With Modifying Agents Patents (Class 209/166)
-
Patent number: 12180071Abstract: This disclosure describes methods, processes and devices that remove or release organics from ores, such as phosphate ores or secondary sources such as mine tailings or waste. The method comprises: preparing an ore to a pre-set size; mixing the ore with a reagent having an initial pH value in a slurry comprising the ore and the reagent; and while mixing the slurry, maintaining a pH level in the slurry to a pH range. While mixing the slurry, the slurry may produce a supernatant containing organic material removed from the ore and sediment containing refined ore. The method may also screen the slurry to create a first stream of materials that does not pass through the screen and a second stream of materials and refined ore that pass through the screen.Type: GrantFiled: April 5, 2019Date of Patent: December 31, 2024Assignee: KOR MINERAL TECHNOLOGIES INC.Inventors: Richard Pilon, Marek Pawlik, Michael Ryan MacIVER
-
Patent number: 12024691Abstract: Described herein is a fabric care composition including at least one hydrophobically modified polyalkyleneimine as dye fixative polymer. Also described herein is a method for providing an improved color care effect during washing or treatment of colored fabric, the method including use of the hydrophobically modified polyalkyleneimine as dye fixative polymer.Type: GrantFiled: August 30, 2019Date of Patent: July 2, 2024Assignee: BASF SEInventors: Yan Kang, Ya Jing Liu, Yungi Lee, Helmut Witteler, Alexandros Lamprou
-
Patent number: 11952714Abstract: A process (1, 101, 201) for separating a fibrous target component (21) from textile waste (2, 5) is shown, said textile waste (2, 5) containing the target component (21) and at least one ancillary component (22), whereby the target component (21) consists of water-swellable textile fibers (51) with a density higher than the density of water, the process (1, 101, 201) comprising the steps: a) dispersing the comminuted textile waste (5) in an aqueous solution (7) to obtain a suspension (8) containing the textile waste (5), and b) separating the dispersed textile waste (5) into a high-density target fraction (81) comprising the target component (21), and a low-density residual fraction (82) comprising the at least one ancillary component (22), according to the respective density of said components (21, 22).Type: GrantFiled: January 14, 2019Date of Patent: April 9, 2024Assignee: LENZING AKTIENGESELLSCHAFTInventors: Christoph Klaus-Nietrost, Richard Herchl, Christian Weilach
-
Patent number: 11697862Abstract: A mineral processing method capable of efficiently separating a copper mineral from a molybdenum mineral is provided. The mineral processing method includes: a conditioning step of adding sulfite as a surface treatment agent to a mineral slurry containing a copper mineral and a molybdenum mineral; and a flotation step of performing flotation using the mineral slurry after the conditioning step. The hydrophilicity of the copper mineral can be selectively enhanced by sulfite, so as to be able to produce a difference in hydrophilicity between the copper mineral and the molybdenum mineral. Therefore, the molybdenum mineral can be selectively caused to float, and the copper mineral and the molybdenum mineral can be efficiently separated from each other.Type: GrantFiled: June 1, 2018Date of Patent: July 11, 2023Assignees: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION, SUMITOMO METAL MINING CO., LTD.Inventors: Tsuyoshi Hirajima, Hajime Miki, Gde Pandhe Wisnu Suyantara, Yuji Imaizumi, Yuji Aoki, Eri Takida
-
Patent number: 11685689Abstract: The present disclosure concerns an aluminosilicate having a Blaine fineness of about 500 m2/kg to about 3000 m2/kg and/or a specific surface area of about 4 m2/g to about 20 m2/g, as well as the uses thereof. The present disclosure also comprises a dry cementing composition and a mortar or concrete composition, the compositions comprising said aluminosilicate. The present disclosure also comprises a process for the manufacture of aluminosilicate. The process comprises: roasting a spodumene concentrate in an acid medium; leaching the acidic roast spodumene concentrate so as to obtain a mixture comprising a solid comprising the aluminosilicate and a leachate; and separating the aluminosilicate from the leachate in an acid medium, wherein said aluminosilicate contains a calcium concentration of less than about 5%.Type: GrantFiled: November 27, 2019Date of Patent: June 27, 2023Assignee: NEMASKA LITHIUM INC.Inventors: Jean-François Magnan, David-Nicolas Allen
-
Patent number: 11638923Abstract: The flotation reagents from acidic olive oil are made by transesterification of acidic olive oil. Acidic olive oil is olive oil having an acid value high enough to render it unsuitable for consumption, typically greater than 3.3% and/or between 3.3-7%. Transesterification of the olive oil with methanol converts fatty acids in the olive oil to an ester fraction and a glycerol fraction. The ester fraction may be sulfonated and used as the collector in a reverse flotation process, selectively removing the carbonate gangue from phosphate-carbonate rock in the froth, leaving phosphates in the sink. The glycerol fraction may be used without modification as the collector in the reverse flotation process. Both fractions are highly selective for carbonates, substantially reducing loss of phosphates in the froth.Type: GrantFiled: September 10, 2020Date of Patent: May 2, 2023Assignee: KING SAUD UNIVERSITYInventors: Saeed Mohammed Al-Zahrani, Arfat Anis, Ranjan Kumar Dwari
-
Patent number: 11613716Abstract: Provided is a binder for a coal-containing formed product, which contains a macromolecular polymer having an intrinsic viscosity of 2.0 dl/g or higher.Type: GrantFiled: March 25, 2019Date of Patent: March 28, 2023Assignee: KURITA WATER INDUSTRIES LTD.Inventor: Takashi Kikkawa
-
Patent number: 11612898Abstract: The present embodiments generally relate to a technology for improving Cu/Mo grade by the addition of cationic polymers as selective depressants for acid insoluble matters, e.g., silicates and/or clays, in the flotation circuit. Various types of cationic polymers are demonstrated to be effective depressants including polyamine, polyDADMAC, and cationic polyacrylamide. Also disclosed are processes for enriching a desired mineral from an ore comprising the desired mineral and gangue, wherein the process comprises carrying out a flotation process in the presence of one or more cationic polymer depressants.Type: GrantFiled: August 30, 2017Date of Patent: March 28, 2023Assignee: KEMIRA OYJInventors: Marcelo Moreira Costa, Xihui Yin, Sergio Cabo
-
Patent number: 11590514Abstract: A process for treating and dewatering tailings comprising fine clay minerals, fine rock-forming minerals and water is provided, comprising treating the tailings with a sufficient amount of a collector to modify the surface properties of both the fine clays and rock-forming minerals; subjecting the treated tailings to froth flotation to form a fine clays and rock-forming minerals froth layer; and recovering the froth layer and subjecting it to dewatering.Type: GrantFiled: October 25, 2019Date of Patent: February 28, 2023Assignee: SYNCRUDE CANADA LTDInventors: Simon Yuan, James Lorentz, Ron Siman
-
Patent number: 11505670Abstract: This invention relates to rigid polyurethane foams which are co-blown with a mixture of a hydrocarbon blowing agent and a halogenated olefin blowing agent. This invention also relates to a process for preparing these rigid polyurethane foams, and to an isocyanate-reactive component containing a polyol blend and the mixture of blowing agents. Phase stable isocyanate-reactive blends are also described.Type: GrantFiled: November 17, 2016Date of Patent: November 22, 2022Assignee: Covestro LLCInventor: Steven L. Schilling
-
Patent number: 11453014Abstract: The present application relates to a concentration process of iron minerals from ultrafine tailings (slimes) from iron ore processing through reverse flotation with pH between 8.5 and 10.5 with the addition of amide-amine type collector, or further a mixture thereof with traditional cationic collectors (amines), in the absence of any depressant, alternatively including a step of high field magnetic concentration, which allows to obtain a concentrate with iron content higher than 66% and contents of SiO2+Al2O3 below 4%.Type: GrantFiled: October 3, 2018Date of Patent: September 27, 2022Assignee: VALE S.A.Inventors: Neymayer Pereira Lima, Klaydison Carlaile Silva, Maurício Curi Segato
-
Patent number: 11420211Abstract: A method includes separating, in a first stage of separating, crushed ore material by size into a first fines stream and a first coarse stream; grinding the first coarse stream in a second stage of grinding; feeding the product of the second stage of grinding back to the step of separating; feeding the first fines stream from the step of separating to a recovery circuit; producing a rejected stream from the recovery circuit of crushed ore material that does not meet the target mineral size; separating, in a second stage of separating, the rejected stream from the recovery circuit into a second fines stream and a second coarse stream; grinding the second coarse stream in a third stage of grinding; and feeding the product of the third stage of grinding back to the recovery circuit.Type: GrantFiled: December 29, 2017Date of Patent: August 23, 2022Assignee: FLUOR TECHNOLOGIES CORPORATIONInventor: Mark Sherman
-
Patent number: 11413629Abstract: In one example, a method includes providing a pulp composed of a combination of particulate materials including particles of a target material. The pulp is mixed with a collector composed of anisotropic particles having at least two separate spatial domains that have different physiochemical properties, and the mixture of pulp and collector is fed into an aqueous solution containing air bubbles.Type: GrantFiled: September 23, 2019Date of Patent: August 16, 2022Assignee: International Business Machines CorporationInventors: Julia Baldauf, Alexe Bojovschi, Benjamin S. Mashford, Christine Schieber, George Yiapanis
-
Patent number: 11407953Abstract: A process for upgrading of a coal product is provided. The process comprising the steps of: (i) providing a purified coal composition, wherein the composition is in the form of solid particles, and wherein at least about 90% by volume (% vol) of the solid particles are no greater than about 500 ?m in diameter; and (ii) combining the purified coal composition with a solid coal feedstock, in order to create a combined solid-solid blend upgraded coal product. Further a process for preparation of a purified coal product is provided.Type: GrantFiled: September 27, 2019Date of Patent: August 9, 2022Assignee: Arq IP LimitedInventors: Paul Groves, John Francis Unsworth
-
Patent number: 11365127Abstract: A large-particle spherical salt with a particle size of 400-950 ?m and a sphericity of 0.5-1.0 is disclosed, which overcomes the existing difficulty in this field for larger particle size as well as higher sphericity. A preparation method of the large-particle spherical salt is also disclosed, wherein in one preparation process, 2% of gum arabic (based on the mass percentage of solute sodium chloride in a sodium chloride saturated solution) is added, and under conditions of an evaporating temperature of 60° C. a stirring rate of 350 rpm, and an evaporating time of 8 hours, a large-particle spherical salt with a particle size of 921.593 ?m and an average sphericity of 0.904 is successfully prepared. The large-particle spherical salt prepared by the method has a uniform particle size distribution and good appearance, can be combined with other substances, adding some extra value to the salt. Meanwhile, the large-particle spherical salt prepared by the method has a high safety grade (e.g.Type: GrantFiled: August 15, 2021Date of Patent: June 21, 2022Assignee: TIANJIN UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Na Tang, Min Lu, Wei Du, Penggao Cheng, Jun Xiang, Lei Zhang, Songbo Wang, Jianping Zhang
-
Patent number: 11326088Abstract: Treatment fluids for use in fluid loss control, diversion, and plugging operations and methods of use are disclosed. The treatment fluids contain a degradable particular langbeinite material that temporarily creates a physical barrier to fluid flow before degrading over time with little to no effect on the environment. This degradable additive can be combined with other traditional downhole additives such as surfactants, viscosifying agents, biocides and the like, allowing for a wide variety of applications in hydrocarbon reservoirs.Type: GrantFiled: May 28, 2020Date of Patent: May 10, 2022Assignee: LyondellBasell Advanced Polymers Inc.Inventor: Bradley L. Todd
-
Patent number: 11247214Abstract: A system for separating mineral particles of interest from an ore features mineral processing operations/stages/circuits configured to receive an ore, or mineral particles or concentrates formed by processing the ore, and provide processed mineral particles or concentrates, or a waste stream, for further enhanced mineral separation downstream processing; an enhanced mineral separation processor having a collection apparatus located therein, the collection apparatus having a collection surface configured with a functionalized polymer including molecules having a functional group configured to attract the mineral particles of interest to the collection surface, the enhanced mineral separation processor receive the processed mineral particles or concentrates, or the waste stream, and provide further enhanced downstream processed mineral particles or concentrates, or a further enhanced downstream processed waste stream; and a high intensity conditioning operation, stage or circuit configured to apply a high intenType: GrantFiled: February 28, 2018Date of Patent: February 15, 2022Assignee: CIDRA CORPORATE SERVICES LLCInventors: Paul J. Rothman, Adam Michael Jordens, Peter A. Amelunxen
-
Patent number: 11180825Abstract: A process for the depression of iron sulphides and other disposable elements in the mineral concentration by flotation and electrochemical reactor. The proposed invention represents a method based on the action of electrodes on the mineral, which can replace, compliment or minimise the consumption of chemical reagents, as well as improving the effect thereof.Type: GrantFiled: August 2, 2017Date of Patent: November 23, 2021Assignee: LAIN TECHNOLOGIES LTDInventor: Eva Maria Laín Rodríguez
-
Patent number: 11168218Abstract: A process is described for manufacturing white pigment containing products. The white pigment containing products are obtained from at least one white pigment and impurities containing material via froth flotation.Type: GrantFiled: February 13, 2017Date of Patent: November 9, 2021Assignee: OMYA INTERNATIONAL AGInventors: Jörg Sötemann, Jörg Andreas Maier
-
Patent number: 11103882Abstract: A separation system is presented that partitions a slurry containing a plurality of particles that are influenced by a fluidization flow (which comprises teeter water and gas bubbles) and a fluidized bed. The separation system comprises a separation tank, a slurry feed distributor, a fluidization flow manifold and a gas introduction system. All of these components are arranged to create the fluidized bed in the separation tank by introducing the slurry through the slurry feed distributor and allowing the slurry to interact with the fluidization flow that enters the separation tank from the fluidization flow manifold. The gas introduction system is configured to optimize the gas bubble size distribution in the fluidization flow. The gas introduction system comprises a gas introduction conduit and a bypass conduit. The gas introduction system can be adjusted by modulating the flow of teeter water through the gas introduction conduit.Type: GrantFiled: January 27, 2016Date of Patent: August 31, 2021Assignee: Eriez Manufacturing Co.Inventors: Michael J. Mankosa, Jaisen N. Kohmuench, Eric S. Yan
-
Patent number: 11078557Abstract: Hydrometallurgical systems, methods, and compositions are described in which amine-based lixiviants are utilized in substoichiometric amounts to recover alkaline earths from raw or waste materials. The lixiviant can be regenerated and recycled for use in subsequent iterations of the process or returned to a reactor in a continuous process. Extraction of the alkaline earth from the raw material and precipitation of the extracted alkaline earth is performed in the same reactor and essentially simultaneously.Type: GrantFiled: March 8, 2016Date of Patent: August 3, 2021Assignee: Lixivia, Inc.Inventors: Michael D. Wyrsta, Zachary J. A. Komon
-
Patent number: 11040888Abstract: The invention provides a low alpha dose barium sulfate particle having a silica content of 0.6% by weight or less, an average particle diameter of 1 ?m or less, a sulfur content of 10 ppm or less, and an alpha dose of 0.07 cph/cm2 or less.Type: GrantFiled: December 23, 2016Date of Patent: June 22, 2021Assignee: SAKAI CHEMICAL INDUSTRY CO., LTD.Inventors: Satoru Sueda, Hironobu Ogata
-
Patent number: 11014096Abstract: The present invention concerns a process for manufacturing white pigment containing products. The white pigment containing products are obtained from at least one white pigment and impurities containing material via froth flotation.Type: GrantFiled: August 8, 2018Date of Patent: May 25, 2021Assignee: OMYA INTERNATIONAL AGInventors: Jorg Sotemann, Jorg Maier, David Gilbert, Tomi Matti Juhani Niitti
-
Patent number: 10961382Abstract: Improved sparge compositions for reverse froth flotation separation and uses thereof, and methods of reverse froth flotation are described. The sparge compositions comprise sulfonated polymeric modifiers which can act as dispersants and depressants, and the compositions are suitably used in the reverse froth flotation of particulate material containing ultrafine particles. For example, the compositions and methods can be used in the separation of iron oxide beneficiary from iron ores comprising silica, silicates, and the like.Type: GrantFiled: August 25, 2017Date of Patent: March 30, 2021Assignee: Ecolab USA Inc.Inventors: Jianjun Liu, Kevin O'Brien, Daniel N. T. Hay
-
Patent number: 10934191Abstract: Methods of making various capillary foams are provided. The foams can include liquid foams having a plurality of particles connected by a network of a secondary fluid at the interface between the discontinuous and continuous phase. The foams can also include solid foams where the continuous phases (bulk fluid) is removed to produce the solid foam having high overall porosities and low densities. Densities as low as 0.3 g cm?3 and porosities as high as 95% or higher can be achieved. The secondary fluid can be polymerized to further strengthen the solid foam. Methods and devices are also provided for oil recovery from water using a capillary foam. The methods can include forming a capillary foam wherein the oil is the secondary fluid, and wherein the foam can transport the oil to the surface of the water.Type: GrantFiled: September 6, 2016Date of Patent: March 2, 2021Assignee: Georgia Tech Research CorporationInventors: Sven Holger Behrens, James Carson Meredith, III, Jie Wu, Yi Zhang
-
Patent number: 10927248Abstract: Improved sparge compositions for reverse froth flotation separation and uses thereof, and methods of reverse froth flotation are described. The sparge compositions comprise sulfonated polymeric modifiers which can act as dispersants and depressants, and the compositions are suitably used in the reverse froth flotation of particulate material containing ultrafine particles. For example, the compositions and methods can be used in the separation of phosphate beneficiary from ores comprising phosphates, dolomite, calcite, clay, silica, silicates, carbonates, and mixtures thereof.Type: GrantFiled: August 25, 2017Date of Patent: February 23, 2021Assignee: Ecolab USA Inc.Inventors: Jianjun Liu, Kevin O'Brien, Paul Wiatr, Daniel N.T. Hay
-
Patent number: 10919048Abstract: A process of phosphate flotation comprising: pulping phosphate ore with water to about 55% to 75% solids to produce an ore slurry; conditioning the ore slurry with a new reagent scheme to produce a conditioned slurry; subjecting the conditioned slurry to flotation to produce an underflow and an overflow; and collecting the overflow as phosphate concentrate. The new reagent scheme may comprise a combination of fatty acid, fuel oil, and fatty acid soap, and may not comprise a pH modifier. The process may also work effectively at a lower percent solids than conventional reagent schemes.Type: GrantFiled: October 31, 2018Date of Patent: February 16, 2021Assignee: ARR-MAZ PRODUCTS, L.P.Inventors: Guoxin Wang, Yu Xiong, Zhengxing Gu
-
Patent number: 10865110Abstract: Processes for removing/recovering heavy metal ions in solutions containing phosphoric acid by adding reagents having at least one organothiophosphorus compound and at least one surfactant to the solution during the wet-process phosphoric acid production process to form heavy metal complexes, and separating the heavy metal complexes from the solution are provided herein.Type: GrantFiled: October 5, 2018Date of Patent: December 15, 2020Assignee: Cytec Industries Inc.Inventors: Lei Zhang, Xueping Qiu, Rajesh Raitani
-
Patent number: 10744517Abstract: Provided is a method of beneficiating an ore including contacting an ore with a compound represented by formula (1): where the structural variables are defined herein.Type: GrantFiled: February 13, 2017Date of Patent: August 18, 2020Assignee: Arkema FranceInventors: Eric Jorda, Alain Baloche, Nathalie Gibert, Isabelle Birken, Gilles Barreto, Jean-Paul Gamet
-
Patent number: 10737280Abstract: The present invention relates to an azolethione flotation collector and application thereof. According to the application, an azolethione compound such as a 1,3,4-thiadiazole-2-thione compound, a 1,3,4-oxadiazole-2-thione compound, a 1,2,4-triazole-3-thione compound or a 1,2,4,5-tetrazole-3-thione compound is used as a mineral flotation collector to be applied to ores containing copper, zinc, lead, nickel, cobalt, platinum, palladium, silver or gold minerals to realize flotation recovery of valuable metal minerals. Compared with common flotation collectors in the existing technologies, the flotation collector of the present invention can effectively improve enrichment and recovery of copper, zinc, lead, nickel, cobalt, platinum, palladium, silver or gold minerals.Type: GrantFiled: March 21, 2019Date of Patent: August 11, 2020Assignee: CENTRAL SOUTH UNIVERSITYInventors: Guangyi Liu, Yaoguo Huang, Longqun Ma, Xiaoxue Niu, Jun Liu, Hong Zhong, Zhe Hu
-
Patent number: 10669201Abstract: A method of making a structural lightweight and thermal insulating concrete is described. The concrete has a coarse aggregate partly replaced by recycled plastic pieces. This enables the concrete to maintain a high compressive strength, low thermal conductivity, and low weight, while providing a use for waste plastic. The waste plastic pieces may comprise polyethylene in the form of flakes, fibers, or granules. Due to its low unit weight, adequate compressive strength and high thermal resistance the developed concrete can be used as a structural lightweight and thermal insulating concrete. The use of this concrete leads to economic and environmental benefits.Type: GrantFiled: July 3, 2018Date of Patent: June 2, 2020Assignee: King Fahd University of Petroleum and MineralsInventors: Mohammed Rizwan Ali, Jobin Jose, Salah U. Al-Dulaijan, Shaik Inayath Basha, Mohammed Maslehuddin
-
Patent number: 10596578Abstract: A process for producing an iron ore having a sulfur content reduced to 0.08% or less, which includes a step of subjecting an iron ore containing sulfur in an amount of more than 0.08% and 2% or less to a flotation. The flotation satisfies any one of the following (1) to (3): (1) a xanthate-based compound and a salt of an amine compound are used as collectors, (2) a xanthate-based compound is used as a collector and a substance which releases a sulfur ion in water is used as an activator, or (3) a xanthate-based compound and a salt of an amine compound are used as collectors and a substance which releases a sulfur ion in water is used as an activator.Type: GrantFiled: June 23, 2014Date of Patent: March 24, 2020Assignee: KOBE STEEL, LTD.Inventors: Eishi Kusaka, Katsuyuki Iijima, Takayasu Fujiura
-
Patent number: 10589293Abstract: Depressants comprising a moderately oxidized polysaccharide having about 0.05 to about 4.5 mmol of anionic charge per gram at a pH of about 6 to about 7, or about 0.2 to about 5 mmol of anionic charge per gram at a pH of about 10 to about 11.2, are provided. Also disclosed are processes for enriching a desired mineral from an ore comprising the desired mineral and gangue, wherein the process comprises carrying out a flotation process in the presence of one or more of the depressants.Type: GrantFiled: September 26, 2016Date of Patent: March 17, 2020Assignee: Kemira OYJInventor: Duane C. Wilson
-
Patent number: 10543493Abstract: The present invention relates to a compound obtainable by reacting an N-acyl neutral amino acid or a salt thereof, or an N-acyl neutral amino acid oligopeptide or a salt thereof with a monohydroxy monocarboxylic acid or a salt thereof. This compound is useful as a collector in a process for froth flotation of non-sulfidic ores, especially phosphate ores. The invention also relates to a method which comprises the steps of a) conditioning a pulped phosphate ore, wherein the phosphate ore comprises a calcium phosphate mineral or a mixture of such minerals, and gangue minerals, with an effective amount of a calcium phosphate mineral collector reagent, which is the above-mentioned compound, and optionally other flotation aids and b) performing a froth flotation process to recover the calcium phosphate mineral(s).Type: GrantFiled: July 2, 2014Date of Patent: January 28, 2020Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.Inventors: Natalija Smolko-Schvarzmayr, Anders Klingberg
-
Patent number: 10472525Abstract: Use of dithiophosphinic acids of the general formula HS2P(R1)(R2) and/or salts thereof for producing chrome-free, polymer-containing corrosion control layers on metallic surfaces, R1 and R2 independently of one another each being organic radicals having 1 to 30 C atoms.Type: GrantFiled: February 19, 2016Date of Patent: November 12, 2019Assignee: BASF COATINGS GMBHInventors: Monica Fernandez Gonzalez, Markus Hickl, Cordula Mock-Knoblauch, Manfred Essig, Wolfgang Schrepp, Manfred Biehler
-
Patent number: 10434520Abstract: The invention is related to a flotation process using an improved collector to remove alkaline earth metal carbonate impurities from phosphate ores. The flotation feed may be conditioned with the improved carbonate collector at acidic pH, and subjected to a reverse flotation. The cell overflow may be collected as waste in which carbonate minerals dominate, and the cell underflow may be the phosphate concentrate. The collector may be a combination of chemicals, comprising: (1) any kind of fatty acids, either conventional fatty acid, saponified fatty acid, or modified fatty acid; (2) chemicals with sulfonate or sulfate groups, such as dodecylbenzene sulfonic acid (DDBSA) or its salt, sodium dodecyl sulfate (SDS), sodium lauryl sulfate (SLS), sodium coco sulfate (SCS), etc.; and (3) phosphorous-bearing chemicals, such as sodium tripolyphosphate (STPP), sodium hexametaphosphate (SFMP), trisodium phosphate (TSP), Tetrasodiumpyrophosphate (TSPP), etc.Type: GrantFiled: August 9, 2017Date of Patent: October 8, 2019Assignee: Arr-Maz Products, L.P.Inventors: Zhengxing Gu, Guoxin Wang, Yu Xiong
-
Patent number: 10384958Abstract: The invention provides methods and compositions for green compositions and technologies. In an embodiment, the present invention provides a method of separating a first material from a second material. For example, the method can comprise mixing the first material and the second material in a slurry with a beneficiation composition. The beneficiation composition can comprise one or more glyceride and fatty acid mixtures extracted from a fuel ethanol process. Air bubbles can be provided in the slurry to form bubble-particle aggregates with the first material and the bubble-particle aggregates can be allowed to be separated from the second material.Type: GrantFiled: January 30, 2015Date of Patent: August 20, 2019Assignee: ECOLAB USA INC.Inventors: Bo L. Tran, Kerem Eraydin, Jianjun Liu, Royce D. Mullins, Jinming Zhang, James A. Counter
-
Patent number: 10376901Abstract: The present invention relates to the use of branched fatty alcohol-based compounds selected from the group of fatty alcohols with 12-16 carbon atoms having a degree of branching of 1-3, and their alkoxylates with a degree of ethoxylation of up to 3, as secondary collectors for the froth flotation of non-sulfidic ores, in combination with a primary collector selected from the group of amphoteric and anionic surface active compounds.Type: GrantFiled: September 15, 2015Date of Patent: August 13, 2019Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.Inventors: Natalija Smolko-Schvarzmayr, Anders Klingberg, Elisabeth Henriksson, Henrik Nordberg
-
Patent number: 10344353Abstract: Methods of recovering metals from metal-bearing materials, and more particularly, methods for improving leaching efficiency in extraction processes by employing a surfactant composition in the extraction process, as well as slurries useful in the methods of recovering metals are provided.Type: GrantFiled: April 7, 2016Date of Patent: July 9, 2019Assignee: Ecolab USA Inc.Inventors: Vladimir Mujicic, Kim Coleman, Kevin O'Brien
-
Patent number: 10315202Abstract: A method of recovering particles from a liquid, a froth flotation apparatus, and a method of recovering particles in a flotation cell are disclosed. In an embodiment, the method comprises a technique of exposing the particles to first-size bubbles having a first predetermined size; the first-size bubbles adhering to the particles; and exposing the particles in a liquid, with the first-size bubbles adhering to the particles, to second-size bubbles having a second predetermined size, the second predetermined size being at least approximately ten times larger than the first predetermined size. The method further comprises the second-size bubbles adhering to the particles and engulfing the first-size bubbles on the particles; and using the second-size bubbles adhering to the particles to recover the particles from the liquid. In one embodiment a first surfactant is used to form the first-size bubbles, and a second surfactant is used to form the second-size bubbles.Type: GrantFiled: July 14, 2015Date of Patent: June 11, 2019Assignee: International Business Machines CorporationInventors: Julia Baldauf, Alexe Bojovschi, Stephen Moore
-
Patent number: 10307770Abstract: The present invention relates to the beneficiation of coal by the process of froth flotation and specifically relates to a process for the froth flotation of coal using a mixture of fatty acids and rosin acids (and/or certain derivatives of fatty acids and rosin acids) as a collector.Type: GrantFiled: December 30, 2014Date of Patent: June 4, 2019Assignee: INGEVITY SOUTH CAROLINA, LLCInventors: John B. Hines, Dennis L. Kennedy, Phillip W. Hurd
-
Patent number: 10258996Abstract: The present invention relates to flotation of sulfidic copper-molybdenum- and gold-containing minerals. More specifically, the invention relates to sulfoxy reagent-assisted floatation for separating of sulfides of copper, molybdenum and gold from pyrite, marcasite, pyrrhotite, arsenopyrite, and other gangue minerals following aerating by an oxidizing gas and contacting by a sulfoxy reagent. To promote collection and flotation the feed mineral materials are preferably not contacted with an externally generated non-oxidizing gas to lower the dissolved molecular oxygen content prior to flotation.Type: GrantFiled: March 22, 2016Date of Patent: April 16, 2019Assignee: Barrick Gold CorporationInventor: Barun Gorain
-
Patent number: 10207275Abstract: The present invention discloses an advantageous and effective process for the concentration of iron ores, which can be fully dry or mixed, part of the process being dry, part wet. The invention thereby improves process efficiency as a whole by increasing recovery of concentrators and increasing the useful life of the mines.Type: GrantFiled: October 25, 2013Date of Patent: February 19, 2019Assignee: VALE S.A.Inventor: Joaquim Donizetti Donda
-
Patent number: 10195614Abstract: This invention relates to a collector composition for the direct froth flotation of nonsulfide ores comprising a) 50-99 wt.-% of a mixture of fatty acids and b) 1-50 wt.-% of an N-acyl derivative of sarcosine of the formula (I) wherein R is a saturated or unsaturated hydrocarbon chain with 7 to 21 carbon atoms, wherein the mixture of comprises 10.0-35.0 wt.-% of fatty acid having a saturated C11 hydrocarbon group, 2.5-15.0 wt.-% of fatty acid having a saturated C13 hydrocarbon group, 10.0-25.0 wt.-% fatty acid having a monounsaturated C17 hydrocarbon group and 20.0-45.0 wt.-% fatty acid having a bisunsaturated C17 hydrocarbon group.Type: GrantFiled: March 1, 2016Date of Patent: February 5, 2019Assignee: Clariant International Ltd.Inventors: Klaus-Ulrich Pedain, Jesús Pitarch López, Gunter Lipowsky, Jacques Collin Bezuidenhout
-
Patent number: 10150839Abstract: Amine-aldehyde resins are disclosed for removing a wide variety of solids and/or ionic species from the liquids in which they are suspended and/or dissolved. These resins are especially useful as froth flotation depressants, for example in the beneficiation of value materials (e.g., bitumen, coal, or kaolin clay) to remove impurities such as sand. The resins are also useful for treating aqueous liquid suspensions to remove solid particulates, as well as for removing metallic ions in the purification of water.Type: GrantFiled: June 23, 2014Date of Patent: December 11, 2018Assignee: INGEVITY SOUTH CAROLINA, LLCInventors: James T. Wright, John B. Hines, Lisa M. Arthur, Carl R. White, Kurt D. Gabrielson, Michael J. Cousin
-
Patent number: 10144012Abstract: Methods of increasing the rate of separating hydrophobic and hydrophilic particles by flotation have been developed. They are based on using appropriate reagents to enhance the hydrophobicity of the particles to be floated, so that they can be more readily collected by the air bubbles used in flotation. The hydrophobicity-enhancing reagents include low HLB surfactants, naturally occurring lipids, modified lipids, and hydrophobic polymers. These methods can greatly increase the rate of flotation for the particles that are usually difficult to float, such as ultrafine particles, coarse particles, middlings, and the particles that do not readily float in the water containing large amounts of ions derived from the particles. In addition, new collectos for the flotation of phosphate minerals are disclosed.Type: GrantFiled: January 14, 2008Date of Patent: December 4, 2018Assignee: MINERAL AND COAL TECHNOLOGIES, INC.Inventor: Roe-Hoan Yoon
-
Patent number: 10147913Abstract: The invention relates to a process for the production of a recyclable product (1, 8, 9) made from a first material, wherein before or during the production of the product (1, 8, 9) a first marking material is added to the first material and the product (1, 8, 9) is produced from the first material with the admixed marking material, wherein the first marking material can be automatically detected in a recycling plant in the first material of the product (1, 8, 9) after the production thereof.Type: GrantFiled: October 16, 2012Date of Patent: December 4, 2018Assignee: Johnson Controls Autobatterie GmbH & Co. KGaAInventors: Eberhard Meissner, Anne-Laure Ledoux, Jurgen Bauer
-
Patent number: 10118183Abstract: The invention relates to a process for selective flotation of kainite from crushed crude potash salts or, for example, from crystallized salt mixtures obtained by evaporation processes, which in addition to kainite may contain further minerals such as halite, sylvine and other salt minerals, for example, in order to produce a kainite concentrate fraction and a residues fraction. The separation process is characterized in that the crushed or crystallized salt mixture is intensively mixed as a crystallizate suspension with a combination of conditioning agents consisting of a sulfated fatty acid or its alkali metal salt as collecting reagent and a frothing agent known for flotation (for example, glycol ether, monohydric aliphatic alcohols, terpene alcohols, polyglycol ethers, etc.) and is then separated by agitator-driven or pneumatic flotation into a kainite concentrate fraction and a residues fraction. The resulting fractions may be further processed in downstream processes.Type: GrantFiled: December 1, 2015Date of Patent: November 6, 2018Assignee: K+S AKTIENGESELLSCHAFTInventors: Uwe Wachsmuth, Jochen Brod
-
Patent number: 10105713Abstract: The instant invention relates to a composition in form of a stable aqueous emulsion comprising a) 1-50 wt.-% of at least one water insoluble thionocarbamate collector selected from the group consisting of dialkyl thionocarbamates, alkyl alkoxycarbonyl thionocarbamates and alkyl allyl thionocarbamates, b) 1-50 wt.-% of one or a mixture of surface active agents of the general formula wherein R1 is a saturated or unsaturated, branched or linear C3 to C30 aliphatic or aromatic hydrocarbon group, R2 and R3 are independently from each other hydrogen or a C1 to C4 alkyl group, R4 is hydrogen or —CH2—COOX where X is hydrogen or sodium salt or potassium salt or ammonium salt, and n and m are independently from each other 0 to 50, c) 0.1-20 wt.-% of a mixture of at least one alcohol and at least one ether and/or ester, e) 1-90 wt.-% of water.Type: GrantFiled: April 22, 2015Date of Patent: October 23, 2018Assignees: CLARIANT INTERNATIONAL LTD., CLARIANT S.A, CLARIANT (CHILE) LTDA.Inventors: Antonio Pedro De Oliveira Filho, Jesus Pitarch López, Wagner Claudio Da Silva, Gunter Lipowsky, Jacques Collin Bezuidenhout, Jaime Osvaldo Gomez Becerra, Rodrigo Alexis Caris Andrade, Franco Aurelio Constanzo Yanez
-
Patent number: 10105714Abstract: The present invention relates to a process for treating an earth contaminated by at least one radionuclide such as cesium 137Cs comprising at least one step of separating said radionuclide by dispersed air flotation foam produced by blowing air bubbles in a suspension comprising said earth and at least one collector. The present invention also relates to the flotation foam obtained by implementing such a process.Type: GrantFiled: May 10, 2013Date of Patent: October 23, 2018Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVESInventors: Sylvain Faure, Marc Messalier