Alkaline Earth Metal Hypochlorite Patents (Class 252/187.27)
  • Patent number: 9464262
    Abstract: The invention relates to compositions, methods of use, and methods of manufacture for an intercalated bleach compound and compositions thereof. The intercalated bleach compound has the formula Mx(OCl)y(O)m(OH)n where M is an alkaline earth metal such as magnesium, calcium or mixture thereof. The values of x and y independently equal any number greater than or equal to 1 (e.g., 1, 2, 3, 4, etc.), and m and n independently equal any number greater than or equal to 0 (e.g., 0, 1, 2, 3, 4, etc.), but m and n are not both 0. In addition, the molar ratio of the alkaline earth metal (e.g., magnesium or calcium) to hypochlorite is at least 3:1. In other words, x is ?3y. The compounds exhibit excellent stability, little or no chlorine bleach odor, exhibit excellent pH buffering characteristics, and less reactivity with organic materials as compared to alternative chlorine bleach products.
    Type: Grant
    Filed: May 10, 2016
    Date of Patent: October 11, 2016
    Assignee: The Clorox Company
    Inventors: Evan Rumberger, Marisa MacNaughtan, William L. Smith, Kelsey Kornaus
  • Patent number: 8603392
    Abstract: Corrosion-inhibited hypochlorite compositions and methods of use are disclosed. Corrosion inhibitors including sugar acids and calcium compounds, polyacrylate and calcium compounds, and/or zinc and calcium compounds are used with hypochlorite sources to enhance the longevity and performance of electrochemical cells as well as reducing corrosion of metal in contact with the generated hypochlorite sources. The methods for generation employ a variety of electrochemical cells, beneficially including use of portable electrochemical cell system for production of corrosion-inhibited hypochlorite cleaning solutions.
    Type: Grant
    Filed: June 25, 2012
    Date of Patent: December 10, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Jenna Johnson, Kim R. Smith, Erik C. Olson, Steven E. Lentsch
  • Patent number: 8557178
    Abstract: Corrosion inhibitor compositions and methods of use are disclosed. Corrosion inhibitors are selected from polyacrylate and calcium corrosion inhibitors, zinc and calcium corrosion inhibitors and/or sugar acids and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.
    Type: Grant
    Filed: July 13, 2012
    Date of Patent: October 15, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Erik C. Olson, Kim R. Smith, Steven E. Lentsch, Sherri L. Tischler
  • Patent number: 8496853
    Abstract: Corrosion inhibitor compositions and methods of use are disclosed. Zinc and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.
    Type: Grant
    Filed: June 12, 2012
    Date of Patent: July 30, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Erik C. Olson, Kim R. Smith, Steven E. Lentsch
  • Patent number: 8486879
    Abstract: A solid composition including calcium and/or magnesium hypochlorite, a builder (e.g., one or more of carbonate, bicarbonate, sesquicarbonate), an acid, a water-soluble polymer, at least one anionic surfactant, and optionally, a hydrotrope. The composition does not include any potassium hypochlorite, sodium hypochlorite, lithium hypochlorite, N-halogenated compounds, peroxides, persulfates, hydantoins, isocyanurates, or carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups. Upon dissolution of the composition in water, the calcium and/or magnesium hypochlorite and acid react to form hypochlorous acid. The use of hypochlorous acid, rather than direct use of an alkaline or alkaline earth hypochlorite results in a composition that is typically acidic rather than basic, and that results in improved cleaning. The composition is particularly suited for cleaning and disinfecting dentures.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: July 16, 2013
    Assignee: The Clorox Company
    Inventors: Evan Rumberger, William L. Smith
  • Patent number: 8481471
    Abstract: The present invention provides a solid-layered composition having at least two parts. The first part comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a functional ingredient, b) a builder or filler, and c) wherein the second part does not contain any oxidant.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: July 9, 2013
    Assignee: The Clorox Company
    Inventors: William L. Smith, Evan M. Rumberger
  • Patent number: 8475678
    Abstract: The present invention provides a method of using a solid-layered composition having at least two parts. The first past comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a surfactant, b) a builder, c) an acid, and d) wherein the second part does not contain any oxidant.
    Type: Grant
    Filed: September 11, 2012
    Date of Patent: July 2, 2013
    Assignee: The Clorox Company
    Inventors: William L. Smith, Evan M. Rumberger
  • Patent number: 8361942
    Abstract: A solid composition including calcium and/or magnesium hypochlorite, a builder (e.g., one or more of carbonate, bicarbonate, sesquicarbonate), an acid, a water-soluble polymer, at least one anionic surfactant, and optionally, a hydrotrope. The composition does not include any potassium hypochlorite, sodium hypochlorite, lithium hypochlorite, N-halogenated compounds, peroxides, persulfates, hydantoins, isocyanurates, or carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups. Upon dissolution of the composition in water, the calcium and/or magnesium hypochlorite and acid react to form hypochlorous acid. The use of hypochlorous acid, rather than direct use of an alkaline or alkaline earth hypochlorite results in a composition that is typically acidic rather than basic, and that results in improved cleaning. The composition is particularly suited for cleaning and disinfecting dentures.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: January 29, 2013
    Assignee: The Clorox Company
    Inventors: William L. Smith, Evan Rumberger
  • Patent number: 8361945
    Abstract: The present invention provides a method for cleaning dentures by contacting the dentures with a solid, multi-layered composition having at least two parts in water. The first part of the composition comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a functional ingredient, b) a builder or filler, and c) wherein the second part does not contain any oxidant.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: January 29, 2013
    Assignee: The Clorox Company
    Inventors: William L. Smith, Evan Rumberger
  • Patent number: 8361943
    Abstract: A solid composition including calcium and/or magnesium hypochlorite, a builder (e.g., one or more of carbonate, bicarbonate, sesquicarbonate), an acid, a water-soluble polymer, at least one anionic surfactant, and optionally, a hydrotrope. The composition does not include any potassium hypochlorite, sodium hypochlorite, lithium hypochlorite, N-halogenated compounds, peroxides, persulfates, hydantoins, isocyanurates, or carboxylic acids that also have hydroxyl, amino, amido, imino, or imido groups. Upon dissolution of the composition in water, the calcium and/or magnesium hypochlorite and acid react to form hypochlorous acid. The use of hypochlorous acid, rather than direct use of an alkaline or alkaline earth hypochlorite results in a composition that is typically acidic rather than basic, and that results in improved cleaning. The composition is particularly suited for cleaning and disinfecting dentures.
    Type: Grant
    Filed: October 14, 2010
    Date of Patent: January 29, 2013
    Assignee: The Clorox Company
    Inventors: William L. Smith, Evan M. Rumberger
  • Patent number: 8361944
    Abstract: The present invention provides a solid-layered composition having at least two parts. The first part comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a functional ingredient, b) a builder or filler, and c) wherein the second part does not contain any oxidant.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: January 29, 2013
    Assignee: The Clorox Company
    Inventors: William L. Smith, Evan Rumberger
  • Patent number: 8343380
    Abstract: Corrosion inhibitor compositions and methods of use are disclosed. Sugar acids and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.
    Type: Grant
    Filed: November 9, 2011
    Date of Patent: January 1, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Erik C. Olson, Steven E. Lentsch
  • Patent number: 8309508
    Abstract: A cleaning substrate which comprises at least one layer of a solid hypohalite precipitate, wherein the hypohalite precipitate is formed in situ on the layer of substrate material. A process for making a fibrous cleaning substrate comprising the steps of: a) providing at least one layer of fibrous material; b) exposing the fibrous layer to an aqueous alkaline earth salt solution; c) treating the fibrous layer with a hypochlorite solution; d) allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate around the fibers in the fibrous material and a liquid phase, and e) removing at least 65% of the liquid phase from the fibrous substrate.
    Type: Grant
    Filed: December 3, 2010
    Date of Patent: November 13, 2012
    Assignee: The Clorox Company
    Inventors: Marc P. Privitera, William L. Smith, Edward Jason White, Leslie N. Adams
  • Patent number: 8287755
    Abstract: The present invention provides a solid-layered composition having at least two parts. The first part comprises a) calcium hypochlorite, magnesium hypochlorite and mixtures thereof, b) a builder, c) a water-soluble polymer, d) an acid, and e) wherein the first part does not contain sodium hypochlorite, lithium hypochlorite, potassium hypochlorite and mixtures thereof. The second part comprises a) a surfactant, b) a builder, c) an acid, and d) wherein the second part does not contain any oxidant.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: October 16, 2012
    Assignee: The Clorox Company
    Inventors: William L. Smith, Evan M. Rumberger
  • Patent number: 8268770
    Abstract: A cleaning substrate which comprises at least one layer of a solid hypohalite precipitate, wherein the hypohalite precipitate is formed in situ on the layer of substrate material. A process for making a fibrous cleaning substrate comprising the steps of: a) providing at least one layer of fibrous material; b) exposing the fibrous layer to an aqueous alkaline earth salt solution; c) treating the fibrous layer with a hypochlorite solution; d) allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate around the fibers in the fibrous material and a liquid phase, and e) removing at least 65% of the liquid phase from the fibrous substrate.
    Type: Grant
    Filed: January 28, 2011
    Date of Patent: September 18, 2012
    Assignee: The Clorox Company
    Inventors: Marc P. Privitera, William L. Smith, Edward Jason White, Leslie N. Adams
  • Patent number: 8252200
    Abstract: The present invention is directed to a water treatment composition, comprising: calcium hypochlorite coated with a coating comprising at least one hydrated or anhydrous salt. The present invention is also directed to a water treatment composition, comprising: (a) an inner core layer comprising calcium hypochlorite; (b) one or more interlayers of selected salts positioned on top of said inner core layer, and (c) one or more outer layers of selected salts positioned on top of said interlayer(s).
    Type: Grant
    Filed: November 21, 2006
    Date of Patent: August 28, 2012
    Assignee: Arch Chemicals, Inc.
    Inventors: Deqing Lei, George Polson, Sonia Oberson, Ellen M. Meyer, James D. Kilby
  • Patent number: 8114344
    Abstract: Corrosion inhibitor compositions and methods of use are disclosed. Sugar acids and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: February 14, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Erik C. Olson, Steven E. Lentsch
  • Patent number: 8114343
    Abstract: Corrosion inhibitor compositions and methods of use are disclosed. Zinc and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: February 14, 2012
    Assignee: Ecolab USA, Inc.
    Inventors: Kim R. Smith, Erik C. Olson, Steven E. Lentsch
  • Patent number: 8105531
    Abstract: Corrosion inhibitor compositions and methods of use are disclosed. Polyacrylate and calcium corrosion inhibitors combined with hypochlorite sources provide use solutions for effective corrosion inhibition for metal surfaces.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: January 31, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Erik C. Olson, Steven E. Lentsch
  • Patent number: 7906459
    Abstract: Soluble and stable liquid compositions containing a plant growth regulator selected from the group consisting of cytokinin and a gibberellin, an acid solubilizer such as citric acid, tartaric acid or glycolic acid and a solvent; as well as methods for making and using the composition are disclosed. The compositions improve solubility, handling, stability, safety, as well as activity improvements such as improved plant growth, yield, fruit thinning or sizing and quality. The compositions are soluble and stable by adding an ethoxylated alkyl alcohol wherein the growth regulator is 6-benzyladenine (6-BA) or forchlorfenuron (CPPU) and the ethoxylated alcohol surfactant is C12-15 alkyl alcohol in propylene glycol. The compositions may also contain a cytokinin such as 6-benzyladenine (6-BA) or forchlorfenuron (CPPU) that is increased in solubility and activity and by synergistically combined with GA3 or GA4A7 as well as in storage stability by adding an antioxidant.
    Type: Grant
    Filed: September 24, 2009
    Date of Patent: March 15, 2011
    Assignee: Valent BioSciences Corporation
    Inventors: Yueh Wang, Mark Beach, Bruce Kirkpatrick, Gregory Clarke, John Lopez, Prem Warrior, Bruce Baldi
  • Patent number: 7857990
    Abstract: Describes a composition comprising a mixture of (1) a major amount of calcium hypochlorite, e.g., hydrated calcium hypochlorite, and (2) a minor amount of calcium hypochlorite-compatible hydrophobic additive (other than discrete particulate Group IIA or IIIA metal stearates) in amounts sufficient to provide the composition with reduced hydrophilic properties. The composition has a solution rate in water at standard conditions that is less than the calcium hypochlorite used to prepare the composition, but sufficient for the intended application. Describes also calcium hypochlorite compositions in which the hydrophobic additive is an organo-silicon material, or a metal oxide, e.g., amorphous precipitated silica, treated with a hydrophobizing agent, such as an organo-silicon material, e.g., an organo-silane and/or organo-siloxane material.
    Type: Grant
    Filed: August 30, 2007
    Date of Patent: December 28, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Stanley R. Pickens, Timothy A. Okel, Erik A. Schoenman, Shantilal M. Mohnot, Patrick Ryan
  • Patent number: 7794607
    Abstract: Compositions and methods for their use are presented that substantially increase the rate of inactivation of microbiological organisms, especially those resistant to inactivation from free halogen based sanitizers, and oxidation of oxidation resistant organic based compounds in aqueous solution. Aquatic facilities susceptible to accumulation of organic N-chloramines, cyanuric acid and other oxidation resistant compounds, as well as oxidation resistant parasitic organisms such as cryptosporidium and Giardia, obtain dramatic improvements in the rate of oxidation and subsequent inactivation of these undesirable contaminants.
    Type: Grant
    Filed: November 13, 2006
    Date of Patent: September 14, 2010
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7695639
    Abstract: Stable compositions of calcium hypochlorite containing selected hydrated inorganic salts having a sufficiently high enthalpy and the ability to provide water release to sufficiently quench reactions and reduce the potential for conflagration.
    Type: Grant
    Filed: March 17, 2008
    Date of Patent: April 13, 2010
    Inventor: John P. Garris
  • Patent number: 7695631
    Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: April 13, 2010
    Assignee: Truox, Inc.
    Inventor: Roy W Martin
  • Patent number: 7572390
    Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor, a transition metal catalyst in contact with the persulfate donor, and a cationic electrolyte. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing product may be applied while the aquatic facilities are being used. A free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate. The cationic electrolyte facilitates the removal of the catalyst from the water.
    Type: Grant
    Filed: September 14, 2005
    Date of Patent: August 11, 2009
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7572384
    Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: August 11, 2009
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7476333
    Abstract: A method and composition for reducing chemical oxygen demand is presented. The composition includes a persulfate donor and a transition metal catalyst in contact with the persulfate donor. When the composition is contacted by water, the transition metal catalyst reacts with persulfate and reduces the persulfate concentration in the water. The composition allows the use of persulfate, which is known to cause irritation to users of aquatic facilities (e.g., pools, spas) that come in contact with it. As the persulfate concentration is reduced rapidly in the water by the catalyzed reaction, the persulfate-containing cleaning product may even be used while the aquatic facilities are being used. Optionally, a free halogen donor may be incorporated into the composition. The composition may be in the form of powder, granules (coated or uncoated), or agglomerate.
    Type: Grant
    Filed: June 22, 2005
    Date of Patent: January 13, 2009
    Assignee: Truox, Inc.
    Inventor: Roy W. Martin
  • Patent number: 7465412
    Abstract: Calcium hypochlorite compositions that are classified as a Packing Group III Division 5.1 oxidizer material or as a non-Division 5.1 oxidizer material are described. In one embodiment, the compositions comprise an admixture of particulate calcium hypochlorite and particulate metaboric acid. The calcium hypochlorite is present in the composition in an amount and is of a concentration such that the composition would be classified as a Packing Group II Division 5.1 oxidizer in the absence of said particulate metaboric acid. Other embodiments described are solid shaped articles, e.g., tablets, comprising the described calcium hypochlorite-metaboric acid composition.
    Type: Grant
    Filed: February 24, 2005
    Date of Patent: December 16, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Stanley R. Pickens, Fred Abraham, Donald W. DuBois
  • Patent number: 7431863
    Abstract: Describes a composition comprising a mixture of calcium hypochlorite and hydrated magnesium sulfate having an average of from 3 to 5.5 moles of water of hydration per mole of magnesium sulfate. The amount of hydrated magnesium sulfate in the composition is such that the composition has at least a DOT Packing Group III Division 5.1 Classification.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: October 7, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Stanley R. Pickens
  • Patent number: 7427170
    Abstract: A device for applying a thickened cleaning composition to a selected surface area that minimizes or eliminates any unintentional or excess application of the composition and/or minimizes or eliminates any spreading or wicking of the composition beyond the selected surface area after application. A dispensing device featuring the combination of a thickened cleaning composition having a specified rheology and a dispenser with one or more orifices of preferred cross-sectional area that enable convenient application of a cleaning composition to the selected region of a soft or hard surface. Additionally, the dispensing device features cleaning compositions having preferred wicking rates with respect to the treated surfaces so that only the selected stained or soiled region of the surface is effectively treated, as the cleaning compositions will not spread or wick into adjacent regions of the surface where damage may occur.
    Type: Grant
    Filed: May 23, 2005
    Date of Patent: September 23, 2008
    Assignee: The Clorox Company
    Inventors: Gregory Van Buskirk, Martha Adair, Susana M. Nazario, legal representative, Mel Salwasser, Cristina Gancedo
  • Patent number: 7364669
    Abstract: Stable compositions of calcium hypochlorite containing selected hydrated inorganic salts having a sufficiently high enthalpy and the ability to provide water release to sufficiently quench reactions and reduce the potential for conflagration.
    Type: Grant
    Filed: June 4, 2007
    Date of Patent: April 29, 2008
    Assignee: BIO-Lab, Inc.
    Inventor: John P. Garris
  • Patent number: 7179400
    Abstract: The invention is a stabilizer composition for halogen-containing polymers, comprising a carrier material of the general formula CaxAl2(OH)2(x+2)HPO3.m H2O, wherein x is a number from 2 to 12 and m is a number from 0 to 12, and a salt of a halogen-containing oxy acid or a mixture of two or more such salts, at least one salt of a halogen-containing oxy acid being present in finely distributed form on the carrier material, to a process for the preparation thereof, and to the use thereof.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: February 20, 2007
    Assignee: Baerlocher GmbH
    Inventors: Bernd Frischkemuth, Christian Helbig
  • Patent number: 7153438
    Abstract: A composition for disinfecting contaminated drinking water. The composition can include a disinfecting agent for disinfecting or sanitizing the water and a masking agent for masking or minimizing undesired characteristics of the disinfecting agent, such as taste and odor. The disinfecting agent can be a halogen-based disinfecting agent, such as a chlorine-based disinfecting agent. The masking agent can be a chlorine-compatible masking agent or flavorant, such as a citrus fruit derived flavor. The composition can also include a substrate. The substrate can be a clay, zeolite, water-soluble carrier, water-insoluble carrier, or mixtures thereof. The flavorant can be loaded onto the substrate. The composition can include other components, such as a primary coagulant, a coagulant aid, a bridging flocculant, a polymeric material, an alkali agent, an autocatalytic oxidant, and mixtures thereof.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: December 26, 2006
    Assignee: Pur Water Purification Products, Inc.
    Inventors: Philip Frank Souter, Colin Ure
  • Patent number: 7144177
    Abstract: A device dispenser for applying a thickened cleaning composition to a selected surface area that minimizes or eliminates any unintentional or excess application of the composition and/or minimizes or eliminates any spreading or wicking of the composition beyond the selected surface area after application. A dispensing device featuring the combination of a thickened cleaning composition having a specified rheology and dispenser with one or more orifices of preferred cross-sectional area that enable convenient application of a cleaning composition to the selected region of a soft or hard surface. Additionally, the dispensing device features cleaning compositions having preferred wicking rates with respect to the treated surfaces so that only the selected stained or soiled region of the surface is effectively treated, as the cleaning compositions will not spread or wick into adjacent regions of the surface where damage may occur.
    Type: Grant
    Filed: March 4, 2005
    Date of Patent: December 5, 2006
    Assignee: The Clorox Company
    Inventors: Gregory Van Buskirk, Martha Adair, Susana M. Nazario, legal representative, Mel Salwasser, Cristina Gancedo, deceased
  • Patent number: 7045077
    Abstract: Stable compositions of calcium hypochlorite containing selected hydrated inorganic salts having a sufficiently high enthalpy and the ability to provide water release to sufficiently quench reactions and reduce the potential for conflagration.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: May 16, 2006
    Assignee: BioLab, Inc.
    Inventor: John P. Garris
  • Patent number: 7009082
    Abstract: A process is described for reducing the discoloration of PO3G. The discolored polymer is contacted with adsorbent and separated therefrom, for instance, by filtration. The treated polytrimethylene, preferably, has an APHA color of less than about 50 and a molecular weight of about 250 to about 5000.
    Type: Grant
    Filed: August 5, 2003
    Date of Patent: March 7, 2006
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Hari Babu Sunkara, Hiep Quang Do
  • Patent number: 6905276
    Abstract: A device for applying a thickened cleaning composition to a selected surface area that minimizes or eliminates any unintentional or excess application of the composition and/or minimizes or eliminates any spreading or wicking of the composition beyond the selected surface area after application. A dispensing device featuring the combination of a thickened cleaning composition having a specified rheology and dispensing means with one or more orifices of preferred cross-sectional area that enable convenient application of a cleaning composition to the selected region of a soft or hard surface. Additionally, the dispensing device features cleaning compositions having preferred wicking rates with respect to the treated surfaces so that only the selected stained or soiled region of the surface is effectively treated, as the cleaning compositions will not spread or wick into adjacent regions of the surface where damage may occur.
    Type: Grant
    Filed: April 9, 2003
    Date of Patent: June 14, 2005
    Assignee: The Clorox Company
    Inventors: Gregory Van Buskirk, Martha Adair, Susana M. Nazario, Mel Salwasser, Cristina Gancedo
  • Patent number: 6824705
    Abstract: The present invention relates to the use of ethyl tricyclo [5.2.1.025] decan-2-carboxylate in a hypochlorite containing products to reduce the bleach odor on skin, when such products come in contact with human skin.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: November 30, 2004
    Assignee: Colgate-Palmolive Co.
    Inventors: Hedeliza Malonzo Mercado, Colette Lallemant, Pierre Boudot, John N. Labows
  • Patent number: 6602442
    Abstract: A dry disinfectant composition for the production of aqueous solutions of chlorine dioxide of predetermined concentration is formulated of a mixture of lithium hypochlorite, sodium bisulfate and sodium chlorite. Special liquid and dry formulations are also contemplated for convenience of use, for quality assurance and for safety.
    Type: Grant
    Filed: October 12, 2000
    Date of Patent: August 5, 2003
    Assignee: Vulcan Chemicals
    Inventor: Anthony R. Pitochelli
  • Patent number: 6325970
    Abstract: A method comprises feeding a chlorite, a chlorine donor, and an acid into a water line connected to a water system through which water is flowing, or a mixing chamber connected to a water system, wherein the chlorite and chlorine donor being present in a molar ratio from 1.0:0.1 to 1.0:15.0 chlorite to chlorine donor; whereby chlorine dioxide is generated substantially instantaneously in solution and substantially no undissolved chlorine dioxide gas is evolved; and feeding the solution comprising chlorine dioxide into the water system. The solution comprising chlorine dioxide in the mixing chamber can have a chlorine dioxide concentration from 20,000 to 50,000 ppm.
    Type: Grant
    Filed: May 22, 2000
    Date of Patent: December 4, 2001
    Assignee: BTG Inter-Corporate Licensing Limited
    Inventors: Timothy John Parkinson, Arthur Ty Harris
  • Patent number: 6197215
    Abstract: A dry disinfectant composition for the production of aqueous solutions of chlorine dioxide is formulated of a mixture of lithium hypochlorite, sodium bisulfate and sodium chlorite.
    Type: Grant
    Filed: February 25, 1999
    Date of Patent: March 6, 2001
    Assignee: Vulcan Chemicals
    Inventor: Anthony R. Pitochelli