Abstract: An oxygen and carbon dioxide absorbent comprising (A) a particulate substance wherein the particles of a hydrous alkali substance are covered with separator particles, (B) iron powder and (C) an electrolyte and a process for storing coffee by using the same is disclosed.
Abstract: Acid gases are removed from waste gases by contacting said gases with an orbent which is a direct reaction product a mixture of red mud and an alkaline earth metal hydroxide or aluminum oxide.
Abstract: A method for removing sulfurous gases such as H.sub.2 S and COS from a fuel gas is disclosed wherein limestone particulates containing iron sulfide provide catalytic absorption of the H.sub.2 S and COS by the limestone. The method is effective at temperatures of 400.degree. C. to 700.degree. C. in particular.
Type:
Grant
Filed:
December 21, 1978
Date of Patent:
February 24, 1981
Assignee:
The United States of America as represented by the United States Department of Energy
Abstract: Removal of hydrogen sulfide from gases using iron oxide-containing solids is improved by introducing a liquid containing a primary or secondary amine into the iron oxide-containing solids.
Abstract: A process for removing SO.sub.x pollutants from a stack gas by (1) absorbing the SO.sub.x pollutants with an aqueous absorbent containing a formate compound and (2) regenerating the spent absorbent containing dissolved SO.sub.x compounds by contact, in the presence of added formate anion, with a water-insoluble, solid substance containing one or more tertiary amine functional groups. Nitrogen monoxide is removed by providing an aqueous absorbent of an iron(II) chelate, such as a chelate of ferrous ion with ethylenediaminetetraacetic acid. Regeneration of spent absorbent containing absorbed NO is accomplished under the same conditions as for spent absorbents containing absorbed SO.sub.x compounds. SO.sub.x and NO pollutants dissolved in the absorbent are, during regeneration, converted to sulfur and nitrogen without the discharge of waste solids.
Abstract: The application is concerned with a process for the manufacture of an aqueous iron (III)-chloride-sulfate solution by the oxidation of iron (II) sulfate with chlorine in aqueous solution.
Type:
Grant
Filed:
March 8, 1978
Date of Patent:
June 10, 1980
Assignee:
Kronos Titan GmbH
Inventors:
Achim Hartmann, Achim Kulling, Dieter Schinkitz, Edgar Klein
Abstract: Pulverent solid sorption agent is injected into and, optionally, admixed with a stream of noxious-contaminant-containing gas and then separated from such gas. The solid sorption agent comprises an alkali-metal and/or alkaline-earth-metal compound and advantageously contains iron-III-oxide; such agent is preferably in the form of dust developed during production of iron or steel.
Type:
Grant
Filed:
October 21, 1977
Date of Patent:
May 6, 1980
Inventors:
Heinz Holter, Heinz Gresch, Heinrich Igelbuscher
Abstract: An oxygen absorbent comprising iron and a metal halide, characterized in that the iron contains sulfur in an amount of from 0.05% to 5% on the basis of the weight of the iron is disclosed.
Abstract: In a "first" scrubbing operation, the sulfur dioxide containing flue gas is scrubbed with an aqueous solution containing ferric sulfate and aluminum sulfate. The ferric sulfate oxidizes the sulfur dioxide to sulfuric acid, which dissolves in the solution, and is reduced to ferrous sulfate. In a subsequent "second" scrubbing operation, the solution, now containing ferrous sulfate, aluminum sulfate, and sulfuric acid, is scrubbed with air. This regenerates, or re-oxidizes the ferrous sulfate to ferric sulfate. The presence of aluminum sulfate accelerates the rate of regeneration. The regenerated solution is then returned to its function in a "first" scrubbing operation, and the indicated cycle of "first" and "second" scrubbing operations are repeated.
Abstract: Hydrogen sulfide is effectively removed from hot gaseous mixtures useful for industrial purposes by employing a solid absorbent consisting of silica-supported iron oxide in pellet form.
Type:
Grant
Filed:
March 1, 1976
Date of Patent:
May 16, 1978
Assignee:
The United States of America as represented by the United States Department of Energy
Abstract: This disclosure describes a process for the preparation of iron-bearing and calcium-bearing sorbent solids for use in the desulfurization of gases. The process involves mechanical procedures for generating porous agglomerated solids that are high in surface area and uniquely suitable in both particle size and mechanical properties for processing in gas-solids contacting equipment of conventional design. The process also involves the use of water in the agglomeration procedures in quantities controlled to react both chemically and mechanically with solid components of the feed materials and to generate adhesive cement between finely divided solids in porous agglomerated particles of the sorbent product.
Abstract: A spill of a compound providing cyanide ion is cleaned up by mixing with the spilled cyanide compound a composition containing a powdered ferrous sulfate and an alkali or alkaline earth metal carbonate.
Abstract: A highly sorbent iron oxide for use in the purification of dilute sulfur and oxygen-bearing gases is prepared by a two step process which involves a low temperature decomposition of iron sulfate and a low temperature oxidation of the intermediate product.