Paraffin Wax; Treatment Or Recovery Patents (Class 208/24)
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Patent number: 11951626Abstract: Examples described herein provide a computer-implemented method that includes determining, using a digital twin, a task to be performed based at least in part on real-time data. The method further includes initiating at least one of a drone, a collaborative robot, or a warehouse system to perform the task.Type: GrantFiled: November 4, 2020Date of Patent: April 9, 2024Assignee: BAKER HUGHES OILFIELD OPERATIONS LLCInventors: Reza Ettehadi Osgouei, Mehrdad Gharib Shirangi, Charles A. Thompson, Jr., Eliah Everhard, Jason Norman
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Patent number: 10556192Abstract: A supercritical extractor system may include extractor chambers coupled to a supercritical fluid pump and configured to receive a matrix for an extraction process and a supercritical fluid from the supercritical fluid pump, and evaporator chambers coupled to the extractor chambers and configured to output an extractant from the matrix. Each evaporator chamber may include a body defining a cavity, a cone within the cavity, and arms coupled between an inner surface of the body and the cone. The supercritical extractor system may include a condenser coupled between the evaporator chambers and the supercritical fluid reservoir, and a controller coupled to the supercritical fluid pump, the extractor chambers, and the evaporator chambers and configured to monitor a characteristic during the extraction process.Type: GrantFiled: April 18, 2017Date of Patent: February 11, 2020Assignee: AG Equipment IP Holding Co, Inc.Inventors: David L. Parker, Scott Delarvin
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Patent number: 10287513Abstract: A method for recovering synthetic oils from a feed stream, the method comprising separating at least a portion of the non-synthetic oil constituents from a commingled stream to produce a partially purified synthetic oil stream and one or more contaminant streams. Extracting at least a portion of the synthetic oil from the partially purified synthetic oil stream to produce a synthetic oil stream and a second contaminant stream.Type: GrantFiled: January 26, 2017Date of Patent: May 14, 2019Assignee: Gen III Oil CorporationInventor: Martin R. MacDonald
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Patent number: 9725408Abstract: Disclosed are methods of recovering urea from a urea/oil complex by drying the complex, combining the complex with water to form a urea solution, and removing water from the urea solution. Methods for recycling the urea in urea complexation processes are also disclosed. Also disclosed are methods of recovering polyunsaturated fatty acids or derivatives thereof from the urea/oil complexes.Type: GrantFiled: March 13, 2014Date of Patent: August 8, 2017Assignee: DSM Nutritional Products AGInventors: Weijie Wang, Paul Frederick Mugford, Theophilus Cornelus Van Den Heuvel
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Patent number: 8876918Abstract: Bio-based wax compositions contain at least one of the following components: epoxides of non-hydrogenated vegetable oils, epoxides of fatty acid esters. epoxides of tall oil fatty acid esters, chemically modified epoxides of non-hydrogenated vegetable oils, chemically modified epoxides of fatty acid esters, and chemically modified epoxides of tall oil fatty acid esters. The wax compositions can be used to produce candle sticks, container candles and/or composite materials.Type: GrantFiled: September 1, 2010Date of Patent: November 4, 2014Assignee: Galata Chemicals, LLCInventors: Andrew J. Clock, Steven McKeown, Eric Wisnefsky, Peter Frenkel
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Patent number: 8748516Abstract: The present disclosure includes a wood composite made from cellulosic particles, a binder, and a water-repelling agent. In some embodiments, the water repelling agent includes aliphatic compounds having a molecular distribution between about 16 and about 36 carbon atoms per molecule. In some embodiments, the water-repelling agent has an average molecular weight of about 220 to about 350 Daltons (solids portion). The water-repelling agent may be applied as a wax emulsion or in neat wax form. The present disclosure also relates to a method for manufacturing a wood composite as described above.Type: GrantFiled: March 31, 2009Date of Patent: June 10, 2014Assignee: Weyerhaeuser NR CompanyInventors: Jack G Winterowd, Travis E. Bjorkman, Erik M Parker
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Patent number: 8734725Abstract: A system for producing enhanced wax alternatives, including a high shear device comprising a rotor and a stator, and configured to process petroleum wax and base oil with a hydrogen-containing gas under shearing conditions to form a feedstock, wherein at least one of the rotor and the stator comprises a toothed surface; and a reactor comprising a reactor inlet and a reactor outlet, and configured for hydrogenation of the feedstock for a time sufficient to produce enhanced hydrogenated products, wherein the high shear device is in fluid communication with the reactor, whereby the feedstock is transferable therebetween.Type: GrantFiled: May 1, 2013Date of Patent: May 27, 2014Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Patent number: 8669401Abstract: A method and system for producing dispersed waxes, including a high shear mechanical device. In one embodiment, the method comprises forming a dispersion of wax globules in a carrier liquid in a high shear device prior to implementation in a waxy product. In another instance the system for producing waxy products comprises a high shear device for dispersing wax in a carrier liquid.Type: GrantFiled: April 24, 2013Date of Patent: March 11, 2014Assignee: H R D CorporationInventors: Abbas Hassan, Aziz Hassan, Gregory G. Borsinger
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Patent number: 8658018Abstract: A lubricant base oil blend having a wt % Noack volatility less than 29, comprising a) a light base oil fraction having a kinematic viscosity at 100° C. between 1.5 and 3.6, and a wt % Noack volatility both between 0 and 100 and less than a Noack Volatility Factor, and b) a petroleum-derived base oil fraction. A process to make the lubricant base oil blend having a wt % Noack volatility less than 29. Also, a pour point depressed lubricant base oil blend having a Brookfield viscosity at ?40° C. of less than 18,000 cP, comprising the light base oil fraction, a petroleum-derived base oil fraction, and a pour point depressant.Type: GrantFiled: December 20, 2006Date of Patent: February 25, 2014Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Nancy J. Bertrand, Scott C. Deskin, Brent K. Lok, Shuibo Xie, Stephen J. Miller
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Patent number: 8506888Abstract: Embodiments disclosed herein describe a system for producing enhanced wax alternatives, the system that includes a reactor having a reactor inlet and a reactor outlet; and a high shear device having a device inlet, a device outlet, a rotor, a stator, and a catalytic surface, wherein the device outlet is in fluid communication with the reactor inlet.Type: GrantFiled: November 13, 2012Date of Patent: August 13, 2013Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Patent number: 8480880Abstract: A process for making a lubricating base oil having a viscosity index of at least 110, comprising the steps of: combining a waxy light neutral base oil and a wax derived from pyrolyzing a plastics feed comprising polyethylene to form a blend; hydroisomerization dewaxing the blend; and recovering the lubricating base oil from an effluent from the hydroisomerization dewaxing step.Type: GrantFiled: January 18, 2011Date of Patent: July 9, 2013Assignee: Chevron U.S.A. Inc.Inventor: Stephen J. Miller
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Patent number: 8450539Abstract: A method and system for producing dispersed waxes, including a high shear mechanical device. In one embodiment, the method comprises forming a dispersion of wax globules in a carrier liquid in a high shear device prior to implementation in a waxy product. In another instance the system for producing waxy products comprises a high shear device for dispersing wax in a carrier liquid.Type: GrantFiled: November 6, 2009Date of Patent: May 28, 2013Assignee: H R D CorporationInventors: Abbas Hassan, Aziz Hassan, Gregory G. Borsinger
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Publication number: 20130004602Abstract: A lotion composition containing a microcrystalline wax, a fibrous structure containing such lotion composition and a method for making such fibrous structure and/or lotion composition are provided.Type: ApplicationFiled: June 29, 2012Publication date: January 3, 2013Inventors: Michael Raymond Mootz, Angela Marie Leimbach
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Publication number: 20120298126Abstract: A composition for imparting reduced ignition propensity properties to a smoking article by treating the smoking article wrapper. The composition comprising at least one phase transition substance which, upon being subjected to the heat of the smoking article burning firecone, physically transforms and at least partially fills the pores of the smoking article wrapper to reduce the permeability of the wrapper in the vicinity of the burning firecone. The reduced permeability of the wrapper in the vicinity of the firecone will permit sufficient air flow to sustain free burn, but, when the smoking article is placed on a substrate, the reduced permeability of the wrapper imparts reduced ignition propensity such that there is insufficient air flow to sustain combustion of the firecone or insufficient air flow to sustain an intensity of the burning firecone necessary to ignite the substrate.Type: ApplicationFiled: March 8, 2012Publication date: November 29, 2012Applicant: Lorillard Tobacco CompanyInventors: Alexander J. Dyakonov, Steven E. Brown, Luis A. Sanchez
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Patent number: 8273137Abstract: A middle distillate fuel composition is provided comprising (a) a middle distillate base fuel, (b) a Fischer-Tropsch derived paraffinic wax component, and (c) one or more cold flow additives; a method for formulating a middle distillate fuel composition comprising a middle distillate base fuel, comprising (i) incorporating into the base fuel a Fischer-Tropsch derived wax component. The use of a Fischer-Tropsch derived wax component in a middle distillate fuel composition, for the purpose of increasing the effect of a CFPP improver additive in the composition is disclosed.Type: GrantFiled: January 8, 2009Date of Patent: September 25, 2012Assignee: Shell Oil CompanyInventors: Mark Lawrence Brewer, Felix Balthasar, Karsten Wilbrand
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Patent number: 8192612Abstract: A base oil slate comprising three or more base oil grades having kinematic viscosities at 100° C. between about 1.8 cSt and about 30 cSt prepared from a waxy feed wherein each of the base oil grades is a base oil blend which comprises: (a) between about 0.1 wt. % and about 99.9 wt. % of a distillation fraction prepared in light block mode operation; and (b) between about 0.1 wt. % and about 99.9 wt. % of a distillation fraction prepared in medium block mode operation. Also, a base oil slate prepared from a waxy feed, said product slate comprising 3 or more base oil grades, each base oil grade having a kinematic viscosity at 100° C. between about 1.8 cSt and about 30 cSt and a VI greater than an amount defined by the equation VI=Ln(Vis100, in cSt)+95, wherein Ln(Vis100, in cSt) is the natural log of the kinematic viscosity at 100° C.Type: GrantFiled: January 28, 2010Date of Patent: June 5, 2012Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Brent K. Lok, Philip E. Quinnett, Christopher Allen Simmons
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Patent number: 8063004Abstract: A chemical composition of matter comprising a wax plasticizing agent (plasticizer) tributoxyethyl phosphate, a mixture of selected long chain fatty acids (preferably C10 to C22), and a mixture of selected low-surface tension surfactants, which when added in solution to crude oil or refined products has been shown to lower both the B.S. & W. (rag layer) and the coefficient of friction of crude oils and refined products. This chemical composition of matter is particularly useful as a wax liquefaction, dispersant, and solubilization agent for asphaltene and paraffins in crude oil and refined products. The reduction in the co-efficient of friction resulting from the addition of this product to crude oil will allow crude oil to pump through pipelines with a minimum amount of resistance due to friction (drag).Type: GrantFiled: July 21, 2005Date of Patent: November 22, 2011Assignee: Malcera, L.L.C.Inventor: Gordon K. Goldman
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Patent number: 8012342Abstract: This invention relates to lubricant base oil having high viscosity indexes and low pour points, and particularly to lubricant base oil consisting essentially of a normal paraffin and an isoparaffin, wherein (a) an average carbon number Nc in one molecule is not less than 28 but not more than 40, and (b) an average branch number Nb in one molecule calculated from a ratio of CH3 carbon to total carbon determined by 13C-NMR analysis and the average carbon number Nc in one molecule is not more than (0.2Nc?3.1) but not less than 1.5.Type: GrantFiled: March 18, 2005Date of Patent: September 6, 2011Assignee: Japan Energy CorporationInventors: Manabu Kobayashi, Katsuaki Ishida, Masayuki Saito, Hiroshi Yachi
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Patent number: 7956018Abstract: A lubricant composition includes a base oil having a consecutive number of carbon atoms and a viscosity index greater than a Viscosity Index Factor calculated by the following equation: 28×Ln(Kinematic Viscosity at 100° C.)+95. The lubricant composition also includes greater than 15 weight % detergent inhibitor (DI) additive package. The lubricant composition has a dynamic viscosity at ?35° C. of less than 6200 mPa·s, a Mini-Rotary Viscosity (MRV) at ?40° C. of less than 60,000 mPa·s, and a Cold Cranking Simulator (CCS) Viscosity at ?35° C. of less than 6200 mPa·s.Type: GrantFiled: December 10, 2007Date of Patent: June 7, 2011Assignee: Chevron U.S.A. Inc.Inventor: James A. McGeehan
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Patent number: 7951759Abstract: The present invention relates to transportable product for the transportation of paraffinic wax and methods of transporting using this transportable product. The transportable product comprises 90 to 20 weight % of a liquid comprising >50 weight % alcohol and having a true vapor pressure of ?14.7 psia when measured at 20° C., and 10 to 80 weight % of wax particles, wherein the wax particles comprise ?75 weight % of wax particles larger than 0.1 mm. The transportable product and methods of transporting according to the present invention are able to accommodate a relatively high weight % of paraffinic wax particles in the transportable product while avoiding interparticle adhesion and clumping by ensuring that the wax particles are not too small and the amount of small wax particles is not excessive.Type: GrantFiled: December 29, 2008Date of Patent: May 31, 2011Assignee: Chevron U.S.A. Inc.Inventors: Gunther H. Dieckmann, Mark R. Buetzow, Dennis J. O'Rear
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Patent number: 7951287Abstract: The present invention relates to distillate fuels or distillate fuel blend stocks comprising a blend of a Fischer-Tropsch derived product and a petroleum derived product that is hydrocracked under conditions to preserve aromatics. The resulting distillate fuel product is a low sulfur, moderately aromatic distillate fuel. The resulting distillate fuel or distillate fuel blend stock exhibits excellent properties, including good seal swell, density, and thermal stability. The present invention also relates to processes for making these distillate fuels or distillate fuel blend stocks.Type: GrantFiled: December 23, 2004Date of Patent: May 31, 2011Assignee: Chevron U.S.A. Inc.Inventors: Stephen J. Miller, Dennis J. O'Rear
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Patent number: 7875166Abstract: The invention relates to a novel and completely synthetic microcrystalline paraffin, said paraffin being obtained in a simple manner and with a high yield by the catalytic hydromerisation of paraffin FT comprising 20 to 105 carbon atoms. Said paraffins can be pasty to solid at room temperature and have a higher percentage of iso-paraffins than n-paraffins. Since they do not contain aromatic compounds they are particularly suitable for use in the pharmaceutical, cosmetic and food industries.Type: GrantFiled: May 31, 2002Date of Patent: January 25, 2011Assignees: Sasol Wax International AG, Sasol Wax GmbHInventors: Michael Matthäi, Günter Hildebrand, Helmuth Schulze-Trautmann, Thorsten Butz
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Patent number: 7862893Abstract: A granular solid wax particle, comprising a) a highly paraffinic wax having a T10 boiling point less than 427° C. and comprising at least 40 weight percent n-paraffins, and b) an inorganic powder coating on the wax particle. Also, a process for making a fuel or a base oil, comprising transporting the granular solid wax particles in a transport vessel to a distant location where the granular solid wax particles are processed into the fuel or the base oil.Type: GrantFiled: December 11, 2008Date of Patent: January 4, 2011Assignee: Chevron U.S.A., Inc.Inventors: Dennis J. O'Rear, Gunther H. Dieckmann
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Patent number: 7754066Abstract: Method for making base oil, comprising transporting a height of greater than 7.5 meters of granular solid wax particles comprising a highly paraffinic wax with defined boiling points and a powder coating to a distant location, and hydroprocessing the transported wax. Also, a method comprising: a) selecting a Fischer-Tropsch wax having a broad boiling range, b) powder coating the wax, and c) transporting and d) hydroprocessing the wax. Also, a method comprising forming inorganic powder coated granular solid wax particles that withstand heavy loads without clumping or sticking together from highly paraffinic wax, wherein the amount of powder is between 0.1 and 5 wt %, transporting, and hydroprocessing the solid wax particles.Type: GrantFiled: February 13, 2008Date of Patent: July 13, 2010Assignee: Chevron U.S.A. IncInventors: Gunther H. Dieckmann, Dennis J. O'Rear
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Patent number: 7754065Abstract: Processes for transporting wax including the steps of producing granular solid wax particles, having a powder coating, that are resistant to breakage or clumping; loading the particles into a transport vessel; transporting the particles; and unloading the particles.Type: GrantFiled: February 13, 2008Date of Patent: July 13, 2010Assignee: Chevron U.S.A. Inc.Inventors: Gunther H. Dieckmann, Dennis J. O'Rear
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Patent number: 7641786Abstract: The invention relates to a method for analyzing a lubricating oil for low temperature properties. The method utilizes 2-dimensional gas chromatography (2D GC) to determine the amounts of paraffins and isoparaffins in the oil. In particular, the method analyzes for a particular isoparaffin fraction which is correlated to low temperature performance. The compositional information thus obtained is correlated with formulated oil Mini Rotary Viscometer (MRV) properties.Type: GrantFiled: November 14, 2005Date of Patent: January 5, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Frank Cheng-Yu Wang, Lei Zhang
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Patent number: 7642095Abstract: A process for producing lube basestocks involving solvent dewaxing a waxy feed to produce at least a partially dewaxed lube oil boiling range stream and then hydrodewaxing the partially dewaxed lube oil boiling range stream to produce a lube basestock.Type: GrantFiled: November 14, 2005Date of Patent: January 5, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Frank Cheng-Yu Wang, Lei Zhang
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Patent number: 7578926Abstract: A process for producing a lubricating base oil having high oxidation stability, wherein the feed used to prepare the lubricating base oil contains at least 5 wt. % olefins, said process comprising (a) determining the weight percent of olefins present in the feed by means of 1H NMR; (b) hydroprocessing the feed under hydroprocessing conditions selected to reduce the amount of olefins present to a target value which has been pre-determined by means of 1H NMR to produce a lubricating base oil having the desired oxidation stability; and (c) collecting a lubricating base oil having the selected oxidation stability from the hydroprocessing zone.Type: GrantFiled: April 20, 2005Date of Patent: August 25, 2009Assignee: Chevron U.S.A. Inc.Inventors: Susan M. Abernathy, David R. Johnson, John M. Rosenbaum, Don Young
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Publication number: 20090152163Abstract: An initial chemical composition comprising selected surfactants, dispersants, and degreasers that liquefy, disperse, demulsify, degrease, inhibit corrosion and scale formation, and lower the pour point of a petroleum, coal, Fischer-Tropsch synthesized, or naturally occurring paraffin-based wax and asphaltene. Such a product is capable of converting crystalline wax (paraffin) in, for example, slop oil into an amorphous form of wax at room temperature, allowing the wax to be dissolved in, for example, crude oil without the need for heating, and maintaining it in solution at room temperature, substantially reducing, indeed in some applications, preventing, for example, wax build-up in pipelines, processing and transportation equipment, etc., and the recovery of the hydrocarbons in the slop oil. In a second aspect of the invention, the pre-blend addition of a hydrotrope-demulsifier, a chelating agent and a wax plasticizer can result in a BS&W of zero for the recovered hydrocarbon blend.Type: ApplicationFiled: November 10, 2008Publication date: June 18, 2009Inventor: Gordon K. Goldman
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Patent number: 7531081Abstract: A lubricating base oil composition having at least 95 wt % saturates, of which saturates fraction between 10 and 30 wt % are cyclo-paraffins and the remainder being n- and iso-paraffins, having a viscosity index of above 120 and a pour point of below ?15° C.Type: GrantFiled: February 13, 2002Date of Patent: May 12, 2009Assignee: Shell Oil CompanyInventors: Mervyn Frank Daniel, Gilbert Robert Bernard Germaine, David John Wedlock
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Patent number: 7402236Abstract: A process for producing one or more white oils, by: a) hydroisomerization dewaxing a waxy feed with a defined composition over a highly selective and active wax hydroisomerization catalyst with a defined composition under conditions sufficient to produce a white oil; and b) collecting one or more white oils, wherein the yield of white oils is high, and they have a low pour point and a good Saybolt color. Also, a process for producing medicinal grade white oils, by a)hydroisomerization dewaxing a waxy feed with a defined composition over a highly selective and active wax hydroisomerization catalyst with a defined composition under conditions sufficient to produce a white oil, b) collecting technical grade white oils having a low pour point and good Saybolt color in high yield, and c) hydrofinishing the technical grade white oils at conditions sufficient to produce medicinal grade white oils that pass the RCS test.Type: GrantFiled: July 22, 2004Date of Patent: July 22, 2008Assignee: Chevron USAInventors: Stephen J. Miller, Susan M. Abernathy, John M. Rosenbaum
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Publication number: 20080073248Abstract: A heat transfer oil, comprising a base oil made from a waxy feed, wherein the base oil has a low pour point, low aromatics, and defined cycloparaffin composition. The heat transfer oil has high AIT and VI, and is an ISO viscosity grade. A process to prepare heat transfer oil, comprising: hydroisomerization of wax feed to make fraction(s) of base oil having low pour point, defined cycloparaffin composition, and high ratio of monocycloparaffins to multicycloparaffins; and blending the fractions with <0.2 wt % antifoam agent. A method to use heat transfer oil, comprising selecting heat transfer oil having high AIT and VI that is made with base oil having defined cycloparaffin composition, providing the heat transfer oil to mechanical system, and transferring heat from heat source to heat sink. Also, heat transfer oil comprising isomerized Fischer-Tropsch derived base oil with a low traction coefficient, and an antifoam agent.Type: ApplicationFiled: September 26, 2006Publication date: March 27, 2008Inventors: Ravindra Shah, John M. Rosenbaum, Nancy J. Bertrand
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Publication number: 20080067129Abstract: Disclosed herein is a method for treating hydrocarbon fluids to inhibit the deposition of paraffin compounds on the interior of pipes and other surfaces. The method includes injecting a catalyst fluid containing scale forming compounds into the hydrocarbon fluid. The scale forming compounds may be calcium carbonate, calcium bicarbonate, calcium, bicarbonate barium sulfate, or other compounds/ingredients. The catalyst fluid may be an aqueous or non-aqueous solution. The method further includes inducing an electromagnetic field in the fluid so as to cause the formation of seed crystals from the scale forming compounds. The paraffin will then adhere to the seed crystals, i.e., scale particles. The resulting particles can then be filtered out or otherwise removed from the solution. Paraffin deposition on the interior of pipes and other surfaces is therefore inhibited. Also disclosed herein are hydrocarbon wells and other piping systems constructed to take advantage of the described techniques.Type: ApplicationFiled: September 14, 2006Publication date: March 20, 2008Applicant: WEATHERFORD/LAMB, INC.Inventors: MICHAEL JUENKE, LAWRENCE RZEZNIK
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Patent number: 7214307Abstract: A composition of white oil having a kinematic viscosity at 100° C. between about 1.5 cSt and 36 cSt, a viscosity index greater than an amount calculated by the equation: Viscosity Index=28×Ln(the Kinematic Viscosity at 100° C.)+105, less than 18 weight percent of molecules with cycloparaffin functionality, a pour point less than zero degrees C., and a Saybolt color of +20 or greater. Also, a composition of white oil having a kinematic viscosity at 100° C. between about 1.5 cSt and 36 cSt, a viscosity index greater than an amount calculated by the equation: Viscosity Index=28×Ln(the Kinematic Viscosity at 100° C.)+95, between 5 and less than 18 weight percent of molecules with cycloparaffin functionality, less than 1.2 weight percent molecules with multicycloparaffin functionality, a pour point less than zero degrees C., and a Saybolt color of +20 or greater.Type: GrantFiled: July 22, 2004Date of Patent: May 8, 2007Assignee: Chevron U.S.A. Inc.Inventors: Stephen J. Miller, Susan M. Abernathy, John M. Rosenbaum
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Patent number: 6790386Abstract: A dielectric fluid comprises an isoparaffinic base oil and hydrogen donor compound. The base oil may be a hydroisomerized isoparaffinic oil, and the hydrogen donor may be a substituted, or partially saturated aromatic compound. The resulting dielectric fluid exhibits negative hydrogen gassing properties along with good oxidative stability and low temperature performance.Type: GrantFiled: April 2, 2002Date of Patent: September 14, 2004Assignee: Petro-CanadaInventors: Michael Fefer, Tomoki Ruo
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Patent number: 6787022Abstract: A process for the production of a winter diesel fuel from wax containing hydrocarbons produced by the Fischer-Tropsch hydrocarbon synthesis process. A 300° F.+ Fischer-Tropsch fraction is upgraded first by hydroisomerization followed by catalytic dewaxing resulting in a diesel fuel suitable for use as a winter diesel fuel having excellent cold flow properties and reduced emissions.Type: GrantFiled: May 2, 2000Date of Patent: September 7, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Paul Joseph Berlowitz, Daniel Francis Ryan, Robert Jay Wittenbrink, W. Berlin Genetti, Jack Wayne Johnson
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Patent number: 6695965Abstract: A wax blending process is disclosed which retains the desirable properties of a Fischer-Tropsch wax, while adjusting the hardness of the wax to within to a desired range. The invention utilizes a synergistic effect between hard virgin Fischer-Tropsch wax and softer mildly isomerized Fischer-Tropsch wax in a blending process which allows the artisan to adjust the hardness of a wax product to within desired ranges. The process involves passing a Fischer-Tropsch wax over a hydroisomerization catalyst under predetermined conditions including relatively mild temperatures such that chemical conversions (e.g., hydrogenation and mild isomerization) take place while less than 10% boiling point conversion (hydrocracking) occurs, thus preserving overall isomerized wax yield.Type: GrantFiled: April 4, 2000Date of Patent: February 24, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Robert J. Wittenbrink, Daniel Francis Ryan
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Patent number: 6635681Abstract: A process is disclosed for preparing a finished fuel product from a stabilized product mixture, which is produced from the effluent of a Fischer-Tropsch synthesis process. In the process, a Fischer-Tropsch synthesis process is conducted at a site which is remote from the market site where the products from the process are ultimately marketed. The Fischer-Tropsch effluent product is hydroprocessed, and the hydroprocessed effluent separated to remove a C4− fraction and to yield a stabilized product mixture which can be exported to the market site. At the market site, the stabilized product mixture is fractionated into at least one finished fuel product. A heavy fraction may also be recovered at the market site for separation into at least one lubricating oil base stock and then conversion at hydroisomerization conditions to form a lubricating base oil.Type: GrantFiled: May 21, 2001Date of Patent: October 21, 2003Assignee: Chevron U.S.A. Inc.Inventors: Richard O. Moore, Jr., Mark Schnell
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Publication number: 20030057132Abstract: A hydrocarbon wax product from a hydrocarbon synthesis slurry comprising liquid synthesis product and catalyst particles is purified by introducing a portion of hydrocarbon synthesis slurry from a hydrocarbon synthesis zone to a treatment zone in which a treatment gas contacts the hydrocarbon synthesis slurry. Hydrogen or a hydrogen-containing gas is useful as the treatment gas. The gas treatment removes impurities from the hydrocarbon wax portion of the hydrocarbon synthesis slurry. Purified wax product is separated and removed in situ via wax withdrawal means. This avoids or minimizes the need for further treating the wax product.Type: ApplicationFiled: August 23, 2002Publication date: March 27, 2003Inventors: Robert Jay Wittenbrink, Loren Leon Ansell, Daniel Francis Ryan, Louis Francis Burns
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Patent number: 6431253Abstract: When a waste wax composition containing a filler is treated so that the filler is recovered and thus reclaimed, almost all the impurities coming from the lost wax casting mold may be removed, thereby recovering and thus refining at a high purity, a filler of a lost wax composition. Crude reclaimed filler is first produced by dissolving and dispersing a waste wax composition in an organic solvent, and separating a dissolved wax phase from a solids/wax-containing fraction. The crude reclaimed filler is then dispersed in an aqueous alkaline solution, so as to dissolve and thus remove alkali-soluble impurities, followed by a water-washing process.Type: GrantFiled: December 4, 2001Date of Patent: August 13, 2002Assignee: Kawasaki Steel Techno-Research CorporationInventor: Tsuneo Kinjo
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Patent number: 6420618Abstract: A premium synthetic lubricating oil base stock having a high VI and low pour point is made by hydroisomerizing a Fischer-Tropsch synthesized waxy, paraffinic feed wax and then dewaxing the hydroisomerate to form a 650-750° F.+ dewaxate. The waxy feed has an initial boiling point in the range of about 650-750° F., from which it continuously boils up to at least 1050° F. and has a T90−T10 temperature difference of at least 350° F. The feed is preferably hydroisomerized without any pretreatment, other than optional fractionation. The 650-750° F.+ dewaxate is fractionated into two or more base stocks of different viscosity.Type: GrantFiled: April 28, 2000Date of Patent: July 16, 2002Assignee: ExxonMobil Research and Engineering CompanyInventors: Paul J. Berlowitz, Jacob J. Habeeb, Robert J. Wittenbrink
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Patent number: 6365037Abstract: A process for producing a low pour-point oil which permits the production of a lower pour point oil without severer hydrodewaxing conditions is disclosed, which comprises hydrodewaxing a mineral oil fraction, which has been separated from a crude oil by distillation and has a boiling point ranging from 250 to 600° C., at a temperature range of from 250° C. to 500° C. in the presence of a zeolite catalyst; and separating a lighter fraction by distillation.Type: GrantFiled: December 15, 1998Date of Patent: April 2, 2002Assignee: Japan Energy CorporationInventors: Kazumitu Fujihara, Yoshiyuki Morishima
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Patent number: 6352098Abstract: When a waste wax composition containing a filler is treated so that the filler is recovered and thus reclaimed, almost all the impurities coming from the lost wax casting mold may be removed, thereby recovering and thus refining at a high purity, a filler of a lost wax composition. Crude reclaimed filler is first produced by dissolving and dispersing a waste wax composition in an organic solvent, and separating a dissolved wax phase from a solids/wax-containing fraction. The crude reclaimed filler is then dispersed in an aqueous alkaline solution, so as to dissolve and thus remove alkali-soluble impurities, followed (or preceded) by dispersion in an acidic aqueous solution so as to dissolve and thus remove acid-soluble impurities.Type: GrantFiled: September 12, 2000Date of Patent: March 5, 2002Assignee: Kawasaki Steel Techno-Research CorporationInventor: Tsuneo Kinjo
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Patent number: 6294076Abstract: The invention is a process for producing a mixture of Fischer-Tropsch product that is solid at ambient conditions (between 32° F. and 95° F.), such as wax, and hydrocarbon liquid, such as naphtha, that can be pumped at ambient temperature (between 32° F. and 95° F.). The temperature of the mixture is controlled below the melting point of the Fischer-Tropsch product. The present invention provides for the transport of Fischer-Tropsch product from a remote location in a readily available medium, such as naphtha, via pipeline, tanker or railcar. At the completion of the transport, the hydrocarbon liquid and Fischer-Tropsch product are separated by conventional methods such as flashing, distillation, or filtration with minimal contamination from the hydrocarbon liquid.Type: GrantFiled: April 21, 2000Date of Patent: September 25, 2001Assignee: ExxonMobil Research and Engineering CompanyInventors: W. B. Genetti, L. L. Ansell, Daniel F. Ryan, Paul J. Berlowitz
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Patent number: 6268401Abstract: The invention is a process for producing a mixture of wax and crude oil which can be pumped at ambient temperature. The wax is preferably a Fisher-Tropsch wax. The temperature of the crude oil is controlled to a level below the dissolution temperature of the wax. The wax crystals are homogenized and dispersed into the crude oil to form a mixture. The present invention prevents the wax from dissolving in the crude oil and subsequently re-crystallizing at lower temperatures which can substantially increase the viscosity of the mixture thereby decreasing the effectiveness of transporting the mixture.Type: GrantFiled: April 21, 2000Date of Patent: July 31, 2001Assignee: ExxonMobil Research and Engineering CompanyInventors: Bruce R. Cook, Eric B. Sirota, Hu Gang, Loren L. Ansell
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Patent number: 6074548Abstract: A process for fractional crystallization of paraffin from mineral oil based and synthetic crude paraffin, wherein crude paraffin having a high oil content is crystallized in a crystallizer equipped with perforated metal sheets (31) extending in a zig-zag in the spaces between the heat exchanger surfaces (39). The paraffin-containing melt is only solidified to an extent such that the fractions and oils for discharge remain liquid and are run off without total solidification of the melt. The perforated sheets (31) support the layers of crystals (43) and during sweating the paraffin is detached in strips from the heat exchanger surface (39) and is adapted to rest on the sloping perforated sheets (31). The inclination of the perforated sheets (31) guides and moves the paraffin strips (53), so that the paraffin strips remain in contact with the heat exchanger surfaces (39) while being pressed by their own weight along the inclined surface (30) towards the heat exchanger surfaces (39).Type: GrantFiled: July 16, 1998Date of Patent: June 13, 2000Assignees: Schumann Sasol GmbH & Co. KG, Sulzer Chemtech AGInventors: Norbert Matzat, Gunther Hildebrand, Ferdinand Richter, Manfred Stepanski, Florian Lippuner, Herbert Engstler, Bernhard J. Jans
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Patent number: 6066250Abstract: A used investment casting wax composition containing a filler and/or a residue after a wax component is removed from the composition is dissolved or dispersed into an organic solvent. The mixture is separated into a dissolved wax fraction and a wax-containing solids fraction. The organic solvent in the dissolved wax fraction is removed to recover a wax component, while the wax component and the organic solvent in the wax-containing solids fraction are removed to recover a crude filler. The crude filler is washed with water and/or an aqueous alkaline solution to recover a high-purity filler. A reclaimed investment casting wax thus obtainable is less degraded by heat.Type: GrantFiled: November 5, 1998Date of Patent: May 23, 2000Assignee: Kawasaki Steel Techno-Research CorporationInventor: Tsuneo Kinjo
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Patent number: 6042715Abstract: A thermodynamic model is formed which allows determination of the temperature at which waxes or paraffins appear in petroleum fluids, and notably in crudes, as well as the solid fraction that precipitates when the temperature of the petroleum fluid falls below this critical value. A differentiation is established between n-paraffins, iso-paraffins, naphthenes and aromatics. The model utilizes an analytical representation of the fluids by pseudo-components, the physico-chemical parameters of most of them being determined by combination of the corresponding parameters of a certain number of pure hydrocarbons gathered in a database. The model takes account of the non-ideality of the solid, liquid, and gas phases. Two of the pseudo-constituents including the heaviest fractions are represented by two ficticious molecules, each being defined by a molar distribution among various groups which constitute them, and a group contribution method is used to calculate the thermodynamic properties thereof.Type: GrantFiled: September 16, 1997Date of Patent: March 28, 2000Assignee: Institut Francais du PetroleInventors: Sandra Calange, Veronique Ruffier-Meray, Emmanuel Behar
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Patent number: 6013171Abstract: A process for dewaxing waxy hydrocarbonaceous materials, such as hydrocarbon fuel and lubricating oil fractions to reduce their cloud and pour points comprises reacting the material with hydrogen in the presence of a dewaxing catalyst comprising at least one metal catalytic component and ferrierite in which at least a portion of its cation exchange positions are occupied by one or more trivalent rare earth metal cations. The rare earth ion exchanged ferrierite catalyst has good selectivity for lubricating oil production, particularly when dewaxing a Fischer-Tropsch wax hydroisomerate. Preferably at least 10% and more preferably at least 15% of the ferreirite cation exchange capacity is occupied by one or more trivalent rare earth metal cations.Type: GrantFiled: February 3, 1998Date of Patent: January 11, 2000Assignee: Exxon Research and Engineering Co.Inventors: Bruce R. Cook, Jack W. Johnson, Guang Cao, Rich A. McEvoy, Richard H. Ernst
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Patent number: 6008164Abstract: The instant invention is directed to a method for producing a lubricating base stock having a preselected oxidative stability comprising the steps of: (a) separating, into a plurality of fractions based on molecular shape, a hydroisomerized hydrocarbon wax, (b) collecting the fractions of step (a) which have the preselected oxidative stability for use as a lubricating base stock, wherein the fractions to be collected are determined by measuring the oxidative stability of each of said fractions of said plurality of fractions to determine which fractions have said preselected oxidative stability. The invention is also directed to an improved lubricating base oil and a formulated lubricating composition using said lubricating base oil.Type: GrantFiled: August 4, 1998Date of Patent: December 28, 1999Assignee: Exxon Research and Engineering CompanyInventors: Haven Scott Aldrich, Robert Jay Wittenbrink