Abstract: The invention relates to a process for forming a low-sulfur motor gasoline and the product made therefrom. In one embodiment, process involves separating a catalytically cracked naphtha into at least a light fraction boiling below about 165° F. and a heavy fraction boiling above about 165° F. The light fraction is treated to remove sulfur by a non-hydrotreating method, and the heavy fraction is hydrotreated to remove sulfur to a level of less than about 100 ppm.

Abstract: The invention provides distillate fuel blend components with improved seal swell and lubricity properties obtained from Fischer Tropsch products. The blends contain a highly paraffinic distillate fuel component and distillate-boiling alkylcycloparaffins and/or distillate-boiling alkylaromatics. The invention further provides processes for obtaining such blends using the products of Fischer Tropsch processes. Finally, the invention provides methods for improving seal swell and lubricity properties for distillate fuels.

Abstract: Provided is a method for blending an unleaded summer gasoline containing ethanol. The method comprises providing a substantially oxygenate free unleaded gasoline blend stock having an RVP of no greater than 7.0, and preferably no greater than 6.0, and then adding sufficient ethanol to the gasoline blend stock such that the ethanol addition does not cause the T50 value to drop below the ASTM D 4814 minimum requirements of 170° F.

Abstract: Aromatic blendstocks suitable for use in making an unleaded gasoline fuel for combustion in a spark ignition engine contain substantial amounts of diisopropylbenzene which provides relatively more energy for doing work while producing fewer carbon dioxide emissions as compared to current gasoline blendstocks. Unleaded gasolines made utilizing the foregoing aromatic blendstocks contain at least about 0.3 weight percent diisopropylbenzene, preferably about 0.3 to about 10 weight percent diisopropylbenzene.

Abstract: A diesel fuel having at least 50% C10 to C20 paraffins, wherein the iso-paraffin to normal paraffin mole ratio is up to 21:1 and higher. This diesel fuel can be produced from a feed containing at least 90% C10+ normal paraffins. This diesel fuel is produced by contacting a feed in an isomerization reaction zone a feed with a catalyst comprising a SAPO-11 and platinum in the presence of hydrogen (hydrogen:feed ratio of from 1,000 to 10,000 SCFB) at a temperature of from 340° C. to 420° C., a pressure of from 100 psig to 600 psig, and a liquid hourly space velocity of from 0.1 hr−1 to 1.0 hr−1.

Abstract: Novel clean fuels comprising selected nonlinear long chain saturated primary monohydric/dihydric alcohols and mixtures thereof, novel diols; and processes for making clean synthetic jet fuels and/or clean synthetic diesel fuels as well as processes for making clean synthetic jet fuels and/or clean synthetic diesel fuels concurrently with making nonlinear alcohols for use by the detergent industry.

Abstract: Provided is a method for blending an unleaded summer gasoline containing ethanol. The method comprises providing a substantially oxygenate free unleaded gasoline blend stock having an RVP of no greater than 7.0, and preferably no greater than 6.0, and then adding sufficient ethanol to the gasoline blend stock such that the ethanol addition does not cause the value to drop below the ASTM D 4814 minimum requirements of 170° F.

Abstract: Provide is a novel gasoline composition which is substantially free of oxygenates and is in compliance with the California Predictive Model. The gasoline composition is suitable for use in the winter months, i.e., having a Reid vapor pressure in the range of greater than 7.0 to about 15.0 psi. The method for blending the gasoline comprises blending streams from a refinery in a controlled manner to maintain compliance with the California Predictive Model.

Abstract: This invention relates to a compound represented by the formula wherein in formula (I): R is a polyisobutene group; R1, R2 and R3 are each independently hydrogen, alkyl groups of 1 to 18 carbon atoms, cycloalkyl groups of 4 to 10 carbon atoms or aryl groups of 6 to 10 carbon atoms; and n is an integer of 0 to 4. The invention relates to an additive package for use in making fuels comprising the foregoing compound. The invention also relates to fuel compositions comprising the foregoing compound.

Abstract: Provided is a method for blending an unleaded summer gasoline containing ethanol. The method comprises providing a substantially oxygenate free unleaded gasoline blend stock having an RVP of no greater than 7.0, and preferably no greater than 6.0, and then adding sufficient ethanol to the gasoline blend stock such that the ethanol addition does not cause the T50 value to drop below the ASTM D 4814 minimum requirements of 170° F.

Abstract: Provided is a method for blending an unleaded summer gasoline containing ethanol. The method comprises providing a substantially oxygenate free unleaded gasoline blend stock having an RVP of no greater than 7.0, and preferably no greater than 6.0, and then adding sufficient ethanol to the gasoline blend stock such that the ethanol addition does not cause the T50 value to drop below the ASTM D 4814 minimum requirements of 170° F.

Abstract: Provided is a method for blending an unleaded summer gasoline containing ethanol. The method comprises providing a substantially oxygenate free unleaded gasoline blend stock having an RVP of no greater than 7.0, and preferably no greater than 6.0, and then adding sufficient ethanol to the gasoline blend stock such that the ethanol addition does not cause the T50 value to drop below the ASTM D 4814 minimum requirements of 170° F.

Abstract: A bitumen is rendered pipelineable by partially hydroconverting the bitumen and then adding sufficient diluent to the partially hydroconverted bitumen to provide a mixture having an API gravity at 15° C. of at least 19° and a viscosity at 40° C. in the range of about 35 to about 60 cP.

Abstract: Diesel fuels or blending stocks having excellent lubricity, oxidative stability and high cetane number are produced from non-shifting Fischer-Tropsch processes by separating the Fischer-Tropsch product into a lighter and heavier fractions, e.g., at about 700° F., subjecting the 700° F.+fraction to hydro-treating, and combining the 700° F.+portion of the hydrotreated product with the lighter fraction that has not been hydrotreated.

Abstract: A process for controlling the composition of a subgrade gasoline so that the subgrade will yield an alcohol-containing gasoline which precisely meets desired specifications when mixed with the desired amount of alcohol. The process involves blending a plurality of blendstocks to produce a subgrade, withdrawing a sample of the subgrade, mixing it with a known amount of alcohol, analyzing the properties of the resulting mixture, and using the analysis results to control and optimize the blending process.

Abstract: An unleaded high octane gasoline composition exhibiting reduced gum formation and improved air intake system and combustion chamber cleanliness is provided comprising at least (A) one reformate fraction produced by a continuous regeneration type reformer and/or (B) at least one reformate fraction produced by a fixed bed type reformer, said unleaded high octane gasoline composition satisfying the following conditions: Z=({fraction (1/100)})[&Sgr;(ax)+({fraction (1/9)})&Sgr;(by)]<0.

Abstract: The invention concerns a petroleum product and a process for the production of a petroleum product which can form part of a blend for an internal combustion engine fuel, the process comprisinga) hydrotreating a hydrocarbon feedstock at a partial pressure of hydrogen at the reactor outlet of about 0.5 MPa to about 6 MPa,b) separating a product (P) from step a) into a product (P1) with a final boiling point of about 300.degree. C. and a product (P2) with an initial boiling point greater than the final boiling point of product (P1),c) performing a liquid-liquid extraction with a solvent (S1), to produce an extract (E1) and a raffinate (R1) from product (P2),d) recovering solvent (S1) from raffinate (R1) to produce a product (Q1), depleted in solvent (S1), which has improved qualities and contains less than 500 ppm by weight of sulphur.

Abstract: By controlling one or more properties of a gasoline fuel suitable for combustion in automobiles, the emissions of NOx, CO and/or hydrocarbons can be reduced. The preferred fuel for reducing all three such emissions has a Reid Vapor Pressure no greater than 7.5 psi (0.51 atm), essentially zero olefins, and a 50% D-86 Distillation Point greater than about 180.degree. F. (82.degree. C.) but less than 205.degree. F. (96.1.degree. C.

Abstract: A low emission diesel fuel suitable for use in underground diesel-engined mining equipment comprises a straight run distillate fuel having an end point not greater than 300.degree. C. (about 660.degree. F.), a cetane number in the range of 55 to 60 a specific gravity not greater than 0.83 a sulfur content not greater than 0.1 wt percent and an aromatics content of 18 to 30 wt. percent. The T.sub.90 of the fuels is typically in the range of 255.degree. to 270.degree. C. (about 490.degree. F. to 525.degree. F.), with an initial boiling points typically in the range of 170.degree. to 190.degree. C. (about 340.degree. to 374.degree. F.). Ten percent points (T.sub.10) are typically in the range from about 200.degree. to 220.degree. C. (about 390.degree. to 430.degree. F.). The API gravity of the fuel is at least 38 and is typically in the range of 38 to 42 and the specific gravity is typically in the range of 0.82 to 0.83.

Abstract: Petroleum products are marked with a marker such as thymolphthalein or cresolphthalein. When the marked petroleum products are contacted with a developing reagent, a color develops.

Abstract: Reaction products of polyolefins having predominantly a terminal double bond and a number average molecular weight of from 250 to 10,000, which possess an aliphatic hydrocarbon skeleton which is straight-chain or carries C.sub.1 -C.sub.4 -alkyl side chains, with from 1 to 10 mol, per equivalent of double bond, of one or more vinyl esters I ##STR1## are obtainable by reacting the stated polyolefins with the vinyl esters I in the presence of a free radical initiator at from 80 to 200.degree. C., it being possible for these reaction products subsequently to have been hydrolyzed to the corresponding alcohols or converted into the corresponding amines by reductive amination with amines II ##STR2## .

Abstract: A low emission diesel fuel suitable for use in underground diesel-engined mining equipment comprises a straight run distillate fuel having an end point not greater than 300.degree. C. (about 660.degree. F.), a cetane number in the range of 55 to 60 a specific gravity not greater than 0.83 a sulfur content not greater than 0.1 wt percent and an aromatics content of 18 to 30 wt. percent. The T.sub.90 of the fuels is typically in the range of 255.degree. to 270.degree. C. (about 490.degree. F. to 525.degree. F.), with an initial boiling points typically in the range of 170.degree. to 190.degree. C. (about 340.degree. to 374.degree. F). Ten percent points (T.sub.10) are typically in the range from about 200.degree. to 220.degree. C. (about 390.degree. to 430.degree. F.). The API gravity of the fuel is at least 38 and is typically in the range of 38 to 42 and the specific gravity is typically in the range of 0.82 to 0.83.

Abstract: Discloses high purity solvent compositions constituted of n-paraffins and isoparaffins, with the isoparaffins containing predominantly methyl branches, and having an isoparaffin:n-paraffin ratio sufficient to provide superior low temperature properties and low viscosities. The solvent compositions are made by a process wherein a waxy, or long chain paraffinic feed, especially a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions at 700.degree. F.+ conversion levels ranging from about 20 to 90 wt.% to provide a C.sub.5 -1050.degree. F. crude fraction. The C.sub.5 -1050.degree. F. crude fraction is then topped via atmospheric distillation to produce a low boiling fraction with an upper end point boiling between about 650.degree. F. and 750.degree. F. The low boiling fraction is fractionated and a narrow boiling range solvent obtained therefrom; one which can be further divided into solvent grades of various boiling ranges.

Abstract: By controlling one or more properties of a gasoline fuel suitable for combustion in automobiles, the emissions of NOx, CO and/or hydrocarbons can be reduced. The preferred fuel for reducing all three such emissions has a Reid Vapor Pressure no greater than 7.5 psi (0.51 atm), essentially zero olefins, and a 50% D-86 Distillation Point greater than about 180.degree. F. (82.degree. C.) but less than 205.degree. F. (96.1.degree. C.

Abstract: Methods are provided for cleaning and inhibiting the formation of fouling deposits on jet engine components during the combustion of turbine combustion fuel oils. Methods are also provided for inhibiting the formation and emission of soot and smoke from jet engine exhaust during turbine combustion fuel oil combustion. The methods employ a derivative of polyalkenylthiophosphonic acid added to the turbine combustion fuel oil. The preferred derivative is pentaerythritol ester of polyisobutenylthio-phosphonic acid.

Abstract: Methods and compositions are provided for cleaning and inhibiting the formation of fouling deposits on jet engine components during the combustion of turbine combustion fuel oils. Methods and compositions are also provided for inhibiting the formation and emission of soot and smoke from jet engine exhaust during turbine combustion fuel oil combustion. The methods employ a derivative of (thio)phosphonic acid added to the turbine combustion fuel oil. The preferred derivative is pentaerythritol ester of polyisobutenylthiophosphonic acid.

Abstract: Markers for petroleum products which can be detected upon addition of a developing reagent which provokes the marker to fluorescence.

Abstract: Disclosed is a fuel for Otto cycle internal combustion engines. The fuel comprises a blend of a gasoline (A) and methanol (B) in a ratio of 10:90 to 30:70 by volume, based on the total volume amount of (A) and (B). Gasoline (A) is obtained by the steps of, (i) selectively hydrotreating a thermally cracked gasoline obtained by thermally cracking petroleum hydrocarbons, (ii) subsequently distilling the thermally cracked gasoline to divide said cracked gasoline into three fractions (1), (2) and (3) which fractions contain hydrocarbons having a carbon number of 5 and less, from 6 to 8, and 9 and more, respectively, and (iii) mixing the two fractions of (1) and (3) either in a ratio which is the same as that in which the two fractions were obtained by the distillation or in a ratio of 50:50 to 90:10 based on the total volume amount of (1) and (3).

Abstract: Disclosed is a fuel for Otto cycle internal combustion engines. The fuel comprises a blend of a gasoline (A) and methanol (B) in a ratio of 10:90 to 30:70 by volume, based on the total amount of (A) and (B). Gasoline (A) is obtained by the steps of, (i) hydrotreating heavy naphtha, (ii) catalytically reforming the hydrotreated heavy naphtha to obtain a catalytically reformed gasoline, (iii) distilling the reformed gasoline to divide the reformed gasoline into three fractions (1), (2) and (3) which fractions contain hydrocarbons having a carbon number of 5 and less, from 6 to 8, and 9 and more, respectively, and (iv) mixing the two fractions of (1) and (3) either in a ratio which is the same as that in which the two fractions were obtained by distillation or in a ratio of 30:70 to 90:10 based on the total volume amount of (1) and (3).

Abstract: A liquid hydrocarbon gasoline is provided by removing both the volatile and non-volatile components from C.sub.4 -C.sub.12 gasoline to yield either a C.sub.6 -C.sub.9 or a C.sub.6 -C.sub.10 intermediate gasoline. The intermediate gasoline of this invention can be combusted in a standard carbureted engine with less C.sub.4 and/or C.sub.5 priming than in required in standard C.sub.4 -C.sub.12 gasoline, and thus provides adequate cold engine starting ability with lower Reid Vapor Pressure. The C.sub.6 -C.sub.9 and C.sub.6 -C.sub.10 fuel can be combusted in a modified engine without any priming by gasifying the fuel. The fuel is gasified by heating it in a chamber in the absence of air; mixing the gas with air and then combusting the mixture. The gasified fuel is advantageous because it doesn't condense into droplets and thereby is combusted more completely in the gaseous state enhancing combustion efficiency.

Abstract: Internal combustion engine liquid fuels are produced by the mixing of a natural gasoline component and at least one octane-enhancing component. The mix is weathered during the blending operation to remove light-weight hydrocarbons comprising one- to four-carbon components. The light-weight hydrocarbons, which preferably constitute less than 3 percent of the blended fuel, can be recovered to generate power to run the process. The liquid fuel mixture is formulated to produce a desired octane rating, an environmentally acceptable vapor pressure, and a mix which, when burned in an internal combustion engine, produces a minimum amount of pollutants.

Abstract: The present invention is directed to a method for converting municipal waste containing plastics to a high quality synthetic crude oil which can be separated by fractionation into gasoline, diesel fuel and gas oils suitable as a feedstock to a catalytic cracker. The presence of cellulosic and proteinaceous waste materials in the municipal waste does not inhibit the process of the invention for converting the municipal waste into a synthetic crude oil. The process generally includes the steps of heating the municipal waste in a reaction gas, of a mixture of hydrogen sulfide and hydrogen or hydrogen at moderate temperatures and pressures.

Abstract: The present invention is directed to a process for the conversion of waste plastics and scrap rubber to a high quality synthetic crude oil which can be separated by fractionation into gasoline, diesel fuel and gas oils suitable as a feedstock to a catalytic cracker. The process generally includes the steps of heating the plastic scrap and scrap automotive tires in a hydrogen atmosphere at moderate temperatures and pressures. It has also been determined that the polymeric waste material must be present in combination with the scrap automotive tires to attain conversion of the scrap automotive tires to liquid hydrocarbon.

Abstract: Blended gasolines are produced by the mixing of a butane-pentane rich component, a natural gasoline component, and at least one octane-enhancing component. The mix is weathered during the blending operation to remove light-weight hydrocarbons comprising two, three and four-carbon components. The light-weight hydrocarbons, which preferably constitute less than 3 percent of the blended gasoline, can be recovered to generate power to run the process. The liquid gasoline mixture is formulated to produce a desired octane rating, an environmentally acceptable vapor pressure, and a mix which, when burned in an internal combustion engine, produces a minimum amount of pollutants.

Abstract: A composition useful as a gasoline additive, preferably to increase engine performance and/or mileage per unit volume of fuel, is described. The composition comprises about 45% to about 55% by weight of toluene and about 45% to about 55% by weight of C.sub.8 alkyl aromatic component selected from the group consisting of ethylbenzene, paraxylene, metaxylene, orthoxylene and mixtures thereof.

Abstract: A liquid hydrocarbon gasoline is provided by removing both the volatile and non-volatile components from C.sub.4 -C.sub.12 gasoline to yield either a C.sub.6 -C.sub.9 or C.sub.6 -C.sub.10 intermediate gasoline. The intermediate gasoline of this invention can be combusted in a standard carbureted engine with less C.sub.4 and/or C.sub.5 priming than is required in standard C.sub.4 -C.sub.12 gasoline, and thus provides adequate cold engine starting ability with lower Reid Vapor Pressure. The C.sub.6 -C.sub.9 and C.sub.6 -C.sub.10 fuel can be combusted in a modified engine without any priming by gasifying the fuel. The fuel is gasified by heating it in a chamber in the absence of air; mixing the gas with air and then combusting the mixture. The gasified fuel is advantageous because it doesn't condense into droplets and thereby is combusted more completely in the gaseous state enhancing combustion efficiency.

Abstract: Blended gasolines are produced by the mixing of a butane-pentane rich component, a natural gasoline component, and a toluene component. The mix is weathered during the blending operation to remove light-weight hydrocarbons comprising two, three and four-carbon components. The light-weight hydrocarbons, which preferably constitute less than 3 percent of the blended gasoline, can be recovered to generate power to run the process. The liquid gasoline mixture is formulated to produce a desired octane rating, an environmentally acceptable vapor pressure, and a mix which, when burned in an internal combustion engine, produces a minimum amount of pollutants.

Abstract: A process is provided wherein premium fuels are manufactured from a high sulfur, low pour point feed and a low sulfur, high pour point feed. The feeds are treated individually (blocked operation) in a catalytic reactor that desulfurizes or dewaxes the feed, depending on temperature, and the effluents are combined. Since cut point limitations due to sulfur or pour point are removed by the process, yield of a fuel (e.g. jet fuel) is materially enhanced.

Abstract: Lead-free, high-octane gasoline is disclosed which is so composed as to have specified distillation and composition characteristics. The gasoline is excellent with respect to stability to ambient conditions, acceleration over a wide range of running speeds, and startability and warmup at low temperature.

Abstract: A process and apparatus for converting light hydrocarbons, such as waste organic solvents, to a useful fuel having a high flash point. A mixture of light hydrocarbon and heavy oil, wherein the ratio of light hydrocarbon to heavy oil preferably lies in the range from about 10:1 to about 1:4, is forced at a pressure of preferably at least about 500 psi through a porous substrate having a catalytically effective amount of an active oxide of hexavalent group 6b metal, such as chromium, thereon. The porous substrate may comprise a sintered powder stainless steel material having an average pore size in the range from about 20 to about 2000 microns. The catalyst is prepared by wetting the porous substrate with a solution of a salt of the group 6b metal and heating the wetted substrate until a catalytically active oxide of hexavalent group 6b metal is formed thereon.

Abstract: The invention concerns a process for the preparation of aliphatic ethers by reacting the corresponding alcohol and/or olefin over a superacid catalyst.

Abstract: Metal salts and amides of alkyl-lactam acetic acids are prepared by reacting gamma-hydrocarbyl butyrolactone acetic acid compounds derived from alkenylsuccinic anhydrides with metal compounds and amines or amines alone. High molecular weight lactam acid salts and amides and metal complexes and metal carbamates thereof are useful as detergents or dispersants in organic industrial fluids. Another aspect of this invention is a method of preparing lactone acetic acids in yields up to 90% conversion from alkenylsuccinic anhydrides.

Abstract: A method for supressing carburetor deposit formation of motor fuels containing untreated cat cracked gasoline by blending adsorbent-treated cat cracked gasoline into the motor fuel. Up to about 50 percent by weight of the total composition is adsorbent-treated cat cracked gasoline, but preferably from about 5 to about 25 percent by weight of the total composition is adsorbent-treated cat cracked gasoline. In a preferred embodiment a standard reference fuel capable of providing a predetermined level of carburetor deposit formation is provided by the addition of either adsorbent-treated cat cracked gasoline, untreated cat cracked gasoline, or aromatic amines to a base fuel.

Abstract: This process applies to effluents from syntheses of the Fischer-Tropsch type; it comprises several treatments applied to the three cuts obtained from these effluents, i.e. a "light fraction", a "light oil" and a "decanted oil". These treatments comprise such steps as distillation, polymerization, alkylation, hydrotreatment, cracking-decarboxylation, isomerization and hydro reforming. The products are mainly gasoline, kerosene and gasoil.

Abstract: Novel disazo colorants or dyes for marking organic liquids, the colorants having the general formula ##STR1## where R.sub.1 is H, CF.sub.3, or alkyl having from 1 to 4 carbon atoms,R.sub.2 is H, or alkyl having from 1 to 4 carbon atoms,R.sub.3 and R.sub.4 are each H, OCH.sub.3, OC.sub.2 H.sub.5 or CH.sub.3, andR.sub.5, r.sub.6 and R.sub.7 are each H, or alkyl having from 1 to 12 carbon atoms, at least one of said R.sub.5, R.sub.6 and R.sub.7 being alkyl.The novel compound of the general formula ##STR2## where R.sub.5, R.sub.6 and R.sub.7 are as described above is provided and is useful as an intermediate in the preparation of said disazo colorants. Methods for the preparation of the colorants are disclosed together with qualitative and quantitative procedures for detecting these colorants in the marked liquids.

Abstract: Novel compositions are prepared from the thermal decomposition product of azidoformate esters reacting with aliphatic hydrocarbon olefins to form aziridine carbamates, which are then reacted with a polyamine free of primary amino groups and having at least one secondary amino group. These compositions find use as detergents and dispersants in lubricating oils and fuels, and also as emulsifiers.

Abstract: At least two gasoline streams, having dissimilar octane ratings, are admixed with a butane-rich stream, the latter for vapor pressure control. A control system is employed to regulate the quantity of a lead-containing compound and/or the relative quantities of the blend components to achieve both the target octane of the final motor fuel blend as well as the desired vapor pressure, or volatility.

Abstract: A petroleum-derived solvent having a distillation range of from about 316.degree.F. to 360.degree.F. is added to hydrocarbon fuels, such as gasoline, diesel oil or heating oils, in a ratio of from about 1 part additive to 6-15 parts fuel. The additive, when added to No. 2 diesel fuel and the fuel burned in conventional, non-pressurized orchard heaters, gives reduced particulate emissions and a higher BTU per pound value of fuel burned.

Abstract: A method is provided for manufacturing a chemical mixture, such as a gasoline blend, which conforms to a set of regulations set by an outside public agency. The invention is directed to a set of regulations which require the manufacturer to prepare a master specification which sets control limits on the chemical characteristics of the chemical mixture and require that the master specification conform to a set of controlling criteria which are dependent upon such control limits--such as predicted exhaust pollution emissions from the burning of the subject gasoline blend.