Abstract: The present invention relates to storage-stable solutions of basic aluminium sulphate containing polynucleate aluminium hydroxide sulphate complexes of the formula[Al(OH).sub.x (SO.sub.4).sub.y (H.sub.2 O).sub.z ].sub.nin which x is 0.75-2.0; y is 0.5-1.12; 2x+y=3; and z is >>4, which solutions contain a stabilizing agent in the form of nitrilotriacetic acid, diethylene triaminopentaacetic acid and/or gallic acid.

Abstract: A method for treating water or waste water to remove pollutants therefrom includes treating fly ash comprising aluminum, iron and silica with an aqueous base, recovering a base-treated, solid fly ash, washing the base-treated solid fly ash with water, recovering a rinsed, base-treated fly ash solid, reacting the rinsed, base-treated fly ash solid with mineral acid, and recovering an aqueous, solubilized acidic fly ash leachate, then mixing the aqueous, acidic solubilized fly ash leachate with water or waste water to remove pollutants therefrom, or with sludge to reduce its resistant to dewatering.

Abstract: Process for clarifying water to coagulate and flocculate particles suspended therein, by introducing into the water an aqueous solution of ferric polychloride having a temperature of at least 85.degree. C.

Abstract: Heavy metal pollutant ions and emulsified fat are removed from a wastewater stream in a two-stage process. The first stage involves the demulsification and removal of fat through the use of chemical emulsion breakers leaving residual fat in suspension and in solution. The second stage involves the preparation and introduction of a calcium sulfide mixture to the wastewater resulting in the precipitation of the heavy metal ions as sulfides and the precipitation of residual fat.

Abstract: This invention relates to a method and apparatus for producing high pH water containing dissolved lime by forcing potable water through a column of powdered lime supported on a porous support without transporting significant quantities of lime out of the column. Two or more columns may be connected in parallel to permit recharging of one while the other remains on stream.

Abstract: A method for the removal of heavy metal ions from an aqueous solution which comprises the steps of admixing an aqueous slurry of FeS.sub.2 with a heavy metal ion bearing aqueous solution at a pH above 7, preferably 8-12, the slurry providing at least the stoichiometric amount of FeS.sub.2, preferably 2 to 6 times the stoichiometric amount of FeS.sub.2, for precipitating the heavy metal ions from the solution as sulfides and separating the precipitated sulfides from the aqueous solution. Desirably, a portion of the heavy metal ions are precipitated from the solution as heavy metal hydroxides and the precipitated hydroxides are separated from the solution prior to admixing the solution with the FeS.sub.2 slurry.

Abstract: Process for the irreversible treatment of toxic waste by means of a silicate, in the presence of water, in such a way as to form a solid aggregate includes treatment of the silicate in an acid medium, for the purpose of obtaining silicic acid of low molecular weight; mixing the silicic acid with the waste to be treated, in the presence of water and controlling the pH between 0 and 4 in a sufficiently acid medium to cause the waste to undergo at least partial solution; precipitation of a gel of high molecular weight from the resultant aqueous mixture; addition thereto of a mixture which reacts with the gel of high molecular weight to form a silicate, possibly in the presence of a cementation agent, in such a way as to produce a sludge, and the hardening of the sludge into a solid aggregate which can not be changed physically so as to release again the harmful or toxic waste into the environment.

Abstract: A method is disclosed of producing a liquid agent for improving the quality of contaminated water, particularly water in pools, natural bodies of water and waste waters, characterized by introducing with agitation comminuted rock-salt clay or a mixture thereof with rock-salt deads into an aqueous solution or suspension of an inorganic base, stirring the resultant mixture for 2 to 5 (preferably 3) hours, thereupon adjusting the pH of the resultant solution to a value of between 7.5 and 10.5 (and preferably between 9.5 and 10.5) by means of the addition of acid or alkali, and removing undissolved portions from the solution.

Abstract: A pumpable water-purifying dispersion containing iron(II)sulphate, the iron(II)sulphate being dispersed in an aqueous phase with a dispersing agent containing an alkaline earth metal and a basic anion. The best dispersion properties are obtained when the dispersing agent is calcium carbonate or calcium hydroxide, whereby the resultant composition having a content of up to about 70% solid iron(II) sulphate, calculated as heptahydrate on the total weight of the composition, can be obtained and handled without difficulty. The aqueous phase can, to advantage, comprise metal ions active in water-purification, such as Fe.sup.2+, Fe.sup.3+ and Al.sup.3+.The invention also provides a method for producing the composition.

Abstract: A method of treating scrubber sludge removed from a gas scrubbing apparatus of the type adapted to reduce SO.sub.x content in the treated gas, is provided. The method comprises collecting the spent residue from a fluidized combustion bed of the type wherein lime or calcium carbonate particles are suspended in a fluidized medium and wherein a carbonaceous fuel is ignited proximate said fluidized medium to absorb therein substantial amounts of SO.sub.x which is generated upon ignition of said carbonaceous fuel. The fluidized bed combustion residue is then subjected to a separating treatment wherein a slurry of residue is mechanically agitated. The supernatant liquor from the slurry is separated therefrom, leaving a precipitate material which latter material is mixed with sludge. The novel composition comprises a combination of scrubber sludge and fluidized bed combustion residue precipitate, as above mentioned.

Abstract: An aqueous slurry of a water-insoluble or slightly water-soluble metal hydroxide can be effectively filtrated and dehydrated by adding an anionic surfactant of the following formula (I):R--O--AO--.sub.n X (I)wherein R represents an alkyl or alkenyl group of 8-24 carbon atoms, A represents an alkyene group of 2-4 carbon atoms, X represents SO.sub.3 M (M being H, K, Na or NH.sub.4), PO.sub.3 M (M being K or Na) or CH.sub.2 COOM (M being K or Na), and n represents an interger of 1-100,to the aqueous slurry of the metal hydroxide or to the washing water.

Abstract: Aqueous basic polyaluminum-iron halide solutions, useful as coagulants in waste water treatment are disclosed. The polyaluminum-iron halide solution is prepared by reacting an aqueous polyaluminum halide solution with one or more members of the group consisting of ferrous halide and ferric halide resulting in a solution containing a concentration of metal ions ranging from about 1.35 to 4.5 mol/liter as a dissolved salt of the formulaAl.sub.1-x Fe.sub.x.sup.III Fe.sub.y.sup.II (OH).sub.3+2y-z Hal.sub.zwherein Hal is chlorine, bromine, iodine or mixtures thereof; (x+y)/(1-x) is about 0.2 to 1.5; 3+2y-z/3+2y is about 0.24 to 0.67; and z is less than 3+2y. Alternatively, the coagulant solution is prepared by reacting an aqueous aluminum halide solution or low basic polyaluminum halide solution with iron. Preferably the halide employed is chloride.

Abstract: Heavy metal pollutant ions are precipitated from a wastewater stream as metal sulfides through the addition of a calcium sulfide mixture to the stream. Methods are disclosed for forming the calcium sulfide mixture and for controlling the amount thereof added to the wastewater stream.

Abstract: A method and an agent for chemical purification of water is provided, especially waste water with subsequent magnetic sludge separation. A precipitation agent comprising as component aluminium sulphate and/or iron sulphate is used together with a magnetic material for the purification. In order to provide uniform distribution of the magnetic material in the agent composition it is added to the aluminum and/or iron sulphate component of the composition when said component is in the form of a melt or solution prior to crystallization of said composition.

Abstract: A physically and functionally stable solution for water treatment comprises an about 1.2-2.7 molar aqueous phosphate-stabilized polyaluminum sulfate solution of a composition having the formulaAl(OH).sub.x (SO.sub.4).sub.y (H.sub.2 PO.sub.4).sub.zwhereinx is about 1.2 to 1.62;y is about 0.595 to 0.87; andz is about 0.06 to 0.19with the proviso that the sum of x+2y+z is 3. The aqueous phosphate-stabilized polyaluminum sulfate solution can be prepared by reacting alumina hydrate with phosphoric acid and contacting the reacted alumina hydrate with an aqueous polyaluminum sulfate solution. Alternatively, the aqueous phosphate-stabilized polyaluminum sulfate solution can be prepared by reacting an aqueous overbasified polyaluminum sulfate phosphate solution with an aqueous aluminum sulfate solution.

Abstract: The present invention relates to novel treating agents for treating waste water containing dyes and/or other organic substances, a process for treating said waste water by using said treating agent, and an equipment for the same.The treating agent is prepared by mixing component A comprising a water-insoluble calcium salts and component B consisting mainly of aluminum hydroxide, aluminum oxide or a mixture thereof at a molar ratio of 3:1 to 1:3 and heating said mixture of components A and B as such or after granulation at a temperature between 100.degree. C. and 450.degree. C.The treating agent thus obtained has excellent adsorption and oxidative ability and is capable of easily clarifying waste water discharged from fiber processing plants that contains a variety of dyes and other organic substances, for example, sizing agents such as starch, polyvinyl alcohol and C.M.C.

Abstract: A precipitating agent for the dephosphatization of effluent comprising by weight about 5 to 75% of active iron (III) sulphate, about 25 to 95% of active iron (III) oxide and 0 to about 10% of anhydrous magnesium sulphate. Optionally, an alkaline constituent such as the oxide or hydroxide of calcium or magnesium may also be present and dephosphatization is effected at a pH of about 4.5 to about 8.5. Extremely low contents of residual phosphorous can be obtained in the filtrate, a precipitate containing iron and phosphorous settling out cleanly.

Abstract: In a process for the treatment of water with ozone a partial current of treated water is contacted under pressure in a packed column with an oxygen-ozone mixture from an ozonizer to oxidize water contaminants and to improve their flocculation. The portion of oxygen which has not dissolved in the water in the packed column is recycled into the ozonizer and the treated partial water current is mixed again with water to be treated. The pressure in the column is adjusted in dependence on the nitrogen content of the water to be treated. By this measure is ensured that the quantity of nitrogen escaping from the water and contained in the cycle oxygen permits an optimum operation of the ozonizer. The nitrogen content in the cycle oxygen is preferably kept below 10% by volume.

Abstract: A method is disclosed for removal of free and complex cyanides from water-containing industrial effluents and wastes by treatment with insoluble solid iron sulfides at a pH in the range of about 7.0 to 8.5. The insoluble solid iron sulfides can be chemically prepared prior to treatment or prepared in situ, usually of a particle size smaller than about 5.mu., or supplied in the form of naturally occurring iron sulfides such as pyrrhotite or pyrite having a particle size smaller than about 300.mu., preferably smaller than about 150.mu.. The weight ratio of iron sulfide to total cyanide in the effluent is greater than 2:1, preferably greater than about 5:1 for prepared iron sulfides and greater than about 100:1 for mineral sulfides. The presence of a reducing agent such as ferrous ions or sodium sulfite to maintain a non-oxidizing environment during treatment enhances removal of cyanide.

Abstract: Diagnostic agents are described for determining high density lipoprotein cholesterol in body fluids such as serum or plasma. One is an enzymatic reagent for quantitative analysis for cholesterol composed of cholesterol oxidase, cholesterol esterase, peroxidase, 4-amino-antipyrine, a phenol or phenol derivative, a surfactant, such as sodium cholate and a polyglycol of molecular weight from about 190 to 1000, buffered to pH 5.5 to 7.8 in water. The other is a single, stable precipitating agent for lipoproteins in body fluids, comprising a bivalent metal salt of a monobasic acid, such as magnesium chloride and a water-soluble polyanion, such as sodium phosphotungstate in water at pH 5 to 8.