Including Temperature Change Patents (Class 210/774)
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Patent number: 5501741Abstract: This is a procedure for purifying rinse solutions used in operations for the shaping of metal. In particular, it is a procedure for removing fatty acids from caustic wash solutions used to rinse metal parts containing various lubricants, particularly tallow lubricants.Type: GrantFiled: January 11, 1994Date of Patent: March 26, 1996Assignee: USS-POSCOInventor: Kelly R. McMahon
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Patent number: 5498339Abstract: A fluid mixture from which an unsaturated hydrocarbon has to be separated, is passed in the first stage at superatmospheric pressure to one side of a first semiselective gas separation membrane with a non-porous active layer, and a liquid complexing agent is passed along the other side of said first membrane, where said unsaturated hydrocarbon is bound through complexation in the interface of membrane and complexing agent. In the second stage said unsaturated hydrocarbon is dissociated from the complexing agent through temperature increase, the mixture of complexing agent and dissociated unsaturated preferably is passed at superatmospheric pressure to one side of a second semiselective membrane with a non-porous active layer and the unsaturated hydrocarbon migrates to the other side of the membrane and is discharged. Finally, the complexing agent is recycled.Type: GrantFiled: July 15, 1994Date of Patent: March 12, 1996Assignees: DSM N.V., Nederlandse Organisatie Voor Toegepast Natuurwetenschappelljk Onderzoek TnoInventors: Raimond J. M. Creusen, Everardus C. A. Hendriks, Jan H. Hanemaaijer
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Patent number: 5496923Abstract: A purification process of an aliphatic polyester prepared in the presence of a catalyst from a hydroxycarboxylic acid or a cyclic ester of a hydroxycarboxylic acid, or a combination of an aliphatic polyhydric alcohol with an aliphatic polybasic acid, or a mixture of these compounds, comprising deactivating the catalyst while maintaining the aliphatic polyester in a molten or dissolved state, or insolubilizing and separating the catalyst and successively removing low molecular compounds. The process can provide aliphatic polyester which has a low content of unreacted monomers and low molecular weight compounds and is excellent in heat resistance and weatherability.Type: GrantFiled: September 14, 1994Date of Patent: March 5, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Hiroshi Suizu, Masatoshi Takagi, Masanobu Ajioka, Akihiro Yamaguchi
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Patent number: 5487907Abstract: This invention generally provides a process and apparatus for the separation of oil or fat from food particles, carbohydrate matrices and crumbs in a continuous process, and for the reuse and/or recycling of the separated oil or fat. This invention more particularly provides an apparatus and a process in which the crumbs are mixed with hot water and agitated for a predetermined time, after which the agitated mixture is introduced into a non-turbulent container where the oil/fat, the water and the crumbs are allowed to stratify. Upon stratification, a high quality oil/fat separates and rises based on its relative buoyancy and can then be removed and reused. The water and the crumbs also separate by stratification and can also be similarly removed.Type: GrantFiled: October 14, 1994Date of Patent: January 30, 1996Inventors: David C. Drown, Karen Montez
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Patent number: 5484539Abstract: A process for filtering polymer melt which minimizes the generation of dead zones in the filter and provides uniform residence time and accurate temperature control. The process is carried out in an apparatus comprising a plurality of heat exchanger pipes, each enclosing a filter cartridge surrounded by an annular space which terminates at its upper end in a plurality of narrow channels. The molten polymer is charged into the annular space and divided into primary and secondary streams. The primary stream flows through the filter cartridge and the secondary stream, which constitutes 0.03 to 3.0 weight percent of the weight of the combined streams, flows through the narrow channels, whereupon the streams are combined and discharged from the apparatus. The discharge temperature of the polymer is maintained within .+-.1.degree. C. of the charging temperature and the heat exchanger fluid enters the apparatus at a temperature within 1.degree. and 5.degree.C. of the temperature of the melt.Type: GrantFiled: March 30, 1995Date of Patent: January 16, 1996Assignee: Zimmer AktiengesellschaftInventors: Paul Tersi, Wolfgang Briegel, Dieter Cermak, Michael Schulze
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Patent number: 5482633Abstract: This invention provides for the separation of higher melting glycerides from vegetable oils. After the vegetable oil is refined and bleached, it is rapidly cooled to provide a blend that contains the vegetable oil and wax particulate; the blend then is filtered through a nonmetallic inorganic filter to remove the wax particulate from the vegetable oil such that the permeate oil has less than about 10 ppm oil at about 65.degree. F.Type: GrantFiled: October 12, 1993Date of Patent: January 9, 1996Assignee: Cargill, IncorporatedInventors: Harapanahalli S. Muraldihara, Bassam F. Jirjis, Gary F. Seymour
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Patent number: 5472612Abstract: A supercritical fluid extraction system and method for extracting a sample from a matrix by use of supercritical fluid and collecting components of the matrix in a solid phase extraction collection column. This system includes a variable restriction valve for depressurizing the fluid with entrained sample and an integral adapter directly connected at a first end with the valve and directly sealingly engaging the collector column and having a second end for passage of the depressurized fluid and sample with matrix components into the collector column.Type: GrantFiled: August 16, 1993Date of Patent: December 5, 1995Assignee: The United States of America as represented by the Secretary of AgricultureInventor: Robert J. Maxwell
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Patent number: 5470481Abstract: A method and apparatus for recovering wash water from effluent generated by a pulp and paper mill. The method includes filtering at least a portion of the effluent to form a filtrate stream and an organic solids feed stream. The organic solids feed stream is exposed to a temperature and a pressure which are supercritical for water to cause a substantial portion of the organic component to oxidize and form a product stream that, when cooled, includes a gaseous component, an inorganic solids component, and a liquid wash water component. The wash water component is separated from the gaseous and inorganic solids components, thereby recovering wash water.Type: GrantFiled: October 13, 1993Date of Patent: November 28, 1995Assignee: Modell Environmental CorporationInventors: Michael Modell, Edward G. Hauptmann, Stuart A. Gairns
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Patent number: 5468395Abstract: Process and apparatus for demineralizing water include a fibrous microporous body having interfiber spaces in communication with one another and a porosity at least equal to 50%, water supply elements for supplying water to be demineralized through the fibrous microporous body, a heating device adapted to heat the fibrous microporous body to a temperature of at least 60.degree. C., and elements adapted to collect the demineralized water.Type: GrantFiled: February 24, 1993Date of Patent: November 21, 1995Assignee: C.O.G.I.A. Societe AnonymeInventors: Didier Carron, Philippe Deblay, Robert Desage
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Patent number: 5466379Abstract: Oil and oil products are adsorbed with a three-dimensional lattice structure formed by coating individual glass fibers, assembling them and drying them at a temperature of about 150.degree. C. so that the structure will have; sufficient capillarity to pick up substantial amounts of oil and yet the mat will have sufficient structural stability to be stable. The coating is formed by a mixture of hydrophobizing silicone oil and starch (94 to 96% by weight starch to 6 to 4% by weight silicone). The latticework of the fibers and baked silicone oil/starch mixture can be used to pick up oil on a surface and recover oil from the latticework before the latticework is ultimately destroyed in a garbage incinerator.Type: GrantFiled: December 13, 1993Date of Patent: November 14, 1995Inventor: Helmut Schiwek
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Patent number: 5466383Abstract: A process and apparatus for treating dried sludge comprising organic material, inorganic material and heavy mertals. The process comprises indirectly heating the sludge in the absence of oxygen to a temperature of from 300.degree. to 550.degree. C. for volatilization of organic material and heating the residual char in the absence of oxygen to a temperature of from 750.degree. C. to 1000.degree. C. together with injecting steam for gasifying non volatile organic carbons in theresidual char, whereby the organic material in the sluge is converted into energy-containing products. The heavy metals remain in the ash as metal-sulfide complexes which are not soluble in acdidic water.Type: GrantFiled: January 6, 1994Date of Patent: November 14, 1995Assignee: Samsung Engineering & Construction Co., Ltd.Inventor: Kunmo Lee
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Patent number: 5464540Abstract: There is described a process for the removal of at least one component of a liquid mixture, the basic process comprising directing a liquid mixture against the feed side of a membrane, directing a condensable vapor sweep stream past the permeate side of the membrane in a manner such that the flow of the condensable vapor sweep is substantially countercurrent to the flow of the liquid mixture, thereby transporting at least a portion of at least one component of the liquid mixture from the feed side to the permeate side of the membrane to form a combined permeate side mixture of condensable vapor and at least one transported component.Type: GrantFiled: December 9, 1993Date of Patent: November 7, 1995Assignee: Bend Research, Inc.Inventors: Dwayne T. Friesen, David D. Newbold, Scott B. McCray, Roderick J. Ray
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Patent number: 5462973Abstract: A method for separating co-mingled polymeric materials, in particular polyethylene terephthalate (PET) and polyvinyl chloride (PVC) is described. The process involves selectively dissolving a supercritical fluid into one of the materials at the appropriate temperature and pressure. Upon rapid reduction of the system pressure, the selected material foams providing a change in density. Under ambient conditions, the polymeric materials having a large density difference can be separated by means of aqueous separation and flotation. The preferred supercritical fluid for the process is carbon dioxide, and PVC is the material into which the supercritical fluid is preferentially dissolved.Type: GrantFiled: July 13, 1994Date of Patent: October 31, 1995Assignee: Hoechst Celanese CorporationInventors: George A. Serad, Theodore S. Thornburg
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Patent number: 5462676Abstract: A system and process for treating solid and liquid wastes, where the solid waste is separated from the liquid waste in a chamber, the liquid waste is passed out of the chamber, the solid waste is converted to ash, a fluid such as liquid waste is introduced into the chamber and combined with the ash, and the ash and fluid are exhausted out of the chamber together. Preferably, the system includes the use of hot air to agitate the solids during their conversion to ash. Desirably, the system also includes a filter and means to swirl the liquid waste as it exits the chamber, so that the liquid waste evenly distributes the solid waste within the filter as the liquid waste is exhausted.Type: GrantFiled: June 28, 1993Date of Patent: October 31, 1995Assignee: Envirowaste Systems, Inc.Inventor: John Pitts
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Patent number: 5454878Abstract: A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).Type: GrantFiled: February 17, 1994Date of Patent: October 3, 1995Assignee: Lockheed Idaho Technologies CompanyInventors: Gregory A. Bala, Charles P. Thomas
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Patent number: 5447642Abstract: A process for the recycling of used and contaminated water-based metalworking fluids comprising separation of solid contaminants by settling and filtration, and separation of unemulsifiable tramp oil, reduction in total dissolved solids, removal of destructive bacteria and fungi, and removal of odors and toxic gases by the injection of steam, said process not requiring the use of a centrifuge.Type: GrantFiled: December 12, 1994Date of Patent: September 5, 1995Inventor: Thomas A. Schenach
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Patent number: 5437791Abstract: Process water from pulp manufacture is purified in a separator device by mechanical or a combination of mechanical and chemical methods and is thereafter evaporated, at least part of the concentrate resulting from the evaporation being recycled and mixed with the process water fed into the separator device. In a preferred embodiment, a precipitant is added to the mixed water comprising the process water and the concentrate. The part of the concentrate not recycled and mixed with the process water is supplied, optionally after further evaporation, with an acid to a pH of 1-5, whereupon resulting flocs and precipitates are removed in a separator device.Type: GrantFiled: February 2, 1994Date of Patent: August 1, 1995Assignee: Eka Nobel ABInventors: Gunnar Goransson, Birgitta Sundblad, Johan Landfors, Hans A. Baltsen
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Patent number: 5435920Abstract: A process is disclosed for cleaving spent emulsions such as cooling lubricants by means of carbon dioxide under pressure, and if necessary, heat in an economic and environment-friendly manner. The emulsion of cooling lubricant is saturated under pressure with carbon dioxide and is heated and/or cooled until cleavage is achieved. Above the cleavage temperature, a floating, water-poor oil phase quickly forms above an oil-poor aqueous phase.Type: GrantFiled: September 10, 1993Date of Patent: July 25, 1995Inventor: Elfie Penth
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Patent number: 5435923Abstract: A process for the production of a durable granular or pelletized sludge product is disclosed whereby a minimal amount of high calcium oxide material is utilized for pathogenic stabilization, a portion of the resulting hot mixture being recycled back to the mixing stage to reduce the requisite lime consumption by utilizing unreacted lime, for energy recovery and to increase dryness.Type: GrantFiled: November 5, 1993Date of Patent: July 25, 1995Assignee: Bio Gro Systems, Inc.Inventor: Mark Girovich
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Patent number: 5431826Abstract: An automatic grease interceptor for separating grease, fats and oils from wastewater is disclosed. The interceptor includes an interceptor chamber having an inlet, an outlet chamber with an outlet and a removable baffle positioned within the interceptor chamber. A grease removal device is attached to the interceptor chamber for removing accumulated grease from the interceptor chamber. A grease level sensor is positioned within the interceptor chamber at a first threshold level, wherein an indication of grease at the first threshold level by the first grease level sensor will activate the grease removal mechanism to thereby automatically remove grease from the interceptor chamber.Type: GrantFiled: March 19, 1993Date of Patent: July 11, 1995Assignee: Zurn Industries, Inc.Inventors: Allen R. Becker, David L. Lawson, Brian N. Creager
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Patent number: 5425883Abstract: The method of separating impurities from an aqueous solution by means of rotating tile aqueous solution at high speeds until a high pressure and a high temperature is reached. At that time the impurities are separated from the solution. The aqueous solution is kept at high temperatures and pressures until the impurities are separated from the liquid. Preferably, a device providing a centrifugal force, such as a centrifuge, is used to achieve the high temperatures and pressures which should preferably be no lower than 705.4.degree. F. and 3,208 psi, respectively.Type: GrantFiled: February 10, 1993Date of Patent: June 20, 1995Inventors: Allen F. Reid, Albert H. Halff
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Patent number: 5425884Abstract: A method has been discovered for recovering polyoxyalkylene glycols from wastewater. A skimming surface is heated to a temperature above the cloud point. The heated surface is contacted with the wastewater, causing the polymer to deposit. Deposited polymer skimmed from the surface is recovered. Heating, or other processing of the bulk wastewater is avoided.Type: GrantFiled: April 21, 1994Date of Patent: June 20, 1995Assignee: Texaco Inc.Inventor: Frank K. Botz
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Patent number: 5423992Abstract: A chemically disinfected sewage sludge-containing material comprising (1) an aqueous slurry of sewage sludge-containing material having a solids content in the range of about 10 to 30 wt. %; and (2) a chemical disinfectant comprising a water soluble silicate of sodium in the amount of 5 to 20 wt. % (basis dry wt. of said sewage sludge). In one embodiment, a pumpable chemically disinfected sewage sludge-containing material was produced by the steps of (1) dewatering sewage sludge to produce an aqueous slurry having a solids content of about 10 to 30 wt. %; (2) shearing the dewatered sewage sludge from (1) at a temperature in the range of about ambient to 230.degree. F. and at a shear rate of at least 30 per second for a period in the range of about 0.5 to 180 minutes; and (3) mixing the following materials together at a temperature in the range of about ambient to 230.degree. F. to produce a pumpable aqueous slurry having a solids content in the range of about 30 to 65 wt.Type: GrantFiled: May 20, 1991Date of Patent: June 13, 1995Assignee: Texaco Inc.Inventors: Matthew A. McMahon, Mitri S. Najjar, Peter D. Robison, Ronald J. McKeon
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Patent number: 5421998Abstract: A system for effective utilization of reaction heat and in situ separation of solid and gaseous products in wet oxidation of waste and wastewater. This invention does not require special preheaters for preheating feed streams, therefore reducing the possibility of scale and char formation in the heat exchange zone. The cold feed stream is introduced into the reactor with part of the effluent which has been recycled through a high temperature pumping means to form a hot, near critical oxidant-containing mixture. The cold feed is directly heated up by the oxidant-containing mixture. The reaction mixture is separated by in situ crossflow filtration elements, including sintered material. Catalyzed reactions and sintered material gas separation are also described.Type: GrantFiled: February 4, 1994Date of Patent: June 6, 1995Assignee: Board of Regents, The University of Texas SystemInventors: Lixiong Li, Earnest F. Gloyna
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Patent number: 5405579Abstract: For the thermal treatment of contaminated soils, excavated soil is heated by indirect heat exchange up to 650.degree. C. in a rotary drum in the absence of oxygen. Pollutants are separated from the soil by a desorption medium. Moisture in the soil vaporized to steam can serve as the desorption medium. The resultant gaseous pollutant stream is condensed, and the pollutants are separated.Type: GrantFiled: July 22, 1992Date of Patent: April 11, 1995Assignee: Linde AktiengesellschaftInventors: Reiner Melzer, Klaus Mikulla
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Patent number: 5403494Abstract: An improved process is provided for the steam conversion of dilute printer ink washup fluids, and especially those of a single color, in order to permit reuse of the ink fraction of the fluids as reconstituted printing inks. Preferably, the washup fluids are acidified to create a pin floc therein, with a final pH of from about 2-7; the acidified fluid is then contacted with a stream of steam in a hydroheater (16) in order to convert the residual ink fraction and permit reconstitution thereof into printing ink. The acidifying agent is preferably an acid polymer or an inorganic acid such as HCl or H.sub.2 SO.sub.4.Type: GrantFiled: July 15, 1993Date of Patent: April 4, 1995Assignee: The Lawrence Paper CompanyInventor: Michael D. Cain
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Patent number: 5401414Abstract: A process isolates, in a closed circulation, the soluble fluid carried over into a rinsing bath from said rinsing bath and to return the fluid into the upstream bath. To this end, enrichment by separating the soluble fluid from the rinsing bath is provided, the enriched fluid, which has been carried over, is returned into the upstream bath together with solvent, where the solvent is separated out with the use of a membrane.Type: GrantFiled: July 21, 1993Date of Patent: March 28, 1995Assignee: Dr. O.K. Wack Chemie GmbHInventors: Oskar K. Wack, Martin Hanek
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Patent number: 5391304Abstract: A method for purifying a hydrocarbon fluid comprising residual hydrocarbons or a blend of residual hydrocarbons with distilled hydrocarbons, to be used as fuel for a diesel engine or a gas turbine, the hydrocarbon fluid containing contaminants colloidally dispersed as stable micelles, the method comprising the following steps, in sequence: (a) disrupting colloidal structure of the micelles by heating the hydrocarbon fluid under pressure to a temperature of at least 110.degree. C.Type: GrantFiled: September 2, 1992Date of Patent: February 21, 1995Inventor: Federico E. Lantos
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Patent number: 5389266Abstract: A method for killing zebra mussels from a bottom surface of a waterway and from the surfaces of watercraft, docks, pilings and similar facilities located within a waterway. The surfaces to be treated are isolated in a batch of water enclosed within a chamber. The isolated batch of water is thereafter heated to a temperature lethal to the zebra mussels and held at that temperature for a sufficient time to kill the zebra mussels. The isolated batch of water and the treated surface are thereafter released from the chamber and the isolated state.Type: GrantFiled: January 11, 1994Date of Patent: February 14, 1995Assignee: Dixstar, Inc.Inventors: David N. Clum, Frederick Krosner, Jewel R. Leak, Jr.
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Patent number: 5384051Abstract: The invention relates to an improved apparatus and method for initiating and sustaining an oxidation reaction. A fuel, such as natural gas or hazardous waste, is introduced into a reaction zone within a pressurized containment vessel. A permeable liner is placed within the containment vessel and around the reaction zone. An oxidizer, preferably oxygen, is mixed with a carrier fluid, such as water, and the mixture is heated and pressurized to supercritical conditions of temperature and pressure. The supercritical oxidizer-carrier mix is introduced to the reaction zone gradually and uniformly, over a comparatively large area, by forcing it radially inward through the permeable liner and toward the reaction zone. A means and method for cooling the exhausted by-products and using them as a cleansing rinse are disclosed.Type: GrantFiled: February 5, 1993Date of Patent: January 24, 1995Inventor: Thomas G. McGinness
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Patent number: 5374337Abstract: A halohydrocarbon solvent recovery process. The process in one embodiment includes heating a gross mixture including solvent, fatty-acid impurities and water in a bath to vaporize at least a portion of the solvent and the impurities. A portion of the vapor is then condensed in a reflux condenser to form a condensate mixture. After drying and impurity absorption, a solvent product of at least 99% purity may be recovered. In one embodiment, the gross mixture is obtained from steam stripping dry-cleaner filter cartridges.Type: GrantFiled: August 20, 1993Date of Patent: December 20, 1994Assignee: Technichem Engineering, Ltd.Inventors: Mark J. Ng, Bruce T. Maeda
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Patent number: 5372725Abstract: A mechanism for converting impurities or contaminants in a fluid to a non-hazardous or less hazardous condition by raising the fluid to a supercritical state. This is accomplished by a rotatable mechanism having a reaction chamber adapted to receive the fluid and by rotating the rotatable mechanism at a high speed and by heating the fluid to cause the temperature and pressure of the fluid in the reaction chamber to reach the supercritical state.Type: GrantFiled: December 24, 1992Date of Patent: December 13, 1994Inventors: Albert H. Halff, Allen F. Reid
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Patent number: 5372724Abstract: A process for removing toxic sulfur-containing compounds, ammonia, oil and grease from an aqueous solution wherein the steps include sequentially adding to the solution sufficiently effective amounts of ferrous sulfate, ferric sulfate, and an insoluble hydrophilic amine polymer; heating the solution; removing the oil and grease as volatile organic compounds; and removing the contaminants from the solution as a precipitate complex. The resulting purified effluent may then be directly discharged into an industrial sewer.Type: GrantFiled: September 30, 1993Date of Patent: December 13, 1994Assignee: ECO Asphalt, Inc., a Calif. Corp.Inventor: Saeed Ahmed
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Patent number: 5360553Abstract: This disclosure relates to a processor comprising means for mixing a process material with a process liquid (such as water) and forming an emulsion or slurry. Means is provided for pressuring and heating the slurry, and the slurry is then fed to means for quickly reducing the pressure to a relatively low value and further increasing the temperature. The rapid drop in pressure and increase in temperature causes components of the slurry to convert to volatile gases and separate from the remainder of the slurry which is removed from the processor in the form of solids. The gas is fed to one or more condensers which separate the gas into useful liquids such as various grades of oil.Type: GrantFiled: August 20, 1993Date of Patent: November 1, 1994Inventor: Paul T. Baskis
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Patent number: 5360554Abstract: A solute can be separated from a solute/solvent solution by dissolving a gas-forming material into said solution and then adjusting the temperature, pressure and solute concentration of the resulting solution such that a Joule-Thompson free expansion of the gas-forming material released from the solution will produce a three-phase separation of the components of said solution.Type: GrantFiled: February 7, 1994Date of Patent: November 1, 1994Assignee: Parhelion, Inc.Inventors: Jack C. Sloan, Walter Lurie, Adrian C. Ferramosca
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Patent number: 5356540Abstract: A pumpable aqueous slurry of sewage sludge as produced by the steps of (1) dewatering sewage sludge to produce an aqueous slurry having a solids content of about 10 to 25 wt. %; (2) pretreating said aqueous slurry of sewage sludge to improve its slurrying characteristics by one or a combination of (a) heating, (b) hydrothermal treatment, and (c) heating, mixing and shearing; and (3) mixing the following materials together at a temperature in the range of about ambient to 400.degree. F. to produce a pumpable aqueous slurry having a solids content in the range of about 30 to 65 wt. %: (a) pretreated aqueous slurry of sewage sludge; (b) a nonionic water soluble alkoxylated alkylphenol additive; and (c) sewage sludge-containing material and/or solid carbonaceous fuel-containing material to increase the solids loading.Type: GrantFiled: May 20, 1991Date of Patent: October 18, 1994Assignee: Texaco Inc.Inventors: Motasimur R. Khan, Christine C. Albert
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Patent number: 5352250Abstract: The invention relates to a process for treating (recycling) lacquer coagulum containing lacquer overspray and layered silicate containing coagulating agents, in which the layered silicate containing paint coagulum is vacuum dried, processed at low temperatures and then ground, and to the use of the processed paint coagulum as a basic component, additive, or filler in lacquers and paints, building materials, sealing materials, car underseal compositions or adhesives.Type: GrantFiled: April 30, 1993Date of Patent: October 4, 1994Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Juergen Geke, Lutz Huesemann, Hans-Joergen Rehm
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Patent number: 5344573Abstract: A method for recovery of printing ink wastes is provided which greatly minimizes pollution problems attendant to the disposal of ink wastes, while permitting formulation of usable ink products from the wastes. The method involves first creating a flowable stream of material including the ink wastes, and directing this stream to a hydroheater (16) along with incoming steam. In the hydroheater (16), the ink wastes are subjected to elevated temperatures and pressures, and intense shear, creating a homogeneous, flowable output. This output may then be dried and powdered, and the powder may be reconstituted as a black ink suitable for commercial printing operations. If desired, the hydroheater (16) output may be treated in a filter press (252) to obtain a filter cake (258), and this cake (258) may be subsequently subdivided and treated with ink carriers to form a processing ink.Type: GrantFiled: March 19, 1993Date of Patent: September 6, 1994Assignee: Lawrence Paper CompanyInventors: Alan M. Hill, Michael D. Cain, Donald D. Cain
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Patent number: 5328353Abstract: Oil pollution floating on a body of water is abated or contained by a fire fence generated by a series of devices which are interconnected by cables and anchored to form a barrier line. Each device comprises a buoy connected to a depending, negatively-buoyant tank of pressurized combustion gas and a burner nozzle disposed for providing a pilot flame near the water's surface to ignite an oil slick thereon. The pilot flame Way be controlled to sustain combustion of the floating oil and dissipation of same.Type: GrantFiled: March 18, 1993Date of Patent: July 12, 1994Assignee: Atlantic Richfield CompanyInventor: Alexander J. Keenan
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Patent number: 5318708Abstract: The local reclamation system includes an accumulation tank for a soiled solution. A tank outlet valve selectively allows a flow of the solid soiled solution into the remainder of the system. A blend conduit leads from the outlet valve. An oxidizing supply selectively provides an oxidizing agent to said soiled solution downstream of the outlet valve in the blend conduit. A blend pump receives the soiled solution with oxidizing agent to promote the flow of the soiled solution through the system and a more uniformed disposal of the oxidizing agent throughout the solution. A six stage filter section selectively removes particulate matter. A biologic stage promotes a sterile reclaimed solution and a solution accumulator accumulates and stores the solution. Repeated injections of oxidizing agents occur before filter stage sections and pumps. The reclaimed solution can be reused or discharged without penalty.Type: GrantFiled: August 20, 1993Date of Patent: June 7, 1994Inventors: Charles O. Benskin, Harley A. Weisse
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Patent number: 5306433Abstract: An improved solvent dewaxing process in which a method and apparatus for continuous hot wash of a dewaxing filter is disclosed. A hot wash solvent is continuously sprayed below the doctor blade followed by a cold solvent spray below the hot solvent spray. Additionally, a solvent management process for changing the proportions of the solvent in response to different viscosity feedstocks thereby increasing filtration efficiency is also disclosed.Type: GrantFiled: December 7, 1992Date of Patent: April 26, 1994Assignee: Mobil Oil CorporationInventor: Lyle A. Leach
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Patent number: 5302300Abstract: An apparatus removes water from a liquid mixture which has formed in a compressed gas system. The apparatus includes a gas compressor having an inlet port for receiving low pressure gas to be compressed and a discharge port through which a stream of compressed gas flows. An aftercooler is disposed in fluid communication with the discharge port for cooling the compressed gas stream. A vessel collects any entrained liquid water and lubricant from the compressed gas stream. The vessel has a sump portion and a vent to an atmosphere external to the compressed air system. A heat exchanger heats the liquid mixture within the vessel to a predetermined temperature to vaporize the water. The water vapor exits the vessel through the vent and the lubricant remains in the sump portion of the vessel. A valve permits the separated lubricant to be drained from the sump portion of the vessel to a location external to the compressed air system.Type: GrantFiled: April 5, 1993Date of Patent: April 12, 1994Assignee: Ingersoll-Rand CompanyInventor: Richard E. Porri
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Patent number: 5294351Abstract: A method and apparatus for controlling zebra mussels in the inlet cell of a utility power plant by isolating a batch of water in the cell from the water supply of a lake or river and the equipment plant by shutting an inlet gate and shutting outlet valves from said cell. The batch of isolated water is thereafter heated to a lethal temperature which is maintained for a sufficient period of time to ensure 100 percent mortality to the zebra mussels within the cell. The water may be maintained in a static condition and heated by a heat exchanger disposed within the cell. Alternatively the water may be fed to a heat exchanger, heated outside the cell, and returned to the cell. The water is heated to a range of approximately 95.degree. F. to 100.degree. F. and held at the heated temperature within the cell for approximately 30 minutes.Type: GrantFiled: March 25, 1993Date of Patent: March 15, 1994Assignee: First Thermal Systems, Inc.Inventors: David N. Clum, Frederick Krosner, Jewel R. Leak, Jr.
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Patent number: 5292442Abstract: A process for disposing of sanitary sewage sludge by producing a pumpable slurry of sewage sludge with or without solid carbonaceous fuel and burning said slurry as fuel in a partial oxidation gas generator, furnace, or boiler. The aqueous slurry of sewage sludge is concentrated by removing water by means of a conventional belt filter press, centrifuge, or hydroclone. The dewatered slurry of sewage sludge is heated by direct contact with steam while air and organic vapors are simultaneously removed, to reduce the pressure in the system; hydrothermally treated in two steps with indirect and direct heat exchange with steam; dewatered by flash evaporation and centrifuging; and burned with or without admixture with solid carbonaceous fuel in a partial oxidation gasifier, furnace, boiler, or incinerator to produce synthesis gas or a hot raw effluent gas stream. In a preferred embodiment, the effluent gas stream is cleaned and purified and non-contaminating ash and slag are separated.Type: GrantFiled: October 1, 1992Date of Patent: March 8, 1994Assignee: Texaco Inc.Inventors: Motasimur R. Khan, Harvey D. Schindler, Christine C. Albert, Stephan J. DeCanio
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Patent number: 5288408Abstract: The subject invention relates generally to a novel method of recycling gelatin-based encapsulation waste material and, more specifically, to a process for the recovery and purification of gelatin and softening agents therefrom. In the preferred embodiment, deionized water is added to the waste material thereby forming an aqueous solution of gelatin and glycerine dispersed within the remaining oil and residual active-ingredient components of the waste material. Extraction methods are employed under specific conditions to effect separation of the bottom aqueous phase from the upper oil phase. The lower phase is hot filtered to remove any remaining traces of oil or other contaminants and the filtrate is then charged to a concentration vessel adapted for vacuum distillation. The water solvent is thus removed under specific thermal and atmospheric conditions until the desired concentration of gelatin and glycerine is achieved.Type: GrantFiled: October 26, 1992Date of Patent: February 22, 1994Assignee: Chemical Industry Consultants, Inc.Inventors: William J. Schmidt, Michael F. Smith, James W. Neal III
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Patent number: 5288413Abstract: A waste sludge that contains water, oil and solids is subjected to filtration under vacuum or an applied inert gas pressure, preferably no more than 50 psia while utilizing a filter aid, to retain the maximum amount of oil in the filter cake. The filter cake is then dried at a relatively low temperature, slightly above the boiling point of water, to selectively remove water and produce a high heating value non-sticking solid. The product thus obtained in suitable for use as a solid fuel for a cement kiln or other combustion facilities. Depending on the amount of oil present in the original sludge, the applied pressure can be varied to retain different amounts of oil and to produce different heating values desired in the final solid fuel.Type: GrantFiled: May 22, 1992Date of Patent: February 22, 1994Assignee: Shell Oil CompanyInventor: Humbert H. Chu
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Patent number: 5284589Abstract: The process for the working-up of effluents and disposal of the loads, present therein, by a combination of concentration by membrane filtration, evaporation and gas phase oxidation, is particularly viable economically because the concentrates to be incinerated have a very low salt content.Type: GrantFiled: September 2, 1992Date of Patent: February 8, 1994Assignee: Bayer AktiengesellschaftInventors: Dietrich Tegtmeyer, Friedrich-Wilhelm Baumann, Gunter Stephan
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Patent number: 5282979Abstract: A desalination system includes a transfer conduit between a pool of salt water and a pool of desalinated water. The conduit is initially filled with water and is then elevated so that a portion of the conduit is above the syphon height of water at atmospheric pressure with the open ends of the conduit submerged below the respective pools. Using solar heat to create a temperature differential in the conduit, desalinated water vapor is transferred across a partial vacuum volume formed in the conduit.Type: GrantFiled: September 30, 1992Date of Patent: February 1, 1994Inventor: Henry A. Wilson
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Patent number: 5269906Abstract: Commercially valuable oil is recovered from refinery-produced, Resource Conservation and Recovery Act classified, hazardous waste oil sludges by a series of volatilizing and condensing steps (which may vary depending on the oil, water, and solids content of the sludge) resulting in the production of nonhazardous water and solid waste byproducts. A pumpable, low viscosity, high oil- and/or water-content sludge is first centrifuged to separate free oil and water. If the waste sludges are acidic or if nickel is present in the sludges in sufficient quantities so as to result in unacceptable levels in the TCLP leach filtrate, a base (such as calcium oxide) is admixed with the thick waste oil sludge, centrifuge solids, or other sludges low in oil and/or water content to render the sludges basic. The basic, admixed sludges are heated to volatilize the contained water and oil. Dry, friable, deoiled solids are recycled with the oily sludge feed to prevent material agglomeration and heat exchanger fouling.Type: GrantFiled: November 13, 1990Date of Patent: December 14, 1993Inventors: Victor R. Reynolds, Steven R. Heuer
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Patent number: 5269947Abstract: This disclosure relates to a processor comprising means for mixing a process material with a process liquid (such as water) and forming an emulsion or slurry. Means is provided for pressuring and heating the slurry, and the slurry is then fed to means for quickly reducing the pressure to a relatively low value and further increasing the temperature. The rapid drop in pressure and increase in temperature causes volatile components of the slurry to convert to a gas and separate from the remainder of the slurry which is removed from the processor in the form of solids. The gas is fed to one or more condensers which separate the gas into useful liquids such as various grades of oil.Type: GrantFiled: September 17, 1992Date of Patent: December 14, 1993Inventor: Paul T. Baskis