Abstract: The present invention relates to an improved process for beneficiating an ore containing sulfide materials with selective rejection of pyrite, pyrrhotite and other metals and gangue. In particular, the process is useful for beneficiating ores and recovering copper from said ores. In one embodiment the process comprises the steps of(A) grinding the ore to an appropriate size range;(B) preparing a slurry comprising(B-1) said ground ore;(B-2) at least one collector which is a water-dispersible or soluble dihydrocarbyldithiodiphosphoric acid or salt having the formula ##STR1## wherein R.sup.1 and R.sup.2 are different hydrocarbyl groups containing up to about 12 carbon atoms, n is an integer equal to the valence of X and X.sup.n+ is a dissociating cation; and(B-3) water;(C) conditioning the slurry with SO.sub.2 under aeration at a pH of about 5.5 to about 7.

Abstract: A process for separating and recovering minerals, such as molybdenum or coal, from ores with which they occur by addition of a dimercaptothiadiazole to an ore flotation process.

Abstract: A new depressant for use in enhanced separation of polymetallic sulphides is described. The depressant agent is used in conjunction with conventional collector agents and frothing agents in the flotation separation of copper, nickel, lead, zinc sulphides by depressing iron sulphides such as pyrrhotite, pyrite and marcasite in the tailing. The depressant consists of a cross-linked starch chemically combined with a polyacrylate and sugar free lignin sulphonate.

Abstract: This invention relates to a method of enhanced recovery of phosphate in the double flotation process for the benefication of phosphate ore, more particularly to the use of pH modifiers-silica depressants:sodium silicate;soda ash (Na.sub.2 CO.sub.3); orsoda silicate and soda ash, alone or in combination with one or more ingredients selected from the group consisting of: starch, dextrin, sodium sulfite and trisodium phosphate, added to the casutic or ammonia reagent used to prepare the patty acid-fuel oil mixture in the first stage of the double flotation process.

Abstract: Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow.

Abstract: Various acrylamide/allyl thiourea polymers and their use as depressants in the beneficiation of sulfide minerals from ores are disclosed.

Abstract: A method of beneficiating a phosphate ore containing apatite and dolomite impurities consisting of reagentizing a sample of the ore with an aqueous solution containing a cationic collector and sodium chloride and subjecting the ore to flotation to float the apatite fraction.

Abstract: A process for the recovery of mineral values from base metal ores is disclosed. Specifically, a froth flotation process is disclosed which comprises contacting an aqueous ore slurry with an effective amount of hemicellulose, a mineral collector and a frothing agent.

Abstract: The separation of coal from pyrite is enhanced by the use of an effective amount of a polymeric acid or salt thereof as a pyrite depressant in conventional flotation processes. The polymeric acid may be a carboxylic or sulfonic acid. An example of a salt of a polymeric acid useful in the process is sodium polyacrylate.

Abstract: The separation of coal from pyrite during a froth flotation process is enhanced by the use of an effective amount of a pyrite depressant. The depressant is a hydrophilic nitrogen-sulfur-containing compound.

Abstract: A collector composition for use in froth flotation processes comprises two collectors. One of the collectors is preferably an N-(hydrocarbyl)-alpha, omega-alkanediamine, an (omega-aminoalkyl) hydrocarbon amide or mixture thereof. The second collector is a thiocarbonate, a thionocarbamate, a thiophosphate, thiocarbinilide, thiophosphinate, mercaptan, xanthogen formate, xanthic ester or mixture thereof. The collector composition floats a broad range of metal-containing minerals.

Abstract: The method of beneficiating a phosphate ore comprising apatite and including dolomitic impurities comprising reagentizing the ore having a particle size in the range of 75 .mu.m to about 420 .mu.m with an aqueous solution having a pH of from 3.5 to 4.5 and containing a fatty acid anionic collector and sodium chloride and subjecting the ore to froth flotation to float away the dolomitic impurities.

Abstract: The flotation of desired mineral ores is selectively depressed by the use of an effective amount of a polycarboxylic acid or salt thereof in a reverse flotation process. As an example, the flotation of iron-containing minerals, such as iron oxides or iron powder, is selectively depressed when compared to the flotation of silicate gangue thus facilitating the recovery of the desired mineral by the use of an effective amount of a polycarboxylic acid or salt thereof such as sodium polyacrylate.

Abstract: A polyamine substituted dithiocarbamate composition is provided. Also provided are minerals depressant compositions for recovering mineral values from an ore or concentrate wherein the values are recovered in a froth from an aqueous slurry. A process of forming the minerals depressant compositions and an improved ore flotation process using the minerals depressant compositions are also provided.

Abstract: A phosphate ore flotation process for subjecting a phosphate ore containing dolomitic impurities to beneficiation as follows: The flotation feed is first conditioned with fatty acid and fuel oil as collectors and then reconditioned with humic acid as a modifier; subjecting the reconditioned flotation feed to rougher phosphate flotation to collect the rougher phosphate concentrate from the overflow; subjecting said rougher phosphate concentrate to at least one cleaner phosphate flotation; and recovering the phosphate product in the overflow from said cleaner phosphate flotation step.

Abstract: A process for beneficiating phosphate containing ores, wherein promoter reagents are added to the ore slurry prior to the addition of collectors and depressants for flotation of the carbonate and silica components. The promoters aid in increasing the rejection of the magnesium present during carbonate and silica flotation steps and recovery of phosphates, so that acceptably low magnesium levels for phosphoric acid production can be achieved in a phosphate concentrate in a single rougher stage. Preferred promoters include sodium carbonate and ammonium hydroxide.

Abstract: Tri-alkali metal di(carboxyalkyl) dithiocarbamates and triammonium-di(carboxyalkyl) dithiocarbamates which can be characterized by the formula ##STR1## wherein R and R' can be the same or different and are selected from the group consisting of alkylene radicals, preferably alkylene radicals each preferably having from 1 to 12 carbon atoms, and wherein M is selected from the group consisting of alkali metal atoms and ammonium; their use as ore flotation depressants; and a process for making these novel compositions are disclosed.

Abstract: A process for the froth flotation separation of value sulfide minerals from gangue iron sulfide minerals in which a novel terpolymer of copolymer of acylamide, acrylic acid and/or derivatives of acrylamide and acrylic acid is employed as a depressant for the gangue iron sulfide minerals.

Abstract: Process for the selective separation of kaolinite and feldspar by flotation in aqueous pulp, wherein flotation is carried out at the pH-value of the pulp which is naturally obtained during suspension of the mixture of minerals in water using water-soluble salts with trivalent metal ions as activators and depressors, in the presence of cationic and/or anionic surfactants as collectors, and optionally in the presence of other standard flotation aids.

Abstract: A process for recovering phosphate values from silica-containing phosphate ores is provided. The ore has a particle size in the range of about 0.6 to 1.2 mm and is subjected to selective flotation in the presence of a cationic flotation reagent comprising a di(hydrophobic group) quaternary ammonium salt, wherein each of the hydrophobic groups contain 6 or more carbon atoms and at least one of the groups contains from about 10-20 carbon atoms, in combination with a hydrocarbon oil and a phosphate depressing agent.

Abstract: A process and reagents are described for separating beryllium silicate concentrates by flotation from oxidic minerals. The process is especially suitable for the separation of phenacite and bertrandite present in ores with complex gangue compositions. The ore is ground and subjected to acid pretreatment, then conditioned by the addition of pH modifier, alkali fluoride activator and a depressant containing sodium hexametaphosphate and carboxymethyl cellulose, or hexametaphosphate and quebracho. The conditioned ore is thereafter treated with a tall oil fatty acid-based collector mixture, of general formula C.sub.17 H.sub.31-35 COOH; which also contains cresylic acid, kerosene and a branched short-chained aliphatic alcohol, such as methyl-iso-butyl carbinol. Mercapto acetic acid and alkali metal hydrogen sulphide may also be added in the second and third stages of conditioning, respectively, for increasing selectivity. The mineral concentration process includes conventional rougher and cleaner flotation steps.

Abstract: A process and composition are provided for the froth flotation beneficiation of iron minerals from iron ores containing silicate and phosphate minerals, comprising as collectors a combination of a primary amine and a nitrogen compound containing an anionic group selected from methylene carboxylic acid, ethylene phosphoric acid and methylene phosphonic acid.

Abstract: Organic ionic collecting agents for the selective flotation of lead and zinc ores, said agents having the following general formula: ##STR1## wherein the symbols have the following meanings: R represents an alkoxyl group having from 3 to 12 carbon atoms;R.sub.1 represents H, a linear or branched chain alkyl group, an alkoxyl or hydroxyalkyl group containing up to 12 carbon atoms;X represents H, Cl, Br, I, F, CN, CONH.sub.2, NO.sub.2, SO.sub.2 NH.sub.2 ;M represents H, Na, K, Li, Cs.

Abstract: A flotation tank which is elongate and is divided along its length into individual compartments. Injectors (2) for each compartment are connected laterally to the tank (1) approximately 30 cm to 50 cm below the surface of the suspension so that the suspension flows out in a forward direction towards the outlet end and scum removal trough (3) of the flotation tank (1). The injectors are preferably connected both at their inlet side and their outlet side to the same compartment. The removal of scum is preferably effected by means of cyclones which are provided in a vertical arrangement at the outlet end of the flotation tank.

Abstract: Disclosed is a process for separating resin from reduced size resin-bearing coal particles by treating the particles with ozone. Particles of reduced size resin-bearing coal are preferably mixed with water to form a slurry. The slurry is then treated with ozone for a short length of time. The slurry is then subjected to froth flotation. The ozone selectively oxidizes the coal, decreasing its hydrophobicity causing the relatively more hydrophobic resin to attach to the bubbles formed during the flotation process. A much improved separation efficiency for resin flotation from coal is observed.

Abstract: An improved method of separating non-sulfide value minerals from non-sulfide ores is disclosed. The improved method includes the step of adding a depressant selective for siliceous gangue minerals and materials to a flotation slurry previously conditioned with an anionic collector. In preferred embodiments, the depressants comprise copolymers or terpolymers derived from acrylamide units and N-acrylamidoglycolic acid units. The method provides generally improved recoveries of non-sulfide value minerals at higher grade, in a reduced number of flotation steps and at reduced consumption levels of flotation reagents.

Abstract: Certain water dissipatable polyester materials containing ether groups and metal sulfonate groups are useful as depressants for siliceous gangue in the froth flotation separation of zinc sulfide concentrates from complex ores containing, minerals of other metals such as lead and iron, as well as various silicon compounds. The polyester materials ae effective in amounts ranging from about 0.03 to about 1.5 kg/tonne of ore feed. Zinc rougher concentrates when conditioned with the depressant yields zinc cleaner concentrates containing less than about 1.5% silica without the need for extensive regrinding of the rougher concentrate. Particularly useful polyester material is prepared from an acid component of from about 80 to 85 mole % isophthalic acid with the remainder comprising mainy 5-sodiosulfoisopthalic acid, and a diol component of from about 50 to 60 mole % diethylene glycol with the remainder comprising mainly 1.4-cyclohexanedimethanol.

Abstract: Process for the selective separation of kaolinite and feldspar by flotation in aqueous pulp, wherein flotation is carried out at the pH-value of the pulp which is naturally obtained during suspension of the mixture of minerals in water using water-soluble salts with trivalent metal ions as activators and depressors, in the presence of cationic and/or anionic surfactants as collectors, and optionally in the presence of other standard flotation aids.

Abstract: Gold values are obtained from gold cyanidation tailings or gold bearing ores by treating the same with a flotation collector consisting of 5 to 20% xanthate collector and 80 to 95% fatty acid collector of a pulp pH range from 5 to 8.

Abstract: An aqueous dispersion of unreacted particulate petroleum coke substantially comprising carbon and containing a small amount of ash substantially comprising vanadium constituents and other materials from a process for the partial oxidation of petroleum coke to produce synthesis gas is mixed with a hydrocarbon alkoxy sulfate and a frothing agent. After pH adjustment, if necessary, the mixture is subjected to aeration with or without mechanical agitation in a froth flotation zone. About 5 to 25 wt. % of the unconverted particulate petroleum coke (basis carbon) particles float in the froth layer that is formed. The remainder of the unconverted petroleum coke comprising coarser particles is suspended in a bottom aqueous dispersion on which the froth layer floats. In addition, selective separation of the vanadium constituents in the unconverted petroleum coke ash takes place. The vanadium content of the ash in the floated portion of unconverted petroleum coke is unexpectedly increased about 10 to 50 weight percent.

Abstract: This invention relates to a method of beneficiating coal or mineral ores containing a metaliferous sulfide, e.g. iron sulfide or pyrite, and comprises removal of unwanted components, including pyrite, from such ores by subjecting an aqueous pulp of the pulverized mineral or coal to a froth flotation process in which pyrites are depressed by a depressant composition comprising xanthan gum, a hydroxycarboxylic acid and sodium silicate. The process is especially useful for removal of pyrite from a solid carbonaceous fuel, e.g., coal containing pyrite, and for the recovery of non-ferrous metal concentrates from ores containing pyrite. The coal or ore may be subjected to a mild preoxidation treatment to enhance sulfide removal in the subsequent froth flotation operation.

Abstract: This invention relates to a novel composition which is useful as a collector for the recovery of nonferrous metal-containing sulfide minerals and sulfidized metal-containing oxide minerals from ores in a froth flotation process. The novel composition comprises (a) an organic compound containing one or more monosulfide units wherein the sulfur atom(s) are bound to aliphatic or cycloaliphatic carbon atoms, and the total carbon content of the compound is such that the compound has sufficient hydrophobic character to cause metal-containing sulfide mineral or sulfidized metal-containing oxide mineral particles to be driven to an air/bubble interface; and (b) an alkyl thiocarbonate, a thionacarbamate, a thiophosphate, or mixtures thereof.

Abstract: A process for separating and recovering non-metallic minerals, particularly phosphate, from an ore containing non-uniform sized particles, including colloidal particles. The ore is slurried in an alkaline, aqueous solution with a dispersing agent. A flotation collector is added, and the mixture is contacted with a hydrophobic, high molecular weight, nonionic polymer to flocculate the fine particles and make them amenable to subsequent flotation. A second embodiment provides a process for the recovery of an upgraded non-metallic ore from ore slimes, such as phosphate slimes, utilizing a high molecular weight, polyacrylamide, anionic flocculating agent.

Abstract: A process for the separation of phosphate minerals from a phosphate-carbonate ore, by flotation, wherein a phenol polymer such as a resol or a novolak, which improves the yield and selectivity of the phosphate minerals with respect to the carbonate minerals, is used in addition to a collector agent in the flotation.

Abstract: The efficiency of metals separation using ore flotation is improved by the use of certain substituted hydrocarbylene trithiocarbonates as suppressants for undesired metals.

Abstract: An aqueous dispersion of unreacted particulate petroleum coke substantially comprising carbon and containing a small amount of ash substantially comprising vanadium constituents and other materials from a process for the partial oxidation of petroleum coke to produce synthesis gas is mixed with C.sub.4 to C.sub.8 acyclic and/or cyclic alkanols and a frothing agent. After pH adjustment, if necessary, the mixture is subjected to aeration with or without mechanical agitation in a froth flotation zone. About 60 to 95 wt. % of the unconverted particulate petroleum coke (basis carbon) particles float in the froth layer that is formed. The remainder of the unconverted petroleum coke comprising coarser particles is suspended in a bottom aqueous dispersion on which the froth layer floats. In addition, selective separation of the vanadium constituents in the unconverted petroleum coke ash takes place.

Abstract: 3-Hydroxytrimethylene sulfides are useful in ore flotation processes as depressants for iron, nickel, lead and/or zinc.

Abstract: The invention concerns the use of 5-hydroxy-3-thiazolidine-2-thiones of the structure I ##STR1## where R.sub.1 =(CHOH).sub.m, R.sub.2 =(CHOH).sub.n where (m+n)=0 to 6, and R.sub.3 is alkyl or hydroxy-alkyl as depressants in the flotation of mixtures of base metal minerals, particularly those containing molybdenum, copper, lead, zinc; and to flotation processes using these compounds.

Abstract: The present invention comprises a process for the separation of ore components by flotation comprising: grinding ore to form pulp, mixing said pulp with sulfide ions and cyanide ions, adjusting the concentration of said sulfide ions to a level at least sufficient to cause depression of base metal mixed sulfides but insufficient to cause substantial activation of pyrites, and adjusting the concentration of said cyanide ions to a level at least sufficient to cause auxiliary depression of the mineral components of said ore which are required to be depressed in said flotation, but insufficient to cause overdepression of said mineral components; said sulfide ions and cyanide ions having been introduced to said pulp at predetermined times and in a predetermined sequence.

Abstract: Polyhydroxytrithiocarbonates can be used as depressants in ore flotation.

Abstract: An improved phosphate ore beneficiation process wherein phosphate ore containing coarse, weathered dolomite in the flotation feed thereof is subjected to beneficiation as follows: The flotation feed is subjected to a rougher phosphate flotation step wherein it is treated with fatty acid and fuel oil and wherefrom is removed the coarse, weathered dolomite in one or more subsequent cleaner phosphate flotation steps without the use of additional flotation reagents added thereto; subjecting the float from said cleaner phosphate flotation step(s) to a sulfuric acid based partial deoiling step and then to a phosphate-carbonate flotation step wherefrom is collected a first fraction of the phosphate flotation feed values as underflow subjecting the overflow from said phosphate-carbonate flotation step to a sulfuric acid based total deoiling step wherefrom the resulting deoiled material from said total deoiling step is subsequently introduced and subjected to carbonate flotation step(s) using alkyl diphosphonic acid a

Abstract: A process for beneficiating phosphate containing ores, wherein promoter reagents are added to the ore slurry prior to the addition of collectors and depressants for flotation of the carbonate and silica components. The promoters aid in increasing the rejection of the magnesium present during carbonate and silica flotation steps and recovery of phosphates, so that acceptably low magnesium levels for phosphoric acid production can be achieved in a phosphate concentrate in a single rougher stage. Preferred promoters include sodium carbonate and ammonium hydroxide.

Abstract: Ammonium dialkylaminoalkyl (thiocarbonyldithio) alkanoates, alkali metal dialkylaminoalkyl (thiocarbonyldithio) alkanoates, their use as flotation agents, and a process for the production of these novel compositions are disclosed. N,N-dialkylaminoalkyl mercaptoalkanoate, its use as an intermediate in the production of the novel ammonium dialkylaminoalkyl (thiocarbonyldithio) alkanoates and alkali metal dialkylaminoalkyl (thiocarbonyldithio) alkanoates, and a process for the production of this novel composition are also disclosed.

Abstract: A phosphate ore beneficiation process wherein phosphate ore containing coarse, weathered dolomite in the flotation feed thereof is subjected to beneficiation as follows: Said feed is sent to rougher phosphate flotation wherein it is treated with fatty acid and fuel oil and wherefrom is removed the coarse weathered dolomite in one or more cleaner phosphate flotations, without the use of additional flotation reagents added thereto, to thereby remove the coarse carbonate, i.e., dolomite fraction, which fraction would not otherwise float in subsequent carbonate flotation. In many instances this process effects reduction of the carbonate, as MgO contamination in the final concentrate, to less than about 1.0 percent by weight. Process feed can be prepared from the coarse pebble waste or the conventional flotation feed of the original phosphate matrix.

Abstract: In an ore flotation process for recovering copper values from an aqueous slurry the improvement comprises a depressant composition of an amino-substituted carboxylic acid derivative or a mercapto-substituted carboxylic acid derivative in combination with a thiocarbonate derivative.

Abstract: A method for the separation of a mixture of polyvinyl chloride particles and polyethylene terephtalate particles comprising the steps of applying a solution composed of a low density solvent of polyvinyl chloride, water and sodium hydroxide to flakes of polyvinyl chloride and polyethylene terephtalate whereby the polyvinyl chloride absorbs the solvent contained in the solution, which changes the density of the polyvinyl chloride so that it is less than the density of the polyethylene terephtalate. The plastics may then be differential density separated by flotation or centrifugation and recovered.

Abstract: An improved froth flotation installation for separating solid particles from an aqueous slurry by delivering a stream of the aqueous slurry directly into a vortex chamber along with a supply of bubble-forming gas. The kinetic energy of the slurry creates necessary froth bubbles, and provides mechanical agitation of the contents of a froth flotation separation zone upon discharge from the bottom of the vortex chamber. In multi-zone froth flotation installations, the direction of flow of the aqueous slurry of unrecovered solid particles is deliberately changed at least twice between a first froth flotation zone and a last froth flotation zone to improve solids-froth contact and to minimize the possibility of particles adopting a short circuit path through the installation. Multiple froth flotation zones are serviced by a single slurry pump in a preferred embodiment.

Abstract: A process for the beneficiation of base metal sulfide mineral values from base metal sulfide ores with selective rejection of gangue sulfide minerals at pH values below about 10.0 by froth flotation is disclosed. The process includes the use of a new and improved collector which at pH values below about 10.0 exhibits unexpectedly high collector activity for base metal sulfide minerals of copper, nickel, molybdenum, cobalt and zinc and selectively rejects gangue sulfide minerals such as pyrite and pyrrhotite. The collector for base metal sulfide mineral values for use in the process comprises at least one diorganomonothiophosphinate compound having the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each, independently, selected from saturated and unsaturated hydrocarbyl radicals, alkyl polyether radicals, and aromatic radicals, and such radicals, optionally and independently, substituted with polar groups selected from halogen, nitrile and nitro groups; or wherein R.sup.1 and R.sup.

Abstract: The method of beneficiating phosphate tailings and debris waste material is disclosed for producing enriched phosphate ore and a sand product which is usable for glass, cement and the like or for land reclamation. The method includes treating the phosphate tailings and waste material with a cationic reagent and subjecting the tailings and waste material to a flotation process to overflow the sand product therefrom. The underflow phosphate ore is subjected to a conventional double flotation process to produce a high grade phosphate product. The sand product may either be directly pumped into an existing phosphate quarry for land reclamation or may be deregentized and treated with anionic reagents to remove remaining impurities providing a sand product suitable for glass, cement and the like.

Abstract: A process for the separation of phosphate minerals from a phosphate-carbonate ore, by flotation, wherein a phenol polymer such as a resol or a novolak, which improves the yield and selectivity of the phosphate minerals with respect to the carbonate minerals, is used in addition to a collector agent in the flotation.