Sulfur Containing Reductant, Bleachant, Deoxidant, Or Generative Patents (Class 252/188.2)
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Patent number: 10850982Abstract: The present invention relates to a method for reducing or preventing the decomposition of a composition Z comprising Z1 a salt of dithionous acid in an amount ranging from 50 to 100 wt % and optionally Z2 an additive selected from the group consisting of alkali metal carbonate, alkaline earth metal carbonate, alkali metal or alkaline earth metal tripolyphosphate (Na5P3O10), alkali metal or alkaline earth metal sulfite, disulfite or sulfate, dextrose and complexing agents in a combined amount ranging from 0.Type: GrantFiled: April 19, 2016Date of Patent: December 1, 2020Assignee: BASF SEInventors: Eberhard Beckmann, Sabine Weiguny, Martin Gärtner, Katharina Federsel
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Patent number: 9724284Abstract: A method of removing a tattoo from skin of a human subject. The method has the step of applying to a region of the skin having the tattoo a reducing composition that includes a reducing agent and a penetration enhancer in admixture. The penetration enhancer is present in an amount effective to effect penetration of at least at least a portion of the reducing agent through the skin to the location of the tattoo. The reducing agent is present in an amount effective to at least partially decolorize or break up a pigment of the tattoo. The reducing agent can be selected from the group consisting of sodium oxymethylene sulfoxylate and sodium hydroxymethane sulfinic acid.Type: GrantFiled: June 16, 2015Date of Patent: August 8, 2017Assignee: Conair CorporationInventors: Leandro P. Rizzuto, Lawrence Cruz
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Patent number: 9028712Abstract: There are provided an oxygen scavenger composition and the like, which are excellent in economy in which the amount of oxygen absorbed per unit volume of the oxygen scavenger composition is large, and rusting at high humidity is inhibited. The oxygen scavenger composition of the present invention comprises (A) an iron powder, (B) a metal bromide and/or a metal iodide, and (C) a thiosulfate.Type: GrantFiled: June 8, 2012Date of Patent: May 12, 2015Assignee: Mitsubishi Gas Chemical Company, Inc.Inventor: Takashi Nakata
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Patent number: 8847000Abstract: It is an object of the present invention to provide a beneficial composition in order to detoxify the harmful compound containing arsenic etc. effectively and systematically and a method for detoxifying a harmful compound by using the composition. The composition for the alkylation according to the present invention is characterized in that the composition contains a cobalt complex. The method of detoxifying the harmful compound according to the present invention is characterized in that a harmful compound containing at least one element selected from the groups comprising arsenic, antimony and selenium is detoxified by the alkylation of the harmful compound, in the presence of the composition according to the present invention.Type: GrantFiled: July 26, 2007Date of Patent: September 30, 2014Assignee: Nippon Sheet Glass Company, LimitedInventors: Koichiro Nakamura, Akihiro Hishinuma, Shinji Kamiya
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Publication number: 20140197359Abstract: An oxygen-scavenging composition includes a sulfide group-containing polyester and a catalyst. The sulfide group-containing polyester is obtained by subjecting a reaction composition to esterification and condensation reactions. The reaction composition includes an aromatic diacid component and a diol component including aliphatic diol and a diol compound represented by the following formula (I): HO—(X1—O)n—X3—S—X4—(O—X2)m—OH??(I) wherein X1 and X2 independently represent a C1-C6 alkylene group, X3 and X4 represent a C6-C10 arylene group, and m and n represent an integer ranging from 1 to 5. The catalyst is for inducing reaction between the sulfide group-containing polyester and oxygen.Type: ApplicationFiled: January 10, 2014Publication date: July 17, 2014Applicant: FAR EASTERN NEW CENTURY CORPORATIONInventors: Fa-Chen Chi, Yi-Hsuan Tang, Yu-Shiang Peng, Wen-Teng Chang
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Publication number: 20140193629Abstract: The present disclosure provides a polyester polymer product which contains partially or fully cobalt-neutralized organic sulphonic acid component and which is substantially free of ether and its preparation. The present disclosure also provides an oxygen scavenging composition made from a mixture of the polyester polymer product of the present disclosure, an organic oxidizable polymeric component and optionally at least one additional polyester component. The present disclosure further provides a packaging article defined by walls having an oxygen transmission rate (OTR) less than 0.2 cc·m?2 day?1 at 0.28 mm thickness and its preparation.Type: ApplicationFiled: February 28, 2014Publication date: July 10, 2014Applicant: Reliance Industries LimitedInventors: Uday Shankar Agarwal, B. V. Venkatarishnan, Rajesh Jalan, Thaliyil Veedu Sreekumar, Srinivasacharya Ramacharya Ayodhya, Ashwin Kumar Jain, Shivamurthy Padadayya Jadimath, Pushap Sudan, Anant Gajanan KelKar
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Patent number: 8758990Abstract: The present invention relates to compositions and methods for detecting Mycobacterium genus (Mycobacterium sp.) bacteria (e.g., M. tuberculosis) and M. avium complex (MAC; M. avium, M. scrofulaceum and M. intracellulaire) in a clinical sample or culture. The present invention also relates to differentiating cultures or samples comprising (Mycobacterium sp.) bacteria (e.g., M. tuberculosis) from cultures or samples comprising M. avium complex (MAC; M. avium, M. scrofulaceum and M. intracellulaire).Type: GrantFiled: October 18, 2007Date of Patent: June 24, 2014Assignee: ID-Fish Technology, Inc.Inventors: Jyotsna S. Shah, Helena Weltman
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Patent number: 8753408Abstract: The invention relates to compositions comprising a combination of (a) at least one organic compound which carries at least one thiol group and at least one optionally derivatized carboxyl group, for example L-cysteine, and (b) at least one organic compound selected from the group which is formed from cyclic, organic carbonates, glycerol and its derivatives and C4-C12 fatty acid dimethylamides. Using these low-odor compositions it is possible to reductively decolor colored keratin-containing fibers, in particular human hair, in a rapid and effective manner.Type: GrantFiled: February 22, 2010Date of Patent: June 17, 2014Assignee: Henkel AG & Co. KGaAInventors: Winfried Emmerling, Holger Bartels, Inge Neubueser
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Publication number: 20140023555Abstract: The present invention includes formulations and methods to reduce Cr(VI) contamination, in which the formulation comprises (1) a reactive reducing agent comprising at least one reducing chemical capable of reducing Cr(VI) to Cr(III); and (b) one or more solvents. Moreover, the present invention includes formulations to reduce Cr(VI) within the coating, and Cr(VI) reducing kits with at least one color reference tool for evaluating the process and/or completion of the Cr(VI) reduction.Type: ApplicationFiled: March 30, 2012Publication date: January 23, 2014Applicant: BATTELLE MEMORIAL INSTITUTEInventors: Bruce F. Monzyk, Paul J. Usinowicz, Derik R. Heiss, Vinay V. Gadkari, John T. Stropki
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Patent number: 8632963Abstract: The present invention provides a method for allowing foreign particles to penetrate, very efficiently, the cell wall, cell membrane, organelle membrane and/or nuclear membrane of a cell and hybridizing or binding to the complimentary target in the cell. The cells may be from a culture or from specimens obtained from a patient. The foreign particle can be a probe consisting of, for example, either individually or in any combination of two or more of the following: DNA, RNA, peptide nucleic acids (PNA), glycopeptides, lipopeptides, glycolipids or prions. The target is a cell, a cell component or, preferably, a pathogen or pathogen component. The pathogen can be, for example, bacteria, fungi, yeast or viruses.Type: GrantFiled: July 27, 2006Date of Patent: January 21, 2014Assignee: ID-FISH Technology Inc.Inventors: Jyotsna Shah, Helena Weltman
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Publication number: 20130200303Abstract: A method of degrading halogenated organic compounds, to use of the method for decontaminating PFOS (perfluorooctanesulfonic acid) and PFOA (perfluorooctanoic acid) contaminated medium, and a composition such as that which is suitable to be applied in said method.Type: ApplicationFiled: February 8, 2012Publication date: August 8, 2013Applicant: Arcadis Nederland B.V.Inventors: Tessa Alida Pancras, Wim Plaisier, Pieter Jacobus Anna Dols, Jan Adriaan Barbier
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Patent number: 8277892Abstract: A method is disclosed for manufacturing one or more oxygen scavenging particles, wherein the particle(s) comprises an oxidizable metal particle, such as elemental iron; an acidifying electrolyte such as sodium or potassium bisulfate and optionally a water hydrolysable Lewis acid, such as aluminum chloride. The method comprises the step of coating the oxidizable particle with a first compound and then reacting the first compound with a second compound to form a third compound, wherein the third compound promotes the reaction of the oxidizable particle with oxygen.Type: GrantFiled: February 23, 2007Date of Patent: October 2, 2012Assignee: Multisorb Technologies, Inc.Inventor: Kevin L. Rollick
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Patent number: 7964111Abstract: The present invention relates to solid compounds which generate hydrogen by combustion, and to a method for generating hydrogen based on the combustion of said compounds. Said compounds have a composition which includes at least one inorganic borohydride, selected from alkali borohydrides, alkaline-earth borohydrides and mixtures thereof, and at least one inorganic oxidant. Characteristically, said composition comprises sulfur. Said method is advantageously implemented for supplying hydrogen to a fuel cell.Type: GrantFiled: July 9, 2008Date of Patent: June 21, 2011Assignee: SNPE Materiaux EnergetiquesInventors: Christian Perut, Joël Renouard
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Publication number: 20110049424Abstract: The present application relates to a process of colour neutralizing treatment liquids, wherein the treatment liquid comprises a chromophore selected from the group consisting of monoazo, triarylmethane, xanthene, anthraquinone, hydrophobic dyes, and mixtures thereof, wherein the hydrophobic dyes are selected from the group consisting of benzodifuranes; methine; triphenylmethanes; naphthalimides; pyrazole; naphthoquinone; mono-azo, di-azo dyes and mixtures thereof, said process comprising the steps of: i. providing a mixing vessel with the treatment composition comprising the chromophore; ii. providing to the mixing vessel more than 0.045% of a reducing agent selected from the group consisting of sulfite, thiodiurea, formaldehyde bisulfite formaldehyde sulfoxilate and mixtures thereof; and iii. mixing until discolouration by color neutralization of the chromophore is achieved.Type: ApplicationFiled: August 23, 2010Publication date: March 3, 2011Inventors: Suzanne Khalaf, Olga Valdimirovna Pryadilova, Regine Labeque
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Publication number: 20100263816Abstract: Steam stripper off gas from chemical pulp mills, for example kraft or sulphite pulp mills is rich in methanol and totally reduced sulphur (TRS) compounds. This gaseous stream is usually burned to avoid further handling of this TRS-rich, odorous stream. We found that once this gaseous stream is condensed, it can be used as a reducing agent in the chlorine dioxide generator, in place of purchased methanol. Surprisingly, we found that, in addition to the methanol component, the TRS components act as reducing agents during the production of chlorine dioxide or, at the very least, do not consume chlorine dioxide. The use of this stream in the ClO2 generator will allow pulp mills to reduce or eliminate the consumption of purchased methanol while providing a new approach to deal with TRS compounds in the chlorine dioxide generator rather than employing a dedicated TRS incinerator or any other combustion device.Type: ApplicationFiled: November 12, 2008Publication date: October 21, 2010Inventors: Naceur Jemaa, Michael Paleogou, George Sacciadis, Richard M. Berry
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Patent number: 7799485Abstract: According to the invention, a fuel cell system features a fuel cell (1) having an electrode (5, 6), and an antioxidant residing in or contacting the electrode (5, 6), for inactivating active oxygen.Type: GrantFiled: July 7, 2005Date of Patent: September 21, 2010Assignee: Nissan Motor Co., Ltd.Inventors: Masashi Ito, Takao Maruyama
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Patent number: 7658288Abstract: Disclosed, among other things, are packaged bisulfite solutions comprising bisulfite reagent in an oxygen-impermeable container and methods.Type: GrantFiled: November 8, 2005Date of Patent: February 9, 2010Assignee: Applied Biosystems, LLCInventors: Yafei Liu, Haley O. Fiske, Steven M. Menchen
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Patent number: 7648032Abstract: Disclosed herein are a method of reductively bleaching a mineral slurry comprising adding in the mineral slurry an effective amount of a formamidine sulfinic acid (FAS) and an effective amount of a borohydride to reductively bleach the mineral slurry, compositions comprising a mineral slurry, a FAS, and a borohydride, and final products comprising a mineral obtained by the method disclosed herein.Type: GrantFiled: March 22, 2005Date of Patent: January 19, 2010Assignee: Imerys Pigments, Inc.Inventors: Jun Yuan, Robert J. Pruett, Larry C. Powell
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Publication number: 20090326313Abstract: It is an object of the present invention to provide a beneficial composition in order to detoxify the harmful compound containing arsenic etc. effectively and systematically and a method for detoxifying a harmful compound by using the composition. The composition for the alkylation according to the present invention is characterized in that the composition contains a cobalt complex. The method of detoxifying the harmful compound according to the present invention is characterized in that a harmful compound containing at least one element selected from the groups comprising arsenic, antimony and selenium is detoxified by the alkylation of the harmful compound, in the presence of the composition according to the present invention.Type: ApplicationFiled: July 26, 2007Publication date: December 31, 2009Applicant: Nippon Sheet Glass Company, LimitedInventors: Koichiro Nakamura, Akihiro Hishinuma, Shinji Kamiya
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Publication number: 20090202407Abstract: An improved method of controlling air pollution, a combustion gas is passed through a solution of an alkaline-earth metal sulfide and a redox buffer (e.g., a mono alkaline-earth metal phosphate salt), preferably but not essentially in combination with an alkaline-earth metal carbonate FGD system. The reagents are provided in a fully soluble form enabling low cost application and retrofitting of existing facilities whilst also including alkaline-earth bases salts, which advantageously afford stability to the process product. The reagents co-precipitate when the solution achieves a pH of 4.5 to 6.5 such as is encountered in the acidic environment in conduits that carry combustion flue gases.Type: ApplicationFiled: January 29, 2009Publication date: August 13, 2009Inventor: Peter J. HURLEY
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Publication number: 20090151779Abstract: There is provided a composition comprising a first compound chosen from compounds of formulas (I) and (III) and a second compound chosen from compounds of formulas (II) and (IV): A-S?M+??(III) A-S—S-A??(IV) Various chemical entities can be used for R1 to R4, A, M, and Z. This composition can be particularly useful as a redox couple.Type: ApplicationFiled: March 29, 2007Publication date: June 18, 2009Inventors: Amer Hammami, Benoit Marsan, Michel Armand, Gregory Hersant
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Publication number: 20090032769Abstract: The present invention provides for liquid antioxidant mixtures of octylated/butylated diphenylamine, phenothiazine and octadecyl (3,5-di-tert-butyl-4-hydroxyphenyl)-propionate. The antioxidant mixtures are useful for polyurethane stabilization.Type: ApplicationFiled: July 31, 2008Publication date: February 5, 2009Inventor: Walid Al-Akhdar
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Patent number: 7125497Abstract: Decontamination formulations for neutralization of toxic industrial chemicals, and methods of making and using same. The formulations are effective for neutralizing malathion, hydrogen cyanide, sodium cyanide, butyl isocyanate, carbon disulfide, phosgene gas, capsaicin in commercial pepper spray, chlorine gas, anhydrous ammonia gas; and may be effective at neutralizing hydrogen sulfide, sulfur dioxide, formaldehyde, ethylene oxide, methyl bromide, boron trichloride, fluorine, tetraethyl pyrophosphate, phosphorous trichloride, arsine, and tungsten hexafluoride.Type: GrantFiled: May 21, 2004Date of Patent: October 24, 2006Assignee: Sandia CorporationInventors: Mark D. Tucker, Rita G. Betty
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Patent number: 7052683Abstract: A chemical compound is disclosed herein for performing a complex enzymatic neutralization and fixation of formaldehyde, providing a method for instantaneous neutralization of formaldehyde vapors and offering a complete and rapid control of incidental releases, and a complete protection of workers against airborne formaldehyde during the course of their work. The compound includes alkanolamine, for instantaneous reaction with formaldehyde, and for absorbing hydrogen sulfide and carbon dioxide from the air, and a human protein, which reacts with airborne formaldehyde and forms the major enzyme involved in formaldehyde oxidation in oral mucosa. The compound also contains cyclodextrins for inclusion complexation of all the components of spent and/or unused aqueous formaldehyde solutions.Type: GrantFiled: November 24, 2003Date of Patent: May 30, 2006Inventor: Gabriel J. Farkas
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Patent number: 6953535Abstract: The invention relates to a redox initiator system which allows dental formulations to be cured in acidic medium by way of a free-radical polymerization and which ensures a high level of adhesion of the polymerizing composition to the hard substances of the teeth, namely enamel and, in particular, dentine. The redox initiator system comprises the following constituents: (A) from 14.9 to 50% by weight of a barbituric acid or thiobarbituric acid and/or of a barbituric or thiobarbituric acid derivative, (B) from 30 to 75% by weight of a peroxodisulfate compound and/or peroxodiphosphate compound, (C) from 10 to 35% by weight of a sulfinic acid compound, and (D) from 0.1 to 5% by weight of a copper compound.Type: GrantFiled: May 13, 2002Date of Patent: October 11, 2005Assignee: 3M Espe AgInventors: Reinhold Hecht, Manfred Ludsteck
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Patent number: 6605234Abstract: Hydroxalkylaminium polysulfides are used to provide cold stability to ammonium polysulfide solutions. Hydroxyalkylaminium sulfides or polysulfides also are used to solubilize unwanted sulfur. Preferred aminium ions are monohydroxyalkylaminium ions, preferably monoethanolaminium ions. When added to an aqueous stream comprising free cyanide ions (including HCN), the polysulfide solution reduces corrosion of metal equipment contacted by the stream by converting the free cyanide ions into thiocyanate ions.Type: GrantFiled: November 23, 1999Date of Patent: August 12, 2003Assignee: Baker Hughes IncorporatedInventors: Glenn L. Roof, Ting S. Go
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Patent number: 6383254Abstract: There are provided a treatment solution for reducing a copper oxide formed on the surface of copper to copper, wherein dimethylamine borane is contained in an amount of 0.3 to 2.0 g/L and the relationship y≧0.232x−0.185 holds between the concentration y (g/L) of dimethylamine borane and an area x (dm2/L) to be treated per unit solution amount, and a treatment method for reducing a copper oxide formed on the surface of a copper material to copper by dipping the copper material in the treatment solution as described above, wherein the addition of dimethylamine borane to water is carried out within 10 minutes before the dipping of the copper material or after the dipping of the copper material.Type: GrantFiled: July 2, 2001Date of Patent: May 7, 2002Assignee: Meltex Inc.Inventors: Yasuji Fujita, Kenji Ikeshima
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Patent number: 6322656Abstract: An improvement in a method of bonding copper and a resin together wherein a copper oxide layer is formed on the surface of copper by the oxidation of metallic copper, the copper oxide layer is reduced to metallic copper with an aqueous reducing solution containing at least one amine borane represented by the general formula: BH3NHRR′ (wherein R and R′ are each a member selected from the group consisting of H, CH3, and CH2CH3), and the metallic copper is bonded to a resin. According to the improvement, a reducing stabilizer is added to the reducing solution in an amount sufficient to decrease consumption of the amine borane during reduction to a level less than that consumed in the absence of the reducing stabilizer during the course of the copper oxide reduction process, wherein the stabilized reduction process is initiated in a reasonable time and the metallic copper layer resulting from the stabilized reduction process is resistant to acid attack.Type: GrantFiled: December 19, 1995Date of Patent: November 27, 2001Assignee: Morton International, Inc.Inventors: John Fakler, Michael Rush, Scott Campbell
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Patent number: 6319288Abstract: A blend is disclosed containing formamidinesulfinic acid, an scale-inhibiting agent that can be neutral or acidic, and/or finely divided silica having good flowability to be used for the purpose of reductive bleaching in the paper and textile industries, whereby, in particular, polcarboxylates and polyacrylic acids are employed having a content of about 10% of a polyamide in the form of a copolymer.Type: GrantFiled: May 19, 1999Date of Patent: November 20, 2001Assignee: Degussa AGInventors: Harald Jakob, Bernd Hopf
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Patent number: 6217933Abstract: The invention relates to a method for treating a denture, comprising passing the denture through the air interface of an aqueous composition comprising a polymeric coating agent, especially a silicone polymer, having a weight average molecular weight of 1,000 or greater.Type: GrantFiled: July 15, 1999Date of Patent: April 17, 2001Assignee: The Procter & Gamble CompanyInventors: Mark Ieuan Edwards, Iain Allan Hughes
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Patent number: 6207073Abstract: A method and composition for the remediation of environmental contaminants in soil, sediment, aquifer material, water, or containers in which contaminants were contained, wherein contaminants are reacted with a remediating composition comprising a metal and a sulfur-containing compound to produce environmentally-acceptable, chemically reduced products. The method is useful for treating contaminants such as halogenated hydrocarbons, pesticides, chemical warfare agents and dyes. The remediating composition preferably contains comminuted, commercial grade iron and iron sulfide. The addition of an alcohol to the reactants enhances the rate of the remediation reaction, particularly for contaminants of soils and sediments.Type: GrantFiled: November 8, 1999Date of Patent: March 27, 2001Assignee: The United States of America as represented by the Environmental Protection AgencyInventors: N. Lee Wolfe, Mark G. Cipollone
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Patent number: 6171347Abstract: A multicomponent kit for coloring and later removing color from fibers is described, which consists of a first component and a second component. The first component includes a composition for oxidative dyeing of hair and the second component includes an aqueous or aqueous-alcoholic composition for reductive removal of color from dyed hair. The composition for reductive removal of color from hair has a pH of from 1.8 to 6 and is in the form of a gel, cream, emulsion, foam or solution. It contains from 1 to 50% by weight of one or more reductones, advantageously ascorbic and/or isoascorbic acid or salts thereof, and, in addition to the reductones, from 0.1 to 10% by weight of one or more thiols or a combination of from 0.1 to 10% by weight of one or more thiols and from 0.001 to 5% by weight of one or more sulfites. It also includes one or more pH adjusting agents and standard cosmetic additive ingredients.Type: GrantFiled: July 1, 1998Date of Patent: January 9, 2001Assignee: Wella AktiengesellschaftInventors: Manuela Kunz, Dominique Le Cruer