Abstract: A paraffinic solvent is mixed with bitumen froth containing water and solids. Sufficient solvent is added to induce inversion when the mixture is subjected to gravity or centrifugal forces. The emulsion reports to the water phase and a dry bitumen product virtually free of inorganic solids, is obtained.

Abstract: A process for the solvent separation of hydrocarbons from tar sand or contaminated soils comprises extracting the hydrocarbons from the sand or soil in a solvent extraction means to form a hydrocarbon rich solvent solution. The rich solvent is separated from the hydrocarbon in a process that utilizes flashing of the solvent in a heated flashing column at ambient pressure. The hydrocarbon is withdrawn from the bottom of the column and the flashed solvent vapors are strategicly withdrawn and passed into a condensation column from which the condensed solvent may be recycled. The flashing column is divided by a series of horizontal, vertically aligned apertured trays. The solution is introduced into the top of the column and the flashing operation is facilitated by the increase in the surface area of the solution as it flows by gravity from tray to tray. The column is maintained at a temperature, preferably above the boiling temperature of the solvent.

Abstract: A method for removal of hydrocarbon materials from solid particulate soil contaminated with the hydrocarbon materials. The method comprises forming an aqueous slurry of a mixture of a hydrophobic adsorbent selected from foamed synthetic materials or natural materials which entrap gas, with the soil in the presence of water. The adsorbent has a density less than water. The slurry is mixed for a period of time, and a gravity separation of the adsorbent from the aqueous admixture thus obtained is effected.

Abstract: A method for extracting bitumen from crushed mined tar sands comprising contacting the mined tar sands with a solvent in the presence of sonic energy in the frequency range of 0.5 to 2.0 kHz. Specifically, a solvent is first mixed with crushed mined tar sands and the mixture is then formed into a slurry of tar sand suspended in the solvent. Thereafter the tar sand slurry is injected into the top of a vertically disposed, substantially rectangular shaped, hollow acoustic chamber of uniform cross-section. Fresh solvent is injected into the bottom of the acoustic chamber and flows upwardly through the cell. The fresh solvent is injected into the bottom of the acoustic chamber at a rate low enough whereby the tar sand particles in the slurry fall by gravity through the upwardly flowing solvent. The tar sand particles and solvent in the acoustic chamber are subjected to acoustic energy in the frequency range of 0.5 to 2.

Abstract: A process for the biological treatment of bitumen froth tailings produced from a tar sands treatment and bitumen froth extraction process is disclosed. In this process bitumen froth tailings, containing native hydrocarbon metabolizing microorganisms, are mixed with a growth media to form an inoculum which is then incubated under isothermal conditions for an amount of time to produce a mixed bacterial culture containing bioliquor and a water product containing a reduced amount of asphaltenes as well as solids such as clays and sands. The bioliquor produced in this process is then utilized in the initial tar sands conditioning process from which bitumen froth is produced as well as in the initial tar sands mining process via bioliquor injection directly into the tar sands formation. Because the mixed bacterial culture is made up of a number of hydrocarbon metabolizing microorganisms, the bioliquor is also used in the degradation of the asphaltenes.

Abstract: In a process for separating oily films from sand particles carried in a sent free water stream, the use of a jet pump scrubber in a density classification tank to treat such oily coated particles at controlled operating temperatures above 65.degree. C. whereby at such controlled temperature enhanced cavitation in said jet pump separates said oily film from said sand particles to form slop oil, said tank providing for recirculation of sand particles through said jet pump before discharge.

Abstract: Tar sand is upgraded to produce a hydrocarbon having a low concentration of water and solids by contacting a bitumen/diluent mix with an alkoxyalkylphenol alkoxylate surfactant prior to separation of a recoverable hydrocarbon phase. The separation of the bitumen/diluent mix into a recoverable hydrocarbon phase and a water/solid phase results in a recoverable hydrocarbon phase that meets the concentration of water and solids desired by tar sand processors. A further refinement of the method involves contacting the bitumen/diluent mix with an anionic and cationic flocculant following the surfactant for further improvement in separation.

Abstract: Average grade oil sand is mixed with water to produce a low temperature (20-35.degree. C.), dense (1.4-1.65 g/cc) slurry. The slurry is pumped through a pipeline for sufficient time to condition it. Air is injected into the slurry after the last pump. The slurry density is adjusted to about 1.5 g/cc by adding flood water near the end of the pipeline. The slurry is introduced into a primary separation vessel slurry as it is introduced into the (PSV), excess air is vented from the PSV and a hot water underwash is used to heat the froth produced. Slurry loading to the PSV is greater than about 4.78 tonnes of oil sand/hour/square meter to reduce velocity gradient in the fluid in the vessel. Bitumen froth is recovered. When fed low grade oil sand, the process is modified by adding flotation aid chemicals to the slurry in the pipeline and subjecting the PSV tailings and middlings to secondary recovery with agitation and aeration in a secondary separation vessel.

Abstract: A process for the extraction of bitumen from bitumen froth generated from tar sands is presented. In this process bitumen froth, extracted from tar sands using a water process not requiring the use of caustic soda, is treated in a counter-current decantation circuit with a paraffinic solvent to remove precipitated asphaltenes, water, and solids from the bitumen froth. The instant invention produces a dilute bitumen product having final water and solids content of about 0.01 to about 1.00% by weight rendering the dilute bitumen product amenable to direct hydrocracking. This process provides an alternative route to the conventional process utilizing centrifuges to separate bitumen from precipitated asphaltenes, water, and solids thereby avoiding the high capital and operating costs associated with the conventional bitumen froth treatment by centrifugation.

Abstract: A sand/liquid separator provides for the conditioning of oil sands. Clean sand is separated from the ore and discharged for use as backfill. The sand/liquid separator machine includes horizontal shafts with paddles that act on a fluidized bed. The overall height of the machine is increased over prior art devices so the water volume is expanded. For a given residence time, more sand can be separated out than is otherwise possible. The water-to-sand ratio is an independent variable, water is recycled independent of the sand. The rate of water recycle depends only on the heat input needed and the clay content of the feed. The rate of water input is limited by the rise velocity needed to separate sand larger than forty-four micron from the water/liquid phase. This, in turn, determines the maximum oil sand feed rate based on the total clay in the feed at up to six percent, by weight, of clay in the middlings in the machine.

Abstract: A hot water extraction process for extracting bitumen from tar sands is taught wherein the tar sand is conditioned using an alkali metal bicarbonate, an alkali metal carbonate and a liquid hydrocarbon. A source of calcium and/or magnesium ions can also be added. The conditioning step replaces the step of conditioning using caustic soda previously used in tar sand extraction. The use of the alkali metal bicarbonate and carbonate and a liquid hydrocarbon substantially eliminates the production of sludge in tar sand extraction and maintains or improves bitumen recovery. The process allows for hot conditioning solution to be recycled to the process by use of a recycle storage tank.

Abstract: A process for the extraction of bitumen from bitumen froth generated from tar sands is disclosed. In this process, bitumen froth is extracted from tar sands using a water process without requiring the use of caustic soda. The froth is treated in a counter-current decantation circuit with a paraffinic solvent to remove precipitated asphaltenes, water, and solids from the bitumen froth. A dilute bitumen product is produced having final water and solids contents of about 0.01 to about 1% by weight. This renders the dilute bitumen product amenable to direct hydrocracking. The process provides an alternative route to the conventional process of utilizing centrifuges to separate bitumen from precipitated asphaltenes, water, and solids and thus avoids the high capital and operating costs associated with the conventional bitumen froth treatment by centrifugation. The invention utilizes bitumen froth produced from a water process in which the use of caustic soda is not required.

Abstract: A paraffinic solvent is mixed with bitumen froth containing water and solids. Sufficient solvent is added to induce inversion when the mixture is subjected to gravity or centrifugal forces. The emulsion reports to the water phase and a dry bitumen product is obtained.

Abstract: A method of treating a dilute aqueous suspension of solid particulate material comprising waste material from a process for recovering petroleum from oil sand includes diluting the suspension with at least 75% of its own volume of water thereby to increase the settling rate of the particulate material and allowing the particulate material to settle to form a concentrated solid sediment. The treated suspension may have been obtained from a process in which an alkaline solution is used to treat the oil sand. The water from which the concentrated solid sediment is separated may be returned to the process for recovering petroleum from oil sand. The solid sediment may be transferred to a separation vessel in which it is fractionated into a coarse particle fraction and a fine particle fraction. The fine particle fraction may comprise essentially particles having an equivalent spherical diameter not greater than 3 .mu.m. The concentrated solid material recovered may be calcined to form a pozzolanic material.

Abstract: A system and method for immediately separating oil sands into three layers uses a logwasher with paddles that mixes the oil sands with hot water and steam. The three layers of bitumen, clay/sand/water slurry and rock separate effectively and immediately and are not re-mixed in further processing as was conventional, further producing a clay fraction from the fines for mineral processing.

Abstract: A process for the thermal conversion of the organic component associated with tar sands to lower boiling, higher value products. The conversion is achieved by subjecting the organic component containing from about 1 to 20 wt. % native solids to elevated temperatures and pressures. Compared to conventional thermal conversion processes, such as visbreaking, much higher conversion of the organic component can be achieved owing to the presence of native solids on which coke is deposited instead of fouling the process equipment. This higher conversion is also associated with enhanced removal of sulfur and metals.

Abstract: A system and method for immediately separating oil sands into three layers uses a logwasher with paddles that mixes the oil sands with hot water and steam. The three layers of bitumen, clay/sand/water slurry and rock separate effectively and immediately and are not re-mixed in further processing as was conventional, further producing a clay fraction from the fines for mineral processing.

Abstract: Tar is separated and recovered from tarsands using an extraction process useful even in cold water which utilizes a liquid admixture of a high boiling alkane; e.g. naphtha, an anionic surfactant and water.

Abstract: Tar sand and Gilsonite are preferably crushed together so that the Gilsonite overcomes the stickiness of the tar sand and the tar sand alleviates Gilsonite dust, the relative proportions and the character of Gilsonite being such as to produce an additive product for an asphalt, usually refinery asphalt, and a resulting modified asphaltic cement for paving purposes to simulate Trinidad Lake Asphalt. One embodiment of the additive composition of the invention results in an asphaltic cement that outperforms that produced by use of Trinidad Lake Asphalt as the additive, while a second embodiment of the additive composition of the invention contains additional tar-sand-extracted bitumen and the resulting asphaltic cement more closely matches the performance of that containing Trinidad Lake Asphalt as the additive. The invention includes a system for extracting bitumen from tar sand and in one form provides for adding Gilsonite to the extracted liquid bitumen so it will effectively solidify when cooled.

Abstract: A method for processing lumps of oil sand containing bitumen to produce a bitumen froth and non segregating tailings of a solid material and a sludge. The method includes depositing the lumps of oil sand into a bath of warm water. The lumps are then conditioned by gently contacting them with the warm water to liberate and separate bitumen from the oil sand while minimizing the dispersal into the bath of fine material contained in the oil sand. Following conditioning, the solid material remaining after the liberation and separation of the bitumen from the oil sand is removed from the bath and collected for further processing. The warm water containing bitumen and dispersed fine material is also removed from the bath and collected for further processing. Following removal from the bath, the warm water containing bitumen and dispersed fine material is separated into the bitumen froth and a suspension of dispersed fine material.

Abstract: A method for extracting oil from oil-contaminated soil containing 2 to 5 wt. % oil, comprising contacting the oil-contaminated soil with a solvent in the presence of sonic energy in the frequency range of 0.5 to 2.0 kHz. Specifically, a solvent is first mixed with the oil-contaminated soil and the mixture is then formed into a slurry of oil-contaminated soil particles suspended in the solvent. Thereafter the oil-contaminated soil slurry is passed through a shaker screen to remove soil particles greater than 1/4 inch. The oil-contaminated soil slurry containing the smaller soil particles is then fed into the top of a vertically disposed, substantially rectangular shaped, hollow acoustic chamber of uniform cross-section. Fresh solvent is injected into the bottom of the acoustic chamber that flows upwardly through the acoustic chamber. The fresh solvent is injected at a rate low enough whereby the oil-contaminated soil particles fall by gravity through the upwardly flowing solvent.

Abstract: The invention relates to a continuous process for producing synthetic crude oil from oil bearing material, e.g., oil shale or tar sand, through continuous loading, calcining and unloading operations in three triangularly placed reactor tubes that are loaded with oil bearing material from a common feed source.

Abstract: A method for processing lumps of oil sand containing bitumen to produce a bitumen froth and non segregating tailings of a solid material and a sludge. The method includes depositing the lumps of oil sand into a bath of warm water. The lumps are then conditioned by gently contacting them with the warm water to liberate and separate bitumen from the oil sand while minimizing the dispersal into the bath of fine material contained in the oil sand. Following conditioning, the solid material remaining after the liberation and separation of the bitumen from the oil sand is removed from the bath and collected for further processing. The warm water containing bitumen and dispersed fine material is also removed from the bath and collected for further processing. Following removal from the bath, the warm water containing bitumen and dispersed fine material is separated into the bitumen froth and a suspension of dispersed fine material.

Abstract: Oil sand is treated to prevent the production of sulfur dioxide ("SO.sub.2 ") from a known rotating kiln-type processor. Lime or calcium oxide ("CaO") is added with the oil sand feed to the kiln. In the kiln, the CaO is mixed with the sulfur-containing bitumen of the oil sand and preheated. The preheated mixture is then pyrolysed, forming coke which is modified by the added CaO to reduce its tendency to produce SO.sub.2 when combusted. The modified coke is then combusted with air, producing substantially no SO.sub.2.

Abstract: Acidic halides, especially chlorides, are removed from gas by contact with particles of solid caustic covered by aqueous and hydrocarbon phases, respectively. Effective neutralization is achieved without swelling or plugging the bed of solid caustic. Halides are removed as brine. Efficient caustic utilization is achieved by controlling water vapor levels in the gas based on pH of brine product.

Abstract: A method and apparatus for extracting bitumen whereby tar sand containing bitumen components is contacted with a heated thinning oil mixture to reduce the tar sand viscosity and dissolve bitumen to form a lower viscosity feed slurry. The feed slurry is contacted with a light oil in a separator wherein the mixture is separated into product oil and oil sand. The oil sand is washed with solvent in a countercurrent fashion to extract occluded oil to form the light oil. Washed sand containing solvent is heated above the boiling point of the solvent in a multi-hearth solvent recovery furnace to vaporize the solvent. The solvent vapors are stripped from the sand by flowing inert gas through the sand in the multi-hearth solvent recovery furnace. Inert gas containing solvent vapors is directed from the multi-hearth solvent recovery furnace to a heat exchanger/scrubber where the inert gas and solvent vapors are contacted with product oil from the separator.

Abstract: An oil sands separator includes a drum (10) having a solids discharge end (24) and a liquid discharge end (22) and a spiral ribbon (14) having a plurality of flights wound inside the interior of the drum. A first plate (28) partially closes the solids discharge end and has a first opening (32) disposed within it. A second plate (26) partially closes the liquid discharge end and has a second opening (30) disposed within it. A conveyor (46) is provided at the liquid discharge end for conveying feed into the drum through the second opening and into the spiral ribbon. A pipe (50) at the solids discharge end conveys hot water into the drum through the first opening. Pockets (40) at the solids discharge end remove solids from the drum as a drive rotates the drum and its spiral ribbon.

Abstract: Middlings from the primary separation vessel ("PSV") are recycled through a line to the PSV. The middlings are aerated with fine air bubbles using in line eductor/aerator assemblies. The aerated middlings are mixed as they are pumped through a line back to the PSV. Bitumen recovery from the PSV is increased as a result.

Abstract: The invention disclosed relates to a process for removing contaminants, such as hydrocarbons, from soil. The process involves contacting the contaminated soil with a suitable solvent for the contaminant, in the presence of a bridging liquid which is immiscible with the solvent, while agitating. The amount of the bridging liquid and the degree of agitation are balanced to control the particle size of the substantially contaminant- and solvent-free soil agglomerates so formed.

Abstract: Aerated bitumen froth containing bitumen, water, air and solids is the product of the hot water extraction process for recovering bitumen from oil sand. Measurements related to the water content of the froth can be obtained by measuring its resonant frequency in a calibrated output, open-ended microwave cavity. By also measuring the bulk density of the froth and assuming a constant relationship for the solids content, one can compute from the assembled data the output quality of the froth. The measurements can be taken repetitively at the vessel as the froth is produced and used to almost instantly provide froth quality information.

Abstract: A process for recovering a hydrocarbon from a hydrocarbon bearing sand comprising the steps of mixing a chemical additive with a chemical composition and with a hydrocarbon bearing sand containing hydrocarbon and residual solids including clay, at a temperature to form a slurry. The chemical composition comprises an aqueous phase and a minor amount of a chemical agent selected from the group consisting of at least one ethoxylated alkylphenol compound, at least one ethoxylated dialkylphenol compound, MIBC, SC-177, Petronate HL, Clacium Lignosulfonate and mixtures thereof. The slurry is aerated to produce essentially sludge-free tailings and a mixture of hydrocarbon, aqueous phase and residual solids including clay. The process further comprises the step of separating the mixture of the hydrocarbon, the aqueous phase and the residual solids including clay from the essentially sludge-free tailings.

Abstract: A process for upgrading bitumen asphaltenes obtained from tar sands to hydrocarbons which comprises contacting the bitumen with a deasphalting solvent to yield a deasphalted oil and a residual solid asphaltene, separating the residual solid asphaltene from the deasphalted oil and treating the solid asphaltene fraction with superheated water containing a soluble carbonate salt at temperatures of from 300.degree. to 425.degree. C.

Abstract: A process suitable for operation at a mine site for recovering a hydrocarbon from a hydrocarbon bearing sand comprising the steps of mixing a chemical additive with a chemical composition and with a hydrocarbon bearing sand containing hydrocarbon and residual solids including clay, at a temperature to form a slurry. The chemical composition comprises an aqueous phase and a minor amount of a chemical agent selected from the group consisting of at least one ethoxylated alkylphenol compound, at least one ethoxylated dialkylphenol compound, MIBC, SC-177, Petronate HL, Calcium Lignosulfonate, NaOH and mixtures thereof. The slurry is conditioned and aerated to produce essentially sludge-free tailings and a mixture of hydrocarbon, aqueous phase and residual solids including clay. The process further comprises the step of separating in a short-residence time apparatus the mixture of the hydrocarbon, the aqueous phase and the residual solids including clay from the essentially sludge-free tailings.

Abstract: A process for upgrading bitumen asphaltenes obtained from tar sands to hydrocarbons which comprises contacting the bitumen with a deasphalting solvent to yield a deasphalted oil and a residual solid asphaltene, separating the residual solid asphaltene from the deasphalted oil and treating the solid asphaltene fraction with superheated water at temperatures of from 300.degree. to 425.degree. C.

Abstract: The invention is a method for generating bitumen-in-water dispersions and emulsions useful for recovering and transporting bitumen, which comprises mixing an aqueous surfactant solution with bitumen at an elevated temperature, said surfactant system comprising about 0.005% to about 5% by weight of a sulfonate surfactant represented by the formula ##STR1## wherein R is an alkyl chain of about 6 to about 16 carbon atoms, x has an average value of about 2 to about 10, y has an average value of about 1 to about 10, R' is ethylene, propylene or butylene, and M.sup.+ is an alkali metal or ammonium ion.

Abstract: As-mined, naturally water-wet oil sand is mixed at the mine site with hot water and NaOH to produce a slurry containing entrained air. The slurry is pumped through a pipeline and is fed directly to a conventional gravity separation vessel. The pipeline is of sufficient length so that, in the course of being pumped therethrough, sufficient coalescence and aeration of bitumen occurs so that, when subsequently retained in the gravity separation vessel under quiescent conditions, a viable amount of the bitumen floats, forms froth, and is recovered.

Abstract: A process for treating bitumen froth containing mixtures of a hydrocarbon component, water and solids, comprises heating said bitumen froth to a temperature in the range of about 80.degree. C. to about 300.degree. C., preferably in the range of 100.degree. C. to 180.degree. C., under pressure of about 150 to about 5000 kPa, preferably in the range of 800 to about 2000 kPa, sufficient to maintain said hydrocarbon component in a liquid phase, passing said heated froth into a plurality of separation stages in series, and gravity settling the solids and water from the hydrocarbon layer while maintaining said elevated temperature and pressure. A diluent miscible with the bitumen may be mixed with the bitumen froth in an amount of 0 to about 60 per cent by weight of the bitumen, preferably in an amount of 15 to 50 per cent by weight of the bitumen in a mixing stage for preconditioning of the froth prior to each gravity separation stage.

Abstract: Drill cuttings are cleaned of oil-based drilling mud and oil using a cleansing agent, such as a C6-C10 carboxylic acid, that is preferentially oil soluble at one pH and preferentially water soluble at another pH. The oily cuttings are treated with the carboxylic acid and then washed with an aqueous, alkaline washing solution, which converts the carboxylic acid to its water soluble salt and, with vigorous agitation, lifts most of the oil from the cuttings. In other embodiments, the process is used for cleaning oil-contaminated soil, sand, and gravel, and for separating the oils from the solids in oily sludges.

Abstract: A process and an apparatus are described for separation of water and solids from oil sands froth in which heated froth is fed into a gravity settling vessel at a level below a bitumen-water interface established between a bitumen froth layer floating on a quiescent body of water whereby water and solids contained in the froth separate from the froth stream, the oil rises to accumulate in the bitumen froth layer, and the solids fall by gravity to the bottom of the gravity settling vessel. The apparatus comprises an injector manifold suspended horizontally within the vessel below the bitumen-water interface, said injector manifold having a plurality of equispaced, inwardly facing openings for the inward discharge of oil sands froth into the body of water. The injector ring manifold may also have a plurality of outwardly facing openings for both inward and outward discharge of froth.

Abstract: A road construction material includes a hydrocarbon-laden mixture of fine aggregates and a hydrocarbon solvent, the hydrocarbon-laden fine aggregate mixture having a hydrocarbon content in a range of approximately five to twenty percent by weight and the hydrocarbon content including at least approximately 50 percent by weight light end crudes, the road composition material being made by cold-blending the hydrocarbon-laden fine aggregate mixture and the hydrocarbon solvent and marinating for a time sufficient to diffuse the hydrocarbon contents of the hydrocarbon-laden fine aggregates with the hydrocarbon solvent. There may also be added a light weight ceramic aggregate mixture for additional strength and stability. Heat stabilzing, anti-stripping agents and anti-track compounds may be added as desired.

Abstract: A process for separating bitumen from tar sands, which comprises: a) agitating a mixture of tar sand with substantially coarse clean sand at ambient or below ambient temperature in the presence of water, so as to mechanically shear bitumen and enhance the detachment of bitumen particles from mineral matter in said tar sand, b) eluting the detached bitumen and fine mineral matter from the coarse sand by an upward flow of water while stirring gently, c) returning the coarse sand to step a) for reuse, and d) subjecting the eluted bitumen and fine mineral matter to froth flotation to separate the bitumen from said fine mineral matter, wherein the flotation is effected without using any reagents.

Abstract: The recovery of bitumen from tar sands by flotation is improved by the use of alkanol amines as flotation promoters. Monoethanolamine and diethanolamine are particularly useful for this purpose.

Abstract: A process for reducing asphaltene content of crude oil and oil-containing materials to improve rheological properties of crude oils enhancing the water-extractabilities of sulphur and metals contained in them. The process employs the cold cracking effect of a binary acid solution containing, preferably, hydrochloric acid and oleic acid. The process is particularly applicable to the exploitation of heavy and ultra-heavy oil deposits, to oil recovery from oil-containing tar sand, shale or clay and to the cleaning of oil tanks, garments and clogged oil-pipelines.

Abstract: Methods for the recovery of bitumen from tar sands comprising the steps of mixing tar sand, solvent and a displacing amount of aqueous medium to form a mixture, followed by separating a bitumen-rich solvent phase from the mixture and recovering bitumen from the bitumen-rich solvent phase are disclosed.

Abstract: An aperature is formed in the bottom wall of the launder. A downwardly extending container communicates with the aperture. A weir is positioned immediately downstream of the aperture. The container and weir combine to form a separator. In the launder, free water and solids contaminants settle and form a bottom layer of dirty water. The layer is diverted into the container through the aperture and the weir temporarily retains a small head of it. Temporary retention in the separator therefore generates a vertical fluid column comprising an upper layer of relatively clean froth and a lower layer of dirty water, said layers having an ascertainable interface. The elevation of the interface is monitored and contaminated fluid is withdrawn from the container as underflow at a rate controlled to keep the interface elevation substantially constant. The froth overflowing the weir is reduced in water and solids relative to the original froth issuing from the flotation vessel.

Abstract: A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

Abstract: Hydrocarbon liquids are recovered from carbonaceous materials such as tar sands utilizing a separation reagent formed in situ by reacting polar resin components of tar sands with an inorganic base such as sodium silicate in sonicated aqueous solution in absence of an organic solvent to form a surfactant. Under the influence of sonication a microemulsion of polar-external micelles forms. The polar groups can associate with anions, especially polyanions such as silicate and act in a membrane mimetic manner to form vesicles. Cavities can form in the surfactant resin molecule that complex with guest cations such as titanium or other metals from the tar sand.When tar sands are added to the sonicated separation reagent, the surfactant penetrates the bitumen. Metal ions complex with the polar groups and aid in removing the bitument from the sand particles. The polarorganic asphaltene materials are carried into the aqueous phase by the anion and stabilized within the micelle structure.

Abstract: Enhanced recovery of oil from an oil-containing particulate shale sludge is achieved by contacting the sludge with a light hydrocarbon solvent fraction, obtained from the processing of oil derived from the shale, in the presence of water to form an oil-solvent liquid phase which is separated from an aqueous phase containing oil-depleted shale. The oil-solvent liquid phase when introduced into a slurry of product oil and particulate contained within a shale retort provides several advantages, including lowering the viscosity of the product oil and enhanced separation of the product oil from the particulate shale.

Abstract: A method and an assembly for decontaminating a material. The material is charged into a container, where at first steam is introduced and fluids including some contaminants are removed. Then extractant is introduced into the container, and fluids comprising condensation water, extractant and contaminants are removed. Then the material is stripped with vapor. The dry or slightly humid material in the container is removed in a condition suitable for return to its place of origin. The used extractant can be purified to be re-used.

Abstract: This invention involves the separation of clay-contaminated bitumen from sand with a solvent. The bitumen is dissolved with an organic solvent such as condensate from a natural gas well. The clay is separated from the dissolved bitumen and the solvent is recoverd and recycled. The sand is washed with water containing a carefully selected, nonanionic surface active agent to remove residual bitumen and solvent. Prior removal of the clay precludes it from unduly contaminating the water.