Tar Sand Treatment With Liquid Patents (Class 208/390)
  • Patent number: 7569137
    Abstract: Processes and apparatus for the treatment of product streams from mineral processing operations, including the treatment of tailings which result from oil sand processing operations. The processes and apparatus relate to the recovery of a diluent solvent from bitumen froth tailings and to the thickening of tailings from a bitumen froth stream and a middlings stream resulting from an oil sand extraction process. In one aspect the processes and apparatus relate particularly to the recycling of product streams to maximize process efficiencies. In a second aspect the processes and apparatus relate particularly to the thickening of tailings to produce an underflow component, a clarified overflow component and an unclarified overflow component.
    Type: Grant
    Filed: April 12, 2004
    Date of Patent: August 4, 2009
    Assignee: Fort Hills Energy L.P.
    Inventors: Alexander William Hyndman, John Patrick Ringstrom, John Sharpe, Douglas Robert Bartlett, W. Scott Hindle, Chris L. Grant
  • Patent number: 7556715
    Abstract: An inline bitumen froth steam heater system is comprised of steam injection and static mixing devices. The steam heater system heats and de-aerates an input bitumen froth without creating downstream processing problems with the bitumen froth such as emulsification or live steam entrainment. The inline bitumen froth steam heater is a multistage unit that injects and thoroughly mixes the steam with bitumen resulting in an output bitumen material having a homogenous temperature of about 190° F. The heating system conditions a superheated steam supply to obtain saturated steam at about 300° F. The saturated steam is contacted with a bitumen froth flow and mixed in a static mixer stage. The static mixers provide a surface area and rotating action that allows the injected steam to condense and transfer its heat to the bitumen froth. The mixing action and the increase in temperature of the bitumen froth results in reduction in bitumen viscosity and also allows the release of entrapped air from the bitumen froth.
    Type: Grant
    Filed: April 16, 2004
    Date of Patent: July 7, 2009
    Assignee: Suncor Energy, Inc.
    Inventors: Les Gaston, Donald Norman Madge, William Lester Strand, Ian Noble, William Nicholas Garner, Mike Lam
  • Publication number: 20090145809
    Abstract: A method of removing bitumen from tar sands comprising contacting the tar sands with a first mixture comprising a petroleum distillate and an oxygenated solvent, and recovering a second mixture comprising (a) at least a portion of the petroleum distillate and oxygenated solvent from the first mixture, (b) bitumen and (c) sand having a reduced amount of bitumen.
    Type: Application
    Filed: December 10, 2007
    Publication date: June 11, 2009
    Applicant: Chevron Phillips Chemical Company LP
    Inventors: Sam B. Ledbetter, JR., Marshall D. Bishop, Bharat B. Patel
  • Publication number: 20090139905
    Abstract: A separation apparatus can include at least one endless cable. The cable can be wrapped around at least two revolvable cylindrical members a plurality of times. The wraps can form gaps between adjacent windings, which, along with the endless cable, can be used to facilitate separations processing. Additionally, the separation apparatus can optionally include a repositioning guide for each multiple wrap endless cable that can guide the endless cable in an endless route and prevent the cable from rolling off or falling off of the cylindrical members. Separation can be accomplished by oleophilic adherence to the cable, electrostatic adherence to the cable, and/or physical retention on the cable. This endless cable system can be particularly useful for separation of oil sand slurries, mass transfer operations, and physical separations.
    Type: Application
    Filed: November 30, 2007
    Publication date: June 4, 2009
    Inventor: Jan Kruyer
  • Patent number: 7540951
    Abstract: A process for preparation of synthetic crude from a deposit of heavy crude, comprises: (a) the extraction of heavy crude by technology using steam; (b) the separation of crude extract and water; (c) the separation of crude into at least one light fraction and one heavy fraction; (d) the conversion of the heavy fraction of separation into a lighter product, said converted product, and a residue; (e) optionally, the partial or total hydrotreatment of the converted product and/or the light fraction (or fractions) obtained during the separation c), (f) the combustion and/or gasification of the conversion residue; the converted product and the light fraction (or fractions) for separation, optionally having been subjected to a hydrotreatment e), constituting the synthetic crude; said combustion allowing the generation of steam and/or electricity and said gasification allowing the generation of hydrogen; the steam and/or electricity thus generated being used for the extraction a) and/or the electricity and/or hydrog
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: June 2, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Arnault Selmen, Thierry Gauthier, Mathieu Pinault, Eric Benazzi
  • Publication number: 20090120844
    Abstract: The present invention relates to a process for the simultaneous recovery and cracking/upgrading of oil from solids such as tar sand and oil shale. With this process a number of the obstacles with the existing technology are solved, and the process upgrades the oil into a lighter product than the existing technology, remove sulphur in the order of 40% and heavy metals in the order of 90%.
    Type: Application
    Filed: May 10, 2007
    Publication date: May 14, 2009
    Applicant: TARBLASTER AS
    Inventors: Olav Ellingsen, Bjarte Sorebo Ellingsen
  • Publication number: 20090090658
    Abstract: In a method for enhancing the efficiency of separation of bitumen from oil sands ore, lipids, lipid by-products, and lipid derivatives are used as process additives for ore-water slurry-based bitumen extraction processes or in situ bitumen recovery processes. The lipids, lipid by-products, and lipid derivatives act as surfactants reducing surface and interfacial tensions, thus promoting breakdown the oil sands ore structure and resultant liberation of bitumen from the ore. Lipid treatment does not deleteriously affect release water chemistry in bitumen recovery processes, and it does not appreciably affect the fuel value of recovered bitumen. Lipids which may be effectively used as additives include biodiesel, tall oil fatty acids, monoglycerides, vegetable oil, and soap water, and combinations thereof.
    Type: Application
    Filed: October 6, 2008
    Publication date: April 9, 2009
    Inventors: ZVONKO BURKUS, BAKI OZUM
  • Publication number: 20090020458
    Abstract: A method of treating tailings comprising a solids fraction and a hydrocarbon fraction is disclosed. A primary flow is supplied to a jet pump, the primary flow comprising water and less than 20% solids by mass. A secondary flow is supplied to a mixing chamber of the jet pump, the secondary flow comprising a slurry of water and tailings, the slurry comprising more solids by mass than the primary flow. The jet pump is operated using the primary flow such that the tailings are agitated to effect at least a partial phase separation of the hydrocarbon fraction from the tailings. The methods disclosed herein may also be applied to treat tailings ponds.
    Type: Application
    Filed: June 13, 2008
    Publication date: January 22, 2009
    Applicant: RJ OIL SANDS INC.
    Inventors: Wade Ralph Bozak, Michael E. Kessick, Roderick Michael Facey
  • Publication number: 20080277318
    Abstract: A process for the separation of bitumen oil from tar sands and the like. Slurry is supplied to a mixing chamber of a jet pump at an input end of the process. The slurry is agitated within the jet pump to effect a partial to full phase separation of the oil fraction from the solids fraction of the slurry. The partially to fully separated slurry is discharged into a pipeline and later into a hydrocyclone to effect a second phase separation of the slurry. One or more hydrocyclone separators may be used to separate the bitumen oil and liquid from the solids fraction.
    Type: Application
    Filed: July 28, 2008
    Publication date: November 13, 2008
    Applicant: RJ OIL SANDS INC.
    Inventors: Wade Ralph Bozak, Roderick Michael Facey
  • Patent number: 7438189
    Abstract: An apparatus for separating bitumen from a bitumen froth output of a oil sands hot water extraction process comprises an inclined plate separator (IPS) for providing a first bitumen separation stage and a cyclone for providing a second bitumen separation stage. The cyclone overflow is recycled to the IPS inlet.
    Type: Grant
    Filed: February 24, 2006
    Date of Patent: October 21, 2008
    Assignee: Suncor Energy, Inc.
    Inventors: William Nicholas Garner, Donald Norman Madge, William Lester Strand
  • Patent number: 7438807
    Abstract: Discloses apparatus to perform a process to remove water and minerals from a bitumen froth output of a oil sands hot water extraction process. A bitumen froth feed stream is diluted with a solvent and supplied to a primary inclined plate separator stage, which separates the bitumen into an overflow stream providing a bitumen product output from the circuit and a bitumen depleted underflow stream. A primary cyclone state, a secondary inclined plate separator stage and a secondary cyclone stage further process the underflow stream to produce a secondary bitumen recovery product stream and a recycle stream. The secondary bitumen recovery product stream is incorporated into and becomes part of the circuit bitumen product output stream. The recycle stream is incorporated into the bitumen froth feed stream for reprocessing by the circuit.
    Type: Grant
    Filed: July 13, 2006
    Date of Patent: October 21, 2008
    Assignee: Suncor Energy, Inc.
    Inventors: William Nicholas Garner, Donald Norman Madge, William Lester Strand
  • Patent number: 7431830
    Abstract: Staged crushing combined with water addition and mixing is practiced at the mine site to prepare an oil sand slurry ready for hydrotransport. More particularly, as-mined oil sand is crushed to conveyable size (e.g. —24?) using a mobile crusher. The pre-crushed ore product is conveyed to a dry ore surge bin. Ore is withdrawn from the bin and elevated to the upper end of a slurry preparation tower having downwardly aligned process components to enable gravity feed. The ore is further crushed in stages to pumpable size (e.g. —4?) by a stack of crushers and water is added during comminution. The ore and water are mixed in a mixing box and delivered to a pump box. The surge bin and tower are relocatable. Screening and oversize reject treatment have been eliminated to achieve compactness and enable relocatability.
    Type: Grant
    Filed: September 2, 2004
    Date of Patent: October 7, 2008
    Assignees: Canadian Oil Sands Limited Partnership, Canadian Oil Sands Limited, ConocoPhillips Oilsands Partnership II, Imperial Oil Resources, Mocal Energy Limited, Nexen Inc., Murphy Oil Company Ltd., Petro-Canada Oil and Gas
    Inventors: Ron Cleminson, David Fudge, Michael Carniato
  • Publication number: 20080223757
    Abstract: In a method for enhancing the efficiency of bitumen recovery from oil sands ore, CaO lime (or Ca(OH)2) is mixed into an oil sands ore-water slurry prior to or during the operation of slurry-based bitumen extraction processes. The lime is introduced at dosages effective to reduce the electro-chemical attraction between clay particles and bitumen in the slurry, thereby promoting detachment of clay particles from bitumen droplets in the ore-wafer slurry. This occurs because water-soluble asphaltic acids formed at the bitumen-water interface act as surfactants which reduce or eliminate the activity of Ca2+ and Mg2+ ions binding the clay particles and bitumen together. The detachment of clay particles promotes the attachment of air bubbles to the bitumen droplets, thereby forming a bitumen-rich froth which will float to the surface of the ore-water slurry, thus facilitating bitumen recovery.
    Type: Application
    Filed: March 14, 2008
    Publication date: September 18, 2008
    Applicant: APEX ENGINEERING INC.
    Inventor: Baki OZUM
  • Publication number: 20080217212
    Abstract: An apparatus for processing bitumen froth comprising a cyclone body having an elongated conical inner surface defining a cyclone cavity extending from an upper inlet region with a diameter DC to a lower apex outlet with a diameter DU of not less than about 40 mm; an inlet means forming an inlet channel extending into the upper inlet region of said cyclone cavity; and a vortex finder forming an overflow outlet of a diameter DO extending into the upper inlet region of said cyclone cavity toward said lower apex outlet and having a lower end extending an excursion distance below said inlet channel, said excursion distance being operable to permit a portion of bitumen that passes through said inlet channel to exit said overflow outlet without having to make a spiral journey down said cyclone cavity, wherein a lower end of the vortex finder within the cyclone cavity is disposed a free vortex height (FVH) distance from said lower apex outlet.
    Type: Application
    Filed: May 19, 2008
    Publication date: September 11, 2008
    Inventors: WILLIAM NICHOLAS GARNER, DONALD NORMAN MADGE, WILLIAM LESTER STRAND
  • Publication number: 20080210602
    Abstract: Various methods and systems for obtaining bitumen from tar sands are disclosed. The disclosed methods and/or systems can be used to economically achieve a high degree of bitumen recovery from tar sands. The method may include a primary leaching or extraction process that separates most of the bitumen from the tar sands and results in a bitumen-enriched component and a bitumen-depleted component. The bitumen-enriched component includes mainly solvent and bitumen. The bitumen-depleted component includes mainly water and mineral solids with some residual bitumen and solvent. The bitumen-depleted component may be mixed with liquefied petroleum gas, e.g., propane and/or butane, to further separate the residual solvent and bitumen. The disclosed system can include separators configured to separate the various components at the various stages in the process.
    Type: Application
    Filed: March 3, 2008
    Publication date: September 4, 2008
    Applicant: MARATHON OIL COMPANY
    Inventor: Willem PC Duyvesteyn
  • Patent number: 7419585
    Abstract: A process for upgrading a residua feedstock using a short vapor contact time thermal process unit comprised of a horizontal moving bed of fluidized hot particles. The residua feedstock is preferably atomized so that the Sauter mean diameter of the residua feedstock entering the reactor is less than about 2500 ?m. One or more horizontally disposed screws is preferably used to fluidize a bed of hot particles.
    Type: Grant
    Filed: January 6, 2003
    Date of Patent: September 2, 2008
    Assignee: Exxonmobil Research and Engineering Company
    Inventors: Peter S. Maa, Craig Y. Sabottke
  • Publication number: 20080190815
    Abstract: A method of recovering hydrocarbons from hydrocarbonaceous materials can include forming a constructed permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume having substantially permeable side walls and a substantially impermeable cap. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom without contamination or substantial leaching of materials outside of the impoundment. During heating the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.
    Type: Application
    Filed: February 8, 2008
    Publication date: August 14, 2008
    Inventors: Todd Dana, James W. Patten
  • Publication number: 20080190814
    Abstract: The present invention provides method for recovering fossil-based materials from oil sources using multifunctional, multipolymer surfactants. The invention also provides methods for reducing the loss of volatile organic compoiunds (VOCs) from oil storage containers using multifunctional, multipolymer surfactants. The multifunctional, multipolymer surfactants are characterized by a hydrophobic part and a hydrophilic part. The hydrophobic part of the polymer surfactants includes functionalities that impart a polarity of greater than 0 Debye to the hydrophobic part. The polymer surfactants are further characterized by molecular weights that are above their entanglement weights. The result is polymer surfactants with demulsifying characteristics.
    Type: Application
    Filed: February 9, 2007
    Publication date: August 14, 2008
    Inventor: Gerard Caneba
  • Publication number: 20080190816
    Abstract: A method of recovering hydrocarbons from hydrocarbonaceous materials can include forming a stationary permeability control infrastructure. This constructed infrastructure defines a substantially encapsulated volume. A comminuted hydrocarbonaceous material can be introduced into the control infrastructure to form a permeable body of hydrocarbonaceous material. The permeable body can be heated sufficient to remove hydrocarbons therefrom within a temperature range which is sufficient to substantially avoid formation of carbon dioxide or non-hydrocarbon leachates. During heating the hydrocarbonaceous material is substantially stationary as the constructed infrastructure is a fixed structure. Removed hydrocarbons can be collected for further processing, use in the process, and/or use as recovered.
    Type: Application
    Filed: February 8, 2008
    Publication date: August 14, 2008
    Inventors: Todd Dana, James W. Patten
  • Publication number: 20080169222
    Abstract: A process and composition for removing heavy oil and bitumen from oil sands is disclosed. The composition comprises an emulsion of d-limonene and water, with an anionic surfactant as an emulsifying agent. The emulsion is contacted with an oil sand slurry until the aqueous and hydrocarbon phases separate. The process may take place at temperatures less than about 80° C.
    Type: Application
    Filed: October 15, 2004
    Publication date: July 17, 2008
    Inventor: Kevin Ophus
  • Patent number: 7399406
    Abstract: Methods are disclosed for identifying and treating oil sand ores having degraded bitumen. This can be done by considering the location from which the ore is mined or its history, or by microscopic examination of a bitumen froth made from the ore, or by near-infrared spectroscopy. Ore which contains degraded bitumen is treated with at least 0.05 wt/wt % alkaline material, preferably 0.1 wt./wt % of such alkaline material, in the water addition step of a hot or warm water extraction process for the making of bitumen froth, such as the Clark process.
    Type: Grant
    Filed: May 2, 2002
    Date of Patent: July 15, 2008
    Assignee: Suncor Energy, Inc.
    Inventors: Randy Mikula, Vicente Munoz, Brad Bjornson, Doug Cox, Anita Marks
  • Patent number: 7381320
    Abstract: Disclosed is a process for the upgrading and demetallizing of heavy oils and bitumens. A crude heavy oil and/or bitumen feed is supplied to a solvent extraction process 104 wherein DAO and asphaltenes are separated. The DAO is supplied to an FCC unit 106 having a low conversion activity catalyst for the removal of metals contained therein. The demetallized distillate fraction is supplied to a hydrotreater 110 for upgrading and collected as a synthetic crude product stream. The asphaltene fraction can be supplied to a gasifier 108 for the recovery of power, steam and hydrogen, which can be supplied to the hydrotreater 110 or otherwise within the process or exported. An optional coker 234 can be used to convert excess asphaltenes and/or decant oil to naphtha, distillate and gas oil, which can be supplied to the hydrotreater 220.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: June 3, 2008
    Assignee: Kellogg Brown & Root LLC
    Inventors: Rashid Iqbal, Anshumali, Odette Eng, Phillip Niccum
  • Publication number: 20080110805
    Abstract: Process and apparatus for the continuous separation of crude oil from tar sands include using a hydrocarbon diluent and an aqueous solution in one or more settling vessels. The light components from the oil are collected and recycled to be used as the hydrocarbon diluent, and the aqueous solution is collected and recycled. A second aqueous solution is introduced in the second and subsequent vessels to prevent the formation of an oil film on the equipment.
    Type: Application
    Filed: November 7, 2007
    Publication date: May 15, 2008
    Inventors: Fred J. Veltri, John B. Fairbanks
  • Publication number: 20080110804
    Abstract: Process and apparatus for the continuous separation of crude oil from tar sands include using a hydrocarbon diluent and an aqueous solution in one or more settling vessels. The light components from the oil are collected and recycled to be used as the hydrocarbon diluent, and the aqueous solution is collected and recycled. A second aqueous solution is introduced in the second and subsequent vessels to prevent the formation of an oil film on the equipment.
    Type: Application
    Filed: November 7, 2007
    Publication date: May 15, 2008
    Inventors: Fred J. Veltri, John B. Fairbanks
  • Publication number: 20080110803
    Abstract: Process and apparatus for the continuous separation of crude oil from tar sands include using a hydrocarbon diluent and an aqueous solution in one or more settling vessels. The light components from the oil are collected and recycled to be used as the hydrocarbon diluent, and the aqueous solution is collected and recycled. A second aqueous solution is introduced in the second and subsequent vessels to prevent the formation of an oil film on the equipment.
    Type: Application
    Filed: November 7, 2007
    Publication date: May 15, 2008
    Inventors: Fred J. Veltri, John B. Fairbanks
  • Patent number: 7357857
    Abstract: Bitumen extraction done using a process comprising: (a) preparing a bitumen froth comprising particulate mineral solids and hydrocarbons dispersed in aqueous lamella in the form of an emulsion; (b) adding a sufficient amount of a paraffinic solvent to the froth to induce inversion of the emulsion and precipitate asphaltenes from the resultant hydrocarbon phase; (c) mixing the froth and the solvent for a sufficient time to dissolve the solvent into the hydrocarbon phase to precipitate asphaltenes; and (d) subjecting the mixture to gravity or centrifugal separation for a sufficient period to separate substantially all of the water and solids and a substantial portion of the asphaltenes from the bitumen; wherein a separation enhancing additive is present in the process. The separation enhancing additive is a polymeric surfactant that has multiple lipophilic and hydrophilic moieties, which can effect easier handling of asphaltene sludges and less foaming during solvent recovery.
    Type: Grant
    Filed: November 29, 2004
    Date of Patent: April 15, 2008
    Assignee: Baker Hughes Incorporated
    Inventors: Paul R. Hart, Edward M. Maharajh
  • Publication number: 20080060978
    Abstract: A method and system for handling tar sands and extracting bitumen or oil from the tar sands. The method includes the steps of depositing tar sands in a hopper assembly having a conical bottom. An organic solvent mixture is sprayed on the tar sands through a series of jets near the walls of the hopper. The oil or bitumen in the tar sands is dissolved by the organic solvent mixture. Sand from the tar sands is allowed to separate and fall toward the bottom of the hopper assembly. The sands and liquid in a slurry of fluid are transported from the hopper assembly to a rinse chamber. The slurry of fluid is delivered into the top of the rinse chamber tangentially to cause cyclonic action of the slurry in the rinsing chamber. Solvent introduced at the bottom of the rinse chamber and the solvent mixture is drawn from the top of the rinse chamber. Thereafter, the solvent and hydrocarbon liquid mixture is pumped to a separator in order to separate the oil and bitumen from the solvent.
    Type: Application
    Filed: June 12, 2007
    Publication date: March 13, 2008
    Inventor: Paul Wegner
  • Patent number: 7341658
    Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: March 11, 2008
    Assignee: Tatanium Corporation Inc.
    Inventor: Robert G. Reeves
  • Patent number: 7338593
    Abstract: A drilling fluid for use in high oil viscosity formations containing tar, sand and oil entrained therein. The drilling fluid can be comprised of a polymer in an amount from between 0.05% and 5% by volume, a solvent in an amount from between 1% and 20% by volume and de-emulsifier in an amount from between 0.05% and 10% by volume.
    Type: Grant
    Filed: October 18, 2006
    Date of Patent: March 4, 2008
    Assignee: Q'MAX Solutions Inc.
    Inventors: Len Baltoiu, Flori Baltoiu, Brent Warren
  • Publication number: 20070284283
    Abstract: A method for processing asphaltenes is disclosed. The method can include separating asphaltenes from an asphaltene-containing composition and oxidizing the separated asphaltenes to form oxidation products. Alternatively, the method can include oxidizing asphaltenes within an asphaltene-containing composition without first separating the asphaltenes. Once formed, the oxidation products can be combined with other hydrocarbons. The amount of oxidation can be limited to an amount sufficient to produce a mixture suitable for the desired application. This method can be used to upgrade asphaltenes from a variety of sources, including oil sands. The oxidation step can be performed, for example, by introducing an oxidizing agent and, in some cases, a catalyst into the asphaltenes. A solvent or miscibility agent also can be introduced to improve mixing between the oxidizing agent and the asphaltenes.
    Type: Application
    Filed: June 8, 2006
    Publication date: December 13, 2007
    Inventors: Willem P. C. Duyvesteyn, Raymond L. Morley
  • Patent number: 7294156
    Abstract: The invention relates to a process for splitting bitumen into two fractions and rendering a heavier bottom fraction as a useable emulsion fuel. The process is particularly effective in creating an alternate fuel to natural gas in a steam-based bitumen recovery process wherein bitumen is recovered from an underground reservoir.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: November 13, 2007
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Tapantosh Chakrabarty, Mainak Ghosh
  • Patent number: 7141162
    Abstract: Discloses apparatus to perform a process to remove water and minerals from a bitumen froth output of a oil sands hot water extraction process. A bitumen froth feed stream is diluted with a solvent and supplied to a primary inclined plate separator stage, which separates the bitumen into an overflow stream providing a bitumen product output from the circuit and a bitumen depleted underflow stream. A primary cyclone stage, a secondary inclined plate separator stage and a secondary cyclone stage further process the underflow stream to produce a secondary bitumen recovery product stream and a recycle stream. The secondary bitumen recovery product steam is incorporated into and becomes part of the circuit bitumen product output stream. The recycle stream is incorporated into the bitumen froth feed stream for reprocessing by the circuit.
    Type: Grant
    Filed: November 29, 2002
    Date of Patent: November 28, 2006
    Assignee: Suncor Energy, Inc.
    Inventors: William Nicholas Garner, Donald Norman Madge, William Lester Strand
  • Patent number: 7112311
    Abstract: A cooling method of a hydrotreating plant having a desulfurization section (1) including a furnace (12) for heating liquid to be processed, reactors (14, 15) for hydrotreating sulfur to generate hydrogen sulfide, a hydrogen sulfide absorber (19) for absorbing the hydrogen sulfide generated in the reactors (14, 15), and a compressor (21) for compressing and transferring fluid from the hydrogen sulfide absorber (19) toward the reactors (14, 15), the cooling method comprising the steps of gradually depressurizing the hydrotreating plant at the desulfurization section (1) to a pressure level at which reactor material does not embrittle and gas does not leak due to difference of mechanical thermal expansion in the plant after stopping supply of the liquid to be processed, operating the compressor (21) approximately at the maximum rotation number, and completely extinguishing burners (12A, 12B) in the furnace (12) during plant shutdown operation.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: September 26, 2006
    Assignees: Nippon Petroleum Refining Co., Ltd., Softard Industries Co., Ltd.
    Inventors: Yuji Yoshizumi, Hidekatsu Honda, Masayuki Shoji, Toshihiko Nasu, Katsuhiko Kawakami, Junichi Takano
  • Patent number: 7090768
    Abstract: A surfactant for separating bitumen from sand includes an aqueous solution of hydrogen peroxide contacted with low rank coal. The low rank coal is preferably lignite. The surfactant may be used to clean bitumen, heavy oil and/or tar from sand, shale or clay at low concentrations and with mild agitation.
    Type: Grant
    Filed: June 25, 2003
    Date of Patent: August 15, 2006
    Inventors: Pat Page, Jack Monkman
  • Patent number: 7008528
    Abstract: A process for continuously extracting oil from a solid or liquid oil-bearing material comprises (a) removing air from the extraction system, (b) introducing an inert gas into the extraction system at a pressure sufficient to maintain a normally gaseous solvent in liquid state, (c) introducing an oil-bearing material into a silo, (d) passing the oil-bearing material from the to a jet pump mixing device, (e) introducing a liquified normally gaseous solvent into the jet pump mixing device, (f) mixing the oil-bearing material and the solvent in the jet pump mixing device for a time sufficient to permit complete wetting of oil-bearing material by the solvent to form a mixture, (g) heating the mixture to near supercritical conditions; (h) passing the mixture through an extractor having a screw conveyor adapted to rotate at a first rpm range and a centrifugal drum adapted to rotate at a second rpm range, (i) treating the mixture within the extractor in such a manner that supercritical temperature and pressure are at
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: March 7, 2006
    Inventors: Allen R. Mitchell, Louis E. Routier, III
  • Patent number: 6811683
    Abstract: A process for producing a diesel fuel stock from bitumen uses steam and a hydroisomerized diesel fraction produced by a gas conversion process, to respectively stimulate the bitumen production and increase the cetane number of a hydrotreated diesel fuel fraction produced by upgrading the bitumen, to form a diesel stock. The diesel stock is used for blending and forming diesel fuel.
    Type: Grant
    Filed: March 27, 2001
    Date of Patent: November 2, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Stephen Mark Davis, Michael Gerard Matturro
  • Publication number: 20040164001
    Abstract: This invention monetizes bitumen reserves utilizing proven refining processes to ultimately produce, primarily, high quality refined oil products. At the same time, a unique operating sequence and mode of operation produces precursors, the primary building blocks, for the petrochemical, fertilizer and energy co-products markets. Essentially, in producing refined oil products, the feedstock requirements of associated industries are satisfied in such a manner that the integration of these entities produces a higher rate of return for the combined entity than the sum of each of the individual entities. Furthermore, the process is tailored with broad functionality as to be able to “dial for profit” dependent upon the agreed upon business for the integrated facility specific to a certain geographical area.
    Type: Application
    Filed: February 25, 2003
    Publication date: August 26, 2004
    Inventor: William George Rhodey
  • Patent number: 6746599
    Abstract: Diluent-diluted bitumen froth containing bitumen and naphtha diluent, hydrocarbons, water, sand and fines (collectively “dilfroth”) is fed into a vapor-tight gravity settler (‘splitter’) and temporarily retained to produce a bottom layer of tails comprising sand and middlings, a rag layer of discrete three-dimensional structures, each comprising hydrocarbons contained in a skin of fines, and a top layer of hydrocarbons containing small droplets of water and fines (‘raw dilbit’). The flux in the splitter is less than 6 m3/h of dilfroth fed per m2 of horizontal cross-sectional rag area. The in-coming dilfroth is fed directly into the splitter middlings. Demulsifier is added to the overflow stream of raw dilbit and the mixture is subjected to prolonged settling in a vapor-tight polisher tank, to produce polished dilbit containing less than 1.0 wt. % water and 0.3 wt. % solids. The splitter underflow tails, containing less than 15 wt.
    Type: Grant
    Filed: June 11, 2001
    Date of Patent: June 8, 2004
    Assignees: AEC Oil Sands Limited Partnership, Athabasca Oil Sands Investments Inc., Nexen Inc., Canadian Oil Sands Investments Inc., Gulf Canada Resources Limited, Imperial Oil Resources, Mocal Energy Limited, Murphy Oil Company Ltd., Petro-Canada
    Inventors: George Cymerman, Pat Dougan, Tom Tran, Jim Lorenz, Corey Mayr
  • Patent number: 6712215
    Abstract: A method of solvent recovery from oil sand extraction plant tailings, using 180 degree opposing steam-assisted accelerating nozzles, impacting on each other's high velocity jets, thus creating an impact area at the point of collision, creating an exceedingly large number of small droplets having a very large surface area exposed to the depressurized environment inside the vessel in which the nozzles are mounted. The diluent thus escaping from the tiny droplets is collected from the vessel space and recovered by condensation in a surface condensor and returned to the process.
    Type: Grant
    Filed: July 16, 2001
    Date of Patent: March 30, 2004
    Inventor: Adolf Frederik Scheybeler
  • Patent number: 6709573
    Abstract: Process and apparatus for extraction of oil and hydrocarbons from crushed hydrocarbonaceous solids, such as oil shale, involving the pyrolyzing of the crushed solids with liquid hydrocarbon and syn gas rich in hydrogen and carbon dioxide. Crushed hydrocarbonaceous solids are treated with liquid hydrocarbon and hot syn gas at an elevated temperature in a rotary kiln where the crushed solids are cascaded into the hot syn gas for sufficient time to strip the volatile liquids and gases found in the solids, removing the vaporized liquids, enriched syn gas and spent crushed solids from the kiln, fractionating the vaporized liquids and enriched syn gas into the desired fractions. The enriched syn gas is particularly suited for use in combined-cycle electricity generation and in the preparation of various by-products. The process efficiently recycles heat and energy to reduce harmful atmospheric emissions and reliance on external energy sources.
    Type: Grant
    Filed: July 12, 2002
    Date of Patent: March 23, 2004
    Inventor: Anthon L. Smith
  • Publication number: 20040035755
    Abstract: A process for recovering heavy minerals (e.g., titanium minerals such as TiO2) from a feedstock comprising tar sands or a tar sands-derived solids fraction. The feedstock comprises bitumen and heavy minerals. The process comprises the steps of: (i) contacting the solids fraction with water at a temperature of at least about 100° F. to cause production a bituminous phase and a heavy minerals phase; and (ii) separating the heavy minerals phase from the bituminous phase. Optionally, these steps may be preceded by one or more steps used to produce a tar-sands derived solids fraction from a tar sands feedstock.
    Type: Application
    Filed: April 17, 2003
    Publication date: February 26, 2004
    Applicant: Titanium Corporation Inc.
    Inventor: Robert G. Reeves
  • Publication number: 20030183557
    Abstract: A method for treating tar separated from a liquid containing an aromatic hydroxybenzene obtained by acidolysis of a liquid containing an aromatic hydroperoxide, which comprises dissolving the tar with an alkaline aqueous solution.
    Type: Application
    Filed: March 20, 2003
    Publication date: October 2, 2003
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Mamoru Seino, Shigefumi Tokumasu
  • Patent number: 6549817
    Abstract: A process for regulating a centrifuge used for solid/liquid separation of sewage sludge commences by measuring the input variables of the operating point ot the centrifuge, the variables including 1) suspended matter content of the centrate; 2) the flow rate of sludge; 3) the flow rate of reagent; and 4) the value of torque of the motor of a conventional centrifuge. Operating zones are established, each of which is two dimensional relative to the input variables. Fuzzy logic rules are established, qualifying the operation of the centrifuge, the rules respectively corresponding to the zones. The rules are implemented in response to the input variable measurements, where actions on the sludge flow rate and reagent flow rate make it possible to bring the operating point into a particular zone of optimal and stable centrifuge operation.
    Type: Grant
    Filed: July 19, 2000
    Date of Patent: April 15, 2003
    Assignee: Degremont
    Inventor: Jacques Audibert
  • Patent number: 6527960
    Abstract: A process for separating oily films from sand particles carried in a solvent free water stream includes the use of a jet pump scrubber in a density classification tank to treat such oily coated particles at controlled operating temperatures above 65° C. whereby, at such controlled temperature, enhanced cavitation in the jet pump separates the oily film from the sand particles to form slop oil, the tank providing for recirculation of the particles through the jet pump before discharge.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: March 4, 2003
    Assignee: Canadian Environmental Equipment & Engineering Technologies, Inc.
    Inventors: Diana L. Bacon, Patrick J. Cochrane, Wade R Bozak, Roderick M. Facey
  • Publication number: 20020173682
    Abstract: The present invention pertains to a process for the catalytic reduction of heavy oils, kerogens, plastics, bio-masses, sludges and organic wastes to light hydrocarbon liquids, carbon dioxide and amines, all in a single reaction vessel. Disclosed are multiple examples of an improved dendritic process for the reaction of variegate raw materials, and the separation and isolation of the products formed thereby. The invention takes advantage of the reduction in the number of profligate process steps, the cycle time for the reactions, and the capacity to separate the products using a dendritic process.
    Type: Application
    Filed: August 21, 2001
    Publication date: November 21, 2002
    Inventors: Venanzio Di Tullio, Paul Herrbach
  • Patent number: 6391190
    Abstract: Aerated bitumen froth obtained from oil sands must be deaerated so that it can be pumped through a pipeline. Mechanical shearing is effective to deaerate bitumen froth to an air content of below 10 volume percent. Mechanical deaeration of bitumen froth can be achieved either by passing the froth through a confining passageway and shearing the froth with an impeller while it is in the passageway or temporarily retaining the aerated froth in a tank and circulating it repeatedly through a pump.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: May 21, 2002
    Assignees: AEC Oil Sands, L.P., AEC Oil Sands Limited Partnership, Athabasco Oil Sands Investments Inc., Nexen Inc., Canadian Oil Sand Investments Inc., Conoco Oilsands Partnership, Imperial Oil Resources, Mocal Energy Limited, Murphy Oil Company Ltd., Petro-Canada Oil and Gas
    Inventors: Jonathan R. Spence, Kevin McDowell, Mike P. Wagner, Sean Sanders
  • Patent number: 6383261
    Abstract: The present invention provides a process for the management of H2S containing gas streams and high alkalinity water streams in which process the H2S is selectively removed from the gas stream and combusted to form an SO2 rich waste gas stream. The SO2 gas stream is then scrubbed with the water stream to substantially remove the SO2 from the gas while subsequent treatment of the water such as softening or settling is improved.
    Type: Grant
    Filed: July 27, 2001
    Date of Patent: May 7, 2002
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ronald Damian Myers, John Brenton MacLeod, Norman A Chambers, Mainak Ghosh
  • Patent number: 6358403
    Abstract: A process for recovery of hydrocarbon diluent from tailings produced in a bitumen froth treatment plant comprises introducing the tailings into a vacuum flash vessel maintained at a sufficiently low sub-atmospheric pressure to vaporize the major portion of the contained diluent and some water. The residual then pool near the bottom of the flash vessel. Steam is then introduced into the tailings pool for vaporizing residual diluent and some water.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: March 19, 2002
    Assignee: AEC Oil Sands, L.P.
    Inventors: Wayne Brown, Barry Bara, Sukhamoy Sarkar, Rodney Denton
  • Patent number: 6358404
    Abstract: A method for recovery of hydrocarbon diluent from tailings produced in a bitumen froth treatment plant comprises introducing the tailings into a steam stripping vessel maintained at near atmospheric pressure, said vessel having a plurality of interior, vertically spaced shed decks, and distributing the tailings over said shed decks. Steam is introduced below the shed decks for vaporizing the major portion of the contained diluent and some water.
    Type: Grant
    Filed: May 21, 1999
    Date of Patent: March 19, 2002
    Assignee: AEC Oil Sands, L.P.
    Inventors: Wayne Brown, Michelle Portwood, Fran King, Barry Bara, Michael Wagner
  • Patent number: 6319395
    Abstract: The invention relates to a continuous process for producing synthetic crude oil from oil bearing material, e.g., oil shale or tar sand, through continuous process for producing synthetic crude oil from bituminous tar sand or shale. The process includes treating the tar sand or shale to produce a fluidizable feed, feeding the fluidizable feed to a fluidized bed reactor, and fluidizing and reacting the fluidizable feed in the fluidized bed reactor with substantially only hydrogen.
    Type: Grant
    Filed: March 9, 2000
    Date of Patent: November 20, 2001
    Assignee: Chattanooga Corporation
    Inventors: Chalmer G. Kirkbride, James A. Doyle, Fred Hildebrandt