With Sorption Agents Patents (Class 208/26)
  • Patent number: 10329216
    Abstract: The invention relates to a new catalytic composition for the alkylation of aromatic compounds with alcohols, or mixtures of alcohols and corresponding olefins, wherein said composition comprises a zeolite of the MTW type and is characterized in that it contains one or more alkaline metals in a total quantity which is less than or equal to 0.02% by weight. The use of said catalyst in the alkylation of aromatic compounds with alcohols, in particular benzene with isopropanol or ethanol, allows the formation, as by-product, of the aldehyde or ketone corresponding to the alcohol used, to be minimized: the formation of reaction by-products of said aldehydes or ketones having a boiling point very close to that of polyalkylation products, is therefore significantly reduced. This provides a considerable advantage in the subsequent transalkylation step for the recovery of said polyalkylates by transformation into the corresponding monoalkylates.
    Type: Grant
    Filed: October 14, 2014
    Date of Patent: June 25, 2019
    Assignee: versalis S.p.A.
    Inventors: Elena Bencini, Giovanni Antonio Fois, Roberto Buzzoni
  • Patent number: 9809739
    Abstract: The present disclosure relates to a method for regeneration of spent ion exchange resins to obtain regenerated ion-exchange resins. The regenerated ion exchange resins can efficiently reduce the total acid number (TAN) of highly acidic crude oils. The present disclosure particularly relates to a method of treatment of spent ion exchange resins using at least one non-acidic crude oil condensate and at least one polar organic solvent.
    Type: Grant
    Filed: August 19, 2014
    Date of Patent: November 7, 2017
    Assignee: RELIANCE INDUSTRIES LIMITED
    Inventors: Biswajit Shown, Swapan Ghosh, Asit Kumar Das, Suyog Subhash Salgarkar, Mukunda Madhav Baishya, Mitul Amrutbhai Ladani, Chirag Dalpatbhai Panseriya
  • Publication number: 20120152802
    Abstract: A process to increase the capacity of the adsorbent in a normal paraffin adsorption separation system is presented. A tertiary flush stream is used to improve the capacity of the simulated moving bed system by flushing residual raffinate from the feed transfer line. The flushing removes residual raffinate containing desorbent that competes with the adsorption of normal paraffins from the feedstream. The flush stream is a material that will displace fluid in the column, but will not enter the pores of the adsorbent.
    Type: Application
    Filed: December 20, 2010
    Publication date: June 21, 2012
    Applicant: UOP LLC
    Inventors: Jeffrey L. Pieper, Stephen W. Sohn, Peter M. Bernard
  • Publication number: 20100116711
    Abstract: Systems and methods for producing n-paraffins are provided. The method can include hydroprocessing at least a portion of a kerosene fraction recovered from a thermally cracked hydrocarbon product to produce a hydroprocessed kerosene product comprising n-paraffins. The n-paraffins can be separated from the hydroprocessed kerosene product to produce an n-paraffins product.
    Type: Application
    Filed: November 11, 2009
    Publication date: May 13, 2010
    Applicant: KELLOGG BROWN & ROOT LLC
    Inventors: Eric Wong, Anand Subramanian, Kiran V. Shah, Faisal Mohmand
  • Patent number: 7468126
    Abstract: The invention is directed to a method of making a small crystal SSZ-32 zeolite, known as SSZ-32X. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is dewaxed to produce an isomerized product, with increased yield of isomerized material and decreased production of light ends.
    Type: Grant
    Filed: August 24, 2006
    Date of Patent: December 23, 2008
    Assignee: Chevron U.S.A., Inc.
    Inventors: Stacey I. Zones, Guang Zhang, Kamala Krishna, Joseph A. Biscardi, Paul Marcantonio, Euthimios Vittoratos
  • Publication number: 20080035525
    Abstract: The invention relates to a zeolite of the ZSM-12 type, especially for the hydroisomerization of higher paraffins, which has a primary crystal size of <0.1 ?m; as well as a specific volume, determined by mercury porosimetry at a maximum pressure of 4000 bar, of 30-200 mm3/g in a pore radius range of 4-10 nm; and which has further been prepared from a synthesis gel composition comprising an aluminum source, precipitated silica as a silicon source, TEA+ as a template, an alkali metal and/or alkaline earth metal ion source M having the valency n; in which the molar H2O:SiO2 ratio is selected between 5 and 15. The invention further relates to a catalyst comprising the above zeolite and its use.
    Type: Application
    Filed: March 27, 2004
    Publication date: February 14, 2008
    Inventors: Gotz Burgfels, Volker Kurth, Alfred Reimer, Friedrich Schmidt, Stephan Wellach
  • Publication number: 20070284284
    Abstract: The present invention relates to new crystalline molecular sieve SSZ-75 prepared using a tetramethylene-1,4-bis-(N-methylpyrrolidinium)dication as a structure-directing agent, and its use in catalysts for hydrocarbon conversion reactions.
    Type: Application
    Filed: June 1, 2007
    Publication date: December 13, 2007
    Inventors: Stacey I. Zones, Allen W. Burton, Theodorus Ludovicus Michael Maesen, Berend Smit, Edith Beerdsen
  • Patent number: 4701254
    Abstract: A process is disclosed for removing color or color inducing impurities to petroleum derived wax by means of an adsorbent comprising a refined inorganic oxide having a pore distribution such that at least 60% of the pores possess a size of less than 350 Angstroms. Preferably, at least 90% of the pores possess a size of less than 350 Angstroms. The preferred inorganic oxide is an aluminum oxide and preferably has a surface area between 200 square meters per gram and 500 square meters per gram. A process is also disclosed for wax finishing utilizing multiple beds of refined alumina which may be operated in a swing bed fashion to intimately regenerate the refined alumina absorbent by such procedural steps as naphtha soaking, steam treating and heating in air.
    Type: Grant
    Filed: October 24, 1986
    Date of Patent: October 20, 1987
    Assignee: Shell Oil Company
    Inventors: Lawrence W. Maas, Richard A. Geiman, Charles T. Adams
  • Patent number: 4448671
    Abstract: An improved adsorptive separation process by the selective sorption properties of certain members of a novel class of zeolites is provided. The novel class of zeolites is characterized by a silica to alumina mole ratio greater than 12 and a Constraint Index within the approximate range of greater than 2 to about 12. The process of this invention involves selective separation of waxy paraffinic compounds in admixture with stocks containing paraffinic compounds, e.g. crude oils, heavy oils, distillate oils and lube base oils, by contacting the mixture with a zeolite having a SiO.sub.2 /Al.sub.2 O.sub.3 mole ratio of at least about 12 and a Constraint Index within the range of greater than 2 to about 12 to effect the selective sorption of said waxy paraffinic compounds by said zeolite.
    Type: Grant
    Filed: September 30, 1981
    Date of Patent: May 15, 1984
    Assignee: Mobil Oil Corporation
    Inventor: Ralph M. Dessau
  • Patent number: 3960703
    Abstract: Aromatic compounds can be separated from slack wax in a continuous cyclic process using a macroporous metal ion loaded cation exchange resin involving successive steps of adsorption, purge, desorption and purge.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: June 1, 1976
    Assignee: Deutsche Texaco Aktiengesellschaft
    Inventors: Maximilian Dielacher, Uwe Hansen