Organic Patents (Class 210/755)
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Patent number: 11939681Abstract: A a plant composite corrosion inhibitor for an oil field and a preparation method thereof belong to the technical field of preparation of oil field chemical agents. The plant composite corrosion inhibitor comprises a first plant ingredient, a second plant ingredient, a corrosion inhibition synergist and an organic solvent. The first plant ingredient is zeaxanthin and a derivative thereof obtained by supercritical CO2 extraction of marigold; the second plant ingredient is prepared from luffa leaves, guava leaves and eclipta according to a mass ratio of 5:8:9; the corrosion inhibition synergist is prepared by mixing potassium iodide, 8-hydroxyquinoline and sodium dodecyl benzene sulfonate according to a mass ratio of 3:4:2; and the organic solvent is ethanol with a mass concentration of 82%. The composite corrosion inhibitor has a good corrosion inhibition effect, and reduces harmful chemical ingredients in the corrosion inhibitor.Type: GrantFiled: September 18, 2023Date of Patent: March 26, 2024Assignee: Southwest Petroleum UniversityInventors: San He, YongLi Zou, XinYue Cai, YueYing Zhao, MengYu Xie, AnLin Yao, ZongMing Yuan
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Patent number: 11203539Abstract: A method of maintaining a safe free chlorine level in a body of water for recreational use where the free chlorine level at a harmful level comprises determining if the free chlorine level in the body of water is above a safe level and adding sufficient DMH to the body of water to bring the free chorine down to a safe level.Type: GrantFiled: September 5, 2019Date of Patent: December 21, 2021Assignee: KING TECHNOLOGY INCInventors: David Guy, Jeffrey D. Johnson, Paul Freeberg, Terry Goeman, Lyle Enderson, Joseph A King, Randy Roseth
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Patent number: 11155745Abstract: This invention relates to a composition comprising 1.) a metal carboxylate, wherein the metal M is selected from the group consisting of Ag, Cn, Hg, Pb, Sn, Ni, Co, Ca, Fe, Zn and Mn, those metals being present as ions in a +2 or +3 charge state, and wherein the carboxylate anion is derived from a hydrocarbyl monocarboxylic acid having 5 to 20 carbon atoms, or a mixture of such acids, 2.) a solvent selected from the group consisting of water, glycol ethers having from 4 to 15 carbon atoms, alkyl alcohols having from 1 to 10 carbons, and aromatic hydrocarbon solvents having from 6 to 30 carbons, and 3.) an emulsion breaker which is a polymeric nonionic surfactant.Type: GrantFiled: March 21, 2016Date of Patent: October 26, 2021Assignee: Clariant International Ltd.Inventor: Jonathan James Wylde
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Patent number: 10870102Abstract: An object of a first aspect of the present invention is to provide a radical generating catalyst that can generate (produce) radicals under mild conditions. In order to achieve the above object, a first radical generating catalyst according to the first aspect of the present invention is characterized in that it includes ammonium and/or a salt thereof. A second radical generating catalyst according to the first aspect of the present invention is characterized in that it includes an organic compound having Lewis acidic properties and/or Brønsted acidic properties.Type: GrantFiled: December 16, 2016Date of Patent: December 22, 2020Assignee: ACENET INC.Inventors: Kiyoto Takamori, Takekatsu Shibata
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Patent number: 10773220Abstract: A method and apparatus for obtaining a product chemistry from a solid block is provided. The product is housed within a dispenser, which utilizes a liquid and a gas to erode the block and produce a concentrate solution. The liquid and gas characteristics can be adjusted in the field to achieve a predetermined concentrate level in the solution. The introduction of air into the dispenser saves water, while producing higher concentrate levels.Type: GrantFiled: October 26, 2018Date of Patent: September 15, 2020Assignee: Ecolab USA Inc.Inventors: Daniel Ronald Schwartz, Ryan Joseph Drake
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Patent number: 10231457Abstract: A water treatment composition for treating a body of water is provided that provides visual feedback to the end-user of the effectiveness of the composition. The composition contains a majority of calcium hypochlorite particles; and an effective amount of colored particles containing an oxidizable pigment oxidizable dye and a water soluble material. The colored particles release the oxidizable dye to the body of the water to provide a transient color to the recreational water during dissolution of the composition in the body of water, the transient color providing a visual cue to the end-user signaling of the biocidal activity of the composition. Also provided is a method of applying the water treatment composition to recreational water.Type: GrantFiled: January 21, 2016Date of Patent: March 19, 2019Assignee: ARCH CHEMICALS, INC.Inventors: Janet Jones, Amber Khanzada, Janet Akande, Michael J. Unhoch
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Patent number: 10136642Abstract: A composition of peracetic acid and at least one organic fungicide, a method and a use involving said composition are described. The composition is for the control and/or treatment of diseases associated with the presence of pathogens, more particularly in and on the tissues of a growing plant. The composition may be a powdered composition comprising the organic fungicide(s) and a peracetic acid precursor system, which once admixed with water, may be applied to the tissues of the plant to be treated. Preferably, the peracetic acid precursor system may comprise hydrogen peroxide or a hydrogen peroxide precursor and an acetylating agent. Also described is a kit for preparing an aqueous solution of the described composition, for use in controlling pathogens on a plant tissue of a growing plant.Type: GrantFiled: February 16, 2016Date of Patent: November 27, 2018Assignee: AGRI-NEO, INC.Inventors: Fadi Dagher, Nicholas Dillon, Steven Kent Whitesides, Johannes Mathieu
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Patent number: 9909219Abstract: The invention provides methods and compositions for addressing the problem of microorganism infestations and especially biocorrosion in slurry transporting pipelines. The method comprises treating pipeline fluid (especially plug fluid) with an oxidizing biocide in an amount higher than the oxidant demand of the pipeline and a non-oxidizing biocide in an amount less than 30% of the minimum necessary to sterilize the microbiological organisms. This treatment makes use of the unique characteristics of a slurry pipeline to eliminate microorganisms without harming the pipeline as would be expected by using an oxidizing biocide.Type: GrantFiled: April 14, 2014Date of Patent: March 6, 2018Assignee: Ecolab USA Inc.Inventors: Michael G. Strominger, Danilo Zim, Fabiane Cássia de Sá Aureliano
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Patent number: 9420796Abstract: A method for controlling bivalve growth in a service water system of a plant is disclosed. Upon detecting an increase in the number of veligers or settlement stage bivalves, chlorine anion is introduced into the service water to obtain a chlorine anion concentration of between 0.10 and 2.0 mg/l for a period of 10 to 40 days. Also disclosed is a two-stage method for controlling bivalve growth in a service water system.Type: GrantFiled: January 31, 2013Date of Patent: August 23, 2016Assignee: ASI Group Ltd.Inventor: Carmelo Sferrazza
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Patent number: 9133109Abstract: The invention provides a process for manufacturing biocidal compositions containing bromourea derivatives, including the reaction of salts or adducts of the urea derivatives with an oxidizer.Type: GrantFiled: September 19, 2011Date of Patent: September 15, 2015Assignee: Bromine Compounds Ltd.Inventors: Shomo Antebi, David Feldman
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Patent number: 9061926Abstract: The present invention provides a composition and method for inhibiting the growth of microorganisms in industrial water systems. Methods employing the composition comprising halogen-based hydantoin or hydantoin-stabilized halogen in combination with peracetic acid demonstrate synergistic control of microbial growth, particularly control of slime deposition.Type: GrantFiled: July 15, 2005Date of Patent: June 23, 2015Assignee: NALCO COMPANYInventor: Bert Simons
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Patent number: 8945397Abstract: This invention offers an effective method of inhibiting the growth of toxic bloom algae caused by cyanobacteria Mycrocystis aeruginosa in freshwater environments comprising administering an effective amount of 5,6-dichlorogramine to the freshwater. Also, the invention offers an effective method of inhibiting the growth of toxic bloom algae caused by M. aeruginosa comprising administering an effective amount of 5,6,7-trichlorogramine to the freshwater. Both compounds, 5,6-dichlorogramine and 5,6,7-trichlorogramine, may be administered individually or in combination to the freshwater. Both compounds are individually very potent and only need to be administered at a very low concentration to be effective at inhibiting the growth of M. aeruginosa in freshwater environments. Both 5,6-dichlorogramine and 5,6,7-trichlorogramine are each individually effective at inhibiting M. aeruginosa at low concentrations, between about 0.01 mg/L and about 0.05 mg/L, or more specifically at a concentration of about 0.03 mg/L.Type: GrantFiled: October 19, 2012Date of Patent: February 3, 2015Assignee: Cyanotrol, LLCInventors: Yuhua Ge, Zheng-Hui He, Weiming Wu
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Patent number: 8877067Abstract: The invention relates to a water treatment using an UV AOP. The invention combines an UV AOP (11) applied to a water containing a free chlorine species (8) with a chemical post treatment (14), a quenching. The quenching (14) is applied to said water (9) after the UV AOP (11) able to reduce a remaining content of said free chlorine species in said water (9).Type: GrantFiled: May 25, 2012Date of Patent: November 4, 2014Assignee: Evoqua Water Technologies LLCInventor: Cosima Sichel
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Patent number: 8784659Abstract: A process has been found which increases the efficiency and effectiveness of introducing antimicrobial compounds into complex biofilm matrices through the use of liposome carriers, thereby removing the biofouling in industrial water bearing systems, including piping, heat exchanges, condensers, filtration systems and fluid storage tanks. According to one embodiment of the invention, antimicrobial compound containing liposomes are added to water systems prone to biofouling and biofilm formation. The liposomes, being similar in composition to microbial membranes or cells, are readily incorporated into the existing biofilm. Once the antimicrobial compound containing liposomes become entrained with the biofilm matrix, the decomposition or programmed disintegration of the liposome proceeds. Thereafter, the biocidal aqueous core is released to react directly with the biofilm encased microorganisms.Type: GrantFiled: September 28, 2010Date of Patent: July 22, 2014Assignee: General Electric CompanyInventors: Wilson Kurt Whitekettle, Gloria Jean Tafel, Qing Zhao, Linna Wang, Dorothy Reynolds, Paul Frail, Juan Jiang, David M. Polizzotti
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Patent number: 8741157Abstract: A system and method for stabilizing bromine in an industrial water system by monitoring and flexible dosing of chlorine oxidant and halide ion stabilizer residual levels. The system comprises chlorine oxidant, and a halide ion source with a halogen stabilizer.Type: GrantFiled: July 25, 2008Date of Patent: June 3, 2014Assignee: Nalco CompanyInventors: Robert L. Wetegrove, Andrew J. Cooper, Steven R. Hatch
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Patent number: 8722579Abstract: An aqueous composition for treatment of water comprising: (a) an N,N-dimethyl-2-hydroxypropylammonium chloride polymer; (b) lanthanum chloride; and (c) a dimethylamine epichlorohydrin ethylenediamine polymer; and a method of treating water using the composition.Type: GrantFiled: February 10, 2012Date of Patent: May 13, 2014Assignee: Waterco LimitedInventors: Robert Ian Anderson, Paul Seidl
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Patent number: 8668779Abstract: A method of simultaneously cleaning and disinfecting an industrial water system is described and claimed. The method involves the addition to the water of the industrial water system of a Compound selected from the group consisting of the alkali salts of chlorite and chlorate and mixtures thereof; and an acid, followed by allowing the water in the industrial water system to circulate for several hours. The reaction of the alkali salts of chlorite and chlorate and acid produces chlorine dioxide in-situ in the water of the industrial water system. The chlorine dioxide kills microorganisms and the acid acts to remove deposits upon the water-contact surfaces of the equipment. This cleaning and disinfecting method works in a variety of industrial water systems including cooling water systems.Type: GrantFiled: April 30, 2002Date of Patent: March 11, 2014Assignee: Nalco CompanyInventors: Andrew J. Cooper, Jasbir S. Gill, Amit Gupta, Robert F. Kelly, Douglas G. Kelley, Eric R. Myers
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Patent number: 8613859Abstract: Synergistic mixtures of haloamines and their use to control the growth of microorganisms in aqueous systems are disclosed. The method of using the synergistic mixtures entails adding an effective amount of a monohaloamine and an effective amount of a dihaloamine to an aqueous system. The ratio of monohaloamine to dihaloamine is selected to result in a synergistic biocidal effect.Type: GrantFiled: October 25, 2010Date of Patent: December 24, 2013Assignee: Hercules IncorporatedInventors: Michael J. Mayer, Freddie L. Singleton
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Patent number: 8591748Abstract: A system and method for maintaining a body of water in a sanitized condition with use of a halogen and a source of silver ions wherein the halogen is maintained at 50% to 75% less than a recommended halogen level for maintaining the body of water in a sanitized condition by adding a compound containing a hydantoin ring to a recreational body of water containing a halogen and a source of metal ions.Type: GrantFiled: May 20, 2010Date of Patent: November 26, 2013Assignee: King Technology, Inc.Inventors: John Hill, Joseph A. King
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Patent number: 8114298Abstract: A device, system and method are provided for treating water, in which a water treating agent is prepared and dispensed to an untreated drinking water source in discrete and consecutive control volumes enabling untreated water in the untreated water source to be treated thereby to provide potable water.Type: GrantFiled: August 2, 2007Date of Patent: February 14, 2012Assignees: Bromine Compounds Ltd., WDT-Werner Dosiertechnik GmbH & Co. KGInventors: Theodore Fishler, David Feldman, Dietmar Werner
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Publication number: 20110259835Abstract: A method for reducing an isocyanuric acid level concentration in swimming pool water to prevent chlorine lock. The method comprises the steps of adding an effective amount of sodium hydroxide combined with an antimicrobial agent to the pool water and reacting the sodium hydroxide with the isocyanuric acid therein to reduce the isocyanuric acid concentration to a level of between about 30 to 50 PPM. The antimicrobial agent reduces the amount of microorganisms that have accumulated in the pool water until the chlorine is released from its “locked-up” condition.Type: ApplicationFiled: April 26, 2010Publication date: October 27, 2011Inventor: David Hodak
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Patent number: 8029677Abstract: A water purification method and devices, and in particular a purification method effective against microbes, that uses a silane-based antimicrobial, and in particular the AEGIS MICROBE SHIELD antimicrobial, where the antimicrobial is embedded, coated, or otherwise permanently applied to a substrate or carrier, such as a solid, a porous solid, fibers or the like. A volume of microbe contaminated water is exposed to the antimicrobial carrier for sufficient residence time such that sufficient quantities of microbes are eradicated and the water is made potable. The antimicrobial carrier may be an object suspended or placed into a container or reservoir for the water, or the antimicrobial carrier may comprise the container or reservoir itself. Particulate filters or the like may also be combined with the antimicrobial container to remove other undesirable contaminants.Type: GrantFiled: September 21, 2010Date of Patent: October 4, 2011Inventors: Mark D. Shaw, J. Tad Heyman
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Patent number: 7976725Abstract: An efficient cyclic process and related compositions for the in-situ generation of chlorine dioxide from dilute solutions of chlorite anions at near neutral pH. The cyclic process provides a means of safe and effective use of chlorine dioxide with reduced concern of chlorite accumulation in the aqueous system. The disclosed chemistry used to support the cyclic process can be applied independently or in various combinations that are effectively inert. This dramatically reduces safety concerns since the chlorine dioxide is produced in-situ to the application and in dilute concentrations. Also, the process allows for regeneration of inert anions such as bromide and chlorite thereby reducing operating cost.Type: GrantFiled: January 9, 2009Date of Patent: July 12, 2011Assignee: Truox, Inc.Inventor: Roy William Martin
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Patent number: 7927509Abstract: An efficient cyclic process and related compositions for the in-situ generation of chlorine dioxide from dilute solutions of chlorite anions at near neutral pH. The cyclic process provides a means of safe and effective use of chlorine dioxide with reduced concern of chlorite accumulation in the aqueous system. The disclosed chemistry used to support the cyclic process can be applied independently or in various combinations that are effectively inert. This dramatically reduces safety concerns since the chlorine dioxide is produced in-situ to the application and in dilute concentrations. Also, the process allows for regeneration of inert anions such as bromide and chlorite thereby reducing operating cost.Type: GrantFiled: January 23, 2009Date of Patent: April 19, 2011Assignee: Truox, Inc.Inventor: Roy William Martin
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Patent number: 7927508Abstract: An efficient cyclic process and related compositions for the in-situ generation of oxyhalogens from anions of chloride, bromide and chlorite in an aqueous system using in-situ generated sulfate free radicals. The cyclic process and compositions enhance the rate of inactivation of microbiological organisms especially those resistant to inactivation from free halogen based sanitizers, and oxidation of oxidation resistant organic based compounds in aqueous solution. Aquatic facilities susceptible to accumulation of organic N-chloramines and other oxidation resistant compounds, as well as oxidation resistant parasitic organisms such as cryptosporidium and Giardia, obtain dramatic improvements in the rate of oxidation and subsequent inactivation of these undesirable contaminants.Type: GrantFiled: December 18, 2008Date of Patent: April 19, 2011Assignee: Truox, Inc.Inventor: Roy W. Martin
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Patent number: 7922933Abstract: This invention relates to a method for enhanced sanitation and oxidation of aqueous solutions at aquatic facilities. The method provides a means for the in-situ generation of chlorine dioxide from dilute solutions of chlorite anions at near neutral pH, and enhanced inactivation rates of microbiological organisms including cryptosporidium.Type: GrantFiled: July 23, 2009Date of Patent: April 12, 2011Assignee: Truox, IncInventor: Roy W. Martin
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Patent number: 7875191Abstract: A two part biocide composition containing metal ions and bromine donor for killing microorganisms in a body of water and a method of killing microorganisms in a body of water by placing both metal ions and a bromine in the body of water to allow use of lower concentrations of bromine than if bromine were used alone as a biocide.Type: GrantFiled: December 2, 2008Date of Patent: January 25, 2011Assignee: King Technology, IncInventors: Joseph A. King, Marlin Frank
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Publication number: 20110011809Abstract: A water purification method and devices, and in particular a purification method effective against microbes, that uses a silane-based antimicrobial, and in particular the AEGIS MICROBE SHIELD antimicrobial, where the antimicrobial is embedded, coated, or otherwise permanently applied to a substrate or carrier, such as a solid, a porous solid, fibers or the like. A volume of microbe contaminated water is exposed to the antimicrobial carrier for sufficient residence time such that sufficient quantities of microbes are eradicated and the water is made potable. The antimicrobial carrier may be an object suspended or placed into a container or reservoir for the water, or the antimicrobial carrier may comprise the container or reservoir itself. Particulate filters or the like may also be combined with the antimicrobial container to remove other undesirable contaminants.Type: ApplicationFiled: September 21, 2010Publication date: January 20, 2011Inventors: Mark D. Shaw, J. Tad Heyman
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Patent number: 7824557Abstract: A process has been found which increases the efficiency and effectiveness of introducing antimicrobial compounds into complex biofilm matrices through the use of liposome carriers, thereby removing the biofouling in industrial water bearing systems, including piping, heat exchanges, condensers, filtration systems and fluid storage tanks. According to one embodiment of the invention, antimicrobial compound containing liposomes are added to water systems prone to biofouling and biofilm formation. The liposomes, being similar in composition to microbial membranes or cells, are readily incorporated into the existing biofilm. Once the antimicrobial compound containing liposomes become entrained with the biofilm matrix, the decomposition or programmed disintegration of the liposome proceeds. Thereafter the biocidal aqueous core is released to react directly with the biofilm encased microorganisms.Type: GrantFiled: August 8, 2007Date of Patent: November 2, 2010Assignee: General Electric CompanyInventors: Wilson Kurt Whitekettle, Gloria Jean Tafel, Qing Zhao
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Patent number: 7820060Abstract: Synergistic mixtures of haloamines and their use to control the growth of microorganisms in aqueous systems are disclosed. The method of using the synergistic mixtures entails adding an effective amount of a monohaloamine and an effective amount of a dihaloamine to an aqueous system.Type: GrantFiled: August 24, 2006Date of Patent: October 26, 2010Assignee: Hercules IncorporatedInventors: Michael J. Mayer, Freddie L. Singleton
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Patent number: 7780859Abstract: The invention provides the use of a water-soluble biocide as an uncoupling agent at an effective amount to control bacterial biomass in an aqueous system. The invention also provides a method for controlling the growth of bacterial biomass in an aqueous system. The method comprises adding to, or contacting with, the aqueous system an effective amount of an uncoupling agent which is a water-soluble biocide. In a preferred embodiment the method comprises contacting an effective amount of an uncoupling agent which is a water-soluble biocide directly with the bacterial biomass in an aqueous system.Type: GrantFiled: June 21, 2004Date of Patent: August 24, 2010Assignee: Rhodia OperationsInventors: Yvette Pescher, Robert Eric Talbot, Luc Olivier Louvel, Agnes Pilas-Begue, Laetitia Catinon, Gilles Michael Moreau
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Patent number: 7736520Abstract: A process for the reduction of N-nitrodimethylamine (NDMA) and for control of trihalomethanes (THMs) and haloacetic acids (HAAs) formation in fully nitrified wastewater effluent, comprising first adding chlorine to the effluent, then adding combined chlorine.Type: GrantFiled: April 18, 2007Date of Patent: June 15, 2010Assignee: County Sanitation Districts of Los Angeles CountyInventor: Shiaw-Jy Huitric
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Publication number: 20100140185Abstract: An antimicrobial method of treating wastewater and a wastewater antimicrobial dispenser containing an antimicrobial agent for treating a body of wastewater to kill microorganisms by increasing the concentration metal ions therein. The antimicrobial method includes the step of increasing the effectiveness of the biocidal component in the body of wastewater to thereby lessen the need for a supplemental biocide by adding a compound containing a hydantoin ring where the compound containing a hydantoin ring may or may not have any antimicrobial properties. The antimicrobial agent including a source of biocidal metal ions and a compound containing a hydantoin ring where the antimicrobial agent may be a powder, a liquid a solid or combinations thereof.Type: ApplicationFiled: December 1, 2009Publication date: June 10, 2010Inventors: John Hill, Joseph A. King
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Patent number: 7727465Abstract: A system and method for extracting active elemental iodine from the contact of water with stored crystal iodine and for introducing the extracted elemental iodine into a water supply line and/or otherwise making the extracted elemental iodine available for an intended use. The system operates by allowing a portion of the water entering from a water supply line to be redirected to a first housing where it makes contact with stored crystal iodine causing to extract active elemental iodine. The iodinized water leaves the first housing and enters a second housing where it makes contact additional stored crystal iodine to help stabilize the elemental iodine concentration. The system can be designed to provide the elemental iodine in more than one potency concentration through the use of a metering valve and different travel routes for the elemental iodine out of the second housing.Type: GrantFiled: April 25, 2008Date of Patent: June 1, 2010Inventor: Spyros J. Papageorge
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Publication number: 20100006513Abstract: A device, system and method are provided for treating water, in which a water treating agent is prepared and dispensed to an untreated drinking water source in discrete and consecutive control volumes enabling untreated water in the untreated water source to be treated thereby to provide potable water.Type: ApplicationFiled: August 2, 2007Publication date: January 14, 2010Applicants: BROMINE COMPOUNDS LTD., WDT-WERNER DOSIERTECHNIK GMBH & CO. KGInventors: Theodore Fishler, David Feldman, Dietmar Werner
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Publication number: 20090242484Abstract: This is a method that is an environmentally friendly hybrid microbiological control compromising a physical method through fine filtration, which removes nutrients, bacteria and suspended solids from open recirculating cooling systems. The method for microbiological control in cooling systems wherein a recirculating fluid containing an oxidising or a non-oxidising biocide or a mixture of an oxidising and a non-oxidising biocide and is passed through a fine filtration system resulting in reduced microbiological matter, suspended solids and nutrients.Type: ApplicationFiled: April 1, 2008Publication date: October 1, 2009Inventors: Ana-Mariana Urmenyi, Jeroen A. Koppes, Robert L. Wetergrove, Menno J.T. van Haasterecht
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Publication number: 20090200246Abstract: A method and apparatus for treating a body of water to kill microorganisms by enhancing the concentration metal ions therein. The apparatus comprising a dispenser with a first housing having a water accessible compartment containing a source of a N-halohydantoin compound for releasing the N-halohydantoin compound when contacted by the body of water with the at least one N-halohydantoin having the formula: wherein R and R1 each independently comprises an alkyl group, and wherein X and Y are independently selected from the group consisting of bromine, chlorine and hydrogen and a second housing having a water accessible compartment containing an insoluble metal ion donor for releasing metal ions when contacted by the body of water containing the N-halohydantoin.Type: ApplicationFiled: April 14, 2009Publication date: August 13, 2009Inventors: Joseph A. King, Nicole A. Weulander, John Hill
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Patent number: 7560033Abstract: A composition comprising a stable anhydrous mixture of an oxidizing agent and an active halogen agent wherein the oxidizing agent is potassium hydrogen peroxymonosulfate and the active halogen agent is an alkali metal salt of dichloro-s-triazinetrione, halogenated dimethylhydantoin, or mixtures thereof, and a method of treating water with such compositions are disclosed.Type: GrantFiled: October 13, 2004Date of Patent: July 14, 2009Inventors: Edward Blake Lightcap, Michael Brian Coxey, Thomas Peter Tufano
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Patent number: 7501067Abstract: A two part biocide composition containing metal ions and bromine donor for killing microorganisms in a body of water and a method of killing microorganisms in a body of water by placing both metal ions and a bromine in the body of water to allow use of lower concentrations of bromine than if bromine were used alone as a biocide.Type: GrantFiled: December 6, 2007Date of Patent: March 10, 2009Inventors: Joseph A. King, Marlin Frank
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Patent number: 7455859Abstract: Liquid and solid bromine-containing compositions are described. A liquid mixed halogen composition is also described. The highly concentrated liquid compositions and the high-activity solid compositions have excellent physical and chemical stability. The compositions are effective biocides in water treatment. Methods of preparing the compositions are also disclosed. These include combining a bromine compound in the oxidation state of ?1 with hydrogen peroxide and a complexing agent followed by the addition of an alkaline source. The methods may further include the use of a solid organic or solid inorganic halogenating agent, conducting a solid-liquid separation, and adding an alkaline source.Type: GrantFiled: January 27, 2006Date of Patent: November 25, 2008Assignee: Enviro Tech Chemical Services, Inc.Inventors: Jonathan N. Howarth, Michael S. Harvey
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Publication number: 20080277355Abstract: A water-insoluble polymeric oxidizing medium is contemplated that has a plurality of polymerized N-pyridinium vinylbenzyl triiodide or tribromide moieties whose pyridinium rings bear two substituents, R1 and R2, that are independently a hydrido or a C1-C4 alkyl group, and correspond in structure to the formula A process for preparing aseptic water and an apparatus useful for carrying out that process, both of which utilize a contemplated polymeric oxidizingType: ApplicationFiled: November 21, 2007Publication date: November 13, 2008Inventors: Paul K. Smith, Timothy J. Badger
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Patent number: 7449119Abstract: Compositions containing chlorine and/or bromine in combination with chlorine dioxide are found to be synergistic against non-tuberculosis mycobacterium such as Mycobacteria chelonae.Type: GrantFiled: July 25, 2006Date of Patent: November 11, 2008Assignee: Chemtura CorporationInventor: Geoffrey Brown
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Patent number: 7445759Abstract: A system and method for extracting active elemental iodine from the contact of water with stored crystal iodine and for introducing the extracted elemental iodine into a water supply line and/or otherwise making the extracted elemental iodine available for an intended use. The system operates by allowing a portion of the water entering from a water supply line to be redirected to a first housing where it makes contact with stored crystal iodine causing to extract active elemental iodine. The iodinized water leaves the first housing and enters a second housing where it makes contact additional stored crystal iodine to help stabilize the elemental iodine concentration. The system can be designed to provide the elemental iodine in more than one potency concentration through the use of a metering valve and different travel routes for the elemental iodine out of the second housing.Type: GrantFiled: April 5, 2006Date of Patent: November 4, 2008Inventor: Spyros J. Papageorge
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Publication number: 20080257001Abstract: The present invention provides a method of reducing the pathogen content of sewage sludge comprising (a) adding to the sludge an effective amount of a phosphorous-containing compound and (b) keeping the phosphorous-containing compound in contact with the sludge for a sufficient time to reduce the amount of pathogens present in the sludge by an amount equivalent to a logarithmic reduction of 2 or more.Type: ApplicationFiled: December 16, 2005Publication date: October 23, 2008Applicant: Rhodia LimitedInventors: Stephanie Edmunds, Paul Douglas Gilbert, Robert Eric Talbot
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Publication number: 20080203034Abstract: The invention relates to a method of inhibiting the growth of microorganisms in fresh or circulating water by adding to the water, separately and essentially continuously, (1) an oxidant and (2) a bromine source.Type: ApplicationFiled: March 15, 2006Publication date: August 28, 2008Applicant: BIM KEMI ABInventors: Petri Lindqvist, Pertti Mattila, Pekka Kultalahti
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Patent number: 7407590Abstract: The present invention provides a method for the removal of biofilm, flocculent bulked sludge or bulked biologically active sludge from an aqueous system. The method involves adding one or more chlorinated hydantoins, such as dichloro- or monochlorodialkylhydantoin, to the aqueous system. Alternatively, the chlorinated hydantoin may be formed in situ by adding a chlorine source and an alkylated hydantoin separately to the aqueous system. The invention is particularly advantageous because of the outstanding photostability of the chlorinated hydantoin solutions even when exposed to sunlight.Type: GrantFiled: June 6, 2003Date of Patent: August 5, 2008Assignee: Lonza, Inc.Inventors: Michael Ludensky, Philip G. Sweeny
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Patent number: 7407623Abstract: Lecithin and 2-bromo-2-nitropropane-1,3 diol (BNPD) are used to inhibit corrosion in boiler steam condensate systems. Aqueous steam condensate corrosion inhibiting compositions of these components are also disclosed. BNPD is also used as a preservative in lecithin containing and in other GRAS additive containing compositions.Type: GrantFiled: October 5, 2004Date of Patent: August 5, 2008Assignee: GE Betz, Inc.Inventors: Wilson K. Whitekettle, Rosa Crovetto
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Publication number: 20080142453Abstract: The present invention is directed to a composition for treating recirculating water systems, comprising: (1) a biocidal effective amount of a first nonoxidizing biocide comprising biguanide; and (2) a biocidal effective amount of a second nonoxidizing biocide comprising dibromonitrilopropionamide (DBNPA); wherein the composition is substantially free from oxidants. The present invention is also directed to a method of controlling the growth of microorganisms in recirculating water systems, comprising the step of treating the recirculating water systems with the above composition.Type: ApplicationFiled: December 5, 2007Publication date: June 19, 2008Inventors: Michael Joseph Unhoch, Sungmee Choi, Katherine P. Roberts, Leon Peter O'Malley
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Patent number: 7341671Abstract: Disclosed is a method of preparing a biocide having improved durability of its biocidal activity as well as disinfection efficiency at an initial stage, comprising the steps of: (a) preparing stabilized alkali or alkaline earth metal hypochlorite having a pH at least 11 by mixing a chlorine oxidant including alkali or alkaline earth metal hypochlorite with a stabilizer in an alkali solution; (b) preparing a bromide ion source; and (c) adding the bromide ion source prepared in step (b) into the stabilized alkali or alkaline earth metal hypochlorite prepared in step (a). Also, a method of controlling the growth of microorganisms using a biocide prepared by the method of the present invention is disclosed.Type: GrantFiled: March 5, 2003Date of Patent: March 11, 2008Assignee: Acculab Co., Ltd.Inventors: Sang-Hea Shim, Chung-Soo Kim
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Patent number: RE41859Abstract: Aquatic nuisance species (ANS) in ship's ballast water are killed by permeating to equilibrium a gaseous mixture consisting essentially of, preferably, ?84% nitrogen, ?11% carbon dioxide and ?4% oxygen through ship's ballast water until the ballast water itself becomes (i) hypercapnic to ?20 ppm carbon dioxide, and, by association, (ii) acidic to pH?7, while preferably further, and also, being rendered (iii) hypoxic to ?1 ppm oxygen. The permeating is preferably realized by bubbling the gaseous mixture preferably obtained from an inert gas generator through the ballast water over the course of 2+ days while the ballast water is continually maintained a pressure less than atmosphere, preferably ?2 p.s.i. or less.Type: GrantFiled: July 10, 2006Date of Patent: October 26, 2010Inventors: Mo Husain, Robert Apple, Dmitry Altshuller, Henry Hunter