Solvent Extraction Patents (Class 208/96)
  • Patent number: 4397734
    Abstract: Process for the preparation of a heavy oil with a low Ramsbottom Carbon Test (RCT) from a short residue by (a) catalytic hydrotreatment for RCT reduction at such severity that the C.sub.4.sup.- gas production per percentage RCT reduction is kept between defined limits, followed by (b) solvent deasphalting of the (vacuum or atmospheric) distillation residue of the hydrotreated product.
    Type: Grant
    Filed: June 15, 1982
    Date of Patent: August 9, 1983
    Assignee: Shell Oil Company
    Inventors: Jacobus Eilers, Willem H. J. Stork
  • Patent number: 4396493
    Abstract: In the preparation of a heavy oil with a low Ramsbottom Carbon Test (RCT) from a short residue by a two-stage process comprising catalytic hydrotreatment followed by solvent deasphalting and recycle of the asphalt to the first stage, the catalytic hydrotreatment for RCT reduction in the first stage is carried out at such severity that the C.sub.4.sup.- production per percent RCT reduction is kept between defined limits.
    Type: Grant
    Filed: June 24, 1982
    Date of Patent: August 2, 1983
    Assignee: Shell Oil Company
    Inventors: Jacobus Eilers, Willem H. J. Stork
  • Patent number: 4396494
    Abstract: In the preparation of a heavy oil with a low Ramsbottom Carbon Test (RCT) from a precipitation asphalt by a two-stage process comprising catalytic hydrotreatment followed by solvent deasphalting and recycle of the separated asphalt to the first stage, the catalytic hydrotreatment for RCT reduction in the first stage is carried out at such severity that the C.sub.4.sup.- gas production per percent RCT reduction is kept between defined limits.
    Type: Grant
    Filed: June 24, 1982
    Date of Patent: August 2, 1983
    Assignee: Shell Oil Company
    Inventors: Jacobus Eilers, Willem H. J. Stork
  • Patent number: 4389302
    Abstract: A process for producing additional liquid products from a heavy hydrocarbon material by vis-breaking of a separated asphaltene-containing fraction under controlled conditions of temperature and pressure. The asphaltene-containing fraction is obtained by contacting the heavy hydrocarbon material with a first solvent under elevated temperature and pressure conditions to separate the asphaltenes as a heavy phase from the remainder of the heavy hydrocarbon material. The products of the vis-breaking operation comprise distillable and substantially nondistillable liquid products in association with a residue including organometallic compounds. The distillable and substantially nondistillable liquid products then are separated from the residue. The distillable products can be separated by distillation. The nondistillable products are separated from the residue employing a second solvent maintained under elevated temperature and pressure conditions and then recovered as a liquid phase product.
    Type: Grant
    Filed: May 15, 1981
    Date of Patent: June 21, 1983
    Assignee: Kerr-McGee Refining Corporation
    Inventors: Leo Garwin, Roger A. Baldwin
  • Patent number: 4364819
    Abstract: A process for the conversion of an asphaltene-containing, hydrocarbonaceous black oil in a catalytic slurry reaction zone wherein an admixture of converted hydrocarbonaceous oil and deasphalter solvent is recycled to the reaction zone.
    Type: Grant
    Filed: April 24, 1981
    Date of Patent: December 21, 1982
    Assignee: UOP Inc.
    Inventors: Leroi E. Hutchings, Algie J. Conner
  • Patent number: 4358365
    Abstract: A process for the conversion of an asphaltene-containing, hydrocarbonaceous black oil in a catalytic slurry reaction zone wherein an admixture of converted hydrocarbonaceous oil and unconverted asphaltenes is recycled to the reaction zone.
    Type: Grant
    Filed: April 24, 1981
    Date of Patent: November 9, 1982
    Assignee: UOP Inc.
    Inventors: LeRoi E. Hutchings, Algie J. Conner
  • Patent number: 4297204
    Abstract: In a process for the thermal cracking of hydrocarbons to produce olefins, improvement of recovering hydrocarbons boiling above 200.degree. C. from the thermal cracking stage, preferably removing polymeric components therefrom, catalytically hydrogenating resultant hydrocarbons boiling above 200.degree. C., and recycling resultant hydrogenated hydrocarbons to the thermal cracking stage.
    Type: Grant
    Filed: February 21, 1979
    Date of Patent: October 27, 1981
    Assignee: Linde Aktiengesellschaft
    Inventors: Claus Schliebener, Hans J. Wernicke
  • Patent number: 4297206
    Abstract: An improvement in the solvent extraction of nonhydrocarbons from a synfuel liquid, e.g., shale oil, involves that the extract from the extractor, rather than being recycled directly back to the extractor, is first hydrotreated. A further improvement involves that a portion of the hydrotreated extract is fractionated and a light fraction is returned to the extractor. Use of the hydrotreated extract as recycle increases the efficiency of the extractor. A still further improvement involves the use as a selective solvent of one of the following: dialkylformamide, aldehydomorpholine, keto-morpholine, morpholine or an aliphatic aromatic ketone. These preferred solvents have the advantage of providing a clear interface between the extract and raffinate in the extractor. Removal of the nonhydrocarbons permits production of more hydrocarbons having enhanced utility as a jet fuel from a synfuel liquid than otherwise would be possible.
    Type: Grant
    Filed: February 1, 1980
    Date of Patent: October 27, 1981
    Assignee: Suntech, Inc.
    Inventor: Edward G. Scheibel
  • Patent number: 4277324
    Abstract: Isotropic carbonaceous pitches are fluxed with an organic liquid thereby providing a fluid pitch which has substantially all of the quinoline insoluble material suspended in the pitch and which quinoline insoluble material is readily separable from the fluid pitch by filtration, centrifugation and the like. Thereafter the pitch is treated with an anti-solvent so as to precipitate at least a substantial portion of the pitch free of the quinoline insoluble solids.
    Type: Grant
    Filed: April 13, 1979
    Date of Patent: July 7, 1981
    Assignee: Exxon Research & Engineering Co.
    Inventor: Sydney H. Greenwood
  • Patent number: 4268378
    Abstract: A method is disclosed for reducing the nitrogen content of shale oil using mild hydrogenation followed by liquid sulfur dioxide extraction of the hydrogenated shale oil. The mild hydrogenation is effective for increasing the fraction of shale oil that is insoluble in the liquid sulfur dioxide. The mild hydrogenation is sufficient for saturating unsaturated compounds present in the shale oil to the substantial exclusion of adding hydrogen to the nitrogen of the nitrogen-containing compounds. Following hydrogenation of the shale oil, it is extracted with liquid sulfur dioxide at a temperature from about 14.degree. F. to about 60.degree. F. forming two fractions, a liquid sulfur dioxide insoluble fraction containing a relatively low nitrogen content and a liquid sulfur dioxide soluble fraction containing a relatively high nitrogen content. The liquid sulfur dioxide fraction is separated from the insoluble shale oil fraction. The liquid sulfur dioxide can be recovered for recycling to another extraction step.
    Type: Grant
    Filed: April 8, 1980
    Date of Patent: May 19, 1981
    Assignee: Occidental Research Corporation
    Inventor: Leslie E. Compton
  • Patent number: 4235701
    Abstract: In an olefin plant in which ethylene, propylene and butenes are prepared, a dripolene fraction is recovered, hydrogenated and a C.sub.6 -C.sub.7 hydrogenated hydrocarbon stream derived from such hydrogenated dripolene is aromatized in the presence of a hydrogen rich recycle stream and in the presence of a catalyst containing platinum and chloride on aluminum whereby the aromatics content is increased above the approximately 64% aromatics content of the hydrogenated C.sub.6 -C.sub.7 hydrocarbon stream. The aromatics are extracted from the liquid effluent from the aromatization zone.
    Type: Grant
    Filed: March 30, 1979
    Date of Patent: November 25, 1980
    Assignee: Atlantic Richfield Company
    Inventor: Fred W. Kopf
  • Patent number: 4191636
    Abstract: This invention relates to a process for continuously converting a heavy oil into an asphaltene-metal-free oil by hydrotreating said heavy oil to crack asphaltenes selectively and remove heavy metals such as vanadium and nickel from said heavy oil simultaneously (hereinafter briefly referred to as "removal of metals"), separating the liquid products into a light fraction of an asphaltene-free and metal-free oil and a heavy fraction of an asphaltene and heavy metal-containing oil (hereinafter referred to as a "heavy fraction"), recovering said light fraction as a product, and recycling said heavy fraction to said hydrotreating step.
    Type: Grant
    Filed: June 6, 1978
    Date of Patent: March 4, 1980
    Assignee: Chiyoda Chemical Engineering & Construction Co., Ltd.
    Inventors: Yoshio Fukui, Yoshimi Shiroto, Mamoru Ando, Yasumasa Homma
  • Patent number: 4179353
    Abstract: An intentionally produced low octane value alkylate is reformed in the presence of steam, and in the absence of added hydrogen, to produce a high octane value, olefinic reformate containing aromatics. The reformate, upon fractionation to remove hydrogen and methane and C.sub.3 and C.sub.4 hydrocarbons, which can be recycled, is subjected to solvent extraction to produce a raffinate which can be used as high octane gasoline and which contains olefins, and an extract which, upon fractionation to remove xylenes therefrom as usable product, and which now contains benzene and toluene, can be combined with said raffinate.
    Type: Grant
    Filed: July 6, 1977
    Date of Patent: December 18, 1979
    Assignee: Phillips Petroleum Company
    Inventors: Thomas Hutson, Jr., Floyd E. Farha, Jr.
  • Patent number: 4170544
    Abstract: An improved hydrocarbon hydrocracking process is disclosed wherein residual nitrogen-containing and/or polycyclic hydrocarbon impurities are extracted from bottoms of the resulting hydrocrackate by contacting the bottoms under liquid-liquid extracting conditions with a furfural solution of ferric chloride.
    Type: Grant
    Filed: June 12, 1978
    Date of Patent: October 9, 1979
    Assignee: Chevron Research Company
    Inventor: Stephen J. Miller
  • Patent number: 4140621
    Abstract: A saturated hydrocarbon charge containing both butane and isobutane is subjected to selective hydrogenolysis in the presence of a catalyst comprising a specific carrier and 0.1 - 10 % b.w. of rhodium. Butane is thus selectively converted to ethane and propane, while isobutane is preserved or formed and can be recovered from the reaction product.
    Type: Grant
    Filed: September 20, 1977
    Date of Patent: February 20, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Pierre Franck, Jean-Francois Le Page, Germain Martino, Jean Miquel
  • Patent number: 4115247
    Abstract: A process for converting a naphtha feedstock to a pure benzene including the steps of: reforming the naphtha; removing a major fraction of C.sub.4 - C.sub.5 and heavy reformate components to obtain a reformate containing a major portion of C.sub.6 - C.sub.8 aromatic hydrocarbons and an associated saturated portion; extracting the aromatic hydrocarbons from the reformate countercurrently in a simplified process with a selective hydrophilic solvent, such as sulfolane, having high solubility for aromatic hydrocarbons and low solubility for paraffinic hydrocarbons to obtain an extract stream rich in C.sub.6 - C.sub.8 aromatic hydrocarbons and a raffinate stream rich in paraffinic hydrocarbons; and recovering the selective solvent from the extract stream to obtain an aromatic component comprising a major C.sub.6 - C.sub.8 aromatic hydrocarbons and about 3 to 18 wt. % paraffinic hydrocarbon impurity.
    Type: Grant
    Filed: July 16, 1976
    Date of Patent: September 19, 1978
    Assignee: Hydrocarbon Research, Inc.
    Inventors: Leon M. Lehman, Glen I. Lambert
  • Patent number: 4111791
    Abstract: In a system wherein a topped crude catalytic cracking system and a gas oil catalytic cracking system are operated, and the heavy cycle oils from each system are combined and the combined heavy cycle oil stream is solvent extracted to provide an aromatic extract suitable as feed for a carbon black operation, the aromaticity of the extract is increased by passing a substantial portion of the topped crude heavy cycle oil to the gas oil fractionator and recovering a heavy cycle oil from the gas oil fractionator as charge to solvent extraction.
    Type: Grant
    Filed: February 24, 1977
    Date of Patent: September 5, 1978
    Assignee: Phillips Petroleum Company
    Inventor: Edgar D. Davis
  • Patent number: 4028219
    Abstract: This invention relates to an improved process for the production of deashed coal which includes contacting coal with coal dissolving solvent at elevated temperature and pressure in a hydrogen atmosphere and thereafter passing the resulting mixture to a vacuum tower to remove coal dissolving solvent for recirculation and leave vacuum tower still bottoms, which are substantially free of coal dissolving solvent. Said still bottoms then are contacted with a solubilizing solvent to dissolve a substantial quantity of said still bottoms after which said dissolved still bottoms are separated from undissolved still bottoms. The separation procedure may be effected by settling, countercurrent decantation, or filtration using pressure precoated rotary and plate filters and the like.
    Type: Grant
    Filed: October 23, 1975
    Date of Patent: June 7, 1977
    Assignee: Kerr-McGee Corporation
    Inventors: Roger Allen Baldwin, Robert Elliott Davis
  • Patent number: 3992465
    Abstract: Process for producing aromatic hydrocarbons, particularly benzene and/or toluene from a feed charge containing saturated and unsaturated hydrocarbons, by catalytic treatment of said charge with hydrogen, fractionation of the resulting product to separate a fraction containing benzene and/or toluene, extractive distillation of at least one aromatic hydrocarbon in a column, by means of an extraction solvent from which said hydrocarbon is subsequently separated, and recycling to the reaction zone of at least one portion of the products recovered at the top of said extractive distillation column and containing essentially C.sub.6 and C.sub.7 saturated hydrocarbons.
    Type: Grant
    Filed: January 2, 1974
    Date of Patent: November 16, 1976
    Assignee: Institut Francais du Petrole, des Carburants et Lubrifiants et Entreprise de Recherches et d'Activities Petrolieres Elf
    Inventors: Bernard Juguin, Georges Cohen, Paul Mikitenko
  • Patent number: 3977964
    Abstract: A process for the production of lubricating oil base which is stable to ultraviolet light, which comprises extracting a mixture of a hydrocracked oil and decanted oil with furfural.
    Type: Grant
    Filed: March 7, 1975
    Date of Patent: August 31, 1976
    Assignee: Standard Oil Company
    Inventor: Richard D. Schieman
  • Patent number: 3970543
    Abstract: Lubricating oils are prepared by a sequence of steps comprising hydrorefining, fractionation and blending.
    Type: Grant
    Filed: October 2, 1974
    Date of Patent: July 20, 1976
    Assignee: Texaco Inc.
    Inventor: Herbert A. McIntosh