Admixtures Patents (Class 208/23)
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Patent number: 11719685Abstract: The present disclosure provides a selection method of base asphalt for rubber asphalt based on grey relational analysis, which belongs to the technical field of selection methods of base asphalt. The selection method includes the following steps: determining factors affecting the performance of rubber asphalt and rubber asphalt performance evaluation indicators; ranking the factors affecting the performance of rubber asphalt according to respective affecting degrees thereof on each of the rubber asphalt performance evaluation indicators by using a grey relational method; and determining affecting factors of chemical components of base asphalt to the performance of rubber asphalt, and selecting base asphalt according to the affecting factors. The present disclosure uses the grey relational analysis method to systematically study the influences of chemical components of base asphalt on the performance of rubber asphalt.Type: GrantFiled: December 9, 2021Date of Patent: August 8, 2023Assignees: Guangxi Transportation Science and Technology Group Co., Ltd., Guangxi Jiaoke New Materials Technology Co., Ltd.Inventors: Honggang Zhang, Hua Tan, Jizong Tan, Haitao Yuan, Hongbo Zhang, Baolin Xiong, Jianping Xiong, Zehua Xie, Dongliang Kuang
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Patent number: 11053391Abstract: This invention provides for a method for producing polymer modified asphalt using base asphalt (bitumen) blended with partially air blown (“puffed”) asphalt which is further modified with polymers and additives to attain desired properties for industrial applications. The partially blown or blown asphalt is oxidized to a target softening point to suit the application. In another embodiment, the base asphalt is blended with hard PEN asphalt (“Zero PEN Asphalt”) which is further modified with polymers and additives to attain desired properties. By using the partially oxidized asphalt or blending the base asphalt with partially oxidized asphalt or hard PEN asphalt, the amount of polymers and additives needed to achieve desired properties and performance are significantly reduced. This technique can be used to attain polymer modified asphalt having a highly desirable combination of characteristics not otherwise attainable using the base asphalt.Type: GrantFiled: October 6, 2017Date of Patent: July 6, 2021Assignee: Building Materials Investment CorporationInventor: Denis Muki Tibah
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Patent number: 9487641Abstract: An additive that modifies rheological properties of asphalt under warm conditions, and makes it possible to mix and compact asphalt mixtures with a temperature reduction of up to 35° C., constituted by wax, an adhesion-improving additive and a fluxing agent, which reduces asphalt oxidation, causing it to be less-aged and more resistant to fatigue, reduces the interfacial tension between the aggregate and the asphalt, increases adhesion between them, making the mixture resistant to the damages caused by humidity, increases resistance to permanent deformation, causes gas emissions to be reduced and leads to savings in fuel consumption. The additive of the invention has the following effects: 1) at temperatures between 100° C. and 160° C., it reduces the asphalt viscosity, 2) at temperatures between 58° C. and 82° C., it increases the asphalt viscosity, and 3) at temperatures lower than 25° C., it reduces the asphalt viscosity, as compared to asphalt without the additive.Type: GrantFiled: November 4, 2011Date of Patent: November 8, 2016Assignee: Quimikao, S.A. DE C.V.Inventors: Alvaro Gutierrez Muniz, Luis Enrique Ramirez Soto, Heleodro Rincon Acha, Raul Teran Orozco, Raymundo Benitez Lopez, Jose Luis Lara Gonzalez
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Patent number: 9120978Abstract: A method for decomposing an asphaltene particle includes contacting the asphaltene particle with an intercalating agent and separating an asphaltene molecule from the asphaltene particle to decompose the asphaltene particle. Dispersing an asphaltene particle includes functionalizing the asphaltene particle and contacting the asphaltene particle with a solvent to disperse the asphaltene particle. Such asphaltene particle decomposition and dispersal can be used in a method for improving oil recovery that includes disposing a reagent in an oil environment; contacting an asphaltene particle with the reagent; decomposing the asphaltene particle to produce decomposed asphaltene; and displacing the decomposed asphaltene to improve oil recovery.Type: GrantFiled: February 24, 2012Date of Patent: September 1, 2015Assignee: Baker Hughes IncorporatedInventors: Oleg A. Mazyar, Houman M. Shammai, Gaurav Agrawal
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Patent number: 8993495Abstract: A novel composition is provided that incorporates the residual solids from solvent deasphalting to make a high value asphalt product. A process for making the asphalt composition is also provided. A first portion of heavy oil or another feedstock can be deasphalted using propane deasphalting or another suitable deasphalting process. This generates a solvated fraction and an insoluble deasphalting residue. The deasphalting residue is then added to a second portion of heavy oil, such as a second portion of the same type of heavy oil that was used as feedstock in the solvent deasphalting. The mixture of deasphalting residue and heavy oil results in a novel dispersion that is suitable for use as an asphalt. Optionally, an additive such as an alkyl substituted aromatic sulfonic acid can be added to the composition to further improve the asphalt properties.Type: GrantFiled: December 2, 2011Date of Patent: March 31, 2015Assignee: ExxonMobil Research and Engineering CompanyInventors: Ramesh Varadaraj, Lyle E. Moran, John Brownie, Mary J. Gale
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Publication number: 20150008156Abstract: A bitumen, characterized in that said bitumen is a mixture.Type: ApplicationFiled: July 3, 2014Publication date: January 8, 2015Inventors: Caroline MARTIN, Placido CARUSO, Hans AERTS
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Patent number: 8821712Abstract: A process for treating a heavy hydrocarbon feedstock is disclosed. The process involves separating the feedstock into a residue component and a light component, the residue component having a lower API gravity than the light component and treating at least a portion of the light component to produce a synthetic transport diluent suitable for combining with at least a portion of the residue component to produce a product which meets applicable criteria for pipeline transport.Type: GrantFiled: August 3, 2011Date of Patent: September 2, 2014Assignee: Statoil Canada Ltd.Inventors: Leonard F. Flint, Patrick B. Carlson, Gareth R. Crandall
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Patent number: 8741125Abstract: The invention provides a stock oil composition for a carbon material for a negative electrode for a lithium ion secondary battery, having a 10 vol % distillation temperature of 280° C. or higher as the distillation property, a density of at least 0.90 g/cm3 at a temperature of 15° C. and a normal paraffin content of at least 3 parts by weight with respect to 100 parts by weight as the total weight of the stock oil composition; and having an aromatic component content of 30-85 parts by weight with respect to 100 parts by weight as the total weight of the stock oil composition and an aromatic component molecular weight of 250-1600 when the aromatic components and non-aromatic components are separated by elution chromatography.Type: GrantFiled: December 25, 2009Date of Patent: June 3, 2014Assignee: JX Nippon Oil & Energy CorporationInventors: Tamotsu Tano, Takashi Oyama, Ippei Fujinaga, Masayuki Tasaki, Akio Sakamoto
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Publication number: 20140083332Abstract: The present invention provides a method for extracting bitumen from an oil sand stream, the method comprising at least the steps of, a) providing an oil sand stream; b) contacting the oil sand stream with a liquid comprising a solvent to obtain a solvent-diluted oil sand slurry; c) separating the oil sand slurry to obtain a first solids-depleted stream and a first solids-enriched stream; d) filtering the first solids-enriched stream obtained in step c) to obtain bitumen-depleted sand and at least a first filtrate; e) separating at least a part of the first filtrate to obtain a second solids-depleted stream and a second solids-enriched stream; and f) contacting at least a part of the second solids-enriched stream from step e) with solvent to obtain a solvent-diluted second solids-enriched stream; and g) separating the solvent-diluted second solids-enriched stream to obtain a third solids-enriched stream and a third solids-depleted stream.Type: ApplicationFiled: September 23, 2013Publication date: March 27, 2014Applicants: SHELL CANADA ENERGY, MARATHON OIL SANDS L.P., CHEVRON CANADA LIMITEDInventors: Ingmar Hubertus Josephina PLOEMEN, Gerhardus Willem COLENBRANDER, Anjana Kalpesh BHALODI
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Patent number: 8656950Abstract: A method of producing treated liquid hydrocarbons. The method begins by pressurizing a latex in a pressure vessel. This is followed by flowing the latex from the pressure vessel into a pipeline containing liquid hydrocarbons to produce treated liquid hydrocarbons. In this embodiment the latex comprises a drag reducing polymer.Type: GrantFiled: August 12, 2011Date of Patent: February 25, 2014Assignee: Phillips 66 CompanyInventor: Timothy L. Burden
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Patent number: 8616236Abstract: A method begins by obtaining a slipstream of a liquid. The slipstream of liquid is then mixed upstream of an injection pump with a latex comprising a drag reducing polymer to produce a drag reducing mixture. The drag reducing mixture is then injected into a liquid hydrocarbon to produce a treated liquid hydrocarbon.Type: GrantFiled: August 12, 2011Date of Patent: December 31, 2013Assignee: Phillips 66 CompanyInventor: Timothy L. Burden
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Patent number: 8575082Abstract: A drag reducing additive for heavy oil, such as crude oil, includes a polymeric alkyl-substituted phenol formaldehyde resin and a solvent having at least one of an ester (e.g. ethyl acetate), an aldehyde (e.g. butyraldehyde), and an aromatic hydrocarbon (e.g. toluene, xylene, and the like), or mixtures thereof. When used together with a diluent (e.g. condensate, naphtha, or the like), the additive may reduce viscosity of the combined oil, diluent, and additive by at least 20%, increase throughput by at least 6%, reduce power consumption by at least 3%, reduce the diluent proportion by at least 3%, or some combination of these effects, as compared with an otherwise identical heavy oil without the additive.Type: GrantFiled: December 4, 2012Date of Patent: November 5, 2013Assignee: Baker Hughes IncorporatedInventors: Samuel Asomaning, Scott E. Lehrer
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Publication number: 20130143778Abstract: A novel composition is provided that incorporates the residual solids from solvent deasphalting to make a high value asphalt product. A process for making the asphalt composition is also provided. A first portion of heavy oil or another feedstock can be deasphalted using propane deasphalting or another suitable deasphalting process. This generates a solvated fraction and an insoluble deasphalting residue. The deasphalting residue is then added to a second portion of heavy oil, such as a second portion of the same type of heavy oil that was used as feedstock in the solvent deasphalting. The mixture of deasphalting residue and heavy oil results in a novel dispersion that is suitable for use as an asphalt. Optionally, an additive such as an alkyl substituted aromatic sulfonic acid can be added to the composition to further improve the asphalt properties.Type: ApplicationFiled: December 2, 2011Publication date: June 6, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Ramesh Varadaraj, Lyle E. Moran, John Brownie, Mary J. Gale
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Patent number: 8450251Abstract: A system for reducing pressure drop associated with the turbulent flow of asphaltenic crude oil through a conduit. The crude oil has a high asphaltene content and/or a low API gravity. Such reduction in pressure drop is achieved by treating the asphaltenic crude oil with a high molecular weight drag reducing polymer that can have a solubility parameter within about 20 percent of the solubility parameter of the heavy crude oil. The drag reducing polymer can also comprise the residues of monomers having at least one heteroatom.Type: GrantFiled: August 11, 2011Date of Patent: May 28, 2013Assignee: Phillips 66 CompanyInventors: Stuart N. Milligan, Ray L. Johnston, Timothy L. Burden, Wayne R. Dreher, Kenneth W. Smith, William F. Harris
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Patent number: 8450249Abstract: A method of introducing a drag reducing polymer into a pipeline such that the friction loss associated with the turbulent flow though the pipeline is reduced by suppressing the growth of turbulent eddies. The drag reducing polymer is introduced into a liquid hydrocarbon having an asphaltene content of at least 3 weight percent and an API gravity of less than about 26° to thereby produce a treated liquid hydrocarbon. The treated liquid hydrocarbon does not have a viscosity less than the viscosity of the liquid hydrocarbon prior to treatment with the drag reducing polymer. Additionally, the drag reducing polymer is added to the liquid hydrocarbon in the range from about 0.1 to about 500 ppmw.Type: GrantFiled: August 11, 2011Date of Patent: May 28, 2013Assignee: Phillips 66 CompanyInventors: Stuart N. Milligan, Ray L. Johnston, Timothy L. Burden, Wayne R. Dreher, Kenneth W. Smith, William F. Harris
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Patent number: 8450250Abstract: A method of preparing a drag reducing polymer wherein the drag reducing polymer is able to be injected into a pipeline, such that the friction loss associated with the turbulent flow through the pipeline is reduced by suppressing the growth of turbulent eddies. The drag reducing polymer is injected into a pipeline of liquid hydrocarbon hydrocarbon having an asphaltene content of at least 3 weight percent and an API gravity of less than about 26° to thereby produce a treated liquid hydrocarbon wherein the viscosity of the treated liquid hydrocarbon is not less than the viscosity of the liquid hydrocarbon prior to treatment with the drag reducing polymer. The drag reducing polymer has a solubility parameter within 4 MPa1/2 of the solubility parameter of the liquid hydrocarbon. The drag reducing polymer is also added to the liquid hydrocarbon in the range from about 0.1 to about 500 ppmw.Type: GrantFiled: August 11, 2011Date of Patent: May 28, 2013Assignee: Phillips 66 CompanyInventors: Stuart N. Milligan, Ray L. Johnston, Timothy L. Burden, Wayne R. Dreher, Kenneth W. Smith, William F. Harris
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Patent number: 8426498Abstract: A method of introducing a drag reducing polymer into a pipeline such that the friction loss associated with the turbulent flow though the pipeline is reduced by suppressing the growth of turbulent eddies. The drag reducing polymer is introduced into a liquid hydrocarbon having an asphaltene content of at least 3 weight percent and/or an API gravity of less than about 26° to thereby produce a treated liquid hydrocarbon. The treated liquid hydrocarbon does not have a viscosity less than the viscosity of the liquid hydrocarbon prior to treatment with the drag reducing polymer. Additionally, the drag reducing polymer is added to the liquid hydrocarbon in the range from about 0.1 to about 500 ppmw.Type: GrantFiled: August 11, 2011Date of Patent: April 23, 2013Assignee: Phillips 66 CompanyInventors: Stuart N. Milligan, Ray L. Johnston, Timothy L. Burden, Wayne R. Dreher, Kenneth W. Smith, William F. Harris
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Patent number: 8404164Abstract: A composition for pelletized bitumen and a method for preparing the same is disclosed. The composition is comprised of: between approximately 30% to approximately 40% by weight of bitumen; between approximately 15% to approximately 30% by weight of stiffening compound; between approximately 35% to approximately 45% by weight of setting compound; and approximately 0.05% by weight of water. The stiffening compound is comprised of between approximately 10% to approximately 20% by weight of ground asphalt shingles; between approximately 5% to approximately 10% by weight of vulcanized rubber; between approximately 1% to approximately 2% by weight of uintahite; and up to approximately 0.5% by weight of zeolite. And the stiffening compound may be Type II Portland cement.Type: GrantFiled: July 8, 2011Date of Patent: March 26, 2013Assignee: Phoenix Industries, LLCInventor: Kelly Sockwell
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Publication number: 20130012744Abstract: A reduced puffing needle coke is formed, which includes a reduced nitrogen content within the coke so that the coke particles do not experience as much puffing during the formation of graphitized carbon articles produced from such coke upon heating to graphitization temperatures.Type: ApplicationFiled: September 14, 2012Publication date: January 10, 2013Inventors: Douglas J. Miller, Ching-Feng Chang, Irwin C. Lewis, Richard T. Lewis, Aaron Tomasek, Richard L. Shao
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Publication number: 20120240824Abstract: A method for extracting bitumen from an oil sand feed stream comprises at least the steps of: (a) providing an oil sand feed stream; (b) contacting the oil sand feed stream with an aliphatic hydrocarbon solvent thereby obtaining a solvent-diluted oil sand slurry; (c) separating the solvent-diluted oil sand slurry, thereby obtaining a solids-depleted stream and a solids-enriched stream; and (d) removing solvent from the solids-enriched stream thereby obtaining a dry product comprising sand and bitumen, wherein the bitumen in the dry product comprises at least 40 wt. % asphaltenes.Type: ApplicationFiled: March 20, 2012Publication date: September 27, 2012Applicant: SHELL OIL COMPANYInventor: Michael David LANKSHEAR
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Patent number: 8252168Abstract: A method for modifying asphalt comprises blowing an oxygen-containing gas through a base asphalt at a high gas flow rate while simultaneously agitating the base asphalt at a high shear rate and at an elevated temperature for a period of time that is effective to substantially improve at least two paving properties of the base asphalt. In preferred embodiments, modified asphalts are produced having both substantially improved rutting resistance and substantially improved fatigue resistance as compared to the base asphalt.Type: GrantFiled: August 2, 2011Date of Patent: August 28, 2012Assignee: Asphalt Technology LLCInventors: Michael V Burris, Bryan B Burris, Hossein Ajideh
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Patent number: 8231775Abstract: A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a particulate solid material to form a heavy hydrocarbon slurry and hydrocracked in a slurry hydrocracking unit to produce vacuum gas oil (VGO) and pitch. A first vacuum column separates VGO from pitch, and a second vacuum column further separates VGO from pitch. As much as 15 wt-% of VGO can be recovered by the second vacuum column and recycled to the slurry hydrocracking unit. A pitch composition is obtained which can be made into particles and transported without sticking together.Type: GrantFiled: June 15, 2010Date of Patent: July 31, 2012Assignee: UOP LLCInventors: James F. McGehee, Ronald S. Smyczynski
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Patent number: 8226921Abstract: The present invention provides a raw coke having such a structure that the graphitized product resulting from graphitization of the raw coke at a temperature of 2800° C. under an inactive gas atmosphere will have ratios of the crystallite size to the lattice constant of 360 or less in the (002) plane and 1500 or less in the (110) plane, as a raw coke providing active carbon produced by alkali-activating the raw coke, which is reduced in remaining alkali content and can simplify washing operation because washing liquid can easily pass through the activated carbon, or as a raw coke for the production of needle coke.Type: GrantFiled: June 10, 2011Date of Patent: July 24, 2012Assignees: Nippon Oil Corporation, Nippon Petroleum Refining Company, LimitedInventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Toshitaka Fujii, Takashi Noro, Akio Sakamoto, Kiwamu Takeshita, Keizou Ikai, Masaki Fujii, Hideki Ono
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Patent number: 8221105Abstract: Systems for pelletizing hot asphaltenes are provided. Asphaltenic hydrocarbons can be dispersed to provide two or more asphaltenic particles. The asphaltenic hydrocarbons can be at a temperature of from about 175° C. to about 430° C. The asphaltenic particles can be contacted with a film of cooling medium. The film can have a thickness of from about 1 mm to about 500 mm. At least a portion of the asphaltenic particles can be solidified by transferring heat from the asphaltenic particles to the cooling medium to provide solid asphaltenic particles. The solid asphaltenic particles can be separated from at least a portion of the cooling medium.Type: GrantFiled: May 18, 2011Date of Patent: July 17, 2012Assignee: Kellogg Brown & Root LLCInventors: Gary L. Behelfer, Maury Schlossman
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Patent number: 8193401Abstract: Slurry hydrocracking a heavy hydrocarbon feed produces a HVGO stream and a pitch stream. At least a portion of the pitch stream is subjected to SDA to prepare a DAO stream low in metals. The DAO is blended with at least a portion of the HVGO stream to provide turbine or marine fuel with acceptable properties for combustion in gas turbines or for marine fuel grades.Type: GrantFiled: December 11, 2009Date of Patent: June 5, 2012Assignee: UOP LLCInventors: James F. McGehee, Lorenz J. Bauer
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Patent number: 8137530Abstract: A process is provided for producing petroleum coke that is high in strength and sufficiently small in thermal expansion coefficient and sufficiently suppressed from puffing. The process includes coking a feedstock containing a first heavy oil having a sulfur content of 1.0 percent by mass or less, a nitrogen content of 0.5 percent by mass or less, and an aromatic index of 0.1 or greater, produced by hydrodesulfurizing a heavy oil with a sulfur content of 1 percent by mass or more under conditions (1) where the total pressure is 10 MPa or greater and less than 16 MPa and the hydrogen partial pressure is 5 MPa or greater and 16 MPa or less or conditions (2) where the total pressure is 20 MPa or greater and 25 MPa or less and the hydrogen partial pressure is greater than 20 MPa and 25 MPa or less, and a second heavy oil with an aromatic index of 0.3 or greater and an initial boiling point of 150° C. or higher.Type: GrantFiled: April 15, 2008Date of Patent: March 20, 2012Assignee: Nippon Petroleum Refining Co., Ltd.Inventors: Tamotsu Tano, Takashi Oyama, Kazuhisa Nakanishi, Toshiyuki Oda, Keiji Higashi
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Patent number: 8022118Abstract: A system for reducing pressure drop associated with the turbulent flow of asphaltenic crude oil through a conduit. The crude oil has a high asphaltene content and/or a low API gravity. Such reduction in pressure drop is achieved by treating the asphaltenic crude oil with a high molecular weight drag reducing polymer that can have a solubility parameter within about 20 percent of the solubility parameter of the heavy crude oil. The drag reducing polymer can also comprise the residues of monomers having at least one heteroatom.Type: GrantFiled: December 22, 2006Date of Patent: September 20, 2011Assignee: ConocoPhillips CompanyInventors: Stuart N. Milligan, Ray L. Johnston, Timothy L. Burden, Wayne R. Dreher, Jr., Kenneth W. Smith, William F. Harris
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Patent number: 8007657Abstract: Described is the use, for preparing or treating bituminous compositions, of at least one compound selected among: esters of glycolic, lactic and gluconic acids, methylic, ethylic and isobutylic esters of glutaric, succinic and adipic acids, and ethers or esters of a product resulting from internal dehydration of a sugar, preferably a hydrogenated sugar. Also described is a method for preparing or treating such compositions and the resulting compositions.Type: GrantFiled: December 20, 2005Date of Patent: August 30, 2011Assignee: Roquette FreresInventors: Léon Mentink, Joël Bernaerts, Michel Maze, Frédéric Delfosse
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Patent number: 7988846Abstract: A method for modifying asphalt comprises blowing an oxygen-containing gas through a base asphalt at a high gas flow rate while simultaneously agitating the base asphalt at a high shear rate and at an elevated temperature for a period of time that is effective to substantially improve at least two paving properties of the base asphalt. In preferred embodiments, modified asphalts are produced having both substantially improved rutting resistance and substantially improved fatigue resistance as compared to the base asphalt.Type: GrantFiled: January 14, 2010Date of Patent: August 2, 2011Assignee: Asphalt Technology LLCInventors: Michael V Burris, Bryan B Burris, Hossein Ajideh
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Patent number: 7968020Abstract: Systems and methods for pelletizing hot asphaltenes are provided. Asphaltenic hydrocarbons can be dispersed to provide two or more asphaltenic particles. The asphaltenic hydrocarbons can be at a temperature of from about 175° C. to about 430° C. The asphaltenic particles can be contacted with a film of cooling medium. The film can have a thickness of from about 1 mm to about 500 mm. At least a portion of the asphaltenic particles can be solidified by transferring heat from the asphaltenic particles to the cooling medium to provide solid asphaltenic particles. The solid asphaltenic particles can be separated from at least a portion of the cooling medium.Type: GrantFiled: April 30, 2008Date of Patent: June 28, 2011Assignee: Kellogg Brown & Root LLCInventors: Gary L. Behelfer, Maury Schlossman
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Patent number: 7964173Abstract: The present invention provides feedstock compositions for use of the production of an activated carbon for electric double layer capacitor electrodes or the production of needle coke, comprising a first heavy oil with an initial boiling point of 300° C. or higher, an asphalten content of 12 percent by mass or less, a saturate content of 50 percent by mass or more and a sulfur content of 0.3 percent by mass or less, produced as a residue resulting from vacuum-distillation of a petroleum-based oil and a second heavy oil with an initial boiling point of 150° C. or higher and a sulfur content of 0.5 percent by mass or less, produced by subjecting a hydrocarbon oil to fluidized catalytic cracking.Type: GrantFiled: December 27, 2006Date of Patent: June 21, 2011Assignees: Nippon Oil Corporation, Nippon Petroleum Refining Company, LimitedInventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Kiwamu Takeshita, Masaki Fujii, Hideki Ono
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Patent number: 7959888Abstract: The present invention provides a raw coke having such a structure that the graphitized product resulting from graphitization of the raw coke at a temperature of 2800° C. under an inactive gas atmosphere will have ratios of the crystallite size to the lattice constant of 360 or less in the (002) plane and 1500 or less in the (110) plane, as a raw coke providing active carbon produced by alkali-activating the raw coke, which is reduced in remaining alkali content and can simplify washing operation because washing liquid can easily pass through the activated carbon, or as a raw coke for the production of needle coke.Type: GrantFiled: December 27, 2006Date of Patent: June 14, 2011Assignees: Nippon Oil Corporation, Nippon Petroleum Refining Company, LimitedInventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Toshitaka Fujii, Takashi Noro, Akio Sakamoto, Kiwamu Takeshita, Keizou Ikai, Masaki Fujii, Hideki Ono
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Patent number: 7906010Abstract: The invention relates to the use of steam cracked tar with the bottoms product of a flash drum integrated with a pyrolysis furnace. In embodiments, the steam cracked tar is added to fuel oil.Type: GrantFiled: January 13, 2006Date of Patent: March 15, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Paul F. Keusenkothen, Alok Srivastava
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Patent number: 7901563Abstract: The present invention relates to a method for preparing an industrial asphalt comprising (1) heating an asphalt flux to a temperature which is within the range of about 400° F. (204° C.) to 550° F. (288° C.) to produce a hot asphalt flux, (2) sparging an oxygen containing gas through the hot asphalt flux for a period of time which is sufficient to increase the softening point of the asphalt flux to a value of at least 100° F. (38° C.), to produce an underblown asphalt composition; and (3) mixing a sufficient amount of a polyphosphoric acid throughout the underblown asphalt composition while the underblown asphalt composition is maintained at a temperature which is within the range of 200° F. (93° C.) to 550° F. (288° C.) to attain a softening point which is within the range of 185° F. (85° C.) to 250° F. (121° C.) and a penetration value of at least 15 dmm at 77° F. (25° C.) to produce the industrial asphalt.Type: GrantFiled: February 1, 2006Date of Patent: March 8, 2011Assignee: Building Materials Investment CorporationInventors: Yonghong Ruan, William K. Longcor, IV, Peter Lars Johnson
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Publication number: 20100147333Abstract: Non-high solvency dispersive power (non-HSDP) crude oil with increased fouling mitigation and on-line cleaning effects includes a base non-HSDP crude oil and an effective amount of resins isolated from a high solvency dispersive power (HSDP) crude oil, and method of making same. Also, methods of using such non-HSDP crude oil for on-line cleaning of a fouled crude oil refinery component, for reducing fouling in a crude oil refinery component, and in a system capable of experiencing fouling conditions associated with particulate or asphaltene fouling.Type: ApplicationFiled: December 11, 2008Publication date: June 17, 2010Applicant: ExxonMobil Research and Engineering CompanyInventors: Chris A. Wright, Glen B. Brons, Sharon A. Feiller, George A. Lutz
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Publication number: 20100133143Abstract: Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.Type: ApplicationFiled: September 2, 2009Publication date: June 3, 2010Applicant: Shell Oil CompanyInventors: Augustinus Wilhelmus Maria Roes, Vijay Nair, Erwin Hunh Munsterman, Petrus Franciscus Van Bergen, Franciscus Gondulfus Antonius Van Den Berg
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Patent number: 7625479Abstract: A binder pitch material includes a petroleum pitch and asphalt fraction obtained from petroleum crude oil and has a significantly lower polycyclic aromatic hydrocarbon composition than a coal tar pitch having a like softening point. The pitch material is useful as a binder material for various applications such as clay pigeons.Type: GrantFiled: June 12, 2008Date of Patent: December 1, 2009Assignee: Marathon Ashland Petroleum LLCInventors: Melvin D. Kiser, David C. Boyer
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Publication number: 20090268375Abstract: The present invention provides a raw coke having such a structure that the graphitized product resulting from graphitization of the raw coke at a temperature of 2800° C. under an inactive gas atmosphere will have ratios of the crystallite size to the lattice constant of 360 or less in the (002) plane and 1500 or less in the (110) plane, as a raw coke providing active carbon produced by alkali-activating the raw coke, which is reduced in remaining alkali content and can simplify washing operation because washing liquid can easily pass through the activated carbon, or as a raw coke for the production of needle coke.Type: ApplicationFiled: December 27, 2006Publication date: October 29, 2009Applicants: NIPPON OIL CORPORATION, NIPPON PETROLEUM REFINING COMPANY, LIMITEDInventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Toshitaka Fujii, Takashi Noro, Akio Sakamoto, Kiwamu Takeshita, Keizou Ikai, Masaki Fujii, Hideki Ono
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Publication number: 20090237860Abstract: The present invention provides feedstock compositions for use of the production of an activated carbon for electric double layer capacitor electrodes or the production of needle coke, comprising a first heavy oil with an initial boiling point of 300° C. or higher, an asphalten content of 12 percent by mass or less, a saturate content of 50 percent by mass or more and a sulfur content of 0.3 percent by mass or less, produced as a residue resulting from vacuum-distillation of a petroleum-based oil and a second heavy oil with an initial boiling point of 150° C. or higher and a sulfur content of 0.5 percent by mass or less, produced by subjecting a hydrocarbon oil to fluidized catalytic cracking.Type: ApplicationFiled: December 27, 2006Publication date: September 24, 2009Applicants: NIPPON OIL CORPORATION, NIPPON PETROLEUM REFINING COMPANY, LIMITEDInventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Kiwamu Takeshita, Masaki Fujii, Hideki Ono
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Publication number: 20090206003Abstract: Hydrogen sulfide evolution from asphalt may be reduced or eliminated using an additive to act as a scavenger. Metal borate complexes when used as an additive in asphalt production, are an effective component in preventing or mitigating the evolution of hydrogen sulfide from asphalt. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.Type: ApplicationFiled: February 17, 2009Publication date: August 20, 2009Applicant: Baker Hughes IncorporatedInventor: Jennifer D. Draper
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Publication number: 20090020453Abstract: The present invention is related to a process oil using as a raw material a deasphalted oil obtained by deasphalting a vacuum residual oil of a crude oil and a manufacturing method of the process oil, the process oil having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (b) a viscosity (100° C.) of 40 to 70 mm2/s; (c) an aniline point of 85 to 100° C.; (d) a flash point of 250° C. or higher; (e) an aromatic hydrocarbon content of 40 to 55 mass %; and (f) a polar substance content of 10 to 15 mass %. The present invention is also related to a process oil and a manufacturing method of the process oil, the process oil obtained by mixing: an extract obtained by deasphalting and solvent-extracting a vacuum residual oil of a crude oil; and a lubricant base oil having a polycyclic aromatics (PCA) content of less than 3 mass %, and having properties of: (a) a polycyclic aromatics (PCA) content of less than 3 mass %; (i) a viscosity (100° C.Type: ApplicationFiled: May 29, 2006Publication date: January 22, 2009Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Meishi Tanaka, Masashi Nakamura, Kazuhiro Teshima, Akihito Abe, Masami Takasaki
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Patent number: 7393449Abstract: A binder pitch material includes a petroleum pitch and asphalt fraction obtained from petroleum crude oil and has a significantly lower polycyclic aromatic hydrocarbon composition than a coal tar pitch having a like softening point. The pitch material is useful as a binder material for various applications such as clay pigeons.Type: GrantFiled: May 31, 2006Date of Patent: July 1, 2008Assignee: Marathon Ashland Petroleum LLCInventors: Melvin D. Kiser, David C. Boyer
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Patent number: 7282135Abstract: A low viscosity, high coking value petroleum tar material having a high coking value as compared to standard petroleum tars and containing at least one biodiesel material dissolved therein, and a method for producing such material, are disclosed.Type: GrantFiled: November 3, 2004Date of Patent: October 16, 2007Assignee: Marathon Ashland Petroleum Co., LLCInventors: Melvin D. Kiser, David C. Boyer
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Patent number: 7252755Abstract: A low-viscosity, high-softening point heavy hydrocarbon material having a viscosity-reducing amount of at least one biodiesel material dissolved in a heavy hydrocarbon, and a method for producing such low-viscosity, high-softening point heavy hydrocarbon material are disclosed.Type: GrantFiled: April 7, 2003Date of Patent: August 7, 2007Assignee: Marathon Ashland Petroleum Co.Inventors: Melvin D. Kiser, David C. Boyer
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Patent number: 7094331Abstract: A low viscosity, high softening point heavy hydrocarbon material having a viscosity reducing amount of at least one dihydric alcohol dissolved therein, and a method for producing such heavy hydrocarbon material, are disclosed.Type: GrantFiled: November 5, 2003Date of Patent: August 22, 2006Assignee: Marathon Ashland Petroleum LLCInventor: Melvin D. Kiser
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Patent number: 7067050Abstract: A binder pitch material includes a petroleum pitch and asphalt fraction obtained from petroleum crude oil and has a significantly lower polycyclic aromatic hydrocarbon composition than a coal tar pitch having a like softening point. The pitch material is useful as a binder material for various applications such as clay pigeons.Type: GrantFiled: November 14, 2002Date of Patent: June 27, 2006Assignee: Marathon Ashland Petroleum LLCInventors: Melvin D. Kiser, David C. Boyer
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Patent number: 7008526Abstract: When a pitch composition prepared by mixing 100 parts by weight of mesophase pitch with 10 to 1,000 parts by weight of coal tar pitch, is heat-treated at a temperature of 500° C. or higher, it is possible to produce a high-density coke at a high yield while avoiding the foaming of the mesophase pitch. In addition, when the coke is graphitized at a temperature of 2,000° C. or higher, it is possible to obtain an artificial graphite having a high graphitization degree. Further, when the coke is first pulverized and then graphitized at a temperature of 2,000° C. or higher, it is possible to obtain a high-crystallinity graphite powder which can be suitably used as a carbon material for a negative electrode of non-aqueous solvent type secondary battery having a high discharge capacity and a high charge-discharge efficiency.Type: GrantFiled: August 8, 2001Date of Patent: March 7, 2006Assignee: Mistubishi Gas Chemical Company, Inc.Inventors: Koichi Kanno, Hirotaka Tsuruya, Ryuji Fujiura
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Publication number: 20040195149Abstract: A low viscosity, high coking value petroleum tar material having a high coking value as compared to standard petroleum tars and containing at least one biodiesel material dissolved therein, and a method for producing such material, are disclosed.Type: ApplicationFiled: April 7, 2003Publication date: October 7, 2004Inventors: Melvin D. Kiser, David C. Boyer
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Publication number: 20040195150Abstract: A low-viscosity, high-softening point heavy hydrocarbon material having a viscosity-reducing amount of at least one biodiesel material dissolved in a heavy hydrocarbon, and a method for producing such low-viscosity, high-softening point heavy hydrocarbon material are disclosed.Type: ApplicationFiled: April 7, 2003Publication date: October 7, 2004Inventors: Melvin D. Kiser, David C. Boyer
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Patent number: 6717021Abstract: A solvating component for a solvated mesophase pitch. The solvated component includes a mixture of aromatic hydrocarbons having boiling points in the atmospheric equivalent boiling point range of about 285° to about 500° C. (about 550° F.-932° F.). At least 80% of the carbon atoms of the hydrocarbons are aromatic as characterized by carbon 13 NMR. The aromatic hydrocarbons are selected from a group consisting of aromatic compounds having 2 to 5 aromatic rings, substituted aromatic compounds having 2 to 5 aromatic rings wherein said substituents are alkyl groups having 1 to 3 carbons, hydroaromatic compounds having 2 to 5 rings, substituted aromatic compounds having 2 to 5 rings wherein said substituents are alkyl groups having 1 to 3 carbons, and mixtures thereof.Type: GrantFiled: June 4, 2001Date of Patent: April 6, 2004Assignee: ConocoPhillips CompanyInventors: H. Ernest Romine, John A. Rodgers, W. Mark Southard, Edward J. Nanni