Abstract: This disclosure provides methods and apparatuses for generating precoding vectors. One method includes: receiving a channel state information (CSI) report, wherein the CSI report indicates a quantity of space-frequency vector pairs to be reported for a quantity of R transport layers, wherein a size of an overhead for indicating the quantity of the space-frequency vector pairs is same when the quantity of R is greater than or equal to 2, wherein each of the space-frequency vector pairs comprises one spatial domain vector and one frequency domain vector, and wherein for each of the R transport layers, one or more frequency domain units associated with the transport layer correspond to one or more precoding vectors, and determining the quantity of space-frequency vector pairs according to the CSI report.

Abstract: Provided is a continuous process for converting waste plastic into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a naphtha/diesel fraction, a heavy fraction, and char. Pyrolysis oil and wax, comprising the naphtha/diesel fraction and heavy fraction, is sent to a refinery FCC unit. A liquid petroleum gas C3-C5 olefin/paraffin mixture is recovered from the FCC unit and passed to a refinery alkylation unit. A propane fraction is recovered from the alkylation unit and passed to a dehydrogenation unit to produce propylene. The propylene is passed to a propylene polymerization reactor.

Abstract: Provided is a continuous process for converting waste plastic into a feedstock for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and then passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is then separated into offgas, a pyrolysis oil comprising a naphtha/diesel/heavy fraction, and char. The pyrolysis oil is passed to a crude unit in a refinery from which a naphtha fraction (C5-C8), or a propane and butane (C3-C4) fraction, is recovered. The naphtha fraction, or propane and butane (C3-C4) fraction, is then passed to a steam cracker for ethylene production.

Abstract: Processes for partially deoxygenating a biomass-derived pyrolysis oil to produce a fuel for a burner are disclosed. A biomass-derived pyrolysis oil stream is combined with a low recycle stream that is a portion of a deoxygenated effluent to form a heated diluted py-oil feed stream, which is contacted with a first deoxygenating catalyst in the presence of hydrogen at first hydroprocessing conditions effective to form the effluent stream. The effluent may be separated and used to provide a product fuel stream for a burner.

Abstract: The present invention relates to a light fuel composition comprising fossil fuel, ethanol, and a bio-hydrocarbon composition as a DVPE adjustment material.

Abstract: The present disclosure relates to novel hydrocarbon fuel blends that provide increased power and a broader operating range when utilized as fuel for homogeneous charge compression ignition engines.

Abstract: A process (20) to produce olefinic products suitable for use as or conversion to oilfield hydrocarbons includes separating (42) an olefins-containing Fischer-Tropsch condensate (64) into a light fraction (68), an intermediate fraction (82) and a heavy fraction (94), oligomerizing (44) at least a portion of the light fraction (68) to produce a first olefinic product (72) which includes branched internal olefins, and carrying out either one or both of the steps of (i) dehydrogenating (50) at least a portion of the intermediate fraction (82) to produce an intermediate product (84) which includes internal olefins and alpha-olefins, and synthesizing (52) higher olefins from the intermediate product which includes internal olefins and alpha-olefins to produce a second olefinic product (86), and (ii) dimerizing (52) at least a portion of the intermediate fraction to produce a second olefinic product (86).

Abstract: This disclosure relates to the fast pyrolysis of organic matter. More specifically, it relates to the catalytic modification of vapors created during the fast pyrolysis of organic matter to create transportation fuel or a transportation fuel component. At least a first portion of pyrolysis vapors is catalytically stabilized or converted, then combined with a portion of raw, unconverted bio-derived pyrolysis vapors at a temperature and pressure sufficient for molecules of the combined vapors to react and produce hydrocarbons of increased molecular weight that are suitable for use as a hydrocarbon transportation fuel or component thereof.

Abstract: Methods and apparatus for refining feedstocks, such as crude or synthetic oil, and like feedstocks, are disclosed herein. In some embodiments, a reactor for refining a feedstock includes: a chamber having an inner volume to hold a liquid feedstock, a feedstock inlet port, a process gas inlet port, and an outlet port; a gas diffuser housed within the chamber and coupled to the process gas inlet port; and a radical generator coupled in fluid communication with the inner volume via the gas diffuser. In some embodiments, a method for refining feedstock includes: providing liquid feedstock to an inner volume of a reactor; flowing a radicalized process gas from a radical generator into the inner volume and into contact with the feedstock via a gas diffuser to fractionate the feedstock and produce one or more fractions of product in a vaporous mixture; and collecting a desired product from the vaporous mixture.

Abstract: A gas to liquids process with a reduced CO2 footprint to convert both natural gas and a renewable feedstock material into fuels or chemicals. In one embodiment of the invention, a natural gas feed is converted into synthesis gas containing hydrogen and carbon monoxide. A minor portion of the hydrogen is thereafter extracted from the synthesis gas. The synthesis gas is converted to hydrocarbons in a Fischer Tropsch reaction. The Fischer Tropsch hydrocarbon product and a renewable feedstock are hydroprocessed with the extracted hydrogen in order to produce fuels and/or chemicals. Waste products from the renewable feed are recycled to produce additional synthesis gas for the Fischer Tropsch reaction.

Abstract: A gas to liquids process with a reduced CO2 footprint to convert natural gas and a renewable feed stock material into fuels or chemicals. In one non-limiting embodiment of the invention, a natural gas feed is converted into synthesis gas containing hydrogen and carbon monoxide. A minor portion of the hydrogen is thereafter extracted from the synthesis gas. The synthesis gas is converted to hydrocarbons in a Fischer Tropsch reaction. The Fischer Tropsch hydrocarbon product and a renewable feedstock are hydro processed with the extracted hydrogen in order to produce fuels and/or chemicals. Waste products from the renewable feed are recycled to produce additional synthesis gas for the Fischer Tropsch reaction.

Abstract: A process for the production of hydrocarbon products from a feed comprising at least one non-pre-treated bio-oil, comprising a first step for hydroreforming in the presence of hydrogen and a hydroreforming catalyst, used alone or as a mixture, to obtain at least one liquid effluent comprising at least one aqueous phase and at least one organic phase, a second step in which at least a portion of the organic phase of the effluent obtained from the first hydroreforming step is recycled to the first hydroreforming step with a recycle ratio equal to the ratio of the mass flow rate of said organic phase to the mass flow rate of the non-pre-treated bio-oil in the range 0.05 to 2 and in which the hydrocarbon effluent obtained from the hydrotreatment and/or hydrocracking step is not recycled to said first hydroreforming step.

Abstract: Processes for producing a fuel from a renewable feedstock which may have more than 60 ppm nitrogen. The renewable feedstock is passed to a deoxygenation zone. A hydrogen stream, preferably formed from a recycled gas, is introduced into the deoxygenation zone at a relatively high rate. The hydrogen introduction may be between 3 to 5 times the rate of hydrogen consumption in the deoxygenation zone. The hydrogen introduction may also be between 6000 to 9000 SCF/BBL. A deoxygenated effluent, comprising less than 1 wppm nitrogen, may be isomerized and separated into one or more product hydrocarbon streams such as a diesel fuel or aviation fuel.

Abstract: Combustion charge compositions comprised of a gasoline-like fuel and air for use in spark ignited internal combustion engines and methods to reduce global warming are described.

Abstract: Disclosed are automated methods and systems for certifying the volatility of butane-enriched gasoline downstream of a butane blending operation. Such automated methods and systems provide significant advantages to comply with volatility requirements imposed by EPA or state regulations.

Abstract: A process for preparing a renewable biofuel consists of subjecting a bio-oil mixture to deoxygenation in a hydrotreater and then separating hydrocarbon fractions from the deoxygenated product to form the biofuel. The bio-oil mixture contains a bio-oil feedstream and a treated bio-oil feed. The treated bio-oil feed is a stream from which undesirable heavy materials and solid materials have been removed.

Abstract: Low sulphur marine fuel compositions are provided. Embodiments comprise greater than 50 to 90 wt % of a residual hydrocarbon component, with the remaining 10 and up to 50 wt % selected from a non-hydroprocessed hydrocarbon component, a hydroprocessed hydrocarbon component, and a combination thereof. Embodiments of the marine fuel composition can have a sulphur content of about 0.1 wt % or less.

Abstract: A fuel composition for use in gasoline engines which has excellent acceleration characteristics at high speeds and excellent fuel consumption. The fuel composition of this invention for use in gasoline engines satisfies the conditions: (1) the research octane number is not less than 99; (2) the density is in the range of from 0.750 to 0.770 g/cm3; (3) the distillation temperature at 50 vol % distilled is in the range of from 95 to 102° C., the distillation temperature at 90 vol % distilled is in the range of from 160 to 180 ° C., and the distillation end point is in the range of from 180 to 220 ° C.; and (4) the content of aromatic hydrocarbons with 9 or more carbon atoms is in the range of from 15 to 25% by volume, and the indane content is in the range of from 0.5 to 3.0% by volume.

Abstract: A fuel composition for use in gasoline engines which has excellent acceleration characteristics at high speeds and excellent fuel consumption. The fuel composition of this invention for use in gasoline engines satisfies the conditions: (1) the research octane number is not less than 90; (2) the density is in the range of from 0.740 to 0.760 g/cm3; (3) the distillation temperature at 50 vol % distilled is in the range of from 95 to 105 ° C., the distillation temperature at 90 vol % distilled is in the range of from 160 to 180° C., and the distillation end point is not more than 220° C.; and (4) the content of aromatic hydrocarbons with 9 or more carbon atoms is in the range of from 12 to 20% by volume, and the indane content is in the range of from 1.5 to 3.0% by volume.

Abstract: A process and apparatus provides for blending a heavy naphtha stream with a diesel stream to increase the yield of diesel. The diesel stream is recovered separately from a kerosene stream to leave the kerosene stream undiminished. The blended diesel provides a valuable composition.

Abstract: A method for starting up a bubble column slurry bed reactor of the present invention includes, when restarting operation of a bubble column slurry bed reactor for producing hydrocarbons by the Fischer-Tropsch synthesis reaction, feeding a hydroprocessed oil produced in the bubble column slurry bed reactor and hydroprocessed that contains 40% by mass or more of paraffin hydrocarbons having carbon number of 21 or more and that has a peroxide value of 1 ppm or less, to the bubble column slurry bed reactor.

Abstract: The subject of the present disclosure is an aviation gasoline composition that is lead-free and free of oxygenated compounds meeting the specifications of the ASTM standard comprising isopentane, isooctane, and (alkyl)aromatics. The aviation gasoline composition according to the disclosure may be obtained simply and economically from a mixture of hydrocarbon bases usually available in a refinery.

Abstract: The present invention provides a gas oil composition for use in a diesel engine containing an FT synthetic base oil and having a sulfur content of 5 ppm by mass or less, an oxygen content of 100 ppm by mass or less, a bulk modulus of 1250 MPa or greater and 1450 MPa or less, a saybolt color of +22 or greater, a lubricity of 400 ?m or less, an initial boiling point of 140° C. or higher and an end point of 380° C. or lower in distillation characteristics, wherein: (1) the cetane number in a fraction range of lower than 200° C. is 20 or greater and less than 40; (2) the cetane number in a fraction range of 200° C. or higher and lower than 280° C. is 30 or greater and less than 60; and (3) the cetane number in a fraction range of 280° C. or higher is 50 or greater.

Abstract: We provide an extracted conjunct polymer naphtha (45), comprising a hydrogenated conjunct polymer naphtha, from a used ionic liquid catalyst, having a final boiling point less than 246° C. (475° F.), a Bromine Number of 5 or less, and at least 30 wt % naphthenes. We also provide a blended alkylate gasoline (97) comprising the extracted conjunct polymer naphtha (45), and integrated alkylation processes to make the extracted conjunct polymer naphtha (45) and the blended alkylate gasoline (97). We also provide a method to analyze alkylate products, by determining an amount of methylcyclohexane in the alkylate products (80).

Abstract: A crude product composition is provided comprising hydrocarbons that have a boiling range distribution between about 30° C. and 538° C. (1,000° F.) at 0.101 MPa, the hydrocarbons comprising iso-paraffins and n-paraffins with a weight ratio of the iso-paraffins to n-paraffins of at most 1.4.

Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an Ft synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.

Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an Ft synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.

Abstract: The present invention provides a gas oil composition for use in a diesel engine with a geometric compression ratio of 16 or less, equipped with a supercharger and an EGR, containing an FT synthetic base oil and having a sulfur content of 5 ppm by mass or less, an oxygen content of 100 ppm by mass or less, a bulk modulus of 1250 MPa or greater and 1450 MPa or less, a saybolt color of +22 or greater, a lubricity of 400 ?m or less, an initial boiling point of 140° C. or higher and an end point of 380° C. or lower in distillation characteristics, and the following characteristics (1) to (3) in each fraction range wherein: (1) the cetane number in a fraction range of lower than 200° C. is 40 or greater and less than 60; (2) the cetane number in a fraction range of 200° C. or higher and lower than 280° C. is 60 or greater and less than 80; and (3) the cetane number in a fraction range of 280° C. or higher is 50 or greater.

Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an FT synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.

Abstract: The present invention is directed to a crude product composition comprising hydrocarbons having a boiling range distribution of from 30° C. to 538° C., the crude product composition having, per gram of crude product composition, from 0.01 grams to 0.2 grams of hydrocarbons having a boiling range distribution of at most 204° C., where olefins comprise at least 0.02 grams per gram of the hydrocarbons having a boiling range distribution of at most 204° C., and from 0.000001 grams to 0.05 grams of hydrocarbons having a boiling range distribution of greater than 538° C.

Abstract: The present invention is directed to a crude composition comprising hydrocarbons having a boiling range distribution of from 30° C. to 538° C., the crude composition having, per gram of crude composition, from 0.01 grams to 0.2 grams of hydrocarbon having a boiling range distribution of at most 204° C., where benzene comprises at most 0.005 grams per gram of the hydrocarbons having a boiling range distribution of at most 204° C., and from 0.000001 grams to 0.05 grams of hydrocarbons having a boiling range distribution of greater than 538° C.

Abstract: The present invention generally relates to a method for producing a naphtha product from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins, and hydrocracking the hydrotreating unit heavy fraction to produce a hydrocracking unit product that includes the naphtha product. The method also includes separating the naphtha fraction and optionally recycling the hydrocracking unit heavy fraction through the hydrocracking unit. The present invention also relates to a biorenewable naphtha product suitable for use as feed stock for steam crackers and catalytic reforming units, and for use as fuel, or fuel blend stock.

Abstract: This invention relates to fuel compositions for use in combustion engines, such as for motor vehicle and aircraft usage. The fuel composition contains at least 99.5% of aromatic hydrocarbons and paraffinic hydrocarbons. The composition also preferably contains no lead, no multi-ring compound (only single ring compounds are present), less than about 15 ppm sulfur, and/or less than about 5 ppm nitrogen species. The resulting fuel is a drop-in fuel that provides clean burning with little to no engine deposit, high lubricity, high stability, and low corrosion.

Abstract: The invention provides synthetically derived distillate kerosene produced by catalytic conversion of Fisher-Tropsch derived light olefins to distillates (COD) and hydrotreating thereof. The kerosene boils in the range of about 170 to 250° C. and includes less than 10% n-paraffins, more than 75% iso-paraffins and less than 1% aromatics.

Abstract: A crude product composition is provided. The crude product composition contains from 0.001 wt. % to 5 wt. % residue. The crude product composition contains hydrocarbons having a boiling point in the ranges of at most 204° C., from 204° C. to 300° C., from 300° C. to 400° C., and from 400° C. to 538° C. The hydrocarbons boiling in a range of at most 204° C. comprise paraffins, where the paraffins comprise iso-paraffins and n-paraffins, and the weight ratio of iso-paraffins to n-paraffins is at most 1.4.

Abstract: A liquid fuel composition comprising a fuel component derived from biomass conversion at increasing temperatures under pressure, the fuel component comprising one or more C4+ compounds.

Abstract: A process for producing a blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from glycerides and free fatty acids in feedstocks such as plant and animal oils. The cyclic rich component is generated from biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.

Abstract: A process for producing at least one blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from glycerides and free fatty acids in feedstocks such as plant and animal oils. The cyclic rich component is generated from biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.

Abstract: A process for producing at least one blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from glycerides and free fatty acids in feedstocks such as plant and animal oils. The cyclic rich component is generated from biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.

Abstract: An unleaded aviation fuel composition, containing at least one saturated branched aliphatic hydrocarbon having a carbon number in the C4 to C10 range, further contains sufficient m-xylene to yield a fuel having a MON of at least 98. A process is further provided for producing the unleaded aviation fuel composition by admixing a m-xylene enriched liquid with alkylate.

Abstract: A gasoline composition is provided containing: (a) a gasoline base fuel; and (b) a terpene composition in an amount in the range of from 0.1 to 40% vol. based on total gasoline composition, said terpene composition comprising at least 60% wt. pinenes and having an acidity of at most 0.05 mgKOH/g.

Abstract: The present invention is directed to a crude product composition. The crude product has, per gram of crude product: at least 0.001 grams of naphtha, the naphtha having an octane number of at least 70, and the naphtha having at most 0.15 grams of olefins per gram of naphtha; at least 0.001 grams of kerosene, the kerosene having at least 0.2 grams of aromatics per gram of kerosene and a freezing point at a temperature of at most ?30° C.; and at most 0.05 grams of residue.

Abstract: An effective method for producing high density fuel candidates from pinenes is provided. MMT-K10 is an efficient catalyst for the reaction, although significant amounts of p-cymene and camphene produced as byproducts limit the overall yield to about 80%. Nafion is also an excellent catalyst for pinene dimerization and was capable of producing dimers in up to 90% yield. Pinene dimers synthesized with these heterogenous catalysts have a density and net heat of combustion comparable to JP-10. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.

Abstract: A process for making products with low hydrogen halide, comprising: a) stripping or distilling an effluent from a reactor into a first fraction having an amount of hydrogen halide, and a second fraction having a reduced amount of hydrogen halide; wherein the reactor comprises: an ionic liquid catalyst having a metal halide, and a hydrogen halide or an organic halide; and b) recovering one or more product streams, from the second fraction, having less than 25 wppm hydrogen halide. In one embodiment the ionic liquid catalyst has metal halide; and the recovering recovers propane, n-butane, and alkylate gasoline having less than 25 wppm hydrogen halide. In another embodiment the recovering uses a distillation column having poor corrosion resistance to hydrogen halide; and the distillation column does not exhibit corrosion. There is also provided an alkylate gasoline having less than 5 wppm hydrogen halide, a high RON, and low RVP.

Abstract: Biofuel compositions obtained by the simultaneous hydroprocessing of at least two distinct hydroprocessing feedstocks, either or both of which are derived from biomass, are disclosed. The co-processing of these feedstocks can result in an upgraded product having suitable characteristics, in terms of composition (e.g., quantities of compounds such as aromatic hydrocarbons, present in relatively large amounts) and in terms of quality (e.g., quantities of compounds such as oxygenates, present in relatively small amounts) for use as a hydroprocessed biofuel such as hydroprocessed aviation biofuel.

Abstract: The present invention is directed to a crude product composition. The crude product composition has, per gram of crude product: at least 0.001 grams of hydrocarbons with a boiling range distribution of at most 204° C. at 0.101 MPa, at least 0.001 grams of hydrocarbons with a boiling range distribution between about 204° C. and about 300° C. at 0.101 MPa, at least 0.001 grams of hydrocarbons with a boiling range distribution between about 300° C. and about 400° C. at 0.101 MPa, and at least 0.001 grams of hydrocarbons with a boiling range distribution between about 400° C. and about 538° C. at 0.101 MPa. The hydrocarbons that have a boiling range distribution of at most 204° C. comprise iso-paraffins and n-paraffins with a weight ratio of the iso-paraffins to the n-paraffins of at most 1.4.

Abstract: A reconstituted non-asphaltenic oil Pa comprising at least 28% by weight of naphtha N, having a ratio R of 1.5 or more and a gasoline potential, POTg, in the range 47 to 70, in which: R=(0.9 N+0.5 VGO+)/(MD+0.1 VGO+), POTg=0.9N+0.5 VGO+, with in % by weight: N=naphtha: [30° C./170° C.]; MD=middle distillates: ]170° C./360° C.] and VGO+=fraction boiling above 360° C. R indicates the relative gasoline potential of a non residual oil over middle distillates during its subsequent refining.

Abstract: A treated oil, such as a treated heavy oil, which has a viscosity which is lower than the viscosity of the oil prior to the treatment thereof (i.e., the initial oil). The temperature at which 80 mass % of the treated oil has boiled is within 25° C. of temperature at which 80 mass % of the oil prior to the treatment thereof has boiled. Thus, the treated oil and the oil prior to the treatment thereof, have distillation curves or boiling point curves which are the same as or approximate to each other.

Abstract: An aviation gasoline (Avgas) formulation free from tetraethyl lead (TEL) for piston driven aircraft is described, the formulation comprising, in volume percent, between 0 and 65.2 base alkylate, between 0 and 50 super-alkylate, between 0 and 25 toluene, between 2 and 10 of a toluidine isomer blend, between 0 and 5 ethyl alcohol, between 0 and 25 C5 cut and between 0 and 10 triptane. The formulations are prepared by admixing the components, with the order of mixing being from the denser to the less dense, except in the case of the toluidine isomer blend, which in spite of being the denser product is the latest to be added to the other streams in order to by-pass homogenization problems.

Abstract: Biogas is converted to a liquid fuel by passing the biogas through a liquid reaction medium that contains a petroleum fraction in the presence of a transition metal catalyst, and doing so at an elevated but non-boiling temperature.