Basis-iron Containing Patents (Class 252/191)
  • Patent number: 4366179
    Abstract: An oxygen and carbon dioxide absorbent comprising (A) a particulate substance wherein the particles of a hydrous alkali substance are covered with separator particles, (B) iron powder and (C) an electrolyte and a process for storing coffee by using the same is disclosed.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: December 28, 1982
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Takanari Nawata, Toshio Komatsu, Masayuki Ohtsuka
  • Patent number: 4341745
    Abstract: Acid gases are removed from waste gases by contacting said gases with an orbent which is a direct reaction product a mixture of red mud and an alkaline earth metal hydroxide or aluminum oxide.
    Type: Grant
    Filed: July 18, 1980
    Date of Patent: July 27, 1982
    Assignee: Kommanditgesellschaft "ALBERTA" Chemische Fabrik GmbH & Co.
    Inventors: Hans Zopff, Hans-Ekkehard Muller
  • Patent number: 4252778
    Abstract: A method for removing sulfurous gases such as H.sub.2 S and COS from a fuel gas is disclosed wherein limestone particulates containing iron sulfide provide catalytic absorption of the H.sub.2 S and COS by the limestone. The method is effective at temperatures of 400.degree. C. to 700.degree. C. in particular.
    Type: Grant
    Filed: December 21, 1978
    Date of Patent: February 24, 1981
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Ralph T. Yang, Ming-Shing Shen
  • Patent number: 4238463
    Abstract: Removal of hydrogen sulfide from gases using iron oxide-containing solids is improved by introducing a liquid containing a primary or secondary amine into the iron oxide-containing solids.
    Type: Grant
    Filed: June 28, 1979
    Date of Patent: December 9, 1980
    Assignee: Chevron Research Company
    Inventor: Stephen W. Nicksic
  • Patent number: 4222991
    Abstract: A process for removing SO.sub.x pollutants from a stack gas by (1) absorbing the SO.sub.x pollutants with an aqueous absorbent containing a formate compound and (2) regenerating the spent absorbent containing dissolved SO.sub.x compounds by contact, in the presence of added formate anion, with a water-insoluble, solid substance containing one or more tertiary amine functional groups. Nitrogen monoxide is removed by providing an aqueous absorbent of an iron(II) chelate, such as a chelate of ferrous ion with ethylenediaminetetraacetic acid. Regeneration of spent absorbent containing absorbed NO is accomplished under the same conditions as for spent absorbents containing absorbed SO.sub.x compounds. SO.sub.x and NO pollutants dissolved in the absorbent are, during regeneration, converted to sulfur and nitrogen without the discharge of waste solids.
    Type: Grant
    Filed: May 18, 1978
    Date of Patent: September 16, 1980
    Assignee: Union Oil Company of California
    Inventor: Robert H. Hass
  • Patent number: 4207201
    Abstract: The application is concerned with a process for the manufacture of an aqueous iron (III)-chloride-sulfate solution by the oxidation of iron (II) sulfate with chlorine in aqueous solution.
    Type: Grant
    Filed: March 8, 1978
    Date of Patent: June 10, 1980
    Assignee: Kronos Titan GmbH
    Inventors: Achim Hartmann, Achim Kulling, Dieter Schinkitz, Edgar Klein
  • Patent number: 4201751
    Abstract: Pulverent solid sorption agent is injected into and, optionally, admixed with a stream of noxious-contaminant-containing gas and then separated from such gas. The solid sorption agent comprises an alkali-metal and/or alkaline-earth-metal compound and advantageously contains iron-III-oxide; such agent is preferably in the form of dust developed during production of iron or steel.
    Type: Grant
    Filed: October 21, 1977
    Date of Patent: May 6, 1980
    Inventors: Heinz Holter, Heinz Gresch, Heinrich Igelbuscher
  • Patent number: 4166807
    Abstract: An oxygen absorbent comprising iron and a metal halide, characterized in that the iron contains sulfur in an amount of from 0.05% to 5% on the basis of the weight of the iron is disclosed.
    Type: Grant
    Filed: November 28, 1977
    Date of Patent: September 4, 1979
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Toshio Komatsu, Yoshiaki Inoue, Megumu Yuyama
  • Patent number: 4157988
    Abstract: In a "first" scrubbing operation, the sulfur dioxide containing flue gas is scrubbed with an aqueous solution containing ferric sulfate and aluminum sulfate. The ferric sulfate oxidizes the sulfur dioxide to sulfuric acid, which dissolves in the solution, and is reduced to ferrous sulfate. In a subsequent "second" scrubbing operation, the solution, now containing ferrous sulfate, aluminum sulfate, and sulfuric acid, is scrubbed with air. This regenerates, or re-oxidizes the ferrous sulfate to ferric sulfate. The presence of aluminum sulfate accelerates the rate of regeneration. The regenerated solution is then returned to its function in a "first" scrubbing operation, and the indicated cycle of "first" and "second" scrubbing operations are repeated.
    Type: Grant
    Filed: July 18, 1977
    Date of Patent: June 12, 1979
    Assignee: American Electronic Laboratories, Inc.
    Inventor: Leopold Pessel
  • Patent number: 4089809
    Abstract: Hydrogen sulfide is effectively removed from hot gaseous mixtures useful for industrial purposes by employing a solid absorbent consisting of silica-supported iron oxide in pellet form.
    Type: Grant
    Filed: March 1, 1976
    Date of Patent: May 16, 1978
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: William L. Farrior, Jr.
  • Patent number: 4061716
    Abstract: This disclosure describes a process for the preparation of iron-bearing and calcium-bearing sorbent solids for use in the desulfurization of gases. The process involves mechanical procedures for generating porous agglomerated solids that are high in surface area and uniquely suitable in both particle size and mechanical properties for processing in gas-solids contacting equipment of conventional design. The process also involves the use of water in the agglomeration procedures in quantities controlled to react both chemically and mechanically with solid components of the feed materials and to generate adhesive cement between finely divided solids in porous agglomerated particles of the sorbent product.
    Type: Grant
    Filed: June 18, 1976
    Date of Patent: December 6, 1977
    Inventor: Patrick John McGauley
  • Patent number: 4011098
    Abstract: A spill of a compound providing cyanide ion is cleaned up by mixing with the spilled cyanide compound a composition containing a powdered ferrous sulfate and an alkali or alkaline earth metal carbonate.
    Type: Grant
    Filed: October 22, 1975
    Date of Patent: March 8, 1977
    Assignee: J. T. Baker Chemical Company
    Inventor: James W. Seidenberger
  • Patent number: 4008169
    Abstract: A highly sorbent iron oxide for use in the purification of dilute sulfur and oxygen-bearing gases is prepared by a two step process which involves a low temperature decomposition of iron sulfate and a low temperature oxidation of the intermediate product.
    Type: Grant
    Filed: March 7, 1975
    Date of Patent: February 15, 1977
    Inventor: Patrick John McGauley