Using Conserved Or Recirculated Fluid Patents (Class 210/677)
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Patent number: 11879092Abstract: An aqueous modified acid composition for industrial activities, said composition comprising: an alkanolamine and strong acid in a molar ratio of not less than 1:15, preferably not less than 1:10; it can also further comprise a metal iodide or iodate. Said composition demonstrates advantages over known conventional acids and modified acids.Type: GrantFiled: November 22, 2019Date of Patent: January 23, 2024Assignee: DORF KETAL CHEMICALS FZEInventors: Clay Purdy, Markus Weissenberger
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Patent number: 10843941Abstract: A method of recovering phosphoric acid from process water includes directing a process water stream having a pH and a first concentration of phosphoric acid and at least one salt into a vessel, contacting the process water stream with a sorption agent in the vessel, the sorption agent adsorbing phosphoric acid from the process water, withdrawing a first effluent including a first concentration of the at least one salt and a second concentration of phosphoric acid from the vessel, and contacting the sorption agent including the phosphoric acid with water, at least a portion of the phosphoric acid desorbing from the ion exchange media into the water to form a second effluent having a third concentration of phosphoric acid.Type: GrantFiled: March 6, 2015Date of Patent: November 24, 2020Assignee: Evoqua Water Technologies LLCInventors: Thomas Kenneth Mallmann, Justin W. Higgs, Kenneth Ray Workman
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Patent number: 10329178Abstract: A base product fluid is produced by adding anhydrous liquid ammonia and a first portion of sulfuric acid to water in a process line to form a mixed fluid. The mixed fluid may be cooled and a second portion of sulfuric acid may be added to the mixed fluid to form the base product fluid. The base product fluid may include a molecular compound that is a chelating compound. The molecular compound may have the formula: ((NH4)2SO4)a.(H2SO4)b.(H2O)c.(NH4HSO4)x. In the formula, a may be between 1 and 5, b may be between 1 and 5, c may be between 1 and 5, and x may be between 1 and 10.Type: GrantFiled: March 1, 2018Date of Patent: June 25, 2019Assignee: EARTH SCIENCE LABORATORIESInventors: David Nicholas, Reid Henry Bowman, Freddie L. Singleton
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Patent number: 9963759Abstract: Methods treat ash from waste incineration, wherein the methods at least comprise: a) the digestion of the ash by a leaching liquor containing phosphate ions in solution such as to form a first solid phase comprising impurities and a first liquid phase comprising phosphate ions; and b) the separation of said first liquid phase comprising phosphate ions from said first solid phase. Step a) is carried out for a duration of less than one hour or at a temperature of more than 40° C.Type: GrantFiled: December 19, 2014Date of Patent: May 8, 2018Assignee: ECOPHOS S.A.Inventor: Mohamed Takhim
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Publication number: 20150136706Abstract: A method of removing chromium from water using a weak base anion exchange resin at a pH above about 5 includes the step of periodically reducing a flow of the water through the ion exchange resin for a rest period, such that a secondary mechanism of chromium removal predominates, wherein chromium ions are removed from the weak base anion exchange groups and precipitated inside the ion exchange resin. In an alternative embodiment, rather than resting, the ion exchange resin is periodically conditioned with an acid so as to enhance the secondary mechanism.Type: ApplicationFiled: November 16, 2013Publication date: May 21, 2015Inventors: Michael C. GOTTLIEB, Peter S. MEYERS
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Patent number: 9017558Abstract: A process according to various approaches includes flushing an intermediate transfer line at first flow rate during a first portion of the step-time interval. The process also includes flushing the intermediate transfer line at as second different flow rate during a second portion of the step-time interval so that a greater volume of fluid is flushed from the intermediate transfer line during one of the first portion and the second portion of the step-time interval than during the other of the first portion and the second portion of the step-time interval.Type: GrantFiled: September 28, 2012Date of Patent: April 28, 2015Assignee: UOP LLCInventors: Jason T. Corradi, Stanley J. Frey, Sara A. Williams
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Publication number: 20150096940Abstract: The present invention relates to water treatment, in particular to a process for the removal of contaminants in a raw water source where the contaminants consist of organic species and inorganic species.Type: ApplicationFiled: May 24, 2013Publication date: April 9, 2015Inventors: Miguel Salvador Arias-Paic, Kelly Bryan Mccurry
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Patent number: 8992779Abstract: A process according to various approach includes flushing an intermediate transfer line between the first intermediate transfer line and the extract stream transfer line away from the adsorptive separation chamber to remove residual fluid from intermediate transfer line. The process may include directing the residual fluid flushed from the intermediate transfer line to a recycle stream to introduce the residual fluid into the adsorptive separation chamber.Type: GrantFiled: September 28, 2012Date of Patent: March 31, 2015Assignee: UOP LLCInventors: James W. Harris, Jason T. Corradi, Lewis H. Pettengill
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Patent number: 8986424Abstract: Method for rhenium recovery from copper solvent extraction solution. It is determined whether the copper solvent extraction solution contains trace amounts of rhenium. If so, a feedstock from the copper solvent extraction solution is provided, which is then filtered, producing filtered feedstock. Trace amounts of rhenium are absorbed from the filtered feedstock using a supply of ion exchange resin selective for rhenium. The ion exchange resin is washed. Trace amounts of rhenium are eluted from the ion exchange resin using a first amount of eluent, a second amount of eluent and a third amount of eluent. The first amount and the third amount of eluent produce supplemental feedstock and the second amount of eluent produces rhenium eluate. The rhenium eluate is collected and the ion exchange resin is protonated.Type: GrantFiled: December 20, 2011Date of Patent: March 24, 2015Assignee: Asarco LLCInventor: Neil Nebeker
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Patent number: 8980100Abstract: We provide a system and method for reverse osmosis treatment of water, including seawater and brackish water. Methods and systems of embodiments of the invention may include, for example, ultrafiltration followed by biofoulant removal, both of which precede reverse osmosis. In preferred embodiments the system is run at a low flux. For example, a flux of 6-8 GFD may be used with seawater. Additional embodiments may provide the above process in conjunction with a reverse-osmosis membrane cleaning system. The membrane cleaning system is a “clean in place” system that includes use of the natural pressure differential in the reverse osmosis system to remove biofoulants and their precursors.Type: GrantFiled: April 23, 2013Date of Patent: March 17, 2015Assignee: Aquatech International CorporationInventor: Ravi Chidambaran
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Patent number: 8961797Abstract: A valve assembly for a twin tank-type water treatment system includes and a tank selector valve assembly that includes first and second rotary selector valves driven in concert with another by a reversible electric motor. The motor drives the first and second selector valves between (a) a first position in which an untreated water inlet and a treated water outlet of the valve assembly are coupled to a first resin tank, and a second resin tank is connected to a regeneration valve, and (b) a second position which the untreated water inlet and the treated water outlet of the valve assembly are coupled to the second resin tank, and the first resin tank is connected to a regeneration valve. The rotary valves may be disks that rotate relatively rapidly on a common shaft driven by the electric motor through an arc of 180° or less.Type: GrantFiled: March 14, 2013Date of Patent: February 24, 2015Assignee: Clack CorporationInventor: Don Vaughan
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Publication number: 20140374351Abstract: A process for treating feed water for desalination, the process comprising: (a) removing one or more polyvalent anions from the feed water by feeding the feed water into a bed comprising one or more anion exchange resins under conditions sufficient to exchange the polyvalent ions in the feed water with one or more monovalent anions in the resin; and (b) regenerating the bed by feeding a brine stream into the bed under conditions sufficient to exchange one or more polyvalent anions in the resins with one or more monovalent anions in the brine stream.Type: ApplicationFiled: May 28, 2014Publication date: December 25, 2014Applicant: Lehigh UniversityInventors: Arup K. SenGupta, Ryan C. Smith
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Patent number: 8840793Abstract: The invention provides waste water treatment processes utilizing an ion exchange resin to remove sulphate anions, while adjusting the pH of the ion exchange loading solution with carbon dioxide gas. The effect of the resin loading reactions is that dissolved sulphate is replaced with sequestered carbon dioxide gas, in the form of dissolved bicarbonate, in the treated water and the cations are not removed from the solution.Type: GrantFiled: October 4, 2013Date of Patent: September 23, 2014Assignee: Bioteq Environmental Technologies Inc.Inventors: Michael Bratty, David Kratochvil
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Patent number: 8835518Abstract: A process for the reactivation of an acidic ion exchange resin is described. The invention relates to the treatment of an at least partially deactivated resin which has been deactivated by contact with an impure ethylenically unsaturated acid or ester containing target impurities. The reactivation includes the step of contacting the at least partially deactivated resin with an alcohol to thereby increase the activity thereof. The invention extends to reactivating a resin deactivated by contact with an impure ethylenically unsaturated acid, ester or nitrile containing target impurities by contacting the at least partially deactivated resin with an alcohol and a carboxylic acid to thereby increase the activity thereof. A reactivated resin and a process for preparing and purifying an ethylenically unsaturated acid or ester of the following formula: —R1—C(?(CH2)m)—COOR2 are also described.Type: GrantFiled: March 25, 2010Date of Patent: September 16, 2014Assignee: Lucite International UK LimitedInventor: Trevor Huw Morris
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Patent number: 8808546Abstract: A system and process for removing hydrocarbons from a gas process feed stream is presented. The treatment process may be, but is not limited to, glycol dehydration, amine sweetening, and MEG reclamation. As an example, a hydrocarbon removal bed containing a solid adsorbent material adsorbs the hydrocarbons in a rich MEG feed stream as it passes through the hydrocarbon removal bed. After the hydrocarbons have been removed, the feed stream flows through a flash separator and a distillation column to reclaim MEG. Alternatively, the hydrocarbon removal bed may be used after the MEG reclamation process to remove hydrocarbons in the distilled water from the distillation column. Spent solid adsorbent material may be regenerated in place.Type: GrantFiled: August 24, 2012Date of Patent: August 19, 2014Assignee: Cameron International CorporationInventors: Daniel W. Phelps, Luis Eduardo Caires Fernandez
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Patent number: 8802913Abstract: A process for separating a product from a multicomponent feedstream to an adsorption apparatus or system is described. The apparatus or system may comprise a moving-bed or a simulated moving-bed adsorption means. The product comprises at least one organic compound, such as an aryl compound with alkyl substitutes. In embodiments the conduits used to supply the feedstream to the apparatus or system are flushed with media of multiple grades. The improvement is a more efficient use of the desorbent. In embodiments the process achieves improvements in one or more of efficiency of adsorption separation, capacity of adsorption apparatus systems, and purity of product attainable by adsorption process.Type: GrantFiled: October 3, 2013Date of Patent: August 12, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventor: John R. Porter
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Patent number: 8741150Abstract: The present invention relates to a lithium recovery device comprising a separator reservoir and manganese oxide, a lithium recovery method using the same, and a lithium adsorption/desorption system. The separator reservoir includes a vacant space therein and an outer wall made of a polymer or a membrane of other useful materials. The manganese oxide is contained, as an adsorbent, in the vacant space inside the separator reservoir. The lithium adsorption/desorption system enables lithium recovery through adsorption and desorption of lithium dissolved in seawater using a lithium adsorbent prepared with the manganese oxide in one system, wherein the manganese oxide can be used as a lithium adsorbent with high lithium selectivity. The invention uses a separator reservoir including an outer wall made of a porous polymer or a membrane of other useful materials.Type: GrantFiled: August 13, 2009Date of Patent: June 3, 2014Assignee: Korea Institute of Geosciences and Mineral ResourcesInventors: Kang-Sup Chung, Jae-Chun Lee, Hwan Lee
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Patent number: 8679347Abstract: Disclosed is a versatile multi-use high water recovery process that integrates the use of water purification membranes including reverse osmosis and nanofiltration with ion exchange water softening resins in a number of configurations that optimize operation and achieve maximum membrane permeate recoveries while eliminating the use of fresh water, sodium chloride and other chemicals needed to regenerate the IX resin. The invention provides process mobility and flexibility that enable selection of optimum process configurations and features to address variability in the Influent Water quality.Type: GrantFiled: May 26, 2011Date of Patent: March 25, 2014Inventor: Riad A. Al-Samadi
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Publication number: 20140076817Abstract: Embodiments of the present invention provide systems and methods for purifying produced water, comprising a closed loop cation exchange unit, a closed loop anion exchange unit, and an intermediate degasifier.Type: ApplicationFiled: September 17, 2012Publication date: March 20, 2014Applicant: SEVERN TRENT WATER PURIFICATION, INC.Inventors: Richard Dennis, Christopher Clark
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Patent number: 8663476Abstract: A new process for ion exchange softening of water used in Once-Through Steam Generators (OTSGs) by recovering and using the salt content of the blowdown water from the OTSG to regenerate the softener resin is provided, thus eliminating the cost for commercial regenerant salt that would otherwise be needed. Further, the very high purity of the salt recovered in the blowdown inherently results in the production of softened water with hardness leakage levels that are an order of magnitude lower than can be attained using commercial salt, thus reducing scale deposit potential and improving operating efficiency and reliability of the OTSG.Type: GrantFiled: February 4, 2009Date of Patent: March 4, 2014Assignee: The Purolite CompanyInventor: Francis Boodoo
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Publication number: 20140054160Abstract: A system and process for removing divalent cations from a rich MEG feed stream is presented. An ion exchange bed containing a cation exchange resin adsorbs the divalent cations in the rich MEG feed stream as it flows through the ion exchange bed. After the divalent ions have been removed, the feed stream flows through a flash separator and a distillation column to reclaim MEG. Alternatively, the feed stream flows through a distillation column to regenerate MEG. The spent cation exchange resin may be regenerated in place using a regeneration brine comprised of sodium chloride and water. After use, the regeneration brine may be disposed as waste or recycled to the brine storage tank and re-used to regenerate the cation exchange resin.Type: ApplicationFiled: August 24, 2012Publication date: February 27, 2014Inventors: Daniel W. PHELPS, Luis Eduardo Caires FERNANDEZ
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Patent number: 8585906Abstract: An apparatus and method for regenerating spent ion exchange resin is described. In one method, a fresh regenerant solution comprising sodium ions and chloride ions is prepared, and passed across spent cation exchange resin to regenerate the spent resin. To recover the spent regenerant solution, a regenerant treatment composition is added to the spent solution to form precipitate flocs, which are then separated out of the regenerant solution. The concentration of at least one of the sodium or chloride ions in the regenerant solution can also be adjusted to form fresh regenerant solution which can be reused.Type: GrantFiled: September 23, 2010Date of Patent: November 19, 2013Assignee: Rayne Dealership CorporationInventors: H. Martin Jessen, Eric John Dole, David Morgan
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Patent number: 8557119Abstract: A novel method for improving water recovery from desalination systems by the removal of cations and/or anions using ion exchange (IX) technology. The system described herein is particularly useful for water recovery in brackish ecosystems and is unique in that important features include recycling, regeneration, and recovery of key components, thereby reducing costs and waste products.Type: GrantFiled: September 13, 2010Date of Patent: October 15, 2013Assignee: STC.UNMInventors: Kerry Howe, Joshua Goldman, Bruce Thomson
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Patent number: 8551340Abstract: The invention provides waste water treatment processes utilizing an ion exchange resin to remove sulphate anions, while adjusting the pH of the ion exchange loading solution with carbon dioxide gas. The effect of the resin loading reactions is that dissolved sulphate is replaced with sequestered carbon dioxide gas, in the form of dissolved bicarbonate, in the treated water and the cations are not removed from the solution.Type: GrantFiled: September 25, 2008Date of Patent: October 8, 2013Assignee: Bioteq Environmental Technologies Inc.Inventors: David Kratochuil, Michael Bratty
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Patent number: 8486269Abstract: A method for generating softened injection water (A) (i) introducing source water having a dissolved solids content of up to 15,000 mg/liter and a multivalent cation content of greater than 40 mg/liter to a bed of cation exchange resin in monovalent cation form, (ii) passing the water through the bed so that at least a portion of the multivalent cations in the water are replaced by monovalent cations from the resin, and (iii) withdrawing the softened injection water having a multivalent cation content of up to 40 mg/liter; (B) regenerating the cation exchange resin by (i) introducing a regenerating brine to the vessel, (ii) passing the brine through the bed and (iii) withdrawing a brine containing displaced multivalent cations, wherein the brine is a naturally occurring high salinity water having a concentration of cations such that the Softening Limit for the source water is up to 40 mg/liter of multivalent cations.Type: GrantFiled: March 24, 2009Date of Patent: July 16, 2013Assignee: BP Corporation North America Inc.Inventor: Patrick Lee McGuire
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Publication number: 20130175221Abstract: Electrically regenerable water softening apparatuses, and methods of operating the same, include a first electrode and a second electrode facing each other; a first electrolyte chamber, a first cation exchange membrane, an ion exchange chamber, a second cation exchange membrane, and a second electrolyte chamber which are interposed between the first electrode and the second electrode; an inflow water flow channel configured to introduce inflow water to the ion exchange chamber; a first treated water flow channel configured to discharge treated water softened in the ion exchange chamber; a second treated water flow channel connecting at least one chamber selected from the first electrolyte chamber and the second electrolyte chamber with an ion exchange chamber; and a current applier configured to apply current to the first electrode and the second electrode. The ion exchange chamber is filled with a cation exchanger.Type: ApplicationFiled: January 7, 2013Publication date: July 11, 2013Applicant: SAMSUNG ELECTRONICS CO., LTD.Inventor: SAMSUNG ELECTRONICS CO., LTD.
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Patent number: 8404120Abstract: An apparatus and method permit continuous separation of an adsorbate from a processing material containing solid particles, sticky substances and water-soluble proteins, alone or in combination, without pretreatment. The processing is carried out while a loop adsorbent is circulated. An adsorbate is adsorbed, not by supply of the processing solution through the adsorbent, but by contact thereof with the adsorbent. In addition, the adsorbent after desorption of the adsorbate is cleaned. As a result, the apparatus and the method achieve continuous processing and separation of the adsorbate even from a processing material containing solid particles, sticky substances and water-soluble proteins alone or in combination without pretreatment.Type: GrantFiled: January 26, 2008Date of Patent: March 26, 2013Assignee: Osaka Prefecture UniversityInventors: Hiroyuki Yoshida, Hidemi Nakamura
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Patent number: 8349187Abstract: A method and solution for eluting one of antimony(V) and a mixture of antimony(III) and antimony(V) from an ion exchange resin, comprises contacting the resin with an eluting solution comprising thiourea having a concentration of at least 0.002 M and hydrochloric acid having a concentration of at least 3 M. The method can be used for electrolytes in an industrial electrorefining process, by the further steps of contacting the electrolyte with an ion exchange resin to adsorb the antimony from the electrolyte and separating the resin from the electrolyte, before contacting the resin with the eluting solution comprising thiourea and hydrochloric acid. The method and solution address the difficulties of removing antimony(V), and allow for increased reuse of the resins.Type: GrantFiled: December 8, 2009Date of Patent: January 8, 2013Assignee: Her Majesty the Queen in Right of Canada as Represented by the Minister of Natural ResourcesInventor: Patricio A. Riveros
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Patent number: 8282832Abstract: A regeneration circuit for the in situ regeneration of an inline adsorbent filter, said filter being part of a normal circuit that is configured to remove one or more contaminant from a fluid circulated through a machine; the regeneration circuit includes a regeneration unit configured to remove one or more contaminant from a contaminated fluid creating a regenerated fluid, such that in operation the regenerated fluid is pumped from the regeneration unit and through the filter extracting the or each contaminant from the filter creating the contaminated fluid, this contaminated fluid then returns to the regeneration unit for contaminant removal, the pressure and flow rate of the regenerated fluid through the filter are maintained at a level that ensures minimal damage to the filter; said machine is isolated from the inline filter during regeneration.Type: GrantFiled: April 15, 2008Date of Patent: October 9, 2012Inventor: Martin Cropp
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Publication number: 20120080376Abstract: One embodiment provides a method of regenerating an ion exchange medium, the method comprising: (i) providing an ion exchange medium comprising at least one first multivalent cation; (ii) providing an effluent comprising at least one monovalent cation and optionally at least one second multivalent cation, wherein the effluent comprises a desalination brine, and wherein, if the second multivalent cation is present, the monovalent cation and the second multivalent cation in the effluent are present at a ratio of at least about 200; and (iii) contacting the ion exchange medium with the effluent to promote an interaction between the second cation and the ion exchange medium, whereby the ion exchange medium is regenerated.Type: ApplicationFiled: October 4, 2010Publication date: April 5, 2012Inventors: Andy Komor, Keisuke Ikehata
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Patent number: 7887707Abstract: In a method and apparatus for operating and regenerating ion exchange material a wash fluid or elution solution for rinsing the ion exchange material (1) is prepared, there is collected as a by-product of said preparation a first waste stream including cationic species to be eliminated, the ion exchange material (1) is subjected to a wash step in which there is eluted from the ion exchange material by the wash fluid or solution an anionic species to be eliminated and a second waste stream including the anionic species to be eliminated is obtained, the first waste stream (12) and the second waste stream (14) are combined to form a precipitate SW comprising a reaction product of said cationic species and said anionic species, and the precipitate is removed. The method provides an efficient means of eliminating undesired species from a circuit containing an ion exchange material to be regenerated.Type: GrantFiled: March 17, 2006Date of Patent: February 15, 2011Assignee: The BOC Group LimitedInventors: Peter James Mawle, Michael John Waite
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Patent number: 7875186Abstract: The invention consists of a water treatment process using selective and regenerable weak base anion exchange resins to remove any number of complex anions, especially oxyanions including perchlorate, nitrate, chlorate, arsenate, selenate, and chromate, from aqueous solutions. The treatment process is comprised of three key processes including 1) pretreatment to lower pH, 2) ion exchange, and 3) post treatment to adjust pH and alkalinity. The invention also includes processes for regenerating weak base anion resins and treatment of the residuals generated. This invention employs pressurized treatment, carbon dioxide management, and reuse of regenerating solution to minimize pumping and treatment costs.Type: GrantFiled: November 23, 2005Date of Patent: January 25, 2011Assignees: Applied Research Associates, Inc., Brotech CorporationInventors: Edward Coppola, John Baxley, Andrea Davis, Francis Boodoo, William Fries, James Dale
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Patent number: 7871523Abstract: A process for providing water with a lowered salinity and which produces at least one recoverable waste stream containing a useful by-product, the process including treating raw water which includes an undesirably high concentration of cations, including Ca2+ and Na+, in a cation exchange stage which includes first and second cation exchangers. The first cation exchanger having a selectivity towards di-valent cations and the second cation exchanger being downstream of the first cation exchanger, to retain at least a portion of the cations of the raw water in or on the first and second cation exchangers, thereby providing upgraded water of a lowered salinity containing no or a low concentration of the cations of the raw water.Type: GrantFiled: May 16, 2006Date of Patent: January 18, 2011Inventors: Ockert Tobias Van Niekerk, Edmund Kevin Hardwick
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Patent number: 7850852Abstract: According to the process for producing amino acid or salt thereof in the present invention, in the adsorption step, an amino acid-containing aqueous solution is fed into a pressure tight column so that a free amino acid is adsorbed on a carbonate-type anion exchange resin packed in the pressure tight column. Subsequently, in the elution step, eluent liquid containing a hydrogen carbonate ion and/or a carbonate ion is injected into the pressure tight column in a pressurized state to elute the amino acid adsorbed on the anion exchange resin and simultaneously to regenarate the anion exchange resin into the carbonate-type. In the case of purifying an acidic amino acid, an aqueous ammonium carbonate solution is employed as the eluent liquid. In the case of purifying a neutral amino acid, an aqueous carbonic acid solution, an aqueous hydrogen carbonate solution, an aqueous ammonium hydrogen carbonate solution or an aqueous ammonium carbonate solution is employed as the eluent liquid.Type: GrantFiled: August 24, 2007Date of Patent: December 14, 2010Assignee: Ajinomoto Co., Inc.Inventors: Yasuhiro Kusunose, Kenji Takahashi
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Patent number: 7846338Abstract: A method is described that relates to reducing amounts of regenerant waste or increasing the concentration of regenerant waste from ion exchange processes. A method is described that may allow a batch ion exchange process to compete on these factors with continuous or simulated continuous ion exchange processes, and/or to improve the efficiency in operation continuous or simulated continuous ion exchange processes. A specific application addressed is the treatment of water in the Coal Bed Methane Process.Type: GrantFiled: November 21, 2007Date of Patent: December 7, 2010Assignee: Amalgamated Research, Inc.Inventors: Michael M. Kearney, Lawrence Velasquez
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Publication number: 20100294717Abstract: An H2S04-based calcite dissolution post-treatment process and apparatii for desalinated water are provided. The process comprises separating cations from seawater by ion exchange resin (s) (12) onto which the ions are loaded, contacting the ion exchange resin (s) (12) loaded with the cations with an effluent (1) of a calcite dissolution reactor (10) wherein the cations are exchanged with Ca2+ from this effluent. The Ca2+ concentration of the resulting desalinated water (6) decreases while the cations concentration increases to comply with required quality criteria. Batch type and continuous apparatii by which the process can be carried out are described.Type: ApplicationFiled: October 21, 2007Publication date: November 25, 2010Applicant: TECHNION RESEARCH & DEVELOPMENT FOUNDATION LTD.Inventors: Ori Lahav, Liat Birnhack, Malka Kochva, Roni Penn
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Patent number: 7811457Abstract: A method of regenerating N-Methyl-D-glu-camine-functional resin that has been used for boron-removal uses a closed recirculating loop for treating the conjugate acid salt of the N-Methyl-D-glucamine functionality of the resin. The new method reduces rinse water demand and improves pH control in a water treatment system. The new method can be used to improve the performance of boron-selective resins in stand-alone systems or as a second stage in a reverse osmosis seawater desalination system. The regeneration method is useful in any application where weakly basic anion exchange resin in the conjugate acid salt form is to be regenerated (neutralized) by alkaline treatment. Possible end use applications are in drinking water processing, agricultural water treatment, sweetener production, waste water processing, mining hydrometallurgy, and condensate polishing.Type: GrantFiled: April 7, 2006Date of Patent: October 12, 2010Assignee: Dow Global Technologies Inc.Inventor: Charles R. Marston
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Patent number: 7722773Abstract: A treatment method of organic compounds included in waste water, comprising the steps of: supplying waste water to an adsorber 2 filled with an adsorbent 3 therein for adsorbing the organic compounds in the waste water by the adsorbent 3 in the adsorber 2, supplying a current between an anode 9 and a cathode 8 in water including an electrolyte in an electrolyzer 6 for electrolyzing the water including an electrolyte, and supplying an electrolyte resulting from electrolysis in the electrolyzer 6 to the adsorbent 3 in the adsorber 2 for contacting the electrolyte with the adsorbent 3, so that the organic compounds adsorbed by the adsorbent 3 are desorbed or decomposed.Type: GrantFiled: February 29, 2008Date of Patent: May 25, 2010Assignees: Hitachi, Ltd., Hitachi Kyowa Engineering Co., Ltd.,Inventors: Akio Honji, Hayahito Ishii, Akira Mochizuki, Norihide Saho, Tsutomu Tsuyama, Hisashi Isogami
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Publication number: 20090242484Abstract: This is a method that is an environmentally friendly hybrid microbiological control compromising a physical method through fine filtration, which removes nutrients, bacteria and suspended solids from open recirculating cooling systems. The method for microbiological control in cooling systems wherein a recirculating fluid containing an oxidising or a non-oxidising biocide or a mixture of an oxidising and a non-oxidising biocide and is passed through a fine filtration system resulting in reduced microbiological matter, suspended solids and nutrients.Type: ApplicationFiled: April 1, 2008Publication date: October 1, 2009Inventors: Ana-Mariana Urmenyi, Jeroen A. Koppes, Robert L. Wetergrove, Menno J.T. van Haasterecht
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Patent number: 7578416Abstract: A water purification apparatus having an inlet and an outlet, and at least one water purification device thereinbetween, wherein the outlet includes at least a first and second water release valve, the first release valve being operable at a first flow rate, and the second release valve being operable at a second flow, is described. Preferably, at least one water release valve is operable at a relatively slow flow rate of generally up to 0.1 liter per minute, and at least one other water release valve is operable at a relatively fast flow rate of, for example, up to 2 liters per minute. The present water purification apparatus provides the operator with the ability to very accurately obtain an exact volume of water desired.Type: GrantFiled: March 7, 2003Date of Patent: August 25, 2009Assignee: OTV SAInventor: Lee Underwood
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Publication number: 20090071906Abstract: In a method and apparatus for operating and regenerating ion exchange material a wash fluid or elution solution for rinsing the ion exchange material (1) is prepared, there is collected as a by-product of said preparation a first waste stream including cationic species to be eliminated, the ion exchange material (1) is subjected to a wash step in which there is eluted from the ion exchange material by the wash fluid or solution an anionic species to be eliminated and a second waste stream including the anionic species to be eliminated is obtained, the first waste stream (12) and the second waste stream (14) are combined to form a precipitate SW comprising a reaction product of said cationic species and said anionic species, and the precipitate is removed. The method provides an efficient means of eliminating undesired species from a circuit containing an ion exchange material to be regenerated.Type: ApplicationFiled: March 17, 2006Publication date: March 19, 2009Applicant: THE BOC GROUP PLCInventors: Peter James Mawle, Michael John Waite
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Publication number: 20090026141Abstract: A process for the treatment of effluent, particularly acid mine drainage, is provided which includes the steps of a. neutralising acid; b. removing cations by ion exchange using a cation resin; c. regenerating the cation resin; d. treating the eluates of the cation ion exchange step; e. adsorbing anions from the effluent of the cation removal step using an anion exchange resin; and f. regenerating the anion exchange resin.Type: ApplicationFiled: February 14, 2007Publication date: January 29, 2009Inventor: Robin Edmund Guthrie Robinson
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Publication number: 20090020478Abstract: Processes comprising: providing an anion exchanger at least partially loaded with hexachlorostannate; and contacting the at least partially loaded anion exchanger with a 1 to 10 wt. % hydrochloric acid solution to regenerate the anion exchanger.Type: ApplicationFiled: July 16, 2008Publication date: January 22, 2009Applicant: Bayer Material Science AGInventors: Torsten Erwe, Knud Werner, Dirk Weissenberg
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Patent number: 7371326Abstract: A treatment system passes feed water containing a contaminant such as perchlorate through a bed of strong base anion exchange resin that has been placed in a form (e.g., in sulfate form) to selectively capture the contaminant while passing other ions (e.g., nitrate) that may also be present in the water. The bed may include a carousel, and the exhausted upstream portion of the resin may efficiently be disposed of by incineration, or may be rotated out for regeneration.Type: GrantFiled: August 12, 2004Date of Patent: May 13, 2008Assignee: Ionics, IncorporatedInventor: Charles A. Dale
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Patent number: 7361281Abstract: The disclosed invention is a fixed bed ion exchange water purification system. It employs a combination of electronically controlled process steps and specific systems configurations to duplicate the effects of moving resin beds from one operating position to another as is required in moving bed ion exchange water purification systems. The invention combines features of single fixed bed ion exchange systems with those of a moving bed system. The invention applies to the treatment of water having typical industrial and drinking water concentrations of various ions.Type: GrantFiled: April 20, 2006Date of Patent: April 22, 2008Assignee: Basin Water, Inc.Inventors: Peter L. Jensen, Gerald A. Guter, Dan Ziol
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Patent number: 7291272Abstract: A method is provided for removing an inorganic ionic species or organometallic ion contaminant, or combination contaminants, including such as arsenic, chromium, bromide, bromate, perchlorate, and/or others from water which contains an unacceptably high concentration of the contaminant(s). The method includes treating the water with an ion exchange resin, preferably a magnetic ion exchange resin such as MIEX® Resin, which is capable of adsorbing the inorganic ionic species contaminant(s), and regenerating and recycling the ion exchange resin back to the process. The method produces potable water from ground water containing such contaminants and eliminates breakthrough and chromatographic peaking problems observed with conventional ion exchange systems.Type: GrantFiled: May 6, 2005Date of Patent: November 6, 2007Assignee: Orica Australia Pty Ltd.Inventors: Michael Francis Bourke, Hung Van Nguyen
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Patent number: 7273555Abstract: A process for continuous countercurrent ion exchange comprises piping a contaminated feed stream into a closed loop ion exchange contactor. The contactor is an ion exchange bed that has three or more reaction segments. The segments are comprised of at least an adsorption segment for treating the contaminated feed stream, a regeneration segment for stripping the contaminant ions from the resin bed, and a pulse segment for advancing the resin bed. Simultaneously, the feed stream is moved through the contactor in the same direction as the regeneration stream. Measuring the quality of this treated feed stream after it exits the contactor monitors the treatment capacity of the resin bed. In response to this quality measurement, the regenerated resin bed is advanced in the pulse segment of the contactor. The spent brine is recycled back to the contactor until the final effluent brine is highly concentrated. After the resin stops advancing, the feed stream and regeneration stream resume flow.Type: GrantFiled: May 30, 2003Date of Patent: September 25, 2007Assignee: Severn Trent Services, Inc.Inventor: Richard S. Dennis
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Patent number: 7160430Abstract: In a sewage treatment plant, dissolved ammonium is extracted from the waste-water stream, and is transferred to a body of secondary water. The secondary water is passed through an electrolysis station, where the ammonium is transformed to nitrogen gas. The capture and transfer can be done by ion-exchange, the electrolysis then being done on the regenerant water. Or the capture and transfer can be done by first transforming the dissolved ammonium to ammonia gas by raising the pH of the waste-water, then passing the ammonia gas through acidic secondary-water, in which the ammonia dissolves, the electrolysis then being done on the acid-water. The electrolysed, ammonium-diminished, secondary-water can be re-used in further capture/transfer episodes. The secondary-water does not mix with the waste-water stream.Type: GrantFiled: September 16, 2003Date of Patent: January 9, 2007Assignee: ENPAR Technologies Inc.Inventors: Gene Sidney Shelp, Leonard Paul Seed
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Patent number: 7067062Abstract: A nanoporous reactive adsorbent incorporates a relatively small number of relatively larger reactant, e.g. metal, enzyme, etc. particles (10) forming a discontinuous or continuous phase interspersed among and surrounded by a continuous phase of smaller adsorbent particles (12) and connected interstitial pores (14) therebetween. The reactive adsorbent can effectively remove inorganic or organic impurities in a liquid by causing the liquid to flow through the adsorbent. For example, silver ions may be adsorbed by the adsorbent particles (12) and reduced to metallic silver by reducing metal, such as irons, as the reactant particles (10). The column can be regenerated by backwashing with the liquid effluent containing, for example, acetic acid.Type: GrantFiled: November 22, 2004Date of Patent: June 27, 2006Assignee: Industrial Science & Technology Network Inc.Inventors: Arthur Jing-Min Yang, Yuehua Zhang
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Patent number: 7041223Abstract: The disclosed invention is a fixed bed ion exchange water purification system. It employs a combination of electronically controlled process steps and specific systems configurations to duplicate the effects of moving resin beds from one operation position to another as is required in moving bed ion exchange water purification systems. The invention combines features of single fixed bed ion exchange systems with those of a moving bed system. The invention applies to the treatment of water having typical industrial and drinking water concentrations of various ions.Type: GrantFiled: March 21, 2005Date of Patent: May 9, 2006Assignee: Basin Water, Inc.Inventors: Peter L. Jensen, Gerald A. Guter, Dan Ziol