Co, S, Negative Element, Or Acid, Bindant Containing Patents (Class 252/189)
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Patent number: 11497230Abstract: The embodiments disclose a method including processing and treating at least one water source supply for mixing with humic acid and fulvic acid, chopping and pulverizing at least one humate source, mixing the chopped and pulverized at least one humate source with the processed and treated at least one water source supply, processing the chopped and pulverized at least one humate source and the processed and treated at least one water source supply for separating, segregating, and suspending fulvic acid and humic acid molecules from the at least one humate source, storing the fulvic acid and humic acid molecules in a fresh quantity of the treated water source supply, adjusting the pH level of the stored fulvic acid and humic acid, and creating at least one or more beverage product for human consumption using the fulvic acid and humic acid molecule ingredients and other ingredients including vitamins, flavorings and additives.Type: GrantFiled: November 30, 2020Date of Patent: November 15, 2022Inventors: Louise Wilkie, Jacqueline Wilkie
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Patent number: 11478743Abstract: A thermochemical energy storage system and method of storing thermal energy are described. The energy storing system described herein comprises a reactor comprising: a) a reactor with a CO2 sorbent including MgO; and b) a supercritical CO2 source with supercritical CO2 and H2O, wherein the supercritical CO2 source is in fluid communication with the reactor and the CO2 sorbent including MgO to allow flow of the supercritical CO2 and H2O between the supercritical CO2 source and the reactor, thereby allowing contact of CO2 with the CO2 sorbent comprising MgO.Type: GrantFiled: September 18, 2019Date of Patent: October 25, 2022Assignee: Southern Research InstituteInventor: Andrew Jerome Muto
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Patent number: 10815415Abstract: Sulfide stress cracking of a metal component may be inhibited by treating the metal component with a mixture comprising at least one organic aldehyde and at least one surfactant. Such metal components may be those suitable for use in a downhole environment, at a well site, in a storage facility, in a transportation infrastructure, in a refinery facility, and any combination thereof where the metal component may be exposed to hydrogen sulfide.Type: GrantFiled: October 16, 2014Date of Patent: October 27, 2020Assignee: Halliburton Energy Services, Inc.Inventors: Gong Chen, Juanita M. Cassidy, Jim L. Lane
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Patent number: 10786781Abstract: A carbon dioxide separation and capture apparatus includes an absorption tower configured to cause an absorbing liquid to absorb a carbon dioxide gas contained in a process gas and a regeneration tower configured to cause the absorbing liquid from the absorption tower to release the carbon dioxide gas. The carbon dioxide separation and capture apparatus further includes an inlet concentration meter configured to measure concentration of an acid component in the process gas supplied to the absorption tower and an outlet concentration meter configured to measure concentration of the acid component in the process gas discharged from the absorption tower.Type: GrantFiled: December 21, 2016Date of Patent: September 29, 2020Assignee: Kabushiki Kaisha ToshibaInventors: Keita Nagano, Mitsuru Udatsu, Masatoshi Hodotsuka
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Patent number: 10711204Abstract: The present invention relates to a hydrogen sulphide scavenging additive composition for scavenging hydrogen sulphide including sulfur containing compounds and mercaptans, particularly for scavenging hydrogen sulfide in hydrocarbons, wherein the additive composition comprises substantially reduced amount of nitrogen based hydrogen sulfide scavengers, and is also required in substantially reduced amount, and wherein the additive composition scavenges the sulfur containing compounds not only at room temperature, but also at higher temperatures, and comprises at least a combination of: (A) at least one nitrogen based hydrogen sulfide scavenger; and (B) at least one aliphatic tertiary amine, wherein the nitrogen based hydrogen sulfide scavenger comprises triazine based hydrogen sulfide scavenger.Type: GrantFiled: December 23, 2016Date of Patent: July 14, 2020Assignee: Dorf Ketal Chemicals (India) Private LimitedInventor: Mahesh Subramaniyam
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Patent number: 10137407Abstract: An absorbent is prepared by dissolving in water 1) monoethanolamine (MEA) and 2) a primary amine represented by the following formula (1) and having high steric hindrance. Releasability of CO2 or H2S during regeneration of the absorbent is thereby improved, and the amount of water vapor used during regeneration of the absorbent in a facility for recovering CO2 or H2S can be reduced. R1 to R3: H or a hydrocarbon group having 1 to 3 carbon atoms, at least one of R1 to R3 being a hydrocarbon.Type: GrantFiled: April 25, 2013Date of Patent: November 27, 2018Assignees: MITSUBISHI HEAVY INDUSTRIES ENGINEERING, LTD., THE KANSAI ELECTRIC POWER CO., INC.Inventors: Hiroshi Tanaka, Hiromitsu Nagayasu, Takuya Hirata, Tsuyoshi Oishi, Takashi Kamijo
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Patent number: 10137404Abstract: The gaseous effluent is contacted with an aqueous solution comprising at least one amine and at least one amine degradation inhibiting compound. A stainless steel withstanding corrosion upon contact with the amine degradation inhibiting compound is first selected. Equipments whose surfaces in contact with the aqueous solution are made from this stainless steel are used.Type: GrantFiled: August 26, 2013Date of Patent: November 27, 2018Assignee: IFP ENERGIES NOUVELLESInventors: Jean Kittel, Serge Gonzalez, Eric Lemaire, Alexandre Bonneau
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Patent number: 9956520Abstract: A carbon dioxide absorbent composition is described, including (i) a liquid, nonaqueous silicon-based material, functionalized with one or more groups that either reversibly react with CO2 or have a high-affinity for CO2, and (ii) a hydroxy-containing solvent that is capable of dissolving both the silicon-based material and a reaction product of the silicon-based material and CO2. The absorbent may be utilized in methods to reduce carbon dioxide in an exhaust gas, and finds particular utility in power plants.Type: GrantFiled: September 9, 2016Date of Patent: May 1, 2018Assignee: General Electric CompanyInventors: Robert James Perry, Grigorii Lev Soloveichik, Malgorzata Iwona Rubinsztajn, Michael Joseph O'Brien, Larry Neil Lewis, Tunchiao Hubert Lam, Sergei Kniajanski, Dan Hancu
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Patent number: 9878356Abstract: The invention relates to composite adsorbent materials, and in particular, to highly porous carbon-based composite materials for the adsorption and stabilization of inorganic substances. The composite adsorbent material comprises a porous carbon carrier matrix and an adsorbent species, wherein the adsorbent species is precipitated within the pores of the carrier matrix. The invention extends to various uses of such adsorbent materials, for example in water purification, recovery of metals from waste streams and remediation applications, and where the adsorbant material is amended into soil, waste etc. for the purpose of breaking pollutant-receptor linkages.Type: GrantFiled: July 31, 2013Date of Patent: January 30, 2018Assignees: The University of Surrey, The Forestry CommissionInventors: Franciscus Antonius Anna Maria De Leij, James Stratford, Helen Sneath, Tony Hutchings
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Patent number: 9816029Abstract: An organic amine decarbonization solution includes: i) one or more organic amines serving as a carbon dioxide absorbent; and ii) an antioxidant. The antioxidant includes: a) one or more organometallic complexes of Formula [Mx(L)y]An, wherein each M independently represents a central atom selected from the group consisting of transition metals, Group IVA metals and Group VA metals at a lower valence state; each L independently represents a bidentate or multidentate organic ligand with each ligating atom thereof being independently one of O, S, N and P; each A independently represents an uncoordinated counter-ion suitable for forming an outer sphere of a complex; x is 1, 2 or 3; y is 1, 2, 3, 4, 5, 6, 7 or 8; and n is 0, 1, 2, 3 or 4; and b) optionally one or more metal chelating agents.Type: GrantFiled: June 18, 2014Date of Patent: November 14, 2017Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF NANJING CHEMICAL INDUSTRIAL GROUPInventors: Songbai Mao, Zhongbin Huang
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Patent number: 9776883Abstract: The disclosure features methods that include obtaining a first plurality of particles that include calcium carbonate, where the particles have a distribution of sizes between 8 mm and 12 mm, and heating the first plurality of particles to a temperature of between 900° C. and 1200° C. for a time period of at least 1 hour to generate a second plurality of particles that include calcium oxide.Type: GrantFiled: September 26, 2016Date of Patent: October 3, 2017Assignee: Clean World Technologies Ltd.Inventor: Lupércio Tarcísio de Oliveira
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Patent number: 9631467Abstract: A method of performing a squeeze treatment comprises pumping a treatment fluid under pressure through a wellbore into a subterranean formation, wherein the treatment fluid includes a hydrogen sulfide scavenging compound that adsorbs onto the subterranean formation in a region around the wellbore. Production fluids are then allowed to flow from the subterranean formation into the wellbore, wherein the production fluids contact the adsorbed hydrogen sulfide scavenging compound as the production fluids flow through the region around the wellbore, and wherein the production fluids contain hydrogen sulfide that reacts with the hydrogen sulfide scavenging compound to reduce an amount of hydrogen sulfide in the production fluids before the production fluids flow into the wellbore.Type: GrantFiled: December 17, 2013Date of Patent: April 25, 2017Assignee: Ecolab USA Inc.Inventors: Joseph P. Bailey, Aaron D. Martinez, Erick J. Acosta Otero, Ravindranath Mukkamala, Maximilian A. Silvestri, Jose M. Macias
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Patent number: 9630139Abstract: Functionalized alpha-hydroxy alkyl ethers have been found to perform as non (or anti-) scaling hydrogen sulfide scavengers. A method of scavenging hydrogen sulfide includes contacting a fluid containing hydrogen sulfide with a treatment fluid including a functionalized alpha-hydroxy alkyl ether. Accordingly, the alpha-hydroxy alkyl ether reacts with the hydrogen sulfide to reduce the amount of hydrogen sulfide in the fluid. The functionalized alpha-hydroxy alkyl ether is functionalized with a phosphate group, phosphonate group, sulfate group, or sulfonate group. A broad range of alpha-hydroxy alkyl ethers are disclosed.Type: GrantFiled: December 17, 2013Date of Patent: April 25, 2017Assignee: Ecolab USA Inc.Inventors: Aaron D. Martinez, Erick J. Acosta Otero, Maximilian A. Silvestri, Joseph P. Bailey, Jose M. Macias
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Patent number: 9550168Abstract: A programmable pH buffer comprises a copolymer that changes pKa at a lower critical solution temperature (LCST) in water. The copolymer comprises a thermally programmable polymer that undergoes a hydrophobic-to-hydrophilic phase change at the LCST and an electrolytic polymer that exhibits acid-base properties that are responsive to the phase change. The programmable pH buffer can be used to sequester CO2 into water.Type: GrantFiled: September 24, 2015Date of Patent: January 24, 2017Assignee: Sandia CorporationInventors: Dara Van Gough, Dale L. Huber, Bruce C. Bunker, Mark E. Roberts
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Patent number: 9468882Abstract: The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures. The aqueous alkanolamine solution comprises (i) an amino compound with the formula: R1R2NCH2CH(OH)CH2OH wherein R1 and R2 independently represent lower alkyl groups of 1 to 3 carbon atoms and (ii) an acid or acid-forming material having a pKa equal to or less than 8, optionally (iii) another amino compound, and optionally (iv) a physical solvent. Further, the present invention relates to a process for removing acid gases from a gaseous mixture, preferably hydrogen sulfide, comprising the step of contacting the gaseous mixture with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140° F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.Type: GrantFiled: June 6, 2013Date of Patent: October 18, 2016Assignee: Dow Global Technologies LLCInventors: Christophe R. Laroche, Gerardo Padilla, Timothy D. Halnon
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Patent number: 9458367Abstract: A liquid aminoether acid gas absorbent which is subject to freezing in a cold climatic zone though which the aminoether is to be shipped is rendered freeze-resistant by mixing the aminoether with water prior to transport through the cold climatic zone; the aminoether/water mixture typically contains 10 to 40 weight percent water, based on the weight of the aminoether. The aminoether/water mixture can also be stored in the cold climatic zone without being externally maintained at a temperature above the inherent freezing point of the aminoether.Type: GrantFiled: March 11, 2013Date of Patent: October 4, 2016Assignee: ExxonMobil Research and Engineering CompanyInventors: Michael Siskin, Robert Basil Fedich, Michel Daage
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Patent number: 9375676Abstract: A recovery apparatus of carbon dioxide includes: an absorption column contacting a carbon dioxide-containing gas into contact with an absorbing liquid and allowing the absorbing liquid to absorb carbon dioxide; a regeneration column for regenerating the absorbing liquid to release carbon dioxide; a circulation system which circulates the absorbing liquid to flow from the absorption column and return to the absorption column through the regeneration column; and a steam supply system which generates steam available for a heat source that regenerates the absorbing liquid, using the absorbing liquid that returns to the absorption column and/or the absorbing liquid in the absorption column, and supplies the steam to the regeneration column. High temperature steam is generated from the absorbing liquid and is provided to the regeneration column to use as a heat source for regenerating the absorbing liquid.Type: GrantFiled: January 17, 2012Date of Patent: June 28, 2016Assignee: IHI CorporationInventors: Shiko Nakamura, Tomoya Muramoto, Yuichi Nishiyama, Shinya Okuno
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Patent number: 9248209Abstract: Compositions comprising hydrophobically modified malodor control polymers and methods thereof are provided. In some embodiments, the composition comprises a malodor control polymer, a malodor counteractant comprising a perfume, an aqueous carrier, and a ph of about 6 to about 8. Such compositions may be used to reduce or neutralize malodors on surfaces or in the air.Type: GrantFiled: January 14, 2011Date of Patent: February 2, 2016Assignee: The Procter & Gamble CompanyInventors: Ricky Ah-Man Woo, Cahit Eylem, Yonas Gizaw, Larissa Azirbayeva, Zaiyou Liu, Jeffrey Scott Dupont
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Patent number: 9074767Abstract: A rotary bottom ash regenerating (RBAR) system [100] comprises a cylindrical body that receives ash [17] containing reactant particles [10] that are partially reacted limestone compounds having unreacted cores [13] from a furnace. Sensors [140] sense physical parameters within the cylindrical body [110]. A controller [170] receives the output of the sensors [140] and information indicating the amount of unreacted core [13] and causes a fluid actuator [135] to spray a proper amount of regeneration fluid regulator [135] from a plurality of spray nozzles [131] to different locations within the cylindrical body [110] to regulate the temperature and to cause the reactant particles [10] to have a require content of regeneration fluid. This causes the reactant particles [10] to be regenerated and reused. This results in a lower limestone costs and less overheating of ash handling systems.Type: GrantFiled: January 19, 2011Date of Patent: July 7, 2015Assignee: ALSTOM Technology LtdInventor: Iqbal F. Abdulally
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Patent number: 9045337Abstract: The system contained within this application for non-provisional patent protection provides the ability to convert municipal solid waste materials, used tires, various biomass including wood chips and other agricultural waste, and the addition of coal into synthesis gas (syngas), with oxygen as plasma gas. The system will accommodate the possibility for variation in feedstock co-gasification of the various materials with plasma torches that will be embedded in a plasma gasification unit. One converted into synthesis gas (syngas), the syngas will be cleaned of acid gases and carbon dioxide (CO2). Carbon dioxide will be captured and converted for various industrial applications instead of being released into the atmosphere. Clean syngas generated by the system will become the gas fuel for various energy solutions including clean electricity, as substitute for natural gas, and ultra clean FT synthetic fuels.Type: GrantFiled: June 27, 2011Date of Patent: June 2, 2015Inventor: Lai O. Kuku
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Patent number: 9034100Abstract: The invention relates to CO2 capturing binder with an amortized environmental cost, the method of manufacture thereof by means of selecting, purifying and optimizing the carbide lime paste for use as a cementing material, and aggregates for the manufacture of lime paints and slurries, stuccos, mortars and concretes having multiple applications in the construction industry, in architectural restoration, in public works and land conditioning, object of the present invention. It is basically characterized in that the raw material is the residue in the form of sludge generated in the industrial manufacture of acetylene (C2H2) from calcium carbide (CaC2) the fundamental component of which is calcium hydroxide (Ca(OH)2) in highly reactive nanometric formations treated in a specific manner according to the invention.Type: GrantFiled: May 4, 2010Date of Patent: May 19, 2015Assignee: GEOSILEX TRENZA METAL, S.L.Inventors: Miguel Angel Bermejo Sotillo, Carlos Rodriguez Navarro, Encarnación Ruiz Agudo, Kerstin Elert
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Publication number: 20150125372Abstract: Compositions comprising an organic salt, an amine and water are described herein. The methods of using the compositions include the removal of an acid gas from a gas mixture.Type: ApplicationFiled: May 14, 2012Publication date: May 7, 2015Applicants: ION ENGINEERING, THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ALABAMAInventors: Ronald C. Stites, Jerrod Hohman, Trevor Carlisle, Andrew L. Lafrate, Jason E. Bara, Gregory Allan Staab, Michael C. Huffman
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Publication number: 20150110695Abstract: The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures. The aqueous alkanolamine solution comprises (i) an amino compound with the formula: R1R2NCH2CH(OH)CH2OH wherein R1 and R2 independently represent lower alkyl groups of 1 to 3 carbon atoms and (ii) an acid or acid-forming material having a pKa equal to or less than 8, optionally (iii) another amino compound, and optionally (iv) a physical solvent. Further, the present invention relates to a process for removing acid gases from a gaseous mixture, preferably hydrogen sulfide, comprising the step of contacting the gaseous mixture with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140° F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.Type: ApplicationFiled: June 6, 2013Publication date: April 23, 2015Applicant: Dow Global Technologies LLCInventors: Christophe R. Laroche, Gerardo Padilla, Timothy D. Halnon
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Publication number: 20150096231Abstract: Elemental sulfur carrying capacity of a hydrocarbonaceous solvent is improved by first loading the solvent with sulfur and subsequent hydrotreatment under conditions that convert at least some of the elemental sulfur in the sulfur loaded solvent to hydrogen sulfide while preserving at least 95% of the monoaromatic and polyaromatic components in the solvent.Type: ApplicationFiled: October 7, 2014Publication date: April 9, 2015Inventors: Curt Graham, Garry Jacobs, Jesus Cabrera, Ghaith Aljazzar
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Patent number: 8992868Abstract: Dry processes, apparatus, compositions and systems are provided for reducing emissions of mercury and optionally sulfur oxides and/or HCl. In an embodiment the copper-based mercury remediation composition comprises a copper ammonium complex having an empirical formula of C2H7CuNO2 or any of the other materials described, which include compositions defined by the formula Cu(NH3)x(lower carboxylate)y, wherein the lower carboxylate is selected from the group consisting of formate, acetate and propionate, x is an integer from 0 to 4, y is an integer from 0 to 2, and x+y is equal to or greater than 1. Sulfur oxides and/or HCl can be additionally reduced by introduction of dolomite hydrate sorbent, and additional mercury remediation chemicals as manganese oxides can be employed. The treated gas stream is treated with a particulate removal device.Type: GrantFiled: April 30, 2013Date of Patent: March 31, 2015Assignee: Fuel Tech, Inc.Inventors: Christopher R. Smyrniotis, Kent W. Schulz, Emelito P. Rivera, Mingming Fang, Ian Saratovsky
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Publication number: 20150087755Abstract: The present invention relates to a composition, which comprises a) an organic material susceptible to oxidative, thermal or light-induced degradation, which is a polymer, an oligohydroxy compound, a wax, a fat or a mineral oil, with the proviso that the polymer is not a polypeptide, agar-agar or a component of agar-agar and the oligohydroxy compound is not glucose or a component of agar-agar; and b) a compound of formula (I) n is 1, 2, 3 or 4; when n is 1, R5 is H, C1-C30-alkyl, C3-C10-cycloalkyl, C6-C10-aryl, which is unsubstituted or substituted by C1-C8-alkyl, C1-C8-alkoxy, halogen or one phenyl, C7-C13-aralkyl, C2-C22-alkenyl, C3-C12-alkinyl, OH, C1-C30-alkyloxy, C3-C10-cycloalkyloxy, C6-C12-aryloxy, C7-C13-aralkyloxy, hydroxy-C1-C8-alkyl, carboxy-C1-C12-alkyl, C1-C12-alkoxycarbonyl-C1-C12-alkyl, C2-C30-alkyl, which is interrupted by one or more oxygen atoms, C2-C16-alkyl, which is interrupted by one sulfur atom, or NR?1R?2; when n is 2, R5 is C1-C12-alkane-diyl, C6-C14-arylene, C4-C8-cycloalkane-bis-(C1-Type: ApplicationFiled: March 19, 2013Publication date: March 26, 2015Applicant: BASF SEInventors: Werner Hoelzl, Bruno Rotzinger
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Publication number: 20150083964Abstract: Apparatus and process for removal of volatile degradation products from the absorbent circuit of a CO2 separation process are provided. The CO2 separation process may use the absorbent circuit in an absorption process and a desorption process. Condensate is withdrawn from a condensation process connected downstream of the desorption process, and purified to substantially free such condensate of degradation products. The purified condensate is recycled back to the absorbent circuit.Type: ApplicationFiled: August 1, 2012Publication date: March 26, 2015Applicant: SIEMENS AKTIENGESELLSCHAFTInventors: Björn Fischer, Erwin Johannes Martinus Giling, Earl Lawrence Vincent Goetheer, Ralph Joh, Markus Kinzl, Diego Andres Kuettel, Rüdiger Schneider, Jan Harm Urbanus
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Publication number: 20150087532Abstract: Disclosed herein are methods and compositions for purifying proteins from crude solutions.Type: ApplicationFiled: March 15, 2013Publication date: March 26, 2015Inventors: Patrick Brown, R. Edward Watts, Pehr Harbury
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Publication number: 20150073150Abstract: Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a blend of piperazine and at least one diamine or triamine.Type: ApplicationFiled: July 18, 2014Publication date: March 12, 2015Inventors: Gary Rochelle, Omkar Namjoshi, Le Li, Yang Du, Thu Nguyen
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Publication number: 20150056114Abstract: Disclosed are a compound including an oxalate, a carbon dioxide absorbent including the same, a method of preparing the carbon dioxide absorbent and a method of removing carbon dioxide, which may overcome issues of high recycling energy and low absorptivity of a conventional carbon dioxide absorbent to considerably reduce recycling energy and absorb a greater amount of carbon dioxide per unit absorbent, so that a size of a carbon dioxide absorption tower may be reduced and a less amount of recycling energy may be used, contributing to a substantial decrease in device manufacture costs and management costs.Type: ApplicationFiled: December 24, 2013Publication date: February 26, 2015Applicant: KOREA INSTITUTE OF ENERGY RESEARCHInventors: Soon Kwan JEONG, Yeo II YOON, Sung Chan NAM, Soo Hyun CHOI, Sung Ho YOON, Nam Seok KIM, Bon Sik JOO
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Patent number: 8961821Abstract: A process of treating a gas stream containing mercury and acid gas pollutants is disclosed. The process includes applying a sorbent composition into a gas stream in order to adsorb mercury containing compounds and acid gas pollutants. The sorbent composition includes a compound having the formula (SiO2)x(OH)yMzSaF.B. The combination of basic inorganic solids for the adsorption of acid gases, and metal sulfide-doped silica for the adsorption of mercury provides dual sorbent functionality, along with additional benefits for each individual sorbent: silica for moisture retention on the surface of the basic inorganic particle and adsorption of acid gas, which will improve metal sulfide performance at higher operating temperatures. The use of a hygroscopic solid effectively dries the metal sulfide-doped silica slurry without the use of filtration of drying equipment, providing significant economic benefit for the manufacture of metal sulfide-doped silica material.Type: GrantFiled: November 25, 2013Date of Patent: February 24, 2015Assignee: Ecolab USA Inc.Inventors: Nicholas S. Ergang, Ian Saratovsky, Tommy Chen
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Publication number: 20150007728Abstract: Disclosed is an aqueous solution for absorbing and recovering carbon dioxide from a carbon dioxide-containing gas, the aqueous solution containing an amino alcohol compound represented by Formula I and an amine compound represented by Formula 2, wherein R represents an alkyl group having 1 to 5 carbon atoms; and n represents 1 or 2, wherein X represents —NR1R2; Y represents —NR3R4; R1, R2, R3 and R4 may be the same or different, and each represents an alkyl group having 1 to 3 carbon atoms; and m represents an integer of 3 to 7.Type: ApplicationFiled: February 7, 2013Publication date: January 8, 2015Inventors: Takayuki Higashii, Firoz A. Chowdhury, Kazuya Goto, Masami Onoda, Yoichi Matsuzaki
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Patent number: 8916120Abstract: Dry processes, apparatus, compositions and systems are provided for reducing emissions of sulfur oxides, and sulfur dioxide in particular, and/or HCl in a process employing a combination of a dolomite hydrate sorbent and a sorbent doping agent administered to achieve coverage of a three-dimensional cross section of a passage carrying SOx and/or HCl —containing gases with a short but effective residence time at a temperature effective to provide significant sulfur dioxide and/or HCl reductions with high rates of reaction and sorbent utilization. The once-through, dry process can advantageously introduce the sorbent and sorbent doping agent dry or preferably as a slurry to enable uniform treatment. Preferred sorbent doping agents include water-soluble or water-dispersible copper and/or iron compositions which can be heated to an active form in situ by the flue gases being treated.Type: GrantFiled: April 1, 2013Date of Patent: December 23, 2014Assignee: Fuel Tech, Inc.Inventors: Christopher R. Smyrniotis, Kent W. Schulz, Emelito P. Rivera, Mingming Fang, Ian Saratovsky
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Publication number: 20140370578Abstract: A process of removing SO2 from a flue gas with a trickling filter using modified ceramsite packing is described. The biological flue gas desulfurization process includes: feeding the flue gas containing sulfur dioxide through the column bottom into the biomembrane trickling filter at certain temperature, contacting with the modified ceramsite biomembrane packing and purifying, which purified flue gas is discharged via the column top; and spraying the nutrient fluid rich in high concentration of the desulfurization strain through the top to the modified ceramsite biomembrane packing, thereby the sulfur-bearing pollution source in the flue gas is degraded, so as to discharge a purified flue gas satisfying the environmental requirements.Type: ApplicationFiled: June 18, 2014Publication date: December 18, 2014Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF NANJING CHEMICAL INDUSTRIAL GROUPInventors: Aixiang HAO, Songbai Mao, Jing Kong
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Publication number: 20140367612Abstract: An organic amine decarbonization solution includes: i) one or more organic amines serving as a carbon dioxide absorbent; and ii) an antioxidant. The antioxidant includes: a) one or more organometallic complexes of Formula [Mx(L)y]An, wherein each M independently represents a central atom selected from the group consisting of transition metals, Group IVA metals and Group VA metals at a lower valence state; each L independently represents a bidentate or multidentate organic ligand with each ligating atom thereof being independently one of O, S, N and P; each A independently represents an uncoordinated counter-ion suitable for forming an outer sphere of a complex; x is 1, 2 or 3; y is 1, 2, 3, 4, 5, 6, 7 or 8; and n is 0, 1, 2, 3 or 4; and b) optionally one or more metal chelating agents.Type: ApplicationFiled: June 18, 2014Publication date: December 18, 2014Applicants: China Petroleum & Chemical Corporation, Research Institute of Nanjing Chemical Industrial GroupInventors: Songbai MAO, Zhongbin Huang
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Publication number: 20140370289Abstract: The present disclosure relates generally to methods and active materials for purifying gas streams containing halide as a contaminant, for example, in amounts as low as parts-per-million (ppm) or even parts-per-billion (ppb). In one aspect of the invention, an active material includes (a) one or more first metals each present as a metal oxide or metal hydroxide, the first metals being selected from the group consisting of iron, cobalt, nickel, copper, ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold; and (b) one or more second metals each present as a metal oxide or metal hydroxide, the one or more second metals being selected from the group consisting of alkali metals, alkaline earth metals, scandium, yttrium, titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, technetium, and rhenium.Type: ApplicationFiled: June 13, 2013Publication date: December 18, 2014Inventors: Justin X. Wang, Simran K. Sokhey, Jason E. Spencer, Yeping Cai
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Publication number: 20140353550Abstract: The invention is directed to an additive composition comprising at least one clarifying and/or nucleating agent for polyolefins, which agent is a powder having a melting point of at least 190° C., in an amount of at least 70 wt. %, based on the weight of the composition, and at least one wax having a viscosity, as defined herein of at least 500 m Pa·s, in an amount between 0.5 and 30 wt. %, based on the weight of the composition.Type: ApplicationFiled: August 14, 2012Publication date: December 4, 2014Applicant: HOLLAND COLOURS N.V.Inventors: Johannes Henricus Hurenkamp, Caspar Jules Albert Anton Roelofs, Jeroen Marissen
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Patent number: 8894956Abstract: Disclosed is an sorbent for removing sulfur dioxide (SO2) contained in combustion flue gases or in the atmosphere by using a diamine-based ionic liquid or a diamine compound supported by a polymer resin. To be specific, the present invention relates to a method of using a tertiary diamine compound immobilized on a polymer surface as a SO2 sorbent and also relates to a novel sorbent for absorbing or adsorbing a sulfur dioxide hydrate (SO2.H2O) formed by a bond between SO2 and water.Type: GrantFiled: November 22, 2013Date of Patent: November 25, 2014Assignee: Korea Institute of Science and TechnologyInventors: Hyun Joo Lee, Seung Rok Lim, Kean Im Lee, Chang Soo Kim, Hoon Sik Kim, Ji Sik Choi, Sang Deuk Lee
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Patent number: 8894954Abstract: The present invention provides a process for removing mercaptans from a gas stream gas stream, comprising the steps: a) providing a first mercaptan-comprising gas stream comprising at least a mercaptan of the general formula: R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms; and b) contacting the mercaptan-comprising gas stream with an absorption medium comprising a substituted disulphide and a nitrogen-containing base to obtain a second mercaptan-depleted gas stream, wherein: the substituted disulphide is of the general formula R2—SS—R3 wherein: R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapor pressure below the vapor pressure of any R1—SH thiol.Type: GrantFiled: November 30, 2011Date of Patent: November 25, 2014Assignee: Shell Oil CompanyInventors: Jozef Jacobus Titus Smits, Sipke Hidde Wadman
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Patent number: 8894955Abstract: The present invention provides a process for removing mercaptans from a gas stream. In the process, a first mercaptan-comprising gas stream comprising at least a mercaptan of the general formula: R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms, and an acid component is contacted with an absorption medium to obtain a mercaptan-depleted gas stream. The absorption medium includes a substituted disulphide and a base. The substituted disulphide is of the general formula R2—SS—R3, wherein R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapor pressure below the vapor pressure of any R1—SH thiol, and at least one of R2 and R3 is an electron withdrawing group.Type: GrantFiled: December 6, 2011Date of Patent: November 25, 2014Assignee: Shell Oil CpmpanyInventors: Jozef Jacobus Titus Smits, Sipke Hidde Wadman
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Publication number: 20140339468Abstract: A method for separating arsenic and heavy metals in an acidic washing solution which contains both arsenic and heavy metal, more particularly in a washing solution which is formed in copper smelting and contains sulphuric acid, comprises a separation process section, in which arsenic and at least one primary heavy metal are separated from one another. The separation process section comprises a processing step, in which hydrogen peroxide H2O2 is added to the washing solution, and the separation process section comprises a precipitation stage, in which the washing solution is admixed with a sulphide precipitation reagent, causing the at least one primary heavy metal to precipitate in the form of a metal sulphide. The processing step in this system is carried out before the precipitation stage.Type: ApplicationFiled: October 26, 2012Publication date: November 20, 2014Inventors: Angela Ante, Marc-Peter Hofmann
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Publication number: 20140288293Abstract: Compositions and methods for the efficient extraction, enrichment and isolation of nucleic acids from fresh, fixed or fixed and embedded cells, tissues, biological materials and cellular source material.Type: ApplicationFiled: March 14, 2014Publication date: September 25, 2014Inventor: Gerard J. Gundling
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Publication number: 20140275510Abstract: Compositions and methods for the efficient extraction, enrichment and isolation of nucleic acids from fresh, fixed or fixed and embedded cells, tissues, biological materials and cellular source material.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: Abbott Molecular Inc.Inventor: Gerard J. Gundling
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Publication number: 20140231311Abstract: A composition useful for scavenging hydrogen sulfide by admixing metal carboxylates which have high viscosity due to polymerization and a viscosity improver selected from the group consisting of glycol ethers having from about 4 to about 10 carbons and alkyl alcohols having from about 1 to about 4 carbons.Type: ApplicationFiled: February 18, 2014Publication date: August 21, 2014Applicant: BAKER HUGHES INCORPORATEDInventors: Corina L. Sandu, Yun Bao, Jerry J. Weers, Ross Poland, Philip L. Leung, Lei Zhang, John A. Schield
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Publication number: 20140227766Abstract: Materials and methods for use of constrained cohydration agents in the purification of biological materials such as antibodies, viruses, cells, and cellular organelles in connection with convective chromatography, fluidized bed or co-precipitation applications.Type: ApplicationFiled: June 1, 2012Publication date: August 14, 2014Applicant: AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCHInventor: Peter Stanley Gagnon
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Publication number: 20140190870Abstract: The use of a composition including a transition metal salt and at least one water-soluble aldehyde or water-soluble aldehyde precursor scavenges H2S that is present in aqueous fluids (e.g. produced water liquid streams), natural gas and in oil and mixtures thereof (e.g. mixed production streams that contain all three phases) better than either component when used alone. The resulting scavenger combination significantly increases the reaction rate and the overall scavenging efficiency, i.e. capacity over the case where each component is used alone, in the same total amount. Non-limiting examples of the metal salt include zinc or iron carboxylates, and a non-limiting example of a water-soluble aldehyde or water-soluble aldehyde precursor is ethylene glycol hemiformal.Type: ApplicationFiled: January 7, 2014Publication date: July 10, 2014Applicant: Baker Hughes IncorporatedInventors: SCOTT E. LEHRER, Vladimir Jovancicevic, Sunder Ramachandran
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Publication number: 20140186923Abstract: Disclosed herein are compounds, compositions, methods and kits for purifying a serine protease and serine proteases purified with the compounds, compositions and methods.Type: ApplicationFiled: March 14, 2013Publication date: July 3, 2014Applicant: Portola Pharmaceuticals, Inc.Inventor: Portola Pharmaceuticals, Inc.
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Publication number: 20140186246Abstract: Methods are provided for synthesizing novel types of self-assembled siloxanes, such as polysiloxanes, with a sufficiently high density of amine functional groups to be useful for CO2 capture and release processes. Additionally, it has been unexpectedly found that some self-assembled polysiloxanes can be used for high temperature adsorption of CO2.Type: ApplicationFiled: November 25, 2013Publication date: July 3, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: David C. Calabro, Quanchang Li, Dennis G. Peiffer, Mobae Afeworki, Stephen M. Cundy, Charanjit S. Paur, Peter I. Ravikovitch
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Publication number: 20140175334Abstract: The invention concerns a capture mass for capturing heavy metals in a liquid or gaseous effluent, comprising a porous solid support, copper sulphide and at least one second metal sulphide the metal of which is selected from the group constituted by chromium, manganese, iron, cobalt and nickel, and in which the ratio of the percentage by weight of the metal or metals other than copper to the percentage by weight of copper is in the range 0.01 to 2. The invention also concerns a process for preparing said capture mass and a process for capturing heavy metals in a gaseous or liquid effluent, in which said effluent is brought into contact with said capture mass.Type: ApplicationFiled: December 17, 2013Publication date: June 26, 2014Applicant: IEP Energies nouvellesInventors: Fabien PORCHERON, Arnaud BAUDOT, Karin BARTHELET
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Publication number: 20140171721Abstract: Processes and compositions for scavenging hydrogen sulfide from hydrocarbon streams are disclosed that reduce, if not substantially eliminate, the formation of crystalline or amorphous solids even under cold conditions. The compositions used in the processes comprise a hexahydrotriazine component and an amphiphilic component that form a hydrophobic micelle when the hexahydrotriazine component becomes spent.Type: ApplicationFiled: December 19, 2013Publication date: June 19, 2014Applicant: Coastal Chemical Co., L.L.C.Inventor: Roy Bertrand, III