Sulfur Containing Reductant, Bleachant, Deoxidant, Or Generative Patents (Class 252/188.2)
  • Patent number: 10850982
    Abstract: The present invention relates to a method for reducing or preventing the decomposition of a composition Z comprising Z1 a salt of dithionous acid in an amount ranging from 50 to 100 wt % and optionally Z2 an additive selected from the group consisting of alkali metal carbonate, alkaline earth metal carbonate, alkali metal or alkaline earth metal tripolyphosphate (Na5P3O10), alkali metal or alkaline earth metal sulfite, disulfite or sulfate, dextrose and complexing agents in a combined amount ranging from 0.
    Type: Grant
    Filed: April 19, 2016
    Date of Patent: December 1, 2020
    Assignee: BASF SE
    Inventors: Eberhard Beckmann, Sabine Weiguny, Martin Gärtner, Katharina Federsel
  • Patent number: 9724284
    Abstract: A method of removing a tattoo from skin of a human subject. The method has the step of applying to a region of the skin having the tattoo a reducing composition that includes a reducing agent and a penetration enhancer in admixture. The penetration enhancer is present in an amount effective to effect penetration of at least at least a portion of the reducing agent through the skin to the location of the tattoo. The reducing agent is present in an amount effective to at least partially decolorize or break up a pigment of the tattoo. The reducing agent can be selected from the group consisting of sodium oxymethylene sulfoxylate and sodium hydroxymethane sulfinic acid.
    Type: Grant
    Filed: June 16, 2015
    Date of Patent: August 8, 2017
    Assignee: Conair Corporation
    Inventors: Leandro P. Rizzuto, Lawrence Cruz
  • Patent number: 9028712
    Abstract: There are provided an oxygen scavenger composition and the like, which are excellent in economy in which the amount of oxygen absorbed per unit volume of the oxygen scavenger composition is large, and rusting at high humidity is inhibited. The oxygen scavenger composition of the present invention comprises (A) an iron powder, (B) a metal bromide and/or a metal iodide, and (C) a thiosulfate.
    Type: Grant
    Filed: June 8, 2012
    Date of Patent: May 12, 2015
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventor: Takashi Nakata
  • Patent number: 8847000
    Abstract: It is an object of the present invention to provide a beneficial composition in order to detoxify the harmful compound containing arsenic etc. effectively and systematically and a method for detoxifying a harmful compound by using the composition. The composition for the alkylation according to the present invention is characterized in that the composition contains a cobalt complex. The method of detoxifying the harmful compound according to the present invention is characterized in that a harmful compound containing at least one element selected from the groups comprising arsenic, antimony and selenium is detoxified by the alkylation of the harmful compound, in the presence of the composition according to the present invention.
    Type: Grant
    Filed: July 26, 2007
    Date of Patent: September 30, 2014
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Koichiro Nakamura, Akihiro Hishinuma, Shinji Kamiya
  • Publication number: 20140197359
    Abstract: An oxygen-scavenging composition includes a sulfide group-containing polyester and a catalyst. The sulfide group-containing polyester is obtained by subjecting a reaction composition to esterification and condensation reactions. The reaction composition includes an aromatic diacid component and a diol component including aliphatic diol and a diol compound represented by the following formula (I): HO—(X1—O)n—X3—S—X4—(O—X2)m—OH??(I) wherein X1 and X2 independently represent a C1-C6 alkylene group, X3 and X4 represent a C6-C10 arylene group, and m and n represent an integer ranging from 1 to 5. The catalyst is for inducing reaction between the sulfide group-containing polyester and oxygen.
    Type: Application
    Filed: January 10, 2014
    Publication date: July 17, 2014
    Applicant: FAR EASTERN NEW CENTURY CORPORATION
    Inventors: Fa-Chen Chi, Yi-Hsuan Tang, Yu-Shiang Peng, Wen-Teng Chang
  • Publication number: 20140193629
    Abstract: The present disclosure provides a polyester polymer product which contains partially or fully cobalt-neutralized organic sulphonic acid component and which is substantially free of ether and its preparation. The present disclosure also provides an oxygen scavenging composition made from a mixture of the polyester polymer product of the present disclosure, an organic oxidizable polymeric component and optionally at least one additional polyester component. The present disclosure further provides a packaging article defined by walls having an oxygen transmission rate (OTR) less than 0.2 cc·m?2 day?1 at 0.28 mm thickness and its preparation.
    Type: Application
    Filed: February 28, 2014
    Publication date: July 10, 2014
    Applicant: Reliance Industries Limited
    Inventors: Uday Shankar Agarwal, B. V. Venkatarishnan, Rajesh Jalan, Thaliyil Veedu Sreekumar, Srinivasacharya Ramacharya Ayodhya, Ashwin Kumar Jain, Shivamurthy Padadayya Jadimath, Pushap Sudan, Anant Gajanan KelKar
  • Patent number: 8758990
    Abstract: The present invention relates to compositions and methods for detecting Mycobacterium genus (Mycobacterium sp.) bacteria (e.g., M. tuberculosis) and M. avium complex (MAC; M. avium, M. scrofulaceum and M. intracellulaire) in a clinical sample or culture. The present invention also relates to differentiating cultures or samples comprising (Mycobacterium sp.) bacteria (e.g., M. tuberculosis) from cultures or samples comprising M. avium complex (MAC; M. avium, M. scrofulaceum and M. intracellulaire).
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: June 24, 2014
    Assignee: ID-Fish Technology, Inc.
    Inventors: Jyotsna S. Shah, Helena Weltman
  • Patent number: 8753408
    Abstract: The invention relates to compositions comprising a combination of (a) at least one organic compound which carries at least one thiol group and at least one optionally derivatized carboxyl group, for example L-cysteine, and (b) at least one organic compound selected from the group which is formed from cyclic, organic carbonates, glycerol and its derivatives and C4-C12 fatty acid dimethylamides. Using these low-odor compositions it is possible to reductively decolor colored keratin-containing fibers, in particular human hair, in a rapid and effective manner.
    Type: Grant
    Filed: February 22, 2010
    Date of Patent: June 17, 2014
    Assignee: Henkel AG & Co. KGaA
    Inventors: Winfried Emmerling, Holger Bartels, Inge Neubueser
  • Publication number: 20140023555
    Abstract: The present invention includes formulations and methods to reduce Cr(VI) contamination, in which the formulation comprises (1) a reactive reducing agent comprising at least one reducing chemical capable of reducing Cr(VI) to Cr(III); and (b) one or more solvents. Moreover, the present invention includes formulations to reduce Cr(VI) within the coating, and Cr(VI) reducing kits with at least one color reference tool for evaluating the process and/or completion of the Cr(VI) reduction.
    Type: Application
    Filed: March 30, 2012
    Publication date: January 23, 2014
    Applicant: BATTELLE MEMORIAL INSTITUTE
    Inventors: Bruce F. Monzyk, Paul J. Usinowicz, Derik R. Heiss, Vinay V. Gadkari, John T. Stropki
  • Patent number: 8632963
    Abstract: The present invention provides a method for allowing foreign particles to penetrate, very efficiently, the cell wall, cell membrane, organelle membrane and/or nuclear membrane of a cell and hybridizing or binding to the complimentary target in the cell. The cells may be from a culture or from specimens obtained from a patient. The foreign particle can be a probe consisting of, for example, either individually or in any combination of two or more of the following: DNA, RNA, peptide nucleic acids (PNA), glycopeptides, lipopeptides, glycolipids or prions. The target is a cell, a cell component or, preferably, a pathogen or pathogen component. The pathogen can be, for example, bacteria, fungi, yeast or viruses.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: January 21, 2014
    Assignee: ID-FISH Technology Inc.
    Inventors: Jyotsna Shah, Helena Weltman
  • Publication number: 20130200303
    Abstract: A method of degrading halogenated organic compounds, to use of the method for decontaminating PFOS (perfluorooctanesulfonic acid) and PFOA (perfluorooctanoic acid) contaminated medium, and a composition such as that which is suitable to be applied in said method.
    Type: Application
    Filed: February 8, 2012
    Publication date: August 8, 2013
    Applicant: Arcadis Nederland B.V.
    Inventors: Tessa Alida Pancras, Wim Plaisier, Pieter Jacobus Anna Dols, Jan Adriaan Barbier
  • Patent number: 8277892
    Abstract: A method is disclosed for manufacturing one or more oxygen scavenging particles, wherein the particle(s) comprises an oxidizable metal particle, such as elemental iron; an acidifying electrolyte such as sodium or potassium bisulfate and optionally a water hydrolysable Lewis acid, such as aluminum chloride. The method comprises the step of coating the oxidizable particle with a first compound and then reacting the first compound with a second compound to form a third compound, wherein the third compound promotes the reaction of the oxidizable particle with oxygen.
    Type: Grant
    Filed: February 23, 2007
    Date of Patent: October 2, 2012
    Assignee: Multisorb Technologies, Inc.
    Inventor: Kevin L. Rollick
  • Patent number: 7964111
    Abstract: The present invention relates to solid compounds which generate hydrogen by combustion, and to a method for generating hydrogen based on the combustion of said compounds. Said compounds have a composition which includes at least one inorganic borohydride, selected from alkali borohydrides, alkaline-earth borohydrides and mixtures thereof, and at least one inorganic oxidant. Characteristically, said composition comprises sulfur. Said method is advantageously implemented for supplying hydrogen to a fuel cell.
    Type: Grant
    Filed: July 9, 2008
    Date of Patent: June 21, 2011
    Assignee: SNPE Materiaux Energetiques
    Inventors: Christian Perut, Joël Renouard
  • Publication number: 20110049424
    Abstract: The present application relates to a process of colour neutralizing treatment liquids, wherein the treatment liquid comprises a chromophore selected from the group consisting of monoazo, triarylmethane, xanthene, anthraquinone, hydrophobic dyes, and mixtures thereof, wherein the hydrophobic dyes are selected from the group consisting of benzodifuranes; methine; triphenylmethanes; naphthalimides; pyrazole; naphthoquinone; mono-azo, di-azo dyes and mixtures thereof, said process comprising the steps of: i. providing a mixing vessel with the treatment composition comprising the chromophore; ii. providing to the mixing vessel more than 0.045% of a reducing agent selected from the group consisting of sulfite, thiodiurea, formaldehyde bisulfite formaldehyde sulfoxilate and mixtures thereof; and iii. mixing until discolouration by color neutralization of the chromophore is achieved.
    Type: Application
    Filed: August 23, 2010
    Publication date: March 3, 2011
    Inventors: Suzanne Khalaf, Olga Valdimirovna Pryadilova, Regine Labeque
  • Publication number: 20100263816
    Abstract: Steam stripper off gas from chemical pulp mills, for example kraft or sulphite pulp mills is rich in methanol and totally reduced sulphur (TRS) compounds. This gaseous stream is usually burned to avoid further handling of this TRS-rich, odorous stream. We found that once this gaseous stream is condensed, it can be used as a reducing agent in the chlorine dioxide generator, in place of purchased methanol. Surprisingly, we found that, in addition to the methanol component, the TRS components act as reducing agents during the production of chlorine dioxide or, at the very least, do not consume chlorine dioxide. The use of this stream in the ClO2 generator will allow pulp mills to reduce or eliminate the consumption of purchased methanol while providing a new approach to deal with TRS compounds in the chlorine dioxide generator rather than employing a dedicated TRS incinerator or any other combustion device.
    Type: Application
    Filed: November 12, 2008
    Publication date: October 21, 2010
    Inventors: Naceur Jemaa, Michael Paleogou, George Sacciadis, Richard M. Berry
  • Patent number: 7799485
    Abstract: According to the invention, a fuel cell system features a fuel cell (1) having an electrode (5, 6), and an antioxidant residing in or contacting the electrode (5, 6), for inactivating active oxygen.
    Type: Grant
    Filed: July 7, 2005
    Date of Patent: September 21, 2010
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Masashi Ito, Takao Maruyama
  • Patent number: 7658288
    Abstract: Disclosed, among other things, are packaged bisulfite solutions comprising bisulfite reagent in an oxygen-impermeable container and methods.
    Type: Grant
    Filed: November 8, 2005
    Date of Patent: February 9, 2010
    Assignee: Applied Biosystems, LLC
    Inventors: Yafei Liu, Haley O. Fiske, Steven M. Menchen
  • Patent number: 7648032
    Abstract: Disclosed herein are a method of reductively bleaching a mineral slurry comprising adding in the mineral slurry an effective amount of a formamidine sulfinic acid (FAS) and an effective amount of a borohydride to reductively bleach the mineral slurry, compositions comprising a mineral slurry, a FAS, and a borohydride, and final products comprising a mineral obtained by the method disclosed herein.
    Type: Grant
    Filed: March 22, 2005
    Date of Patent: January 19, 2010
    Assignee: Imerys Pigments, Inc.
    Inventors: Jun Yuan, Robert J. Pruett, Larry C. Powell
  • Publication number: 20090326313
    Abstract: It is an object of the present invention to provide a beneficial composition in order to detoxify the harmful compound containing arsenic etc. effectively and systematically and a method for detoxifying a harmful compound by using the composition. The composition for the alkylation according to the present invention is characterized in that the composition contains a cobalt complex. The method of detoxifying the harmful compound according to the present invention is characterized in that a harmful compound containing at least one element selected from the groups comprising arsenic, antimony and selenium is detoxified by the alkylation of the harmful compound, in the presence of the composition according to the present invention.
    Type: Application
    Filed: July 26, 2007
    Publication date: December 31, 2009
    Applicant: Nippon Sheet Glass Company, Limited
    Inventors: Koichiro Nakamura, Akihiro Hishinuma, Shinji Kamiya
  • Publication number: 20090202407
    Abstract: An improved method of controlling air pollution, a combustion gas is passed through a solution of an alkaline-earth metal sulfide and a redox buffer (e.g., a mono alkaline-earth metal phosphate salt), preferably but not essentially in combination with an alkaline-earth metal carbonate FGD system. The reagents are provided in a fully soluble form enabling low cost application and retrofitting of existing facilities whilst also including alkaline-earth bases salts, which advantageously afford stability to the process product. The reagents co-precipitate when the solution achieves a pH of 4.5 to 6.5 such as is encountered in the acidic environment in conduits that carry combustion flue gases.
    Type: Application
    Filed: January 29, 2009
    Publication date: August 13, 2009
    Inventor: Peter J. HURLEY
  • Publication number: 20090151779
    Abstract: There is provided a composition comprising a first compound chosen from compounds of formulas (I) and (III) and a second compound chosen from compounds of formulas (II) and (IV): A-S?M+??(III) A-S—S-A??(IV) Various chemical entities can be used for R1 to R4, A, M, and Z. This composition can be particularly useful as a redox couple.
    Type: Application
    Filed: March 29, 2007
    Publication date: June 18, 2009
    Inventors: Amer Hammami, Benoit Marsan, Michel Armand, Gregory Hersant
  • Publication number: 20090032769
    Abstract: The present invention provides for liquid antioxidant mixtures of octylated/butylated diphenylamine, phenothiazine and octadecyl (3,5-di-tert-butyl-4-hydroxyphenyl)-propionate. The antioxidant mixtures are useful for polyurethane stabilization.
    Type: Application
    Filed: July 31, 2008
    Publication date: February 5, 2009
    Inventor: Walid Al-Akhdar
  • Patent number: 7125497
    Abstract: Decontamination formulations for neutralization of toxic industrial chemicals, and methods of making and using same. The formulations are effective for neutralizing malathion, hydrogen cyanide, sodium cyanide, butyl isocyanate, carbon disulfide, phosgene gas, capsaicin in commercial pepper spray, chlorine gas, anhydrous ammonia gas; and may be effective at neutralizing hydrogen sulfide, sulfur dioxide, formaldehyde, ethylene oxide, methyl bromide, boron trichloride, fluorine, tetraethyl pyrophosphate, phosphorous trichloride, arsine, and tungsten hexafluoride.
    Type: Grant
    Filed: May 21, 2004
    Date of Patent: October 24, 2006
    Assignee: Sandia Corporation
    Inventors: Mark D. Tucker, Rita G. Betty
  • Patent number: 7052683
    Abstract: A chemical compound is disclosed herein for performing a complex enzymatic neutralization and fixation of formaldehyde, providing a method for instantaneous neutralization of formaldehyde vapors and offering a complete and rapid control of incidental releases, and a complete protection of workers against airborne formaldehyde during the course of their work. The compound includes alkanolamine, for instantaneous reaction with formaldehyde, and for absorbing hydrogen sulfide and carbon dioxide from the air, and a human protein, which reacts with airborne formaldehyde and forms the major enzyme involved in formaldehyde oxidation in oral mucosa. The compound also contains cyclodextrins for inclusion complexation of all the components of spent and/or unused aqueous formaldehyde solutions.
    Type: Grant
    Filed: November 24, 2003
    Date of Patent: May 30, 2006
    Inventor: Gabriel J. Farkas
  • Patent number: 6953535
    Abstract: The invention relates to a redox initiator system which allows dental formulations to be cured in acidic medium by way of a free-radical polymerization and which ensures a high level of adhesion of the polymerizing composition to the hard substances of the teeth, namely enamel and, in particular, dentine. The redox initiator system comprises the following constituents: (A) from 14.9 to 50% by weight of a barbituric acid or thiobarbituric acid and/or of a barbituric or thiobarbituric acid derivative, (B) from 30 to 75% by weight of a peroxodisulfate compound and/or peroxodiphosphate compound, (C) from 10 to 35% by weight of a sulfinic acid compound, and (D) from 0.1 to 5% by weight of a copper compound.
    Type: Grant
    Filed: May 13, 2002
    Date of Patent: October 11, 2005
    Assignee: 3M Espe Ag
    Inventors: Reinhold Hecht, Manfred Ludsteck
  • Patent number: 6605234
    Abstract: Hydroxalkylaminium polysulfides are used to provide cold stability to ammonium polysulfide solutions. Hydroxyalkylaminium sulfides or polysulfides also are used to solubilize unwanted sulfur. Preferred aminium ions are monohydroxyalkylaminium ions, preferably monoethanolaminium ions. When added to an aqueous stream comprising free cyanide ions (including HCN), the polysulfide solution reduces corrosion of metal equipment contacted by the stream by converting the free cyanide ions into thiocyanate ions.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: August 12, 2003
    Assignee: Baker Hughes Incorporated
    Inventors: Glenn L. Roof, Ting S. Go
  • Patent number: 6383254
    Abstract: There are provided a treatment solution for reducing a copper oxide formed on the surface of copper to copper, wherein dimethylamine borane is contained in an amount of 0.3 to 2.0 g/L and the relationship y≧0.232x−0.185 holds between the concentration y (g/L) of dimethylamine borane and an area x (dm2/L) to be treated per unit solution amount, and a treatment method for reducing a copper oxide formed on the surface of a copper material to copper by dipping the copper material in the treatment solution as described above, wherein the addition of dimethylamine borane to water is carried out within 10 minutes before the dipping of the copper material or after the dipping of the copper material.
    Type: Grant
    Filed: July 2, 2001
    Date of Patent: May 7, 2002
    Assignee: Meltex Inc.
    Inventors: Yasuji Fujita, Kenji Ikeshima
  • Patent number: 6322656
    Abstract: An improvement in a method of bonding copper and a resin together wherein a copper oxide layer is formed on the surface of copper by the oxidation of metallic copper, the copper oxide layer is reduced to metallic copper with an aqueous reducing solution containing at least one amine borane represented by the general formula: BH3NHRR′ (wherein R and R′ are each a member selected from the group consisting of H, CH3, and CH2CH3), and the metallic copper is bonded to a resin. According to the improvement, a reducing stabilizer is added to the reducing solution in an amount sufficient to decrease consumption of the amine borane during reduction to a level less than that consumed in the absence of the reducing stabilizer during the course of the copper oxide reduction process, wherein the stabilized reduction process is initiated in a reasonable time and the metallic copper layer resulting from the stabilized reduction process is resistant to acid attack.
    Type: Grant
    Filed: December 19, 1995
    Date of Patent: November 27, 2001
    Assignee: Morton International, Inc.
    Inventors: John Fakler, Michael Rush, Scott Campbell
  • Patent number: 6319288
    Abstract: A blend is disclosed containing formamidinesulfinic acid, an scale-inhibiting agent that can be neutral or acidic, and/or finely divided silica having good flowability to be used for the purpose of reductive bleaching in the paper and textile industries, whereby, in particular, polcarboxylates and polyacrylic acids are employed having a content of about 10% of a polyamide in the form of a copolymer.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: November 20, 2001
    Assignee: Degussa AG
    Inventors: Harald Jakob, Bernd Hopf
  • Patent number: 6217933
    Abstract: The invention relates to a method for treating a denture, comprising passing the denture through the air interface of an aqueous composition comprising a polymeric coating agent, especially a silicone polymer, having a weight average molecular weight of 1,000 or greater.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: April 17, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Mark Ieuan Edwards, Iain Allan Hughes
  • Patent number: 6207073
    Abstract: A method and composition for the remediation of environmental contaminants in soil, sediment, aquifer material, water, or containers in which contaminants were contained, wherein contaminants are reacted with a remediating composition comprising a metal and a sulfur-containing compound to produce environmentally-acceptable, chemically reduced products. The method is useful for treating contaminants such as halogenated hydrocarbons, pesticides, chemical warfare agents and dyes. The remediating composition preferably contains comminuted, commercial grade iron and iron sulfide. The addition of an alcohol to the reactants enhances the rate of the remediation reaction, particularly for contaminants of soils and sediments.
    Type: Grant
    Filed: November 8, 1999
    Date of Patent: March 27, 2001
    Assignee: The United States of America as represented by the Environmental Protection Agency
    Inventors: N. Lee Wolfe, Mark G. Cipollone
  • Patent number: 6171347
    Abstract: A multicomponent kit for coloring and later removing color from fibers is described, which consists of a first component and a second component. The first component includes a composition for oxidative dyeing of hair and the second component includes an aqueous or aqueous-alcoholic composition for reductive removal of color from dyed hair. The composition for reductive removal of color from hair has a pH of from 1.8 to 6 and is in the form of a gel, cream, emulsion, foam or solution. It contains from 1 to 50% by weight of one or more reductones, advantageously ascorbic and/or isoascorbic acid or salts thereof, and, in addition to the reductones, from 0.1 to 10% by weight of one or more thiols or a combination of from 0.1 to 10% by weight of one or more thiols and from 0.001 to 5% by weight of one or more sulfites. It also includes one or more pH adjusting agents and standard cosmetic additive ingredients.
    Type: Grant
    Filed: July 1, 1998
    Date of Patent: January 9, 2001
    Assignee: Wella Aktiengesellschaft
    Inventors: Manuela Kunz, Dominique Le Cruer