Abstract: A multi-stage process for the production of an ISO 8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a Reaction System composed of one or more reactor vessels selected from a group reactor wherein said one or more reactor vessels contains one or more reaction sections configured to promote the transformation of the Feedstock Heavy Marine Fuel Oil to the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed that can utilize a modular reactor vessel contained within a frame work based on ISO 40 foot or ISO 20 foot container dimensions.

Abstract: Process for hydrotreating a heavy hydrocarbon fraction using a system of switchable fixed bed guard zones each containing at least one catalyst bed including at least one step during which the flow of feed supplied to the first guard zone brought into contact with the feed is partly displaced to the next guard zone downstream, preferably progressively.

Abstract: An oxidative treatment process, e.g., oxidative desulfurization or denitrification, is provided in which the oxidant is produced in-situ using an aromatic-rich portion of the original liquid hydrocarbon feedstock. The process reduces or replaces the need for the separate introduction of liquid oxidants such as hydrogen peroxide, organic peroxide and organic hydroperoxide in an oxidative treatment process.

Abstract: Methods and apparatuses for desulfurizing hydrocarbon streams are provided herein. In one embodiment, a method for desulfurizing a hydrocarbon stream includes separating the hydrocarbon stream into a heavier fraction and a lighter fraction. The heavier fraction includes a relatively higher amount of lower octane mono-unsaturates and the lighter fraction includes a relatively higher amount of higher octane mono-unsaturates. The method further includes hydrodesulfurizing the heavier fraction in a first hydrodesulfurization zone and hydrodesulfurizing the lighter fraction in a second hydrodesulfurization zone. Further, the method forms a hydrodesulfurized stream from the heavier fraction and the lighter fraction.

Abstract: A system for producing an auxiliary fuel stream containing a low concentration of sulfur compounds from a primary fuel stream includes a first separation stage to separate a portion of a primary fuel stream into a first vapor permeate stream and a first retentate stream, a first separation stage partial condenser connected to the first vapor permeate stream condensing a portion of the first vapor permeate stream into a first liquid stage stream and a first vapor stage stream, and a second separation stage partial condenser condensing a portion of the first vapor stage stream into a second liquid stage. The stream may then be processed through a sorbent bed to effectively remove the sulfur compounds.

Abstract: A system and process for desulfurizing a hydrocarbon feed stream containing organosulfur compounds is provided. In general, the system includes a conventional hydrotreating unit through the high pressure cold or hot separator. Aqueous oxidant and an oxidative catalyst are mixed with the hydrotreated hydrocarbon effluent from the high pressure cold or hot separator, and oxidative desulfurization reactions occur in the low pressure separation zone, thereby minimizing or eliminating the requirement of additional oxidative desulfurization reactors.

Abstract: Disclosed is a process for removing organic sulfur from more than one reactive fuel gas stream. A reactor vessel that is provided with at least one bed of hydrodesulfurization catalyst is used to hydrodesulfurize multiple reactive fuel gas streams with a less reactive fuel gas stream being introduced into the reactor vessel at a point above the introduction point of a more reactive fuel gas stream. An hydrotreated fuel gas is yielded from the reactor vessel having a hydrogen sulfide concentration and a low organic sulfur content.

Abstract: A process for the desulfurization of a fluid catalytically cracked naphtha wherein the valuable olefins are retained and recombinant mercaptans are prevented from forming, resulting in a low sulfur naphtha. Embodiments disclosed herein may allow for more flexibility in varying the end point of the naphtha used in gasoline blending.

Abstract: Disclosed is a method for steam-cracking naphtha, according to which a charge of hydrocarbons containing a portion of paraffinic naphtha, which is modified by adding a combination of a first component containing a portion of gasoline and a second component containing a portion of at least one hydrocarbonated refinery gas, and a paraffin-rich change containing at least one paraffin selected among propane, butane, or a mixture thereof are fed through a steam cracker in the presence of vapor. Also disclosed is a hydrocarbon composition suitable for steam cracking, containing a portion of a paraffinic naphtha, which is modified by adding a combination of a first component containing a portion of gasoline and a second component containing a portion of at least one hydrocarbonated refinery gas and a paraffin-rich charge containing at least one paraffin selected among propane, butane, or a mixture thereof.

Abstract: A process for the production of low sulfur diesel and a residual hydro-carbon stream containing a reduced concentration of sulfur. A residual hydrocarbon stream is desulfurized and the resulting diesel boiling range hydrocarbons are desulfurized in a second desulfurization zone to produce low sulfur diesel. Hydrogen sulfide is removed from the process by the purification of the recycle gas.

Abstract: A system for producing an auxiliary fuel stream containing a low concentration of sulfur compounds from a primary fuel stream includes a first separation stage to separate a portion of a primary fuel stream into a first vapor permeate stream and a first retentate stream, a first separation stage partial condenser connected to the first vapor permeate stream condensing a portion of the first vapor permeate stream into a first liquid stage stream and a first vapor stage stream, and a second separation stage partial condenser condensing a portion of the first vapor stage stream into a second liquid stage. The first vapor permeate stream is preferable sent through a vapor phase reactive desulfurization catalyst reactor to condition any sulfur compounds present into species that can be easily separated from the fuel stream.

Abstract: An integrated process for the hydroprocessing of multiple feedstreams including vacuum gas oil and light cycle oil. The light cycle oil is reacted with hydrogen in a hydrocracking zone and the hydrocarbon feedstream comprising vacuum gas oil is reacted with hydrogen in a hydrodesulfurization reaction zone. The hydrotreated vacuum gas oil is good FCC feedstock. Naphtha and ultra low sulfur diesel are recovered in a common fractionation column.

Abstract: A continuous process for upgrading sour crude oil by treating the sour crude oil in a two step process that includes a hydro-demetallization section and a hydro-desulfurization section, both of which are constructed in a permutable fashion so as to optimize the operating conditions and catalyst lifespan to produce a high value crude oil having low sulfur and low organometallic impurities.

Abstract: A system for producing an auxiliary fuel stream containing a low concentration of sulfur compounds from a primary fuel stream includes a first separation stage to separate a portion of a primary fuel stream into a first vapor permeate stream and a first retentate stream, a first separation stage partial condenser connected to the first vapor permeate stream condensing a portion of the first vapor permeate stream into a first liquid stage stream and a first vapor stage stream, and a second separation stage partial condenser condensing a portion of the first vapor stage stream into a second liquid stage. The first vapor permeate stream is preferable sent through a vapor phase reactive desulfurization catalyst reactor to condition any sulfur compounds present into species that can be easily separated from the fuel stream.

Abstract: A process for the selective hydrodesulfurization of olefinic naphtha streams containing a substantial amount of organically-bound sulfur and olefins. The olefinic naphtha stream is selectively desulfurized in a first hydrodesulfurization stage. The effluent stream from this first stage is sent to a separation zone wherein a lower boiling naphtha stream and a higher boiling naphtha stream are produced. The lower boiling naphtha stream is sent through at least two more separation zones, each at a lower temperature than the preceding separation stage. The higher boiling naphtha stream, which contains most of the sulfur moieties, is passed to a second hydrodesulfurization stage wherein at least a fraction of the sulfur moieties are removed.

Abstract: A process for concurrently fractionating and treating a full range naphtha stream. The full boiling range naphtha stream is first subjected to simultaneous thioetherification and splitting into a light boiling range naphtha, an intermediate boiling range naphtha and a heavy boiling range naphtha. The intermediate boiling range naphtha containing thiophene and thiophene boiling range mercaptans is passed on to a polishing hydrodesulfurization reactor where a low sulfur, low olefin gas oil is concurrently fed to the polishing reactor to insure that a liquid phase is present.

Abstract: Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.

Abstract: A process for concurrently fractionating and hydrotreating a full range naphtha stream.

Abstract: The instant invention relates to a process to produce high octane, low sulfur naphtha products through the removal of basic nitrogen-containing compounds with subsequent skeletal isomerization of feed olefins and hydrotreating.

Abstract: The process for desulfurizing a gas oil fraction according to the invention comprises a low-boiling gas oil fraction hydrodesulfurization step (I) wherein a low-boiling gas oil fraction is desulsurized under the condition of a H2/Oil ratio of 70 to 200 Nm3/kl to obtain a treated oil, a high-boiling gas oil fraction hydrodesulfurization step (II) wherein a high-boiling gas oil fraction is desulsurized under the condition of a H2Oil ratio of 200 to 800 Nm3/kl to obtain a treated oil, and a step (III) wherein the treated oil obtained in the step (I) is mixed with the treated oil obtained in the step (II), and in this process, at least a part of a gas containing unreacted hydrogen in the step (II) is used for the hydrodesulfurization of the step (I).

Abstract: A method for processing a gasoline range hydrocarbon stream wherein a single reactor/distillation tower stream is fractionated into a light fraction and a heavy fraction, the light fraction is hydrodesulfurized, the heavy fraction is optionally hydrocracked and then hydrodesulfurized, and the light and heavy fractions are separately recovered.

Abstract: A process wherein all of the unsaturates within a cracked naphtha stream are substantially hydrogenated to alkanes and the olefin depleted stream is then subjected to hydrodesulfurization to achieve the desired sulfur levels without the formation of recombinant mercaptans.

Abstract: The invention relates to a process for the production of gasoline with a low sulfur content comprising at least three stages: a first stage in which the sulfur-containing compounds present in the gasoline are at least partially transformed into H2S and into saturated sulfur-containing compounds; a second stage whose purpose is to eliminate the H2S from the gasoline produced in the first stage; and a third stage in which the saturated sulfur-containing compounds remaining in the gasoline are transformed into H2S. The process according to the invention optionally also comprises a pretreatment stage whose purpose is to hydrogenate the diolefins of the feedstock before the first stage.

Abstract: A process for the treatment of light naphtha hydrocarbon streams is disclosed wherein the mercaptans contained therein are reacted with diolefins simultaneous with fractionation into a light stream and a heavy stream. The heavy stream is then simultaneously treated at high temperatures and low pressures and fractionated. The naphtha is then stripped of the hydrogen sulfide in a final stripper.

Abstract: A process for concurrently fractionating and treating a full range naphtha stream. The full boiling range naphtha stream is first subjected to simultaneous thioetherification and splitting into a light boiling range naphtha, an intermediate boiling range naphtha and a heavy boiling range naphtha. The intermediate boiling range naphtha containing thiophene and thiophene boiling range mercaptans is passed on to a polishing hydrodesulfurization reactor where a low sulfur, low olefin gas oil is concurrently fed to the polishing reactor to insure that a liquid phase is present.

Abstract: Processes for generating and removing oxidized sulfur species, and in particular sulfoxides, from crude oil and various fractions derived therefrom. Initially, the sulfur species present in the crude oil or fractions derived from the crude oil, is oxidized such that substantially all of the sulfur species are converted to sulfoxides and/or a combination of sulfoxides and sulfones. Thereafter, the fossil fuel containing the oxidized sulfur species are subjected to conventional hydrodesulfurization processes where substantially all of the sulfones are converted to hydrogen sulfide gas.

Abstract: The invention relates to a method for treating naphtha, such as catalytically cracked naphtha, in order to remove acidic impurities, such as mercaptans. In particular, the invention relates to a method for mercaptans having a molecular weight of about C4 (C4H10S=90 g/mole) and higher, such as recombinant mercaptans.

Abstract: Economical processes are disclosed for the production of fuels of reduced sulfur content from a feedstock, typically derived from natural petroleum, wherein the feedstock is comprised of limited amounts of sulfur-containing organic compounds as unwanted impurities. The processes involve an integrated, multiple stage system for converting these impurities to higher boiling products by alkylation and removing the higher boiling products by fractional distillation. Advantageously, the processes include selective hydrogenation of the high-boiling fraction whereby the incorporation of hydrogen into hydrocarbon compounds, sulfur-containing organic compounds, and/or nitrogen-containing organic compounds assists by hydrogenation removal of sulfur and/or nitrogen. Products can be used directly as transportation fuels and/or blending components to provide, for example, more suitable components for blending into fuels which are more friendly to the environment.

Abstract: Economical processes are disclosed for the production of fuels of reduced sulfur content from a feedstock, typically derived from natural petroleum, wherein the feedstock is comprised of limited amounts of sulfur-containing organic compounds as unwanted impurities. The processes involve integrated, multistage processes which include pretreatment of a light naphtha with a solid adsorbent to remove basic nitrogen containing compounds, chemical conversion of one or more of the sulfur-containing impurities to higher boiling products by alkylation, and removing the higher boiling products by fractional distillation. Advantageously, the processes include selective hydrogenation of the high-boiling fraction whereby the incorporation of hydrogen into hydrocarbon compounds, sulfur-containing organic compounds, and/or nitrogen-containing organic compounds assists by hydrogenation removal of sulfur and/or nitrogen.

Abstract: The desulfurization of petroleum distillates can be carried out by cyclic low-temperature adsorption of oxidized sulfur compounds with activated carbon followed by regeneration of the activated carbon using an organic solvent. The activated carbon used in the process is commercially available and its surface area that ranges from approximately 500 to 2000 m2/g having a substantial portion of its pores in the range between 10 to 100 Angstroms.

Abstract: A method for processing a gasoline range hydrocarbon stream wherein a single reactor/distillation tower stream is fractionated into a light fraction and a heavy fraction, the light fraction is hydrodesulfurized, the heavy fraction is optionally hydrocracked and then hydrodesulfurized, and the light and heavy fractions are separately recovered.

Abstract: A process for desulfurizing a gasoline stream while continuing to maintain the octane rating of the blend stock. A gasoline stream containing sulfur compounds and olefins is introduced into a fractionation zone to produce a low boiling fraction containing mercaptan sulfur compounds and olefins, a mid boiling fraction containing thiophene and olefins, and a high boiling fraction containing sulfur compounds. The low boiling fraction containing mercaptan sulfur compounds is contacted with an aqueous alkaline solution to selectively remove mercaptan sulfur compounds. The mid boiling fraction containing thiophene is extracted to produce a raffinate stream containing olefins and having a reduced sulfur content relative to the mid boiling fraction and a hydrocarbonaceous stream rich in thiophene.

Abstract: The invention relates to a process for forming a low-sulfur motor gasoline and the product made therefrom. In one embodiment, process involves separating a catalytically cracked naphtha into at least a light fraction boiling below about 165° F. and a heavy fraction boiling above about 165° F. The light fraction is treated to remove sulfur by a non-hydrotreating method, and the heavy fraction is hydrotreated to remove sulfur to a level of less than about 100 ppm.

Abstract: A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification catalyst in a reaction zone under conditions which are effective to produce an intermediate product which has a reduced amount of olefinic unsaturation relative to that of the feedstock as measured by bromine number. The intermediate product is then separated into fractions of different volatility, and the lowest boiling fraction is contacted with a hydrodesulfurization catalyst in the presence of hydrogen under conditions which are effective to convert at least a portion of its sulfur-containing impurities to hydrogen sulfide.

Abstract: The invention relates to a method and dual reactor system for hydrotreating a wide cut cat naphtha stream comprising heavy cat naphtha (HCN) and intermediate cat naphtha (ICN). Accordingly, a HCN fraction is hydrotreated under non-selective hydrotreating conditions and an ICN fraction is hydrotreated under selective hydrotreating conditions. The hydrotreated HCN and ICN effluents may be conducted to heat exchangers to pre-heat the ICN feed, obviating the need for a furnace.

Abstract: The desulfurization of petroleum distillates can be carried out by cyclic low-temperature adsorption of oxidized sulfur compounds with activated carbon followed by regeneration of the activated carbon using an organic solvent. The activated carbon used in the process is commercially available and its surface area that ranges from approximately 500 to 2000 m2/g having a substantial portion of its pores in the range between 10 to 100 Angstroms.

Abstract: A process for the removal of sulfur compounds from a hydrocarbon stream is disclosed. In a preferred embodiment, the process includes extractive distillation of a gasoline stream from a fluid catalytic cracker to reject olefins to a raffinate stream and simultaneously extract sulfur compounds to an extract stream.

Abstract: Economical processes are disclosed for the production of fuels of reduced sulfur content from a feedstock, typically derived from natural petroleum, wherein the feedstock is comprised of limited amounts of sulfur-containing organic compounds as unwanted impurities. The processes involve integrated, multistage processes which include pretreatment of a light naphtha with a solid adsorbent to remove basic nitrogen containing compounds, chemical conversion of one or more of the sulfur-containing impurities to higher boiling products by alkylation, and removing the higher boiling products by fractional distillation. Advantageously, the processes include selective hydrogenation of the high-boiling fraction whereby the incorporation of hydrogen into hydrocarbon compounds, sulfur-containing organic compounds, and/or nitrogen-containing organic compounds assists by hydrogenation removal of sulfur and/or nitrogen.

Abstract: A process for concurrently fractionating and hydrotreating of a full range naphtha stream. The full boiling range naphtha stream is first subjected to simultaneous thioetherification and fractionation to remove the mercaptans the light fraction and then to simultaneous hydrodesulfurization and splitting of the remainder into an intermediate boiling range naphtha and a heavy boiling range naphtha. The three boiling range naphthas are treated separately according to the amount of sulfur in each cut and the end use of each fraction.

Abstract: A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification catalyst in a reaction zone under conditions which are effective to produce an intermediate product which has a reduced amount of olefinic unsaturation relative to that of the feedstock as measured by bromine number. The intermediate product is then separated into fractions of different volatility, and the lowest boiling fraction is contacted with a hydrodesulfurization catalyst in the presence of hydrogen under conditions which are effective to convert at least a portion of its sulfur-containing impurities to hydrogen sulfide.

Abstract: A process for concurrently fractionating and treating of a full range naphtha stream. The full boiling range naphtha stream is first subjected to simultaneous thioetherification or selective hydrogenation and splitting into a light boiling range naphtha, an intermediate boiling range naphtha and a heavy boiling range naphtha. The intermediate boiling range naphtha containing thiophene and thiophene boiling range mercaptans, dienes or mixtures may be subjected to a second thioetherification or selective hydrogenation, depending on its make-up, and then passed on to a polishing hydrodesulfurization reactor or the entire intermediate stream may be passed directly to the polishing reactor. The bottoms are subjected to concurrent hydrodesulfurization and fractional distillation and the combined overheads and bottoms are fed to the polishing reactor.

Abstract: A process for treating a light cracked naphtha to be used as an etherification feed stock is disclosed in which mercaptans, H2S and diolefins are removed simultaneously in a distillation column reactor using a reduced nickel catalyst. The mercaptans and H2S are reacted with the diolefins to form sulfides which are higher boiling than that portion of the naphtha which is used as feed to the etherification unit. The higher boiling sulfides are removed as bottoms along with any C6 and heavier materials. Any diolefins not converted to sulfides are selectively hydrogenated to mono-olefins for use in the etherification process.

Abstract: A process for producing a gasoline with a low sulphur content comprises: separating a sulphur-containing gasoline into a light fraction and a heavy fraction, hydrodesulphurising the light gasoline on a nickel-based catalyst, hydrodesulphurising the heavy fraction on a catalyst comprising at least one group VIII metal and/or at least one group VIB metal, and mixing the desulphurised fractions.

Abstract: A process for treating a light cracked naphtha to be used as an etherification feed stock is disclosed in which mercaptans, H2S and diolefins are removed simultaneously in a distillation column reactor using a reduced nickel catalyst. The mercaptans and H2S are reacted with the diolefins to form sulfides which are higher boiling than that portion of the naphtha which is used as feed to the etherification unit. The higher boiling sulfides are removed as bottoms along with any C6 and heavier materials. Any diolefins not converted to sulfides are selectively hydrogenated to mono-olefins for use in the etherification process.

Abstract: A three stage hydroprocessing process includes two liquid and one vapor reaction stages, both of which produce an effluent comprising liquid and vapor. Both vapor effluents comprise vaporized hydrocarbonaceous material. Fresh hydrogen is used for the hydroprocessing in both liquid stages. The second stage liquid effluent comprises the product liquid. The first stage liquid effluent is the feed for the second stage. The first stage vapor effluent is hydroprocessed in the vapor stage and then cooled to condense and recover at least a portion of the processed vapor as additional product liquid.

Abstract: A process for hydrodesulfurization of a sulfur-containing petroleum hydrocarbon diesel gas oil comprising; hydrodesulfurizing a sulfur-containing petroleum hydrocarbon diesel gas oil feedstock, separating the hydrodesulfurized diesel gas oil feedstock into light and heavy fractions by distillation, hydrodesulfurizing further the separated heavy fraction, and mixing the further hydrodesulfurized heavy fraction and the separated light fraction into the hydrocarbon diesel gas oil.

Abstract: A process for the reduction of sulphur content in a FCC gasoline includes fractionation of the FCC gasoline into three fractions: a light fraction comprising 50-80% of the FCC gasoline, an intermediate boiling fraction comprising 10-30% of the FCC gasoline, and a heavy fraction comprising 5-20% of the FCC gasoline. The heaviest fraction is hydrotreated in the first bed of a hydrotreater at conditions that result in essentially total removal of the sulphur. The effluent from the first bed is quenched with the intermediate fraction. The combined oil stream is hydrotreated in a second and final bed in the hydrotreater at conditions that ensure the required overall sulphur reduction.

Abstract: A process for desulfurizing and enhancing the octane of cracked gasoline by first aromatizing the cracked gasoline and, second, hydrodesulfurizing the resulting intermediate product stream.

Abstract: A product of reduced sulfur content is produced from a feedstock which is comprised of a mixture of hydrocarbons and includes sulfur-containing aromatic compounds as unwanted impurities. The process involves separating the feedstock by fractional distillation into a lower boiling fraction which contains the more volatile sulfur-containing aromatic impurities and at least one higher boiling fraction which contains the less volatile sulfur-containing aromatic impurities. Each fraction is then separately subjected to reaction conditions which are effective to convert at least a portion of its content of sulfur-containing aromatic impurities to higher boiling sulfur-containing products by alkylation with an alkylating agent in the presence of an acidic catalyst. The higher boiling sulfur-containing products are removed by fractional distillation.

Abstract: Catalytic cracking gaseolines are treated by: (a) fractionating the raw gasoline cut into two cuts; (b) optional selective diene hydrodenation of the light cut, then mild hydrotreatment and stripping; (c) sweetening the light cut which is conducted before the mild hydrotreatment step by contact with a supported catalyst containing 0.1-1% by weight of palladium, or after the mild hydrotreatment step and which is then an extractive sweetening step, or with a catalyst having an alkaline base optionally incorporated and also an oxidizing agent. The heavy gaseoline fraction is optionally desilphurized in a hydrotreatment unit. The desulpurized and sweetened light gaesoline can be added to the gasoline pool either directly or mixed with the desulphurized heavy gaseoline cut.