Tar Sand Treatment With Liquid Patents (Class 208/390)
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Patent number: 7569137Abstract: Processes and apparatus for the treatment of product streams from mineral processing operations, including the treatment of tailings which result from oil sand processing operations. The processes and apparatus relate to the recovery of a diluent solvent from bitumen froth tailings and to the thickening of tailings from a bitumen froth stream and a middlings stream resulting from an oil sand extraction process. In one aspect the processes and apparatus relate particularly to the recycling of product streams to maximize process efficiencies. In a second aspect the processes and apparatus relate particularly to the thickening of tailings to produce an underflow component, a clarified overflow component and an unclarified overflow component.Type: GrantFiled: April 12, 2004Date of Patent: August 4, 2009Assignee: Fort Hills Energy L.P.Inventors: Alexander William Hyndman, John Patrick Ringstrom, John Sharpe, Douglas Robert Bartlett, W. Scott Hindle, Chris L. Grant
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Patent number: 7556715Abstract: An inline bitumen froth steam heater system is comprised of steam injection and static mixing devices. The steam heater system heats and de-aerates an input bitumen froth without creating downstream processing problems with the bitumen froth such as emulsification or live steam entrainment. The inline bitumen froth steam heater is a multistage unit that injects and thoroughly mixes the steam with bitumen resulting in an output bitumen material having a homogenous temperature of about 190° F. The heating system conditions a superheated steam supply to obtain saturated steam at about 300° F. The saturated steam is contacted with a bitumen froth flow and mixed in a static mixer stage. The static mixers provide a surface area and rotating action that allows the injected steam to condense and transfer its heat to the bitumen froth. The mixing action and the increase in temperature of the bitumen froth results in reduction in bitumen viscosity and also allows the release of entrapped air from the bitumen froth.Type: GrantFiled: April 16, 2004Date of Patent: July 7, 2009Assignee: Suncor Energy, Inc.Inventors: Les Gaston, Donald Norman Madge, William Lester Strand, Ian Noble, William Nicholas Garner, Mike Lam
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Publication number: 20090145809Abstract: A method of removing bitumen from tar sands comprising contacting the tar sands with a first mixture comprising a petroleum distillate and an oxygenated solvent, and recovering a second mixture comprising (a) at least a portion of the petroleum distillate and oxygenated solvent from the first mixture, (b) bitumen and (c) sand having a reduced amount of bitumen.Type: ApplicationFiled: December 10, 2007Publication date: June 11, 2009Applicant: Chevron Phillips Chemical Company LPInventors: Sam B. Ledbetter, JR., Marshall D. Bishop, Bharat B. Patel
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Publication number: 20090139905Abstract: A separation apparatus can include at least one endless cable. The cable can be wrapped around at least two revolvable cylindrical members a plurality of times. The wraps can form gaps between adjacent windings, which, along with the endless cable, can be used to facilitate separations processing. Additionally, the separation apparatus can optionally include a repositioning guide for each multiple wrap endless cable that can guide the endless cable in an endless route and prevent the cable from rolling off or falling off of the cylindrical members. Separation can be accomplished by oleophilic adherence to the cable, electrostatic adherence to the cable, and/or physical retention on the cable. This endless cable system can be particularly useful for separation of oil sand slurries, mass transfer operations, and physical separations.Type: ApplicationFiled: November 30, 2007Publication date: June 4, 2009Inventor: Jan Kruyer
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Patent number: 7540951Abstract: A process for preparation of synthetic crude from a deposit of heavy crude, comprises: (a) the extraction of heavy crude by technology using steam; (b) the separation of crude extract and water; (c) the separation of crude into at least one light fraction and one heavy fraction; (d) the conversion of the heavy fraction of separation into a lighter product, said converted product, and a residue; (e) optionally, the partial or total hydrotreatment of the converted product and/or the light fraction (or fractions) obtained during the separation c), (f) the combustion and/or gasification of the conversion residue; the converted product and the light fraction (or fractions) for separation, optionally having been subjected to a hydrotreatment e), constituting the synthetic crude; said combustion allowing the generation of steam and/or electricity and said gasification allowing the generation of hydrogen; the steam and/or electricity thus generated being used for the extraction a) and/or the electricity and/or hydrogType: GrantFiled: August 23, 2006Date of Patent: June 2, 2009Assignee: Institut Francais du PetroleInventors: Arnault Selmen, Thierry Gauthier, Mathieu Pinault, Eric Benazzi
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Publication number: 20090120844Abstract: The present invention relates to a process for the simultaneous recovery and cracking/upgrading of oil from solids such as tar sand and oil shale. With this process a number of the obstacles with the existing technology are solved, and the process upgrades the oil into a lighter product than the existing technology, remove sulphur in the order of 40% and heavy metals in the order of 90%.Type: ApplicationFiled: May 10, 2007Publication date: May 14, 2009Applicant: TARBLASTER ASInventors: Olav Ellingsen, Bjarte Sorebo Ellingsen
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Publication number: 20090090658Abstract: In a method for enhancing the efficiency of separation of bitumen from oil sands ore, lipids, lipid by-products, and lipid derivatives are used as process additives for ore-water slurry-based bitumen extraction processes or in situ bitumen recovery processes. The lipids, lipid by-products, and lipid derivatives act as surfactants reducing surface and interfacial tensions, thus promoting breakdown the oil sands ore structure and resultant liberation of bitumen from the ore. Lipid treatment does not deleteriously affect release water chemistry in bitumen recovery processes, and it does not appreciably affect the fuel value of recovered bitumen. Lipids which may be effectively used as additives include biodiesel, tall oil fatty acids, monoglycerides, vegetable oil, and soap water, and combinations thereof.Type: ApplicationFiled: October 6, 2008Publication date: April 9, 2009Inventors: ZVONKO BURKUS, BAKI OZUM
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Publication number: 20090020458Abstract: A method of treating tailings comprising a solids fraction and a hydrocarbon fraction is disclosed. A primary flow is supplied to a jet pump, the primary flow comprising water and less than 20% solids by mass. A secondary flow is supplied to a mixing chamber of the jet pump, the secondary flow comprising a slurry of water and tailings, the slurry comprising more solids by mass than the primary flow. The jet pump is operated using the primary flow such that the tailings are agitated to effect at least a partial phase separation of the hydrocarbon fraction from the tailings. The methods disclosed herein may also be applied to treat tailings ponds.Type: ApplicationFiled: June 13, 2008Publication date: January 22, 2009Applicant: RJ OIL SANDS INC.Inventors: Wade Ralph Bozak, Michael E. Kessick, Roderick Michael Facey
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Publication number: 20080277318Abstract: A process for the separation of bitumen oil from tar sands and the like. Slurry is supplied to a mixing chamber of a jet pump at an input end of the process. The slurry is agitated within the jet pump to effect a partial to full phase separation of the oil fraction from the solids fraction of the slurry. The partially to fully separated slurry is discharged into a pipeline and later into a hydrocyclone to effect a second phase separation of the slurry. One or more hydrocyclone separators may be used to separate the bitumen oil and liquid from the solids fraction.Type: ApplicationFiled: July 28, 2008Publication date: November 13, 2008Applicant: RJ OIL SANDS INC.Inventors: Wade Ralph Bozak, Roderick Michael Facey
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Patent number: 7438189Abstract: An apparatus for separating bitumen from a bitumen froth output of a oil sands hot water extraction process comprises an inclined plate separator (IPS) for providing a first bitumen separation stage and a cyclone for providing a second bitumen separation stage. The cyclone overflow is recycled to the IPS inlet.Type: GrantFiled: February 24, 2006Date of Patent: October 21, 2008Assignee: Suncor Energy, Inc.Inventors: William Nicholas Garner, Donald Norman Madge, William Lester Strand
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Patent number: 7438807Abstract: Discloses apparatus to perform a process to remove water and minerals from a bitumen froth output of a oil sands hot water extraction process. A bitumen froth feed stream is diluted with a solvent and supplied to a primary inclined plate separator stage, which separates the bitumen into an overflow stream providing a bitumen product output from the circuit and a bitumen depleted underflow stream. A primary cyclone state, a secondary inclined plate separator stage and a secondary cyclone stage further process the underflow stream to produce a secondary bitumen recovery product stream and a recycle stream. The secondary bitumen recovery product stream is incorporated into and becomes part of the circuit bitumen product output stream. The recycle stream is incorporated into the bitumen froth feed stream for reprocessing by the circuit.Type: GrantFiled: July 13, 2006Date of Patent: October 21, 2008Assignee: Suncor Energy, Inc.Inventors: William Nicholas Garner, Donald Norman Madge, William Lester Strand
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Patent number: 7431830Abstract: Staged crushing combined with water addition and mixing is practiced at the mine site to prepare an oil sand slurry ready for hydrotransport. More particularly, as-mined oil sand is crushed to conveyable size (e.g. —24?) using a mobile crusher. The pre-crushed ore product is conveyed to a dry ore surge bin. Ore is withdrawn from the bin and elevated to the upper end of a slurry preparation tower having downwardly aligned process components to enable gravity feed. The ore is further crushed in stages to pumpable size (e.g. —4?) by a stack of crushers and water is added during comminution. The ore and water are mixed in a mixing box and delivered to a pump box. The surge bin and tower are relocatable. Screening and oversize reject treatment have been eliminated to achieve compactness and enable relocatability.Type: GrantFiled: September 2, 2004Date of Patent: October 7, 2008Assignees: Canadian Oil Sands Limited Partnership, Canadian Oil Sands Limited, ConocoPhillips Oilsands Partnership II, Imperial Oil Resources, Mocal Energy Limited, Nexen Inc., Murphy Oil Company Ltd., Petro-Canada Oil and GasInventors: Ron Cleminson, David Fudge, Michael Carniato
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Publication number: 20080223757Abstract: In a method for enhancing the efficiency of bitumen recovery from oil sands ore, CaO lime (or Ca(OH)2) is mixed into an oil sands ore-water slurry prior to or during the operation of slurry-based bitumen extraction processes. The lime is introduced at dosages effective to reduce the electro-chemical attraction between clay particles and bitumen in the slurry, thereby promoting detachment of clay particles from bitumen droplets in the ore-wafer slurry. This occurs because water-soluble asphaltic acids formed at the bitumen-water interface act as surfactants which reduce or eliminate the activity of Ca2+ and Mg2+ ions binding the clay particles and bitumen together. The detachment of clay particles promotes the attachment of air bubbles to the bitumen droplets, thereby forming a bitumen-rich froth which will float to the surface of the ore-water slurry, thus facilitating bitumen recovery.Type: ApplicationFiled: March 14, 2008Publication date: September 18, 2008Applicant: APEX ENGINEERING INC.Inventor: Baki OZUM
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Publication number: 20080217212Abstract: An apparatus for processing bitumen froth comprising a cyclone body having an elongated conical inner surface defining a cyclone cavity extending from an upper inlet region with a diameter DC to a lower apex outlet with a diameter DU of not less than about 40 mm; an inlet means forming an inlet channel extending into the upper inlet region of said cyclone cavity; and a vortex finder forming an overflow outlet of a diameter DO extending into the upper inlet region of said cyclone cavity toward said lower apex outlet and having a lower end extending an excursion distance below said inlet channel, said excursion distance being operable to permit a portion of bitumen that passes through said inlet channel to exit said overflow outlet without having to make a spiral journey down said cyclone cavity, wherein a lower end of the vortex finder within the cyclone cavity is disposed a free vortex height (FVH) distance from said lower apex outlet.Type: ApplicationFiled: May 19, 2008Publication date: September 11, 2008Inventors: WILLIAM NICHOLAS GARNER, DONALD NORMAN MADGE, WILLIAM LESTER STRAND
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Publication number: 20080210602Abstract: Various methods and systems for obtaining bitumen from tar sands are disclosed. The disclosed methods and/or systems can be used to economically achieve a high degree of bitumen recovery from tar sands. The method may include a primary leaching or extraction process that separates most of the bitumen from the tar sands and results in a bitumen-enriched component and a bitumen-depleted component. The bitumen-enriched component includes mainly solvent and bitumen. The bitumen-depleted component includes mainly water and mineral solids with some residual bitumen and solvent. The bitumen-depleted component may be mixed with liquefied petroleum gas, e.g., propane and/or butane, to further separate the residual solvent and bitumen. The disclosed system can include separators configured to separate the various components at the various stages in the process.Type: ApplicationFiled: March 3, 2008Publication date: September 4, 2008Applicant: MARATHON OIL COMPANYInventor: Willem PC Duyvesteyn
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Patent number: 7419585Abstract: A process for upgrading a residua feedstock using a short vapor contact time thermal process unit comprised of a horizontal moving bed of fluidized hot particles. The residua feedstock is preferably atomized so that the Sauter mean diameter of the residua feedstock entering the reactor is less than about 2500 ?m. One or more horizontally disposed screws is preferably used to fluidize a bed of hot particles.Type: GrantFiled: January 6, 2003Date of Patent: September 2, 2008Assignee: Exxonmobil Research and Engineering CompanyInventors: Peter S. Maa, Craig Y. Sabottke
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Publication number: 20080190815Abstract: A method of recovering hydrocarbons from hydrocarbonaceous materials can include forming a constructed permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume having substantially permeable side walls and a substantially impermeable cap. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom without contamination or substantial leaching of materials outside of the impoundment. During heating the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.Type: ApplicationFiled: February 8, 2008Publication date: August 14, 2008Inventors: Todd Dana, James W. Patten
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Publication number: 20080190814Abstract: The present invention provides method for recovering fossil-based materials from oil sources using multifunctional, multipolymer surfactants. The invention also provides methods for reducing the loss of volatile organic compoiunds (VOCs) from oil storage containers using multifunctional, multipolymer surfactants. The multifunctional, multipolymer surfactants are characterized by a hydrophobic part and a hydrophilic part. The hydrophobic part of the polymer surfactants includes functionalities that impart a polarity of greater than 0 Debye to the hydrophobic part. The polymer surfactants are further characterized by molecular weights that are above their entanglement weights. The result is polymer surfactants with demulsifying characteristics.Type: ApplicationFiled: February 9, 2007Publication date: August 14, 2008Inventor: Gerard Caneba
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Publication number: 20080190816Abstract: A method of recovering hydrocarbons from hydrocarbonaceous materials can include forming a stationary permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom within a temperature range which is sufficient to substantially avoid formation of carbon dioxide or non-hydrocarbon leachates. During heating the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.Type: ApplicationFiled: February 8, 2008Publication date: August 14, 2008Inventors: Todd Dana, James W. Patten
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Publication number: 20080169222Abstract: A process and composition for removing heavy oil and bitumen from oil sands is disclosed. The composition comprises an emulsion of d-limonene and water, with an anionic surfactant as an emulsifying agent. The emulsion is contacted with an oil sand slurry until the aqueous and hydrocarbon phases separate. The process may take place at temperatures less than about 80° C.Type: ApplicationFiled: October 15, 2004Publication date: July 17, 2008Inventor: Kevin Ophus
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Patent number: 7399406Abstract: Methods are disclosed for identifying and treating oil sand ores having degraded bitumen. This can be done by considering the location from which the ore is mined or its history, or by microscopic examination of a bitumen froth made from the ore, or by near-infrared spectroscopy. Ore which contains degraded bitumen is treated with at least 0.05 wt/wt % alkaline material, preferably 0.1 wt./wt % of such alkaline material, in the water addition step of a hot or warm water extraction process for the making of bitumen froth, such as the Clark process.Type: GrantFiled: May 2, 2002Date of Patent: July 15, 2008Assignee: Suncor Energy, Inc.Inventors: Randy Mikula, Vicente Munoz, Brad Bjornson, Doug Cox, Anita Marks
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Patent number: 7381320Abstract: Disclosed is a process for the upgrading and demetallizing of heavy oils and bitumens. A crude heavy oil and/or bitumen feed is supplied to a solvent extraction process 104 wherein DAO and asphaltenes are separated. The DAO is supplied to an FCC unit 106 having a low conversion activity catalyst for the removal of metals contained therein. The demetallized distillate fraction is supplied to a hydrotreater 110 for upgrading and collected as a synthetic crude product stream. The asphaltene fraction can be supplied to a gasifier 108 for the recovery of power, steam and hydrogen, which can be supplied to the hydrotreater 110 or otherwise within the process or exported. An optional coker 234 can be used to convert excess asphaltenes and/or decant oil to naphtha, distillate and gas oil, which can be supplied to the hydrotreater 220.Type: GrantFiled: August 30, 2004Date of Patent: June 3, 2008Assignee: Kellogg Brown & Root LLCInventors: Rashid Iqbal, Anshumali, Odette Eng, Phillip Niccum
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Publication number: 20080110805Abstract: Process and apparatus for the continuous separation of crude oil from tar sands include using a hydrocarbon diluent and an aqueous solution in one or more settling vessels. The light components from the oil are collected and recycled to be used as the hydrocarbon diluent, and the aqueous solution is collected and recycled. A second aqueous solution is introduced in the second and subsequent vessels to prevent the formation of an oil film on the equipment.Type: ApplicationFiled: November 7, 2007Publication date: May 15, 2008Inventors: Fred J. Veltri, John B. Fairbanks
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Publication number: 20080110804Abstract: Process and apparatus for the continuous separation of crude oil from tar sands include using a hydrocarbon diluent and an aqueous solution in one or more settling vessels. The light components from the oil are collected and recycled to be used as the hydrocarbon diluent, and the aqueous solution is collected and recycled. A second aqueous solution is introduced in the second and subsequent vessels to prevent the formation of an oil film on the equipment.Type: ApplicationFiled: November 7, 2007Publication date: May 15, 2008Inventors: Fred J. Veltri, John B. Fairbanks
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Publication number: 20080110803Abstract: Process and apparatus for the continuous separation of crude oil from tar sands include using a hydrocarbon diluent and an aqueous solution in one or more settling vessels. The light components from the oil are collected and recycled to be used as the hydrocarbon diluent, and the aqueous solution is collected and recycled. A second aqueous solution is introduced in the second and subsequent vessels to prevent the formation of an oil film on the equipment.Type: ApplicationFiled: November 7, 2007Publication date: May 15, 2008Inventors: Fred J. Veltri, John B. Fairbanks
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Patent number: 7357857Abstract: Bitumen extraction done using a process comprising: (a) preparing a bitumen froth comprising particulate mineral solids and hydrocarbons dispersed in aqueous lamella in the form of an emulsion; (b) adding a sufficient amount of a paraffinic solvent to the froth to induce inversion of the emulsion and precipitate asphaltenes from the resultant hydrocarbon phase; (c) mixing the froth and the solvent for a sufficient time to dissolve the solvent into the hydrocarbon phase to precipitate asphaltenes; and (d) subjecting the mixture to gravity or centrifugal separation for a sufficient period to separate substantially all of the water and solids and a substantial portion of the asphaltenes from the bitumen; wherein a separation enhancing additive is present in the process. The separation enhancing additive is a polymeric surfactant that has multiple lipophilic and hydrophilic moieties, which can effect easier handling of asphaltene sludges and less foaming during solvent recovery.Type: GrantFiled: November 29, 2004Date of Patent: April 15, 2008Assignee: Baker Hughes IncorporatedInventors: Paul R. Hart, Edward M. Maharajh
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Publication number: 20080060978Abstract: A method and system for handling tar sands and extracting bitumen or oil from the tar sands. The method includes the steps of depositing tar sands in a hopper assembly having a conical bottom. An organic solvent mixture is sprayed on the tar sands through a series of jets near the walls of the hopper. The oil or bitumen in the tar sands is dissolved by the organic solvent mixture. Sand from the tar sands is allowed to separate and fall toward the bottom of the hopper assembly. The sands and liquid in a slurry of fluid are transported from the hopper assembly to a rinse chamber. The slurry of fluid is delivered into the top of the rinse chamber tangentially to cause cyclonic action of the slurry in the rinsing chamber. Solvent introduced at the bottom of the rinse chamber and the solvent mixture is drawn from the top of the rinse chamber. Thereafter, the solvent and hydrocarbon liquid mixture is pumped to a separator in order to separate the oil and bitumen from the solvent.Type: ApplicationFiled: June 12, 2007Publication date: March 13, 2008Inventor: Paul Wegner
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Patent number: 7341658Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.Type: GrantFiled: April 17, 2003Date of Patent: March 11, 2008Assignee: Tatanium Corporation Inc.Inventor: Robert G. Reeves
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Patent number: 7338593Abstract: A drilling fluid for use in high oil viscosity formations containing tar, sand and oil entrained therein. The drilling fluid can be comprised of a polymer in an amount from between 0.05% and 5% by volume, a solvent in an amount from between 1% and 20% by volume and de-emulsifier in an amount from between 0.05% and 10% by volume.Type: GrantFiled: October 18, 2006Date of Patent: March 4, 2008Assignee: Q'MAX Solutions Inc.Inventors: Len Baltoiu, Flori Baltoiu, Brent Warren
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Publication number: 20070284283Abstract: A method for processing asphaltenes is disclosed. The method can include separating asphaltenes from an asphaltene-containing composition and oxidizing the separated asphaltenes to form oxidation products. Alternatively, the method can include oxidizing asphaltenes within an asphaltene-containing composition without first separating the asphaltenes. Once formed, the oxidation products can be combined with other hydrocarbons. The amount of oxidation can be limited to an amount sufficient to produce a mixture suitable for the desired application. This method can be used to upgrade asphaltenes from a variety of sources, including oil sands. The oxidation step can be performed, for example, by introducing an oxidizing agent and, in some cases, a catalyst into the asphaltenes. A solvent or miscibility agent also can be introduced to improve mixing between the oxidizing agent and the asphaltenes.Type: ApplicationFiled: June 8, 2006Publication date: December 13, 2007Inventors: Willem P. C. Duyvesteyn, Raymond L. Morley
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Patent number: 7294156Abstract: The invention relates to a process for splitting bitumen into two fractions and rendering a heavier bottom fraction as a useable emulsion fuel. The process is particularly effective in creating an alternate fuel to natural gas in a steam-based bitumen recovery process wherein bitumen is recovered from an underground reservoir.Type: GrantFiled: August 22, 2003Date of Patent: November 13, 2007Assignee: ExxonMobil Upstream Research CompanyInventors: Tapantosh Chakrabarty, Mainak Ghosh
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Patent number: 7141162Abstract: Discloses apparatus to perform a process to remove water and minerals from a bitumen froth output of a oil sands hot water extraction process. A bitumen froth feed stream is diluted with a solvent and supplied to a primary inclined plate separator stage, which separates the bitumen into an overflow stream providing a bitumen product output from the circuit and a bitumen depleted underflow stream. A primary cyclone stage, a secondary inclined plate separator stage and a secondary cyclone stage further process the underflow stream to produce a secondary bitumen recovery product stream and a recycle stream. The secondary bitumen recovery product steam is incorporated into and becomes part of the circuit bitumen product output stream. The recycle stream is incorporated into the bitumen froth feed stream for reprocessing by the circuit.Type: GrantFiled: November 29, 2002Date of Patent: November 28, 2006Assignee: Suncor Energy, Inc.Inventors: William Nicholas Garner, Donald Norman Madge, William Lester Strand
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Patent number: 7112311Abstract: A cooling method of a hydrotreating plant having a desulfurization section (1) including a furnace (12) for heating liquid to be processed, reactors (14, 15) for hydrotreating sulfur to generate hydrogen sulfide, a hydrogen sulfide absorber (19) for absorbing the hydrogen sulfide generated in the reactors (14, 15), and a compressor (21) for compressing and transferring fluid from the hydrogen sulfide absorber (19) toward the reactors (14, 15), the cooling method comprising the steps of gradually depressurizing the hydrotreating plant at the desulfurization section (1) to a pressure level at which reactor material does not embrittle and gas does not leak due to difference of mechanical thermal expansion in the plant after stopping supply of the liquid to be processed, operating the compressor (21) approximately at the maximum rotation number, and completely extinguishing burners (12A, 12B) in the furnace (12) during plant shutdown operation.Type: GrantFiled: October 31, 2001Date of Patent: September 26, 2006Assignees: Nippon Petroleum Refining Co., Ltd., Softard Industries Co., Ltd.Inventors: Yuji Yoshizumi, Hidekatsu Honda, Masayuki Shoji, Toshihiko Nasu, Katsuhiko Kawakami, Junichi Takano
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Patent number: 7090768Abstract: A surfactant for separating bitumen from sand includes an aqueous solution of hydrogen peroxide contacted with low rank coal. The low rank coal is preferably lignite. The surfactant may be used to clean bitumen, heavy oil and/or tar from sand, shale or clay at low concentrations and with mild agitation.Type: GrantFiled: June 25, 2003Date of Patent: August 15, 2006Inventors: Pat Page, Jack Monkman
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Patent number: 7008528Abstract: A process for continuously extracting oil from a solid or liquid oil-bearing material comprises (a) removing air from the extraction system, (b) introducing an inert gas into the extraction system at a pressure sufficient to maintain a normally gaseous solvent in liquid state, (c) introducing an oil-bearing material into a silo, (d) passing the oil-bearing material from the to a jet pump mixing device, (e) introducing a liquified normally gaseous solvent into the jet pump mixing device, (f) mixing the oil-bearing material and the solvent in the jet pump mixing device for a time sufficient to permit complete wetting of oil-bearing material by the solvent to form a mixture, (g) heating the mixture to near supercritical conditions; (h) passing the mixture through an extractor having a screw conveyor adapted to rotate at a first rpm range and a centrifugal drum adapted to rotate at a second rpm range, (i) treating the mixture within the extractor in such a manner that supercritical temperature and pressure are atType: GrantFiled: March 21, 2002Date of Patent: March 7, 2006Inventors: Allen R. Mitchell, Louis E. Routier, III
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Patent number: 6811683Abstract: A process for producing a diesel fuel stock from bitumen uses steam and a hydroisomerized diesel fraction produced by a gas conversion process, to respectively stimulate the bitumen production and increase the cetane number of a hydrotreated diesel fuel fraction produced by upgrading the bitumen, to form a diesel stock. The diesel stock is used for blending and forming diesel fuel.Type: GrantFiled: March 27, 2001Date of Patent: November 2, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Stephen Mark Davis, Michael Gerard Matturro
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Publication number: 20040164001Abstract: This invention monetizes bitumen reserves utilizing proven refining processes to ultimately produce, primarily, high quality refined oil products. At the same time, a unique operating sequence and mode of operation produces precursors, the primary building blocks, for the petrochemical, fertilizer and energy co-products markets. Essentially, in producing refined oil products, the feedstock requirements of associated industries are satisfied in such a manner that the integration of these entities produces a higher rate of return for the combined entity than the sum of each of the individual entities. Furthermore, the process is tailored with broad functionality as to be able to “dial for profit” dependent upon the agreed upon business for the integrated facility specific to a certain geographical area.Type: ApplicationFiled: February 25, 2003Publication date: August 26, 2004Inventor: William George Rhodey
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Patent number: 6746599Abstract: Diluent-diluted bitumen froth containing bitumen and naphtha diluent, hydrocarbons, water, sand and fines (collectively “dilfroth”) is fed into a vapor-tight gravity settler (‘splitter’) and temporarily retained to produce a bottom layer of tails comprising sand and middlings, a rag layer of discrete three-dimensional structures, each comprising hydrocarbons contained in a skin of fines, and a top layer of hydrocarbons containing small droplets of water and fines (‘raw dilbit’). The flux in the splitter is less than 6 m3/h of dilfroth fed per m2 of horizontal cross-sectional rag area. The in-coming dilfroth is fed directly into the splitter middlings. Demulsifier is added to the overflow stream of raw dilbit and the mixture is subjected to prolonged settling in a vapor-tight polisher tank, to produce polished dilbit containing less than 1.0 wt. % water and 0.3 wt. % solids. The splitter underflow tails, containing less than 15 wt.Type: GrantFiled: June 11, 2001Date of Patent: June 8, 2004Assignees: AEC Oil Sands Limited Partnership, Athabasca Oil Sands Investments Inc., Nexen Inc., Canadian Oil Sands Investments Inc., Gulf Canada Resources Limited, Imperial Oil Resources, Mocal Energy Limited, Murphy Oil Company Ltd., Petro-CanadaInventors: George Cymerman, Pat Dougan, Tom Tran, Jim Lorenz, Corey Mayr
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Patent number: 6712215Abstract: A method of solvent recovery from oil sand extraction plant tailings, using 180 degree opposing steam-assisted accelerating nozzles, impacting on each other's high velocity jets, thus creating an impact area at the point of collision, creating an exceedingly large number of small droplets having a very large surface area exposed to the depressurized environment inside the vessel in which the nozzles are mounted. The diluent thus escaping from the tiny droplets is collected from the vessel space and recovered by condensation in a surface condensor and returned to the process.Type: GrantFiled: July 16, 2001Date of Patent: March 30, 2004Inventor: Adolf Frederik Scheybeler
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Patent number: 6709573Abstract: Process and apparatus for extraction of oil and hydrocarbons from crushed hydrocarbonaceous solids, such as oil shale, involving the pyrolyzing of the crushed solids with liquid hydrocarbon and syn gas rich in hydrogen and carbon dioxide. Crushed hydrocarbonaceous solids are treated with liquid hydrocarbon and hot syn gas at an elevated temperature in a rotary kiln where the crushed solids are cascaded into the hot syn gas for sufficient time to strip the volatile liquids and gases found in the solids, removing the vaporized liquids, enriched syn gas and spent crushed solids from the kiln, fractionating the vaporized liquids and enriched syn gas into the desired fractions. The enriched syn gas is particularly suited for use in combined-cycle electricity generation and in the preparation of various by-products. The process efficiently recycles heat and energy to reduce harmful atmospheric emissions and reliance on external energy sources.Type: GrantFiled: July 12, 2002Date of Patent: March 23, 2004Inventor: Anthon L. Smith
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Publication number: 20040035755Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.Type: ApplicationFiled: April 17, 2003Publication date: February 26, 2004Applicant: Titanium Corporation Inc.Inventor: Robert G. Reeves
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Publication number: 20030183557Abstract: A method for treating tar separated from a liquid containing an aromatic hydroxybenzene obtained by acidolysis of a liquid containing an aromatic hydroperoxide, which comprises dissolving the tar with an alkaline aqueous solution.Type: ApplicationFiled: March 20, 2003Publication date: October 2, 2003Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Mamoru Seino, Shigefumi Tokumasu
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Patent number: 6549817Abstract: A process for regulating a centrifuge used for solid/liquid separation of sewage sludge commences by measuring the input variables of the operating point ot the centrifuge, the variables including 1) suspended matter content of the centrate; 2) the flow rate of sludge; 3) the flow rate of reagent; and 4) the value of torque of the motor of a conventional centrifuge. Operating zones are established, each of which is two dimensional relative to the input variables. Fuzzy logic rules are established, qualifying the operation of the centrifuge, the rules respectively corresponding to the zones. The rules are implemented in response to the input variable measurements, where actions on the sludge flow rate and reagent flow rate make it possible to bring the operating point into a particular zone of optimal and stable centrifuge operation.Type: GrantFiled: July 19, 2000Date of Patent: April 15, 2003Assignee: DegremontInventor: Jacques Audibert
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Patent number: 6527960Abstract: A process for separating oily films from sand particles carried in a solvent free water stream includes the use of a jet pump scrubber in a density classification tank to treat such oily coated particles at controlled operating temperatures above 65° C. whereby, at such controlled temperature, enhanced cavitation in the jet pump separates the oily film from the sand particles to form slop oil, the tank providing for recirculation of the particles through the jet pump before discharge.Type: GrantFiled: August 17, 2000Date of Patent: March 4, 2003Assignee: Canadian Environmental Equipment & Engineering Technologies, Inc.Inventors: Diana L. Bacon, Patrick J. Cochrane, Wade R Bozak, Roderick M. Facey
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Publication number: 20020173682Abstract: The present invention pertains to a process for the catalytic reduction of heavy oils, kerogens, plastics, bio-masses, sludges and organic wastes to light hydrocarbon liquids, carbon dioxide and amines, all in a single reaction vessel. Disclosed are multiple examples of an improved dendritic process for the reaction of variegate raw materials, and the separation and isolation of the products formed thereby. The invention takes advantage of the reduction in the number of profligate process steps, the cycle time for the reactions, and the capacity to separate the products using a dendritic process.Type: ApplicationFiled: August 21, 2001Publication date: November 21, 2002Inventors: Venanzio Di Tullio, Paul Herrbach
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Patent number: 6391190Abstract: Aerated bitumen froth obtained from oil sands must be deaerated so that it can be pumped through a pipeline. Mechanical shearing is effective to deaerate bitumen froth to an air content of below 10 volume percent. Mechanical deaeration of bitumen froth can be achieved either by passing the froth through a confining passageway and shearing the froth with an impeller while it is in the passageway or temporarily retaining the aerated froth in a tank and circulating it repeatedly through a pump.Type: GrantFiled: March 4, 1999Date of Patent: May 21, 2002Assignees: AEC Oil Sands, L.P., AEC Oil Sands Limited Partnership, Athabasco Oil Sands Investments Inc., Nexen Inc., Canadian Oil Sand Investments Inc., Conoco Oilsands Partnership, Imperial Oil Resources, Mocal Energy Limited, Murphy Oil Company Ltd., Petro-Canada Oil and GasInventors: Jonathan R. Spence, Kevin McDowell, Mike P. Wagner, Sean Sanders
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Patent number: 6383261Abstract: The present invention provides a process for the management of H2S containing gas streams and high alkalinity water streams in which process the H2S is selectively removed from the gas stream and combusted to form an SO2 rich waste gas stream. The SO2 gas stream is then scrubbed with the water stream to substantially remove the SO2 from the gas while subsequent treatment of the water such as softening or settling is improved.Type: GrantFiled: July 27, 2001Date of Patent: May 7, 2002Assignee: ExxonMobil Research and Engineering CompanyInventors: Ronald Damian Myers, John Brenton MacLeod, Norman A Chambers, Mainak Ghosh
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Patent number: 6358403Abstract: A process for recovery of hydrocarbon diluent from tailings produced in a bitumen froth treatment plant comprises introducing the tailings into a vacuum flash vessel maintained at a sufficiently low sub-atmospheric pressure to vaporize the major portion of the contained diluent and some water. The residual then pool near the bottom of the flash vessel. Steam is then introduced into the tailings pool for vaporizing residual diluent and some water.Type: GrantFiled: May 21, 1999Date of Patent: March 19, 2002Assignee: AEC Oil Sands, L.P.Inventors: Wayne Brown, Barry Bara, Sukhamoy Sarkar, Rodney Denton
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Patent number: 6358404Abstract: A method for recovery of hydrocarbon diluent from tailings produced in a bitumen froth treatment plant comprises introducing the tailings into a steam stripping vessel maintained at near atmospheric pressure, said vessel having a plurality of interior, vertically spaced shed decks, and distributing the tailings over said shed decks. Steam is introduced below the shed decks for vaporizing the major portion of the contained diluent and some water.Type: GrantFiled: May 21, 1999Date of Patent: March 19, 2002Assignee: AEC Oil Sands, L.P.Inventors: Wayne Brown, Michelle Portwood, Fran King, Barry Bara, Michael Wagner
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Patent number: 6319395Abstract: The invention relates to a continuous process for producing synthetic crude oil from oil bearing material, e.g., oil shale or tar sand, through continuous process for producing synthetic crude oil from bituminous tar sand or shale. The process includes treating the tar sand or shale to produce a fluidizable feed, feeding the fluidizable feed to a fluidized bed reactor, and fluidizing and reacting the fluidizable feed in the fluidized bed reactor with substantially only hydrogen.Type: GrantFiled: March 9, 2000Date of Patent: November 20, 2001Assignee: Chattanooga CorporationInventors: Chalmer G. Kirkbride, James A. Doyle, Fred Hildebrandt