Abstract: A method of removing silver from a solution containing silver halide and silver ion is described, which comprises a step of adding an a sulfur atom-containing hydrophilic polymer chelating agent to the solution.

Abstract: A change-over apparatus for use in conjunction with a cooling system of an internal combustion engine having an engine and radiator and having an upper hose between the radiator and the engine which has been cut to form an upper radiator hose section and an upper engine hose section wherein a change-over apparatus comprising at least one tubular body having first and second tube bodies having end openings, with the end opening for connection to said upper radiator hose section, said second end opening for connection to said upper engine hose section, a liquid ingress opening spaced from said first end opening, a liquid egress opening spaced from said second end opening, and, optionally, a flow regulating means placed between said liquid ingress opening and said liquid egress opening.

Abstract: A method which uses a combination of polymeric cationic and an anionic flocculants to clarify an aqueous solution containing cells of a microorganism and parts thereof is described. The anionic flocculant is based upon a copolymer of an alpha-beta unsaturated monomer of an anhydride, a carboxylic acid or salt and an alpha-beta Unsaturated sulfonic acid or salt monomer. The polymeric cationic surfactant is preferably a quaternary ammonium or tertiary amine containing polymer produced from an alpha-beta unsaturated amino monomer. The method is particularly useful for clarifying solutions wherein a bacterium is used to produce an expressed material such as a protein, peptide, or amino acid dissolved in the solution which is to be separated from the cells or cell parts.

Abstract: Finely divided solids suspensions can be dewatered by adding to the solids suspension a mixed hydroxy ether of the formula ##STR1## wherein R.sup.1 is a linear hydroxy alkyl group containing from 2 to 16 carbon atoms with the hydroxyl group on the carbon atom adjacent to the carbon atom with the ether linkage and R.sup.2 is a linear alkyl group with 1 to 15 carbon atoms with the proviso that the sum of the total carbon atoms in R.sup.1 and R.sup.2 is 5 to 17, R.sup.3 is a linear or branched alkyl group with 1 to 12 carbon atoms and n is a number of from 1 to 20. The mixed hydroxy ethers are readily biodegradable, generate very little foam and have a low solidification point.

Abstract: A process for removing proteinaceous materials, fats and oils from food processing wastewater using a coagulant such as lignin or a halogen ion containing compound together with a flocculant such as a natural polymer such as a polysaccharide or synthetic polymer is described. The combination of lignin or halogen and polymer is effective for coagulating and flocculating proteinaceous materials, fats and oils in food processing wastewater at low pH.

Abstract: The invention comprises a process for improved flocculation of Bayer process red mud-containing slurry. The improvement comprises adding to the red mud-containing liquor a phosphonic acid polymer optionally in addition to the conventional flocculant. The polymer is added to the red mud-containing liquor in an amount sufficient to reduce the concentration of suspended solids in the supernatant phase and/or increase the rate of sedimentation.

Abstract: The invention provides an improved method for dewatering coal tailing aqueous slurries in a twin belt press process. The method including the step of adding to the slurry a high molecular weight anionic flocculant followed by a coagulant containing vinylamine. The flocculated coal is then mechanically dewatered using a twin belt press.

Abstract: A process for removing printing inks from printed wastepaper in the presence of a deinking chemical is provided. In this process printed wastepaper is disintegrated to form a paper stock suspension and the detached printing ink particles are removed in known manner by flotation or washing in another stage. In this process, alkoxylates of blown oils are used as the deinking chemical. The deinking chemical is added during disintegration and/or before the flotation or washing step. Preferably, the printed wastepaper is disintegrated in the presence of 0.02 to 2% by weight and preferably 0.1 to 0.8% by weight, based on air-dry paper stock, of alkoxylates of blown oils. This deinking chemical also removed printing inks from paper circuit waters.

Abstract: A method, composition and filter for reducing the presence of sludge or varnish precursors in a lubricating oil circulating within an internal combustion engine. The lubricating oil containing sludge or varnish precursors is contacted with discrete particles of an oil insoluble, oil wettable compound having an antioxidant functional group and/or a dispersant functional group, which are capable of complexing with sludge or varnish precursors. Preferably the compounds comprises a crosslinked amine having ethylene amine functionality. The starting polyethylene amines have a number average molecular weight in the range of about 100 to about 60,000, preferably 200 to 250 and are crosslinked with a silicon oxide, silane, silicate, epoxide, quinone, or phenol-formaldehyde crosslinking agent. The particles are encaged within a one or two stage oil filter together with filtering media such as chemically active filter media, physically active filter media and inactive filter media.

Abstract: A method of cleaning an oil or gas well includes mixing a caustic with a saline solution to precipitate hydroxide species from the saline solution and form a milky suspension. The suspension is contacted with contaminants in a well bore to entrap the contaminants. A polymeric flocculant is then mixed with the suspension in the well bore to aggregate the hydroxide species and the entrapped contaminants into flocs. The flocs are extremely strong and can withstand the highly turbulent flow existing in the well bore and can be readily flushed out of the well bore.

Abstract: A process is disclosed for the purification of waste water containing a silver compound, comprising the steps of (1) adding to said waste water a salt of a poly(guanidine) or poly(biguanidine) polymer (2) adding a flocculant, and (3) filtrating the formed flocculate.The invention is particularly suitable for the removal of silver from the effluent of a photographic processor, and more specifically the effluent of a processor of wash-off materials, said effluent also containing gelatin.A most preferred poly(guanidine) compound is poly(hexamethyleneguanidine) hydrochloride.

Abstract: Water-in-oil emulsions are broken by the use of adducts prepared by reacting high molecular weight polyalkylene glycol with ethylene oxide, or diglycidyl ether, or both ethylene oxide and diglycidyl ether. The adduct demulsifiers may be used alone or as a blend with other demulsifiers.

Abstract: A composition and method for separating red blood cells from whole blood including a rouleaux-forming aggregator and an enhancer for enhancing the settling rate. The enhancer is a material which alters directly or indirectly the properties of the red blood cell and may alter the structure and/or reactivity of the aggregator, without adversely affecting the morphology and function of white blood cells. In most instances, the red blood cell enhancers of the invention are osmotic agents. Such agents create a hypertonic solution while not entering the cells themselves. Preferably the enhancer is a salt of oxalic acid, a salt of malonic acid, mannitol or sucrose. Potassium oxalate is most preferred. High molecular weight substances which are large enough to form molecular bridges between red blood cells form the aggregators used in the invention.

Abstract: A secondary polishing process for Bayer Process liquors suspension is described. The polishing process uses a combination of bio-polymers, particularly such bio-carbohydrates as dextran, with an inert insoluble solid, such as a filter aid, to treat the primary red mud settler overflow, then clarifying these treated overflow liquors in a secondary clarifier. Results provide for from 0-20 milligrams per liter suspended solids, often from 0-5 ppm suspended solids, and may make sand filter or Kelly filter operation an option in the Bayer Process.

Abstract: Addition of alkyl and/or alkenyl polyalkylene glycol ethers as filtration aids in the filtration and/or dehydration of mineral or coal suspensions reduces the dehydration time, and filter cakes with a low residual moisture content are obtained.

Abstract: A urea-formaldehyde resin useful as a binder for making a variety of products, and of a method for making the resin. The resin is prepared by reacting formaldehyde, urea, triethanolamine, and optionally ammonia in a two-step process, first under alkaline conditions and then under acidic conditions. The urea-formaldehyde resin thus produced has good resistance to hydrolysis, cures quickly without smoking, and is characterized by low formaldehyde release.

Abstract: Wood-resin-containing process water or wastewater from the pulp industry is purified by adding, as flocculants, a high-molecular-weight polyethylene oxide and a water-soluble, non-ionic cellulose ether, suitably having a flocculation temperature of 35.degree.-80.degree. C. The added amount per liter of water is preferably 2-20 mg of the high-molecular-weight polyethylene oxide and preferably 5-30 mg of the non-ionic cellulose ether.

Abstract: A flocculating agent which comprises: a particulate polyethylene oxide; an inert liquid vehicle comprising a mixture of a glycol and glycerine, wherein the specific gravity of the polyethylene oxide is approximately the same as the specific gravity of the inert liquid vehicle; a suspension agent, and, optionally, an acidic compound.

Abstract: A process capable of operation under hostile conditions for accelerating the sedimentation of suspended solids in an aqueous suspension using a flocculating agent comprising a water-soluble polymer composition produced from a monomer composition comprising at least one of a hydrophilic N-vinyl lactam or a hydrophilic vinyl-containing sulfonate.

Abstract: The method of treating used liquid coolant employed in the coolant passages of an engine or radiator, and employing a coolant pumping structure, that includes providing a source of supply coolant liquid, and a used coolant reservoir; operating the pumping structure to displace supply coolant liquid from the source into the coolant passages, thereby displacing used coolant from the passages for flow into the reservoir structure; and chemically treating the used coolant liquid to remove metallic and other contaminants therefrom, thereby to produce treated coolant liquid usable as the supply coolant liquid.

Abstract: A mobile multi reservoir unit aspirates liquid with solids from septic tanks, treats immediately the liquor by a flocculent polymer and dehydrates the product by a low speed vertical centrifugal machine; the liquid is returned to the septic tank and the solid is maintained in a mud stade, easy to rake off by a rotating folding knife, followed by transfer to a storage reservoir; a pump unit enacts the material transfer from and to each reservoir in succession by aspiration and by pressure build up.

Abstract: Use of polymeric two-phase systems for removing microbial contaminants from industrial lubricating agents, a method of purifying microbial contaminated lubricating agents by mixing the lubricating agent with a polymeric two-phase system, allowing the mixture to separate so as to form a top-phase containing the lubricating agent and a bottom-phase containing at least part of the microbial contaminants, and separating at least a major part of the microbially enriched bottom-phase from the top-phase, a plant for microbial purification of lubricating agents comprising a mixing tank (4) having means (7, 8) for feeding microbially contaminated lubricating agent (S) to the mixing tank, means (13) for feeding a polymeric two-phase system to the mixing tank, a stirrer (5) in the mixing tank, means (9, 10) for feeding the mixture to a separation device (6) for separating the mixture into a top-phase (T) containing lubricating agents, and a bottom-phase (B) containing microbial contaminants, and means (18) for recoverin

Abstract: Materials such as amines, alcohols, aminoalcohols, ethers and mixtures thereof, including halogenated adducts thereof, have been found to be useful floc modifiers for water clarifiers to form an effective overall water clarifier composition. The water clarifier portion of the composition is a dithiocarbamate. The floc modifier of a particular water clarifier composition need not be the same compound that is reacted with carbon disulfide (CS.sub.2) to make the water clarifier portion of the novel compositions.

Abstract: The invention provides a method for removing a solid material, e.g., sludge, from the bottom of a body of water. The method includes the steps of: a) placing a turbidity curtain of water impermeable material about a first minor portion of a body of water, the curtain extending from the surface to the bottom of the body and defining a first cell, b) pumping sludge from the first cell, c) placing a turbidity curtain around a second minor portion of the body of water, the curtain extending from the surface to the bottom of the body and defining a second cell, d) pumping sludge from the second cell after pumping from the first cell has ceased, e) after the resuspended solids in the water in the first cell have been allowed to settle for a predetermined time after pumping, moving the first cell to a different location in the body of water, and f) repeating steps d) and e) with the first cell, after being moved, becoming the second cell and the second cell becoming the first cell.

Abstract: A composition for the detackification and clarification of acid and alkaline paint and lacquer waste waters and paint spray booth wastes, comprising:an inorganic-organic and/or organic adduct alloy polymer composition having the formula:A.multidot.B.sup.+ .multidot.D.sup.+wherein:A=[(SiO.sub.2 /Me.sup.I.sub.2 O).sub.u Me.sup.II.sub.m Me.sub.m.sup.III(OH) p.sup.(SO 4.sup.) y.sup.(Aci) (2m+3n)-p-2y].sub.4wherer=1 to 98% bw;u=0 to 10% bw; ##STR1## where: x=0 to 98% bw; Z is a divalent substituted or unsubstituted aliphatic, cycloaliphatic, heterocyclic or aromatic radicalD.sup.+ (PQAM).sub.wwherew=2 to 98% b.w. of polyquaternized polymer (PQAM)Me.sub.m.sup.II is selected from the divalent cationic group comprising: Mg, Zn, Ca, and Fe.sup.2+m=0 to 5Me.sub.n.sup.III is a tri-or more valent metal selected from the group comprising: Fe, Al, and Al-Zn complexes;n=1 to 20Aci is selected from the monovalent anionic group comprising Cl.sup.-, Br.sup.-, I.sup.-, NO.sub.3 --, H.sub.2 PO.sub.4 --, CH.sub.3 COO.sup.-, OH.

Abstract: A process for improving the flocculation of suspended solids in a Bayer process liquor in a primary settler stage. The method includes the step of adding to a primary settler feed from about 1 to about 100 parts per million of a composition including a non-inverted, water-continuous polymer, said polymer being hydrolyzable in a Bayer process liquor to an acid form, said acid form being an active red mud flocculant.

Abstract: A method for treating waste water such as that from an industrial processing facility comprising the separation of the waste water into a dilute waste stream and a concentrated waste stream. The concentrated waste stream is treated chemically to enhance precipitation and then allowed to separate into a sludge and a supernate. The supernate is skimmed or filtered from the sludge and blended with the dilute waste stream to form a second dilute waste stream. The sludge remaining is mixed with cementitious material, rinsed to dissolve soluble components, then pressed to remove excess water and dissolved solids before being allowed to cure. The dilute waste stream is also chemically treated to decompose carbonate complexes and metal ions and then mixed with cationic polymer to cause the precipitated solids to flocculate. Filtration of the flocculant removes sufficient solids to allow the waste water to be discharged to the surface of a stream.

Abstract: The invention concerns a device and its use for separating plasma from whole blood by means of a fibre-containing layer which contains an erythrocyte-aggregating substance and is characterized in that the fibre-containing layer contains glass fibres which are coated with polyvinyl alcohol or with polyvinyl alcohol/polyvinyl acetate. The invention also concerns a test carrier for the determination of a blood component as well as a process for separation from whole blood in which the device according to the present invention is used.

Abstract: Sodium Aluminate when used to adjust pH of paint detackifying systems improves the efficiency of polymeric paint detackifiers used in the detackification of paint from paint spray booths and similar equipment.

Abstract: Method of breaking the desalter emulsion in a crude oil desalting system in which oil based demulsifiers are added to the wash water stream and mixed prior to contacting the crude oil. The method is effective for crude oils which form reverse (oil-in-water) emulsions when mixed with the wash water at the process temperature.

Abstract: A flocculating agent which comprises: a particulate ethylene oxide polymer present in an amount of between about 20 to about 35% by weight; an inert liquid vehicle comprising a mixture of a glycol which is present in an amount between about 25 to about 30% by weight, and glycerine which is present in an amount between about 45 to about 50% by weight, wherein the specific gravity of the ethylene oxide polymer is approximately the same as the specific gravity of the inert liquid vehicle; and a suspension agent which is present in an amount between about 0.4 to about 0.6% by weight, wherein the flocculating agent has a viscosity in the range between about 1800 to about 5900 cps.

Abstract: The use of mixed hydroxyethers of the general formula IR.sup.1 O--(CH.sub.2 CH.sub.2 O).sub.x --CH.sub.2 --CH(OH)R.sup.2 (I)in whichR.sup.1 denotes an alkyl group having 1 to 10 carbon atomsR.sup.2 denotes an alkyl group having 8 to 20 carbon atoms and x denotes a number in the range from 1 to 20 as auxiliaries for the dehydration of water-containing finely divided solids, gives solids having a low water content without foaming in the water separated therefrom.

Abstract: A method of treating BCTMP/CTMP wastewater to improve retention and purification of cellulose fiber suspension and clarification of the BCTMP/CTMP wastewater which comprises the addition of a cationic, water soluble coagulant having a molecular weight less than 15,000,000 in an amount of about 1 to about 300 ppm; and a high molecular weight flocculant selected from the group consisting of: nonionic polymers having a molecular weight in the range between about 500,000 to about 30,000,000, low charge cationic polymers having a molecular weight in the range between about 5,000,000 to about 30,000,000, and low charge anionic polymers having a molecular weight in the range between about 5,000,000 to about 30,000,000, in an amount of about 0.1 to about 100 ppm.

Abstract: A flocculating agent which comprises: a particulate ethylene oxide polymer present in an amount of between about 20 to about 35% by weight; an inert liquid vehicle comprising a mixture of a glycol which is present in an amount between about 25 to about 30% by weight, and glycerine which is present in an amount between about 45 to about 50% by weight, wherein the specific gravity of the ethylene oxide polymer is approximately the same as the specific gravity of the inert liquid vehicle; and a suspension agent which is present in an amount between about 0.4 to about 0.6% by weight, wherein the flocculating agent has a viscosity in the range between about 1800 to about 5900 cps.

Abstract: Tall oily fatty acids when combined with certain non-ionic surfactants having an HLB number from 10-14 are superior dewatering agents for Bayer Process alumina trihydrate filter cakes.

Abstract: A process for removing cyanide anions from waste waters using halogen-free ferric salts is disclosed. The process is particularly effective when treatment of cyanide waste waters is done by adding ferric sulfate while adjusting pH of the waste waters with a halogen-free acid, such as sulfuric acid, to a pH ranging from about 3.0 to 5.0.The ferric ferricyanides formed are agglomerated and flocculated using synthetic polymers along with whatever other dispersed or suspended solids may be present in the waste waters, and this dense sludge is separated in a clarifier. Cyanide removal is at least 80%, relative to initial cyanide concentrations, and preferably 90% removal or higher.Cyanide wastes from coke oven off gas scrubbing waters are particularly waste waters amenable to this treatment.

Abstract: The invention pertains to the composition of a novel polymeric initiator and method for initiating the polymerization of vinyl monomers into water soluble polymers or block copolymers. The polymeric initiator has the formula: ##STR1## wherein M is H or a cation, R.sub.1 is a linear or branched lower alkylene group having from about 1 to 8 carbon atoms, R.sub.2 is H or a lower alkyl group having from about 1 to 5 carbon atoms and n is from 1 to 10. The resulting water soluble block copolymers are very useful in sludge dewatering applications.

Abstract: A chelation process and apparatus for treating an acid solution, namely nitric acid photoengraving etchant, having a high concentration of magnesium and having a heavy metal contaminant produced by zinc leached during etching. The process requires adjusting pH of a batch quantity of the etch solution to a value permitting chelating to occur and mixing carbamic sodium salt hydrate chelating agent with the solution in quantity sufficient to cause precipitation from the solution of a carbamic salt compound precipitate of the contaminant, and separating the precipitate from the remaining solution by filter press for removal from the solution for safe environmental disposal. The remaining liquor is safely sewered. The apparatus is mobile for use on photoengraving premises.

Abstract: A process for improving a solid/liquid separation of tails from acidulated or non-acidulated liquors obtained by leaching phosphate ores or waste comprising: adding a mixture of dissolved polymers of hydroxyalkyl cellulose and polyoxyethylene into an aqueous slurry of leached phosphate wastes to obtain flocks of phosphatic clay wastes; allowing said flocks to settle into an agglomerated mass; decanting luqiid from insoluble residues to obtain tails having a solid content from about 55 to 70%.

Abstract: Process for the purifiying water using an effective proportion of a flocculating agent consisting of a reverse microlatex comprising a polymer of at least one water-soluble cationic vinyl monomer, which may be copolymerized with at least one water-soluble anionic or non-ionic vinyl monomer, possessing a molecular weight at least equal to 2.times.10.sup.6.The said microlatex is in the form of particles of a microlatex having a diameter of between 30 and 160 nm and its polydispersity index is between 1.05 and 1.2.

Abstract: A dry flocculant powder comprises an inorganic substrate consisting essentially of metal oxide/hydroxide particles having an average particle size of less than about 30 microns, said substrate having a cationic or anionic polyelectrolyte coated onto its outer surface, preferably under other than high shear conditions. A method for coating or adhering polyelectrolytes to the outermost surface of inorganic particles comprises dispersing a polyelectrolyte in a substantially non-aqueous solvent, preferably having a low boiling point and a low to intermediate polarity relative to the polyelectrolyte; adding the inorganic particles to the solvent to form a slurry; mixing the slurry under low to moderate shear conditions; and removing excess solvent from the slurry. There is also disclosed a method for removing clay, clay-like materials, humic acids, yeast, biological cells and/or other cell debris from an aqueous stream through contact with the aforementioned dry flocculant powder.

Abstract: An improved method for detackifying over-sprayed paint, lacquer or enamel entrained in the circulating water of paint spray booths comprises maintaining in the wash water a small amount of an N-methylolacrylamide copolymer with methyldiallylamine.

Abstract: A process for detackifying paint in a wet paint spray booth wherein water is used to wash the air containing oversprayed paint from the paint spray operation. The process comprises forming stable colloid solutions consisting of weakly electropositive metals. Additionally, to activate the metal cation, various anionic or cathionic polymers may be selected and used.

Abstract: A method for treating muddy water which comprises adding a first chemical containing an alkali metal or alkaline earth metal oxide or hydroxide to muddy water to be treated, thereby rendering muddy water alkaline, adding a second chemical containing an anionic polymer coagulant to muddy water simultaneously with or after the addition of the chemical, further adding a third chemical containing a sulfate thereby rendering the muddy water weakly alkaline, and then adding a fourth chemical containing an anionic polymer coagulant to muddy water. As a result, large-sized and hard flocs are produced.

Abstract: A composition for the purification of water includes a suitable coagulant for coagulating solid impurities dispersed in the water to form flocs and an organic hydrophilic colloid capable, when dispersed in the water, of absorbing large quantities of water to form a sol for aggregating the flocs. The proportion of organic hydrophilic colloid in the composition is such that when the composition is used to purify the intended quantity of water, the organic hydrophilic colloid does not interfere with coagulant dispersal in the water or with floc formation.

Abstract: A method for rapid and efficient cleaning of an internal combustion engine cooling system includes forcing the coolant liquid from the cooling system to the exterior of that system, driving the coolant liquid from the cooling system to the exterior of that system, treating the coolant liquid in a zone or zones outside the cooling system, such treating including effecting preciptation of anions and cations, in the coolant liquid to product contaminant particulate and removing contaminant particulate from the coolant liquid, and returning the treated coolant liquid to the cooling system.

Abstract: Co-polymers of diallyldimethyl ammonium chloride with up to 30 mole percent of a water soluble anionic monomer such as acrylic acid are superior coagulants for deinking process waters.

Abstract: Water-dispersible polymeric latexes are excellent paint detackifying agents for treating the circulating water in paint spray booths when latexes have an average particle size less than 10 microns.

Abstract: The present invention provides a method of coagulating sludge, which comprises adding sequentially an anionic polymer coagulant and a cationic polymer coagulant to sludge, and furthermore, adding an anionic polymer coagulant.According to the present invention, it is possible to coagulate sludge at a far higher efficiency with a far smaller dewatering load than in the typical conventional methods using an inorganic salt and a pH adjusting reagent.

Abstract: The present invention provides an improved biological sludge dewatering process. The process comprises the steps of: (a) heating biological sludge to a temperature of about 90.degree. to about 150.degree. C. which corresponds to a pressure of about 0 to about 55 psig and retaining the biological sludge at that temperature for less than about 15 minutes; (b) centrifuging the heated biological sludge to isolate the solids of the heated biological sludge from the liquid of the heated biological sludge; (c) chemically conditioning the isolated solids; and (d) dewatering the conditioned solids to produce a high solids biological sludge. The present process is used for dewatering any biological sludge to produce a high solids cake. The resulting high solids cake may be used as landfill, incinerated, or used as fertilizer by spreading on land and plowing said fertilizer into the soil.