Halogen Contaminant Removal Patents (Class 208/262.1)
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Patent number: 10722833Abstract: A process is described for removing halogen compounds, particularly chlorine compounds, from a process fluid, comprising the steps of (i) passing a process fluid containing hydrogen halide over a first sorbent to remove hydrogen halide and generate a hydrogen halide depleted process fluid and then, (ii) passing the hydrogen halide depleted process fluid over a second different sorbent to remove organic halide compounds therefrom. A purification system suitable for removing hydrogen halide and organic halide compounds from process fluids is also described.Type: GrantFiled: September 12, 2018Date of Patent: July 28, 2020Assignee: Johnson Matthey Public Limited CompanyInventors: Colin Baptist, Claire Cahill, Matthew John Cousins, David Davis, Michelle Taylor Wilson, Christopher John Young
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Patent number: 10381170Abstract: In an example of a method, a halogenide-hydrocarbon, an aprotic hydrocarbon solvent, and a reductant are combined to initiate a reaction that forms intermediate particles having a microporous framework. The intermediate particles are subjected to a heat treatment at a heat treatment temperature ranging from about 300° C. to less than 1500° C. for a heat treatment time period ranging from about 20 minutes to about 10 hours to form a precursor to microporous carbon.Type: GrantFiled: March 29, 2017Date of Patent: August 13, 2019Assignee: GM Global Technology Operations LLCInventors: Fang Dai, Jingmei Shen, Mei Cai, Anne M. Dailly
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Patent number: 9982200Abstract: A method for removing chloride impurities from a heavy hydrocarbon stream is disclosed. The heavy hydrocarbon stream is contacted with a stripping medium at a temperature ranging between 100-450° C. and at a pressure ranging between 0.1-2 bar with ratio of the heavy hydrocarbon stream to the stripping medium ranging between 1-30; wherein the temperature is maintained below the initial boiling point of the hydrocarbon stream.Type: GrantFiled: July 10, 2013Date of Patent: May 29, 2018Assignee: Reliance Industries LimitedInventors: Mahesh Gopalrao Marve, Amit Kumar Parekh, Asit Kumar Das, Rajeshwer Dongara, Devpal Singh Rana, Harender Bisht, Hitesh Kumar Sahu, Jai Kumar Singh, Kalyan Nath, Manoj Yadav, Sampath Nerivetla, Sukumar Mandal
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Patent number: 9944578Abstract: The present invention provides a process for the preparation of a (hydro)(chloro)fluoroalkene by contacting a reagent stream comprising a hydrochlorofluoroalkane with a catalyst in a reactor to dehydrochlorinate at least a portion of the hydrochlorofluoroalkane to produce a product stream comprising the (hydro)(chloro)fluoroalkene and hydrogen chloride (NCI), wherein the catalyst is selected from the group consisting of metal oxide catalysts, metal halide catalysts, zero-valent metal catalysts, carbon-based catalysts and mixtures thereof, and wherein (i) the catalyst is chlorinated prior to contacting it with the reagent stream comprising the hydrochlorofluoroalkane; and/or (ii) the contacting step is carried out in the presence of a HCI co-feed.Type: GrantFiled: July 27, 2015Date of Patent: April 17, 2018Assignee: MEXICHEM AMANCO HOLDING S.A. DE C.V.Inventors: Andrew Paul Sharratt, Claire Nicola Rees, Maxine Doran
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Patent number: 9862785Abstract: A method for producing an olefin polymer, in which an olefin compound is polymerized in the presence of a Lewis acid catalyst at a temperature of 0° C. or lower to obtain an olefin polymer, the method comprising a step of feeding a raw material liquid including the olefin compound to a reactor provided with a cooling unit, a step of polymerizing the olefin compound in the reactor to obtain a reaction liquid including the olefin polymer, a deactivation step of adding a deactivator to the reaction liquid taken out from the reactor to deactivate the Lewis acid catalyst, and a step of supplying the reaction liquid after the deactivation step to a cold recovery unit to recover cold from the reaction liquid, wherein the amount of the Lewis acid catalyst is 0.5×10?3 to 1.0×10?1 mol % based on the total amount of the olefin compound.Type: GrantFiled: February 20, 2015Date of Patent: January 9, 2018Assignee: JX NIPPON OIL & ENERGY CORPORATIONInventors: Tatsuya Chiba, Koichi Sato, Teruhisa Kuroki, Ryuichiro Furusawa, Takeshi Omata
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Patent number: 9850437Abstract: Herein disclosed is a method of producing value-added product from light gases, the method comprising: (a) providing light gases comprising at least one compound selected from the group consisting of C1-C6 compounds and combinations thereof; (b) intimately mixing the light gases with a liquid carrier in a high shear device to form a dispersion of gas in the liquid carrier, wherein the dispersion is supersaturated with the light gases and comprises gas bubbles at least some of which have a mean diameter of less than or equal to about 5 micron(s); (c) allowing the value-added product to form and utilizing vacuum to extract unreacted light gases from the liquid carrier; (d) extracting the value-added product; wherein the value-added product comprises at least one component selected from the group consisting of higher hydrocarbons, hydrogen, olefins, alcohols, aldehydes, and ketones. A system for producing value-added product from light gases is also disclosed.Type: GrantFiled: August 20, 2014Date of Patent: December 26, 2017Assignee: H R D CorporationInventors: Abbas Hassan, Aziz Hassan, Rayford G. Anthony, Gregory G. Borsinger
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Patent number: 9815043Abstract: This application provides an apparatus for making a hydrocarbon with a reduced amount of an organic halide, comprising: a. a process unit comprising an effluent port, that produces and discharges the hydrocarbon comprising the organic halide; and b. a halide removal vessel with an inlet that feeds the hydrocarbon from the process unit, wherein the halide removal vessel comprises an anhydrous metal chloride and in which the hydrocarbon comprising the organic halide is contacted with the anhydrous metal chloride under anhydrous conditions to produce a contacted hydrocarbon having from 50-100 wt % of a total halide in the hydrocarbon removed.Type: GrantFiled: April 20, 2015Date of Patent: November 14, 2017Assignee: Chevron U.S.A. Inc.Inventor: Howard Steven Lacheen
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Patent number: 9765263Abstract: Dehydration method for a liquid or gaseous effluent selected from LPG, gasoline, diesel, kerosene, solvents and natural gases, by inserting the liquid or gaseous effluent against gravity through a drying column having a drying bed with an initial height (H+h) constituted in its lower area by an inert material bed having the height of h and in its upper area by deliquescent desiccants having an initial height of H. The deliquescent desiccants have an initial weight of between 3 and 40 g, the h/H ratio is lower than 0.49, and the inert material has a specific surface area greater than 100 m2/m3 and lower than 800 m2/m3. The method further includes separating water obtained from the liquid or gaseous effluent.Type: GrantFiled: July 4, 2013Date of Patent: September 19, 2017Assignee: QUADRIMEX CHEMICAL SASInventors: Maxime Vassieu, Jean-Claude Chinh
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Patent number: 9744392Abstract: The present application relates to methods for the reduction of halogenated hydrocarbons using compounds of Formula (I): wherein the reduction of the halogenated compounds is carried out, for example, under ambient conditions without the need for a transition metal containing co-factor. The present application also relates to methods of recovering precious metals using compounds of Formula (I) that are absorbed onto a support material.Type: GrantFiled: February 23, 2017Date of Patent: August 29, 2017Assignee: UNIVERSITY OF GUELPHInventors: Michael K. Denk, Nicholas Milutinovic, Katherine Marczenko
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Patent number: 9745518Abstract: Methods are provided for enhancing oxidative molecular weight reduction in a hydrocarbon-containing material. For example, some methods include (a) providing a first hydrocarbon-containing material comprising a first hydrocarbon, said first hydrocarbon-containing material having been exposed to irradiation from a beam of particles, the beam of particles imparting one or more functional groups to said first hydrocarbon containing material; and (b) oxidizing the first hydrocarbon-containing material with one or more oxidants in the presence of one or more compounds comprising one or more naturally-occurring, non-radioactive group 5, 6, 8, 9, 10 or 11 elements, the one or more elements participating in a Fenton-type reaction while oxidizing, to produce a second hydrocarbon-containing material comprising a second hydrocarbon, the second hydrocarbon having a molecular weight lower than that of the first hydrocarbon, the functional groups enhancing the effectiveness of the oxidizing reaction.Type: GrantFiled: July 25, 2016Date of Patent: August 29, 2017Assignee: XYLECO, INC.Inventors: Marshall Medoff, Thomas Craig Masterman
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Patent number: 9663421Abstract: A method can include reacting a stream including one or more C3 to C10 alkanes with bromine in a bromination reactor to form a bromination reactor discharge stream that includes alkylbromides and HBr. The method further includes coupling the alkylbromides in a coupling reactor to form a coupling reactor effluent comprising alkylbromides having between 5 and about 1000 carbon atoms, olefins having between 5 and about 1000 carbon atoms and HBr. The method also includes hydrogenating the alkylbromides having between 5 and about 1000 carbon atoms and olefins having between 5 and about 1000 carbon atoms to form alkanes having between 5 and about 1000 carbon atoms and HBr.Type: GrantFiled: June 24, 2014Date of Patent: May 30, 2017Assignee: REACTION35, LLCInventors: Jeffrey H. Sherman, Peter Stoimenov
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Patent number: 9580770Abstract: A process is provided for preparing a spent noble metal fixed-bed catalyst for precious metals recovery, comprising: a) adding the catalyst to a caustic solution to wash the spent catalyst and to make a wash slurry having an alkaline pH, wherein the spent catalyst has been in contact with chloroaluminate ionic liquid catalyst, and wherein the spent catalyst comprises from 5 to 35 wt % chloride; and b) filtering the wash slurry and collecting: i) a filter cake having from at least 70 wt % of the chloride in the spent catalyst removed and having the noble metals retained, and ii) a wash filtrate. Also provided is a filter cake comprising a washed consolidated cake having 40 to 75 wt % solids, a cake moisture content from 25 to less than 60 wt %, 0.1 to 1.5 wt % total noble metals, and a residual chloride content of from zero to less than 4 wt %.Type: GrantFiled: October 22, 2014Date of Patent: February 28, 2017Assignee: Chevron U.S.A. Inc.Inventors: Rahul Shankar Bhaduri, Hye Kyung Cho Timken, Philip Ian Cuspard
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Patent number: 9467787Abstract: A hearing aid has a coupling structure, a first hearing aid housing portion and a second hearing aid housing portion including a flexible material so that the second hearing aid housing portion is adaptable to different ear canal size. The second hearing aid housing portion is detachably coupled to the first hearing aid housing portion via the coupling structure.Type: GrantFiled: June 16, 2009Date of Patent: October 11, 2016Assignee: Sivantos Pte. Ltd.Inventors: Yew Yee Marcus Lim, Kok Hong Ng
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Patent number: 8969645Abstract: We provide a process comprising: a. feeding a chlorinated-hydrocarbon and an ionic liquid catalyst to a treatment unit; b. operating the treatment unit at an elevated temperature to produce dechlorinated-hydrocarbon and HCl; and c. collecting the dechlorinated-hydrocarbon, wherein at least 90 wt % of the chlorides are removed. A second process comprises: a. creating an ionic liquid catalyst-rich zone in a distillation unit; b. passing chlorinated-hydrocarbon to the distillation unit; c. operating the unit under conditions causing removal of alkyl chloride to produce dechlorinated-hydrocarbon having a final boiling point close to a first final boiling point. A third process comprises: a. feeding alkylate gasoline blending component and ionic liquid catalyst to a treatment unit; b. operating the treatment unit; and c. collecting a dechlorinated-hydrocarbon, wherein at least 90 wt % of the chlorides have been removed and the dechlorinated-hydrocarbon has a second RON that is close to a first RON.Type: GrantFiled: December 14, 2012Date of Patent: March 3, 2015Assignee: Chevron U.S.A. Inc.Inventors: Bi-Zeng Zhan, Hye Kyung Cho Timken, Michael Sean Driver
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Publication number: 20150053589Abstract: A method for processing hydrocarbons includes providing a hydrocarbon stream including chlorides from one or more of a crude, vacuum or coker column and contacting the provided hydrocarbon stream with an adsorbent capable of adsorbing the chlorides from the hydrocarbon stream. The dechlorinated hydrocarbon stream is then provided to a hydrotreater reactor.Type: ApplicationFiled: August 21, 2013Publication date: February 26, 2015Applicant: UOP LLCInventors: Vikrant Vilasrao Dalal, Pijus Kanti Roy
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Patent number: 8795515Abstract: Processes for the catalytic dechlorination of one or more hydrocarbon products involve contacting a mixture comprising the hydrocarbon product(s) and a carrier gas with a dechlorination catalyst under catalytic dechlorination conditions to provide a dechlorinated hydrocarbon product, HCl, and the carrier gas. The dechlorinated hydrocarbon product may be separated from the HCl and the carrier gas to provide liquid fuel or lubricating base oil.Type: GrantFiled: June 28, 2011Date of Patent: August 5, 2014Assignee: Chevron U.S.A. Inc.Inventors: Bi-Zeng Zhan, Michael Driver, Hye-Kyung Timken
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Patent number: 8771501Abstract: The invention concerns a process for purification by elimination of chlorine in the form of hydrogen chloride and organochlorine compounds by contacting in the presence of hydrogen of at least a part of the effluent from a reforming, aromatics production, dehydrogenation, isomerisation or hydrogenation zone, said part of the effluent comprising olefins, hydrogen chloride and organochlorine compounds, on an elimination zone comprising a chain arrangement of two masses, the first mass being a mass comprising at least one metal from group VIII deposited on a mineral carrier and the second mass being a hydrogen chloride adsorbent.Type: GrantFiled: March 27, 2009Date of Patent: July 8, 2014Assignee: IFP Energies NouvellesInventors: Jean Cosyns, Olivier Ducreux, Quentin Debuisschert, Fabienne Le Peltier
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Patent number: 8551328Abstract: Chemically combined chlorides are removed from intermediate and product streams of a hydrocarbon reforming process by contacting the streams with zeolite 13X, having a Si/Al ratio of less than 1.25.Type: GrantFiled: June 24, 2011Date of Patent: October 8, 2013Assignee: BASF CorporationInventors: Alfonse Maglio, Richard T. McCaffrey
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Patent number: 8536393Abstract: The present invention provides an integrated process for producing aromatic hydrocarbons and/or C4+ non-aromatic hydrocarbons from low molecular weight alkanes, which includes contacting the low molecular weight alkanes with a halogen and coupling the monohaloalkanes to form aromatic hydrocarbons and/or C4+ non-aromatic hydrocarbons.Type: GrantFiled: May 11, 2010Date of Patent: September 17, 2013Assignee: Shell Oil CompanyInventors: Wayne Errol Evans, Glenn Charles Komplin, Duraisamy Muthusamy
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Patent number: 8487155Abstract: The removal of fluoroalkanes from fluoroalkane-containing hydrocarbon streams, preferably C3 to C5 hydrocarbon streams. The fluoroalkane-containing hydrocarbon stream is contacted with an adsorbent containing a strong acid function, preferably a silica gel or a strong cation ion-exchange resin having sulfonic acid functionality.Type: GrantFiled: December 7, 2010Date of Patent: July 16, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Kenneth A. Boateng, Marc-Andre Poirier
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Patent number: 8480988Abstract: The present invention is a method for synthesizing non-zeolitic molecular sieves which have a three dimensional microporous framework comprising [AlO2] and [PO2] units. In preparing the reaction mixture, a surfactant is used, coupled with non-aqueous impregnation to prevent acid sites from being destroyed by water during Pt impregnation. The superior SAPO exhibits higher activity and selectivity especially in catalytic hydroisomerization of waxy feeds, due to the presence of medium-sized silica islands distributed throughout the SAPO.Type: GrantFiled: December 12, 2012Date of Patent: July 9, 2013Assignee: Chevron U.S.A. Inc.Inventor: Stephen Joseph Miller
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Publication number: 20130001133Abstract: Processes for the catalytic dechlorination of one or more hydrocarbon products involve contacting a mixture comprising the hydrocarbon product(s) and a carrier gas with a dechlorination catalyst under catalytic dechlorination conditions to provide a dechlorinated hydrocarbon product, HCl, and the carrier gas. The dechlorinated hydrocarbon product may be separated from the HCl and the carrier gas to provide liquid fuel or lubricating base oil.Type: ApplicationFiled: June 28, 2011Publication date: January 3, 2013Applicant: Chevron U.S.A. Inc.Inventors: Bi-Zeng Zhan, Michael Driver, Hye-Kyung Timken
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Publication number: 20120325724Abstract: Processes for the rejuvenation of a spent adsorbent, wherein the adsorption capacity of the spent adsorbent may be repeatedly restored by treating the spent adsorbent with a basic solution and subsequent adsorbent activation, thereby allowing a plurality of adsorption cycles using a single adsorbent sample. Processes for ionic liquid catalyzed hydrocarbon conversion and hydrocarbon product purification are also disclosed.Type: ApplicationFiled: June 27, 2011Publication date: December 27, 2012Inventors: Michael S. Driver, Hye Kyung Timken
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Patent number: 8237004Abstract: A process for making products with low hydrogen halide, comprising: a) stripping or distilling an effluent from a reactor into a first fraction having an amount of hydrogen halide, and a second fraction having a reduced amount of hydrogen halide; wherein the reactor comprises: an ionic liquid catalyst having a metal halide, and a hydrogen halide or an organic halide; and b) recovering one or more product streams, from the second fraction, having less than 25 wppm hydrogen halide. In one embodiment the ionic liquid catalyst has metal halide; and the recovering recovers propane, n-butane, and alkylate gasoline having less than 25 wppm hydrogen halide. In another embodiment the recovering uses a distillation column having poor corrosion resistance to hydrogen halide; and the distillation column does not exhibit corrosion. There is also provided an alkylate gasoline having less than 5 wppm hydrogen halide, a high RON, and low RVP.Type: GrantFiled: December 31, 2009Date of Patent: August 7, 2012Assignee: Chevron U.S.A. Inc.Inventors: Hye-Kyung Timken, Christine Phillips, Robert F. Cleverdon
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Publication number: 20120152807Abstract: A method for processing an acidic hydrocarbon feed comprising a hydrocarbon material and an acidic constituent soluble in the feed is provided. The method may comprise contacting the feed under a first condition with an active agent having an initial solubility in the feed and the acidic constituent and providing a second condition wherein the active agent has a secondary solubility in the feed lesser than the initial solubility to form a separable enriched active agent phase. The acidic constituent solubility in the active agent may be greater than its solubility in the hydrocarbon material under both the first and second conditions such that the acidic constituent dissolves in the active agent. The acidic constituent solubility in the active agent under the second condition may be greater than its solubility in the active agent under the first condition.Type: ApplicationFiled: August 27, 2010Publication date: June 21, 2012Applicant: SUNCOR ENERGY INC.Inventor: Richard A. McFarlane
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Patent number: 8105481Abstract: A method for reducing halide concentration in a hydrocarbon product having an organic halide content from 50 to 4000 ppm which is made by a hydrocarbon conversion process using an ionic liquid catalyst comprising a halogen-containing acidic ionic liquid comprising contacting at least a portion of the hydrocarbon product with at least one molecular sieve having pore size from 4 to 16 Angstrom under organic halide absorption conditions to reduce the halogen concentration in the hydrocarbon product to less than 40 ppm is disclosed.Type: GrantFiled: December 19, 2007Date of Patent: January 31, 2012Assignee: Chevron U.S.A. Inc.Inventors: Michael S. Driver, Howard S. Lacheen, Mitra A. Hosseini
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Patent number: 8093441Abstract: The removal of fluoroalkanes from fluoroalkane-containing hydrocarbon streams, preferably C3 to C5 hydrocarbon streams. The fluoroalkane-containing hydrocarbon stream is contacted with an adsorbent containing a strong acid function, preferably a silica gel or a strong cation ion-exchange resin having sulfonic acid functionality.Type: GrantFiled: November 6, 2009Date of Patent: January 10, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Marc-André Poirier, Robert J. Falkiner
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Patent number: 7955498Abstract: A method for reducing halide concentration in a hydrocarbon product having an organic halide content which is made by a hydrocarbon conversion process using a halogen-containing acidic ionic liquid catalyst comprising contacting at least a portion of the hydrocarbon product with an aqueous caustic solution under conditions to reduce the halide concentration in the hydrocarbon product is disclosed.Type: GrantFiled: December 16, 2008Date of Patent: June 7, 2011Assignee: Chevron, U.S.A. Inc.Inventors: Michael S. Driver, Saleh A. Elomari, Hye-Kyung C. Timken
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Patent number: 7956230Abstract: A method for reducing halide concentration in a hydrocarbon product made by a hydrocarbon conversion process using an ionic liquid catalyst comprising a halogen-containing an acidic ionic liquid comprising: (i) separating at least a portion of the hydrocarbon product from the ionic liquid catalyst used in the hydrocarbon conversion process from the hydrocarbon product; (ii) contacting at least a portion of the separated hydrocarbon product with an ionic liquid catalyst having the same formula as the ionic liquid catalyst used in the hydrocarbon conversion process; (iii) separating at least a portion of the hydrocarbon product from the ionic liquid catalyst of step (ii); and (iv) recovering at least a portion of the separated hydrocarbon product of step (iii) having a halide concentration less than the halide concentration of the hydrocarbon product of step (i) is disclosed.Type: GrantFiled: December 21, 2007Date of Patent: June 7, 2011Assignee: Chevron U.S.A. Inc.Inventors: Hye-Kyung C. Timken, Michael S. Driver, Thomas V. Harris
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Publication number: 20100320125Abstract: A method for reducing halide concentration in a hydrocarbon product having an organic halide content from 50 to 4000 ppm which is made by a hydrocarbon conversion process selected from the group consisting of polymerization, dimerization, oligomerization, acetylation, metatheses, copolymerization, isomerization, olefin hydrogenation, hydroformylation, and combinations thereof, using an ionic liquid catalyst comprising a halogen-containing acidic ionic liquid, comprising contacting at least a portion of the hydrocarbon product with at least one molecular sieve having a pore size from 4 to 16 Angstrom under organic halide absorption conditions, wherein the organic halide is absorbed during the contacting, to reduce the halogen concentration in the hydrocarbon product to less than 40 ppm.Type: ApplicationFiled: September 1, 2010Publication date: December 23, 2010Inventors: Michael Driver, Howard Lacheen, Mitra Hosseini
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Publication number: 20100282641Abstract: A process for reducing the Bromine Index of a hydrocarbon feedstock, the process comprising the step of contacting the hydrocarbon feedstock with a catalyst at conversion conditions, wherein the catalyst includes at least one molecular sieve and at least one clay, and wherein said catalyst is sufficient to reduce more than 50% of the Bromine Index of a hydrocarbon feedstock.Type: ApplicationFiled: April 23, 2010Publication date: November 11, 2010Inventors: Stephen Harold Brown, Gary David Mohr, Michael Christopher Clark, Selma Lawrence
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Publication number: 20100270212Abstract: A process for the purification of aromatic streams is provided that includes a new start up procedure that in embodiments significantly reduces impurities in an aromatics feedstock.Type: ApplicationFiled: April 8, 2010Publication date: October 28, 2010Inventor: Stephen H. Brown
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PROCESSING UNCONVENTIONAL AND OPPORTUNITY CRUDE OILS USING ONE OR MORE MESOPORE STRUCTURED MATERIALS
Publication number: 20100176032Abstract: A process for removing contaminants and breaking emulsions in a feedstream comprising a crude source composition comprising unconventional or opportunity crude oil, the process comprising: providing the feedstream comprising the crude source composition comprising unconventional or opportunity crude oil, the feedstream comprising an emulsion comprising one or more contaminants, a salt content, and a water content; and, contacting the feedstream directly with one or more mesopore structured materials and one or more demulsifiers under conditions effective to separate a majority of the water content, the salt content, and the one or more contaminants from the feedstream, thereby breaking the emulsion and producing a purified hydrocarbon phase.Type: ApplicationFiled: March 19, 2010Publication date: July 15, 2010Inventor: CHARLOTTE DROUGHTON -
Publication number: 20100032346Abstract: The present invention relates to a process for reducing the Bromine Index of a hydrocarbon feedstock having at least 50 wt. % of C8 aromatics, comprising the step of contacting the hydrocarbon feedstock with a catalyst at conversion conditions, wherein the catalyst includes a molecular sieve having a zeolite structure type of MWW.Type: ApplicationFiled: October 15, 2009Publication date: February 11, 2010Inventors: Stephen H. Brown, James R. Waldecker, Khavinet Lourvanij
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Patent number: 7645606Abstract: The present invention provides a method and gaseous composition for the in situ bioremediation of soil and groundwater contaminated with organic compounds, including halogenated hydrocarbons. The gaseous composition, which readily permeates a subsurface region, comprises hydrogen (H2) and one or more volatile phosphates, such as triethylphosphate (TEP) and tributylphosphate (TBP). The volatile phosphates serve as nutrients that stimulate the growth and activity of indigenous microbes that are capable of degrading the contaminants. The addition of hydrogen facilitates the direct reductive dehalogenation of highly halogenated contaminants. The gaseous composition may optionally contain one or more of a volatile alkane and nitrous oxide as additional supports for microbial growth, and carbon dioxide to lower the pH of remediation sites that are highly alkaline.Type: GrantFiled: March 24, 2003Date of Patent: January 12, 2010Assignee: PHA Environmental RestorationInventors: Lamar E. Priester, III, Brian Harmison, John Huff
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Publication number: 20090308759Abstract: A variety of methods and systems are disclosed herein, including, in one embodiment, a method comprising: providing a stream comprising halogenated alkanes; forming synthesis products comprising hydrocarbons and hydrogen bromide from synthesis reactants comprising at least a portion of the halogenated alkanes; and recovering at least a portion of the bromine, the recovering comprising electrolysis.Type: ApplicationFiled: June 3, 2009Publication date: December 17, 2009Applicant: MARATHON GTF TECHNOLOGY, LTD.Inventor: John J. Waycuilis
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Publication number: 20090266745Abstract: A method is provided for removing HF and organic fluorides from fluid streams in which the fluoride species exist as impurities and, in particular, from hydrocarbon fluid streams containing no more than about 1.0% by weight total fluorides. The method consists of first contacting the fluid stream first with a nonpromoted alumina and then with an adsorbent consisting essentially of activated alumina that has been treated with a promoter material selected from the oxides and phosphates of alkali metals and alkaline earth metals, and mixtures thereof. This is preferably accomplished by providing a suitable absorber vessel charged with the adsorbent in a fixed bed, and then contacting the fluoride-contaminated fluid through the fixed bed.Type: ApplicationFiled: April 23, 2008Publication date: October 29, 2009
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Patent number: 7601255Abstract: A process for reducing the level of residual catalyst comprising one or more alkylhalide, alkoxyhalide, metal halide, metal oxyhalide, alkyl metal, alkoxy metal, boron compound and coordinated metal compound wherein the metal is a Group III, Group IV, Group V, Group VI and/or Group VIII metal, from a crude organic product (e.g., polyolefins, alkylated aromatic compounds, alkylated amines, etc.) comprising the residual catalyst is provided, the process comprising contacting the crude organic product with a solid adsorbent in an adsorbent system.Type: GrantFiled: September 6, 2006Date of Patent: October 13, 2009Assignee: Chemtura CorporationInventors: Vilan Kosover, Jesus R. Fabian, Daniel C. Knowles, Mitchel Cohn
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Patent number: 7553406Abstract: This invention relates to a process for removing polarizable impurities from hydrocarbons and mixtures of hydrocarbons using ionic liquids as an extraction medium. By way of extraction, the degree of contamination of the hydrocarbon or mixture of hydrocarbons is reduced to a low or very low level. The specific ionic liquids are compounds of the Formula 1, which are organic salts that are liquid or can be melted to form a liquid and that can form at least a biphasic mixture with a hydrocarbon. The process is suitable for purifying a wide range of hydrocarbons under a wide range of process conditions.Type: GrantFiled: April 30, 2004Date of Patent: June 30, 2009Assignee: Merck Patent GmbHInventors: Peter Wasserscheid, Andreas Bösmann, Andreas Jess, Leonid Datsevich, Christoph Schmitz, Andrea Wendt
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Publication number: 20080053873Abstract: A process for reducing the level of residual catalyst comprising one or more alkylhalide, alkoxyhalide, metal halide, metal oxyhalide, alkyl metal, alkoxy metal, boron compound and coordinated metal compound wherein the metal is a Group III, Group IV, Group V, Group VI and/or Group VIII metal, from a crude organic product (e.g., polyolefins, alkylated aromatic compounds, alkylated amines, etc.) comprising the residual catalyst is provided, the process comprising contacting the crude organic product with a solid adsorbent in an adsorbent system.Type: ApplicationFiled: September 6, 2006Publication date: March 6, 2008Inventors: Vilan Kosover, Jesus R. Fabian, Daniel C. Knowles, Mitchel Cohn
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Patent number: 7196034Abstract: The invention is directed to a catalyst suitable for the hydrogenation of hydrocarbon resins, comprising a supported nickel on silica and alumina catalyst, said catalyst having a nickel content of 45 to 85 wt. %, a silicon content, calculated as SiO2, of 14 to 45 wt. %, an aluminium content, calculated as Al2O3, of 1 to 15 wt. % an iron content, calculated as Fe, 0.25 to 4 wt. %, all percentages having been calculated on the basis of the reduced catalyst, and which catalyst has a volume of pores between 2 and 60 nm, as defined herein, of at least 0.35 ml/g of catalyst.Type: GrantFiled: November 17, 2000Date of Patent: March 27, 2007Assignee: Engelhard CorporationInventor: Lucas Laurentius Kramer
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Patent number: 6998050Abstract: The present invention provides a method of treating fats and oils containing low concentrations of aromatic halogen compounds and other contaminants by contacting the fats or oils with an adsorbing agent. The adsorbing agent contains a porous body and a non-protonic polar solvent held in the interiors of fine pores in the porous body to adsorb the contaminants. In one embodiment, the porous body also carries noble metal fine particles. In another embodiment, the adsorbing body comprises a solid acid for adsorbing the contaminants and there is a step of contacting the adsorbing body with an organic solvent to extract the adsorbed contaminants into the organic solvent.Type: GrantFiled: February 5, 2003Date of Patent: February 14, 2006Assignee: Kabushiki Kaisha ToshibaInventors: Katsuhiko Nakajoh, Takehiko Muramatsu, Yukishige Maezawa, Masao Kon, Tomohiro Todoroki, Katsushi Nishizawa, Atsushi Ohara
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Patent number: 6991720Abstract: Structured catalysts comprising thick porous inorganic catalyst support coatings disposed on monolithic catalyst support structures, the support coatings having open interconnected porosities of controlled pore size but being characterized by improved durability, physical integrity, and adherence sufficient for use in liquid phase applications under harsh reaction conditions, and methods for making and using them, are disclosed.Type: GrantFiled: February 28, 2003Date of Patent: January 31, 2006Assignee: Corning IncorporatedInventors: Philippe Caze, Didier Letourneur, Paulo Marques, Christophe Remy, Pierre Woehl
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Patent number: 6979394Abstract: A process for producing a product aromatic compound is disclosed which uses an on-stream alkylation reactor and an off-stream alkylation reactor, and in which at least a portion of the feed aromatic compound in the effluent stream of off-stream alkylation reactor undergoing regeneration is passed to the on-stream alkylation reactor. An embodiment of this process that uses on-stream and off-stream aromatic byproducts removal zones is also disclosed.Type: GrantFiled: May 21, 2004Date of Patent: December 27, 2005Assignee: UOP LLCInventors: Andrea G. Bozzano, Kurt A. Detrick
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Patent number: 6902662Abstract: A method of reducing hydrolysis in a hydrocarbon stream comprising adding to a hydrocarbon stream containing a chloride compound which undergoes hydrolysis at elevated temperatures in the presence of water to form hydrochloric acid, an effective amount of a treating agent that is at least one overbased complex of a metal salt and an organic acid complexing agent, the treating agent being added to hydrocarbon stream when the stream is at a temperature below which any substantial hydrolysis of the chloride containing compound occurs.Type: GrantFiled: February 21, 2003Date of Patent: June 7, 2005Assignee: Champion Technologies, Inc.Inventors: Paul Eugene Eaton, Petrous Johannes Venter, George Burton Jones
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Publication number: 20040178125Abstract: In a method of removing an aromatic halide from oil containing the aromatic halide, the aromatic halide compound being extracted from the oil containing the aromatic halide compound safely and highly efficiently, by extraction using an extracting solvent containing 1,3-dialkyl-2-imidazolidinone which is sulfur free and has extremely high extraction separation ability, or by using an extraction solvent containing an aqueous solution of 1,3-dialkyl-2-imidazolidinone. A system of removing aromatic halide compound from oil containing the aromatic halide compound includes a first supply source of a first extracting solvent containing 1,3-dialkyl-2-imidazolidinone; a second supply source of the oil containing the aromatic halide compound; and a first extractor which extracts the aromatic halide compound from the oil containing the aromatic halide compound supplied from the second supply source, by the first extracting-solvent supplied from the first supply source.Type: ApplicationFiled: December 23, 2003Publication date: September 16, 2004Inventors: Katsuhiko Nakajoh, Takehiko Muramatsu, Masao Kon, Hiroaki Kinoshita, Tomohiro Todoroki
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Patent number: 6649044Abstract: The present invention relates to a process for the reductive dehalogenation of halogenated hydrocarbons. It comprises reacting halogenated hydrocarbons with a reducing metal and a hydrogen donating compound in the presence of an amine. Preferably, the halogenated hydrocarbons are reacted with lithium, potassium, calcium, sodium, magnesium, aluminum, zinc or iron. Depending on the metal, the complete reductive dehalogenation takes place at temperatures ranging from room temperature to 400° C.Type: GrantFiled: February 1, 2000Date of Patent: November 18, 2003Assignee: DCR International Environmental Services B.V.Inventors: Friedrich Bölsing, Achim Habekost
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Patent number: 6638488Abstract: Method and apparatus for isolating, decomposing, and fixing the organic hazardous substances in a stable manner using chemical techniques and isolating and decomposing the organic hazardous substances from various waste mixtures. The temperature treatment is preferably kept within room temperature range of between 0-30° C. The detoxification of the organic hazardous substances avoids secondary pollution of the environment when the treated materials are released in the soil, atmosphere, or in groundwater.Type: GrantFiled: March 6, 2000Date of Patent: October 28, 2003Inventors: Yukoh Akae, Kazuo Kote
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Patent number: 6576122Abstract: 1. Process for the reductive dehalogenation of liquid or solid halogenated hydrocarbons. 2.1 Toxic liquid or solid halogenated hydrocarbons such as DDT, HCH, in particular halogenated aromatics such as TCB, PCB, PCP and PCDD/PCDF as such or as contaminants in waste oil or contaminated soil or soil like materials can, in most cases, not at all be dehalogenated or, at best, on a very lavish scale. According to the present invention said halogenated hydrocarbons can be dehalogenated without any problems. 2.2 This can be achieved according to the present invention through transforming the halogenated hydrocarbons as such and the contaminated material respectively into a finely dispersed solid formulation and heating said formulation for a short time with finely dispersed reducing metals. 2.Type: GrantFiled: February 1, 2000Date of Patent: June 10, 2003Assignee: DCR International Environmental Services B.V.Inventor: Friedrich Bölsing
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Publication number: 20030032847Abstract: A substantially hydrogenated and/or substantially dehalogenated polyalphaolefin homo- or copolymer is obtained by a hydrogenation/dehalogenation process employing hydrogen and a substantially amorphous catalyst containing a metal component on an inorganic material based support. The substantially hydrogenated/dehalogenated polyalphaolefin homo- or copolymers provided herein are useful for manufacturing a variety of products including lubricating oils in which the polyalphaolefin functions as a viscosity modifier.Type: ApplicationFiled: June 4, 2001Publication date: February 13, 2003Applicant: CROMPTON CORPORATIONInventor: Michael P. Reynolds