Abstract: The invention relates to a method for producing low-odor n-butane by catalytic hydrogenation of a feed mixture. The aim of the invention is to provide such a method, wherein the feed material, in addition to n-butane, n-butene and up to 1 mass % formic acid and/or up to 1 mass % pentanals and/or up to 0.5 mass % pentanols, also comprises carbon monoxide. The aim is achieved by treating the feed mixture in the temperature range of 15 to 120° C. with an aqueous solution of an alkali metal or alkaline earth metal hydroxide in the concentration range of 0.5 to 30 mass % and subsequently subjecting the feed mixture to the catalytic hydrogenation.

Abstract: The present invention is a method of reducing the formation of fouling deposits occurring in a caustic scrubber used to remove acid gases comprising: a) providing a caustic scrubber fed with an alkaline aqueous solution comprising essentially one or more of NaOH, KOH or LiOH, b) providing an olefin-containing hydrocarbon stream, contaminated with oxygenated compounds and acid gases, and said oxygenated compounds are capable to make polymeric fouling deposits in the presence of the alkaline solution of the scrubber, c) sending the above hydrocarbon stream to the caustic scrubber to recover an olefin-containing hydrocarbon stream essentially free of acid gases, wherein, d) an efficient amount of a solvent capable to reduce the formation of fouling deposits is introduced in the caustic scrubber and/or in the alkaline solution fed to the scrubber, e) the liquid outlet of the scrubber is sent to means to separate the solvent from the alkaline solution, and wherein the caustic scrubber has several stages with vario

Abstract: A catalyst for ultra-deep desulfurization of diesel via oxidative distillation is an amphiphilic oxidative catalyst, which is expressed as Qm[XMnOq], wherein 1?m?12; 9?n?18; 34?q?62; Q is a quaternary ammonium cation; X is P, Si, As or B; and M is Mo) or W. A desulfurization method comprises a) mixing well a diesel, the amphiphilic catalyst, and hydrogen peroxide, reacting for 10-300 minutes at ambient temperature and normal pressure, transforming the sulfur-containing compounds in the diesel into sulfone to obtain an oxidized diesel; b) distilling the oxidized diesel obtained in step a) under reduced pressure to obtain the ultra-low sulfur diesel having a sulfur content of less than 10 ppm; and c) separating and recovering the catalyst and sulfone.

Abstract: A rust preventive oil composition includes at least one base oil selected from the group consisting of mineral oils and synthetic oils, having a 5%-distillation temperature of not less than 140° C. and not more than 250° C., a 95%-distillation temperature of 250° C. or less, a difference between the 5%-distillation temperature and the 95%-distillation temperature of 90° C. or less, an aromatic content of 5% by volume or less, a naphthene content of not less than 30% by volume and not more than 95% by volume, a density at 15° C. of 0.75 g/cm3 or more, and a kinematic viscosity at 40° C. of not less than 0.3 mm2/s and not more than 5.0 mm2/s; at least one base oil selected from the group consisting of mineral oils and synthetic oils; and a rust-preventing additive.

Abstract: An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs rework material obtained from a process to prepare a hydroprocessing catalyst as part of the metal precursor feed. In one embodiment, the process comprises mixing the rework material with a hydrocarbon diluent to form a slurried metal precursor for subsequent in-situ sulfiding in a heavy oil upgrade process. In another embodiment, the rework is slurried in a hydrocarbon carrier and a sulfiding agent, forming a slurry catalyst. In yet another embodiment, the rework material is mixed directly with a heavy oil feedstock under in-situ sulfiding conditions, forming a slurry catalyst.

Abstract: A method of producing a crude product from a hydrocarbon feed is provided. A hydrocarbon feed is contacted with a catalyst containing a Col. 6-10 metal or compound thereof to produce the crude product, where the catalyst has a pore size distribution with a median pore diameter ranging from 105 ? to 150 ?, with 60% of the total number of pores in the pore size distribution having a pore diameter within 60 ? of the median pore diameter, with at least 50% of its pore volume in pores having a pore diameter of at most 600 ?, and between 5% and 25% of its pore volume in pores having a pore diameter between 1000 ? and 5000 ?.

Abstract: A method of upgrading a heteroatom-containing hydrocarbon feed by removing heteroatom contaminants is disclosed. The method includes contacting the heteroatom-containing hydrocarbon feed with an oxidant to oxidize the heteroatoms, contacting the oxidized-heteroatom-containing hydrocarbon feed with caustic and a selectivity promoter, and removing the heteroatom contaminants from the heteroatom-containing hydrocarbon feed. The oxidant may be used in the presence of a catalyst.

Abstract: A process for converting feedstock into liquid hydrocarbon fuel condensate includes the steps of providing an unconventional feedstock for producing liquid hydrocarbon fuel, providing a heated heat transfer medium flowing through at least one thermal reaction zone under substantially carbon rejection process conditions and placing the feedstock onto the heated heat transfer medium flow so that the feedstock substantially rides on the flow surface of the heated heat transfer medium without substantially any mixing of the feedstock with the heat transfer medium, vaporizing at least a portion of the feedstock to form vapours while the feedstock is in the thermal reaction zones by heat transfer to the feedstock from the heat transfer medium and condensing the vapours into a liquid hydrocarbon fuel condensate.

Abstract: Reactive phosphorus species can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains water-soluble hydroxyacids. Suitable water-soluble hydroxyacids include, but are not necessarily limited to glycolic acid, gluconic acid, C2-C4 alpha-hydroxy acids, poly-hydroxy carboxylic acids, thioglycolic acid, chloroacetic acid, polymeric forms of the above hydroxyacids, poly-glycolic esters, glycolate ethers, and ammonium salt and alkali metal salts of these hydroxyacids, and mixtures thereof. The composition may optionally include a mineral acid to reduce the pH of the desalter wash water. A solvent may be optionally included in the composition. The invention permits transfer of reactive phosphorus species into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase. The composition is particularly useful in treating crude oil emulsions, and in removing calcium and other metals therefrom.

Abstract: The present invention relates to a process for removing organic silicon compounds from hydrocarbon streams by contact with an adsorbent and hydrogen. The adsorbent is composed of lamellar double hydroxides and group VI-B or group VIII hydrogenating metal. More specifically, the process of the present invention involves a stage of activation for formation of the lamellar double hydroxide, and maintaining the phase of lamellar double hydroxide by adding water.

Abstract: Metal hydride compounds, which are prepared by mixing together from about 1 to about 10 parts by molecular weight of at least one metal selected from the group consisting of silicon, aluminum, tin, and zinc; from about 1 to about 3 parts by molecular weight of an alkali metal hydroxide; and from about 5 to about 10 parts by molecular weight of water and allowing this mixture to stand for a time sufficient to form a metal hydride, can be used for making fuel additives, treating sour gas, enhancing oil refining, extracting oil from tar sands and shale, increasing production of hydrogen from a hydrogen plant, treating oil and gas wells to enhance production, eliminate PCBs, cleaning soil contaminated by hydrocarbons and/or heavy metals, controlling odors, cleaning polluting stack emissions, extracting edible and essential oils, and eliminating bacteria, fungicides, and parasites from vegetation.

Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.

Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.

Abstract: A method of reducing hydrolysis in a hydrocarbon stream comprising adding to a hydrocarbon stream containing a chloride compound which undergoes hydrolysis at elevated temperatures in the presence of water to form hydrochloric acid, an effective amount of a treating agent that is at least one overbased complex of a metal salt and an organic acid complexing agent, the treating agent being added to hydrocarbon stream when the stream is at a temperature below which any substantial hydrolysis of the chloride containing compound occurs.

Abstract: The present invention relates to a process for reducing naphthenic acid content of crude oils and its fractions in the essential absence of oxygen and in the presence of an aqueous base selected from Group IA and IIA hydroxides and ammonium hydroxide and mixtures thereof, a phase transfer agent that is a quaternary onium salt in amounts of from 10−5 to 10−1 at a temperature and pressure effective to produce a treated petroleum feed having a decreased naphthenic acid content and an aqueous phase containing naphthenate salts, phase transfer agent and base.

Abstract: The invention describes a method for decreasing the viscosity of crude oils and residuum utilizing a combination of acid and sonic treatment.

Abstract: An improved process is disclosed for removing trace acidic compounds from liquid hydrocarbons. Traces of acidic compounds, including carboxylic acids, H2S, naphthenic acids, et al., are present in most hydrocarbon streams. The presence of these acidic compounds is considered deleterious to accepted product specifications. The trace acidic compounds which interfere are removed via injection of a dilute aqueous alkaline solution into the hydrocarbon stream and passage of this stream through a coalescing bed.

Abstract: An oil, such as a mineral oil, for example, transformer oil, is contacted with calcium carbide and the mixture is stirred until a liquid phase containing less than 1 ppm water and a solid phase containing Ca(OH)2 and unreacted CaC2 are obtained. The oil obtained can be used to give samples of known quantities of water by adding corresponding amounts thereto.

Abstract: The invention provides a method of purifying hydrocarbon streams from metallic impurities which comprises passing the stream through media comprising alumina with relatively minor amounts of calcia and magnesia.

Abstract: Phosphates can be removed from a hydrocarbon stream by contacting said stream with a ceramic formed of a basic material which is insoluble in the hydrocarbon stream. A ceramic as used in this patent document is a solid solution formed by calcination of a compound. The removal of the organic acid is accomplished at temperatures ranging from 20.degree. C. to 400.degree. C., a preferred temperature is between 200.degree. C. and 370.degree. C. A hydrocarbon stream consists of C.sub.5 + hydrocarbons. The basic material can be made up of one or more alkaline earth oxides, alkaline earth compounds, alkaline metal compounds, group IIIA element compounds, group IVA element compounds, group VIA element compounds. Preferred alkaline earth oxides are sodium, magnesium, potassium, calcium, aluminum and silicon. The support for the basic material can be made from any inorganic oxide.

Abstract: Oxygenate impurities are removed from an organic chemical feed or stream by treatment with an aqueous reducing agent and aqueous base, accompanied by separation. An aqueous solution of reducing agent and an aqueous solution of base are typically introduced sequentially into the organic chemical stream, where they may react with any oxygenate impurities present. The reaction products of the oxygenate impurities and aqueous reducing agent and aqueous base are water soluble, and are typically removed in sequential fashion via any suitable separation means. For example, oxygenate impurities such as formaldehyde, acetaldehyde, propionaldehyde, and methyl formate may be removed from a propylene stream by treating the stream sequentially with aqueous sodium bisulfite and aqueous sodium hydroxide, accompanied by separation of the oxygenate impurity reaction products in coalescers.

Abstract: A method for upgrading an oil stream containing naphthenic acid and sulfur contaminants is described. In this method, an oil stream with naphthenic acid and sulfur contaminants is upgraded by the following steps. First, the oil stream is mixed with an alkaline earth metal oxide in an amount effective to convert substantially all of the naphthenic acid contaminants to non-acidic compounds and alkaline earth metal carbonate and also to convert substantially all of the sulfur contaminants to alkaline earth metal sulfide. Then, the mixture is heated under a pressure sufficient to prevent vaporization of the mixture to a temperature sufficient and for a time sufficient to react the naphthenic acid contaminants with the alkaline earth oxide to form the corresponding non-acidic compounds and alkaline earth carbonates. In the meantime, substantially all of the sulfur contaminants react with the alkaline earth oxide to form the alkaline earth sulfide.

Abstract: The instant invention is directed to a process for reducing organic acids in petroleum feeds containing organic acids comprising: (a) thermally treating a petroleum feed containing organic acids in a thermal reaction zone comprising a plurality of stages in series, at a temperature and pressure sufficient to decompose at least a portion of said organic acids while sweeping said plurality of stages with an inert gas, to produce a volatile organic acid containing hydrocarbon fraction and a non-volatile hydrocarbon fraction; (b) treating said volatile hydrocarbon fraction to neutralize at least a portion of said organic acids therein and to produce a treated volatile hydrocarbon fraction; (c) collecting said non-volatile hydrocarbon fraction from said thermal reaction zone; and (d) blending said treated volatile hydrocarbon fraction of step (b) with said collected non-volatile hydrocarbon fraction.

Abstract: The present invention relates to a continuous in-situ process for reducing the viscosity, corrosivity and density of heavy oils comprising the steps of (a) contacting a heavy oil with an aqueous alkaline earth, Group IIA metal hydroxide at a temperature of about 380.degree. to about 450.degree. C. for a time sufficient to form the corresponding alkaline earth metal sulfide, recovering the reduced sulfur feed and regenerating the alkaline metal hydroxide for recycle to treat additional feed. Beneficially, the process removes heteroatoms (sulfur and nitrogen).

Abstract: Acidic halogens, especially chlorides, are removed from a dry gas stream by contact with dry particles of solid caustic. The solid caustic particles are preferably non-porous, and disposed in a bed with at least a 10% bed interstitial volume. Limiting halogen content in gas, and operating with a bone dry gas, ensures that salts deposit on the surface of the solid caustic without plugging the bed of solid caustic. Efficient halogen removal can be achieved even when treating a bone dry gas, one having less than 10 ppmv water vapor, at ambient temperature, without plugging the bed.

Abstract: Acidic halides, especially chlorides, are removed from gas by contact with particles of solid caustic covered by aqueous and hydrocarbon phases, respectively. Effective neutralization is achieved without swelling or plugging the bed of solid caustic. Halides are removed as brine. Efficient caustic utilization is achieved by controlling water vapor levels in the gas based on pH of brine product.

Abstract: Acidic halides, especially chlorides, are removed from dry liquid hydrocarbon streams such as catalytic reformate by contact with large particles of low surface area solid caustic such as a bed of NaOH pellets. Effective neutralization is achieved in a bed which is essentially free of any aqueous phase. Salt formed by the neutralization reaction deposit as solids on the surface of the solid caustic. A process for producing a low chloride, dry reformate product is also disclosed.

Abstract: A process for separating finely divided petroleum cracking catlyst from a mixture of the finely divided catalyst particles with a high boiling refractory hydrocarbon oil by intimately contracting said mixture with a concentrated aqueous solution of a basic alkali metal compound at a temperature above 170.degree. F., the quantity of aqueous solution employed being substantially greater than the quantity of said mixture with which it is contracted.

Abstract: Rerefined used oil supplies are treated on a continuous basis so as to clarify the flow and so as to neutralize oxidation product components such as carboxylic acids which remain within the oil stocks after they have been rerefined by upstream procedures. The process is carried out on a continuous basis, and the treatment includes utilizing very low quantities of strong base for each volume of rerefined used oil that is thus treated. The treatment process includes continuously vacuum distilling a continuous flow of used oil stock and strong base composition.

Abstract: Arsenic is removed from shale oil by the addition of one or more basic materials to the shale oil.

Abstract: A process for enhancement of the cetane number of a diesel fuel which in one embodiment comprises:(1) treating a diesel oil with a nitrogenous treating agent in a nitrogen amount, equivalent on a 100% nitric acid basis, to about 10 weight percent or less of the diesel oil feed;(2) separating unreacted nitrogenous treating agent from the diesel oil of step (1);(3) treating the diesel oil of step (2) with an inorganic alkali to produce a treated diesel oil; and(4) blending the treated diesel oil of step (3) with an untreated diesel oil to produce a blended diesel fuel such that the added nitrogen content in the blended diesel fuel is(a) about 300 ppm or less of nitrogen added when the diesel oil treated in step (1) is obtained from virgin diesel oil stock; or(b) about 450 ppm or less of nitrogen added when the diesel oil treated in step (1) is obtained from hydrotreated diesel oil stock.

Abstract: A process for upgrading oils is disclosed, in which the oil to be upgraded is contacted with liquid phase water and free oxygen at an elevated temperature and at a pressure sufficient to maintain at least part of the water in the liquid phase.

Abstract: A process for treating liquid hydrocarbons to remove toxic, mutagenic and/or carcinogenic aromatic hydrocarbons comprises feeding the hydrocarbons into a reactor where vapors are thermally treated in contact with a catalyst consisting essentially of calcium oxide or a calcium oxide containing mineral. Thermally treating liquid hydrocarbons in contact with calcium oxide preferentially increases the cracking of aromatics thus producing a product having a reduced amount of aromatic compounds.

Abstract: A process for eliminating and removing impurities including sulfur compounds and microorganisms as well as preventing further microbial contamination is accomplished by treating petroleum products or other hydrocarbon fluids with an aqueous solution of an oxidizing agent such as hydrogen peroxide or ozone together with a metallic ion catalyst, such as a mixture of ferric chloride and cupric chloride, where the metal ion is capable of forming activated oxygen complexes in the presence of such oxidizing agent, or by treatment with an aqueous solution of metallic ion catalyst and activated oxygen complexes formed from permanganate, peroxyborate or chromate ions.

Abstract: Purity of hydrocarbon streams is increased by contacting with stable oxides of calcium, titanium, zinc, or zirconium prior to passage to a catalytic conversion process. In one embodiment, the stable metal oxides are preactivated by heating with vaporous hydrocarbon at an elevated temperature which is effective in extending the temperature at which metal oxides are subsequently effective for purification of hydrocarbon streams.

Abstract: Slurryform products of coal liquefaction are treated with caustic soda in presence of H.sub.2 O in an inline static mixer and then the treated product is separated into a solids fraction and liquid fractions, including liquid hydrocarbons, by gravity settling preferably effected in a multiplate settling separator with a plurality of settling spacings.

Abstract: The rate of separation of suspended mineral particles from a coal liquid is increased by adding a mixture of a hydrocarbonaceous oil and a calcium salt, such as calcium carbonate, to the coal liquid. The increase in the separation rate is achieved even though the coal mineral particles naturally contain a calcium salt. The premixing of the calcium salt with hydrocarbonaceous oil considerably enhances the separation rate as compared to the addition of the calcium salt alone even when the hydrocarbonaceous oil is a distillate fraction which is derived from the coal liquid itself.

Abstract: Traces of furfural are removed from an aromatic feed by passing the aromatic feed containing greater than 50 ppm furfural through a bed of solid particles of a selected treating agent.

Abstract: Processes for the simultaneous desulfurization and hydroconversion of heavy carbonaceous feeds, including various sulfur-containing heavy petroleum oils, are disclosed. These feeds are contacted with alkali metal hydroxides in a conversion zone, in the presence of added hydrogen, and at elevated temperatures, whereby the feeds are substantially desulfurized, while at the same time significant upgrading of these feedstocks is obtained as demonstrated by decreased Conradson carbon, increased API gravity, and the conversion of a substantial portion of the 1,050.degree. F+ portion of the feedstream. In addition, methods for the regeneration of alkali metal hydroxides from the alkali metal salts produced in the conversion zone are disclosed.

Abstract: A process for removing sulfur from crude oil by contacting with calcium hydroxide containing material at atmospheric pressures and temperatures less than about 100.degree.F.