Split Feed Patents (Class 208/80)
  • Patent number: 12163096
    Abstract: A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; feeding the light stream to a first Fluid Catalytic Cracking (FCC) reaction zone; feeding the middle stream to a second FCC reaction zone; and feeding the hydrotreated heavy stream to a third FCC reaction zone, thereby producing a heavy product stream comprising light olefins; and feeding one or more of the product streams to one or more fractionators, thereby producing one or more finished product streams and one or more recycle streams comprising one or more of light cycle oil (LCO), heavy cycle oil (HCO), and slurry oil; and hydrotreating one or more of the recycle streams to form the hydrotreated heavy stream.
    Type: Grant
    Filed: February 2, 2023
    Date of Patent: December 10, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Ali Al Jawad, Qi Xu, Aaron Akah, Musaed Salem Al-Ghrami, Raed Hasan Abudawoud
  • Patent number: 11485917
    Abstract: According to at least one aspect of the present disclosure, a method for processing a heavy oil includes introducing the heavy oil to a hydroprocessing unit, the hydroprocessing unit being operable to hydroprocess the heavy oil to form a hydroprocessed effluent by contacting the heavy oil feed with an HDM catalyst, an HDS catalyst, and an HDA catalyst. The hydroprocessed effluent is passed directly to a HS-FCC unit, the HS-FCC unit being operable to crack the hydroprocessed effluent to form a cracked effluent comprising at least one product. The cracked effluent is passed out of the HS-FCC unit. The heavy oil has an API gravity of from 25 degrees to 50 degrees and at least 20 wt. % of the hydroprocessed effluent passed to the HS-FCC unit has a boiling point less than 225 degrees ° C.
    Type: Grant
    Filed: February 17, 2021
    Date of Patent: November 1, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami
  • Patent number: 11377609
    Abstract: A process for treatment of PFO from a steam cracking zone includes hydrodealkylating PFO or a portion thereof for conversion of polyaromatics compounds contained in the PFO into hydrodealkylated aromatic compounds with one benzene ring, a hydrodealkylated BTX+ stream. In addition, a naphtha reformer is integrated, so that the hydrodealkylated BTX+ stream and a reformate stream are separated into BTX compounds.
    Type: Grant
    Filed: October 30, 2019
    Date of Patent: July 5, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Raed Abudawoud, Qi Xu
  • Patent number: 11001766
    Abstract: A method for producing a diesel having improved cold flow properties, the method comprising the steps of introducing a crude oil to a distillation column, separating the crude oil in the distillation unit to produce a light gas oil, and a light vacuum gas oil, where the light gas oil has a T95% cut point in the range between 300 deg C. and 340 deg C., where the light vacuum gas oil has a T95% cut point in the range between 400 deg C. and 430 deg C., processing the light vacuum gas oil in the supercritical water unit to produce an upgraded vacuum gas oil, separating the upgraded vacuum gas oil in the fractionator to produce an upgraded light fraction, an upgraded light gas oil, and upgraded heavy fraction, introducing the upgraded light gas oil into a diesel pool, and blending the light gas oil into the diesel pool.
    Type: Grant
    Filed: February 14, 2018
    Date of Patent: May 11, 2021
    Inventors: Ki-Hyouk Choi, Vinod Ramaseshan, Mohnnad H. Alabsi
  • Patent number: 10899979
    Abstract: A process for producing olefins comprising introducing a steam cracker feed to a liquid steam cracker furnace section to produce a steam cracker product comprising olefins, and wherein an amount of olefins in the steam cracker product is greater than in the steam cracker feed; separating the steam cracker product in a separation unit into a hydrogen stream, a methane stream, an olefin gas stream (ethylene and propylene), a saturated gas stream (ethane and propane), a hydrocarbons gas stream (C4-5 hydrocarbons), an aromatics stream (C6-8 aromatic hydrocarbons), a raffinate stream (C6-8 non-aromatic hydrocarbons), and a heavies stream (C9+ hydrocarbons); feeding the hydrocarbons gas stream and hydrogen to one or more hydroprocessing reactors to produce a hydrocracking product comprising ethane and propane; and recycling the hydrocracking product and the saturated gas stream to the liquid steam cracker furnace section.
    Type: Grant
    Filed: August 14, 2018
    Date of Patent: January 26, 2021
    Assignee: Sabic Global Technologies, B.V.
    Inventors: Dustin Fickel, Travis Conant, Raul Velasco Pelaez, Kaushik Anil Gandhi
  • Patent number: 10577293
    Abstract: Processes and apparatuses for producing para-xylenes are provided. The processes comprises providing a hydrocarbon stream comprising C7+ hydrocarbons. The hydrocarbon stream is separated to provide a C8 aromatics stream and an ortho-xylene rich stream. The C8 aromatics stream is passed to a para-xylene separation unit for separating para-xylene to provide a para-xylene stream and a raffinate stream. At least a portion of the raffinate stream is passed to a first isomerization unit to provide a first isomerization effluent, wherein the first isomerization effluent is produced in the presence of an ethylbenzene (EB) isomerization catalyst. At least a portion of the ortho-xylene rich stream is contacted with an isomerization catalyst in a second isomerization unit in liquid phase at isomerization conditions in substantial absence of hydrogen to produce a second isomerization effluent.
    Type: Grant
    Filed: April 19, 2017
    Date of Patent: March 3, 2020
    Assignee: UOP LLC
    Inventors: Ashish Suresh Bambal, Anton N. Mlinar, James A. Johnson
  • Patent number: 10550336
    Abstract: The present disclosure provides methods and apparatus for catalytic cracking of hydrocarbon feed. The apparatus includes a plurality of stages, wherein hydrocarbon feed is introduced into a bottom stage reactor and flows in an overall upward direction. A reaction catalyst stream is introduced into a top stage reactor and flows in an overall downward direction. In each of the stages, the hydrocarbon feed is allowed to come in contact with the reaction catalyst stream received at the particular stage for cracking of the hydrocarbon feed. The final cracked product stream is obtained at an outlet of the top stage reactor and a final spent catalyst stream is obtained at an outlet of the bottom stage reactor.
    Type: Grant
    Filed: December 3, 2015
    Date of Patent: February 4, 2020
    Assignee: BHARAT PETROLEUM CORPORATION LIMITED
    Inventors: Ravi Kumar Voolapalli, Seetaram Chebrolu, Biswanath Saha
  • Patent number: 10513664
    Abstract: Aromatics extraction and hydrocracking processes are integrated with a stream pyrolysis unit to optimize the performance of the hydrocracking units by processing the aromatic-rich and aromatic-lean fractions separately in order to better control the hydrocracking operating severity and/or catalyst reactor volume design requirements.
    Type: Grant
    Filed: December 17, 2018
    Date of Patent: December 24, 2019
    Assignee: Saudi Arabian Oil Company
    Inventor: Omer Refa Koseoglu
  • Patent number: 10487276
    Abstract: Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include one or more naphtha fractions from hydroprocessing zones within the battery limits, including vacuum residue hydrocracking, within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feeds to the gas oil steam cracker include gas oil range intermediates from the vacuum gas oil hydroprocessing zone and the vacuum residue hydrocracking zone.
    Type: Grant
    Filed: November 17, 2017
    Date of Patent: November 26, 2019
    Assignee: Saudi Arabian Oil Company
    Inventors: Mohammed Saeed Al-Ghamdi, Bader BaHammam, Naif Al Osaimi, Sami Barnawi
  • Patent number: 10487275
    Abstract: Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include one or more naphtha fractions from hydroprocessing zones within the battery limits, including vacuum residue hydrocracking, within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feed to the gas oil steam cracker in certain embodiments includes gas oil range intermediates from the vacuum residue hydrocracking zone.
    Type: Grant
    Filed: November 17, 2017
    Date of Patent: November 26, 2019
    Assignee: Saudi Arabian Oil Company
    Inventors: Mohammed Saeed Al-Ghamdi, Bader BaHammam, Naif Al Osaimi, Sami Barnawi
  • Patent number: 10472574
    Abstract: Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include light products and naphtha from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feeds to the gas oil steam cracker include gas oil range intermediates from the vacuum gas oil hydroprocessing zone.
    Type: Grant
    Filed: November 17, 2017
    Date of Patent: November 12, 2019
    Assignee: Saudi Arabian Oil Company
    Inventors: Mohammed Saeed Al-Ghamdi, Bader BaHammam, Naif Al Osaimi, Sami Barnawi
  • Patent number: 10472580
    Abstract: Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and conversion of naphtha to chemical rich reformate. Feeds to the mixed feed steam cracker include light products from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Chemical reformate from straight run naphtha streams is used as an additional feed to the aromatics extraction zone and or the mixed feed steam cracker.
    Type: Grant
    Filed: November 17, 2017
    Date of Patent: November 12, 2019
    Assignee: Saudi Arabian Oil Company
    Inventors: Mohammed Saeed Al-Ghamdi, Bader BaHammam, Naif Al Osaimi, Sami Barnawi
  • Patent number: 10472579
    Abstract: Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include light products and naphtha from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feeds to the gas oil steam cracker include unconverted oil intermediates from vacuum gas oil hydrotreating.
    Type: Grant
    Filed: November 17, 2017
    Date of Patent: November 12, 2019
    Assignee: Saudi Arabian Oil Company
    Inventor: Mohammed Saeed Al-Ghamdi
  • Patent number: 9856421
    Abstract: The present invention provides a process for upgrading a heavy hydrocarbon mixture, said process comprising: i) dividing said heavy hydrocarbon mixture into at least a first portion and a second portion, wherein said first portion comprises 10-45% wt of the heavy hydrocarbon mixture and said second portion comprises 90-55% wt of the heavy hydrocarbon mixture; ii) thermally upgrading said first portion of heavy hydrocarbon mixture in an upgrader to produce a lighter hydrocarbon mixture; and iii) mixing said lighter hydrocarbon mixture with a heavy hydrocarbon mixture to produce an upgraded hydrocarbon mixture, wherein, on entry to said upgrader, the composition of said first portion of heavy hydrocarbon mixture is identical to that of said second portion of heavy hydrocarbon mixture.
    Type: Grant
    Filed: January 3, 2013
    Date of Patent: January 2, 2018
    Assignee: STATOIL PETROLEUM AS
    Inventors: Harald Vindspoll, Knut Vebjørn Grande, Carsten Frithjof Sørlie, Marianne Haugan
  • Patent number: 9550707
    Abstract: An integrated process comprising to convert crude oil, comprising: converting crude oil (10) in a feed preparation facility (800) by separating the crude oil to a gas fraction (101), liquid fraction (102), and first residuum fraction in an atmospheric distillation unit (100); separating the 1st residuum to a vacuum gas oil fraction (202) and a second residuum (201) in a vacuum distillation unit (200); converting the vacuum gas oil fraction to a CU gas fraction (301,401), a CU liquid fraction (302), and an CU higher boiling fraction (303,402) in a cracking unit (300,400); and processing the second residuum fraction to DCU gas oil/lighter fraction (501) in a coking unit (500); and steam cracking at least one of the gas fraction (101), liquid fraction (102), CU gas fraction (301,401), and DCU gas oil/lighter fraction (501) to the hydrocarbon products (920).
    Type: Grant
    Filed: April 3, 2013
    Date of Patent: January 24, 2017
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventors: Heinrich Manfred Schrod, Wilfried J. Petzny
  • Patent number: 9284495
    Abstract: One exemplary embodiment can be a process for fluid catalytic cracking. The process can include withdrawing a catalyst from a reaction vessel to replace a catalyst inventory over a period of about 10- about 35 days for maximizing propylene yield.
    Type: Grant
    Filed: March 20, 2009
    Date of Patent: March 15, 2016
    Assignee: UOP LLC
    Inventors: Lawrence L. Upson, Brian W. Hedrick, Keith Allen Couch
  • Patent number: 9243192
    Abstract: A method for producing aromatic hydrocarbons by bringing a feedstock derived from a fraction containing a light cycle oil produced in a fluid catalytic cracking into contact with a catalyst containing a crystalline aluminosilicate, wherein the proportion of the naphthene content within the feedstock is adjusted so as to be greater than the proportion of the naphthene content in the fraction containing the light cycle oil, and the contact between the feedstock and the catalyst is performed under a pressure within a range from 0.1 MPaG to 1.0 MPaG.
    Type: Grant
    Filed: March 26, 2010
    Date of Patent: January 26, 2016
    Assignee: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Shinichiro Yanagawa, Yuko Aoki, Kazuaki Hayasaka
  • Patent number: 9090836
    Abstract: The invention relates to upgraded pyrolysis products, processes for upgrading products obtained from hydrocarbon pyrolysis, equipment useful for such processes, and the use of upgraded pyrolysis products.
    Type: Grant
    Filed: August 31, 2012
    Date of Patent: July 28, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Stephen H. Brown, S. Mark Davis, Teng Xu, Keith G. Reed, Ananthakrishnan Bhasker
  • Patent number: 9023194
    Abstract: A process for reforming a feed composed of one or more hydrocarbon cuts containing 9 to 22 carbon atoms which includes, at least one first step for reforming the feed in at least one reforming unit, during which a stream of hydrogen is produced and at least one first step for distillation of the effluent from the reforming unit in the presence of a reforming catalyst in order to obtain 4 cuts. The 4 cuts are, a liquefied petroleum gas cut (LPG) (A), a C5-C8 cut: naphtha (B), a C9-C15 cut: densified kerosene (C), and a C16-C22 cut: densified gas oil cut (D). The invention also concerns the device for carrying out this process.
    Type: Grant
    Filed: October 26, 2011
    Date of Patent: May 5, 2015
    Assignee: IFP Energies nouvelles
    Inventors: Eric Sanchez, Jacques Rault, Pierre Yves Le Goff, Christophe Pierre, Joana Fernandes
  • Publication number: 20150027925
    Abstract: Methods are provided for producing a plurality of lubricant base oil products with an increased overall yield. Prior to the final hydrocracking stage for viscosity index uplift, a feed for making a lubricant base oil is fractionated in order to form at least a feed for making a lighter lubricant base oil and a feed for making a heavier lubricant base oil. The fractionation cut points are selected to so that the feed fraction for forming a light lubricant base oil has a higher Noack volatility and a lower viscosity than the desired targets for the lighter lubricant base oil. The feed fractions are then hydroprocessed separately to achieve desired properties. After hydroprocessing, a portion of the heavier base oil is blended into the light lubricant base oil to produce a blended base oil product. This returns the volatility and the viscosity of the blended base oil to the desired specifications.
    Type: Application
    Filed: September 21, 2011
    Publication date: January 29, 2015
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Eric D. Joseck, Michael Brian Carroll, David Mentzer, Sara M. Berberich, Yogi V. Shukla
  • Patent number: 8940154
    Abstract: A system and process for the preparation of high quality gasoline through recombination of catalytic hydrocarbon includes fractionator and extractor. The upper part of the fractionator is equipped with light petrol pipeline, the lower part of the fractionator is equipped with heavy petrol pipeline, the middle part of the fractionator is equipped with medium petrol pipeline. The medium petrol pipeline is connected with a medium petrol extractor, the upper part of the medium petrol extractor is connected with the medium petrol raffinate oil hydrogenation unit through the pipeline, the lower part of the medium petrol extractor is connected with the medium petrol aromatic hydrocarbon hydrogenation unit through the pipeline.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: January 27, 2015
    Inventor: Ranfeng Ding
  • Patent number: 8932451
    Abstract: Methods are provided for processing crude oil feeds with reduced or minimized energy usage, reduced or minimized numbers of processing steps, improved allocation of hydrogen, and reduced or minimized formation of low value products. The methods reduce or minimize the use of vacuum distillation, and in many aspects reduce or minimize the use of both atmospheric and vacuum distillation. The methods also reduce or minimize the use of coking and fluid catalytic cracking processes.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: January 13, 2015
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ramon A. Strauss, Stephen Harold Brown, Donald E. Stratton, Stefan Maria Willy Ceulemans
  • Patent number: 8926830
    Abstract: Processes for producing aromatics from a naphtha feedstream are provided. An exemplary process includes passing the feedstream to a fractionation unit, thereby generating a first stream including hydrocarbons having less than 8 carbon atoms and a second stream including hydrocarbons having at least 8 carbon atoms. The first stream is passed to a first reformer operated at a first set of reaction conditions to generate a first product stream. The first set of reaction conditions includes a first temperature and a first pressure. The second stream is passed to a second reformer operated at a second set of reaction conditions to generate a second product stream. The second set of reaction conditions includes a second temperature and a second pressure. The first pressure is lower than the second pressure.
    Type: Grant
    Filed: April 3, 2013
    Date of Patent: January 6, 2015
    Assignee: UOP LLC
    Inventors: Gregory J. Gajda, Mary J. Wier, Clayton Colin Sadler
  • Patent number: 8926829
    Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: January 6, 2015
    Assignee: UOP LLC
    Inventors: Manuela Serban, Antoine Negiz, Kurt M. VandenBussche, Mark D. Moser, David A. Wegerer, Gregory J. Gajda
  • Patent number: 8911616
    Abstract: One exemplary embodiment can be a hydrotreating process. The hydrotreating process can include providing a first feed stream having a coker naphtha with a bromine number of about 10-about 120, combining the first feed stream with a second feed stream having a straight run naphtha with a bromine number of less than about 10 to create a combined feed, providing the combined feed to a hydrotreating reactor having at least one catalyst bed, and separating a quench stream from the second feed stream and providing the quench stream after the at least one catalyst bed.
    Type: Grant
    Filed: April 26, 2011
    Date of Patent: December 16, 2014
    Assignee: UOP LLC
    Inventors: Soumendra Banerjee, Richard Hoehn, Srinivasa Gopalan Varadarajan
  • Patent number: 8906226
    Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: December 9, 2014
    Assignee: UOP LLC
    Inventors: Gregory J. Gajda, Kurt M. VandenBussche, Mark D. Moser, David A. Wegerer
  • Patent number: 8900443
    Abstract: Methods for processing a hydrocarbonaceous feedstock flows are provided. In one embodiment, the method includes providing two or more hydroprocessing stages disposed in sequence, each hydroprocessing stage having a hydroprocessing reaction zone with a hydrogen requirement and each stage in fluid communication with the preceding stage. The hydrocarbonaceous feedstock flow may be separated into portions of fresh feed for each hydroprocessing stage, and the first portion of fresh feed to the first hydroprocessing stage is heated. The heated first portion of fresh feed may be supplied with hydrogen from the hydrogen source in an amount satisfying substantially all of the hydrogen requirements of the hydroprocessing stages to a first hydroprocessing zone. The unheated second portion of fresh feed is injected counter current to the process flow as quench at one or more locations in one or more of the reaction zones.
    Type: Grant
    Filed: April 6, 2012
    Date of Patent: December 2, 2014
    Assignee: UOP LLC
    Inventors: Paul A. Sechrist, Robert L. Bunting, Nicholas W. Bridge
  • Patent number: 8882994
    Abstract: A process is presented for the increasing the yields of aromatics from reforming a hydrocarbon feedstream. The process includes splitting a naphtha feedstream into a light hydrocarbon stream, and a heavier stream having a relatively rich concentration of naphthenes. The heavy stream is reformed to convert the naphthenes to aromatics and the resulting product stream is further reformed with the light hydrocarbon stream to increase the aromatics yields. The process includes passing a catalyst stream in a counter-current flow relative to the hydrocarbon process stream.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: November 11, 2014
    Assignee: UOP LLC
    Inventors: Mark D. Moser, David A. Wegerer, Kurt M. VandenBussche, Manuela Serban, Mark P. Lapinski, Mary Jo Wier, Gregory J. Gajda
  • Patent number: 8877042
    Abstract: The production of light hydrocarbons consisting of ethylene, propylene, butylenes, and of gasoline is enhanced by introducing a heavy oil feedstream derived from an external source into an ancillary downflow reactor that utilizes the same catalyst composition as an adjacent FCC unit for cracking the heavy oil and withdrawing the desired lighter hydrocarbon reaction product stream from the downflow reactor and regenerating the catalyst in the same regeneration vessel that is used to regenerate the spent catalyst from the FCC unit. The efficiency of the recovery of the desired lighter olefinic hydrocarbons is maximized by limiting the feedstream to the downflow reactor to heavy oils that can be processed under relatively harsher conditions, while minimizing production of undesired by-products.
    Type: Grant
    Filed: May 19, 2011
    Date of Patent: November 4, 2014
    Assignees: Saudi Arabian Oil Company, Nippon Oil Corporation
    Inventors: Christopher F. Dean, Yuichiro Fujiyama, Takata Okuhara
  • Patent number: 8845883
    Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: September 30, 2014
    Assignee: UOP LLC
    Inventors: Gregory J. Gajda, Kurt M. VandenBussche, Mark D. Moser, David A. Wegerer
  • Patent number: 8845884
    Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
    Type: Grant
    Filed: March 10, 2012
    Date of Patent: September 30, 2014
    Assignee: UOP LLC
    Inventors: Gregory J. Gajda, Mary Jo Wier, Mark P. Lapinski, David A. Wegerer, Kurt M. VandenBussche, Mark D. Moser
  • Publication number: 20140221712
    Abstract: Integrated processes for upgrading crude shale-derived oils, such as those produced by oil shale retorting or by in situ extraction or combinations thereof. Processes disclosed provide for a split-flow processing scheme to upgrade whole shale oil. The split flow concepts described herein, i.e., naphtha and kerosene hydrotreating in one or more stages and gas oil hydrotreating in one or more stages, requires additional equipment as compared to the alternative approach of whole oil hydrotreating. While contrary to conventional wisdom as requiring more capital equipment to achieve the same final product specifications, the operating efficiency vis a vis on-stream time efficiency and product quality resulting from the split flow concept far exceed in value the somewhat incrementally higher capital expenditure costs.
    Type: Application
    Filed: February 1, 2013
    Publication date: August 7, 2014
    Applicant: LUMMUS TECHNOLOGY INC.
    Inventors: Marvin I. Greene, Ujjal K. Mukherjee, Arun Arora
  • Publication number: 20140221713
    Abstract: A process for upgrading residuum hydrocarbons and decreasing tendency of the resulting products toward asphaltenic sediment formation in downstream processes is disclosed. The process may include: contacting a residuum hydrocarbon fraction and hydrogen with a hydroconversion catalyst in a hydrocracking reaction zone to convert at least a portion of the residuum hydrocarbon fraction to lighter hydrocarbons; recovering an effluent from the hydrocracking reaction zone; contacting hydrogen and at least a portion of the effluent with a resid hydrotreating catalyst; and separating the effluent to recover two or more hydrocarbon fractions.
    Type: Application
    Filed: February 4, 2013
    Publication date: August 7, 2014
    Applicant: LUMMUS TECHNOLOGY INC.
    Inventors: Mario C. Baldassari, Ujjal K. Mukherjee, Ann-Marie Olsen, Marvin I. Greene
  • Publication number: 20140110308
    Abstract: In an FCC process and system, a whole crude oil feedstock is directly converted into light olefins and other products. The feed is separated into a high boiling fraction and a low boiling fraction, and each fraction is processed in separate FCC downflow reactors. The catalyst, combined from both downflow reactors, is regenerated in a common vessel. The low carbon content in the catalyst particles from the low boiling fraction downflow reactor is insufficient to provide the necessary heat. By combining catalyst particles from the high boiling fraction having high carbon content helps to provide additional heat for regeneration.
    Type: Application
    Filed: October 10, 2013
    Publication date: April 24, 2014
    Applicant: Saudi Arabian Oil Company
    Inventors: Abdennour Bourane, Musaed Salem Al-Ghrami, Ibrahim A. Abba, Wei Xu, Kareemuddin M. Shaik
  • Patent number: 8696888
    Abstract: The invention concerns integration of hydroprocessing and steam cracking. A feed comprising crude or resid-containing fraction thereof is severely hydrotreated and passed to a steam cracker to obtain an olefins product.
    Type: Grant
    Filed: October 17, 2006
    Date of Patent: April 15, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Paul F. Keusenkothen, Megan L. Renstrom, Julian A. Wolfenbarger, Stephen H. Brown, John S. Buchanan
  • Patent number: 8668823
    Abstract: This invention relates to methods and units for mitigation of carbon oxides during hydrotreating hydrocarbons including mineral oil based streams and biological oil based streams. A hydrotreating unit includes a first hydrotreating reactor for receiving a mineral oil based hydrocarbon stream and forming a first hydrotreated product stream, and a second hydrotreating reactor for receiving a biological oil based hydrocarbon stream and forming a second hydrotreated product stream.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: March 11, 2014
    Assignee: BP Corporation North America Inc.
    Inventors: Nicholas J. Gudde, John W. Shabaker
  • Patent number: 8604262
    Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.
    Type: Grant
    Filed: March 9, 2012
    Date of Patent: December 10, 2013
    Assignee: UOP LLC
    Inventors: David A. Wegerer, Kurt M. Vanden Bussche, Mark D. Moser
  • Patent number: 8603324
    Abstract: The present invention relates to a method of hydro-upgrading inferior gasoline through ultra-deep desulfurization and octane number recovery. The method comprises the following steps: cutting inferior full-range gasoline into light fraction gasoline and heavy fraction gasolines; contacting the light fraction gasoline successively with a catalyst for selective diene removal and a catalyst for desulfurization and hydrocarbon multi-branched-chain hydroisomerization; contacting the heavy fraction gasoline with the catalyst for selective hydrodesulfurization in a first reactor, and contacting the reaction effluent from the first reactor with a catalyst for supplemental desulfurization and hydrocarbon aromatization/single-branched-chain hydroisomerization in a second reactor; and blending the treated light fraction gasoline and the heavy fraction gasoline to obtain the ultra-clean gasoline product.
    Type: Grant
    Filed: March 17, 2010
    Date of Patent: December 10, 2013
    Assignee: China University of Petroleum—Bejing (CUPB)
    Inventors: Yu Fan, Xiaojun Bao, Gang Shi, Haiyan Liu
  • Patent number: 8597494
    Abstract: The present invention relates to a method for producing ultra-clean gasoline. The invention provides a method of hydro-upgrading inferior gasoline through deep desulfurization and octane number recovery, which comprises the following steps: cutting inferior full-range gasoline into the light and heavy fraction gasolines; contacting the light fraction gasoline successively with a catalyst for selective diene removal and a catalyst for desulfurization and hydrocarbon aromatization/single-branched-chain hydroisomerization; contacting the heavy fraction gasoline with a catalyst for selective hydrodesulfurization, and contacting the reaction effluent with a catalyst for supplemental desulfurization and hydrocarbon multi-branched-chain hydroisomerization; and blending the treated light and heavy fraction gasolines to obtain the ultra-clean gasoline product.
    Type: Grant
    Filed: March 17, 2010
    Date of Patent: December 3, 2013
    Assignee: China University of Petroleum—Beijing (CUPB)
    Inventors: Yu Fan, Xiaojun Bao, Gang Shi, Haiyan Liu
  • Patent number: 8586812
    Abstract: Processes for upgrading condensate in a first hydrocarbon stream to provide distillate material may involve ionic liquid catalyzed olefin oligomerization of olefins in the first hydrocarbon stream to provide a first distillate enriched stream, dechlorination of the first distillate enriched stream, hydroprocessing at least one of a second and a third hydrocarbon stream to provide a second distillate enriched stream, and separation of a distillate product from the first and second distillate enriched streams.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: November 19, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Hye-Kyung C. Timken, Bi-Zeng Zhan
  • Publication number: 20130248421
    Abstract: An integrated hydroprocessing and fluid catalytic cracking process is provided for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals. Crude oil and hydrogen are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity. The hydroprocessed effluent is separated into a low boiling fraction and a high boiling fraction. The low boiling fraction is cracked in a first downflow reactor of a fluid catalytic cracking unit in the presence of a predetermined amount of catalyst to produce cracked products and spent catalyst, and the high boiling fraction is cracked in a second downflow reactor of the fluid catalytic cracking unit in the presence of a predetermined amount of catalyst to produce cracked products and spent catalyst.
    Type: Application
    Filed: March 20, 2013
    Publication date: September 26, 2013
    Applicant: SAUDI ARABIAN OIL COMPANY
    Inventors: Ibrahim A. ABBA, Raheel SHAFI, Abdennour BOURANE, Essam SAYED
  • Publication number: 20130206644
    Abstract: A method for producing diesel fuel with improved yield and quality by integration of fluidized catalytic cracking (FCC) and hydrocracking (HC), comprising the following stages: arrangement of FCC and HC processes in parallel; feedstock segregation to each of such processes depending on the content of aromatic hydrocarbons; and a fractioning common stage for both output streams from HC and FCC processes, also comprising recycling the unconverted fraction towards the FCC unit.
    Type: Application
    Filed: February 13, 2013
    Publication date: August 15, 2013
    Applicant: YPF S.A.
    Inventor: YPF S.A.
  • Publication number: 20130105361
    Abstract: A nozzle reactor system for increasing the conversion rate of material feed injected into the nozzle reactor system. The system includes two or more nozzle reactors aligned in parallel. A main stream of material to be upgraded is divided such that one stream is produced for each nozzle reactor in the system. Each nozzle reactor includes an interior reactor chamber and an injection passage and material feed passage that are each in material injecting communication with the interior reactor chamber. Furthermore, the injection passage is aligned transversely to the injection passage. The injection passage is configured to accelerate cracking material passed therethrough to a supersonic speed. The product produced from each of the nozzle reactors is combined into one product stream.
    Type: Application
    Filed: October 29, 2012
    Publication date: May 2, 2013
    Applicant: MARATHON OIL CANADA CORPORATION
    Inventors: Jose Armando Salazar, Mahendra Joshi, Christopher Daniel Ard
  • Publication number: 20130068659
    Abstract: Aromatic extraction and hydrocracking processes are integrated to optimize the hydrocracking units design and/or performance. By processing aromatics-rich and aromatic-lean fractions separately, the hydrocracking operating severity and or catalyst reactor volume requirement decreases.
    Type: Application
    Filed: July 27, 2012
    Publication date: March 21, 2013
    Inventor: Omer Refa KOSEOGLU
  • Publication number: 20130062254
    Abstract: Aromatic extraction and hydrocracking processes are integrated to optimize the hydrocracking units design and/or performance. By processing aromatic-rich and aromatic-lean fractions separately, the hydrocracking operating severity and/or catalyst reactor volume requirement decreases.
    Type: Application
    Filed: July 27, 2012
    Publication date: March 14, 2013
    Inventor: Omer Refa KOSEOGLU
  • Publication number: 20130056394
    Abstract: A process for hydroconversion-distillation of heavy and/or extra-heavy crude oils, which comprises four stages: 1) desalting and separation of the feedstock; 2) catalytic hydrotreating of light fraction (optional); 3) catalytic hydroconversion of heavy fraction, and 4) distillation of hydrotreated products to provide products that can be processed in conventional refining schemes designed to operate with light and intermediate crude oils.
    Type: Application
    Filed: August 30, 2012
    Publication date: March 7, 2013
    Applicant: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Jorge ANCHEYTA JUAREZ, Jose Antonio Domingo MUNOZ MOYA, Luis Carlos CASTANEDA LOPEZ, Sergio RAMIREZ AMADOR, Gustavo Jesus MARROQUIN SANCHEZ, Guillermo CENTENO NOLASCO, Fernando ALONSO MARTINEZ, Rodolfo Antonio AGUILAR ESCALANTE
  • Publication number: 20130026065
    Abstract: An integrated process and system for conversion of a heavy crude oil to produce transportation fuels is provided. The process includes separating the hydrocarbon feed into an aromatic-lean fraction and an aromatic-rich fraction. The aromatic-rich fraction is hydrocracked under relatively high pressure to convert at least a portion of refractory aromatic organosulfur and organonitrogen compounds and to produce a hydrocracked product stream. Unconverted bottoms effluent is recycled to the aromatic separation step. The aromatic-lean fraction is cracked in a fluidized catalytic cracking reaction zone to produce a cracked product stream, a light cycle oil stream and a heavy cycle oil stream. In certain embodiments the aromatic-lean fraction can be hydrotreated prior to fluidized catalytic cracking.
    Type: Application
    Filed: July 25, 2012
    Publication date: January 31, 2013
    Inventor: Omer Refa Koseoglu
  • Publication number: 20130015100
    Abstract: This invention relates to systems and methods for catalytic steam cracking of non-asphaltene containing heavy hydrocarbon fractions. The method enables upgrading heavy hydrocarbons to hydrocarbons capable of being transported through pipelines and/or a pretreated step before further treatment in an upgrading refinery, including the steps of separating the heavy hydrocarbon mixture into a light fraction, a full gasoil fraction and a vacuum residue fraction with or without at least partial reduction or asphaltenes; adding a catalyst to the full gasoil and/or to the blend of this with a reduced asphaltenes fraction and subjecting the catalyst-full gasoil and/or deasphalted oil fraction to catalytic steam cracking to form an effluent stream; separating the effluent stream into a gas stream and a liquid stream; and mixing the liquid stream with the light fraction and the vacuum residue fraction to form an upgraded oil. The system includes hardware capable of performing the method.
    Type: Application
    Filed: June 28, 2012
    Publication date: January 17, 2013
    Applicant: Nexen Inc.
    Inventors: Pedro Pereira Almao, Gustavo Luis Trujillo, Enzo Peluso, Carmen Galarraga, Clementina Sosa, Carlos Scott Algara, Francisco Lopez-Linares, Lante Antonio Carbognani Ortega, Nestor Gregorio Zerpa Reques
  • Patent number: 8333884
    Abstract: Partial conversion hydrocracking process comprising the steps of (a) hydrotreating a hydrocarbon feedstock with a hydrogen-rich gas to produce a hydrotreated effluent stream comprising a liquid/vapor mixture and separating the liquid/vapor mixture into a liquid phase and a vapor phase, and (b) separating the liquid phase into a controlled liquid portion and an excess liquid portion, and (c) combining the vapor phase with the excess liquid portion to form a vapor plus liquid portion, and (d) separating an FCC feed-containing fraction from the controlled liquid portion and simultaneously hydrocracking the vapor plus liquid portion to produce a diesel-containing fraction, or hydrocracking the controlled liquid portion to produce a diesel-containing fraction and simultaneously separating a FCC feed-containing fraction from the vapor plus liquid portion. The invention also includes an apparatus for carrying out the partial conversion hydrocracking process.
    Type: Grant
    Filed: November 23, 2009
    Date of Patent: December 18, 2012
    Assignee: Haldor Topsoe A/S
    Inventors: Michael Glenn Hunter, Angelica Hidalgo Vivas, Lars Skov Jensen, Gordon Gongngai Low
  • Publication number: 20120168348
    Abstract: A process for cracking a heavy hydrocarbon feed comprising a vaporization step, a catalytic cracking step, a hydrotreating step, and a steam cracking step is disclosed. The heavy hydrocarbon feed is passed to a first zone of a vaporization unit to separate a first vapor stream and a first liquid stream. The first liquid stream is passed to a second zone of the vaporization unit and contacted with a counter-current steam to produce a second vapor stream and a second liquid stream. The first vapor stream and the second vapor stream are cracked in the radiant section of the steam cracker to produce a cracked effluent. The second liquid stream is catalytically cracked to produce a cracked product. The cracked product is distilled to produce a overhead stream, a light cycle oil, and a heavy cycle oil. The light cycle oil is reacted with hydrogen in the presence of a catalyst to produce a hydrotreated light cycle oil. The hydrotreated light cycle oil and the overhead stream are fed to the vaporization unit.
    Type: Application
    Filed: December 29, 2010
    Publication date: July 5, 2012
    Inventor: Steven T. Coleman