With Other Organic Compound Patents (Class 208/233)
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Patent number: 7985331Abstract: The liquid hydrocarbon stream including COS is introduced via line 1 into membrane contactor CM to be placed in contact, through membrane M, with the aqueous alkanolamine solution arriving via line 3. The COS contained in the hydrocarbon stream is absorbed by the aqueous alkanolamine solution. The liquid hydrocarbons from which the COS has been removed are evacuated from CM via line 2. The aqueous solution containing COS is sent via line 4 to zone R to be regenerated. The compounds released during regeneration, particularly COS and COS-derived products, are evacuated from zone R via line 5. The regenerated aqueous alkanolamine solution is recycled via line 3 into membrane contactor CM.Type: GrantFiled: July 11, 2006Date of Patent: July 26, 2011Assignee: Institut Francais du PetroleInventors: Arnaud Baudot, Renaud Cadours, Raphaël Huyghe, Elsa Jolimaitre, Pascal Mougin, Eszter Toth
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Patent number: 7838712Abstract: Disclosed is a method for steam-cracking naphtha, according to which a charge of hydrocarbons containing a portion of paraffinic naphtha, which is modified by adding a combination of a first component containing a portion of gasoline and a second component containing a portion of at least one hydrocarbonated refinery gas, and a paraffin-rich change containing at least one paraffin selected among propane, butane, or a mixture thereof are fed through a steam cracker in the presence of vapor. Also disclosed is a hydrocarbon composition suitable for steam cracking, containing a portion of a paraffinic naphtha, which is modified by adding a combination of a first component containing a portion of gasoline and a second component containing a portion of at least one hydrocarbonated refinery gas and a paraffin-rich charge containing at least one paraffin selected among propane, butane, or a mixture thereof.Type: GrantFiled: January 9, 2003Date of Patent: November 23, 2010Assignees: Total Petrochemicals Research Feluy, Total Raffinage MarketingInventors: François Bouvart, Robert Duchesnes, Claude Gutle
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Patent number: 7713409Abstract: A method for reducing the level of elemental sulfur from sulfur-containing hydrocarbon streams as well as reducing the level of total sulfur in such streams. Preferred hydrocarbon streams include fuel streams such as naphtha streams that are transported through a pipeline. The sulfur-containing hydrocarbon stream is contacted with a mixture of water, a caustic, a surfactant, at least one metal sulfide, and optionally an aromatic mercaptan. This results in an aqueous phase and a hydrocarbon phase containing reduced levels of both elemental sulfur and total sulfur.Type: GrantFiled: May 6, 2005Date of Patent: May 11, 2010Assignee: ExxonMobil Research & Engineering CompanyInventor: Joseph L. Feimer
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Patent number: 7632396Abstract: A method for reducing the level of elemental sulfur from sulfur-containing hydrocarbon streams as well as reducing the level of total sulfur in such streams. Preferred hydrocarbon streams include fuel streams such as naphtha and distillate streams that are transported through a pipeline. The sulfur-containing hydrocarbon stream is blended with an aqueous solution of water, a caustic, and at least one metal sulfide thereby resulting in an organic phase and an aqueous phase. The blended stream is then passed through a bed of solids having a suitable surface area so that a substantial amount of the sulfur moieties are removed by the aqueous phase.Type: GrantFiled: May 6, 2005Date of Patent: December 15, 2009Assignee: Exxonmobil Research and Engineering CompanyInventors: Joseph L. Feimer, David J. LeClair, Lawrence J. Lawlor
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Patent number: 5674378Abstract: The present invention is directed to a process for the removal of elemental sulfur from fluids such as fuels, e.g. gasoline, kerosene, diesel or jet, by contacting said fluids with an immiscible treatment solution comprising water or immiscible alcohol, caustic, sulfide or hydrosulfide and optionally mercaptan, in a staged co-current mixer under conditions such that the immiscible treatment solution constitutes the continuous phase.Type: GrantFiled: June 11, 1996Date of Patent: October 7, 1997Assignee: Exxon Research & Engineering CompanyInventors: Daniel William Kraemer, Ramesh Relumal Hemrajani
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Patent number: 5582714Abstract: A process is disclosed for the removal of sulfur from petroleum fractions such as FCC gasoline by employing a solvent selected from the group consisting of a polyalkylene glycol, polyalkylene glycol ether, and mixtures thereof and having a molecular weight less than 400. The process is useful for saving energy, saving hydrogen consumption, and retaining octane. By requiring only the mild hydrotreatment of an extracted or absorbed stream concentrated with the sulfur impurities, the sulfur impurities are removed without the loss of octane resulting from conversion of either high octane olefins or aromatic components. In addition, the extract stream is a significantly smaller stream than the original feedstream.Type: GrantFiled: March 20, 1995Date of Patent: December 10, 1996Assignee: UOPInventor: Paulino Forte
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Patent number: 5199978Abstract: The present invention provides a process for removing elemental sulfur from fluids such as refined petroleum products transported through pipelines for the transportation of sour hydrocarbon streams. The sulfur-containing fluids are mixed with an inorganic caustic material, an alkyl alcohol and an organo mercaptan or sulfide compound capable of reacting with sulfur to form a fluid-insoluble polysulfide salt reaction product at ambient reaction temperatures. The treated fluid is then contacted with an adsorbent or filtered to remove the insoluble salt leaving a product of very low residual sulfur content.Type: GrantFiled: June 17, 1991Date of Patent: April 6, 1993Assignee: Exxon Research and Engineering CompanyInventors: Marc A. Poirier, Robert J. Falkiner, Daniel W. Kraemer, John B. Gilbert, Ian D. Campbell
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Patent number: 4290879Abstract: Carbonyl sulfide is removed from propane and other similar liquefied petroleum gas products by mixing liquid methanol with the untreated liquefied gas and then contacting the liquid mixture with solid potassium hydroxide.Type: GrantFiled: August 10, 1976Date of Patent: September 22, 1981Assignee: Exxon Production Research CompanyInventors: Robert M. Woodall, Eugene Damron, Martin B. Mick