Abstract: The invention relates to a method for removing arsenic as scorodite from solutions that contain iron and arsenic. In accordance with the method, arsenic is first precipitated as ferric arsenate and subsequently processed hydrothermally into crystalline scorodite.

Abstract: A method for treating a sludge to be fed to a bioreactor for treating wastewater, or an anaerobic or aerobic sludge digester, the method comprising contacting the sludge with free nitrous acid.

Abstract: Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed or remove one or more active chemical species into or from the hot water system and further operable to change at least one system parameter.

Abstract: A method for treating hydrogen sulfide in a solution includes providing the solution containing hydrogen sulfide. The method also includes adding sodium nitrite to the solution in an amount suitable to react with the hydrogen sulfide and treat the hydrogen sulfide.

Abstract: Disclosed is a process for separating solids from liquid in a slurry. The process is characterized by using two filtration media. One filtration medium contains less than 10 mm in thickness of a filter cake containing the solids, and the other filtration medium contains at least 10 mm in thickness of a filter cake containing the solids. The second filtration medium has a higher separation efficiency that the first filtration medium. The process is particularly useful for separating terephthalic acid solids from an oxidation product slurry.

Abstract: The installation comprises three reaction vessels (100, 200, 300) in series, each containing an aqueous phase and a specific bacterial population. The vessels serve in succession to dissolve the liquid feedstock for treatment by enzymatic hydrolysis, then to biodegrade the resulting effluent by biological digestion, and finally to reduce the residual bacterial components by biological action. The vessels are mutually isolated by tangential filters (108, 208, 308) and by centrifugal separators (212, 312) for filtering the biomass from the reaction products. The result is a final liquid effluent (EFF/N) that is essentially non-organic, with the filtered biomass downstream constituting an ultimate organic waste (DU) of reduced volume.

Abstract: The present disclosure is directed towards systems and methods for the treatment of wastewater. A system in accordance with one particular embodiment may include a front end system including at least one resin tank configured to contain an ion exchange resin configured to target a particular metal. The at least one resin tank may be configured to receive an output from an oxidation reactor configured to receive a flow of wastewater from a wastewater producing process. The system may further include a central processing system configured to receive a saturated resin tank from the at least one resin tank. The central processing system may further include a vacuum filter band system configured to receive a slurry from the saturated resin tank and to provide a cascading resin rinse to the slurry. The central processing system may further include a repetitive stripping system configured to receive a metal-filled purification unit from a metal specific purification system.

Abstract: A method and system of providing ultrapure water for semiconductor fabrication operations is provided. The water is treated by utilizing a free radical scavenging system and a free radical removal system. The free radical scavenging system can utilize actinic radiation with a free radical precursor compound, such as ammonium persulfate. The free radical removal system can comprise use of a reducing agent. The ultrapure water may be further treated by utilizing ion exchange media and degasification apparatus. A control system can be utilized to regulate addition of the precursor compound, the intensity of the actinic radiation, and addition of the reducing agent to the water.

Abstract: A method of inhibiting water from ionizing and reacting with carbon dioxide includes: providing processed water having a potential for reacting H2O with CO2 in a system substantially devoid of O2 and/or CO2; providing at least about 20 PPM of negative ions to the H2O in a sufficient amount to react therein in the system substantially devoid of O2 and/or CO2; and inhibiting the H2O from reacting with CO2 to form carbonic acid by reacting the H2O with the negative ions in a sufficient amount in the system substantially devoid of O2 and/or CO2 so as to stabilize the processed water to form stabilized water. Obtaining chilled water and vortexing the chilled water over lodestones with or without aeration.

Abstract: A method for reprocessing spent nuclear fuel from a light water reactor includes the step of reacting spent nuclear fuel in a voloxidation vessel with an oxidizing gas having nitrogen dioxide and oxygen for a period sufficient to generate a solid oxidation product of the spent nuclear fuel. The reacting step includes the step of reacting, in a first zone of the voloxidation vessel, spent nuclear fuel with the oxidizing gas at a temperature ranging from 200-450° C. to form an oxidized reaction product, and regenerating nitrogen dioxide, in a second zone of the voloxidation vessel, by reacting oxidizing gas comprising nitrogen monoxide and oxygen at a temperature ranging from 0-80° C. The first zone and the second zone can be separate. A voloxidation system is also disclosed.

Abstract: Systems and methods for removing organic contaminants from water may be used, for example, to treat produced water from a steam assisted heavy oil recovery operation. The treated produced water may be re-used to create steam. Alternatively, the produced water may be a blowdown stream treated to facilitate further treatment in a thermal crystallizer. The treatments may include pH adjustment or separating de-solubilized organics or both. Other treatments may include one or more of oxidation, sorption and biological treatments. The treatments may be used alone or in various combinations. One exemplary combination includes reducing the pH of produced water, separating de-solubilized organics from the produced water, and oxidizing the produced water or contacting the produced water with activated carbon.

Abstract: A method and system of providing ultrapure water for semiconductor fabrication operations is provided. The water is treated by utilizing a free radical scavenging system and a free radical removal system. The free radical scavenging system can utilize actinic radiation with a free radical precursor compound, such as ammonium persulfate. The free radical removal system can comprise use of a reducing agent. The ultrapure water may be further treated by utilizing ion exchange media and degasification apparatus. A control system can be utilized to regulate addition of the precursor compound, the intensity of the actinic radiation, and addition of the reducing agent to the water.

Abstract: A system and method for stabilizing bromine in an industrial water system by monitoring and flexible dosing of chlorine oxidant and halide ion stabilizer residual levels. The system comprises chlorine oxidant, and a halide ion source with a halogen stabilizer.

Abstract: A mercury remediation method and apparatus for reducing mercury levels in water to a nanogram per liter level that uses four treatment steps: (1) chelation; (2) oxidation; (3) reduction; and (4) air stripping, vapor/liquid separation. There is a fifth step in the process, which does not involve the wastewater. It is to scrub the stripper air of the volatile mercury in an off-gas adsorption unit or to condense volatile mercury in a cryogenic mercury trap.

Abstract: A method of making an aqueous ozone solution for an industrial cleaning system is described. The method includes providing a reaction vessel for entraining ozone gas in an aqueous solution. The reaction vessel includes a conical-shaped surface having a two or more edges or ridges. The conical-shaped surface defines an interior, and two or more edges or ridges are in contact with the interior. The reaction vessel is in fluidic communication with a supply of water. The reaction vessel is in fluidic communication with a supply of a first aqueous ozone solution. The first aqueous ozone solution is directed to the conical-shaped surface. Water is directed to the conical-shaped surface, and the water and the first aqueous ozone solution are mixed to form a second aqueous ozone solution.

Abstract: Advanced oxidation process namely ozonation and Fenton's (hydrogen peroxide/Fe:2+) were utilized to degrade kinetic hydrate inhibitor (KHI). The oxidized solution after scavenging oxygen can be successfully disposed to the injection well. This facilitates use of KHI more frequently and in higher concentrations for future projects oil & gas operations. It also offers an alternative that competes efficiently with thermodynamic hydrate inhibitor (THI) or complements THI.

Abstract: Methods for treating animal waste, particularly liquid fractions separated from manure, with high purity oxygen are provided to increase the dissolved oxygen content of the wastewater and minimize stripping of volatile gases. In particular, methods of the invention for treating animal waste comprise separating animal waste into a liquid fraction and a solid fraction, and aerating at least a portion of the liquid fraction with oxygen having a purity greater than 90% until the dissolved oxygen (DO) level of the liquid fraction is between about 2.0 mg/L and about 9.0 mg/L.

Abstract: An apparatus and methods for measuring the concentration of an additive are disclosed. The apparatus comprises a treatment stream (1) and a dosing stream (2). An additive is added to the dosing stream using a metering device (3). In some embodiments, the dosing stream is mixed after adding the additive using a first mixing device (4). Downstream from the metering device and the mixing device, the concentration of the additive in the dosing stream is measured using a monitor flow cell (5). In some embodiments, the dosing stream and treatment stream are combined (6) and mixed using a second mixing device (7). The concentration of the additive in the treatment stream can be calculated as a function of the volumetric flow rate ratio of the dosing stream to the treatment stream and the measured concentration of the additive in the dosing stream.

Abstract: A method of removing contaminants from slurry samples is set forth. The method includes the utilization of repeated pressurizing and depressurizing steps to disrupt solidified particles in solid-containing slurries thereby increasing decontamination efficiency. An expansion fluid is injected into the slurry sample sufficient to create microbubbles when the slurry sample is depressurized. The micro bubbles mechanically disrupt the solidified particles increasing contaminant exposure. The microbubbles also provide for increased interfacial regions where contaminants can accumulate at gas-liquid thin films that are in close proximity to and can be effectively removed using a suitable expansion fluid and optional decontamination agents.

Abstract: A method for treating hydrogen sulfide in a solution includes providing the solution containing hydrogen sulfide. The method also includes adding sodium nitrite to the solution in an amount suitable to react with the hydrogen sulfide and treat the hydrogen sulfide.

Abstract: An aeration control valve system may be used with a water treatment system to control aeration and flow of water in accordance with various operating cycles. The aeration control valve system pumps air into the water treatment system to provide an air charge for aerating the water to facilitate water treatment. The aeration control valve system may pump air into the water treatment system at atmospheric pressure or may pump air at higher pressures such that the air may be recharged while also treating the water. The aeration control valve may also control the release of air from the water treatment system. The operating cycles may include, for example, a service cycle, a backwash cycle, an air regeneration cycle, a service/air charge cycle, an air release cycle, and a rinse cycle.

Abstract: A method of removing color bodies from a fermentation broth includes precipitating a color-forming impurity (color body) by adjusting the fermentation broth to a pH greater than about 13; filtering our precipitated color-forming impurities from the broth; and bleaching a second color impurity by treating the broth with an oxidizing agent.

Abstract: Provided are compositions and methods for removing excess formaldehyde from aqueous systems. The compositions comprise: a hydroxylamine compound of formula I: OH I R—N—H (I) wherein R is as defined herein; and an activated olefm.

Abstract: Methods, apparatus and systems for treating wastewater onboard small marine vessels. A pre-determined volume of wastewater generated onboard the vessel is mixed with a larger volume of seawater. This mixture is disinfected and subjected to further oxidation. The excess oxidants are neutralized and the treated effluent is discharged overboard the vessel.

Abstract: According to one embodiment, a treatment apparatus includes a treatment liquid storage unit and a supply unit. The treatment liquid storage unit is configured to store a treatment liquid containing an acid and an oxidizing substance. The supply unit is configured to supply the treatment liquid stored in the treatment liquid storage unit to a fluid extracted via a production well.

Abstract: Wastewater is treated by providing a distribution conduit and providing a diffuser assembly. An aperture is created in the distribution conduit having an initial minimum diameter. The diffuser assembly, in turn, comprises a diffuser membrane in fluidic communication with a mating tube. The mating tube has an initial outside diameter at a location along its length greater than the initial minimum inside diameter of the aperture. The mating tube is inserted into the aperture until the location on the mating tube that, before insertion, had the initial outside diameter is encircled by the aperture where the aperture, before insertion, had the initial minimum inside diameter. This forms an airtight interference fit between the distribution conduit and diffuser assembly.

Abstract: In a system for decomposing organic compounds in water for use in semiconductor manufacturing, a chemical reactor vessel having a fluid inlet and a fluid outlet, a persulfate anion addition system upstream of the reactor vessel, and a light emitting device contained within the reactor vessel. The light emitting device provides light capable of decomposing persulfate anions.

Abstract: Novel devices for synthesizing ferrate and uses thereof are described. One aspect of the invention relates to devices and systems for synthesizing ferrate at a site proximal to the site of use.

Abstract: The present invention provides a process of oxygenated feed-water treatment of boilers in power station, carried out under an OT treatment process, suitable for both the monotube type boiler and the drum type boiler, and comprising an oxygenation stage comprising: a normal oxygenation converting stage and a decreased oxygenation film-supplementing stage; the normal oxygenation converting stage is a stage in which the feed water system is oxygenated both at the outlet of a condensate polishing system and at the inlet of a feed water pump of a high pressure feed water system, and the concentration of dissolved oxygen in the main steam is controlled to be ?5 ?g/L; the decreased oxygenation film-supplementing stage is a stage in which, after an oxide film is formed in the feed water system, the amount of oxygenation at the high pressure feed water system is decreased so that the amount of the oxygen added is only for supplementing and maintaining the oxide film, while the concentration of dissolved oxygen in the

Abstract: A standing wave in a water current, which is subject to purification, is swirled in the lower mass-exchange chamber in order to create negative pressure along the central axis, the atmosphere air intake and crating of two countercurrents interacting with each other, resulting in a standing wave and oxygenation of the water current. A cylindrical mixing chamber, which is divided into the upper mass-exchange chamber and the lower mass-exchange chamber by dividing walls with a coaxial orifice towards the air-supply pipe and peripheral bypass channel. In the lower mass-exchange chamber, water, which is subject to purification, is swirled and under the negative pressure in the center it intakes air from the air-supply pipe, creating hydrosol and reaction area of ion exchange due to forming of the standing acoustic wave. Part of the processed current is outlet into the volume through a permeable wall in the side surface of the upper mass-exchange chamber.

Abstract: Accelerated dechlorination of soil and water contaminated with chlorinated solvents in situ is achieved by delivering ferric ammonium citrate into the soils and/or water. The induction of ferric ammonium citrate into sulfate-rich reducing conditions initiates a combined abiotic and biotic mechanism for the dechlorination of subsurface contaminants. Initial and rapid removal of chlorinated solvents is achieved by way of reductive transformation, a mechanism utilizing the creation of an iron-bound soil mineral (pyrite) followed by stimulating conditions for enhanced biological natural attenuation.

Abstract: A system for treating ballast water in ballast tanks onboard vessels and offshore constructions is provided. The system comprises one or more ballast tanks, a circulation pump capable of circulating or recirculating, via a tubing, ballast water from and to the one or more ballast tanks, a gas supply unit which is connected to the tubing on the delivery side of the recirculation pump in such a manner that gas, such as air and/or inert gas such as nitrogen and/or carbon dioxide can be supplied to the ballast water; and one or more nozzle heads that are functionally connected to the tubing and is/are arranged in one or more ballast tanks, said one or more nozzle heads comprising at least one nozzle for injection of the gas-containing water into the one or more ballast tanks, and a device configured for removing and/or killing live organisms in the ballast water.

Abstract: Disclosed are methods for controlling, mercury emissions, and more particularly, to methods for controlling mercury re-emissions from a wet flue gas desulfurizer used in a combustion process. A method of controlling mercury re-emission from a combustion process includes measuring either mercury concentration, oxidation-reduction, potential (ORP), and/or sulfide concentration within a scrubber liquor of a wet flue gas desulpherizer (wFGD); correlating the mercury concentration, ORP, and /or sulfide concentration with an amount of mercury re-emission additive required in the scrubber liquor to reduce and/or prevent mercury re-emission to a selected level; and adjusting the rate of addition of mercury re-emission additive into the scrubber liquor to attain the selected level of mercury re-emission.

Abstract: A device for treating a liquid has a chamber and a rotatable cavitation element arranged within the chamber. According to a first aspect, the chamber has a cross-section with different roundnesses in the region of the cavitation element. According to a second aspect, the substantially disk-shaped cavitation element has (preferably oblong) passage openings which have rounded inner walls.

Abstract: Embodiments of the invention provide a method and system for providing a regeneration stage in a water treatment system. The method can include entering a first air bleed state to allow pressurized, deoxygenated air to exit the water treatment system, entering a second air bleed state to equalize a first air pressure of remaining deoxygenated air inside the water treatment system with a second air pressure outside the water treatment system, entering a backwash state to expel remaining deoxygenated air and particulates from inside the water treatment system, and entering an air draw state to allow oxygenated air to enter the water treatment system.

Abstract: A stabilized mixed oxidant solution may be produced by flowing a starting solution (e.g., salt brine, hypochlorous acid, and/or sodium hypochlorite) through a flow-through electrochemical module including first and second passages separated by an ion permeable membrane while electric power is applied between an anode and cathode in electrical communication with the first and second passages, respectively. An initially acidic anolyte solution received from the first (anode) passage is stabilized by elevating pH to yield a stabilized mixed oxidant solution. Methods of using the mixed oxidant solution are further provided.

Abstract: Disclosed is an apparatus for mechanically treating a liquid composition contained in a pool, including: —a frame which supports a motor (2) out of the liquid composition, —a drive shaft (6) which is rotatably driven by the motor, —a centrifugal surface aerator (4) which is rotatably driven by the drive shaft in a first rotation direction, —a bottom mixer (8), which is rotatably driven by the drive shaft, in which the motor (2) can be driven in a second rotation direction, counter to the first rotation direction. The apparatus includes a device for activation/deactivation of the aerator, which device is capable of deactivating the aerator (4) in the second rotation direction of the drive shaft (6), so that the aerator is not to rotatably driven by the drive shaft (6), the aerator being inoperative on the liquid composition.

Abstract: Treatment of waste water from a biomass-to-liquid process, said process comprising producing synthesis gas from biomass and conversion of said synthesis gas into liquid hydrocarbons by a Fisher-Tropsch process. The waste waters obtained are purified in common with waste waters from another industrial process to which said biomass-to-liquid process is integrated, such as in forestry, power and/or heat generation, waste incineration or a process in a metal-, petrochemical and/or oil refining industry. The biomass-to-liquid. process and said another industrial process may have a common feed water process unit, a common cooling water process unit and a common waste water treatment unit. The waste water treatment process may comprise a biological purification process and said Fischer-Tropsch process may utilize a cobalt catalyst. An integrated factory comprising a biomass-to-liquid plant and another industrial facility in which both plants are connected to a common waste water treatment facility is also described.

Abstract: A portable system for extracting iodine from brine on-site is disclosed. The portable system includes a mobile platform containing a treatment unit for oxidizing iodine ions into elemental iodine, an adsorption unit capable of binding iodine, and may also have an electrolytic cell and/or a gas-liquid separator. The treatment unit and the adsorption unit may be located in the same or different portable operating devices. When transported to a field site containing natural gas wells, the natural gas wells provide a fluid stream containing natural gas and brine. The separators can separate the natural gas from the brine, and the brine is then run through the treatment unit and the adsorption unit to bind iodine present in the brine. The brine is then returned to the natural gas well. Upon saturation, the portable operating device is transported to a second location, where iodine is extracted from the adsorption unit.

Abstract: A process for treating waste includes reacting an organic feedstock in a reactor. The organic feedstock is part of a reaction mixture that includes a first oxidizing acid (e.g., sulfuric acid) and nitric acid. The weight ratio of solids in the organic feedstock to the total of the first oxidizing acid and the nitric acid is at least 0.2. The weight ratio of solids in the organic feedstock to the first oxidizing acid is at least 0.3. The weight ratio of solids in the organic feedstock to the nitric acid is at least 0.5.

Abstract: An apparatus is disclosed. The apparatus includes a bubble implosion reactor cavitation device. The bubble implosion reactor cavitation device includes a tube-shaped cylindrical body including an upstream, a distal end surface and a downstream, proximal end surface. The tube-shaped cylindrical body defines an axial passage that extends through the tube-shaped cylindrical body between the upstream, distal end surface and the downstream, proximal end surface. The apparatus also includes a bubble generator subassembly connected to the tube-shaped cylindrical body. The bubble generator subassembly is at least partially disposed within the axial passage defined by the tube-shaped cylindrical body. The apparatus also includes a retaining member connected to the tube-shaped cylindrical body for retaining the bubble generator subassembly within the axial passage defined by the tube-shaped cylindrical body.

Abstract: A method and system for control of a gas or chemical. In one embodiment, the system comprises a reactor for receipt of a fluid and the gas and/or chemical for dissolving, mixing, diffusing, or infusing the gas and/or chemical into the fluid, and a controller to control the flow of the fluid and the gas and/or chemical into the reactor. In some embodiments, the system may also monitor the operation of the system in accordance with predetermined operating conditions. In at least one embodiment, the system also comprises a gas/chemical generation system for generation of the gas and/or chemical to be introduced into the reactor.

Abstract: A hybrid chemical/mechanical water treatment plant and method employing rapid sulfur dioxide chemical disinfection and dewatering technology in conjunction with lime and oxidization/reduction agents to removal pharmaceuticals and personal care products from waters to meet operating constraints and environmental permitting restrictions and siting limitations for water treatment.

Abstract: A method for treating effluent containing dissolved or suspended solids includes directing the effluent containing dissolved or suspended solids to a reactor and oxidizing at least a portion of the dissolved or suspended solids in the reactor with an oxidizing agent. Oxidation is carried out at a temperature ranging between approximately 20° C. and approximately 350° C. and at a pressure ranging between approximately 1 bar and approximately 160 bar. A gaseous phase and a liquid phase form within the reactor during oxidation. The method includes separating the gaseous phase from the liquid phase and heating the effluent in the reactor with the heat produced from the oxidation of the dissolved or suspended solids.

Abstract: A method for reprocessing spent nuclear fuel from a light water reactor includes the step of reacting spent nuclear fuel in a voloxidation vessel with an oxidizing gas having nitrogen dioxide and oxygen for a period sufficient to generate a solid oxidation product of the spent nuclear fuel. The reacting step includes the step of reacting, in a first zone of the voloxidation vessel, spent nuclear fuel with the oxidizing gas at a temperature ranging from 200-450° C. to form an oxidized reaction product, and regenerating nitrogen dioxide, in a second zone of the voloxidation vessel, by reacting oxidizing gas comprising nitrogen monoxide and oxygen at a temperature ranging from 0-80° C. The first zone and the second zone can be separate. A voloxidation system is also disclosed.

Abstract: An apparatus and methods for measuring the concentration of an additive are disclosed. The apparatus comprises a treatment stream (1) and a dosing stream (2). An additive is added to the dosing stream using a metering device (3). In some embodiments, the dosing stream is mixed after adding the additive using a first mixing device (4). Downstream from the metering device and the mixing device, the concentration of the additive in the dosing stream is measured using a monitor flow cell (5). In some embodiments, the dosing stream and treatment stream are combined (6) and mixed using a second mixing device (7). The concentration of the additive in the treatment stream can be calculated as a function of the volumetric flow rate ratio of the dosing stream to the treatment stream and the measured concentration of the additive in the dosing stream.

Abstract: The invention is directed to processes for treating biosolids that result in high-value, nitrogen-containing, slow-release, organically-augmented inorganic fertilizer that are competitive with less valuable or more costly conventional commercially manufactured fertilizers. The process involves conditioning traditional waste-water biosolids and processing the conditioned biosolids continuously in a high throughput manufacturing facility. The exothermic design and closed loop control of the primary reaction vessel decreases significantly the amount of power necessary to run a manufacturing facility. The process utilizes green technologies to facilitate decreased waste and enhanced air quality standards over traditional processing plants. The fertilizer produced from recovered biosolid waste is safe and meets or exceeds the United States Environment Protection Agency (USEPA) Class A and Exceptional Quality standards and is not subject to restrictions or regulations.

Abstract: The present invention provides an apparatus for producing photocatalytic reaction water through a photocatalytic reaction, which can produce water containing a satisfactory amount of active oxygen species, can eliminate microorganisms, parasites or protozoa, shows high oxidizing ability for a prolonged period of time, can reduce the power requirements, is small in size, and is applicable to various devices. A photocatalyst is radiated with light emitted from a light source to produce active oxygen species, and the active oxygen species is diffused in water, whereby the water is provided with functions of the active oxygen species. An oxidation reaction with the water is utilized to perform at least one selected from the elimination of microorganisms, the elimination of parasites, and the elimination of protozoa.

Abstract: The present invention is directed to a method of oxidizing an organic compound present in soil, groundwater, process water or wastewater comprising contacting such organic compound with a persulfate and an organic acid selected from the group consisting of ascorbic acid, formic acid, oxalic acid, lactic acid and citric acid, wherein the molar ratio of such organic acid to persulfate is between 1:100 and 3:1.

Abstract: The present invention is directed to a method of oxidizing an organic compound present in soil, groundwater, process water or wastewater comprising contacting such organic compound with a persulfate and ferrous lactate.