Split Treatment Patents (Class 208/218)
  • Patent number: 5968346
    Abstract: A hydroprocessing process includes two hydroprocessing reaction stages, both of which produce a liquid and a vapor effluent, and a liquid-vapor contacting stage. The first stage vapor effluent contains impurities, such as heteroatom compounds, which are removed from the vapor by contact with processed liquid effluent derived from one or both reaction stages and, optionally, also liquid recovered from processed vapor. The first and contact stage liquid effluents are passed into the second stage to finish the hydoprocessing. The contact and second stage vapor effluents are cooled to recover additional hydroprocessed product liquid.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: October 19, 1999
    Assignee: Exxon Research and Engineering Co.
    Inventors: Henry Jung, Ramesh Gupta, Edward S. Ellis, William E. Lewis
  • Patent number: 5932090
    Abstract: The process for the conversion of heavy crude oils or distillation residues to distillates comprises the following steps:mixing the heavy crude oil or distillation residue with a suitable hydrogenation catalyst and sending the mixture obtained to a hydrotreating reactor introducing hydrogen or a mixture of hydrogen and H.sub.2 S;sending the stream containing the hydrotreating reaction product and the catalyst in slurry phase to a distillation zone where the most volatile fractions are separated;sending the high-boiling fraction obtained in the distillation step to a deasphaltation step obtaining two streams, one consisting of deasphalted oil (DAO), the other consisting of asphaltenes, catalyst in slurry phase, possibly coke and rich in metals coming from the initial charge;recycling at least 60%, preferably at least 80% of the stream consisting of asphaltenes, catalyst in slurry phase, optionally coke and rich in metals, to the hydrotreatment zone.
    Type: Grant
    Filed: May 1, 1996
    Date of Patent: August 3, 1999
    Assignee: Snamprogetti S.p.A.
    Inventors: Mario Marchionna, Alberto DelBianco, Nicoletta Panariti
  • Patent number: 5837130
    Abstract: A process for hydrotreating petroleum fractions early in the refining process by employing catalyst prepared as components of distillation structures or as contained beds of catalyst in atmospheric distillation columns and or side draw columns. For example, a crude petroleum is hydrotreated by taking side streams from an atmospheric distillation column and the vacuum gas oil from a vacuum distillation column which are individually fed to separate desulfurizations, preferably in distillation column reactors containing a hydrodesulfurization catalyst. The overheads from each of the distillation column reactors is returned to the atmospheric column and the bottoms from each distillation column reactor is withdrawn as hydrotreated product. The process may also be used for upgrading the effluent from a fluid catalytic cracking unit, preferably operated as a catalytic distillation reactor.
    Type: Grant
    Filed: October 22, 1996
    Date of Patent: November 17, 1998
    Assignee: Catalytic Distillation Technologies
    Inventor: Clifford S. Crossland
  • Patent number: 5707511
    Abstract: A process for simultaneously removing heteroatoms, such as sulfur, from a virgin distillate stream and a light catalytic cyclic stream in two reaction zones in a hydrotreating process unit. One reaction zone will be a low temperature reaction zone and the other will be the high temperature zone. In the low temperature reaction zone, the cracked stream is reacted with a hydrotreating catalyst at a predetermined temperature and in high temperature reaction zone, the virgin distillate stream is reacted with a catalyst which is less reactive than that of the first reaction zone. When catalyst in the high reaction zone is replaced with fresh catalyst the temperature is lowered so that it now becomes the low temperature zone in which the cracked stream is redirected.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: January 13, 1998
    Assignee: Exxon Research and Engineering Company
    Inventors: Gerald E. Markley, George C. Hadjiloizou
  • Patent number: 5164070
    Abstract: The recovery of distillate products from a hydrocracking process includes passing the liquid-phase portion of the reaction zone effluent into a stripping column. A naphtha sidecut stream is recovered off the stripping column and combined with the net overhead liquid of the column. These combined streams are then combined with the naphtha recovered from the primary product recovery column. This minimizes the hydrogen sulfide present in the total naphtha product.
    Type: Grant
    Filed: March 6, 1991
    Date of Patent: November 17, 1992
    Assignee: UOP
    Inventor: William H. Munro
  • Patent number: 4990242
    Abstract: An enhanced process to reduce the sulfur content in petroleum distillate products through fractionation of a feedstock followed by segregated hydrotreating. Improved performance and more controlled desulfurization is achieved.
    Type: Grant
    Filed: June 14, 1989
    Date of Patent: February 5, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Stephen Louie, Gerald E. Markley
  • Patent number: 4885080
    Abstract: A heavy crude oil is fractionated into at least three liquid fractions which include a distillate fraction boiling in the 400.degree. F.-650.degree. F. range and a 650.degree. F.+ boiling range residuum. The distillate cut is hydrodesulfurized and the residuum is hydrodemetallized. The cuts thus hydrotreated, and at least a part of the third liquid fraction, are then combined to form an upgraded synthetic crude oil of relatively low sulfur content and relatively low vanadium and nickel content.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: December 5, 1989
    Assignee: Phillips Petroleum Company
    Inventors: Ronald E. Brown, Robert J. Hogan, Daniel M. Coombs, Simon G. Kukes
  • Patent number: 4333855
    Abstract: The catalytic hydrodesulfurization and/or hydrodenitrogenation of organic compounds containing sulfur and/or nitrogen is carried out in the presence of a catalyst composition comprising zinc, titanium and at least one promoter selected from the group consisting of vanadium, chromium, cobalt, nickel, molybdenum, tungsten, rhenium, platinum, palladium, rhodium, ruthenium, and compounds thereof.
    Type: Grant
    Filed: April 30, 1981
    Date of Patent: June 8, 1982
    Assignee: Phillips Petroleum Company
    Inventors: Lloyd E. Gardner, Floyd E. Farha, Jr., Alan D. Eastman, Lewis E. Drehman
  • Patent number: 4126538
    Abstract: Residual hydrocarbon stocks obtained after vacuum distillation are converted into light distillates by certain sequences of processing steps including vacuum distillation, deasphalting, hydrocracking, atmospheric distillation and catalytic hydrotreating.
    Type: Grant
    Filed: September 12, 1977
    Date of Patent: November 21, 1978
    Assignee: Shell Oil Company
    Inventors: Frans Goudriaan, Jakob Van Klinken
  • Patent number: 4120778
    Abstract: A process is disclosed for the conversion of a hydrocarbon oil vacuum distillation residue to one or more atmospheric distillates by a processing sequence comprising vacuum fractionation, catalytic cracking or hydrocracking, atmospheric fractionation, hydrotreating, atmospheric fractionation, and vacuum fractionation with certain recycle of intermediate streams to achieve efficient, economic operation.
    Type: Grant
    Filed: September 9, 1977
    Date of Patent: October 17, 1978
    Assignee: Shell Oil Company
    Inventors: Frans Goudriaan, Jakob Van Klinken
  • Patent number: 4116816
    Abstract: In a hydrodesulfurization process having separate naphtha and distillate hydrodesulfurization zones, volatile fractions of the distillate hydrodesulfurization effluent are recycled to the naphtha feed stream before it combines with the hydrogen stream and enters the hydrodesulfurization zone and heavy fractions separated from the naphtha hydrodesulfurization effluent are combined with a diesel fuel oil fraction separated from the distillate hydrodesulfurization effluent. Alternatively, light fractions separated from the distillate hydrodesulfurization effluent are combined with a condensed liquid stream being returned to a distillation fractionation zone separating light fractions from the naphtha hydrodesulfurization effluent.
    Type: Grant
    Filed: March 1, 1977
    Date of Patent: September 26, 1978
    Assignee: Phillips Petroleum Company
    Inventors: Edgar D. Davis, Gilbert L. Colbert
  • Patent number: 4062758
    Abstract: A process is disclosed for the production of distillate hydrocarbons from atmospheric distillation hydrocarbon residue.
    Type: Grant
    Filed: August 26, 1976
    Date of Patent: December 13, 1977
    Assignee: Shell Oil Company
    Inventors: Frans Goudriaan, Jakob VAN Klinken
  • Patent number: 4062762
    Abstract: A sulfur-containing naphtha is separated into at least three fractions. Each fraction is desulfurized separately by a different desulfurization method. Subsequently, the desulfurized fractions are recombined. The intermediate boiling point naphtha fraction is desulfurized by an alkali metal desulfurization process, preferably in the presence of added hydrogen.
    Type: Grant
    Filed: September 14, 1976
    Date of Patent: December 13, 1977
    Inventors: Kent A. Howard, William E. Winter, Jr., Karsten H. Moritz, John D. Paynter
  • Patent number: 4006076
    Abstract: Hydrocarbon mixtures having low sulfur contents are obtained from sulfur-containing vacuum gas oils by hydrodesulfurizing the gas oils under mild hydrodesulfurizing conditions, including use of:1. a select high-activity hydrodesulfurization catalyst,2. a temperature in the range 550.degree.F. to 850.degree. F., and3. a hydrogen partial pressure in the range 300 to 800 psig.New and advantageous results are obtained by integrating the foregoing process with one or more other process steps including:1. hydrodesulfurization of sulfur-containing vacuum residuum,2. solvent deasphalting of vacuum residuum, or3. hydrodesulfurizing a vacuum residuum and delayed coking at least a portion of the product.
    Type: Grant
    Filed: June 2, 1975
    Date of Patent: February 1, 1977
    Assignee: Chevron Research Company
    Inventors: Robert I. Christensen, George D. Gould
  • Patent number: 3957625
    Abstract: Gasoline product of cracking desulfurized with a selective desulfurizing catalyst by processing particularly a high boiling portion thereof to minimize hydrogenation of desired olefins in the gasoline product of cracking.
    Type: Grant
    Filed: February 7, 1975
    Date of Patent: May 18, 1976
    Assignee: Mobil Oil Corporation
    Inventor: Bernard A. Orkin