Synthetic Resin Patents (Class 210/654)
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Patent number: 12048903Abstract: Embodiments disclosed herein are directed to membranes for filtration, methods of manufacturing the same, and membrane modules incorporating the same. In an embodiment, a membrane is disclosed. The membrane includes a porous cellulose layer, a polyamide thin film layer bonded to the porous cellulose layer, and a fabric support layer that supports the porous cellulose layer and the polyamide thin film layer. The porous cellulose layer has a pore size of about 30 nm to about 500 nm at an exposed surface of the porous cellulose layer.Type: GrantFiled: September 11, 2017Date of Patent: July 30, 2024Inventors: John Herron, Edward Gerard Beaudry
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Patent number: 11549876Abstract: An apparatus and method for determining an amount of chemical input, and more particularly to an apparatus and method for determining the amount of a chemical to be added, which is necessary to achieve target water quality, wherein a required chemical concentration can be accurately calculated based on the temperature of the water and the target turbidity of the water includes an information-receiving unit configured to receive at least one of environmental information, chemical information, and water-quality information of the water present in a specific area and a chemical input determination unit configured to derive a multiple regression equation based on the received environmental information, chemical information, and water-quality information and to determine the future input of a chemical that is added to satisfy a target turbidity of the water present in the specific area based on the multiple regression equation.Type: GrantFiled: September 11, 2017Date of Patent: January 10, 2023Assignee: DOOSAN ENERBILITY CO., LTD.Inventors: Seongjoon Kim, Jungwon Park, Youngkyu Lee
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Patent number: 11198100Abstract: The present invention relates to a composite semipermeable membrane including: a supporting membrane including a substrate and a porous supporting layer; and a separation functional layer disposed on the porous supporting layer, in which the separation functional layer includes: a crosslinked polyamide; and a hydrophilic polymer which is a polymer of a monomer having an ethylenically unsaturated group, and a surface of the separation functional layer has a ratio of the number of oxygen atoms to the number of nitrogen atoms (O/N ratio), both determined by X-ray photoelectron spectrometry, of 1.5-10, and a standard deviation of the O/N ratio of 0.15 or larger.Type: GrantFiled: June 29, 2017Date of Patent: December 14, 2021Assignee: TORAY INDUSTRIES, INC.Inventors: Tsuyoshi Hamada, Jun Okabe, Takafumi Ogawa, Koji Nakatsuji, Masahiro Kimura
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Patent number: 11130094Abstract: The use of an amine of the formula (I) in which the R1 to R5 radicals are each as defined in the description, and an absorbent and a process for removing acidic gases from a fluid stream, especially for selectively removing hydrogen sulfide over carbon dioxide. The invention also relates to particular amines suitable for selective removal of hydrogen sulfide. Absorbents based on amines of the formula (I) have high selectivity, high loading capacity and good regeneration capacity.Type: GrantFiled: October 7, 2019Date of Patent: September 28, 2021Assignee: BASF SEInventors: Thomas Ingram, Georg Sieder, Torsten Katz, Gerald Vorberg, Ralf Notz
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Patent number: 10898857Abstract: The invention relates to membranes, membrane modules, and applications therefor. In particular, the invention relates to the construction of membranes for use in osmotically driven membrane processes.Type: GrantFiled: September 7, 2017Date of Patent: January 26, 2021Assignee: OASYS WATER LLCInventors: Diego Amado-Torres, John Charest
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Patent number: 10766005Abstract: Nanostructured polyelectrolyte bilayers deposited by Layer-by-Layer deposition on nanoporous membranes can be selectively crosslinked to modify the polyelectrolyte charge density and control ionic selectivity independent of ionic conductivity. For example, the polyelectrolyte bilayer can comprise a cationic polymer layer, such as poly(ethyleneimine), and an anionic polymer layer, such as poly(acrylic acid). Increasing the number of bilayers increases the cation selectivity when the poly(ethyleneimine) layer is crosslinked with glutaraldehyde. Crosslinking the membranes also increases the chemical and mechanical strength of the polyelectrolyte films. This controllable and inexpensive method can be used to create ion-selective and mechanically robust membranes on porous supports for a wide range of applications.Type: GrantFiled: September 11, 2018Date of Patent: September 8, 2020Assignee: National Technology & Engineering Solutions of Sandia, LLCInventors: Leo J. Small, Stephen Percival, Erik David Spoerke
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Patent number: 10696025Abstract: A structure, and methods of making the structure are provided in which the structure can include: a membrane having a first layer and a second layer, the first layer comprising polymer chains formed with coordination complexes with metal ions, and the second layer consisting of a porous support layer formed of polymer chains substantially, if not completely, lacking the presence of metal ions. The structure can be an asymmetric polymeric membrane containing a metal-rich layer as the first layer. In various embodiments the first layer can be a metal-rich dense layer. The first layer can include pores. The polymer chains of the first layer can be closely packed. The second layer can include a plurality of macro voids and can have an absence of the metal ions of the first layer.Type: GrantFiled: July 13, 2015Date of Patent: June 30, 2020Assignee: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Klaus-Viktor Peinemann, Luis Francisco Villalobos Vazquez de la Parra
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Method of preparing thin film composite forward osmosis membranes using polyethylene porous supports
Patent number: 10525422Abstract: The present invention relates to a thin film composite forward osmosis membrane with a polyethylene porous support, and a thin film composite forward osmosis membrane which is low cost, has excellent durability and chemical resistance, and outstanding performance (water flux and specific salt flux) may be provided in the present invention.Type: GrantFiled: July 6, 2017Date of Patent: January 7, 2020Assignee: Korea University Research and Business DevelopmentInventors: Jung-hyun Lee, Sang Hee Park, Soon Jin Kwon -
Patent number: 10384171Abstract: The present invention relates to a complete process for preparation of high flux and salt rejection thin film composite (TFC) reverse osmosis (RO) membrane including process for preparation of support membrane for thin film, process for thin film coating of support membrane by in-situ interfacial polymerization between diamines and trimesoyl chloride, machine design, chemistry and details of process (engineering+chemistry+ambient) parameter at 1×100 sqm scale upgradeable to a scale even 10-20 times higher. The produced membrane is characterized by 96% salt rejection and 48 LM-2H 1 flux with 2000 ppm sodium chloride solution at 250 psi pressure and 95% salt rejection and 46 LM2H 1 flux with 35000 ppm sodium chloride solution at 900 psi pressure. The present invention also relates to complete machine design for PSF ultrafiltration membrane casting and coating for TFC membrane production at commercial level.Type: GrantFiled: November 25, 2013Date of Patent: August 20, 2019Assignee: Council of Scientific & Industrial ResearchInventors: Alamuru Venkata Rami Reddy, Saha Nirmal Kumar, Jewrajka Suresh Kumar, Jitendra Jaydevprasad Trivedi, Paramita Ray, Nagendra Pathak, Gaurang Shambuprasad Trivedi, Temubha Bhupatsinh Gohil, Rahul Shubhash Patil
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Patent number: 10258935Abstract: The present invention provides a high-flux polyamide composite membrane, which includes a composite membrane body, wherein the composite membrane body includes a non-woven fabric, a porous supporting layer and a polyamide layer which are successively arranged; and the polyamide layer is prepared by a polyamine solution and a poly-acyl chloride solution through an interface polymerization reaction, wherein the polyamine solution contains amino acid. The amino acid adopted in the technical solution of the present invention can be used as an end-capping reagent to react with acyl chloride groups, thereby regulating a polyamide layer structure, decreasing a cross-linking degree of the polyamide layer, and opening a channel for the passing of water molecules; and moreover, the hydrophilic performance of a membrane surface can also be improved, and a water flux is increased while a high interception rate is ensured.Type: GrantFiled: June 7, 2017Date of Patent: April 16, 2019Assignee: HUNAN OVAY TECHNOLOGY CO., LTD.Inventors: Bo Peng, Hongwei Lu, Qunhui Hu, Hui Yu, Pan He, Jin Wang, Dan Liu, Chunqing Wang, Pengjun Liu
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Patent number: 10011692Abstract: The present invention relates to a hollow fiber (HF) module having fibers modified with a thin film composite (TFC) layer comprising aquaporin water channels.Type: GrantFiled: January 30, 2015Date of Patent: July 3, 2018Assignee: Aquaporin A/SInventors: Jörg Vogel, Jesper S. Groth, Kent Høier Nielsen, Oliver Geschke
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Patent number: 10005887Abstract: The present invention relates a mobile electronic device comprising at least one part made of a polymer composition comprising for more than 80% by weight (% wt.) relative to the total weight of the composition (C) of an aromatic polysulfone polymer comprising a residual chlorine content in an amount of less than 25 ?eq/g polymer.Type: GrantFiled: December 18, 2013Date of Patent: June 26, 2018Assignee: Solvay Specialty Polymers USA, LLCInventors: Atul Bhatnagar, Hong Chen, Theodore Moore
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Patent number: 9700848Abstract: A composite membrane comprising: a) a porous support; b) a gutter layer, a portion of which is present within the support and a portion of which is outside of the support; and c) a discriminating layer on the gutter layer; wherein: (i) the portion of the gutter layer outside of the support has an average thickness (GLe) of 10 nm to 900 nm; and (ii) the portion of the gutter layer present within the support has an average thickness (GLi) of 10% to 350% of GLe.Type: GrantFiled: June 26, 2013Date of Patent: July 11, 2017Assignee: Fujifilm Manufacturing Europe B.V.Inventors: Takeshi Umehara, Shigehide Itoh, Petrus Van Kessel, Yujiro Itami, Masatoshi Nakanishi, Hiroyuki Noda, Akihiro Kurima, Kimiko Iwahashi
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Patent number: 9616392Abstract: A thin film composite polyamide membrane comprising a porous support and a thin film polyamide layer characterized by possessing: i) an azo (—N?N—) content of from 0.30% to 0.80%, as measured by pyrolysis gas chromatography; and ii) a dissociated carboxylate content of at least 0.18 mol/kg as measured by RBS at pH 9.5.Type: GrantFiled: December 15, 2014Date of Patent: April 11, 2017Assignee: Dow Global Technologies LLCInventors: Ian A. Tomlinson, Robert C. Cieslinski, Bruce B. Gerhart, David D. Hawn, Mou Paul, XiaoHua Qiu, Mark A. Rickard, Steven Rosenberg, Abhishek Roy, Chengli Zu
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Patent number: 9561474Abstract: A thin film composite membrane includes an active layer on a support membrane, wherein the active layer includes at least two chemically distinct first and second crosslinked polyamide film sub-layers. The first film sub-layer includes a polyamide unit; and the second film sub-layer includes a copolyamide with two chemically distinct polyamide units. The first film sub-layer is closer to the support than is the second film sub-layer.Type: GrantFiled: June 7, 2012Date of Patent: February 7, 2017Assignee: International Business Machines CorporationInventors: Radwan A. Alrasheed, Blake W. Davis, Jacquana T. Diep, Geraud J. Dubois, Young-Hye Na, Majed S. Nassar, Ankit Vora
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Patent number: 9527042Abstract: A separation membrane for water treatment, comprising a porous layer that is obtained by a phase separation method using a solution containing a resin and at least one of either an N,N-disubstituted isobutylamide or an N-monosubstituted isobutylamide.Type: GrantFiled: January 26, 2012Date of Patent: December 27, 2016Assignee: TORAY INDUSTRIES, INC.Inventors: Kentaro Takagi, Masakazu Koiwa, Masahiro Kimura, Yutaro Suzuki
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Patent number: 9314736Abstract: A separation composite membrane including: a separating layer for separating fluid components, the separating layer being constituted of a polymer having cross-linked structure, and a porous layer for supporting the separating layer, the porous layer having a maximum pore diameter of 0.05 to 0.5 ?m, the separating layer being partly impregnated into the porous layer in the range of 0.1 to 30% in terms of the impregnation amount ratio (?a) defined by Formula (A): [impregnation amount ratio (?a){%}=impregnation depth (s)/(membrane thickness (t1) of separating layer)×100]??(A).Type: GrantFiled: August 12, 2014Date of Patent: April 19, 2016Assignee: FUJIFILM CorporationInventor: Shigehide Itou
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Patent number: 9254279Abstract: Therapeutic compositions capable of removing excess nitric oxide are provided. The therapeutic compositions include nitronyl nitroxide monoradicals, B12 derivatives, flavonoid derivatives, the like and combinations thereof. The therapeutic compositions can be utilized in a number of suitable applications, such as to prevent or treat intradialytic hypotension during dialysis.Type: GrantFiled: May 12, 2004Date of Patent: February 9, 2016Assignees: Baxter International Inc., Baxter Healthcare S.A.Inventors: Sujatha Karoor, Ton That Hai, Cong Jiang, Paul Sanders, Cliff Holmes
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Patent number: 9211507Abstract: A method of manufacturing a water-treatment separating membrane includes forming an aqueous amine solution layer on a porous support, and forming a polyamide active layer by dropping droplets of an organic solution including an acyl halide compound on the aqueous amine solution layer. A water-treatment separating membrane manufactured by the same also is provided.Type: GrantFiled: April 24, 2014Date of Patent: December 15, 2015Assignee: LG CHEM, LTD.Inventors: Jae-Hong Kim, Young-Hoon Ko, Chong-Kyu Shin, Phill Lee
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Patent number: 9205384Abstract: The present invention relates to a reverse osmosis membrane including a porous support including a polysulfone layer; and a polyamide active layer formed on the porous support, wherein a concentration of sulfur (S) detected on a surface of the polyamide active layer is 1.8×10?3 units or less on average or a concentration of sulfur dioxide (SO2) detected on the surface of the polyamide active layer is 7×10?3 units or less on average, and a method of manufacturing a reverse osmosis membrane, the method including forming a porous support; and forming a polyamide active layer on the porous support by interfacially polymerizing a polyfunctional amine solution including a carbodiimide compound, and a polyfunctional acid halide compound solution.Type: GrantFiled: May 31, 2013Date of Patent: December 8, 2015Assignee: LG CHEM, LTD.Inventors: Jae-Hong Kim, Young-Ju Lee, Chong-Kyu Shin
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Patent number: 9079139Abstract: There is provided a reverse osmosis membrane including a porous support; a polysulfone layer formed on the porous support and having pores formed in a surface thereof, pores having a diameter of 40 nm or greater accounting for less than 0.5% of total pores; and an active layer.Type: GrantFiled: September 13, 2013Date of Patent: July 14, 2015Assignee: LG CHEM, LTD.Inventors: Hye-Jin Kwon, Seung-Yup Lee, Seung-Pyo Jeong, Phill Lee, Chong-Kyu Shin
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Publication number: 20150060364Abstract: Provided are thin film composite membrane structures comprising: a selective membrane layer for ion rejection attached to a support layer, the support layer comprising a multi-zone microfiltration membrane comprising: a porous support material; and at least two microfiltration zones, where a first zone comprises a first membrane and a second zone that is attached to the first zone and that coats at least a portion of the porous support material. Thin film composite membrane structures may be provided in reverse osmosis systems or nanofiltration systems. Also, thin film composite membrane structures may be provided in direct osmotic concentration systems, forward osmosis systems, or pressure retarded osmosis systems.Type: ApplicationFiled: March 15, 2013Publication date: March 5, 2015Inventors: Jeffrey R. McCutcheon, Thomas J. Hamlin, Mark T. Meyering, Liwei Huang
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Publication number: 20140353253Abstract: A polymeric membrane includes an active layer on a support. The active layer includes at least two chemically distinct crosslinked, polyamide films, and the films are crosslinked with each other at an interface.Type: ApplicationFiled: August 14, 2014Publication date: December 4, 2014Inventors: Robert David Allen, Young-Hye Na, Ratnam Sooriyakumaran
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Publication number: 20140284276Abstract: The present invention includes systems and methods for treatment of seawater RO system for recovering most of the water (i.e., 85-90%) from the concentrate of a brackish groundwater reverse osmosis treatment system that may use, e.g., a batch method. With proper pH control and antiscalant dosage, the batch-treatment SWRO system of the present invention can be used to recovery water from silica-saturated RO concentrate without fouling the membranes. Silica concentrations of over 1,000 mg/L are attainable with relatively minimal pre-treatment of the silica-saturated feed solution.Type: ApplicationFiled: June 9, 2014Publication date: September 25, 2014Inventor: Anthony J. Tarquin
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Patent number: 8839960Abstract: The present disclosure relates to polymeric matrices composed of protected amine compound residues and membranes composed from such polymeric matrices. In particular, the present disclosure relates to a polymeric matrix comprising amine compound residues, acyl compound residues and protected amine compound residues.Type: GrantFiled: December 21, 2010Date of Patent: September 23, 2014Assignee: General Electric CompanyInventor: Qingshan Jason Niu
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Patent number: 8778186Abstract: The invention provides a method of contacting a membrane having a highly cross-linked polydicyclopentadiene matrix with a feed solution having a) a first component with a molecular weight in the range of from about 100 g mol?1 to about 600 g mol?1 and a cross-sectional area of less than about 0.40 nm2 and b) a second component with a molecular weight in the range of from about 100 to about 600 grams g mol?1 and a cross-sectional area of greater than about 0.50 nm2 so that the feed solution is fractionated into a permeate comprising the first component and a retentate enriched in the second component.Type: GrantFiled: July 11, 2012Date of Patent: July 15, 2014Assignee: University of Iowa Research FoundationInventors: Ned B. Bowden, Abhinaba Gupta, Tyler R. Long
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Patent number: 8771516Abstract: Permselective asymmetric membranes suitable e.g. for hemodialysis, hemodiafiltration and hemofiltration of blood, and having improved performance, including improved sieving characteristics, providing enhanced removal of middle molecular weight substances, e.g. inflammatory mediators having a molecular weight between 20 and 40 kDa. The improved sieving characteristics are due to a narrow pore size distribution of the membranes created in the production process. Processes for the preparation of these membranes, devices comprising these membranes, and the use of these membranes in hemodialysis, hemodiafiltration and hemofiltration of blood, as well as in bioprocessing, plasma fractionation and the preparation of protein solutions.Type: GrantFiled: May 19, 2010Date of Patent: July 8, 2014Assignee: Gambro Lundia ABInventors: Bernd Krause, Carina Zweigart, Heinrich Behr
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Patent number: 8748556Abstract: A method of preparation for Self-supporting dynamic polymer membranes (called “dynamer” membranes) of the polyimine type is provided along with their use in separation processes, especially for separating gaseous species.Type: GrantFiled: March 11, 2010Date of Patent: June 10, 2014Assignee: Centre National de la Recherche ScientifiqueInventors: Gihane Nasr, Mihail-Dumitru Barboiu, Christophe Charmette, José Gregorio Sanchez Marcano
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Publication number: 20140054228Abstract: The present disclosure describes an additive that may be used in the manufacture of thin-film polyamide composite membranes. Thin-film polyamide composite membranes are used in filtration processes, such as reverse osmosis and nanofiltration. The additive may be an amino-siloxane compound. The amino-siloxane compound includes repeated groups of silicon bonded to oxygen with at least one amine functional group. Optionally, the amino-siloxane compound may also include a hydrophilic group. The additive reacts with an aqueous phase and an organic phase to form a thin polyamide film on a porous substrate.Type: ApplicationFiled: August 21, 2012Publication date: February 27, 2014Applicant: GENERAL ELECTRIC COMPANYInventors: Xingpeng ZHANG, Lawrence C. COSTA, Steven John HARROLD, Babu NARAYANSWAMY
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Patent number: 8616380Abstract: Improved methods for reducing boron concentration in seawater or brackish water, while simultaneously maintaining or improving the salt rejection of membrane and flow performance of polyamide reverse osmosis (RO) membranes include contacting the water with a composite membrane comprising moieties derived from an aromatic sulfonyl halide, a heteroaromatic sulfonyl halide, a sulfinyl halide; a sulfenyl halide; a sulfuryl halide; a phosphoryl halide; a phosphonyl halide; a phosphinyl halide; a thiophosphoryl halide; a thiophosphonyl halide, an isocyanate, a urea, a cyanate, an aromatic carbonyl halide, an epoxide or a mixture thereof.Type: GrantFiled: June 20, 2012Date of Patent: December 31, 2013Assignee: General Electric CompanyInventors: Hua Wang, David Allen Olson, Jiang Ji, Michael Todd Luttrell, Gary William Yeager, Joseph Anthony Suriano, Lawrence Charles Costa
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Publication number: 20130341277Abstract: A reverse osmosis (RO) membrane can include a porous substrate, a multilayer film arranged on the substrate, which includes a first layer including a polyelectrolyte and a second layer including a plurality of clay particles, where the first layer is arranged adjacent to the second layer. The multilayer film can be prepared by a spray-LbL process. The resulting RO membrane can provide high water permeability combined with high salt rejection.Type: ApplicationFiled: June 25, 2013Publication date: December 26, 2013Inventors: Jason R. Kovacs, Paula T. Hammond
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Publication number: 20130118983Abstract: Improved integrally skinned asymmetric membranes for organic solvent nanofiltration, and their methods of preparation and use are disclosed. Membranes are formed from polybenzimidazoles by phase inversion and are then crosslinked by addition of crosslinking agents. These stabilise the membranes and allow solvent nanofiltration to be maintained even in the solvents from which the membranes were formed by phase inversion, and in strongly acidic and strongly basic solvents.Type: ApplicationFiled: July 19, 2011Publication date: May 16, 2013Applicant: IMPERIAL INNOVATIONS LIMITEDInventors: Andrew Guy Livingston, Yogesh Suresh Bhole
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Publication number: 20130112618Abstract: Filtration membrane comprising polymeric nanofibers and/or microfibers attaching dendrimer component presenting reactive sites selective for chemicals to be filtered, and related nanofibers and microfibers, composite materials, compositions, methods and system.Type: ApplicationFiled: August 8, 2012Publication date: May 9, 2013Inventors: Mamadou S. DIALLO, William A. GODDARD, III, Seong-Jik PARK, Manki CHO
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Publication number: 20130105395Abstract: In one aspect, the invention relates to engineered osmosis and related membrane-based separation technologies. Disclosed are semi-permeable nanostructured osmosis membranes comprising a film polymerized on a nanofiber support fabric, methods for osmotically-driven separation, the method comprising creating an osmotic pressure gradient across a semi-permeable nanostructured osmosis membrane comprising a film polymerized on a nanofiber support fabric, and methods of generating power comprising creating an osmotic pressure gradient across a semi-permeable nanostructured osmosis membrane comprising a film polymerized on a nanofiber support fabric. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: ApplicationFiled: November 11, 2010Publication date: May 2, 2013Inventors: McCutcheon Jeffrey R., Hoek Eric M.V., Bui Ngoc, Lind Mary L.
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Patent number: 8419941Abstract: A method for yielding concentrated ethanol from an ethanol water solution yielded from ethanol fermentation of a water solution of saccharide generated by a saccharification of the lignocellulose by enzyme is provided. Water is separated from the ethanol water solution yielded from ethanol fermentation of the water solution of saccharide generated by the saccharification of the lignocellulose by enzyme with pervaporation method using a water separation membrane. Condensate prepared by condensing ethanol vapor existing in a space above a liquid level of the ethanol water solution is collected.Type: GrantFiled: March 31, 2010Date of Patent: April 16, 2013Assignee: Honda Motor Co., Ltd.Inventors: Kazuhiro Kagawa, Pu Qian, Akihisa Tanaka
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Publication number: 20130020262Abstract: The invention provides highly cross-linked polydicyclopentadiene matrices and methods for using such matrices to separate components having varying cross-sectional areas.Type: ApplicationFiled: July 11, 2012Publication date: January 24, 2013Applicant: UNIVERSITY OF IOWA RESEARCH FOUNDATIONInventors: Ned B. Bowden, Abhinaba Gupta, Tyler R. Long
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Publication number: 20130015137Abstract: Disclosed and claimed is a method of removing contaminants from a process stream or stabilizing a system parameter in the process stream. The method includes providing a filtration system in communication with a controller, wherein the controller is operable to automatically initiate a flow from the process stream into the filtration system when the system parameter of the process stream is within above an upper threshold value and/or below a lower threshold value; and activating the filtration system, wherein the flow comprises a flow rate through the filtration system and the controller is operable to adjust the flow rate.Type: ApplicationFiled: July 14, 2011Publication date: January 17, 2013Inventors: Ana-Mariana Urmenyi, Amit Gupta, Chris D. Davies, Bert Simons
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Publication number: 20120325744Abstract: In a process and apparatus for treating produced water, for example for re-use in an oil or bitumen extraction operation of for treating frac water, the produced water flows through a series of treatment units. A portion of the produced water may by-pass one or more of the treatment units but the by-pass portion may be such that the treated water is still acceptable, for example for discharge or reuse. Concentrations of oil and grease, organic carbon, silica, pH or related parameters in the produced water may be monitored and used to control the process or apparatus. Control of the process may involve one or more of altering a by-pass portion, altering the addition of chemicals, and altering the operation of a unit process. The process may be controlled to respond to upset conditions, or such that the concentration of one or more limiting contaminants is near, but not over, a specified maximum for re-use or discharge.Type: ApplicationFiled: June 22, 2011Publication date: December 27, 2012Inventors: David M. Polizzotti, Kevin Paul McEvoy, Anthony Yu-Chung Ku, Carl Vess, Abdul Rafi Khwaja, Matthew Alan Petersen
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Patent number: 8313651Abstract: The present invention discloses a membrane stack comprising a first and second membrane layers, and a spacer layer disposed between said first and second membrane layers, said membrane stack configured such that fluid passes through said membrane stack in a direction substantially perpendicular to the plane of said membrane layers and said spacer layer. The application also discloses a module comprising a membrane as described above, said module having a fluid flow path that is substantially perpendicular to the plane of the major surface of the membrane and spacer layers ins aid membrane stack.Type: GrantFiled: June 27, 2011Date of Patent: November 20, 2012Assignee: Natrix Separations Inc.Inventors: Ronald F. Childs, Elena N. Komkova, Donna Lisa Crossley, Alicja M. Mika
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COMPOSITE MEMBRANES COMPRISING A SULFONATED POLYARYLETHER AND THEIR USE IN FORWARD OSMOSIS PROCESSES
Publication number: 20120273423Abstract: The present invention is directed to thin film composite membrane (TFC membrane) comprising a substrate layer (S) based on a sulfonated polymer, e.g. a sulfonated polyarylether, and a polyamide film layer (F) and further to a method for their preparation. Furthermore, the present invention is directed to osmosis processes, in particular to forward osmosis (FO) processes, using said membrane.Type: ApplicationFiled: April 27, 2012Publication date: November 1, 2012Applicants: National University of Singapore, BASF SEInventors: Martin Weber, Christian Maletzko, Volker Warzelhan, Natalia Widjojo, Tai-Shung Chung -
Publication number: 20120273421Abstract: Solvent and acid stable ultrafiltration and nanofiltration membranes including a non-cross-linked base polymer having reactive pendant moieties, the base polymer being modified by forming a cross-linked skin onto a surface thereof, the skin being formed by a cross-linking reaction of reactive pendant moieties on the surface with an oligomer or another polymer as well as methods of manufacture and use thereof, including, inter alia separating metal ions from liquid process streams.Type: ApplicationFiled: January 13, 2010Publication date: November 1, 2012Inventors: Mordechai Perry, Vera Ginzburg, Boris Ginzburg, Polina Lapido
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Publication number: 20120261344Abstract: Reverse osmosis membranes made by interfacial polymerization of a monomer in a nonpolar (e.g. organic) phase together with a monomer in a polar (e.g. aqueous) phase on a porous support membrane. Interfacial polymerization process is disclosed for preparing a highly permeable RO membrane, comprising: contacting on a porous support membrane, a) a first solution containing 1,3-diaminobenzene, and b) a second solution containing trimesoyl chloride, wherein at least one of solutions a) and b) contains nanoparticles when said solutions are first contacted, and recovering a highly permeable RO membrane.Type: ApplicationFiled: April 30, 2012Publication date: October 18, 2012Inventors: Christopher James Kurth, Jeffrey Alan Koehler, Meijuan Zhou, Brett Anderson Holmberg, Robert Leon Burk
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Publication number: 20120255909Abstract: Improved methods for reducing boron concentration in seawater or brackish water, while simultaneously maintaining or improving the salt rejection of membrane and flow performance of polyamide reverse osmosis (RO) membranes include contacting the water with a composite membrane comprising moieties derived from an aromatic sulfonyl halide, a heteroaromatic sulfonyl halide, a sulfinyl halide; a sulfenyl halide; a sulfuryl halide; a phosphoryl halide; a phosphonyl halide; a phosphinyl halide; a thiophosphoryl halide; a thiophosphonyl halide, an isocyanate, a urea, a cyanate, an aromatic carbonyl halide, an epoxide or a mixture thereof.Type: ApplicationFiled: June 20, 2012Publication date: October 11, 2012Applicant: GENERAL ELECTRIC COMPANYInventors: Hua Wang, David Allen Olson, Jiang Ji, Michael Todd Luttrell, Gary William Yeager, Joseph Anthony Suriano, Lawrence Charles Costa
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Publication number: 20120234761Abstract: This invention relates to heterogenous pore polymer nanotube membranes useful in filtration, such as reverse osmosis desalination, nanofiltration, ultrafiltration and gas separation.Type: ApplicationFiled: April 27, 2012Publication date: September 20, 2012Applicant: NanOasis Technologies Inc.Inventors: Timothy V. Ratto, Jason K. Holt, Alan W. Szmodis
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Publication number: 20120211424Abstract: The invention comprises a cross-linkable lyotropic (i.e., surfactant) liquid crystal (LLC) monomer platform that forms type I bicontinuous cubic (QI) polymer networks containing 3-D interconnected nanopores.Type: ApplicationFiled: January 25, 2012Publication date: August 23, 2012Inventors: Christopher Gabriel, Douglas Gin, Evan Hatakeyama, Brian Wiesenauer
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Publication number: 20120193291Abstract: A group of mutant PTP ? genes in malignant tumor are provided, which are ?PTP?245, ?PTP?652 and ?PTP?445 respectively. The mutation includes insertion of 95 new nucleotides after nucleotide at position 711, deletion of nucleotides at position 1015-1437, and deletion of nucleotides at position 1015-1437 accompanied by insertion of 340 nucleotides after coding exon at position 1681 and fusion of 26 new amino acids at C-terminal. The group of mutant PTP ? genes in different types of malignant tumor disclosed in the present application have not been reported all over the world so far. The detection method of using PTP ? mutant genes is useful in exactly diagnosing malignant tumor, developing new anti-tumor drugs, and targeted treatment at molecular pathologic level.Type: ApplicationFiled: November 25, 2010Publication date: August 2, 2012Inventor: Zhiwei Pan
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Publication number: 20120160771Abstract: A separating material formed by a solid substrate having a substrate surface, primary or secondary amines coupled to the substrate surface, and a graft polymer formed on the substrate by covalently coupling the primary or secondary amines with a thermally labile radical initiator and subsequently contacting the substrate surface with a solution of one or more polymerizable monomers. Methods for the extracorporeal treatment of blood, blood plasma or blood serum employing the separating material, for affinity adsorption, ion-exchange adsorption, hydrophobic adsorption, or hydrophilic adsorption employing the separating material, and a separating column employing the separating material are also disclosed.Type: ApplicationFiled: February 16, 2012Publication date: June 28, 2012Applicant: GAMBRO LUNDIA ABInventors: Markus Storr, Egbert Müller, Wolfgang Freudemann
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Patent number: 8197693Abstract: Sea water is not suitable for human consumption. Naturally present dissolved chemicals in sea water make it inconsumable. The precipitants and dissolved chemicals need to be separated from water to make it consumable. A combination of aeration system, filtration system, crystallizer, hydrophobic membrane carrying filter and pressure retarded osmosis system are used in various combination to desalinate the sea water. Pressure retarded osmosis process is also used to produce pressurized diluted brine which is further decompressed to by the turbine and used by the generators to produce electricity. Various heat exchange apparatus are used for energy conservation and efficient processing of water in a feasible way. The disclosure enables to purify water and provide an economical means for producing electricity.Type: GrantFiled: January 15, 2012Date of Patent: June 12, 2012Assignee: King Abdulazia City for Science and Technology (KACST)Inventor: Saad A Al-Jlil
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Patent number: 8196754Abstract: Water permeable membranes and methods of forming water permeable membranes are provided. The water permeable membranes are comprised of a cross-linked polyamide containing at least one bifunctional additive that is hydrophilic and reactive. Additionally, in accordance with other embodiments of this invention, methods of forming water permeable membranes comprised of a cross-linked polyamide containing at least one bifunctional additive that is hydrophilic and reactive are provided. Specifically, the water permeable membranes may comprise a membrane formed from a cross-linked aromatic or aromatic/aliphatic polyamide interfacially polymerized on a porous support. The presence of the at least one hydrophilic and reactive additive improves the flux and salt retention properties of the membrane in comparison to a membrane formed without the at least one hydrophilic and reactive additive.Type: GrantFiled: July 17, 2008Date of Patent: June 12, 2012Assignee: The Ohio States University Research FoundationInventor: W. S. Winston Ho
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Patent number: 8182695Abstract: This invention is related to the fields of organic chemistry and nanotechnology. In particular, it relates to materials and methods for the preparation of organic synthons and bridged macrocyclic module compounds. The bridged macrocyclic module compounds may be used to prepare macrocyclic compositions such as nanofilms, which may be useful for filtration.Type: GrantFiled: March 19, 2008Date of Patent: May 22, 2012Inventors: Jeffery A. Whiteford, William Freeman, Joshua W. Kriesel