Abstract: The present disclosure provides a curing agent comprising a polyetheramine, a tertiary amine substantially free of an aromatic tertiary amine and glycerin. The curing agent may be combined with an epoxy resin to form a curable composition which is capable of being applied to a substrate and cured to form a cured article.

Abstract: The present disclosure provides a curing agent comprising a polyetheramine, a tertiary amine and an alkanolamine. The curing agent may be combined with an epoxy resin to form a curable composition which is capable of being applied to a substrate and cured to form a cured article.

Abstract: Provided are: a resin additive composition containing a specific metal phosphate, which composition has excellent dispersibility in a resin even when made into a pellet form and exhibits a desired physical property improving effect when incorporated into a resin; and a synthetic resin composition using the same. The resin additive composition contains, with respect to 100 parts by mass of (A) sodium-2,2?-methylene-bis(4,6-di-tert-butylphenyl)phosphate: 25 to 400 parts by mass of (B) a lithium phosphate compound represented by the following Formula (1); and 10 to 300 parts by mass of (C) a fatty acid metal salt represented by the following Formula (2). The component (C) is incorporated in an amount of 10 parts by mass to 50 parts by mass with respect to a total of 100 parts by mass of the components (A) and (B).

Abstract: The present invention relates to polyaspartic acid ester compositions which contain polyaspartic acid esters with primary amino groups and small amounts of fumaric acid dialkyl esters, to a method for preparing same and the use thereof as a reactive component for polyisocyanates in two-component polyurethane systems.

Abstract: A curable composition includes a reaction product of an isocyanate component that includes one or more isocyanates, at an isocyanate index being from 90 to 150, and an isocyanate reactive component that includes a blend including from 5 wt % to 95 wt % of a first butylene oxide based polyol and from 5 wt % to 95 wt % of a second butylene oxide based polyol. The first butylene oxide based polyol has a number average molecular weight from 200 g/mol to 1,000 g/mol and a nominal hydroxyl functionality from 2 to 6. The second butylene oxide based polyol has a number average molecular weight greater than 1,000 g/mol and less than 8,000 g/mol and a nominal hydroxyl functionality from 2 to 4. The blend accounts for at least 50 wt % of a total weight of polyols in the isocyanate-reactive component.

Abstract: Disclosed is a biosourced polymer obtained by dual chemical functionalization of chitosan, usable for catalytic carbonation of cyclic ethers by carbon dioxide, and a binder composition for creating layers and/or coatings for road construction and/or civil engineering, marking materials, or sealing or insulation materials. The composition contains a polyhydroxyurethane polymer binder resulting from the reaction of at least one polyamine with at least one polycyclocarbonate. The polycyclocarbonate was obtained by carbonating a (cyclic) poly(ether) with carbon dioxide catalyzed by the biosourced polymer.

Abstract: This disclosure provides a solvent-borne system for forming an n-acyl urea coating on a substrate. In one embodiment, the solvent-borne system comprises a polycarbodiimide-polyurethane hybrid. The solvent-borne system also comprises an acid functional polymer and an organic solvent, and comprises less than or equal to 10 weight percent of water based on a total weight of said solvent-borne system. The solvent-borne system also comprises less than about 100 parts by weight of toluene diisocyanate per one million parts by weight of the solvent-borne system.

Abstract: The invention relates to an improved process for making monomeric triglycidyl compounds, wherein the triglycidyl compounds include N, O-triglycidyl compounds containing at least one primary aromatic amine and one phenolic functional group attached to the same or a different aromatic ring. The methods of the present invention result in the production of N, O-triglycidyl compounds, such as those of formula I and II. The improved process is energy efficient, environment friendly, and results in increased yields of product. The methods of the present invention can be performed in the absence of protic organic co-solvents during the reaction of an epihalohydrin with an aminophenol, such as compounds of formula II and IV, which provides an intermediate halohydrin compound. The methods of the present invention may also be performed in the absence of a phase transfer catalyst.

Abstract: Process for the preparation of etherified melamine/formaldehyde condensates, in which first a methylolation of melamine with a formaldehyde component in the molar ratio of from 1:6 to 1:15, preferably at a pH of >7, is carried out. This is followed by an etherification of the resulting hydroxymethylation intermediate in the presence of a C1-C20-alkyl, preferably of a C1-C6-alcohol, particularly preferably of a C1-C4-alcohol, at a pH of <4.5, and subsequently by at least one distillation step in order to remove in particular methanol from the system, the pH of >9.5 being established before, during and/or after the distillation. According to the invention, a plurality of hydroxymethylation, etherification and distillation steps follow in order to achieve an etherified melamine/formaldehyde condensate which is distinguished by a high degree of hydroxymethylation, a high solids content and a low viscosity.

Abstract: There are provided a novel aromatic aldehyde compound capable of providing an epoxy resin coating film and an epoxy resin cured material satisfying all of the excellent surface property (smoothness, gloss), drying property, water resistance, transparency and adhesion, and an epoxy resin curing agent and an epoxy resin composition containing the aromatic aldehyde compound. The aromatic aldehyde has a branched alkyl group having 10 to 14 carbon atoms.

Abstract: The subject of the present invention is a process for preparing a precomposite based on nanotubes, comprising bringing said nanotubes into contact with at least one given plasticizing agent. It also relates to a precomposite thus obtained, and to its use for conferring at least one electrical, mechanical and/or thermal property on a polymer material. It also relates to the use of a given plasticizer for improving the dispersion and/or mechanical properties and/or electrical conductivity and/or thermal conductivity of nanotubes in a polymer matrix.

Abstract: The present disclosure provides a liquid curing agent composition comprising at least 50% by weight of a polyamine and 0.2% to 10% by weight of dicyandiamide, the amine/epoxy composition and the product from the cured amine/epoxy composition.

Abstract: The method for the preparation of epoxy-clay nanocomposites uses high shear mixing of Nanomer 1.30 E nanoclay into the diglycidyl ether of bisphenol A (DGEBA) epoxy by optimization of high shear mixing speeds, mixing times and degassing temperature. The results showed that the optimum high shear mixing speed and mixing time for optimal clay dispersion were 6000 rpm and 60 min, respectively. Increasing the degassing temperature from 65° C. to 100° C. for the first two hours of the degassing process enhanced nanoclay dispersion, resulting in nanocomposites with a morphology dominated by disorder intercalation with some exfoliated structure. This enhancement in nanocomposite morphology can be attributed to the improvement in epoxy diffusion into the intergallery spacing between clay layers due to temperature rise.

Abstract: The invention provides a ceramic green sheet having plasticity, punching property, and sinterability of satisfactory levels as well as a low percent (heat) shrinkage. In the production of a ceramic slurry serving as a raw material of the sheet, ingredients thereof are mixed under such conditions that the functional group ratio (polyol to isocyanate) is 1.5/11.5 to 11.5/11.5; the urethane resin formed from isocyanate and polyol has a repeating-unit-based molecular weight of 290 to 988; and the ratio by weight of the urethane resin to a ceramic powder falls within a range of 4.5 to 10 parts by weight of the urethane resin with respect to 100 parts by weight of the ceramic powder. A ceramic green sheet having, in well balance, all of the properties (i.e., plasticity, punching property, sinterability, and (heat) shrinkage) required for facilitating subsequent processes such as mechanical working and firing can be provided.

Abstract: The present invention relates to an alkoxysilylated epoxy compound, a composite exhibiting good heat resistance properties, low CTE and high glass transition temperature and not requiring a coupling agent, a composition including the same, a cured product formed of the composition, a use of the cured product, and a method of preparing the epoxy compound having alkoxysilyl group. An epoxy compound having an epoxy group and an alkoxysilyl group, a composition including the epoxy compound, a curing agent, a filler and/or a reaction catalyst, a cured product of the composition, and a use of the composition including an electronic part are provided. In a composite and/or cured product, the epoxy composition exhibits improved heat resistance properties, decreased CTE, and increased glass transition temperature or Tg-less. The cured product exhibits good flame retardant properties by the introduction of the alkoxysilyl group.

Abstract: Provided herein is technology relating to depositing and/or placing a macromolecule at a desired site for an assay and particularly, but not exclusively, to methods and systems for transporting a macromolecule such as a protein, a nucleic acid, or a protein:nucleic acid complex to an assay site, such as the bottom of a nanopore, a nanowell, or a zero mode waveguide.

Abstract: The invention provides a process for preparing esters from formates and olefinically unsaturated compounds with catalysts based on palladium compounds. In addition, the invention discloses a polyphasic reaction mixture and nonyl methyl ester mixtures prepared by the process according to the invention.

Abstract: A urethane adhesive composition includes a first liquid and a second liquid, the first liquid containing a prepolymer obtained by reacting a polyisocyanate and a high-molecular-weight polyol (I), and at least one filler selected from talc and calcium carbonate, and containing 20 parts by mass or more of talc, 0 to 40 parts by mass of calcium carbonate, and 10 parts by mass or more of zeolite based on 100 parts by mass of the polyisocyanate, the high-molecular-weight polyol (I), and the prepolymer in total, the second liquid containing a high-molecular-weight polyol (II) and a low-molecular-weight polyol, the ratio of the number of moles of hydroxyl groups derived from the low-molecular-weight polyol to the total number of moles of hydroxyl groups derived from the high-molecular-weight polyol (I) and the high-molecular-weight polyol (II) being four or more.

Abstract: The present invention provides Mannich base derivatives of N,N?-dimethyl secondary diamine polymers including Mannich base derivatives of methylamine-terminated poly-(N-methylazetidine) and Mannich base derivatives of methylamine-terminated poly-(N-methylazacycloheptane). Amine curing agent compositions and amine-epoxy compositions containing Mannich base derivatives of N,N?-dimethyl secondary diamine polymers are also disclosed.

Abstract: The present invention pertains to the field of thermosetting or thermoset polymers mainly used as materials, coatings or adhesives. The invention more specifically relates to the use of specific molecules having associative groups including a nitrogen heterocycle as a hardener or co-hardener of thermosetting polymers.

Abstract: A method for providing a secondary or tertiary amine with formula (R1R2NR3)2NR4 is provided, wherein each of R1 and R2 are chosen from the group consisting of a methyl group, an ethyl group, an iso-propyl group and an n-propyl group; R3 being an alkoxyalkyl group chosen from the group consisting of —CH2CH2OCH2CH2—, —CH2CH2OCH2CH2— and —CH2CH2CH2OCH2CH2CH2—; R4 is chosen from the group consisting of a hydrogen, a methyl group, an ethyl group, an iso-propyl group, an n-propyl group and a group with formula R1R2NR3. The method comprises the steps: (?) reacting R1R2NR3(OH) with ammonia, thereby providing a mixture comprising (R1R2NR3)2NR4; (?) separating (R1R2NR3)2NR4 from said mixture.

Abstract: A crosslinkable composition including a component A with at least 2 acidic protons C—H in activated methylene or methine groups (the RMA donor group), and a component B with at least 2 activated unsaturated groups (the RMA acceptor group), and a catalyst system C that contains, or is able to generate a basic catalyst capable of activating the RMA reaction between components A and B, characterised in that the cross-linkable composition further includes an X—H group containing component D that is also a Michael addition donor reactable with component B under the action of catalyst C, wherein X is N, P, O, S or wherein X is C as part of an acidic methyl (CH3) group. A component D and catalyst additive mixtures for the manufacture of RMA crosslinkable composition.

Abstract: The present invention relates to a polyimide resin surface modifier which modifies the surface of a polyimide resin to permit easy absorption of metal ions, and a surface-modifying method for polyimide resins using the same. The surface modifier contains an alkali component, an organic solvent having hydroxy groups and a boiling point of 120° C. or higher, and a water content of 0-10% by weight. The surface-modifying method includes a printing process wherein a predetermined pattern is printed on the surface of a polyimide resin substrate using the polyimide resin surface modifier, an organic solvent-removing process wherein an organic solvent in the polyimide resin surface modifier pattern-printed on the surface of said polyimide resin substrate is removed and a water-treatment process wherein said polyimide resin surface modifier after removing the organic solvent is brought into contact with water.

Abstract: A composition comprising: at least one conjugated polymer, at least one second polymer comprising repeat units represented by: (I) optionally, —[CH2—CH(Ph-OH)]— and (II) —[CH2—CH(Ph-OR)]— wherein Ph is a phenyl ring and R comprises a fluorinated group, an alkyl group, an alkylsulfonic acid group, an alkylene oxide group, or a combination thereof is described. Other polymers can be used as second polymer including polymers comprising modified naphthol side groups. The composition can be used in hole injection and hole transport layers for organic electronic devices. Increased lifetime and better processability can be achieved. Versatility with useful OLED emitters can be achieved. Ink formulations can be adapted for ink jet printing. The conjugated polymer can be a polythiophene. Applications include OLEDs and OPVs.

Abstract: A cyclic carbonate monomer including the reaction product of (a) a divinylarene dioxide, and (b) carbon dioxide; a process for making the cyclic carbonate monomer; and a polymer such as a poly(hydroxyurethane) composition made therefrom. The poly(hydroxyurethane) composition made from the above cyclic carbonate monomer forms a reactive intermediate that can be used for making, for example, a poly(hydroxyurethane) foam product.

Abstract: Provided is a hydroxyalkylated polyalkylene polyamine composition, and a method for preparing the composition at low cost. Further disclosed is a method for producing a polyurethane resin by using the hydroxyalkylated polyalkylene polyamine composition containing at least two hydroxyalkylated polyalkylene polyamines as defined herein.

Abstract: The present invention relates to stable, zero or low VOC epoxy-containing polysiloxane oligomer compositions that provide for a high degree of chemical resistance to compositions containing organic resins, while at the same time, maintaining or improving the flexibility of these organic resin-containing compositions, to processes for preparing epoxy-containing polysiloxane oligomer compositions, and to uses in coatings, sealants, adhesives, and composites containing the same.

Abstract: Process for the preparation of a composition comprising di-(tert-butylcyclohexyl) peroxydicarbonate comprising the steps of (a) preparing a pre-mix comprising di-(tert-butylcyclohexyl) peroxydicarbonate, one or more organic solvents, a hydrophilic silica, and apolyalkoxylated butyl ether, and (b) milling the pre-mix resulting from step (a).

Abstract: The present invention concerns a low-odor, low-viscosity hardener for epoxy resins comprising the amine of formula (I), as well as a method for thinning of hardeners for epoxy resins by adding the amine of formula (I). These hardeners harden with epoxy resins quickly and without blushing to form films of high hardness and little brittleness, even without non-incorporable thinners such as benzyl alcohol. They are especially suitable for low-emission coatings.

Abstract: An initiator for cationic polymerization comprises a salt of a protic acid as well as a protic add. The molar ratio of protic acid to salt is in the range from 1:0.01 to 1:2000. The initiator is used for example for cationic homo- or copolymerization of trioxane, and permits stable and flexible operation of the polymerization.

Abstract: A half ester of an organic polyol made by reacting polyols with anhydrides; a thermosettable composition including (i) the half ester of an organic polyol, (ii) an anhydride, (iii) an epoxide, and (iv) a catalyst; and a thermoset product made from such thermosettable composition. The thermosettable compositions of the present invention are useful in various applications such as casting, potting, and encapsulation, such as electrical and electronics applications, and composites. The thermoset products made from the thermosettable compositions of the present invention have improved mechanical performances, especially toughness and mechanical strength, while maintaining high thermal resistance.

Abstract: The invention provides methods of removing nucleic acid contamination from reverse transcription reactions and hot-start PCR, wherein said hot-start PCR is a barrier hot-start PCR set up and/or involves a hot-start DNA polymerase, which methods comprise use of a DNase that is substantially irreversibly inactivated by heating at a temperature of about 50° C. for 5 minutes, and that is substantially specific for double stranded DNA. The invention further provides a DNase that is substantially irreversibly inactivated by heating at a temperature of about 50° C. for 5 minutes, and that is substantially specific for double stranded DNA, nucleic acids encoding said DNase and kits or compositions comprising said DNase or said nucleic acid.

Abstract: The present invention relates to an acrylic pressure sensitive adhesive composition comprising acrylic copolymers wherein the gel fraction represented by the specific formula (1) is 45 to 75%, the swelling ratio represented by the specific formula (2) is 5 to 20, and the weight average molecular weight of non-crosslinking polymer contained in a pressure sensitive adhesive prepared from the pressure sensitive adhesive composition sol eluted from the adhesive prepared by the composition with ethyl acetate is at least 300,000.

Abstract: The present invention relates to novel high-latency liquid hardeners for hardening of curable polymer resins, especially epoxy resins, and to epoxy resin compositions comprising liquid hardeners for the production of fibre composite materials.

Abstract: Disclosed herein is a composition having a thermoset polymer and a plurality of hollow microsphere homogenously dispersed in the composition. The polymer is a cyanate ester thermoset, a phthalonitrile thermoset, a crosslinked acetylene thermoset, or a hydrosilation thermoset. Also disclosed herein is a method of: providing a thermosetting compound; adding microspheres to the thermosetting compound; and mixing the thermosetting compound while initiating crosslinking of the thermosetting compound.

Abstract: There are provided a photosensitive composition, and a cured product of the photosensitive composition, the photosensitive composition being an ultraviolet curable composition that is curable in a short time while a portion of the photosensitive composition such as a dark portion where radicals are not generated at all is curable. A cured product is obtained by curing a photosensitive composition by ultraviolet irradiation, the photosensitive composition containing an ultraviolet curable material, and a chain transfer agent that contains an ingredient (a) that is a compound containing at least one kind selected from the group consisting of a urethane bond, a urea bond and an isocyanate group, and an ingredient (b) that is a metal-containing compound, wherein a portion of the composition where irradiation light does not reach is curable.

Abstract: The present invention relates to a mixture including at least O,O-tert-butyl-O-(2-ethylhexyl) monoperoxycarbonate and at least O,O-tert-amyl-O-2-ethylhexyl monoperoxycarbonate, where the O,O-tert-amyl-O-2-ethylhexyl monoperoxycarbonate is present in the mixture in an amount of from 0.001% to 45% by weight relative to the total weight of the mixture. The invention also relates to a crosslinkable composition that includes such a peroxide mixture and an elastomer; and to uses of the crosslinkable composition and mixture.

Abstract: Methods of producing a hybrid petro-plant oil polyol having a high bio-content by coupling a petro-chemical polyol with a plant oil based polyol is provided, including coupling an intermediate petro-polyol prepolymer with a plant oil polyol so as to synthesize a hybrid petro-plant oil polyol having a high bio-content and a hydroxyl number of between about 50 and 60.

Abstract: This application is directed to a method of treating tires so that the tires will have better performance, especially when used for racing. The method disclosed herein is especially suited for use in go kart racing, although the method can be used for other applications in which the adhesion and hardness of tires and dynamic coefficient of friction, after their manufacture is to be altered. The method also includes cleaning steps and formulations. This method involves the selective use of various esters to alter tire characteristics as desired. The esters can be used in a process in which the exterior of the tire is cleaned by esters before application of an ester based tire treatment.

Abstract: The present invention pertains to the field of thermosetting or thermoset polymers mainly used as materials, coatings or adhesives. The invention more specifically relates to the use of specific molecules having associative groups including a nitrogen heterocycle as a hardener or co-hardener of thermosetting polymers.

Abstract: Compounds VB of the formula (I) or (II), said compounds being particularly suitable as curing agents for epoxide resins. The compounds can be produced easily and rapidly. They can be used in the form of aqueous curing agents and form stabile aqueous emulsions in particular. This facilitates the formulation of ECC compounds for use primarily as coatings.

Abstract: Provided is a complex of hydrogen peroxide and at least one compound represented by Formula I: wherein X is: —C(R3)3, —C?C(R3), —O(R3), —N(R3)2, or —S(R3); and R1, R2, and R3 are each independently selected from H, alkyl, alkenyl, alkynyl, aralkyl, aryl, heteroaryl heteroarylalkyl, heterocyclyl, and cycloalkyl, or R2 and an R3 are optionally taken together to form an alicyclic ring. Also provided are anaerobic cure systems and curable compositions employing the complexes described herein.

Abstract: A method of producing anhydrous calcium nitrate, anhydrous magnesium nitrate or mixture thereof involves removing water from a solution of calcium nitrate, magnesium nitrate or mixture thereof in a pulse combustion drier. The invention also provides a mixture of anhydrous calcium nitrate, anhydrous magnesium nitrate and the individual anhydrous nitrate salts in a sealed container.

Abstract: The present invention discloses both amine compositions and amine-epoxy compositions containing N,N?-dimethyl-meta-xylylenediamine. A novel process for producing amines such as N,N?-dimethyl-meta-xylylenediamine, and structurally similar amines, is also disclosed.

Abstract: A melamine epoxy resin monomer including: a glycidyl group; and a structural unit having a melamine residue and being represented by the following Formula (I) is disclosed. In Formula (I), each of R1 to R4 independently represents a hydrogen atom, a group represented by R5OCH2—, or a group derived from a melamine derivative and represented by the following Formula (II). R5 represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or a glycidyl group. In Formula (II), each of R21 to R25 independently represents a hydrogen atom, a group represented by R26OCH2—, or a group derived from a melamine derivative and represented by Formula (II). R26 represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or a glycidyl group.

Abstract: Two component resin system consisting of a first component A and a second component B characterized in that component A comprises: a. a compound capable of undergoing a radical copolymerization selected from the group consisting of unsaturated polyester resins, vinyl ester resins and mixtures thereof, b. an epoxide functional resin as compound capable of reacting with an aliphatic amine and in that component B comprises a mixture of c. an aliphatic amine d. a perester.

Abstract: Controlled thermal crosslinking in a polyacrylate-based composition is accomplished by a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at least one substance comprising at least one epoxide group (crosslinker) and at least one substance of the general formula (I) R1R2N—CR3R4—CR5R6—(CR7R8)n—NR9R10??(I) wherein the radicals R1, R2, R9 and R10 independently of one another are a hydrogen atom or a substituted or unsubstituted alkyl or cycloalkyl radical having 1 to 8 carbon atoms or an alkylene group bonded to the main chain and having 1 to 8 carbon atoms, where at least one of the radicals R1, R2, R9 and R10 is not a hydrogen atom; the radicals R3, R4, R5, R6, R7 and R8 independently of one another are a hydrogen atom or an alkyl group having 1 to 8 carbon atoms or form a 5-7-membered cycloalkylene group; and n is an integer from 0 to 4 (accelerator).

Abstract: In the context of a polyacrylate-based composition, the intention is to allow controlled thermal crosslinking. This is accomplished by provision of a crosslinker-accelerator system for the thermal crosslinking of polyacrylates having functional groups suitable for entering into linking reactions with epoxide groups, comprising at least one substance comprising at least one epoxide group (crosslinker) and at least one substance conforming to the general formula (I) NR3??(I), in which the radicals R independently of one another are a hydrogen atom or an organic radical having 1 to 20 carbon atoms, with at least one of the radicals R being an organic radical with 1 to 20 carbon atoms, and comprising at least one alcoholic OH group.

Abstract: A diamond reference standard contains a diamond composite of 60-90% diamond crystals and 10-40% silicon carbide binding agent doped with a plurality of elements. The standard is prepared by doping a diamond composite containing a silicon carbide binder with a plurality of elements, the presence of which can readily be detected using a variety of instruments, e.g. a mass spectrometer.

Abstract: The invention relates to a composition that can be thermally cured, containing relative to the total composition, a) 5 to 90% by weight of a diene-based polymer or copolymer containing an olefinic double bond and/or an aromatically substituted olefin, wherein the polymer or copolymer is liquid, or paste-like, at 22° C. and has a glass transition temperature between ?30° C. and +15° C., measured according to a DSC method; b) a vulcanization system selected from the group consisting of: b1) sulfur, and one or more accelerator(s), b2) peroxidic or disulfidic vulcanization systems, b3) quinones, quinone dioximes, or dinitrosobenzene.