that for each powered primary electrode pair one electrode provides dissolved ions which act as an attractant for impurities to aid removal of the impurities from the water. The agitator can be operated during the first electrolysis phase to cause movement in the water and particles and gases therein to aid carriage of ions and impurities away from the electrodes.

Abstract: The present invention relates to the treatment of wastewater by electrochemical reactions. More particularly, an Electro-Reaction Unit (ERU) is disclosed. The ERU is provided with at least one electrolytic cell comprising a pair of self-cleaned electrodes for purifying wastewater. Along with electro-reactions, electrodes of the ERU are submitted to passivation, i.e. coverage with an oxide layer. The present invention provides a solution for alleviating passivation with a self-cleaning system comprising hard elements, confined in a cage and movable therein, for bombardment of the electrodes and rupture of the oxide layer. The present invention further provides a related process.

Abstract: Methods for electrolysis of water to oxygen gas are provided. The method utilizes dimeric copper cations in water at a basic pH. The cations are provided in the water by adding a complex in solid form with an appropriate anion, or through a “self-assembly” method whereby a copper salt and appropriate ligands are added to water adjusted to a basic pH. The cations decrease the overpotential of water electrolysis, thereby providing for efficient generations of oxygen gas using a catalyst formed from an abundant material (copper).

Abstract: In a method of decomposing partially fluorinated and perfluorinated surfactants which are, in particular, present in wastewater, sewage sludges and the like, the surfactant is present in solution or suspension and is electrolytically decomposed. An anodic oxidation of the surfactants preferably takes place here. The method is particularly suitable for decomposing perfluorinated alkylsulfonates, in particular PFOS. The invention also describes an apparatus for electrolytically decomposing partially fluorinated and perfluorinated surfactants.

Abstract: Disclosed is a method of purifying fluid, typically an aqueous fluid steam, with the method involving at least two reverse osmosis stages with retentate from a first reverse osmosis stage being subjected to the second reverse osmosis stage, and with intermediate treatment of retentate from the first reverse osmosis stage by exposure to an electric field. The intermediate treatment may involve electrocoagulation to remove sparingly-soluble compounds and permit enhanced reverse osmosis recovery. Additional treatment may be performed prior to the first reverse osmosis stage, between the first reverse osmosis stage and the intermediate treatment with an electric field, between such intermediate treatment and the second reverse osmosis stage, or after the second reverse osmosis stage.

Abstract: A method and apparatus are provided for receiving a cleaning liquid having a pH in a range between pH6-pH8 and an oxidation reduction potential (ORP) between ±50 mV. The liquid is converted into an anolyte liquid and a catholyte liquid having respective pHs outside of the range between pH6-pH8 and having respective ORPs outside the range between ±50 mV. The anolyte and catholyte liquids are applied to a surface, wherein the anolyte and catholyte liquids are, for example, in a combined state on the surface and substantially neutralize to a pH between pH6-pH8 and an ORP between ±50 mV within one minute of the time at which the anolyte and catholyte liquids are converted.

Abstract: A method is provided, which includes generating a cleaning liquid by a combination of a sparging process and an electrochemical process that produces an anolyte and a catholye.

Abstract: A method is provided, which includes moving a mobile floor cleaning machine along a floor. Onboard the mobile floor cleaning machine, a liquid is sparged by electrolysis. The sparged liquid is dispensed from the mobile floor cleaning machine.

Abstract: A method is provided, which includes moving a mobile floor cleaning device along a floor; electrochemically activating a liquid on the mobile floor cleaning device, and dispensing the electrochemically activated liquid from the mobile floor cleaning device.

Abstract: An electrochemically activated fluid is provided, which has an anolyte and a catholyte. For example, a sparged anolyte and a sparged catholyte are provided. In another example, a combined anolyte and catholyte is provided.

Abstract: A method is provided, which includes moving a mobile floor cleaning device along a floor; electrochemically activating a liquid on the mobile floor cleaning device, and dispensing the electrochemically activated liquid from the mobile floor cleaning device.

Abstract: A method is provided, which includes moving a mobile floor cleaning machine along a floor. Onboard the mobile floor cleaning machine, a liquid is sparged by electrolysis. The sparged liquid is dispensed from the mobile floor cleaning machine.

Abstract: A method is provided, which includes generating a cleaning liquid by a combination of a sparging process and an electrochemical process that produces an anolyte and a catholye.

Abstract: A modular waste disinfection system for the disinfection of substantially liquid infectious waste streams and methods of treating such waste streams are disclosed. The modular waste disinfection system includes a metal ion generation chamber for introducing metal ions into the waste material; an oxidant generation chamber in fluid flow communication with the metal ion generation chamber for disinfection of the waste material with an oxidizing agent; and a chelation chamber in fluid flow communication with the oxidant generation chamber for deactivation of metal ions in the waste material, wherein the waste is discharged to a sanitary sewer after disinfection.

Abstract: A modular waste treatment system for substantially liquid waste streams and methods of treating liquid waste streams are disclosed. The modular waste treatment system includes a maceration chamber for initial treatment and homogenization of waste material; a metal ion infusion chamber in fluid flow communication with the maceration chamber for introducing metal ions into the waste material; and an oxidation chamber for wet oxidation of the waste stream.

Abstract: Chemical decontamination method of dissolving oxide film adhered to contaminated component including, preparing decontamination solution in which ozone is dissolved and oxidation additive agent, which suppresses corrosion of metal base of the contaminated component, is added, and applying the decontamination solution to the contaminated component, thereby to remove the oxide film by oxidation.

Abstract: A wastewater treatment system for removing contaminants from wastewater on a vessel using electricity. The wastewater treatment system may inject wastewater with one or more disinfectants or ionized gases, or both, to remove at least a portion of contaminants from the wastewater. The water treatment system may produce disinfectants from saltwater using one or more disinfectant generators and return the byproducts to a water body. The wastewater treatment system may also pass wastewater through an electrical coagulation unit in which an electrical current may be emitted into the wastewater, whereby flocculants are formed and cause suspended solids and other materials to settle out of the wastewater. The wastewater treatment system may include a secondary treatment system for further reducing concentrations of contaminants. In addition, the wastewater treatment system may include a solid waste treatment system for incinerating solids produced by the wastewater treatment system.

Abstract: Methods for electrolytic oxygenation of aqueous systems, including substantially immersing an anode and a cathode in an aqueous medium, injecting oxygen into the aqueous medium, and applying a current to the electrodes.

Abstract: The present invention provides a method and apparatus for sterilizing articles using an ozone-containing gas, where condensation of water from the sterilization atmosphere during the sterilization process is substantially prevented. The inventive sterilization method includes providing a sterilization chamber and placing an article into the sterilization chamber. The sterilization chamber is sealed prior to equalizing the temperature of the article and the atmosphere in the sterilization chamber. A vacuum is applied to achieve a preselected vacuum pressure in the sterilization chamber. Once the vacuum pressure is set, water vapour is supplied to the sterilization chamber. Ozone-containing gas is then supplied to the sterilization chamber and the sterilization chamber remains sealed for a preselected treatment period, where the sterilization chamber remains sealed throughout the whole process. Finally, vacuum in the sterilization chamber is released.

Abstract: This invention describes a one step process for the removal of heavy metals, particularly arsenic, from water. The process consists in promoting the circulation of the water to be treated in an electrolytic cell equipped with iron, or iron alloy anodes and cathodes made of iron or iron alloy or other metals, while the contemporary insufflation into the cell of a gas, partially or totally composed of oxygen. In this way the iron of the anode electrodes dissolves as iron hydroxide. The ferrous hydroxide thus generated, under the action of the oxygen contained in the insufflated gas is converted to ferric hydroxide, which, through a complex mechanism, adsorbs and forms insoluble complexes with the arsenic ions. At the same time As(III) is subject to oxidation both at the anode and at the cathode. By this process both forms of arsenic, As(III) and As(V), are equally removed. The treated water is further processed by conventional clarifying and filtering.

Abstract: The present invention relates to gaseous discharge and applied biotechnology. In particularly, the present invention relates to a method for killing organisms in the course of conveying ballast water in ship, comprising applying a voltage with frequency of 400-40000 Hz between the anode electrode and the cathode electrode of the free radical generator, thereby forming strong ionization discharge of electric field strength of 250-600 Td between the anode electrode and the cathode electrode, ionizing, dissociating, and exciting O2 and H2O, or O2, processing into active particles comprising O3, OH. and HO2, dissolving excitedly to obtain free radical solution mainly consisted of OH, adding the free radical solution to conveying pipeline of ballast water, conveying for 2-20 s in the pipeline, thereby killing organisms of ballast water selected from the group consisted of bacteria, single cell alga, and protozoan.

Abstract: A method and apparatus for contaminant separation utilizes an interleaved array of oppositely charged electrode plates for fluid treatment. Spacing between the parallel electrode plates is graduated so that the volume of the cavities between the opposing electrodes provides varying levels of treatment of a broad range of contaminants from a variety of fluid columns. A fluid flow path extending substantially orthogonal to the direction of the electrical field established between opposing electrode plates provides a feed stream with exposure to the varying levels of electrical charges between the electrode plates. The method and apparatus provide an effective means of contaminant separation by a device having a small footprint and requiring low amounts of electrical energy.

Abstract: There is provided a nitrogen treating method capable of treating nitrogen compounds efficiently. The method is a nitrogen treating method of treating nitrogen compounds in for-treatment water by electrolysis and performs a first treating step of producing ammonia from the nitrogen compounds in the for-treatment water by electrolysis using a cathode and an anode between which a cation exchange film is interposed so as to define a cathode reaction region and an anode reaction region, and a second treating step of removing the ammonia in the for-treatment water treated in the cathode reaction region by the first treating step.

Abstract: The sterilization method disclosed includes the steps of providing a sterilization chamber; placing the article into the sterilization chamber; equalizing the temperature of the article and the sterilization atmosphere; sealing the sterilization chamber; applying a vacuum of a preselected vacuum pressure to the sterilization chamber; supplying water vapour to the sterilization chamber under vacuum; supplying ozone-containing gas to the sterilization chamber; maintaining the sterilization chamber sealed for a preselected treatment period; and releasing the vacuum in the sterilization chamber; whereby a vacuum pressure is used which lowers the boiling temperature of water in the sterilization chamber below the temperature in the sterilization chamber. One or more ventilating cycles can be added to the preferred method for removing the remaining ozone and humidity from the sterilization chamber.

Abstract: A method and apparatus for contaminant separation utilizes an interleaved array of oppositely charged electrode plates for fluid treatment. Spacing between the parallel electrode plates is graduated so that the volume of the cavities between the opposing electrodes provides varying levels of treatment of a broad range of contaminants from a variety of fluid columns. A fluid flow path extending substantially orthogonal to the direction of the electrical field established between opposing electrode plates provides a feed stream with exposure to the varying levels of electrical charges between the electrode plates. The method and apparatus provide an effective means of contaminant separation by a device having a small footprint and requiring low amounts of electrical energy.

Abstract: Contaminated water, particularly, ballast water, blackwater, galley water, accommodation water, laundry water, fresh water and seawater, is disinfected by admixture of a highly reactive gas stream containing ions of oxygen and nitrogen, formed by exposure of air to short-wavelength ultraviolet radiation, and of chlorine, formed in situ by electrolysis of salt in the water. Solids removal can be accomplished by electrophoresis in the same unit employed for electrolysis to release chlorine, or in a separate unit. Heavy metals maybe removed by plating or sacrificing electrodes.

Abstract: A redox bipolar cell fabric washing system and method is disclosed that provides for washing fabrics without the use of any added detergents, fabric softeners, or bleaches, or other chemical al additives. The system includes a conventional fabric washing machine with a redox bipolar cell that through a circulation pump continuously treats the wash water by using mixed oxidants or charged wash water to remove contaminants from the fabric. The redox cell includes a housing, a plurality of cathode plates, a plurality of membranes, and a plurality of anodes proximately positioned in an alternate manner with a plurality of flow channels in the housing. The cell produces charged wash water by an electrochemical reaction utilizing electrically charged anodes and cathodes with semi permeable membranes, wherein the oxidation reduction potential of the charged wash water is continuously controlled with a sensor to determine when the fabrics are clean.

Abstract: A water purification system for a swimming pool, pond, aquatic mammal tank, spa or fountain, which is simple to operate, low in maintenance, and highly reliable. The system takes advantage of synergistic benefits derived from the combination of ozonation and electrolytic chlorination in the same system. Combining both of the technologies of Ozonation and Electrolysis allows as in-site production of at least one of chlorine dioxide that is used as a disinfectant agent for treating water reservoirs.

Abstract: A novel system and method for purification and disinfection of water containing contaminates is provided. The system includes an aeration column, a first intermediate tank, a first mechanical filter, an electric discharge device, a second intermediate tank, a second mechanical filter and a sorption filter. The water is firstly aerated by continuous mixing the water with air and ozone-air mixture. The water obtained after the aeration is treated with coagulant materials in a medium of the ozone-air mixture. Further, the water is filtered from coagulated particles. Thereafter, the water is treated by electric discharges in an air medium. The water is then treated again with coagulant materials. Finally, the water is filtered from remaining contaminates.