Abstract: There is described a process for the recovering of inorganic chemicals of pulp and paper making processes (IC) and the production of biochemicals from black liquor (BL) using microwaves (MW) comprising: (a) filtration of BL to produce filtered BL, in a media, (b) drying of said filtered BL with MW in said media to produce dried BL, (c) pyrolysis of said dried BL with MW in said media to produce bio-oil, biogas, and solid residue, (d) recovering of said bio-oil, and (e) recovering of IC and biocarbon from said solid residue. The disclosed process does not require chemical additives compared to processes rely on precipitation of lignin to recover said IC. The disclosed process supports efficient, direct, and long-lasting reductions in greenhouse gas emissions and local air pollutants resulting from the current processes rely on burning BL in recovery boilers to recover said IC.

Abstract: The present invention relates to an azeotropic or quasi-azeotropic composition comprising hydrogen fluoride, 2,3,3,3-tetrafluoropropene and 1,1,1,2,2-pentafluoropropane, characterized in that said composition has a boiling point above 40° C.

Abstract: The present disclosure relates to methods of synthesizing slurries comprising ferrihydrite nanoparticles, and systems and methods employing the same. The method may include the steps of preparing an aqueous solution having ferric iron cations, halide anions, and a two-line iron promoter, and precipitating the ferrihydrite nanoparticles in the aqueous solution, thereby producing a ferrihydrite slurry. The ferrihydrite slurries may be useful in treating a polluted fluid having sulfur contaminants therein.

Abstract: Provided are a newly developed tandem malonate-based amphipathic molecule, a method of preparing the same, and a method of extracting, solubilizing, stabilizing, crystallizing or analyzing a membrane protein using the same. In addition, the compound may be used to efficiently extract membrane proteins having various structures and characteristics from a cell membrane, compared to a conventional compound, to stably store the proteins in an aqueous solution for a long time, and may be used in functional and structural analysis thereof. The analysis of the structures and functions of the membrane proteins is one of the most attractive fields in current biology and chemistry, which are closely related to new drug development.

Abstract: In one aspect of the present invention, a dental cement contains a glass powder, wherein the glass powder contains zinc, silicon, and fluorine and does not substantially contain aluminum.

Abstract: In one aspect of the present invention, a dental glass powder contains zinc, silicon, and fluorine and does not substantially contain aluminum.

Abstract: The present invention relates to a method for preparing high-purity 1,3-cyclohexanedimethanol capable of achieving a high conversion rate by allowing most of the reactant to participate in the reaction, and of increasing reaction efficiency and economic efficiency by further simplifying the reaction process, while minimizing by-products within a shorter period of time. Specifically, the method for preparing 1,3-cyclohexanedimethanol includes reducing 1,3-cyclohexanedicarboxylic acid in the presence of a metal catalyst, which is fixed to a silica support and includes a ruthenium (Ru) compound, a tin (Sn) compound and a platinum (Pt) compound in a weight ratio of 1:0.8 to 1.2:1.2 to 2.4.

Abstract: An azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene and one or more (hydro)halogen-carbon compounds including between 1 and 3 carbon atoms. Also an azeotropic or quasi-azeotropic composition including hydrogen fluoride, 3,3,3-trifluoro-2-chloropropene, and one or more compounds selected from among 1,3,3,3-tetrafluoropropene, 1,1,1,2,2-pentafluoropropane, 2,3,3,3-tetrafluoropropene, 3,3,3-trifluoropropene, E-3,3,3-trifluoro-1-chloropropene, trifluoropropyne, 1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropane, 1,1,1,3,3-pentafluoropropene, 1,1,1,2,3-pentafluoropropene and 2-chloro,1,1,1,2-1 tetrafluoropropane.

Abstract: Provided herein are systems and methods for the facile extraction and purification of oils from plant material, including cannabis and hemp. The systems and methods herein are versatile, and may utilize a wide range of solvents to extract oils from a variety of plant-based material. Further, the provided systems and methods are closed loop, reducing the loss solvent and decreasing the risk of safety concerns such as human exposure to solvent chemicals or explosion of volatiles. In some embodiments, the systems and methods remove impurities from the extracted oils, for example waxes or other precipitates, and provide a higher purity and higher quality extract.

Abstract: Disclosed is (i) a process of making phenol and/or cyclohexanone from cyclohexylbenzene including a step of removing methylcyclopentylbenzene from (a) the cyclohexylbenzene feed supplied to the oxidation step and/or (b) the crude phenol product (ii) a phenol composition and (iii) a cyclohexylbenzene composition that can be made using the process.

Abstract: A polysaccharide based aerogel comprising a network of polysaccharide fibers with pores therebetween, wherein the sizes of the pores are in the micrometer range.

Abstract: Esters of oligo-hydroxycarboxylic acids have the general formula ( ): wherein at least one of the radicals R1, R4 or R5 is a linear or branched aliphatic hydrocarbon radical having 6 to 30 carbon atoms and 0, 1, 2 or 3 double bonds. Cosmetic and pharmaceutical agents contain said esters. These esters are effective as thickeners, in particular for compositions containing surfactants.

Abstract: A solid base material for skin external application has a breaking strength high enough to be used for a stick-shaped base material and the like. A solid base material for skin external application has: a surfactant; water; and a lipid peptide compound including at least one of compounds of Formula (1) and the analogous thereof or pharmaceutically usable salts of the compound: wherein R1 is a C9-23 aliphatic group; R2 is a hydrogen atom, or a C1-4 alkyl group that may have a C1 or C2 branched chain; R3 is a —(CH2)n—X group, where n is a number from 1 to 4, and X is amino group, guanidino group, —CONH2 group, or a 5-membered or 6-membered ring that may have 1 to 3 nitrogen atoms or a condensed heterocycle composed of 5-membered and 6-membered rings that may have 1 to 3 nitrogen atoms.

Abstract: The present invention relates to a process for preparing a porous material, at least comprising the steps of providing a mixture (I) comprising a water soluble polysaccharide, at least one compound suitable to react as cross-linker for the polysaccharide or to release a cross-linker for the polysaccharide, and water, and preparing a gel (A) comprising exposing mixture (I) to carbon dioxide at a pressure in the range of from 20 to 100 bar for a time sufficient to form a gel (A), and depressurizing the gel (A). Gel (A) subsequently is exposed to a water miscible solvent (L) to obtain a gel (B), which is dried. The invention further relates to the porous materials which can be obtained in this way and the use of the porous materials as thermal insulation material, for cosmetic applications, for biomedical applications or for pharmaceutical applications.

Abstract: A compound represented by the following formula is provided: Also provided is a solution including a compound disclosed herein, a volume of dense carbon dioxide (CO2), and a co-solvent, where the solution has an increased viscosity greater than the viscosity of dense CO2. Methods of increasing the viscosity of dense CO2 and natural gas liquids (NGLs) by, for example, dissolving a compound disclosed herein to form a solution, are also provided.

Abstract: The present disclosure relates to compositions comprising 2,3,3,3-tetrafluoropropene that may be useful as heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, extinguishing agents, and fire suppression agents in liquid or gaseous form. Additionally, the present disclosure relates to compositions comprising 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane, which may be useful in processes to produce 2,3,3,3-tetrafluoropropene.

Abstract: An object of the present invention is to provide an organic semiconductor composition, which improves the insulation reliability of an organic thin-film transistor without greatly reducing the mobility of the organic thin-film transistor, an organic thin-film transistor which is prepared by using the organic semiconductor composition, and electronic paper and a display device which use the organic thin-film transistor. The organic semiconductor composition of the present invention contains an organic semiconductor material (A) and a polymer compound (B) containing a repeating unit represented by the following Formula (B).

Abstract: Mixture of L- and D-enantiomers of methyl glycine diacetic acid (MGDA) or its respective mono-, di or trialkali metal or mono-, di- or triammonium salts, said mixture containing predominantly the respective L-isomer with an enantiomeric excess (ee) in the range of from 10 to 75%.

Abstract: Nanocrystalline cellulose (NCC)-based supramolecular materials, a method for their preparation and their use in thermoplastic and thermoset polymer composites are disclosed. Supramolecular materials of NCC and one or two polymers are synthesized by in situ surface graft copohmerization in a multitude of solvent systems, including water. The nano-scale size supramolecular materials are engineered to have a unique combination of lower polarity and high hydrophobicity and function as copohmers for demanding pohmeric systems such as, but not limited to, polyolefins and polyesters. Nanocomposite materials of enhanced functionality and mechanical properties are produced by compounding the NCC-based supramolecular materials with polymer matrices. The supramolecular materials are used in composite development for packaging materials, structural composites for automotive and construction, as sandwiched foam composites or, combined with biocompatible polymers, in medical applications.

Abstract: Systems for extracting solute from a source material are shown and described. Each of the systems includes: a solvent source container configured to store a cooled solvent, a canister configured to contain the source material and receive solvent to produce an extract solution, and one or more extract containers in communication configured to receive and distill the extract solution, the solvent source container being configured to receive a post-extraction portion of the solvent. In some examples, the one or more extract containers are first and second extract containers that are each selectively coupleable to the canister and are selectively removable for storage of the extract mixture or the solute. In some other examples, the system further includes a cooling mechanism coupled to the solvent source container for cooling the recycled solvent within the solvent collection container.

Abstract: The present invention relates to wound care products, devices and methods incorporating acetic acid for the treatment of bacterial infections, in particular bacterial biofilm infections. In particular it relates to a wound care product comprising acetic acid, wherein the product comprises at least one further antibacterial compound; a delivery system comprising a container connected to a means of delivery which is connected to a pad, wherein said container comprises a composition comprising acetic acid and said pad comprises a self-adhesive material; a kit comprising a dressing and an adhesive membrane, wherein the dressing comprises a composition comprising acetic acid; a method of treating a wound comprising a) applying acetic acid to the wound and b) applying a negative pressure to the wound.

Abstract: A hydrogel-forming material for preparing hydrogel even after a process of stirring gelator in medium heat to dissolve and disperse the gelator, and cooling the mixture to room temperature with stirring, a hydrogel material wherein a gel can reform by standing at room temperature even after a hydrogel obtained using the material is converted sol by shaking. The hydrogel-forming material with lipid peptide gelator includes Formula (1) or a pharmaceutically usable salt thereof: R1 is a C9-23 aliphatic group, R2 is a hydrogen atom or C1-4 alkyl group optionally having a C1-2 branched chain, R3 is a —(CH2)n—X group, n is 1 to 4, and X is an amino-group, guanidino group, CONH2 group, 5-membered ring optionally having 1-3 nitrogen atom(s), 6-membered ring optionally having 1-3 nitrogen atom(s), or fused heterocycle composed of 5-membered ring and 6-membered rings optionally having 1-3 nitrogen atom(s), water, and fatty acid salt as additive.

Abstract: Augmented or synergized anti-inflammatory constructs are disclosed including terpenes covalently conjugated with other anti-inflammatory molecules such as nonsteroidal anti-inflammatory drugs, vanilloids, amino acids and polyamines; and anti-inflammatory molecules covalently conjugated with specific amino acids. For the latter, further conjugation with a choline bioisostere further augments the anti-inflammatory activity.

Abstract: The present invention provides a biomimetic polymer for stabilizing wellbore, a method for preparation of the biomimetic polymer, and a drilling fluid. The polymer contains carboxymethyl chitosan that serves as a backbone and dopamine-derived groups grafted on the backbone. The polymer provided in the present invention can improve the strength of shale in the wellbore, seal the shale pores and reduce the filter loss of drilling fluid, and thereby attains an effect of stabilizing the wellbore in shale formation in drilling process.

Abstract: The present disclosure relates to compositions comprising 2,3,3,3-tetrafluoropropene that may be useful as heat transfer compositions, aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, extinguishing agents, and fire suppression agents in liquid or gaseous form. Additionally, the present disclosure relates to compositions comprising 1,1,2,3-tetrachloropropene, 2-chloro-3,3,3-trifluoropropene, or 2-chloro-1,1,1,2-tetrafluoropropane, which may be useful in processes to produce 2,3,3,3-tetrafluoropropene.

Abstract: The present invention provides a process for preparing at least one chlorine-containing fluorocarbon compound selected from the group consisting of chlorine-containing fluoropropane compounds represented by Formula (1): CFnCl3-nCHClCH2Cl, wherein n is 1 or 2, and chlorine-containing fluoropropene compounds represented by Formula (2): CFnCl3-nCCl?CH2, wherein n is 1 or 2, wherein the process includes the step of contacting at least one chlorine-containing compound selected from the group consisting of 1,1,1,2,3-pentachloropropane, 1,1,2,3-tetrachloropropene, and 2,3,3,3-tetrachloropropene with hydrogen fluoride in the absence of a catalyst while heating. According to the present invention, the chlorine-containing propane and propene compounds having 1 or 2 fluorine atoms can be prepared by an industrially applicable, simple and effective process.

Abstract: The invention provides non-naturally occurring microbial organisms having a 4-hydroxybutyrate, 1,4-butanediol, or other product pathway and being capable of producing 4-hydroxybutyrate, 1,4-butanediol, or other product, wherein the microbial organism comprises one or more genetic modifications. The invention additionally provides methods of producing 4-hydroxybutyrate, 1,4-butanediol, or other product or related products using the microbial organisms.

Abstract: A method for transforming selected renewable oils and fats, and optionally polyester waste plastic materials, into a plurality of reaction products via supercritical water is disclosed. The method comprises: conveying the selected oils and fats material through an extruder, wherein the extruder is configured to continuously convey the selected oils and fats material to a supercritical fluid reaction zone; injecting hot compressed water into the supercritical fluid reaction zone, while the extruder is conveying the selected oil and fats material into the supercritical fluid reaction zone so as to yield a mixture; retaining the mixture within the reaction zone for a period of time sufficient to yield the plurality of reaction products.

Abstract: Process for the preparation of etherified melamine/formaldehyde condensates, in which first a methylolation of melamine with a formaldehyde component in the molar ratio of from 1:6 to 1:15, preferably at a pH of >7, is carried out. This is followed by an etherification of the resulting hydroxymethylation intermediate in the presence of a C1-C20-alkyl, preferably of a C1-C6-alcohol, particularly preferably of a C1-C4-alcohol, at a pH of <4.5, and subsequently by at least one distillation step in order to remove in particular methanol from the system, the pH of >9.5 being established before, during and/or after the distillation. According to the invention, a plurality of hydroxymethylation, etherification and distillation steps follow in order to achieve an etherified melamine/formaldehyde condensate which is distinguished by a high degree of hydroxymethylation, a high solids content and a low viscosity.

Abstract: Presented herein is a method for obtaining a dissolved selenium liquid mixture from solid selenium. The method involves mixing an amine solvent and a thiol solvent with the solid selenium to produce a liquid intermediate solution and removing a sulfur containing compound from the liquid intermediate solution to produce a dissolved selenium liquid mixture. A method for obtaining dissolved sulfur liquid mixture by mixing an amine with a thiol to produce a liquid solution that dissolves sulfur to produce a dissolved sulfur liquid mixture is also presented. In addition, a method for obtaining a dissolved sulfur and selenium liquid mixture from solid selenium and solid sulfur by mixing an amine solvent with a thiol solvent is presented.

Abstract: The instant invention relates to 3,3?-bis(3,4-dihydro-3-phenyl-2H-1,3-benzoxazin-6-yl)-1(3H)-isobenzofuranone and analogues based on phenolphthalein, formaldehyde and a primary amine. Such compounds are, when cured to form polymeric networks, difficultly inflammable and resistant to high temperatures. Such compounds may especially be used in the production of printed wiring boards.

Abstract: Disclosed are novel engineered fuel feed stocks, feed stocks produced by the described processes, and methods of making the fuel feed stocks. Components derived from processed MSW waste streams can be used to make such feed stocks which are substantially free of glass, metals, grit and noncombustibles. These feed stocks are useful for a variety of purposes including co-firing with coal and as substitutes for coal.

Abstract: A Diesel Exhaust Fluid (DEF) that includes urea, demineralized water and between 5 and 300 ppm formaldehyde, acetaldehyde, propianaldehyde, or butyraldehyde, and this formulation of DEF include less than 0.6 ppm of phosphates, calcium, iron, aluminum, magnesium, sodium, and potassium, the formulation also includes less than 0.3 ppm copper, zinc, chromium, and nickel. This formulation of DEF reduces the accumulation of urea deposit in the diesel exhaust system relative to other formulation of specification grade DEF that include less formaldehyde.

Abstract: The present invention relates to a battery separator, comprising cellulosic fibers of the lyocell genus, wherein the R10-value, the R18-value and the hemicellulose content of the lyocell fibers is as follows: R10>83%, preferably >84% R18>93%, preferably >94% Hemicellulose content <3%. The present invention furthermore relates to novel lyocell fibers useful for battery separators, as well as batteries comprising the inventive battery separator.

Abstract: Disclosed are a polyol with a molecular weight distribution Mw/Mn of 4 or more, obtained by reacting a compound comprising an alkylene oxide compound (II) having a hydroxyl group in a base polyol (I) with a molecular weight of 2000 or more; and a polyol composition for a flexible polyurethane foam, comprising a polyol compound and a crosslinker, wherein the crosslinker comprises a polyol (a) with a hydroxyl value of 50 to 1100 mgKOH/g and with a primary hydroxylate ratio of 25% or more and 60% or less, which is obtained by an addition of a compound comprising alkylene oxide compound (ii) having a hydroxyl group to active hydrogen compound (i).

Abstract: In a process for producing 3,4? and/or 4,4? dimethyl-substituted biphenyl compounds, a feed comprising toluene is contacted with hydrogen in the presence of a hydroalkylation catalyst under conditions effective to produce a hydroalkylation reaction product comprising (methylcyclohexyl)toluenes. At least part of the hydroalkylation reaction product is dehydrogenated in the presence of a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising a mixture of dimethyl-substituted biphenyl isomers. The dehydrogenation reaction product is then separated into at least a first stream containing at least 50% of 3,4? and 4,4? dimethylbiphenyl isomers by weight of the first stream and at least one second stream comprising one or more 2,x? (where x? is 2?, 3?, or 4?) and 3,3? dimethylbiphenyl isomers.

Abstract: The invention relates to a method for producing homogeneous solutions of metal complexes of general formula (2): [MaLxXn]Ym, where M is a metal from the group comprising Mn(II), Mn(III), Mn(IV), Fe(III), Fe(III) or Fe(IV), X is a coordinated compound selected from mono- bi- or tri-charged anions or neutral molecules which are able to coordinate with a metal mono- bi- or tri-dentate, Y is a non-coordinated counter-ion which ensures charge equalization of the complex, L is a ligand of general formula (1) or the protonized or de-protonized form thereof, and a, x, n, m, R, R1, R2, R3 and z are as specified in claim 1, in diols or polyols, the monoethers or mixtures of said substances. Said method is characterized in that a ligand of the formula (1) is reacted with an iron or manganese salt in a heterogeneous reaction in the diol or polyol, the monoethers or mixtures of these substances.

Abstract: A Diesel Exhaust Fluid (DEF) that includes urea, demineralized water and between 5 and 300 ppm formaldehyde, this formulation of DEF include less than 0.6 ppm of phosphates, calcium, iron, aluminum, magnesium, sodium, and potassium, the formulation also includes less than 0.3 ppm copper, zinc, chromium, and nickel. This formulation of DEF reduces the accumulation of urea deposit in the diesel exhaust system relative to other formulation of specification grade DEF that include less formaldehyde.

Abstract: A sugar composition comprising at least 40% dissolved solids in an aqueous solution having a viscosity at least 10% lower than a 42 DE (Dextrose Equivalents) reference solution with a same dissolved solids concentration at a given temperature. Another sugar composition comprising at least 30% glucose relative to total sugars, at least 10% mannose relative to total sugars, at least 5% xylose relative to total sugars, and less than 0.25% ash. Another sugar composition comprising at least 30% glucose relative to total sugars at least 10% mannose relative to total sugars, at least 5% xylose relative to total sugars, and at least 2% total furfurals.

Abstract: The present invention relates to, inter alia, gyroidal mesoporous carbon materials and methods of use and manufacture thereof. In one embodiment, the present invention relates to a mesoporous carbon composition comprising a gyroidal mesoporous carbon having an ordered gyroidal structure and mesopores having a pore size of greater than 2 nanometers (nm) in diameter, and more particularly greater than 11 nm in diameter.

Abstract: Compositions comprising an alkyl 3-hydroxybutyrate and one or more additional components are provided. The compositions of the present invention may include at least one alkyl 3-hydroxybutyrate having at least 3 and not more than 5 carbon atoms, along with one or more additional components including, for example, alkyl butyrates, alkyl acetates, alkyl alcohols, and dimers and/or trimers of the alkyl 3-hydroxybutyrate. Such compositions may be products of, for example, the hydrogenation of an acetoacetate-containing composition.

Abstract: Phosphonium-based room temperature ionic liquids (“RTILs”) were prepared. They were used as matrices for Matrix-Assisted Laser Desorption Ionization (MALDI) mass spectrometry and also for preparing samples of dyes for analysis.

Abstract: A resin-impregnated fiber tube for an inner lining of ducts and pipelines contains, in addition to identical or different types of fibrous material, at least one polymer reaction resin for impregnating the fibrous material and subsequent hardening, as well as at least one chemical additive based on urea or a chemically modified urea, wherein the chemical additive acts as a thixotroping agent. The resin-impregnated fiber tube may also contain a thickening agent, wherein oxides or hydroxides of alkaline earth metals are preferably used. The resin-impregnated fiber tube is preferably hardened by UV light.

Abstract: The disclosure provides a method of producing a scyllo-inositol or a new scyllo-inositol derivative in a one-step process, from ubiquitous and inexpensive raw materials. Also provided is a scyllo-inositol derivative bonded to saccharides such as glucose and similar.

Abstract: A method for preparing a mixture (M) including at least one alcohol (Aj), wherein said method includes a gas-phase oligomerization reaction of at least one alcohol (Ai) with a solid acid-base catalyst doped with one or more metals, said reaction being carried out in the presence of hydrogen and at a temperature of no less than 50° C. and strictly less than 200° C.

Abstract: A nanometal dispersion and a method for preparing a nanometal dispersion are provided. The method comprises mixing a metal seed crystal aqueous solution, a polysaccharide aqueous solution, and a metal compound aqueous solution, followed by allowing the resulting mixture to conduct a reduction-oxidation reaction to form a nanometal. The produced nanometal dispersion comprises a polysaccharide and a nanometal. The polysaccharide is composed of N-actyl-D-glucosamine and glucuronic acid, and the nanometal has multimorphology.

Abstract: The invention provides a droplet encapsulate comprising: a drop of a hydrophobic medium; a peripheral layer of non-polymeric amphipathic molecules around the surface of the drop; and an aqueous droplet within the peripheral layer, the aqueous droplet comprising: (a) an aqueous medium and (b) an outer layer of non-polymeric amphipathic molecules around the surface of the aqueous medium. The invention also provides processes for preparing the droplet encapsulates. Various uses of the droplet encapsulates are also described, including their use as drug delivery vehicles, in synthetic biology, and in the study of membrane proteins.

Abstract: The present invention provides derivatives of native lignin having a certain aliphatic hydroxyl content. Surprisingly, it has been found that consistent and predictable antioxidant activity may be provided by selecting for derivatives of native lignin having a certain aliphatic hydroxyl content.

Abstract: The present invention relates to redox-curing type nonaqueous curable compositions having: at least one liquid radical polymeric monomer (a); an organic peroxide (b); and a powdered water-soluble reducing compound (c), where the powdered water-soluble reducing compound (c) is dispersed in the liquid radical polymeric monomer (a).

Abstract: Disclosed in this specification is a lignin composition having unique characteristics relative to its characteristics as found in its natural environment. The lignin has been modified so that more lignin decomposes at the lower lignin decomposition temperature than decomposes at the higher lignin decomposition temperature and the lignin composition has a very high surface area relative to naturally occurring lignin compositions.