In Combustible Gas (e.g., Air/fuel Mixture For Internal Combustion Engine, Etc.) Patents (Class 205/784.5)
  • Patent number: 7144494
    Abstract: A compensation circuit (KS) is provided between the output of a differential amplifier (Diff_Amp) and the input of a controller (R). The compensation circuit generates a compensation signal, whose characteristic curve approximates to that of the parasitic signal, with the same amplitude and frequency (Phi1) as the parasitic signal, but by 180 DEG out of phase. The compensation signal is subtracted from the differential signal (DELTA Vs) and allows the parasitic signal to be eliminated to a great extent.
    Type: Grant
    Filed: January 13, 2003
    Date of Patent: December 5, 2006
    Assignee: Siemens Aktiengesellschaft
    Inventor: Stephan Bolz
  • Patent number: 7052595
    Abstract: A gas sensor for determining the concentration of gas components in gas mixtures is used in particular to measure the concentration of nitrogen oxides in exhaust gases of internal combustion engines or in the interiors of motor vehicles. It contains an electrochemical measuring cell which includes a first electrode situated on a solid electrolyte and an additional electrode. The electrode is made of an oxide material containing lanthanum which at least catalytically decomposes nitrogen oxides. The pump current flowing between the electrodes is used as a measure of the nitrogen oxide concentration in the gas mixture.
    Type: Grant
    Filed: December 9, 2000
    Date of Patent: May 30, 2006
    Assignee: Robert Bosch GmbH
    Inventors: Thomas Schulte, Thomas Wahl, Bernd Mueller
  • Patent number: 7052596
    Abstract: The pumping current source (P) required for operating the linear lambda probe is wired in such a manner that its inverting input is connected to the third probe terminal (Vp+), its non-inverting input is connected to the potential of the mean voltage (VM), and that its output is connected to the second probe terminal (Vp?/Vs?).
    Type: Grant
    Filed: December 16, 2002
    Date of Patent: May 30, 2006
    Assignee: Siemens Aktiengesellschaft
    Inventor: Stephan Bolz
  • Patent number: 6994780
    Abstract: A gas sensor includes a measurement gas chamber into which a measurement gas is introduced. An oxygen pumping cell adjusts an oxygen concentration in the measurement gas chamber. An oxygen monitor cell has a monitor electrode exposed in the measurement gas chamber. The monitor electrode has an oxidizing activity with respect to a specific component of the measurement gas. A sensor cell has a sensor electrode exposed in the measurement gas chamber. The sensor electrode has an oxidizing activity with respect to the specific component of the measurement gas which is lower than the oxidizing activity of the monitor electrode. An oxygen-ion current in the oxygen monitor cell is detected. An oxygen-ion current in the sensor cell is detected. A concentration of the specific component of the measurement gas is detected from a relation between the detected oxygen-ion currents in the oxygen monitor cell and the sensor cell.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: February 7, 2006
    Assignees: Denso Corporation, Nippon Soken, Inc.
    Inventors: Keigo Mizutani, Kazunori Suzuki, Toshitaka Saito, Daisuke Makino
  • Patent number: 6923902
    Abstract: A method for detecting the concentration of a specific component in gas discharged from an internal combustion engine, which includes detecting the concentration of the specific component under certain driving conditions to determine a zero point, which indicates a zero concentration of the specific component, of the detection output; calibrating the detection output of the gas sensor based on the determined zero point; and detecting the concentration of the specific component in exhaust gas based on the calibrated detection output.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: August 2, 2005
    Assignee: NGK Spark Plug Co, Ltd.
    Inventors: Masashi Ando, Noboru Ishida, Satoshi Sugaya, Takafumi Oshima, Norihiko Nadanami, Takaki Otsuka, Yoshikuni Sato, Tatsuo Okumura, Yasuhisa Kuzuya
  • Patent number: 6890422
    Abstract: An electrochemical gas sensor determining the concentration of oxidizable gas components which has an electrochemical measuring cell having a measuring electrode and a reference electrode. Measuring electrode is made of a material which is not able, or not completely able to catalyze the establishment of gas equilibrium. In addition to the electrochemical measuring cell, at least one electrochemical pumping cell, having at least one inner pumping electrode, is provided, which, together with measuring electrode, is positioned in a measuring gas compartment. Oxygen is pumped into or out of measuring gas compartment by pumping cell, the partial pressure of oxygen in measuring gas compartment being set to a lambda value of ?1.3.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: May 10, 2005
    Assignee: Robert Bosch GmbH
    Inventors: Frank Stanglmeier, Bernd Schumann, Thomas Moser
  • Patent number: 6849174
    Abstract: A gas concentration measuring apparatus which has a gas sensor designed to measure, for example, the concentrations of O2 and HOx contained in exhaust emissions of an automotive engine is provided. The apparatus includes a signal processing circuit which converts a current signal outputted from the gas sensor as a function of the concentration of either of O2 and NOx into a voltage signal. The gas sensor and the signal processing circuit are connected electrically through a conductor. The conductor has a length which is determined as a function of a level of the current signal outputted from the gas sensor. The weaker the level of the current signal is, the shorter the length of the conductor. This minimizes addition of electrical noises to the current signal outputted from the gas sensor.
    Type: Grant
    Filed: February 26, 2003
    Date of Patent: February 1, 2005
    Assignee: Denso Corporation
    Inventors: Satoshi Hada, Eiichi Kurokawa, Tomoo Kawase, Toshiyuki Suzuki, Satoshi Haseda
  • Patent number: 6818120
    Abstract: An O2-sensor fault diagnosis apparatus and method therefor, which are capable of detecting wire breaking of an O2-sensor with reliability and successively performing fault diagnosis with minimal effect on an exhaust gas. An O2-sensor 19 detects concentration of oxygen contained in an exhaust gas of an engine 1. An ECU 20 controls a quantity of fuel supplied to the engine 1 through feedback control according to an output signal of the O2-sensor. A fault diagnosis portion changes an input resistance value of an input circuit that is connected to the O2-sensor 19 and constitutes the ECU 20 each time a control condition for determining that the O2-sensor 19 is in an inactive state is satisfied, determines that wire breaking occurs in the O2-sensor 19 only if the output voltage of the O2-sensor 19 exceeds a predetermined voltage, and activates an informing portion to send a notice showing that there is a fault in the O2-sensor 19.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: November 16, 2004
    Assignee: Mitsubishi Denki Kabushiki Kaisha
    Inventors: Masaki Nakamichi, Ryoichi Hanazaki
  • Publication number: 20040178082
    Abstract: Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).
    Type: Application
    Filed: March 12, 2003
    Publication date: September 16, 2004
    Inventors: Anthony H. McDaniel, J. Will Medlin, Robert J. Bastasz
  • Publication number: 20040149595
    Abstract: A sensor including: an upper shell, an outer shield disposed in physical communication with the upper shell, a sensing element comprising a sensing electrode and a reference electrode disposed at a sensing end of the sensing element, wherein the sensing end is disposed in the outer shield, and a sampling tube extending from the outer shield. The sampling tube is configured to enable fluid communication between the sensing element and an environment external to the outer shield.
    Type: Application
    Filed: September 24, 2003
    Publication date: August 5, 2004
    Inventor: Wayne R. Moore
  • Patent number: 6767449
    Abstract: Method for operating a sensor for determining the concentration of oxidizing gases in gas mixtures, especially of the nitrogen oxide concentration in exhaust gases of internal combustion engines, wherein the sensor includes: at least one chamber (1; 2) mounted in a solid state electrolyte (20), the chamber being connected to the gas mixture via a first diffusion barrier (4); a second chamber (3) arranged in the solid state electrolyte (20) and the chamber having a pregivable constant oxygen partial pressure; on the solid state electrolyte, an oxygen pump electrode (9) subjected to the exhaust gas; a further oxygen pump electrode (7; 8) as well as an NO pump electrode (10) in the at least one chamber (1; 2); and an oxygen reference electrode (6) arranged in the second chamber (3); and at least a voltage is made available at the electrodes and at least a pump current is evaluated as a measurement signal.
    Type: Grant
    Filed: November 30, 2001
    Date of Patent: July 27, 2004
    Assignee: Robert Bosch GmbH
    Inventors: Berndt Cramer, Bernd Schumann
  • Patent number: 6743352
    Abstract: A method for detecting the concentration of a specific gas (NOx) in an engine exhaust gas using a gas sensor and a process of correcting the gas sensor. According to the correcting process, the amount of moisture in the exhaust gas is estimated, then a a gas concentration detection signal output by the gas sensor on the basis of an estimated amount of moisture is corrected. Finally, the effect of the amount of moisture in the exhaust gas is removed or reduced from the detected value of gas concentration.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: June 1, 2004
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Masashi Ando, Noboru Ishida, Satoshi Sugaya, Takafumi Oshima, Norihiko Nadanami, Takaki Otsuka, Yoshikuni Sato, Tatsuo Okumura, Yasuhisa Kuzuya
  • Publication number: 20040094415
    Abstract: The invention relates to a gas sensor (S) that comprises at least one gas-sensitive region (2) that is applied to a substrate (1), said substrate (1) being provided with at least one diffusion-open section.
    Type: Application
    Filed: July 23, 2003
    Publication date: May 20, 2004
    Inventors: Andreas Bausewein, Rolf Bruck, Hans Meixner, Meike Reizig
  • Publication number: 20040055900
    Abstract: An apparatus 20 may include a generator 22 and a combustion turbine 24 for driving the generator, the combustion turbine having an air inlet 40 for receiving an inlet air flow. The apparatus may also include an inlet air flow sampling sensor 26. The inlet air flow sampling sensor 26, in turn, may include a solution container 46 for containing a solution 50 for sampled air from the inlet air flow. The inlet air flow sampling sensor 26 additionally may include sensing circuitry for sensing at least one dissolved material in the solution 50. For example, the material may be salt, such as found in the inlet air for coastal power plants.
    Type: Application
    Filed: September 23, 2002
    Publication date: March 25, 2004
    Applicant: Siemens Westinghouse Power Corporation
    Inventors: Eugene E. Smeltzer, Brian D. Ottinger, Mary Anne Alvin
  • Patent number: 6699383
    Abstract: A thick-film measurement sensor includes two measurement cells and is used to measure the NOx concentration in the exhaust gas from an internal combustion engine. The 1/&lgr; value of the exhaust gas is determined from an oxygen ion pump current flowing in the first measurement cell, for example, by a characteristic diagram, and, a measurement error, which can be used to correct the measured NOx concentration, is determined from this 1/&lgr; value, for example, by a characteristic curve that has previously been determined in a calibration measurement. The invention is based on the discovery that the measurement error is dependent on the air ratio in the exhaust gas. If this is expressed by the 1/&lgr; value, there is no need for a complex division calculation during the correction.
    Type: Grant
    Filed: May 28, 2002
    Date of Patent: March 2, 2004
    Assignee: Siemens Aktiengesellschaft
    Inventors: Bertrand Lemire, Tim Walde
  • Publication number: 20030221976
    Abstract: A device for determining the ozone conversion rate of an ozone conversion element which is coated with a catalyst material, in particular of a radiator in a motor vehicle. The device having a first air-guidance passage and a second air-guidance passage for receiving air upstream and downstream of the ozone conversion element, the air-guidance passages being connected via a switching device to a third air-guidance passage, in which an ozone sensor element is arranged. By means of the switching device, either the airstream upstream of the ozone conversion element or the airstream downstream of the ozone conversion element can be passed to the ozone sensor element.
    Type: Application
    Filed: January 27, 2003
    Publication date: December 4, 2003
    Inventors: Joerg Friedel, Anton Grabmaier, Hans-Peter Gottler, Alexander Sommer
  • Patent number: 6605202
    Abstract: A mixed potential electrochemical sensor for the detection of gases has a ceria-based electrolyte with a surface for exposing to the gases to be detected, and with a reference wire electrode and a sensing wire electrode extending through the surface and fixed within the electrolyte as the electrolyte is compressed and sintered. The electrochemical sensor is formed by placing a wire reference electrode and a wire sensing electrode in a die, where each electrode has a first compressed planar section and a second section depending from the first section with the second section of each electrode extending axially within the die. The die is filled with an oxide-electrolyte powder and the powder is pressed within the die with the wire electrodes. The wire-electrodes and the pressed oxide-electrolyte powder are sintered to form a ceramic electrolyte base with a reference wire electrode and a sensing wire electrode depending therefrom.
    Type: Grant
    Filed: June 18, 2002
    Date of Patent: August 12, 2003
    Assignee: The Regents of the University of California
    Inventors: Rangachary Mukundan, Eric L. Brosha, Fernando Garzon
  • Publication number: 20030116448
    Abstract: A gas sensor element which may be employed in measuring the concentration of gas such O2, NOx, or CO. The gas sensor element consists of an electrochemical cell made up of a solid electrolyte body formed by a partially stabilized zirconia and a pair of electrodes disposed on the solid electrolyte body. The electrochemical cell is subjected to an aging treatment in which the dc current is applied to the electrodes at a given voltage to enhance the activation of the electrochemical cell.
    Type: Application
    Filed: December 20, 2002
    Publication date: June 26, 2003
    Inventors: Makoto Nakae, Susumu Naito, Namitsugu Fujii, Hiromi Sano, Tomio Sugiyama, Kazuya Nakagawa
  • Patent number: 6576118
    Abstract: According to the present invention, there is provided: a sensor element including an oxygen concentration detection section consisting of solid electrolyte for outputting a detection signal corresponding to an oxygen concentration in a hollow chamber to which an exhaust of an internal combustion engine is introduced and an oxygen pump section for controlling an electric current to be applied to a solid electrolyte wall that divides the hollow chamber from an exhaust side of the engine so that the oxygen concentration in the hollow chamber becomes a predetermined oxygen concentration, to flow oxygen into/out of the hollow chamber; an air-fuel ratio detection circuit for outputting an air-fuel ratio detection value based on the electric current applied to the solid electrolyte wall by the oxygen pump section; and a pump current cut off circuit for cutting off the power supply to the solid electrolyte wall by the oxygen pump section, and a detection value of air-fuel ratio is corrected based on an output value o
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: June 10, 2003
    Assignee: Unisia Jecs Corporation
    Inventor: Shigeo Ohkuma
  • Publication number: 20030101569
    Abstract: A heater is inserted into an inside chamber of a sensor element until a tip end of the heater is surely brought into contact with a bottom surface of the inside chamber. Next, a metallic holder is attached on an outside surface of the heater. Then, the metallic holder is slid along the outside surface of the heater toward the bottom surface of the sensor element to engage the metallic holder with an edge of the sensor element.
    Type: Application
    Filed: January 2, 2003
    Publication date: June 5, 2003
    Applicant: DENSO CORPORATION
    Inventors: Isao Watanabe, Michihiro Yamakawa, Masanori Fukutani
  • Publication number: 20030080003
    Abstract: A testing and calibrating device for an evaluation circuit of a linear oxygen probe (S) of an internal combustion engine is disclosed. Said device comprises a probe equivalent circuit (SES) having the same terminals (Vs+, Vs−/Vp−, Vp+ and Rc) as the oxygen probe (S). The probe equivalent circuit can largely emulate the electrical and chemical behaviors of the oxygen probe (S) and simulate probe faults and, at least during a testing and calibrating process, is connected to the evaluation circuit in place of the oxygen probe (S) or is connected parallel to said oxygen probe.
    Type: Application
    Filed: November 22, 2002
    Publication date: May 1, 2003
    Inventors: Dariusch Akhavan, Stephan Bolz
  • Patent number: 6551499
    Abstract: This invention provides a method for monitoring the function and/or regeneration of a gas probe. The invention includes a measurement of first and second pump currents of the gas probe and a determination of a difference between the first and second pump currents (&Dgr;I). If &Dgr;I exceeds a pregiven value, then a saturation pump voltage is applied and the difference between a resulting pump current and a previously stored minimum pump current (&Dgr;I plus) is determined. If &Dgr;I plus exceeds a pregiven value, then a regeneration voltage is applied.
    Type: Grant
    Filed: June 20, 2001
    Date of Patent: April 22, 2003
    Assignee: Robert Bosch GmbH
    Inventors: Carsten Springhorn, Bernd Schumann, Sabine Thiemann-Handler
  • Patent number: 6551498
    Abstract: The protective shield arrangement for an exhaust sensor and method of making and using the same is achieved by providing a protective shield for an exhaust gas sensor that comprises a porous mesh material formed as a cap for placement over an end portion of a sensing element. This is formed by a method that comprises providing a unitary piece of the mesh material, and folding the mesh material to form the cap. Thereby, gas passes through the tortuous pathway created by the mesh material to be sensed by the sensor.
    Type: Grant
    Filed: February 13, 2001
    Date of Patent: April 22, 2003
    Assignee: Delphi Technologies, Inc.
    Inventor: Charles Scott Nelson
  • Patent number: 6550305
    Abstract: Before starting an air-fuel ratio feedback control utilizing an air-fuel ratio sensor, activation of a wide-range air-fuel ratio sensor in an internal combustion engine is diagnosed by calculating heat transferred to and from the air-fuel ratio sensor, the output value of the wide-range air-fuel ratio sensor varies in response to oxygen concentration in exhaust which varies according to the air-fuel ratio of an intake air-fuel mixture of the internal combustion engine. The activation time from the starting of the engine until the air-fuel ratio sensor is activated is estimate based on the calculated result of the heat transfer. Alternatively, activation of the sensor is diagnosed under the condition that an output voltage of the oxygen concentration detecting unit of the sensor is fixed to a value either equal to or above a rich-side set voltage or equal to or under a lean-side set voltage, before starting the air-fuel ratio feedback control.
    Type: Grant
    Filed: September 12, 2002
    Date of Patent: April 22, 2003
    Assignee: Unisia Jecs Corporation
    Inventor: Naoki Tomisawa
  • Patent number: 6547955
    Abstract: A gas concentration measuring apparatus which has a gas sensor designed to measure, for example, the concentrations of O2 and HOx contained in exhaust emissions of an automotive engine is provided. The apparatus includes a signal processing circuit which converts a current signal outputted from the gas sensor as a function of the concentration of either of O2 and HOx into a voltage signal. The gas sensor and the signal processing circuit are connected electrically through a conductor. The conductor has a length which is determined as a function of a level of the current signal outputted from the gas sensor. The weaker the level of the current signal is, the shorter the length of the conductor. This minimizes addition of electrical noises to the current signal outputted from the gas sensor.
    Type: Grant
    Filed: December 3, 1999
    Date of Patent: April 15, 2003
    Assignee: Denso Corporation
    Inventors: Satoshi Hada, Eiichi Kurokawa, Tomoo Kawase, Toshiyuki Suzuki, Satoshi Haseda
  • Patent number: 6544405
    Abstract: An exhaust gas sensor element having an electrochemical cell, a protective material in fluid communication with the electrochemical cell, and a reactive inhibitive coating disposed over the protective material. The reactive inhibitive coating prevents the reaction of compounds with acids(e.g., phosphates) in the exhaust gas, which may form a dense glass layer on the outside of the gas sensor. The reactive inhibitive coating is either an alkaline earth oxide ethoxide, and/or carbonate that is deposited on the gas sensor to a thickness so as to preferably provide an excess of either the alkaline earth material.
    Type: Grant
    Filed: December 15, 2000
    Date of Patent: April 8, 2003
    Assignee: Delphi Technologies, Inc.
    Inventors: Eric P. Clyde, Paul Kikuchi, Richard F. Beckmeyer, William J. LaBarge
  • Patent number: 6533921
    Abstract: Apparatus for detecting the NOx concentration includes a first measurement chamber 20 communicating with the gas under measurement via a diffusion rate defining layer 4d and a second measurement chamber 26 communicating with the first measurement chamber 20 via diffusion limiting layers 6d, 22d. A first pump current IP1 is controlled so that an output of a Vs cell 6 will be equal to the reference voltage VCO for controlling the oxygen concentration in the first measurement chamber 20 to a pre-set low value. A constant voltage is applied across the second pump cell 8 for decomposing the NOx component in the second measurement chamber 26 for pumping out oxygen for detecting the NOx concentration from a second pump current IP2. The sensor temperature is detected from the internal resistance of the Vs cell for controlling the current supplied to the heaters 12, 14. If the temperature of the gas under measurement is changed rapidly, the sensor temperature is changed.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: March 18, 2003
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Shigeru Miyata, Noriaki Kondo, Hiroshi Inagaki
  • Patent number: 6527929
    Abstract: A gas sensor for measuring an amount of a measurement gas component, including a solid electrolyte having an internal space, a gas-introducing port for introducing measurement gas from an external space into the internal space, diffusion rate-determining means between the internal space and the gas-introducing port, and inner and outer pumping electrodes for pumping-processing oxygen contained in the measurement gas. The diffusion rate-determining means includes slits each having, when viewed in a plane substantially perpendicular to a longitudinal extension axis thereof, two dimensions, with at least one dimension of each slit being not more than 10 microns.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: March 4, 2003
    Assignee: NGK Insulators, Ltd.
    Inventors: Nobuhide Kato, Kunihiko Nakagaki
  • Patent number: 6517702
    Abstract: To determine the oxidizable portion of exhaust gases in the presence of the reducible portion with the legally required precision, a method and a sensor are disclosed for analyzing a flow of exhaust gas components. The sensor includes a limit current measurer, one limit current pump for reducible gases and, downstream from this pump in the direction of diffusion, another limit pump for oxidizable gases. The electrodes of the limit current pump for reducible gases are made of a material that does not catalyze the reaction between oxidizable and reducible gases.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: February 11, 2003
    Assignee: Robert Bosch GmbH
    Inventor: Roland Stahl
  • Publication number: 20020179458
    Abstract: A thick-film measurement sensor includes two measurement cells and is used to measure the NOx concentration in the exhaust gas from an internal combustion engine. The 1/&lgr; value of the exhaust gas is determined from an oxygen ion pump current flowing in the first measurement cell, for example, by a characteristic diagram, and, a measurement error, which can be used to correct the measured NOx concentration, is determined from this 1/&lgr; value, for example, by a characteristic curve that has previously been determined in a calibration measurement. The invention is based on the discovery that the measurement error is dependent on the air ratio in the exhaust gas. If this is expressed by the 1/&lgr; value, there is no need for a complex division calculation during the correction.
    Type: Application
    Filed: May 28, 2002
    Publication date: December 5, 2002
    Inventors: Bertrand Lemire, Tim Walde
  • Patent number: 6482310
    Abstract: A method for applying and controlling current applied to an air reference oxygen sensor included in a vehicle exhaust system is disclosed. In an exemplary embodiment of the invention, the method includes measuring an output voltage across the oxygen sensor when the exhaust system is initially activated and applying a current through the oxygen sensor when the output voltage reaches a value determinative of light off of a catalyst within the exhaust system. The magnitude of the applied current corresponds to a predefined purge value.
    Type: Grant
    Filed: December 18, 2000
    Date of Patent: November 19, 2002
    Assignee: Delphi Technologies, Inc.
    Inventors: Eric J. Detwiler, Richard C. Kuisell, Joseph V. Bonadies
  • Patent number: 6454931
    Abstract: A modified universal exhaust gas oxygen sensor, referred to herein as a CEGA sensor, is provided which can be used to measure the concentration of a variety of components of a gaseous fuel emission including CO, CO2, O2, H2, and H2O. The CEGA sensor-employs at least one additional electrode on a ceramic substrate which possess a different catalytic activity relative to the electrodes that normally found on a UEGO sensor. The ceramic substrate may be made of any suitable ceramic and is preferably made of zirconia. The difference in catalytic activity between the additional electrode(s) and the electrodes native to the UEGO sensor create an oxygen gradient which enables a measure of combustion completeness to be calculated. In combination with an air/fuel ratio measured by the sensor, the concentrations of different components in the emission can be calculated.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: September 24, 2002
    Assignee: ECM Engine Control and Monitoring
    Inventors: Ronald S. Patrick, Fabio DeAmicis
  • Patent number: 6451187
    Abstract: A detector for an air/fuel ratio sensor, which is comprised of a structure formed by stacking an oxygen reference electrode, a dense zirconia solid electrolyte, a negative electrode, a porous zirconia solid electrolyte, a positive electrode and a porous protection film on one another, is formed over a ceramic substrate having a heater built therein. Thus, a combined air/fuel ratio sensor can be obtained which is operated in a short time (about 5 seconds or less) after power-on so as to comply with emission control applied immediately after startup and provides low power consumption and a high degree of reliability.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: September 17, 2002
    Assignee: Hitachi, Ltd.
    Inventors: Seikou Suzuki, Masahiro Komachiya, Tsuyoshi Fujita
  • Patent number: 6447660
    Abstract: A circuit configuration for controlling a pump current includes a microcontroller, an analog circuit and a read-only memory. A pulse-width modulated signal, which is output by the micro-controller, is converted, by using the analog circuit, into the pump current for a pump cell of an exhaust probe which operates according to the principle of the galvanic oxygen concentration cell with a solid electrolyte. A pump current actual value is determined from a voltage drop across a measuring resistor, and a pump current setpoint value is determined from a voltage difference between an actual value of a Nernst voltage in the corresponding measuring cell and a predefined setpoint value. An exhaust probe configuration is also provided.
    Type: Grant
    Filed: February 12, 2001
    Date of Patent: September 10, 2002
    Assignee: Siemens Aktiengesellschaft
    Inventors: Markus Amtmann, Stephan Bolz, Jürgen Rössler
  • Patent number: 6444114
    Abstract: A modified universal exhaust gas oxygen sensor, referred to herein as a CEGA sensor, is provided which can be used to measure the concentration of a variety of components of a gaseous fuel emission including CO, CO2, O2, H2, and H2O. The CEGA sensor-employs at least one additional electrode on a ceramic substrate which possess a different catalytic activity relative to the electrodes that normally found on a UEGO sensor. The ceramic substrate may be made of any suitable ceramic and is preferably made of zirconia. The difference in catalytic activity between the additional electrode(s) and the electrodes native to the UEGO sensor create an oxygen gradient which enables a measure of combustion completeness to be calculated. In combination with an air/fuel ratio measured by the sensor, the concentrations of different components in the emission can be calculated.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: September 3, 2002
    Assignee: ECM Engine Control and Monitoring
    Inventors: Ronald S. Patrick, Fabio DeAmicis
  • Publication number: 20020100698
    Abstract: A method for controlling current applied to an air reference oxygen sensor included in a vehicle exhaust system. In an exemplary embodiment of the invention, the method includes measuring an output voltage across the oxygen sensor when the exhaust system is initially activated and applying a current through the oxygen sensor when the output voltage reaches a predetermined light off value. The magnitude of the applied current corresponds to a predefined purge value.
    Type: Application
    Filed: December 18, 2000
    Publication date: August 1, 2002
    Inventors: Eric J. Detwiler, Richard C. Kuisell, Joseph V. Bonadies
  • Publication number: 20020092779
    Abstract: The present invention is a gas component sensor comprising novel electrolyte compositions. The electrolyte compositions in bulk, sintered or thin film embodiments are capable of forming with different-metal sensing and reference electrodes a highly stable gas oxide sensors. The novel electrolyte composition changes electrochemical reactions at the sensing and reference electrodes and the overall reaction of the electrodes and electrolyte. The novel electrolyte compositions have: (1) excellent chemical stability and thermal compatibility as to the electrodes and a preferred ceramic substrate, (2) excellent chemical stability with the environment as to the reference and sensing electrodes, which need not be sealed against the atmosphere to be sensed, (3) effective adherence to the substrate and electrode metals. An improvement is disclosed where a correction of calculated gas concentration is made by comparison of measured voltages of two gas sensors.
    Type: Application
    Filed: July 26, 2001
    Publication date: July 18, 2002
    Inventors: Abdeltif Essalik, Howard Rosen
  • Publication number: 20020060150
    Abstract: The invention provides a deterioration detector for an exhaust gas sensor capable of detecting an amount of change with age of an internal resistance and conducting deterioration judgment taking into consideration fluctuation between products and temperature dependency of the internal resistance of the exhaust gas sensor.
    Type: Application
    Filed: May 17, 2001
    Publication date: May 23, 2002
    Applicant: MITSUBISHI DENKI KABUSHIKI KAISHA
    Inventors: Kohji Hashimoto, Masaharu Yuhara
  • Patent number: 6375828
    Abstract: A nitrogen oxide concentration detector has a first measurement chamber 2 into which is introduced a measurement gas via a first diffusion resistance 1; an oxygen concentration detection electrode 7a for measuring the oxygen concentration in the measurement gas in said first measurement chamber 1; a first oxygen ion pump cell 6 for pumping out oxygen in the measurement gas from said first measurement chamber 2 based on the potential of said oxygen concentration detection electrode 7a; a second measurement chamber 8 into which the gas is introduced from said first measurement chamber 2 via a second diffusion resistance 3; and a second oxygen ion pump cell 8 having a pair of electrodes 8a,8b across which a voltage is applied to decompose NOx in the second measurement chamber 4 to pump out dissociated oxygen to cause a circuit Ip2 corresponding to the NOx concentration to flow in the second oxygen ion pump cell 8. Variation of NOx concentration is a function of variation of Ip2.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: April 23, 2002
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Masashi Ando, Noboru Ishida, Satoshi Sugaya, Takafumi Oshima, Norihiko Nadanami, Takaki Otsuka, Yoshikuni Sato, Tatsuo Okumura, Yasuhisa Kuzuya
  • Publication number: 20020043461
    Abstract: To determine the oxidizable portion of exhaust gases in the presence of the reducible portion with the legally required precision, a method and a sensor are disclosed for analyzing a flow of exhaust gas components. The sensor includes a limit current measurer, one limit current pump for reducible gases and, downstream from this pump in the direction of diffusion, another limit pump for oxidizable gases. The electrodes of the limit current pump for reducible gases are made of a material that does not catalyze the reaction between oxidizable and reducible gases.
    Type: Application
    Filed: November 12, 1999
    Publication date: April 18, 2002
    Inventor: ROLAND STAHL
  • Patent number: 6372120
    Abstract: A NOx concentration of a gas is measured with a NOx measuring sensor which has two measuring cells. An oxygen concentration is respectively corrected by a oxygen-ion pumping current. A controller is used for correcting a transitional resistance through which the first oxygen-ion pumping current flows at the first measuring cell, the controller correcting at least partially a correction value for the transitional resistance by using the second oxygen-ion pumping current at the second measuring cell.
    Type: Grant
    Filed: October 30, 2000
    Date of Patent: April 16, 2002
    Assignee: Siemens Aktiengesellschaft
    Inventors: Jürgen Rössler, Hong Zhang
  • Patent number: 6365036
    Abstract: The sensor of the present invention comprises a solid electolyte with an electrode disposed on both sides thereof and an electrical lead connected to each electrode. The solid electrolyte is yttria doped zirconia. The first electrode, the sensing electrode, is exposed to the sensing gas such as an exhaust gas. The second electrode, the reference electrode, is exposed to a reference gas, wherein at least one of the sensing electrode and the reference electrode comprises a noble metal, platinum, metal oxide and alumina or in mixtures thereof.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: April 2, 2002
    Assignee: Delphi Technologies, Inc.
    Inventor: Kaius Kiiren Polikarpus
  • Publication number: 20020029980
    Abstract: The present invention discloses a trace oxygen measuring apparatus comprising a trace oxygen generating unit capable of generating oxygen in an arbitrary amount within a range of from 1 to 2 ppm, a concentration detecting cell configured so as to ensure followup of Nernst's formula, an opposite pump electrode provided in a special air duct, and a concentration detecting cell and a pump cell electrode independently provided; and a trace oxygen generating apparatus used such trace oxygen measuring apparatus.
    Type: Application
    Filed: July 31, 2001
    Publication date: March 14, 2002
    Applicant: NGK INSULATORS, LTD.
    Inventors: Akihiro Muroguchi, Yoshihiko Mizutani
  • Patent number: 6355151
    Abstract: A gas sensor is provided for measurement of oxygen and/or the air-to-fuel lambda ratio and hydrocarbons and/or carbon monoxide in gas mixtures. To reliably measure a plurality of gaseous components, the sensor is provided with a reference electrode representing a constant oxygen partial pressure, an oxygen ion-conducting solid electrolyte, and at least two measuring electrodes, the measuring electrodes and the reference electrode being mounted directly on the solid electrolyte and having electrical leads for connection and for take-away of electrical measurement signals. The solid electrolyte (1) is constructed with a measurement gas side exposed to the gas mixture and a reference gas side separated from the gas mixture.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: March 12, 2002
    Assignee: Heraeus Electro-Nite International N.V.
    Inventors: Susanne Brosda, Ulrich Guth, Silvia Lenaerts, Götz Reinhardt, Ulrich Schönauer
  • Publication number: 20020017467
    Abstract: A nitrogen oxide concentration detector has a first measurement chamber 2 into which is introduced a measurement gas via a first diffusion resistance 1; an oxygen concentration detection electrode 7a for measuring the oxygen concentration in the measurement gas in said first measurement chamber 1; a first oxygen ion pump cell 6 for pumping out oxygen in the measurement gas from said first measurement chamber 2 based on the potential of said oxygen concentration detection electrode 7a; a second measurement chamber 8 into which the gas is introduced from said first measurement chamber 2 via a second diffusion resistance 3; and a second oxygen ion pump cell 8 having a pair of electrodes 8a,8b across which a voltage is applied to decompose NOx in the second measurement chamber 4 to pump out dissociated oxygen to cause a current Ip2 corresponding to the NOx concentration to flow in the second oxygen ion pump cell 8. Variation of NOx concentration is a function of variation of Ip2.
    Type: Application
    Filed: March 23, 1998
    Publication date: February 14, 2002
    Inventors: MASASHI ANDO, NOBORU ISHIDA, SATOSHI SUGAYA, TAKAFUMI OSHIMA, NORIHIKO NADANAMI, TAKAKI OTSUKA, YOSHIKUNI SATO, TATSUO OKUMURA, YASUHISA KUZUYA
  • Patent number: 6342151
    Abstract: A method of measuring oxygen and/or the air-to-fuel lambda ratio and hydrocarbons and/or carbon monoxide in gas mixtures using a gas sensor is provided. To reliably measure a plurality of gaseous components, the sensor is provided with a reference electrode representing a constant oxygen partial pressure, an oxygen ion-conducting solid electrolyte, and at least two measuring electrodes, the measuring electrodes and the reference electrode being mounted directly on the solid electrolyte and having electrical leads for connection and for take-away of electrical measurement signals. The solid electrolyte is constructed with a measurement gas side exposed to the gas mixture and a reference gas side separated from the gas mixture.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: January 29, 2002
    Assignee: Heracus Electric-Nite International N.V.
    Inventors: Susanne Brosda, Ulrich Guth, Silvia Lenaerts, Götz Reinhardt, Ulrich Schönauer
  • Patent number: 6334946
    Abstract: A method of stabilizing pump current in a gas sensor through suppression of oscillations of the pump current which result from pulsations of measured gas is provided. The gas sensor includes an oxygen pump element, an oxygen concentration cell element and a measurement gap between the oxygen pump element and the oxygen concentration cell element, and is operative to control the pump current through the oxygen pump element so that an output voltage of the oxygen concentration cell element is constant in order that an oxygen concentration in the measurement gap is maintained constant and detect an oxygen concentration in the measured gas on the basis of the pump current. The method comprising adjusting an activity of electrodes of an oxygen pump element so as to change a responsiveness in control of the pump current and thereby reduce an amplitude of the oscillations of the pump current.
    Type: Grant
    Filed: May 28, 1999
    Date of Patent: January 1, 2002
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Tomohiro Mabuchi, Shigeki Mori, Satoshi Teramoto, Takeshi Kawai
  • Publication number: 20010040105
    Abstract: A modified universal exhaust gas oxygen sensor, referred to herein as a CEGA sensor, is provided which can be used to measure the concentration of a variety of components of a gaseous fuel emission including CO, CO2, O2, H2, and H2O. The CEGA sensor employs at least one additional electrode on a ceramic substrate which possess a different catalytic activity relative to the electrodes that normally found on a UEGO sensor. The ceramic substrate may be made of any suitable ceramic and is preferably made of zirconia. The difference in catalytic activity between the additional electrode(s) and the electrodes native to the UEGO sensor create an oxygen gradient which enables a measure of combustion completeness to be calculated. In combination with an air/fuel ratio measured by the sensor, the concentrations of different components in the emission can be calculated.
    Type: Application
    Filed: March 27, 2001
    Publication date: November 15, 2001
    Inventors: Ronald S. Patrick, Fabio DeAmicis
  • Publication number: 20010040104
    Abstract: A modified universal exhaust gas oxygen sensor, referred to herein as a CEGA sensor, is provided which can be used to measure the concentration of a variety of components of a gaseous fuel emission including CO, CO2, O2, H2, and H2O. The CEGA sensor-employs at least one additional electrode on a ceramic substrate which possess a different catalytic activity relative to the electrodes that normally found on a UEGO sensor. The ceramic substrate may be made of any suitable ceramic and is preferably made of zirconia. The difference in catalytic activity between the additional electrode(s) and the electrodes native to the UEGO sensor create an oxygen gradient which enables a measure of combustion completeness to be calculated. In combination with an air/fuel ratio measured by the sensor, the concentrations of different components in the emission can be calculated.
    Type: Application
    Filed: March 27, 2001
    Publication date: November 15, 2001
    Inventors: Ronald S. Patrick, Fabio DeAmicis
  • Patent number: 6309534
    Abstract: The subject method and apparatus pertains to the accurate determination of a composition of gases, over a very wide range of compositions. The subject invention can utilize an ionic electrolyte (1), which separates gases of different compositions, a source of potential difference (2) which is applied across the ionic electrolyte, means for reversing the current, and means (3) for measuring the respective currents. The ratio of currents is a function of the ratio of the gas compositions on opposite sides of the electrolyte. By varying the applied potential, the sensitivity of the apparatus can be increased.
    Type: Grant
    Filed: March 21, 2000
    Date of Patent: October 30, 2001
    Inventors: Derek John Fray, Ramachandran Vasant Kumar